Patent Application
20110271659
1. Field of the Invention
The present invention relates to a temperature sensor, a sulfur component detector, and an exhaust purification system for an internal combustion engine.
2. Description of the Related Art
In an exhaust purification system for an internal combustion engine that includes a NOx storage-reduction catalyst, a sulfur component in exhaust gas is stored in the NOx storage-reduction catalyst, and thereby decreases NOx purification efficiency of the NOx storage-reduction catalyst.
When the NOx purification efficiency of the NOx storage-reduction catalyst is decreased by sulfur poisoning, the NOx storage-reduction catalyst is heated in a rich air-fuel ratio atmosphere to regenerate the catalyst. However, this results in thermal aging of the NOx storage-reduction catalyst, which is caused by the catalytic regeneration, and reduced fuel efficiency.
Considering the above, as shown in
However, when the amount of sulfur accumulated in a sulfur trap catalyst or a sulfur adsorbent exceeds a threshold capacity in the sulfur trap device 20, the sulfur component passes through the sulfur trap device 20. The NOx storage-reduction catalyst 30 downstream of the sulfur trap device 20, is then subjected to sulfur poisoning. Accordingly, the sulfur trap catalyst or the sulfur adsorbent needs to be replaced. More specifically, it is a precondition of the configuration in
Conventionally, the amount of the sulfur component that flows into the NOx storage-reduction catalyst 30 is estimated based on the reduced performance of the NOx storage-reduction catalyst 30, and means for detecting sulfur poisoning of the NOx storage-reduction catalyst 30 itself is not provided. In this case, sulfur poisoning of the NOx storage-reduction catalyst 30 usually starts on the upstream side of the catalyst, as shown in the graph C of
Japanese Patent Application Publication No. 2000-45753 (JP-A-2000-45753) describes an exhaust purification system for an internal combustion engine that includes: a NOx adsorbent that adsorbs the sulfur component in the exhaust gas; and a SOx sensor that is provided upstream of the NOx adsorbent to determine deterioration in a NOx adsorbing capacity of the NOx adsorbent, which is caused by sulfur poisoning of the NOx adsorbent.
In the exhaust purification system that described in JP-A-2000-45753, the SOx sensor detects the concentration of SOx in the exhaust gas in real time based on the potential difference between electrodes that each includes a SOx reduction catalyst such as platinum. Then, based on a detected value, the SOx sensor calculates an accumulated amount of SOx that is estimated to be adsorbed by the NOx adsorbent.
It is described in JP-A-2000-45753 that the sulfur component of several hundred ppm is contained in fuel. However, the amount of the sulfur component in fuel has been reduced with improved fuel properties, and today, less than ten ppm of the sulfur component is contained in fuel, and thus is extremely lean. Accordingly, it has become difficult to detect the sulfur component in the passing exhaust gas in real time based on the potential difference between the electrodes that each includes the SOx reduction catalyst such as platinum. Therefore, the SOx sensor described in JP-A-2000-45753 is no longer practical.
The present invention provides a temperature sensor that catalyzes an exothermic reaction of a reactant in gas to detect a temperature, and means for accurately detecting sulfur components in exhaust gas, even at low concentrations by utilizing the temperature sensor. The present invention also provides an exhaust purification system for an internal combustion engine that utilizes the means for detecting the sulfur component.
The temperature sensor according to a first aspect of present invention includes temperature detecting means, and at least one of a catalyst and an adsorbent that is applied to a surface of the temperature detecting means. At least one of the catalyst and the adsorbent catalyzes the exothermic reaction of the reactant in the gas. At least one of the catalyst and the adsorbent catalyzes the exothermic reaction of the reactant in the gas on the temperature detecting means. Then, the temperature detecting means detects a temperature that is increased by the exothermic reaction.
In the temperature sensor according to the above aspect, a temperature-detecting portion of the temperature detecting means is coated with at least one of the catalyst and the adsorbent, and the exothermic reaction of the reactant in the gas is catalyzed on the temperature detecting means. The temperature detecting means detects the temperature that is increased by the exothermic reaction. Thus, the temperature sensor according to the above aspect is unlike a conventional temperature sensor that simply detects the temperature of an object. The present invention has been made on the basis of a novel idea that the exothermic reaction is catalyzed on the temperature detecting means so as to detect the temperature that is increased by the exothermic reaction.
In the temperature sensor according to the first aspect, at least one of the catalyst and the adsorbent may be a catalyst or an adsorbent whose catalytic efficiency for the exothermic reaction of the reactant in the gas is degraded by sulfur poisoning.
When the catalyst or the adsorbent of the temperature sensor is poisoned by sulfur, thereby decreasing the catalytic activity of the catalyst or the adsorbent, the exothermic reaction of the reactant in the gas is no longer initiated on the temperature detection means. Considering the above, the temperature sensor according to the above aspect is provided with a SOx sensor that detects the sulfur component in the gas with high accuracy, even when only a minute amount of the sulfur component is contained in the gas. A conventional SOx sensor measures, in real time, a potential difference between electrodes that each includes a SOx reduction catalyst, such as platinum, and cannot detect minute amounts of SOx below 10 ppm. Because the catalyst or the adsorbent applied to the surface of the temperature detecting means stores SOx, it is possible in the present invention to detect concentrations of SOx below 10 ppm with high accuracy as an accumulated amount of SOx that passes through.
In the temperature sensor according to the first aspect, at least one of the catalyst and the adsorbent that is applied to the surface of the temperature detecting means in the temperature sensor may be a carrier in which alumina or zirconia is supported by alkali metal or alkaline-earth metal and which also carries palladium.
In the temperature sensor according to the above aspect, a catalytic species whose activity is significantly decreased by sulfur poisoning is adopted as a catalyst. A basic carrier that is also susceptible to sulfur poisoning is adopted as a carrier. Materials with an oxygen storage capacity (OSC), such as ceria and praseodymium, should not used for the temperature sensor. Accordingly, the temperature sensor only detects heat generation during NOx reduction with significantly improved sensitivity.
In the temperature sensor according to the first aspect, the gas is exhaust gas from an internal combustion engine. At least one of the catalyst and the adsorbent that is applied to the surface of the temperature detecting means stores oxygen or nitrogen oxide in the exhaust gas when the internal combustion engine operates at a lean air-fuel ratio, and releases oxygen or nitrogen oxide into the exhaust gas when the internal combustion engine operates at a rich air-fuel ratio. At least one of the catalyst and the adsorbent utilizes released oxygen or nitrogen oxide to initiate the exothermic reaction of the reactant in the exhaust gas on the temperature detecting means. Then, the temperature detecting means detects the temperature that is increased by the exothermic reaction. An oxygen or nitrogen oxide storage capacity and a catalytic efficiency for the exothermic reaction of at least one of the catalyst and the adsorbent is reduced by sulfur poisoning.
The temperature sensor according to the above aspect is provided with the SOx sensor that detects the sulfur component with high accuracy even if only a minute amount of the sulfur component is present in the exhaust gas that is produced after combustion of fuel that contains sulfur. A material that has the OSC, such as ceria and praseodymium, is utilized as the catalyst or the adsorbent that is applied to the surface of the temperature detecting means. The catalyst or the adsorbent utilizes stored oxygen to catalyze the exothermic reaction of the reactant in the exhaust gas. Alternatively, a material such as alkali metal, alkali-earth metal, or rare earth that stores oxygen as NOx may be utilized as the catalyst or the adsorbent. The catalyst or the adsorbent utilizes stored NOx to catalyze the exothermic reaction of the reactant in the exhaust gas. Then, because the OSC and the NOx storage capacity are reduced by sulfur poisoning, the SOx sensor is provided that accurately detect the concentration of the sulfur component even if only a minute amount of the sulfur component is present in the exhaust gas.
The temperature sensor according to the first aspect may undergo a pretreatment. In the pretreatment, the temperature sensor is first subjected to sulfur poisoning, and then purged of the sulfur component that is adsorbed by at least one of the catalyst and the adsorbent applied to the surface of the temperature detection means.
The sensitivity of temperature sensor according to the above aspect decreases as the amount of the sulfur component that passes through increases. Once the degree of sulfur poisoning of the temperature sensor reaches a threshold degree, the purging of the sulfur component that is adsorbed by at least one of the catalyst and the adsorbent applied to the surface of the temperature detecting means is performed. However, there is a region in the temperature sensor that cannot recover from sulfur poisoning even with the purge treatment and is permanently poisoned by sulfur. Thus, when the temperature sensor is installed in a real machine, the temperature sensor may undergo the pretreatment before installment. In the pretreatment, the temperature sensor is first subjected to sulfur poisoning, and then the purge treatment of the sulfur component adsorbed by at least one of the catalyst and the adsorbent is performed.
The temperature sensor according to the first aspect may further include a pump cell that has an oxygen-pumping function, and a heater.
When the purge treatment is performed in the temperature sensor that is being utilized in the real machine, it is required to obtain the exhaust gas at the rich air-fuel ratio and at a high temperature by injecting the fuel into the exhaust gas and combusting oxygen in the exhaust gas. However, a large amount of the fuel is required to make a total amount of the exhaust gas at the rich air-fuel ratio and the high temperature. Considering the above, the temperature sensor according to the above aspect may further include the pump cell that has the oxygen-pumping function, and the heater. In such configuration, when the pump cell removes oxygen from the exhaust gas flowing near the temperature sensor, the air-fuel ratio of the atmosphere near the temperature sensor becomes rich. Thus, the purge treatment in the temperature sensor may easily be performed by heating the temperature sensor with the heater. Accordingly, there is no need to inject the fuel into the exhaust gas or to make the total amount of the exhaust gas at the rich air-fuel ratio and the high temperature. Therefore, the purge treatment can be performed very economically.
The temperature sensor according to the first aspect, the sensitivity of the temperature sensor may be corrected to sensitivity that is suited for the rich air-fuel ratio when the temperature sensor is disposed downstream of a NOx storage-reduction catalyst to measure a sulfur release amount of the NOx storage-reduction catalyst during a catalytic regeneration operation.
The temperature sensor according to the above aspect is disposed downstream of the NOx storage-reduction catalyst, and thus can measure the sulfur release amount from the NOx storage-reduction catalyst during the catalytic regeneration operation. In this case, when the NOx storage-reduction catalyst is in the rich air-fuel ratio atmosphere during the catalyst regeneration operation, the catalyst or the adsorbent of the temperature sensor is also in a regeneration atmosphere. Accordingly, a trapped amount of sulfur in the temperature sensor decreases in comparison with the trapped amount of sulfur during a normal operation. Thus, when the sulfur release amount of the NOx storage-reduction catalyst during the catalytic regeneration operation is measured, the sensitivity of the temperature sensor in the rich air-fuel ratio atmosphere is obtained in advance. Then, by creating a sensitivity map and the like that utilize the obtained sensitivity of the temperature sensor, it is possible to correct the sensitivity of the temperature sensor.
In a sulfur component detector according to a second aspect of the present invention, the temperature sensor according to the first aspect is disposed in a flow passage of the gas, detects a temperature T1 that is increased by the exothermic reaction, compares the temperature T1 with a temperature T0 that is increased by the exothermic reaction when the sulfur component is not present in the gas, and determines that the sulfur component is present in the gas in the flow passage if the temperature T1 is below the temperature T0.
The sulfur component detector according to the above aspect utilizes the temperature sensor according to the first aspect to accurately detect whether the sulfur component is present in the gas flowing in the flow passage. More specifically, if the catalyst or the adsorbent of the temperature sensor according to the first aspect is subjected to sulfur poisoning and thereby decreases its activity, the exothermic reaction of the reactant in the gas can no longer be initiated on the temperature detecting means. The detected temperature T1 becomes lower than the temperature T0 that is obtained before sulfur poisoning. Accordingly, by utilizing a difference between the temperatures, the sulfur component detector detects that the sulfur component is present in the gas flowing in the flow passage.
In the sulfur component detector according to the second aspect, the temperature sensor may be disposed upstream in an exhaust pipe of an internal combustion engine; the sulfur component adsorbed by at least one of the catalyst and the adsorbent that is applied to the temperature detecting means may be treated with a purge treatment if a temperature difference dT1 between the temperature T0 and, the temperature T1 becomes equal to or larger than a specified value due to a decrease in the temperature T1 that is indicated by the sulfur component detector; and it may be determined that fuel in use contains a high concentration of the sulfur component if a fuel consumption amount after the adsorbed sulfur component has been purged and before the next purge treatment falls below a specified fuel consumption amount.
In the sulfur component detector according to the second aspect, the temperature sensor may be disposed upstream in an exhaust pipe of an internal combustion engine; the sulfur component adsorbed by at least one of the catalyst and the adsorbent that is applied to the temperature detecting means may be treated with a purge treatment if a temperature difference dT1 between the temperature T0 and the temperature T1 becomes equal to or larger than a specified value due to a decrease in the temperature T1 that is indicated by the sulfur component detector; and it may be determined that fuel in use contains a high concentration of the sulfur component if a time interval after the adsorbed sulfur component has been purged and before the next purge treatment falls below a specified time interval due to a increased degree of sulfur poisoning.
The sulfur component detector according to the above aspect is disposed upstream in the exhaust pipe of the internal combustion engine, and is utilized to determine whether the fuel used contains a high concentration of the sulfur component. It is advantageous to use the determination to further determine that deterioration in the exhaust purification system for an internal combustion engine is not attributed to the exhaust purification system itself but to deterioration in a fuel property. More specifically, if the fuel contains a high concentration of the sulfur component, the sulfur component in the exhaust gas is also high. Accordingly, a cycle of the purge treatment of the catalyst or the adsorbent that is applied to the surface of the temperature detecting means and is subjected to sulfur poisoning is shortened. Based on the above, the sulfur component detector is provided to determine whether the fuel used contains a high concentration of the sulfur component.
The sulfur component detector according to the second aspect may further include a member that has a specified heat capacity. The temperature sensor may be disposed in an exhaust passage of the internal combustion engine, and the member that has the specified heat capacity may be disposed upstream of the temperature sensor, so that time at which an exhaust temperature increase by combustion in the internal combustion engine is detected by the temperature sensor is delayed. Accordingly, the sulfur component detector may separately detect the exhaust temperature increase by combustion in the internal combustion engine from a temperature increase by the exothermic reaction in the temperature sensor.
If the member with the heat capacity such as a sulfur trap device is not provided upstream of the sulfur component detector according to the above aspect, the exhaust temperature increase at a position immediately downstream of the internal combustion engine overlaps the temperature increase by the exothermic reaction in the temperature sensor. Thus, the sulfur component detector according to the above aspect separates the temperature increases from one another, so that the temperature sensor only detects the temperature increase by the exothermic reaction. Therefore, the detection accuracy of the sulfur component detector according to the second aspect is improved.
In a sulfur component detector according to a third aspect of the present invention, the temperature sensor according to claim 6 is disposed downstream of a NOx storage-reduction catalyst;
oxygen is released near the temperature sensor by the oxygen pumping function; and
a sulfur release amount of the NOx storage-reduction catalyst during a catalytic regeneration operation is measured after the atmosphere near the temperature sensor becomes a lean air-fuel ratio atmosphere.
The sulfur component detector according to the above aspect utilizes the temperature sensor according to the first aspect. The oxygen-pumping function of the pump cell in the temperature sensor according to the first aspect is actuated to deliver oxygen toward the temperature sensor. Then, oxygen is released near the temperature sensor to maintain only the proximity of the temperature sensor in the lean air-fuel ratio atmosphere. Accordingly, it is possible to measure the amount of sulfur released by the NOx storage-reduction catalyst during the catalytic regeneration operation without reducing the sensitivity of the temperature sensor.
An exhaust purification system for an internal combustion engine according to a fourth aspect of the present invention includes: a sulfur trap device disposed upstream of the exhaust purification system to store a sulfur component present in exhaust gas; and the sulfur component detector according to claim 8 is provided downstream of the sulfur trap device and upstream of the exhaust purification system. If performance of the sulfur trap device to store the sulfur component in the exhaust gas is decreased, and thus, the exhaust gas that contains the sulfur component flows into the exhaust purification system, it is determined by the sulfur component detector that the sulfur component is present in the exhaust gas flowing into the exhaust purification system.
The exhaust purification system for an internal combustion engine according to the above aspect includes the sulfur trap device upstream of the exhaust purification system. When the sulfur trap device is subjected to sulfur poisoning and thereby decreases its performance to store the sulfur component in the exhaust gas, the exhaust gas that contains the sulfur component flows into the exhaust purification system downstream of the sulfur trap device. In this case, the minute amount of the sulfur component that passes through the sulfur trap device is detected by the sulfur component detector according to the second aspect.
An exhaust purification system for an internal combustion engine according to a fifth aspect of the present invention includes: a sulfur trap device disposed upstream of the exhaust purification system and stores a sulfur component present in exhaust gas; a sulfur component detector wherein: the temperature sensor according to claim 4 is disposed downstream of the sulfur trap device and upstream of the exhaust purification system; a temperature T1 that is increased by an exothermic reaction of a reactant in the temperature sensor is detected; the detected temperature T1 is then compared with a temperature T0 that is increased by the exothermic reaction if the sulfur component is not present in the exhaust gas; and wherein it is determined that the sulfur component is present in the exhaust gas if the temperature T1 is below the temperature T0; and oxygen consumption means for providing upstream of the temperature sensor. When the internal combustion engine operates at the rich air-fuel ratio, the oxygen consumption means consumes oxygen remaining in the exhaust gas.
The exhaust purification system for an internal combustion engine according to the above aspect momentarily provides the rich air-fuel ratio atmosphere to the NOx storage-reduction catalyst that stores NOx when NOx purification is performed by the NOx storage-reduction catalyst. In other words, a rich spike is performed to reduce NOx that is stored in the NOx storage-reduction catalyst. At this time, the catalyst or the adsorbent applied to the surface of the temperature detecting means releases oxygen that is stored at the lean air-fuel ratio. Consequently, the exothermic reaction of the reactant or a reducing agent that is contained in the rich spike is initiated on the temperature detecting means. Then, by comparing the temperature T0 that is indicated by the sulfur component detector with the temperature T1 that is indicated by the sulfur component detector after sulfur poisoning, it may be determined that the sulfur component is contained in the exhaust gas. In this case, because the exhaust gas in a rich air-fuel ratio operating condition contains a minute amount of oxygen, the exothermic reaction of the reducing agent is initiated with oxygen in the exhaust gas. Accordingly, the accuracy in detecting the presence of the sulfur component decreases. In order to prevent the decrease in the accuracy to detect the sulfur component, the oxygen consumption means is provided upstream of the sulfur component detector to consume oxygen that is present in the exhaust gas in the rich air-fuel ratio operating condition. Accordingly, the exothermic reaction on the temperature sensor only utilizes oxygen that is released by the catalyst or the adsorbent applied to the surface of the temperature detecting means. Therefore, it is possible detect whether the sulfur component is present in the exhaust gas flowing into the exhaust purification system with improved accuracy.
An exhaust purification system for an internal combustion engine according to a sixth aspect of the present invention includes: a sulfur trap device provided upstream of the exhaust purification system to store a sulfur component present in exhaust gas; and a sulfur component detector, wherein: the temperature sensor according to claim 4 is disposed downstream of the sulfur trap device and upstream of the exhaust purification system; a temperature T1 that is increased by an exothermic reaction of a reactant in the temperature sensor is detected; and the detected temperature T1 is then compared with a temperature T0 that is increased by the exothermic reaction if the sulfur component is not present in the exhaust gas; and wherein it is determined that the sulfur component is present in the exhaust gas if the temperature T1 is below the temperature T0, wherein: if the internal combustion engine operates at a rich air-fuel ratio, a remaining amount of oxygen in the exhaust gas is estimated from an operating condition of the internal combustion engine; a temperature increase dTox that depends on the remaining amount of oxygen and is indicated by the sulfur component detector is estimated. When a temperature T1′ that is obtained by subtracting the temperature increase dTox from the temperature T1 that is indicated by the sulfur component detector is below the temperature T0, it is determined that the sulfur component is present in the exhaust gas flowing into the exhaust purification system.
Like the exhaust purification system according to the fifth aspect, the exhaust purification system for an internal combustion engine according to the above aspect utilizes the temperature sensor according to the first aspect to determine whether the sulfur component is present in the exhaust gas. In this case, in order to prevent a decrease in the accuracy of detecting the sulfur component that is caused by the exothermic reaction of the reducing agent that is initiated with oxygen contained in the exhaust gas in the rich air-fuel ratio operating condition, the amount of heat generation that depends on oxygen contained in the exhaust gas in the rich air-fuel ratio operating condition is corrected by calculation. More specifically, the sulfur component detector includes an operation map from which the remaining amount of oxygen in the exhaust gas is obtained in accordance with the operating condition of the engine. The temperature increase dTOX that is determined by the sulfur component detector based on the remaining amount of oxygen is obtained from the operation map. Then, the temperature T1 detected by the sulfur component detector is corrected. As described above, the temperature T1′, which only depends on the heat generation by oxygen released by the catalyst or the adsorbent that is applied to the surface of the temperature detecting means, is calculated. Because the temperature T1′ is below the temperature T0, it may be determined with greater accuracy that the sulfur component is present in the exhaust gas flowing into the exhaust purification system.
An exhaust purification system for an internal combustion engine according to a seventh aspect of the present invention includes: a sulfur trap device provided upstream of the exhaust purification system to store a sulfur component present in exhaust gas; and a sulfur component detector, wherein: the temperature sensor according to claim 4 is disposed downstream of the sulfur trap device and upstream of the exhaust purification system; a temperature T1 that is increased by an exothermic reaction of a reactant in the temperature sensor is detected; and the detected temperature T1 is then compared with a temperature T0 that is increased by the exothermic reaction if the sulfur component is not present in the exhaust gas; and wherein it is determined that the sulfur component is present in the exhaust gas if the temperature T1 is below the temperature T0. The remaining amount of oxygen in the exhaust gas is estimated from an operating condition of the internal combustion engine if the internal combustion engine operates at a rich air-fuel ratio. A heating value Q1 that depends on the remaining amount of oxygen is estimated; a total heating value Q2 is calculated from a detected value by the sulfur component detector; the heating value Q1 is subtracted from the heating value Q2; and it is determined that the sulfur component is present in the exhaust gas flowing into the exhaust purification system if the resulting difference between Q1 and Q2 is equal to or below a prescribed value.
The present invention provides a temperature sensor that initiates an exothermic reaction of a reactant in gas to detect a temperature, and means for accurately detecting a lean sulfur component in exhaust gas by utilizing the temperature sensor. The present invention also provides an exhaust purification system for an internal combustion engine that utilizes the means for detecting the sulfur component.
The foregoing and/or further objects, features and advantages of the invention will become more apparent from the following description of example embodiments with reference to the accompanying drawings, in which like numerals are used to represent like elements and wherein:
Embodiments of the present invention will hereinafter be described with reference to the accompanying drawings. In the accompanying drawings, the same or like members are denoted with the same reference numerals.
When the gas is exhaust gas from an internal combustion engine, a catalyst (or the adsorbent) that adsorbs oxygen or NOx under a lean air-fuel ratio atmosphere and releases oxygen or NOx under a rich air-fuel ratio atmosphere] is adopted as the catalyst (or the adsorbent) 2. The exothermic reaction of the reactant is initiated with oxygen or NOx that is released by the catalyst (or the adsorbent) 2. Then, the increase in temperature by the exothermic reaction is detected by the temperature detecting means 1. The catalyst (or the adsorbent) 2 in this case may be a carrier that has an oxygen storage capacity (OSC) such as ceria and praseodymium, or a material carrying alkali metal, alkali-earth metal, or rare earth that that adsorbs oxygen or NOx under a lean air-fuel ratio atmosphere] and releases oxygen or NOx under a rich air-fuel ratio atmosphere.
As described above, the catalyst (or the adsorbent) 2 applied to the surface of the temperature detecting means 1, may be a catalyst (or an adsorbent) that stores oxygen or NOx under a learn air-fuel ratio atmosphere and releases oxygen or NOx under a rich air-fuel ratio atmosphere. However, in this case, oxygen remains in the exhaust gas in a rich air-fuel ratio operating condition, and consequently, the exothermic reaction of the reactant is initiated on the temperature detecting means 1 with the remaining oxygen. Accordingly, the temperature detected by the temperature sensor 10 includes the amount of heat generated through the combustion of the remaining oxygen and the amount of heat generated through the release of oxygen or NOx from the catalyst (or the adsorbent) 2. Therefore, there is a possible reduction in the accuracy to determine whether the sulfur component is contained in the exhaust gas. The above relationship is shown in
To solve the above problem, oxygen consumption means (not shown) is disposed upstream of the sulfur component detector (temperature sensor 10) to consume any remaining oxygen in the exhaust gas in the rich air-fuel ratio operating condition, when the internal combustion engine operates at the rich air-fuel ratio. Accordingly, the temperature t detected by the temperature sensor 10 only indicates the amount of heat generated by oxygen or NOx that is released from the catalyst (or the adsorbent) 2. Therefore, it is possible to improve the accuracy in detecting the sulfur component of the exhaust gas flowing into the exhaust gas purification system.
Such oxygen consumption means can be a carrier such as alumina, zirconia, ceria, and titania, or a carrier that is a complex composed of at least two of alumina, zirconia, ceria, and titania, which supports an active species with an oxidative activity such as platinum, palladium, rhodium, gold, silver, and iron.
The amount of heat generated by combusting the remaining oxygen in the exhaust gas in the rich air-fuel ratio operating condition may also be calculated. The sulfur component detector includes a control unit that determines whether the sulfur component is present in the exhaust gas flowing into the exhaust purification system based on the detected temperature. The control unit includes an operation map that shows the relationship between an operating condition of the internal combustion engine and the remaining amount of oxygen in the exhaust gas. The control unit calculates the remaining amount of oxygen in the exhaust gas using the operation map in step 100 shown in
In another embodiment of the present invention, for example, the temperature sensor 10 is disposed upstream in the exhaust pipe of the internal combustion engine, and determines high sulfur concentration when concentration of sulfur in fuel is high. First, the temperature difference dT1 between the temperature T0 that is indicated by the temperature sensor 10 before the catalyst (or the adsorbent) 2, which is applied to the surface of the temperature detecting means 1 in the temperature sensor 10, is subjected to sulfur poisoning, and the detected temperature T1 are calculated. If the temperature T1 is decreased by sulfur poisoning and the temperature difference dT1 becomes equal to or larger than a specified value, a purge treatment is performed on the sulfur component adsorbed by the catalyst (or the adsorbent) 2, which is applied to the surface of the temperature detecting means 1. Next, when the purge treatment is frequently performed due to increased sulfur poisoning, it is determined that the concentration of sulfur in the fuel is high. The purge treatment of the sulfur component may be performed by heating the catalyst (or the adsorbent) 2 to a high temperature. At this time, it is preferable that the catalyst (or the adsorbent) 2 is heated to a high temperature in a rich air-fuel ratio atmosphere. In this case, the time interval between the purge treatments is reduced in comparison with a specified time interval. Thus, it is determined that the fuel used contains a high concentration of the sulfur component. Meanwhile, instead of utilizing the time interval for determination, as shown in
If a member that having a predetermined heat capacity is disposed upstream of the temperature sensor 10 when the sulfur component detector according to the embodiments of the present invention is applied for the exhaust gas in the internal combustion engine, as shown in
If the embodiment of the present invention further adopts both an active species with activity that is significantly decreased by sulfur poisoning as the catalyst and a basic carrier that is also susceptible to sulfur poisoning while eliminating a material with an oxygen storage capacity (OSC) such as ceria and praseodymium in order to detect the temperature only during NOx reduction, it is possible to significantly increase the sensitivity of the temperature sensor 10. For example, when a carrier, such as alumina and zirconia, that is supported by alkali metal or alkali-earth metal and that also carries palladium is employed, the sensitivity of the sensor may significantly be improved.
The sensitivity of the temperature sensor 10 decreases as the amount of the sulfur component that passing through increases. Once the degree of sulfur poisoning that the temperature sensor 10 is subjected to reaches a prescribed degree, the purge treatment is performed on the sulfur component adsorbed by the catalyst (or the adsorbent) 2 applied to the surface of the temperature detecting means 1. However, there is a region in the temperature sensor 10 that cannot recover from sulfur poisoning through the purge treatment and is permanently poisoned by sulfur.
When the purge treatment is performed in the temperature sensor 10 that is being utilized in the real machine, it is required to obtain the rich air-fuel ratio and to heat the exhaust gas to a high temperature by injecting the fuel into the exhaust gas and combusting oxygen in the exhaust gas. However, a large amount of the fuel is required to make a total amount of the exhaust amount at the rich air-fuel ratio and the high temperature. Therefore, in another embodiment of the present invention, as shown in
In another embodiment, the sulfur trap catalyst 20 as shown in
In further another embodiment, in a system equipped with a diesel particulate filter (DPF), the temperature sensor 10 is disposed upstream of the DPF. If fuel or engine oil with the high sulfur content is utilized, the temperature sensor 10 monitors the amount of the sulfur component trapped in the DPF to prevent generation of sulfate fumes from the DPF. The temperature sensor also controls the DPF such that the DPF is regenerated before the amount of trapped sulfur in the DPF exceeds a prescribed amount.
In a system equipped with the NOx storage-reduction catalyst, it is possible to optimize a regeneration operation interval of the NOx storage-reduction catalyst in accordance with the sulfur concentration in the fuel and the engine oil. More specifically, a relationship among the sulfur concentration in the fuel and the engine oil, the air-fuel ratio of the rich spike during the regeneration operation of the NOx storage-reduction catalyst, and an interval of a catalytic regeneration operation is shown in
In further another embodiment, as shown in
Also, in this case, the temperature sensor 10 includes the above-described oxygen pumping function. The oxygen pumping function acts in an opposite direction by reversing the polarity of voltage applied to the pump cell 15 to send oxygen toward the temperature sensor 10. Thus, oxygen is released near the temperature sensor 10. Therefore, it is possible to measure the sulfur release amount of the NOx storage-reduction catalyst during the catalyst regeneration operation by maintaining only the atmosphere near the temperature sensor 10 in the rich air-fuel ratio atmosphere to prevent deterioration in the sensitivity of the temperature sensor 10.
Deterioration of temperature sensor 10 occurs not only through sulfur poisoning. If the temperature sensor 10 continues to be used, the initial sensitivity will not be recovered even if the sulfur component adsorbed by the catalyst (or the adsorbent) 2, which is applied to the surface of the temperature detecting means 1, is periodically purged. More specifically, as shown in
In this case, if the sensitivity of the deteriorated temperature sensor 10 is determined after the purge treatment, it is possible to estimate the decreased sensitivity in the entire sensitivity curve. Therefore, in another embodiment, a map that indicates deterioration in sensitivity of the temperature sensor 10 is provided in advance. Thus, it is preferable to correct the sensitivity in the entire sensitivity curve by obtaining the sensitivity of the temperature sensor 10 after the purge treatment.
While the invention has been described with reference to example embodiments thereof, it should be understood that the invention is not limited to the described embodiments or constructions. To the contrary, the invention is intended to cover various modifications and equivalent arrangements. In addition, while the various elements of the example embodiments are shown in various combinations and configurations, other combinations and configurations, including more, less or only a single element, are also within the spirit and scope of the invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2009-007983 | Jan 2009 | JP | national |
| 2009-216098 | Sep 2009 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/IB2010/000016 | 1/8/2010 | WO | 00 | 7/18/2011 |
