Patent Application
20230411729
The present invention relates to the technology field of battery device of electric vehicle, and more particularly to a thermal interface material coating method for battery cells.
All-electric vehicles (EVs), also referred to as battery electric vehicles, have electric motors instead of internal combustion engines. The vehicle uses a large traction battery pack to power the electric motor and must be plugged in to a wall outlet or charging equipment, also called electric vehicle supply equipment (EVSE). As explained in more detail, electric vehicle battery (EVB) is the foregoing traction battery pack used to power the electric motor of a battery electric vehicle (BEV) or a hybrid electric vehicle (HEV), and the electric vehicle battery (EVB) typically is designed to be a battery pack comprising a plurality of battery cells and a battery management circuit.
When manufacturing a battery pack, multiple battery cells are firstly assembled to form a battery module, and then at least one battery module and a battery management circuit are integrated to form the battery pack. For example, the China patent, publication No. CN111799405A, has disclosed a battery module comprising a plurality of cylindrical battery cells. The cylindrical battery cells are arranged into a plurality of columns and a plurality of rows, and are divided into the first block, the second block and the third block. The columns include the first column and the second column. The second block is located between the first block and the third block. In the second column, the cylindrical battery cells in the second block are disposed in a horizontal line, and at least one row of cylindrical battery cells in the first block and the third block protrude out of the horizontal line. By such an arrangement, there is more spacing between the battery cells and the problems of the heat accumulation existing in the conventional battery module can be solved. It is worth mentioning that, each of the battery cells is coated with a thermal interface material (TIM) thereon before being assembled to form the battery module. Conventionally, the cylindrical battery cell is soaked in a TIM solution to form a TIM film on the sides of cylindrical battery cell. However, the formed TIM film is found to be laterally uneven in thickness.
On the other hand, the China patent, publication No. CN110915020A, has also disclosed a battery module comprising multiple prismatic battery cells. For enhancing the heat dissipation of the prismatic battery cells, each of the multiple prismatic battery cells is also coated with a thermal interface material (TIM) thereon. Furthermore, the China patent, publication No. CN111653707A, has also disclosed a battery module comprising a plurality of pouch battery cells installed in a battery shell. For enhancing the heat dissipation of the pouch battery cells, each of the battery cells is also coated with a thermal interface material (TIM) thereon. Nowadays, slot die coater is utilized to form the TIM film on the surface of the pouch battery cell and/or the prismatic battery cell.
Slot die coater is known having a slot-die. The slot-die has a high aspect ratio outlet controlling the final delivery of the TIM fluid onto the surface of the battery cell. This results in the continuous production of a wide layer of coated TIM material on the surface of the battery cell, with adjustable width depending on the dimensions of the slot-die outlet. After coating the TIM material onto the battery cell, the battery cell subsequently proceeds with the spin process, so as to make the coated TIM film comprises a laterally uniform thickness. However, after the abovementioned TIM coating, it is inevitable to adopt a spinning process, and then the equipment cost of the slot die coater due to the spinning process increases.
According to above descriptions, it is understood that there are rooms for improvement in the conventional TIM coating method for battery cells. In view of that, the present application provides a novel thermal interface material coating method for battery cells.
One of the embodiments provides a thermal interface material (TIM) coating method for battery cells. According to another embodiment, a coating system comprising a rotating mechanism, a slot die coater and a substrate is provided for coating a TIM material onto at least one battery cell. Particularly, the substrate is a meshed plate including a plurality of pores. As such, if the coating fluid flow rate of a slit nozzle of the slot die coater, the rotation speed of the rotation mechanism, the thickness of the substrate, and the pore size of the substrate all are properly designed, a TIM film having a laterally-uniform thickness can be formed on the battery cell by using the provided coating system.
The embodiment of a thermal interface material coating method for battery cells comprises the steps of:
In another embodiment, the rotation speed of the battery cell is negative correlation to the stickiness of the TIM fluid.
In another embodiment, the substrate is an arc-shaped meshed plate comprising a curvature radius in a range between 3 mm and 50 mm.
In one embodiment, the substrate comprises a thickness in a range between 0.05 mm and 100 mm, and the pore comprises a mesh size in a range between 10 mesh and 200 mesh.
In another embodiment, the slick layer is formed on the surface of the substrate, comprising the inner surface of each pore, therefore the supplied TIM fluid is allowed to pass substrate through the pores smoothly.
In another embodiment, the battery cell is a cylindrical battery cell, and the TIM fluid comprising a thermal interface material, such as a polymer matrix and a plurality of thermally conductive filler distributed in the polymer matrix.
In another embodiment, there is a scraping member connected to an edge of the slit nozzle, and the scraping plate help distribute the TIM fluid evenly across the substrate immediately after the slit nozzle supplies the TIM fluid onto the substrate.
In another embodiment, there is a pressing plate disposed in the reservoir, and a pressurizing apparatus is adopted for supplying a pressing force to the pressing plate, so as to press down the pressing plate at a given speed, thereby controlling a fluid supplying rate of the slit nozzle. The pressurizing apparatus may be a pneumatic-type pressurizing apparatus or mechanical-type pressurizing apparatus.
In another embodiment, a heating device is connected to the reservoir for heating the TIM fluid contained in the reservoir.
In another embodiment, the thermal interface material coating method for battery cells comprises the steps of:
In another embodiment, the battery cell is moved horizontally moved at a speed in a range between 1 cm/s and 30 cm/s.
In another embodiment, the substrate comprises a thickness in a range between 0.05 mm and 100 mm, and the pore comprises a mesh size in a range between 10 mesh and 200 mesh.
In another embodiment, the slick layer is formed on a surface of the substrate, comprising the inner surface of each said pore, therefore the supplied TIM fluid is allowed to pass the substrate through said pore smoothly.
In another embodiment, the battery cell may be a prismatic battery cell or a pouch battery cell, and the TIM fluid comprises a thermal interface material, such as a polymer matrix and a plurality of thermally conductive filler spread distributed in the polymer matrix.
In another embodiment, there is a scraping plate connected to an edge of the slit nozzle, and the scraping member spreads help distribute the TIM fluid evenly across the substrate immediately after the slit nozzle supplies the TIM fluid onto the substrate.
In another embodiment, there is a pressing plate disposed in the reservoir, and a pressurizing apparatus is adopted for supplying a pressing force to the pressing plate, so as to press down the pressing plate at a motion speed, thereby controlling a fluid supplying rate of the slit nozzle. The pressurizing apparatus may be a pneumatic-type pressurizing apparatus and or mechanical-type pressurizing apparatus.
In another embodiment, a heating device is connected to the reservoir for heating the TIM fluid contained in the reservoir.
The invention as well as a preferred mode of use and advantages thereof will be best understood by referring to the following detailed description of an illustrative embodiment in conjunction with the accompanying drawings, wherein:
To more clearly describe a thermal interface material coating method according to the present invention, embodiments of the present invention will be described in detail with reference to the attached drawings hereinafter.
In an embodiment, the method utilizes a rotating mechanism, a slot die coater and an arc-shaped meshed plate to coat a thermal interface material (TIM) film on at least one battery cell. In other words, the method utilizes a TIM coating system comprising one rotating mechanism, one slot die coater and one arc-shaped meshed plate to achieve coating a TIM film on at least one battery cell.
With reference to
In another embodiment, the substrate 13 is an arc-shaped meshed plate having a curvature radius in a range between 3 mm and 50 mm. Moreover, the battery cell B1 is a cylindrical battery cell, therefore the curvature radius of the arc-shaped meshed plate (i.e., substrate 13) is designed to match the radius of the cylindrical battery cell. On the other hand, the substrate 13 comprises a thickness in a range between 0.05 mm and 100 mm, and the pore comprises a mesh size in a range between 10 mesh and 200 mesh. U.S. mesh size is defined as the number of openings in one square inch of a screen. For example, a 36 mesh comprises 36 openings per square inch while a 150 mesh comprises 150 openings per square inch.
The method subsequently proceeds with step S4. In step S4, the rotating mechanism 11 is driven to rotate the battery cell B1, and the slot die coater 12 moves the slit nozzle 122 over the substrate 13 to spray the TIM fluid onto the substrate 13. As shown in
In order to form a TIM film having a laterally-uniform thickness on the battery cell B1, the rotating mechanism 11 is driven to rotate the battery cell B1 at a rotation speed, and the rotation speed is negative correlation to a stickiness of the TIM fluid. In other words, the higher stickiness the TIM fluid has, the slower the battery cell B1 rotates. The rotation speed of the battery cell B1 can be determined by the formula ω*R=V, where R is the radius of the battery cell B1, ω is the angular velocity of the rotating mechanism, and V is the tangent speed.
In another embodiment, a slick layer is formed on the surface of the substrate, and the inner surface of each pore is also provided with the slick layer thereon. Therefore, the TIM fluid is allowed to pass the substrate 13 through the pores smoothly. Moreover, the slick layer comprises, in weight percent, 6-68% polymer and 5-40% inorganic material. The polymer can be poly (methyl methacrylate) (PMMA), polyamide (PA), polystyrene (PS), polyethylene (PE), polypropylene (PP), polyimide (PI), polyurethane (PU), polypyrrole (PPy), polylactic acid (PLA), fluorocarbon resin, epoxy resin, or a combination of any two or more of the foregoing. On the other hand, said inorganic material can be graphite particles, boron nitride particles, carbon black, activated carbon, fullerenes, graphene, or a combination of any two or more of the foregoing.
As shown in
TIM fluid comprises a thermal interface material such as a polymer matrix and a plurality of thermal conductive filler distributed in the polymer matrix. According to the disclosures of the China patent, publication No. CN101351755A, the thermal conductive filler can be metal oxide particles, nitride particles, carbide particles, diboride particles, graphite particles, or metal particles. In addition, it can further mix a ceramic filler into the thermal interface material, and the ceramic filler can be alumina, magnesium oxide, zinc oxide, zirconium oxide, aluminum nitride, boron nitride, or silicon nitride. Moreover, it can also further mix a carbon-based filler into the thermal interface material, and the carbon-based filler can be graphite, graphene, silicon carbide, tungsten carbide, carbon nanotubes, graphite, carbon black.
As shown in
In another embodiment, the method utilizes a moving mechanism, a slot die coater and an arc-shaped meshed plate to coat a thermal interface material (TIM) film on at least one battery cell. In other words, the method utilizes a TIM coating system comprising one moving mechanism, one slot die coater and one arc-shaped meshed plate to achieve coating a TIM film on at least one battery cell. With reference to
As shown in
The method subsequently proceeds with step S4a. In step S4a, the moving mechanism 11a is driven to move battery cell B2 along a horizontal direction, and the slot die coater 12 moves a slit nozzle 122 over the substrate 13 to spray the TIM fluid onto the substrate 13. As shown in
It is worth mentioning that, when the moving mechanism 11a t moves battery cell B2 along the horizontal direction, the battery cell B2 horizontally move at a speed in a range between 1 cm/s and 30 cm/s. As explained in more detail below, the mathematical formula Q=A*V1=V2*t*W may be used to determine a suitable motion speed for the battery cell B2 and a coating weight for the TIM fluid, where Q is the coating weight, A is a cross-sectional area of the slit nozzle 122, V1 is the fluid supplying rate of the slit nozzle 122, V2 is the motion speed, t is a thickness of the TIM film formed on the battery cell B2, and W is a coating width. Therefore, when a coating fluid flow rate of a slit nozzle of the slot die coater, a moving speed of the battery cell B2, a thickness of the substrate 13, and a pore size of the substrate 13 all are properly designed, it is able to form a TIM film having a laterally-uniform thickness on the battery cell B2 by using the coating system.
As shown in
TIM fluid comprises a thermal interface material, such as a polymer matrix and a plurality of thermal conductive filler distributed in the polymer matrix. According to the disclosures of the China patent, publication No. CN101351755A, the thermal conductive filler can be metal oxide particles, nitride particles, carbide particles, diboride particles, graphite particles, or metal particles. In addition, it can further mix a ceramic filler into the thermal interface material, and the ceramic filler can be alumina, magnesium oxide, zinc oxide, zirconium oxide, aluminum nitride, boron nitride, or silicon nitride. Moreover, it can also further mix a carbon-based filler into the thermal interface material, and the carbon-based filler can be graphite, graphene, silicon carbide, tungsten carbide, carbon nanotubes, graphite, carbon black.
Moreover, as shown in
Therefore, through the above descriptions, all embodiments of the thermal interface material coating method for battery cells according to the present invention have been introduced completely and clearly. Moreover, the above description is made on embodiments of the present invention. However, the embodiments are not intended to limit the scope of the present invention, and all equivalent implementations or alterations within the spirit of the present invention still fall within the scope of the present invention.
