The present invention relates to temperature measuring devices, and more particularly, this invention relates to a thermocouple assembly for use in semiconductor processing.
Semiconductor processing chambers are used for depositing various material layers onto a substrate surface or surfaces. The processing chambers can be used for low-temperature processing, high-temperature processing, or a combination of both high- and low-temperature processing. One or more substrates or workpieces, such as silicon wafers, are placed on a workpiece support within the processing chamber. Both the substrate and workpiece support are heated to a desired temperature. In a typical chemical vapor deposition (“CVD”) processing step, reactant gases are passed over each heated substrate, whereby a CVD reaction deposits a thin layer of the reactant material in the reactant gases on the substrate surface(s). The processing may also include atomic layer deposition (“ALD”), plasma enhanced atomic layer deposition (“PEALD”), reduced pressure CVD (“RPCVD”), or any other process for depositing a thin layer of material onto a substrate. Through subsequent processes, these layers are made into integrated circuits, and tens to thousands or even millions of integrated devices, depending on the size of the substrate and the complexity of the circuits.
Various process parameters must be carefully controlled to ensure the high quality of the resulting deposited layers. One such critical parameter is the temperature of the substrate during each processing step. During CVD, for example, the deposition gases react at particular temperatures to deposit the thin layer on the substrate. If the temperature varies greatly across the surface of the substrate, the deposited layer could be uneven or have defects which may result in unusable areas on the surface of the finished substrate. Accordingly, it is important that the substrate temperature be stable and uniform while the reactant gases are introduced into the processing chamber.
Similarly, non-uniformity or instability of temperatures across a substrate during other thermal treatments can affect the uniformity of resulting structures on the surface of the substrate. Other processes for which temperature control can be critical include, but are not limited to, oxidation, nitridation, dopant diffusion, sputter depositions, photolithography, dry etching, plasma processes, and high temperature anneals.
Methods and systems are known for measuring the temperature at various locations near and immediately adjacent to the substrate being processed. Typically, thermocouples are disposed at various locations near the substrate being processed, and these thermocouples are operatively connected to a controller to assist in providing a more uniform temperature across the entire surface of the substrate. For example, U.S. Pat. No. 6,121,061 issued to Van Bilsen teaches a plurality of temperature sensors measuring the temperature at various points surrounding the substrate, including a thermocouple placed near the leading edge of the substrate, another near the trailing edge, one adjacent to a side of the substrate, and another below the substrate near the center of thereof.
Thermocouples used in semiconductor processing chambers typically have an elongated sheath to protect the thermocouple wires disposed therewithin from the gases and reactants introduced into the reaction chamber. The thermocouple typically also includes a support member that extends the length of the sheath and is configured to receive a pair of wires formed of dissimilar metals such that they form a thermocouple therebetween. The lifetime of the thermocouples is important in a semiconductor processing tool because a shorter lifetime requires more frequent down-time in an industry in which throughput, or the number of workpieces processed over a given time, is an important indicator of quality and cost of ownership of the entire tool. Accordingly, it is important that thermocouples are able to withstand cyclical changes in temperature as well as pressure. Typical issues that relate to shortened thermocouple lifetime include broken wires and inconsistent temperature measurement. The inconsistent temperature measurement of thermocouples may result from an inconsistent location of the junction of the wires (i.e., thermocouple junction) relative to the measuring tip of the sheath. When the location of the junction varies, the accuracy and consistency of the temperature measurement decreases. One example of when a thermocouple is considered to have failed is when the temperature measured is not accurate or is inconsistent from measurement to measurement. The reaction chamber must subsequently be shut down so that the failed thermocouple can be removed, and the tool down-time decreases profitability and increases cost of ownership of the tool. Accordingly, there is a need for a thermocouple design that provides a consistent position at which the junction is located to prevent the shifting of the junction relative to the sheath.
A need exists for a temperature sensing thermocouple that includes a guarded junction that is spaced-apart from the measuring tip of the sheath that is easily manufacturable such that the gap between the junction and the sheath is readily repeatable between subsequently-produced thermocouples. In one aspect of the present invention, a thermocouple assembly for measuring a temperature within a reaction chamber is provided. The thermocouple includes a sheath having a measuring tip located at a distal end of the sheath. The thermocouple also includes a support member. At least a portion of the support member is received within the sheath. A first wire and a second wire are formed of dissimilar metals and are received within the support member. An end of each of the first and second wires is fused together to form a thermocouple junction therebetween. A recessed region is formed in a distal end of the support member, and the distal end of the support member is received within the sheath. The junction is located immediately adjacent to the base of the recessed region.
In another aspect of the present invention, a thermocouple assembly for measuring temperature within a chemical vapor deposition reactor is provided. The thermocouple assembly includes an elongated support member. The support member is configured to receive at least a portion of a first wire and a second wire therewithin, wherein the first wire and second wire are formed of dissimilar metals. The thermocouple assembly also includes an elongated sheath having a measuring tip. The sheath is configured to receive the support member such that a distal end of the support member contacts an inner surface of the sheath at the measuring tip. The thermocouple assembly further includes a thermocouple junction formed by fusing an end of each of the first and second wires. A recessed region is formed into the distal end of the support member adjacent to the measuring tip, and the junction is maintained at a substantially fixed position relative to the measuring tip of the sheath.
In yet another aspect of the present invention, a temperature control system for use in a semiconductor processing reactor is provided. The temperature control system includes at least one heating element located within the reactor. The temperature control system also includes a controller operatively connected to the heating element(s), and the controller is configured to control the heating element(s). The temperature control system further includes at least one temperature sensor located within the reactor, wherein the temperature sensor is operatively connected to the controller for providing temperature data to the controller. At least one temperature sensor is a thermocouple assembly, and the thermocouple assembly includes a sheath having a measuring tip located at a distal end of the sheath. The thermocouple assembly also includes a support member, wherein at least a portion of the support member is received within the sheath. The thermocouple assembly further includes a first wire and a second wire formed of dissimilar metals, wherein a portion of the first and second wires is received within the support member. An end of each of the first and second wires is fused together to form a thermocouple junction therebetween. A recessed region is formed in a distal end of the support member, and the distal end of said support member is received within the sheath. The distal end of the support member contacts the measuring tip of the sheath. The junction is located at a substantially fixed position relative to the measuring tip of the sheath.
Advantages of the present invention will become more apparent to those skilled in the art from the following description of the embodiments of the invention which have been shown and described by way of illustration. As will be realized, the invention is capable of other and different embodiments, and its details are capable of modification in various respects. Accordingly, the drawing(s) and description are to be regarded as illustrative in nature and not as restrictive.
Referring to
The heating elements 16 form an upper bank and a lower bank, as shown in
The substrate support mechanism 18 includes a substrate holder 28, upon which the substrate 24 may be disposed, and a susceptor support member 30, as shown in
A plurality of temperature sensors are located adjacent to the substrate 24 and the substrate holder 28 for measuring temperatures at a variety of locations near the substrate 24, as shown in
In an embodiment, a temperature sensor used in the temperature control system 44 is a thermocouple assembly 48. It should be understood by one skilled in the art that the other temperature sensors 36, 38, 40, 42 may be formed as optical pyrometers, thermocouples previously known in the art, and any combination thereof. A typical embodiment of a thermocouple assembly 48 commonly known in the art, as shown in
The thermocouple assembly 48 includes a first wire 56 and second wire 58, as shown in
The distance between the thermocouple junction 70 and the location at which the thermocouple assembly 48 is measuring the temperature is a vital characteristic of the design of the thermocouple assembly 48. In the process of manufacturing the thermocouple assembly 48, it is also important that the location of the thermocouple junction 70 within the measuring tip 66 is substantially constant from thermocouple-to-thermocouple. The spring 60 is configured to exert a spring force onto the collar 54 that is integrally attached to the support member 52, wherein the spring force applied to the collar 54 biases the collar 54 toward the measuring tip 66 to ensure constant contact between the thermocouple junction 70 and the measuring tip 66. During assembly of thermocouple assemblies previously known in the art, the thermocouple junction 70 may slide, or become offset within the measuring tip 66, thereby reducing the accuracy of the temperature measured by the thermocouple assembly 48. Additionally, during thermal cycling within the reaction chamber 12 (
An exemplary embodiment of an improved thermocouple assembly 100 is shown in
The thermocouple assembly 100 includes a first wire 108 and second wire 110, as shown in
In an embodiment, the tip of the support member 104 adjacent to the measuring tip 118 forms a recessed region 122, as shown in
During assembly, a portion of the first and second wires 108, 110 extend from their corresponding bores 120 into the recessed region 122, as shown in
In another embodiment of the thermocouple assembly 100, illustrated in
During assembly, a portion of the first and second wires 108, 110 extend from their corresponding bores 120 into the recessed region 122, as shown in
In the embodiment illustrated in
During assembly, a portion of the first and second wires 108, 110 extend from their corresponding bores 120 into the recessed region 122, as shown in
In the embodiment illustrated in
During assembly, a portion of the first and second wires 108, 110 extend from their corresponding bores 120 into the recessed region 122, as shown in
The recessed regions 122 illustrated in
In an embodiment, the thermocouple junction 130 is in an abutting relationship with the inner surface of the sheath 102 at the measuring tip 118. The contact between the side walls 138 of the support member 104 and the sheath 102 absorbs nearly all of the spring force applied to the support member 104 by the spring 112 such that there is substantially no spring force biasing the thermocouple junction 130 against the measuring tip 118. Because the spring force is absorbed by the contact between the support member 104 and the sheath 102, the thermocouple junction 130 may remain in a substantially fixed location in contact with the measuring tip 118 without slipping or becoming deformed. In other embodiments, as shown in FIGS 6A-6E, the thermocouple junction 130 is located immediately adjacent to the inner surface of the sheath 102 at the measuring tip 118, thereby providing a minute gap between the thermocouple junction 130 and the sheath 102. It should be understood by one skilled in the art that the thermocouple junction 130 can be in contact with, or spaced apart from, the inner surface of the sheath 102 at the measuring tip 118, wherein the contact between the support member 104 and the sheath 102 is configured to reduce or eliminate the spring force that is typically biases the thermocouple junction 130 against the measuring tip 118 so as to allow the thermocouple junction 130 to remain in a substantially fixed location relative to the measuring tip 118 from thermocouple to thermocouple.
In the embodiment illustrated in
As illustrated in FIGS, 6A-6D, the thermocouple junction 130 is located at the base of the recessed region 122 formed in the support member 104. When located adjacent to the base of the recessed region 122, the spring 112 does not introduce a compression force into the thermocouple junction 130 as the spring 112 biases the support member 104 toward the measuring tip 118 of the thermocouple assembly 100. In center thermocouples commonly known in the art, the spring biases the junction into contact with the measuring tip to maintain contact between the junction and measuring tip. However, this spring force exerted on the junction compresses the junction against the inner surface of the sheath and typically causes the deformation of the junction that may result in errors in temperature measurements and premature failure of the thermocouple. In contrast, the thermocouple junction 130 of the improved thermocouple assembly 100 of the present invention is able to remain in a substantially fixed position within the recessed region 122 and in contact with, or immediately adjacent to, the sheath 102 at the measuring tip 118 such that the thermocouple junction 130 does not slide or become offset relative to the measuring tip 118 which may otherwise result if the thermocouple junction 130 were under constant compression between the support member 104 and the sheath 102 by the spring force from the spring 112. Because the thermocouple junction 130 remains in a substantially fixed location within the recessed region 122 of the support member 104 without sliding or becoming offset relative to the sheath 102, the temperature data provided by the thermocouple assembly 100 remains consistent. Further, preventing accidental sliding or the offset of the thermocouple junction 130 relative to the sheath 102 also increases the lifetime of the thermocouple assembly 100, because the temperature data of the thermocouple assembly 100 remains consistent after more thermal cycles within the reaction chamber 12.
The recessed region 122 is a generally indented region formed into the distal end of the support member 104 of the thermocouple assembly 100. In the embodiments illustrated in
As illustrated in
While preferred embodiments of the present invention have been described, it should be understood that the present invention is not so limited and modifications may be made without departing from the present invention. The scope of the present invention is defined by the appended claims, and all devices, process, and methods that come within the meaning of the claims, either literally or by equivalence, are intended to be embraced therein.
This application is a continuation application of and claims priority to U.S. patent application Ser. No. 12/436,300 entitled, “THERMOCOUPLE ASSEMBLY WITH GUARDED THERMOCOUPLE JUNCTION” and filed on May 6, 2009, which is hereby incorporated by reference in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
154695 | Manly | Sep 1874 | A |
2059480 | Obermaier | Nov 1936 | A |
2266416 | Duclos | Dec 1941 | A |
2480557 | Cummins | Aug 1949 | A |
2563931 | Harrison | Aug 1951 | A |
2660061 | Lewis | Nov 1953 | A |
3011006 | Nicholson | Nov 1961 | A |
3038951 | Mead | Jun 1962 | A |
3263502 | Springfield | Aug 1966 | A |
3588192 | Drutchas et al. | Jun 1971 | A |
3867205 | Schley | Feb 1975 | A |
3913058 | Nishio et al. | Oct 1975 | A |
4093491 | Whelpton et al. | Jun 1978 | A |
4217463 | Swearingen | Aug 1980 | A |
4234449 | Wolson et al. | Nov 1980 | A |
4355912 | Haak | Oct 1982 | A |
4377347 | Hanmyo et al. | Mar 1983 | A |
4444990 | Villar | Apr 1984 | A |
4454370 | Voznick | Jun 1984 | A |
4527005 | Mckelvey et al. | Jul 1985 | A |
4590326 | Woldy | May 1986 | A |
4592307 | Jolly | Jun 1986 | A |
4692556 | Bollen et al. | Sep 1987 | A |
4721533 | Phillippi et al. | Jan 1988 | A |
4721534 | Phillippi et al. | Jan 1988 | A |
4749416 | Greenspan | Jun 1988 | A |
4830515 | Cortes | May 1989 | A |
4934831 | Volbrecht | Jun 1990 | A |
4976996 | Monkowski et al. | Dec 1990 | A |
4978567 | Miller | Dec 1990 | A |
4984904 | Nakano et al. | Jan 1991 | A |
4989992 | Piai | Feb 1991 | A |
5027746 | Frijlink | Jul 1991 | A |
5061083 | Grimm et al. | Oct 1991 | A |
5065698 | Koike | Nov 1991 | A |
5071258 | Usher et al. | Dec 1991 | A |
5104514 | Quartarone | Apr 1992 | A |
5108192 | Mailliet et al. | Apr 1992 | A |
5158128 | Inoue et al. | Oct 1992 | A |
5176451 | Sasada et al. | Jan 1993 | A |
5181779 | Shia et al. | Jan 1993 | A |
5193912 | Saunders | Mar 1993 | A |
5228114 | Suzuki | Jul 1993 | A |
5246500 | Samata et al. | Sep 1993 | A |
5271967 | Kramer et al. | Dec 1993 | A |
5294778 | Carman et al. | Mar 1994 | A |
5315092 | Takahashi et al. | May 1994 | A |
5336327 | Lee | Aug 1994 | A |
5360269 | Ogawa et al. | Nov 1994 | A |
5374315 | Deboer et al. | Dec 1994 | A |
5421893 | Perlov | Jun 1995 | A |
5456761 | Auger et al. | Oct 1995 | A |
5474618 | Allaire | Dec 1995 | A |
5493987 | McDiarmid et al. | Feb 1996 | A |
5514439 | Sibley | May 1996 | A |
5527111 | Lysen et al. | Jun 1996 | A |
5562774 | Breidenbach et al. | Oct 1996 | A |
5571333 | Kanaya | Nov 1996 | A |
5611265 | Ronci et al. | Mar 1997 | A |
5663899 | Zvonar et al. | Sep 1997 | A |
5697706 | Ciaravino et al. | Dec 1997 | A |
5716133 | Hosokawa et al. | Feb 1998 | A |
5753835 | Gustin | May 1998 | A |
5788799 | Steger et al. | Aug 1998 | A |
5791782 | Wooten et al. | Aug 1998 | A |
5806980 | Berrian | Sep 1998 | A |
5857777 | Schuh | Jan 1999 | A |
5863123 | Lee | Jan 1999 | A |
5902407 | deBoer et al. | May 1999 | A |
5904778 | Lu et al. | May 1999 | A |
5910221 | Wu | Jun 1999 | A |
6045260 | Schwartz et al. | Apr 2000 | A |
6054678 | Miyazaki | Apr 2000 | A |
6056823 | Sajoto et al. | May 2000 | A |
6066209 | Sajoto et al. | May 2000 | A |
6091062 | Pfahnl et al. | Jul 2000 | A |
6102565 | Kita et al. | Aug 2000 | A |
6104011 | Juliano | Aug 2000 | A |
6120640 | Shih et al. | Sep 2000 | A |
6121061 | Van Bilsen et al. | Sep 2000 | A |
6129808 | Wicker et al. | Oct 2000 | A |
6170429 | Schoepp et al. | Jan 2001 | B1 |
6193414 | Balzano | Feb 2001 | B1 |
6227140 | Kennedy | May 2001 | B1 |
6235858 | Swarup et al. | May 2001 | B1 |
6243654 | Johnson et al. | Jun 2001 | B1 |
6257758 | Culbertson | Jul 2001 | B1 |
6293700 | Lund et al. | Sep 2001 | B1 |
6311016 | Yanagawa et al. | Oct 2001 | B1 |
6325858 | Wengert et al. | Dec 2001 | B1 |
6342691 | Johnsgard et al. | Jan 2002 | B1 |
6438502 | Awtrey | Aug 2002 | B1 |
6536950 | Green | Mar 2003 | B1 |
6580050 | Miller et al. | Jun 2003 | B1 |
6676290 | Lu | Jan 2004 | B1 |
7008802 | Lu | Mar 2006 | B2 |
7090394 | Hashikura et al. | Aug 2006 | B2 |
7166165 | Halpin | Jan 2007 | B2 |
7168852 | Linnarsson | Jan 2007 | B2 |
7223014 | Lojen | May 2007 | B2 |
7274867 | Peukert | Sep 2007 | B2 |
7320544 | Hsieh | Jan 2008 | B2 |
7410290 | Tanaka | Aug 2008 | B2 |
7561982 | Rund et al. | Jul 2009 | B2 |
7621672 | Ripley | Nov 2009 | B2 |
7651269 | Comendant | Jan 2010 | B2 |
7661299 | Kusunoki | Feb 2010 | B2 |
7753584 | Gambino et al. | Jul 2010 | B2 |
7789559 | Waser et al. | Sep 2010 | B2 |
7806587 | Kobayashi | Oct 2010 | B2 |
7871198 | Rempe et al. | Jan 2011 | B2 |
7874726 | Jacobs et al. | Jan 2011 | B2 |
7946762 | Yednak, III | May 2011 | B2 |
7957708 | Karschnia et al. | Jun 2011 | B2 |
7997795 | Schwagerman et al. | Aug 2011 | B2 |
8046193 | Yetter et al. | Oct 2011 | B2 |
8078310 | Nishimoto et al. | Dec 2011 | B2 |
8100583 | Conner et al. | Jan 2012 | B2 |
8262287 | Darabnia et al. | Sep 2012 | B2 |
8382370 | Aggarwal et al. | Feb 2013 | B2 |
8496377 | Harr et al. | Jul 2013 | B2 |
8506162 | Schick et al. | Aug 2013 | B2 |
8616765 | Darabnia et al. | Dec 2013 | B2 |
8864375 | Abe et al. | Oct 2014 | B2 |
20010040511 | Bushner et al. | Nov 2001 | A1 |
20020011211 | Halpin | Jan 2002 | A1 |
20020043337 | Goodman et al. | Apr 2002 | A1 |
20030002562 | Yerlikaya et al. | Jan 2003 | A1 |
20030035905 | Lieberman et al. | Feb 2003 | A1 |
20030192435 | McNair | Oct 2003 | A1 |
20030231698 | Yamaguchi | Dec 2003 | A1 |
20040208228 | Hashikura et al. | Oct 2004 | A1 |
20050042778 | Peukert | Feb 2005 | A1 |
20050092733 | Ito et al. | May 2005 | A1 |
20050101843 | Quinn et al. | May 2005 | A1 |
20050141591 | Sakano | Jun 2005 | A1 |
20060026314 | Franchuk et al. | Feb 2006 | A1 |
20060275933 | Du Bois et al. | Dec 2006 | A1 |
20070062439 | Wada et al. | Mar 2007 | A1 |
20070119377 | Halpin | May 2007 | A1 |
20070129621 | Kellogg et al. | Jun 2007 | A1 |
20070258506 | Schwagerman et al. | Nov 2007 | A1 |
20080043803 | Bandoh | Feb 2008 | A1 |
20080205483 | Rempe et al. | Aug 2008 | A1 |
20080228306 | Yetter et al. | Sep 2008 | A1 |
20080289574 | Jacobs et al. | Nov 2008 | A1 |
20080291964 | Shrimpling et al. | Nov 2008 | A1 |
20090034582 | Carcasi | Feb 2009 | A1 |
20090052498 | Halpin et al. | Feb 2009 | A1 |
20090159000 | Aggarwal et al. | Jun 2009 | A1 |
20090204403 | Hollander et al. | Aug 2009 | A1 |
20090308425 | Yednak, III | Dec 2009 | A1 |
20100145547 | Darabnia et al. | Jun 2010 | A1 |
20100246630 | Kaszynski et al. | Sep 2010 | A1 |
20100282163 | Aggarwal et al. | Nov 2010 | A1 |
20100284438 | Aggarwal et al. | Nov 2010 | A1 |
20100286842 | Aggarwal et al. | Nov 2010 | A1 |
20120231771 | Marcus | Sep 2012 | A1 |
20120310440 | Darabnia et al. | Dec 2012 | A1 |
Number | Date | Country |
---|---|---|
2101223 | Apr 1992 | CN |
1815155 | Aug 2006 | CN |
102439402 | May 2012 | CN |
102439712 | May 2012 | CN |
0229488 | Jul 1987 | EP |
0723141 | Jul 1996 | EP |
0887632 | Dec 1998 | EP |
2156155 | Feb 2010 | EP |
2185745 | May 2010 | EP |
2304402 | Apr 2011 | EP |
2370996 | Oct 2011 | EP |
1408266 | Aug 1965 | FR |
0752277 | Jul 1956 | GB |
5819462 | Apr 1982 | JP |
7-209093 | Aug 1985 | JP |
02185038 | Jul 1990 | JP |
05-023079 | Mar 1993 | JP |
5-64627 | Mar 1993 | JP |
05118928 | May 1993 | JP |
09-089676 | Apr 1997 | JP |
10-153494 | Jun 1998 | JP |
10-227703 | Aug 1998 | JP |
11-118615 | Apr 1999 | JP |
11-183264 | Jul 1999 | JP |
11-183265 | Jul 1999 | JP |
11-287715 | Oct 1999 | JP |
11281497 | Oct 1999 | JP |
2003035574 | Feb 2003 | JP |
2004-113270 | Apr 2004 | JP |
2005-172489 | Jun 2005 | JP |
2006-090762 | Apr 2006 | JP |
2006-153706 | Jun 2006 | JP |
2010537202 | Dec 2010 | JP |
2012526282 | Oct 2012 | JP |
10-2000-0031098 | Jun 2000 | KR |
10-2002-0086763 | Nov 2002 | KR |
10-2003-0092305 | Dec 2003 | KR |
321717 | Dec 1997 | TW |
200636827 | Oct 2006 | TW |
200730803 | Aug 2007 | TW |
9531582 | Nov 1995 | WO |
9706288 | Feb 1997 | WO |
9923690 | May 1999 | WO |
9923276 | May 1999 | WO |
0111223 | Feb 2001 | WO |
2008147731 | Dec 2008 | WO |
2009029532 | Mar 2009 | WO |
2009154896 | Dec 2009 | WO |
2010077533 | Jul 2010 | WO |
2010129428 | Nov 2010 | WO |
2010129430 | Nov 2010 | WO |
2010129431 | Nov 2010 | WO |
Entry |
---|
Summary of Office Action received Apr. 25, 2013 in Japanese Application No. 2012-509857. |
Office Action dated May 28, 2013 in U.S. Appl. No. 13/563,274. |
Office Action dated May 31, 2013 in U.S. Appl. No. 12/436,306. |
Advisory Action dated Jul. 9, 2013 in U.S. Appl. No. 12/193,924. |
Office Action dated Jan. 21, 2013 in Chinese Application No. 201080020268.1. |
Final Office Action dated Apr. 17, 2013 in U.S. Appl. No. 12/193,924. |
Introduction to Materials Science for Engineers, 3rd Ed., James F. Schackelford, pp. 398, Macmillan Publishing Co. (1992). |
Linke, J. And Vietzke, E., “Behavior of Boron Doped Graphites, Plasma Sprayed Boron Carbides and a—C/B H as Plasma Facing Material,” J. Fusion Tech., V.20, pp. 228-231 (Sep. 1991). |
Ponnekanti et al., “Failure Mechanisms of Anodized Aluminum Parts Used in Chemical Vapor Deposition Chambers,” J. Vac. Sci. Technol. A 14(3) (May 1, 1996). |
“Thermocouples for Silicon Process Technologies,” Vulcan Electric Company brochure. |
“Thermocouples for the Semiconductor Industry,” Engelhard Corporation brochure (2004). |
Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration, for International App. No. PCT/US2008/063919 dated Aug. 21, 2008. |
Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration, for International App. No. PCT/US2008/074063 dated Mar. 5, 2009. |
Notification of Transmittal of the International Search Report and Written Opinion for International Application No. PCT/ US2009/043454 dated Nov. 27, 2009. |
International Preliminary Report on Patentability for International App. No. PCT/US2008/074063 dated Feb. 24, 2010. |
Non-Final Office Action for U.S. Appl. No. 12/121,085 dated Apr. 28, 2010. |
International Search Report and Written Opinion for International Application No. PCT/US2010/033244 dated Jun. 29, 2010. |
International Search Report and Written Opinion for International Application No. PCT/US2009/066377 dated Jul. 1, 2010. |
Chinese Office Action dated Jul. 14, 2010 in Application No. 200880012927.X. |
International Search Report and Written Opinion for International Application No. PCT/US2010/033248 dated Jul. 29, 2010. |
Notice of Allowance for U.S. Appl. No. 12/121,085 dated Jul. 26, 2010. |
Non-Final Office Action for U.S. Appl. No. 12/140,809 dated Sep. 13, 2010. |
Notice of Allowance dated Oct. 4, 2010 in U.S. Appl. No. 12/121,085. |
Final Office Action for U.S. Appl. No. 12/140,809 dated Dec. 28, 2010. |
International Search Report and Written Opinion for International Application No. PCT/US2010/033252 dated Jan. 28, 2011. |
Non-Final Office Action dated Mar. 15, 2011 for U.S. Appl. No. 12/193,924. |
Notice of Allowance dated Mar. 17, 2011 for U.S. Appl. No. 12/140,809. |
Examination Report Dated May 26, 2011 for App. No. 09733043.5-2313. |
International Preliminary Report on Patentability dated Jun. 23, 2011 in Application No. PCT/US2009/066377. |
Non-Final Office Action dated Jul. 28, 2011 for U.S. Appl. No. 12/330,096. |
Non-Final Office Action dated Aug. 3, 2011 for U.S. Appl. No. 12/436,300. |
Non-Final Office Action dated Aug. 3, 2011 for U.S. Appl. No. 12/436,315. |
Final Office Action dated Sep. 30, 2011 for U.S. Appl. No. 12/193,924. |
International Preliminary Report on Patentability for International Application No. PCT/US2010/033244 dated Nov. 9, 2011. |
Notice of Allowance for U.S. Appl. No. 12/436,315 dated Nov. 17, 2011. |
International Preliminary Report on Patentability for PCT/US2010/033244 dated Nov. 17, 2011. |
International Preliminary Report on Patentability for PCT/US2010/033248 dated Nov. 17, 2011. |
International Preliminary Report on Patentability for PCT/US2010/033252 dated Nov. 17, 2011. |
Restriction Requirement for U.S. Appl. No. 12/436,306 dated Dec. 20, 2011. |
Official Action for Japanese Patent Application 2010-522075 dated Dec. 20, 2011. |
Final Office Action dated Jan. 13, 2012 for U.S. Appl. No. 12/330,096. |
Final Office Action dated Jan. 23, 2012 for U.S. Appl. No. 12/436,300. |
Notice of Allowance dated Mar. 6, 2012 for U.S. Appl. No. 12/330,096. |
Advisory Action dated Mar. 6, 2012 for U.S. Appl. No. 12/436,300. |
Non-Final Office Action dated Mar. 20, 2012 for U.S. Appl. No. 12/330,096. |
Non-Final Office Action dated Apr. 11, 2012 for U.S. Appl. No. 12/436,306. |
Official Action for Japanese Patent Application 2010-522075 mailed on Apr. 13, 2012. |
Non-Final Office Action dated May 22, 2012 in U.S. Appl. No. 12/436,300. |
Office Action dated Jun. 4, 2012 in Japanese Application No. 2011-514650. |
Notice of Allowance dated Jun. 7, 2012 in U.S. Appl. No. 12/330,096. |
Office Action dated Sep. 13, 2012 in Japanese Application No. 2011-514650. |
Final Office Action dated Sep. 26, 2012 in U.S. Appl. No. 12/436,306. |
Notice of Allowance dated Nov. 28, 2012 in U.S. Appl. No. 12/436,300. |
Office Action dated Oct. 24, 2012 in U.S. Appl. No. 12/193,924. |
Extended Search Report dated Nov. 9, 2012 in European Application No. 08798519.8. |
Notice of Allowance dated Dec. 21, 2012 in Japanese Application No. 2011-514650. |
Office Action dated Sep. 3, 2013 in Taiwanese Application No. 97132391. |
Office Action dated Sep. 26, 2013 in Chinese Application No. 201080020268.1. |
Notice of Allowance dated Sep. 27, 2013 in U.S. Appl. No. 13/563,274. |
Final Office Action dated Oct. 17, 2013 in U.S. Appl. No. 12/436,306. |
Office Action dated Apr. 3, 2014 in Chinese Application No. 201080020268.1. |
Office Action dated Dec. 10, 2013 in Chinese Application No. 201080020267.7. |
Office Action dated Dec. 20, 2013 in Taiwan Application No. 98117513. |
Office Action dated Feb. 4, 2014 in U.S. Appl. No. 12/436,306. |
USPTO; Final Office Action dated Jun. 23, 2014 in U.S. Appl. No. 12/436,306. |
Office Action dated Aug. 14, 2014 in Taiwan Application No. 099114331. |
Non-Final Office Action dated Feb. 3, 2015 in U.S. Appl. No. 12/436,306. |
Office Action dated Sep. 23, 2014 in Chinese Application No. 201080020268.1. |
Office Action dated Aug. 1, 2014 in Taiwan Application No. 099114329. |
Office Action dated Dec. 30, 2014 in Taiwan Application No. 099114330. |
Non-Final Office Action dated Oct. 14, 2015 in U.S. Appl. No. 12/436,306. |
Final Office Action dated Dec. 31, 2015 in U.S. Appl. No. 12/436,306. |
Number | Date | Country | |
---|---|---|---|
20130148693 A1 | Jun 2013 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 12436300 | May 2009 | US |
Child | 13760160 | US |