Patent Application
20130306350
This application claims the benefit of priority from European Patent Application No. 11 306 665.8, filed on Dec. 15, 2011, the entirety of which is incorporated by reference.
1. Field of the Invention
The present invention relates to a temperature resistant electrical line, particularly for use as an installation line in buildings, which may consist of an encased strand, or may have two, three or more strands in a casing.
The electrical line according to the invention is distinguished by the fact that it is temperature resistant, particularly up to 90° C., that it is halogen free, and meets the requirements of Standard UL83, particularly a maximum permissible temperature of use of 90° C., a high resistance to flame development and fire.
2. Description of Related Art
Single-strand lines of this type consist of a solid or stranded conductor, particularly aluminum or copper, on which rests a temperature resistant insulation layer of PVC, which is surrounded by a casing of a polyamide containing polymer mixture, in particular nylon.
U.S. Pat. No. 5,521,009 describes strands in which the conductor has an insulation layer of 20 to 80 phr or percent by weight ethylene propylene copolymer or another polyolefin, wherein the resistance to deformation or against foaming when heated can be increased by an addition of polyamide, polyphenylene sulfide, polybutylene terephthalate, polyethylene terephthalate, polyether ketone, and polyether ketone and polyether ether ketone as crystalline aromatic polymer or their mixtures. For increasing the heat resistance, 0.1-5 phr of a retarded phenol antioxidant can be added, particularly in order to increase the decomposition, foaming or deformation up to 200° C. for a short period of time. An insulation layer of polyamide is not provided. The flame resistance of the mixture is not discussed.
U.S. Pat. No. 5,358,786 describes an insulation layer for wires of 20 to 80 phr (percent by weight) polyolefin. For the flame resistance, an additional outer layer can be applied, in accordance with a second embodiment, around the insulated wire, while such a flame retardant layer of polyphenylene oxide, polyarylate, polyether ether ketone, and polyetherimide are indicated. The flame resistance of the mixture is not addressed.
WO 97/41569 describes strands insulated by means of polyolefin, a layer which may be of polyamide placed on the polyolefin, and an outer casing of polyvinylidene fluoride. It is mentioned that polyolefin ignites easily and that flame retardant ingredients negatively affect the electrical properties and physical properties of polyolefin.
It is the object of the invention to make available an electrical line, which has a similar or higher resistance to fire than lines whose strands have an insulation layer of PVC within a nylon casing, which has a maximum temperature resistance of at least 90° C. and is halogen free.
Further preferred, it should be possible to manufacture the layers which surround the conductor, at most, for the same costs as a conventional temperature and fire resistant halogen containing electrical line whose strands consist of a conductor with an insulation layer of PVC within a casing of nylon.
The invention meets this object with the features of the Claims, particularly with an electrical line with a maximum temperature resistance of at least 90° C. and particularly with fire properties which meet the Standard UL83 (corresponds to CSA Standard C22.2 No.75-08) and is halogen free as a result, has at least one electrical strand which consists of a conductor, especially solid or stranded aluminum or copper and a flame retardant, temperature resistant, halogen free insulation layer surrounding the conductor, wherein the strand is surrounded by a casing of a polyamide containing polymer mixture, particularly of polyamide. The casing rests on the insulation layer of the strand, or the line has an intermediate layer which forms an intermediate casing and borders the insulation layers of at least two strands and the casing which includes the in layer, which is also called intermediate casing.
The insulation layer of a strand consists of a halogen free polymer mixture which comprises or consists of
Preferably, the polymer mixture of which the insulating layer of the strand consists, comprises or consists of
optionally 2 to 15 phr silicon, in particular dimethylsiloxane oil and/or polydimethylsiloxane rubber,
optionally an inorganic salt, in particular an oxide of a two valent metal ion, for example, from the group comprising or consisting of calcium, magnesium, strontium, barium and zinc, for example, at 1 to 15 phr,
preferably a total of 0.1 to 20 phr stabilizers and processing aids.
The parts indicated in the mixtures are given as phr (parts per hundred rubber), i.e. the parts by weight of the components are indicated from 100 parts by weight organic polymer, selected from polyolefin and/or polyethylene. Therefore, phr correspond to percent by weight in relation to the content of organic cross linkable polymer.
The casing preferably consists of a second polymer mixture whose polymer component comprises or consists of, polyamide, preferably with a composition which comprises or consists of
This polyamide containing polymer mixture may consist of polyamide, particularly PA6, PA4 and/or PA12, to which optionally flame protection agent, processing aids and/or stabilizers are added.
The electrical line according to the invention preferably has the mechanical properties and fire properties which are defined in Standard UL83 for THHN lines with a casing of polyamide (particularly nylon).
Alternatively or additionally, the insulation layer of the strand, when stored in air of 97±1° C. for at least twelve weeks, at most 36 weeks, at least during the last 6 weeks of storage at increased temperature, should be 3 GΩm or more, particularly for use as installation line in surroundings up to at most at least 90° C. Preferably, during the storage at 97±1° C. and/or while measuring the resistance of the insulation layer, a voltage of 600 volts rms is applied.
Preferably, the electrical line according to the invention is not damaged at room temperature after aging at 136° C. in the convection oven for seven days, particularly no cracks after winding onto a coil in accordance with Standard UL83. In addition, after this aging, the tensile strength is at least 75% of the initial value, and/or the elongation at rupture is at least 65% of the initial value.
Preferably, the line according to the invention has, in the deforming test according to UL83 at 136±1° C., a maximum decrease of the thickness of 30% under load.
In particular, the line according to the invention has a flame and fire resistance according to UL83, particularly such that the flames, after use of a test flame five times for 15 s each with interruptions of 15 s each, expire again within 60 s or, that after the use of the test flame, no more flames are present after 60 s, and particularly without dripping of material which could ignite a cotton cloth arranged underneath the line.
The line according to the invention may have a single strand or may consist of a conductor, the insulating layer surrounding the conductor, and a casing of: a polyamide containing polymer mixture which rests on the insulating layer.
Alternatively, the electrical line may consist of two or more strands, each of which has an insulation layer surrounding the conductor, within a casing of a polyamide containing polymer mixture surrounding the strands.
In an embodiment, the electrical line may consist of two, three or more strands whose insulating layers, each surrounded by a separate directly placed polyamide containing polymer mixture, are contained in a common casing of a temperature resistant, halogen free polymer mixture according to the invention. In this embodiment it is preferred that the insulating layer of each strand has the same composition as the temperature proof, halogen free polymer mixture within which the strands are contained with their respective casings of a polyamide containing polymer mixture. Optionally, an additional outer casing of a polyamide containing polymer mixture may be placed on the temperature proof, halogen free polymer mixture which has, at the two or more strands, a conductor each, an insulating layer each and a casing each placed on the insulating layer of a polyamide containing polymer mixture.
In another embodiment, the line according to the invention may have two, three or more strands, each of which consist of a conductor and an insulating layer of a temperature proof, halogen free polymer mixture surrounding the conductor, an intermediate layer which surrounds the strands and consists of a temperature proof, halogen free polymer mixture, and may have or consist of an outer casing placed on the intermediate layer of a polyamide containing polymer mixture.
In the Figures identical reference numerals refer to functionally equivalent elements.
Preferred embodiments of cables have, for example, at least one strand with an insulation of the conductor of a mixture according to the invention (HFFR), and an intermediate layer of polyamide (PA), and a casing of a mixture according to the invention based on polyolefin (HFFR),
at least one strand with an insulation of the conductor of: a mixture according to the invention (HFFR), an intermediate layer of polyamide (PA) and a casing of polyamide (PA),
at least one strand with an insulation of the conductor of a mixture according to the invention (HFFR), an intermediate layer of polyamide (PA) and a two-layer casing of an intermediate layer of the mixture according to the invention with an outer layer of polyamide (HFFR/PA) placed thereon, or
at least one strand with an insulation of the conductor of a mixture according to the invention based on polyolefin (HFFR) with a two-layer casing of an intermediate layer of a mixture according to the invention with an outer layer of polyamide (HFFR/PA) placed thereon, or consists thereof.
The advantageous properties of the halogen free mixture (HFFR), according to the invention, are demonstrated in the following tables for electrical lines having one strand whose insulation consists of HFFR (HFFR 1 and HFFR 2) or of PVC for comparison, with a casing of polyamide.
The mixture HFFR 1 consists of:
and the mixture HFFR 2 consists of:
This data shows that the halogen free polymer mixture according to the invention provides the lines with sufficiently high mechanical strength values and good fire resistance and temperature properties, in particular, develops less smoke and the fire gasses have a significantly lower corrosiveness.
The invention will now be described in more detail with reference to the Figures which schematically show
In the Figures identical reference numerals refer to functionally equivalent elements.
An embodiment of: the line with a plurality of strands is shown in
An embodiment of a three strand line is illustrated in
In accordance with a further development of the embodiment shown in
In the embodiments shown in
| Number | Date | Country | Kind |
|---|---|---|---|
| 11 306 665.8 | Dec 2011 | EM | regional |
