This application claims the benefit of Korean Application Nos. 10-2009-0081979, filed on Sep. 1, 2009 and 10-2010-0014276, filed on Feb. 17, 2010, in the Korean Intellectual Property Office, the disclosures of which are incorporated herein by reference.
1. Field of the Invention
Aspects of the present invention relates to a thin film deposition apparatus, and more particularly, to a thin film deposition apparatus that can be simply applied to manufacture thin films on the substrate on a mass scale and that improves manufacturing yield.
2. Description of the Related Art
Organic light-emitting display devices have a larger viewing angle, better contrast characteristics, and a faster response rate than other display devices, and thus have drawn attention as a next-generation display device.
In general, organic light-emitting display devices have a stacked structure including an anode, a cathode, and an emission layer interposed between the anode and the cathode, and display images in color when holes and electrons, injected respectively from the anode and the cathode, recombine in the emission layer such that light is emitted. However, it is difficult to achieve high light-emission efficiency with such a structure, and thus intermediate layers, including an electron injection layer, an electron transport layer, a hole transport layer, a hole injection layer, etc., may be additionally interposed between the emission layer and one or both of the electrodes.
Also, it is very difficult in practice to form fine patterns in organic thin films such as the emission layer and the intermediate layers, and red, green, and blue light-emission efficiency varies according to characteristics of the organic thin films. For these reasons, it is not easy to form an organic thin film pattern on a large substrate, such as a mother glass having a size of 5G or more, by using a conventional thin film deposition apparatus, and thus it is difficult to manufacture large organic light-emitting display devices having satisfactory driving voltage, current density, brightness, color purity, light-emission efficiency, life-span characteristics. Thus, there is a desire for improvement in this regard.
An organic light-emitting display device includes intermediate layers, including an emission layer disposed between a first electrode and a second electrode that are arranged opposite to each other. The electrodes and the intermediate layers may be formed by using various methods, one of which is a deposition method. When an organic light-emitting display device is manufactured by using the deposition method, a fine metal mask (FMM) having the same pattern as a thin film to be formed is disposed to closely contact a substrate, and a thin film material is deposited over the FMM in order to form the thin film having the desired pattern.
Aspects of the present invention provides a thin film deposition apparatus that may be easily manufactured, that may be simply applied to manufacture thin films on the substrate on a mass scale, that improves manufacturing yield and deposition efficiency, and that allows deposited materials to be reused.
According to an aspect of the present invention, there is provided a thin film deposition apparatus that forms a thin film on a substrate, the apparatus including: a deposition source that discharges a deposition material; a deposition source nozzle unit that is disposed at a side of the deposition source and includes a plurality of deposition source nozzles arranged in a first direction; a patterning slit sheet that is disposed opposite to the deposition source nozzle unit and includes a plurality of patterning slits arranged in the first direction; a barrier plate assembly that is disposed between the deposition source nozzle unit and, and includes a plurality of barrier plates in the first direction that partition a space between the deposition source nozzle unit and the patterning slit sheet into a plurality of sub-deposition spaces; and a blocking member that is disposed between the substrate and the deposition source and that is spaced apart from the substrate, wherein the thin film deposition apparatus is spaced apart from the substrate by a predetermined distance, the substrate and the thin film deposition apparatus move relative to each other, and when the substrate and the thin film depositon apparatus are moved relative to each other, the blocking member is moved along with the substrate to be positioned to screen at least one portion of the substrate.
According to a non-limiting aspect, the blocking member may screen a non-deposition region of the substrate.
According to a non-limiting aspect, the blocking member may screen edges of the substrate.
According to a non-limiting aspect, the blocking member may be positioned to move between the barrier plate assembly and the pattern slit sheet.
According to a non-limiting aspect, the blocking member may include a first blocking member that screens a first non-deposition region formed at a first end of the substrate and a second blocking member that screens a second non-deposition region formed at a second end of the substrate.
According to a non-limiting aspect, the first and second blocking members may have a flat plate shape.
According to a non-limiting aspect, the first and second blocking members may be moved along with the substrate such that the first blocking member is disposed to block deposition on the first non-deposition region, and the second blocking member is disposed to block deposition on the second non-deposition region.
According to a non-limiting aspect, the first and second blocking members may be moved at the same speed as that of the substrate.
According to a non-limiting aspect, positions of the first and second blocking members with respect to the substrate may be constantly maintained.
According to a non-limiting aspect, the first and second blocking members may have a U-shaped cross-section.
According to a non-limiting aspect, one of the first and second blocking members may have a U-shaped cross-section, and the other of the first and second blocking members may have an L-shaped cross-section.
According to a non-limiting aspect, the first and second blocking members may overlap with each other when deposition is not being performed on the substrate.
According to a non-limiting aspect, the first and second blocking members may be moved along with the substrate such that the first blocking member screens the first non-deposition region while the first blocking member is moved between the blocking plate assembly and the patterning slit sheet, and the second blocking member screens the second non-deposition region while the second blocking member is moved between the blocking plate assembly and the patterning slit sheet.
According to a non-limiting aspect, the first blocking member may be moved at the same speed as that of the substrate while the first blocking member is moved between the barrier plate assembly and the patterning slit sheet, and the second blocking member may be moved at the same speed as that of the substrate while the second blocking member is moved between the barrier plate assembly and the patterning slit sheet.
According to a non-limiting aspect, t position of the first blocking member with respect to the substrate may be constantly maintained while the first blocking member is moved between the barrier plate assembly and the patterning slit sheet, and a position of the second blocking member with respect to the substrate may be constantly maintained while the second blocking member is moved between the barrier plate assembly and the patterning slit sheet.
According to a non-limiting aspect, the patterning slit sheet may be smaller than the substrate.
According to a non-limiting aspect, each of the plurality of barrier plates may extend in a second direction that is substantially perpendicular to the first direction.
According to a non-limiting aspect, each of the barrier plate assemblies may include a first barrier plate assembly including a plurality of first barrier plates, and a second barrier plate assembly including a plurality of second barrier plates.
According to a non-limiting aspect, the deposition material contained in the deposition source of thin film deposition apparatus may be continuously deposited on the substrate while the substrate is moved relative to the thin film deposition apparatus.
According to a non-limiting aspect, the thin film deposition apparatus or the substrate may move relative to each other along a plane parallel to a surface of the substrate on which the deposition materials are deposited.
According to an aspect of the present invention, there is provided a thin film deposition apparatus for forming a thin film on a substrate, the apparatus including: a deposition source that discharges a deposition material; a deposition source nozzle unit that is disposed at a side of the deposition source and includes a plurality of deposition source nozzles arranged in a first direction; a patterning slit sheet that is disposed opposite to the deposition source nozzle unit and includes a plurality of patterning slits arranged in a second direction perpendicular to the first direction; and a blocking member that is disposed between the substrate and the deposition source, wherein a deposition is performed while the substrate and the thin film deposition apparatus move relative to each other in the first direction, the deposition source, the deposition source nozzle unit, and the patterning slit sheet are formed integrally with each other, and when a deposition is performed, the blocking member moves along with the substrate to be positioned to screen at least one portion of the substrate.
According to a non-limiting aspect, the blocking member may screen a non-deposition region of the substrate.
According to a non-limiting aspect, the blocking member may screen edges of the substrate.
According to a non-limiting aspect, the blocking member may be positioned to move between the barrier plate assembly and the pattern slit sheet.
According to a non-limiting aspect, the blocking member may include a first blocking member that screens a first non-deposition region formed at a first end of the substrate and a second blocking member that screens a second non-deposition region formed at a second end of the substrate.
According to a non-limiting aspect, the first and second blocking members may have a flat plate shape.
According to a non-limiting aspect, the first and second blocking members may be moved along with the substrate such that the first blocking member is disposed to block deposition on the first non-deposition region, and the second blocking member may be disposed to block deposition on the second non-deposition region.
According to a non-limiting aspect, the first and second blocking members may be moved at the same speed as that of the substrate.
According to a non-limiting aspect, positions of the first and second blocking members with respect to the substrate may be constantly maintained.
According to a non-limiting aspect, the first and second blocking members may have a U-shaped cross-section.
According to a non-limiting aspect, one of the first and second blocking members may have a U-shaped cross-section, and the other of the first and second blocking members may have an L-shaped cross-section.
According to a non-limiting aspect, the first and second blocking members may be overlap with each other when deposition is not being performed on the substrate.
According to a non-limiting aspect, the first and second blocking members may be moved along with the substrate such that the first blocking member screens the first non-deposition region while the first blocking member is moved between the blocking plate assembly and the patterning slit sheet, and the second blocking member may screen the second non-deposition region while the second blocking member is moved between the blocking plate assembly and the patterning slit sheet.
According to a non-limiting aspect, the first blocking member may be moved at the same speed as that of the substrate while the first blocking member is moved between the barrier plate assembly and the patterning slit sheet, and the second blocking member may be moved at the same speed as that of the substrate while the second blocking member is moved between the barrier plate assembly and the patterning slit sheet.
According to a non-limiting aspect, a position of the first blocking member with respect to the substrate may be constantly maintained while the first blocking member is moved between the barrier plate assembly and the patterning slit sheet, and a position of the second blocking member with respect to the substrate may be constantly maintained while the second blocking member is moved between the barrier plate assembly and the patterning slit sheet.
According to a non-limiting aspect, the deposition source and the deposition source nozzle unit, and the patterning slit sheet may be connected to each other by a connection member.
According to a non-limiting aspect, the connection member may guide movement of the discharged deposition material.
According to a non-limiting aspect, the connection member may seal a space between the deposition source and the deposition source nozzle unit, and the patterning slit sheet.
According to a non-limiting aspect, the thin film deposition apparatus may be spaced apart from the substrate by a predetermined distance.
According to a non-limiting aspect, the deposition material discharged from the thin film deposition apparatus may be continuously deposited on the substrate while the substrate is moved relative to the thin film deposition apparatus in the first direction.
According to a non-limiting aspect, the patterning slit sheet of the thin film deposition apparatus may be smaller than the substrate.
According to a non-limiting aspect, the plurality of deposition source nozzles may be tilted at a predetermined angle.
According to a non-limiting aspect, the plurality of deposition source nozzles may include deposition source nozzles arranged in two rows arranged in the first direction, and the deposition source nozzles in each of the two rows may be tilted at the predetermined angle toward a corresponding deposition source nozzle of the other of the two rows.
According to a non-limiting aspect, the plurality of deposition source nozzles may include deposition source nozzles arranged in two rows formed in the first direction, the deposition source nozzles arranged in a row located at a first side of the patterning slit sheet may be arranged to face a second side of the patterning slit sheet, and the deposition source nozzles arranged in the other row located at the second side of the patterning slit sheet may be arranged to face the first side of the patterning slit sheet.
According to another aspect of the present invention, a thin film deposition apparatus that forms a thin film on a substrate includes a deposition source that discharges a deposition material; a patterning slit sheet that is disposed opposite to and spaced apart from the deposition source and comprises a plurality of patterning slits arranged in the first direction through which the deposition material travels to be deposited on the substrate; a blocking member that is positioned between the substrate and the deposition source to screen a non-deposition region of the substrate, wherein the substrate and the thin film deposition apparatus move relative to each other during a deposition process, and wherein when the substrate and the thin film deposition apparatus are moved relative to each other during the deposition process, the blocking member is moved between the deposition source and the patterning slit sheet to maintain a screening position with respect to the non-deposition region of the substrate
Additional aspects and/or advantages of the invention will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the invention.
These and/or other aspects and advantages of the invention will become apparent and more readily appreciated from the following description of the embodiments, taken in conjunction with the accompanying drawings of which:
Reference will now be made in detail to the present embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to the like elements throughout. The embodiments are described below in order to explain the aspects of the present invention by referring to the figures.
Referring to
Although a chamber is not illustrated in
In particular, in order to deposit a deposition material 115 that is emitted from the deposition source 110 and is discharged through the deposition source nozzle unit 120 and the patterning slit sheet 150, onto a substrate 400 in a desired pattern, it is desirable to maintain a chamber (not shown) in a high-vacuum state as in a deposition method using a fine metal mask (FMM). In addition, the temperatures of barrier plates 131 and the patterning slit sheet 150 may be sufficiently lower than the temperature of the deposition source 110. In this regard, the temperatures of the barrier plates 131 and the patterning slit sheet 150 may be about 100° C. or less, since the deposition material 115 that has collided against the barrier plates 131 does not become vaporized again when the temperature of the barrier plates 131 is sufficiently low. In addition, thermal expansion of the patterning slit sheet 150 may be minimized when the temperature of the patterning slit sheet 150 is sufficiently low. The barrier plate assembly 130 faces the deposition source 110 which is at a high temperature. In addition, the temperature of a portion of the barrier plate assembly 130 close to the deposition source 110 may rise by a maximum of about 167° C., and thus a partial-cooling apparatus may be further included if needed. To this end, the barrier plate assembly 130 may include a cooling member.
The substrate 400, which constitutes a deposition target on which a deposition material 115 is to be deposited, is disposed in the chamber. The substrate 400 may be a substrate for flat panel displays. A large substrate, such as a mother glass, for manufacturing a plurality of flat panel displays, may be used as the substrate 400. Other substrates may also be employed.
In the current embodiment of the present invention, deposition may be performed while the substrate 400 or the thin film deposition apparatus 100 is moved relative to each other. Herein, where it is stated that the substrate and thin film deposition assembly are moved relative to each other, it is to be understood that such statement encompasses an embodiment in which only the substrate is moved and the thin film deposition assembly remains stationary, an embodiment in which only the thin film deposition assembly is moved and the substrate remains stationary and an embodiment in which both the thin film deposition assembly and the substrate are moved.
In particular, in the conventional FMM deposition method, the size of the FMM is typically greater than or equal to the size of a substrate. Thus, the size of the FMM has to be increased when performing deposition on a larger substrate. However, it is difficult to manufacture a large FMM and to extend an FMM to be accurately aligned with a pattern.
In order to overcome this problem, in the thin film deposition apparatus 100 according to the current embodiment of the present invention, deposition may be performed while the thin film deposition apparatus 100 and the substrate 400 are moved relative to each other. In other words, deposition may be continuously performed while the substrate 400, which is disposed such as to face the thin film deposition apparatus 100, is moved in a Y-axis direction. That is, deposition is performed in a scanning manner while the substrate 400 is moved in a direction of arrow A in
Thus, in the thin film deposition apparatus 100 according to the current embodiment of the present invention, the patterning slit sheet 150 may be significantly smaller than an FMM used in a conventional deposition method. In other words, in the thin film deposition apparatus 100 according to the current embodiment of the present invention, deposition is continuously performed, i.e., in a scanning manner, while the substrate 400 is moved in the Y-axis direction. Thus, lengths of the patterning slit sheet 150 in the X-axis and Y-axis directions may be significantly less than the lengths of the substrate 400 in the X-axis and Y-axis directions. As described above, since the patterning slit sheet 150 may be formed to be significantly smaller than an FMM used in a conventional deposition method, it is relatively easy to manufacture the patterning slit sheet 150 used in embodiments of the present invention. In other words, using the patterning slit sheet 150, which is smaller than an FMM used in a conventional deposition method, is more convenient in all processes, including etching and subsequent other processes, such as precise extension, welding, moving, and cleaning processes, compared to the conventional deposition method using the larger FMM. This is more advantageous for manufacturing a relatively large display device.
In order to perform deposition while the thin film deposition apparatus 100 and the substrate 400 are moved relative to each other as described above, the thin film deposition apparatus 100 and the substrate 400 may be separated from each other by a predetermined distance. This will be described later in detail.
The deposition source 110 that contains and heats the deposition material 115 is disposed in the chamber at a side of the thin film deposition assembly 100 that is opposite to and spaced apart from the substrate 400. As the deposition material 115 contained in the deposition source 110 is vaporized, the deposition material 115 is deposited on the substrate 400.
In particular, the deposition source 110 includes a crucible 111 that is filled with the deposition material 115, and a heater 112 that heats the crucible 111 to vaporize the deposition material 115, which is contained in the crucible 111. The vaporized deposition material 115 travels from the crucible 111 towards the deposition source nozzle unit 120.
The deposition source nozzle unit 120 is disposed at a side of the deposition source 110, and in particular, at the side of the deposition source 110 facing the substrate 400. The deposition source nozzle unit 120 includes a plurality of deposition source nozzles 121 arranged at equal intervals in the X-axis direction. The deposition material 115 that is vaporized in the deposition source 110, passes through the deposition source nozzle unit 120 towards the substrate 400.
The barrier plate assembly 130 is disposed at a side of the deposition source nozzle unit 120. The barrier plate assembly 130 includes a plurality of barrier plates 131, and a barrier plate frame 132 that covers sides of the barrier plates 131. The plurality of barrier plates 131 may be arranged parallel to each other at equal intervals in X-axis direction. In addition, each of the barrier plates 131 may be arranged parallel to an YZ plane in
The barrier plates 131 may be respectively disposed between adjacent deposition source nozzles 121. In other words, each of the deposition source nozzles 121 may be disposed between two adjacent barrier plates 131. The deposition source nozzles 121 may be respectively located at the midpoint between two adjacent barrier plates 131. As described above, since the barrier plates 131 partition the space between the deposition source nozzle unit 120 and the patterning slit sheet 150 into the plurality of sub-deposition spaces S, the deposition material 115 discharged through each of the deposition source nozzles 121 is not mixed with the deposition material 115 discharged through the other deposition source nozzles slits 121, and passes through patterning slits 151 so as to be deposited on the substrate 400. In other words, the barrier plates 131 guide the deposition material 115, which is discharged through the deposition source nozzles 121, to move straight, not to flow in the (X-axis direction).
As described above, the deposition material 115 is forced to move straight by the presence of the barrier plates 131, so that a smaller shadow zone may be formed on the substrate 400 compared to a case where no barrier plates are installed. Thus, the thin film deposition apparatus 100 and the substrate 400 can be separated from each other by a predetermined distance. This will be described later in detail.
The barrier plate frame 132, which forms upper and lower sides of the barrier plates 131, maintains the positions of the barrier plates 131, and guides the deposition material 115, which is discharged through the deposition source nozzles 121, not to flow beyond the boundaries of the barrier wall assembly 130 in the Y-axis direction.
Although the deposition source nozzle unit 120 and the barrier plate assembly 130 are illustrated as being separated from each other by a predetermined distance, the present invention is not limited thereto. In order to prevent the heat emitted from the deposition source 110 from being conducted to the barrier plate assembly 130, the deposition source nozzle unit 120 and the barrier plate assembly 130 may be spaced apart from each other by a predetermined distance. Alternatively, if a heat insulator is disposed between the deposition source nozzle unit 120 and the barrier plate assembly 130, the deposition source nozzle unit 120 and the barrier plate assembly 130 may be joined together with the heat insulator therebetween.
In addition, the barrier plate assembly 130 may be constructed to be detachable from the thin film deposition apparatus 100. A conventional FMM deposition method has low deposition efficiency. Herein, deposition efficiency refers to the ratio of the amount of deposition material deposited on a substrate to the amount of deposition material vaporized from a deposition source. The conventional FMM deposition method has a deposition efficiency of about 32%. Furthermore, in the conventional FMM deposition method, about 68% of organic deposition material, which has not been deposited on the substrate, remains adhered to a deposition apparatus, and thus it is difficult to reuse the deposition material.
In order to overcome these problems, in the thin film deposition apparatus 100 according to the current embodiment of the present invention, the deposition space is enclosed by using the barrier plate assembly 130, so that the vaporized deposition material 115 that is not deposited on the substrate 400 is mostly deposited within the barrier plate assembly 130. Thus, since the barrier plate assembly 130 is constructed to be detachable from the thin film deposition apparatus 100, when a large amount of the deposition material 115 is present on the barrier plate assembly 130 after a long deposition process, the barrier plate assembly 130 may be detached from the thin film deposition apparatus 100 and then placed in a separate deposition material recycling apparatus in order to recover the deposition material 115. Due to the structure of the thin film deposition apparatus 100 according to the present embodiment, a reuse rate of the deposition material 115 is increased, so that the deposition efficiency is improved, and thus, the manufacturing costs are reduced.
The patterning slit sheet 150 and a frame 155 in which the patterning slit sheet 150 is bound are disposed between the deposition source 110 and the substrate 400. The frame 155 may be formed in a lattice shape, similar to a window frame. The patterning slit sheet 150 is bound inside the frame 155. The patterning slit sheet 150 includes a plurality of patterning slits 151 arranged in the X-axis direction. The deposition material 115 that is vaporized in the deposition source 110, passes through the deposition source nozzle unit 120 and the patterning slit sheet 150 towards the substrate 400. The patterning slit sheet 150 may be manufactured by etching, which is the same method as used in a conventional method of manufacturing an FMM, and in particular, a striped FMM.
In the thin film deposition apparatus 100 according to the current embodiment of the present invention, the total number of patterning slits 151 may be greater than the total number of deposition source nozzles 121. In addition, there may be a greater number of patterning slits 151 than deposition source nozzles 121 disposed between two adjacent barrier plates 131.
In other words, at least one deposition source nozzle 121 may be disposed between each two adjacent barrier plates 131. Meanwhile, a plurality of patterning slits 151 may be disposed between each two adjacent barrier plates 131. The space between the deposition source nozzle unit 120 and the patterning slit sheet 150 is partitioned by the barrier plates 131 into sub-deposition spaces S that correspond to the deposition source nozzles 121, respectively. Thus, the deposition material 115 discharged from each of the deposition source nozzles 121 passes through a plurality of patterning slits 151 disposed in the sub-deposition space S corresponding to the deposition source nozzle 121, and is then deposited on the substrate 400.
The first and second blocking members 161 and 162 are disposed between the barrier plate assembly 130 and the patterning slit sheet 150. In the thin film deposition apparatus according to the current embodiment of the present invention, the first and second blocking members 161 and 162 are disposed to move along with the substrate 400 and screen first and second non-deposition regions 401 and 402 of the substrate 400 so that an deposition material 115 is prevented from being deposited on the first and second non-deposition regions 401 and 402 of the substrate 400. This will be described later in detail with reference to
The barrier plate assembly 130 and the patterning slit sheet 150 may be formed to be spaced apart from each other by a predetermined distance. Alternatively, the barrier plate assembly 130 and the patterning slit sheet 150 may be connected by a connection member 135. The temperature of the barrier plate assembly 130 may increase to 100° C. or higher due to exposure to the deposition source 110, which has a high temperature. Thus, in order to prevent the heat of the barrier plate assembly 130 from being conducted to the patterning slit sheet 150, the barrier plate assembly 130 and the patterning slit sheet 150 may be spaced apart from each other by a predetermined distance.
As described above, the thin film deposition apparatus 100 according to the current embodiment of the present invention performs deposition while being moved relative to the substrate 400. In order for the thin film deposition apparatus 100 to be movable relative to the substrate 400, the patterning slit sheet 150 is spaced apart from the substrate 400 by a predetermined distance. In addition, in order to prevent the formation of a relatively large shadow zone on the substrate 400 when the patterning slit sheet 150 and the substrate 400 are separated from each other, the barrier plates 131 are arranged between the deposition source nozzle unit 120 and the patterning slit sheet 150 to force the deposition material 115 to move in a straight direction. Thus, the size of the shadow zone formed on the substrate 400 is sharply reduced.
In particular, in a conventional deposition method using an FMM, deposition is performed with the FMM in close contact with a substrate in order to prevent formation of a shadow zone on the substrate. However, when the FMM is used in close contact with the substrate, the contact may cause defects. In addition, in the conventional deposition method, the size of the mask has to be the same as the size of the substrate since the mask cannot be moved relative to the substrate. Thus, the size of the mask has to be increased as display devices become larger. However, it is not easy to manufacture such a large mask.
In order to overcome this and/or other problems, in the thin film deposition apparatus 100 according to the current embodiment of the present invention, the patterning slit sheet 150 is disposed to be separated from the substrate 400 by a predetermined distance. Shadow zones on the substrate 400 are minimized by installing the barrier plates 131.
As described above, according to aspects of the present invention, a mask is formed to be smaller than a substrate, and deposition is performed while the mask is moved relative to the substrate. Thus, the mask can be easily manufactured. In addition, defects caused due to the contact between a substrate and an FMM, which occurs in the conventional deposition method, may be prevented. Furthermore, since it is unnecessary to use the FMM in close contact with the substrate during a deposition process, the manufacturing speed may be improved.
Hereinafter, the size of a shadow zone formed on a substrate when barrier plates are installed and the size of a shadow zone formed on a substrate when no barrier plates are installed are compared.
Referring to
When the space between the deposition source nozzle unit 120 and the patterning slit sheet 150 is partitioned by the barrier plate assembly 130, as illustrated in
SH1=s*ds/h [Equation 1]
where s denotes a distance between the patterning slit sheet 150 and the substrate 400, ds denotes a width of each of the deposition source nozzles 121, and h denotes a distance between the deposition source 110 and the patterning slit sheet 150.
However, when the space between the deposition source nozzle unit 120 and the patterning slit sheet 150 is not partitioned by the barrier plates 131, as illustrated in
SH2=s*2d/h [Equation 2]
where s denotes a distance between the patterning slit sheet 150 and the substrate 400, d denotes an interval between adjacent barrier plates 131, and h denotes a distance between the deposition source 110 and the patterning slit sheet 150.
Referring to Equations 1 and 2, ds, which is the width of each of the deposition source nozzles 121, is a few to tens times less than d, which is the interval between the adjacent barrier plates 131, and thus the shadow zone may have a smaller width when the space between the deposition source nozzle unit 120 and the patterning slit sheet 150 is partitioned by the barrier plates 131. The width SH2 of the shadow zone formed on the substrate 400 may be reduced by either one of the following: (1) by reducing the interval d between the adjacent barrier plates 131, (2) by reducing the distance s between the patterning slit sheet 150 and the substrate 400, or (3) by increasing the distance h between the deposition source 110 and the patterning slit sheet 150.
As described above, the shadow zone formed on the substrate 400 may be reduced by installing the barrier plates 131. Thus, the patterning slit sheet 150 can be spaced apart from the substrate 400.
It is to be understood that the thin film deposition apparatus 100 may vary from what is described above.
Hereinafter, a method of performing thin film deposition using the first and second blocking members 161 and 162 of the thin film deposition apparatus 100, according to the current embodiment of the present invention, will be described in detail.
Referring to
Specifically, an anode electrode pattern or a cathode electrode pattern is formed on the edges of the substrate 400, wherein the anode electrode pattern or cathode electrode pattern is used as a terminal for product testing or manufacturing. If the organic material is deposited on the first and second non-deposition regions 401 and 402, the anode electrode or the cathode electrode may not function properly. Thus, it is desirable to avoid deposition of organic material on the first and second non-deposition regions 401 and 402. As described above, however, since deposition is performed using a scanning method while the substrate 400 is moved relative to the thin film deposition apparatus 100 according to the current embodiment of the present invention, it is not easy to prevent the organic material from being deposited on the first and second non-deposition regions 401 and 402 of the substrate 400.
As such, in order to prevent the deposition of the organic material on the first and second non-deposition regions 401 and 402 of the substrate 400, the thin film deposition apparatus 100 according to the current embodiment of the present invention includes the first and second blocking members 161 and 162 disposed at the edges of the substrate 400.
Referring to
As described above, deposition may be continuously performed while the substrate 400, which is disposed such as to face the thin film deposition apparatus 100, is moved in the Y-axis direction. In other words, deposition is performed in a scanning manner while the substrate 400 is moved in a direction of an arrow A in
As shown in
In addition, as shown in
Since the first and second blocking members 161 and 162 screen the first and second non-deposition regions 401 and 402 of the substrate 400, the organic material may be prevented from being deposited on the first and second non-deposition regions 401 and 402 of the substrate 400 without the necessity of providing another structure.
As shown in
Hereinafter, a method of performing thin film deposition using first and second blocking members 161 and 162 of a thin film deposition apparatus 100 according to a modification of the current embodiment will be described in detail.
Referring to
Since the space in a chamber (not shown) in which the thin film deposition apparatus 100 is disposed is limited, it is desirable that the space taken up by the first and second blocking members 161 and 162 be minimized to improve space utilization. In this regard, if the position of the first blocking member 161 that screens the first non-deposition region 401 of the substrate 400 relative to the substrate 400 and the position of the second blocking member 162 that screens the second non-deposition region 402 of the substrate 400 relative to the substrate 400 are fixed, the space occupied by the first and second blocking members 161 and 162 increases in the chamber.
Thus, in order to minimize the space occupied by the first and second blocking members 161 and 162 in the chamber, as shown in
As shown in
In this regard, the cross-sections of the first and second blocking members 161 and 162 may have a U shape in order to prevent the deposition material 115 from being deposited on the first and second non-deposition regions 401 and 402 by blocking the deposition material 115 incident from the side of the first and second blocking members 161 and 162 from reaching the first and second non-deposition regions 401 and 402.
However, as described above, in order to minimize the space occupied by the first and second blocking members 161 and 162 in the chamber, at least one side of one of the first and second blocking members 161 and 162 may be open. That is, as shown in
Since the first and second non-deposition regions 401 and 402 are screened by the first and second blocking members 161 and 162, the organic material may be prevented from being deposited on the first and second non-deposition regions 401 and 402 of the substrate 400 without the necessity of providing another structure. In addition, the pathway of the first and second blocking members 161 and 162 may be reduced, and space utilization in the chamber may be improved.
Referring to
Although a chamber is not illustrated in
The substrate 400, which constitutes a deposition target on which the deposition material 515 is to be deposited, is disposed in the chamber. The deposition source 510 that contains and heats the deposition material 515 is disposed in the chamber at a side of the thin film deposition apparatus 500 that is opposite to and spaced apart from the substrate 400.
Since the deposition source 510 and the patterning slit sheet 550 are the same as those described with reference to
The second barrier plate assembly 540 is disposed at a side of the first barrier plate assembly 530. The second barrier plate assembly 540 includes a plurality of second barrier plates 541, and a second barrier plate frame 542 that covers sides of the second barrier plates 541.
The plurality of second barrier plates 541 may be arranged parallel to each other at equal intervals in the X-axis direction. In addition, each of the second barrier plates 541 may be formed to extend in the YZ plane in
The plurality of first barrier plates 531 and second barrier plates 541 arranged as described above partition the space between the deposition source nozzle unit 520 and the patterning slit sheet 550. In the thin film deposition apparatus 500 according to the current embodiment of the present invention, the deposition space is divided by the first barrier plates 531 and the second barrier plates 541 into sub-deposition spaces that respectively correspond to the deposition source nozzles 521 through which the deposition material 515 is discharged.
The second barrier plates 541 may be disposed to correspond respectively to the first barrier plates 531. In other words, the second barrier plates 541 may be respectively disposed to be parallel to and to be on the same plane as the first barrier plates 531. Each pair of the corresponding first and second barrier plates 531 and 541 may be located on the same plane. Although the first barrier plates 531 and the second barrier plates 541 are respectively illustrated as having the same thickness in the X-axis direction, the present invention is not limited thereto. In other words, the second barrier plates 541, which may be accurately aligned with the patterning slit sheet 551, may be formed to be relatively thin, whereas the first barrier plates 531, which do not need to be precisely aligned with the patterning slit sheet 550, may be formed to be relatively thick. This makes it easier to manufacture the thin film deposition apparatus 500.
The first and second blocking members 561 and 562 of the thin film deposition apparatus 500 according to the present embodiment are moved along with the substrate 400 and screen first and second non-deposition regions 401 and 402 of the substrate 400 so as to prevent the organic material from being deposited on the first and second non-deposition regions 401 and 402 of the substrate 400. The first and second blocking members 561 and 562 are also the same as the first and second blocking members 161 and 162 described with
Referring to
An active layer 52 having a predetermined pattern is formed on the buffer layer 51. A gate insulating layer 53 is formed on the active layer 52, and a gate electrode 54 is formed in a predetermined region of the gate insulating layer 53. The gate electrode 54 is connected to a gate line (not shown) that applies a TFT ON/OFF signal. An interlayer insulating layer 55 is formed on the gate electrode 54. Source/drain electrodes 56 and 57 are formed such as to contact source/drain regions 52a and 52c, respectively, of the active layer 52 through contact holes. A passivation layer 58 is formed of SiO2, SiNx, etc. on the source/drain electrodes 56 and 57. A planarization layer 59 is formed of an organic material, such as acryl, polyimide, benzocyclobutene (BCB), etc., on the passivation layer 58. A pixel electrode 61, which functions as an anode of the OLED, is formed on the planarization layer 59, and a pixel defining layer 60 formed of an organic material is formed to cover the pixel electrode 61. An opening is formed in the pixel defining layer 60, and then an organic layer 62 is formed on a surface of the pixel defining layer 60 and on a surface of the pixel electrode 61 exposed through the opening. The organic layer 62 includes an emission layer. The present invention is not limited to the structure of the organic light-emitting display device described above, and various structures of organic light-emitting display devices may be applied to the various aspects of the present invention.
The OLED displays predetermined image information by emitting red, green and blue light as current flows. The OLED includes the pixel electrode 61, which is connected to the drain electrode 56 of the TFT and to which a positive power voltage is applied, a counter electrode 63, which is formed so as to cover the entire sub-pixel and to which a negative power voltage is applied, and the organic layer 62, which is disposed between the pixel electrode 61 and the counter electrode 63 to emit light.
The pixel electrode 61 and the counter electrode 63 are insulated from each other by the organic layer 62, and respectively apply voltages of opposite polarities to the organic layer 62 to induce light emission in the organic layer 62.
The organic layer 62 may include a low-molecular weight organic layer or a high-molecular weight organic layer. When a low-molecular weight organic layer is used as the organic layer 62, the organic layer 62 may have a single or multi-layer structure including at least one selected from the group consisting of a hole injection layer (HIL), a hole transport layer (HTL), an emission layer (EML), an electron transport layer (ETL), an electron injection layer (EIL), etc. Examples of available organic materials include copper phthalocyanine (CuPc), N,N′-di(naphthalene-1-yl)-N,N′-diphenyl-benzidine (NPB), tris-8-hydroxyquinoline aluminum (Alq3), etc. The low-molecular weight organic layer may be formed by vacuum deposition.
When a high-molecular weight organic layer is used as the organic layer 62, the organic layer 62 may mostly have a structure including a HTL and an EML. In this case, the HTL may be formed of poly(ethylenedioxythiophene) (PEDOT), and the EML may be formed of polyphenylenevinylenes (PPVs) or polyfluorenes. The HTL and the EML may be formed by screen printing, inkjet printing, or the like.
The organic layer 62 is not limited to the organic layers described above, and may be embodied in various ways.
The pixel electrode 61 may function as an anode, and the counter electrode 63 may function as a cathode. Alternatively, the pixel electrode 61 may function as a cathode, and the counter electrode 63 may function as an anode.
The pixel electrode 61 may be formed as a transparent electrode or a reflective electrode. Such a transparent electrode may be formed of indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), or indium oxide (In2O3). Such a reflective electrode may be formed by forming a reflective layer from silver (Ag), magnesium (Mg), aluminum (Al), platinum (Pt), palladium (Pd), gold (Au), nickel (Ni), neodymium (Nd), iridium (Ir), chromium (Cr) or a compound thereof and forming a layer of ITO, IZO, ZnO, or In2O3 on the reflective layer.
The counter electrode 63 may be formed as a transparent electrode or a reflective electrode. When the counter electrode 63 is formed as a transparent electrode, the counter electrode 63 functions as a cathode. To this end, such a transparent electrode may be formed by depositing a metal having a low work function, such as lithium (Li), calcium (Ca), lithium fluoride/calcium (LiF/Ca), lithium fluoride/aluminum (LiF/Al), aluminum (Al), silver (Ag), magnesium (Mg), or a compound thereof on a surface of the organic layer 62 and forming an auxiliary electrode layer or a bus electrode line thereon from a transparent electrode forming material, such as ITO, IZO, ZnO, In2O3, or the like. When the counter electrode 63 is formed as a reflective electrode, the reflective layer may be formed by depositing Li, Ca, LiF/Ca, LiF/Al, Al, Ag, Mg, or a compound thereof on the entire surface of the organic layer 62.
In the organic light-emitting display apparatus described above, the organic layer 62 including the emission layer may be formed by using any of the embodiments of a thin film deposition apparatus described herein or by using a chamber including a plurality of such thin film deposition apparatuses. The thin film deposition apparatus may also be used to form an organic layer or inorganic layer of an organic TFT, and other layers formed of various material.
It is to be understood that the organic light-emitting display device may vary from what is described above.
Referring to
Although a chamber is not illustrated in
In particular, in order to deposit a deposition material 915 that is emitted from the deposition source 910 and is discharged through the deposition source nozzle unit 920 and the patterning slit sheet 950, onto a substrate 400 in a desired pattern, it is required to maintain a chamber (not shown) in a high-vacuum state as in a deposition method using a fine metal mask (FMM). In addition, the temperature of the patterning slit sheet 950 have to be sufficiently lower than the temperature of the deposition source 910. In this regard, the temperature of the patterning slit sheet 950 may be about 100° C. or less. This is because thermal expansion of the patterning slit sheet 950 may be minimized when the temperature of the patterning slit sheet 950 is sufficiently low.
The substrate 400, which constitutes a deposition target on which a deposition material 915 is to be deposited, is disposed in the chamber. The substrate 400 may be a substrate for flat panel displays. A large substrate, such as a mother glass, for manufacturing a plurality of flat panel displays, may be used as the substrate 400. Other substrates may also be employed.
In the current embodiment of the present invention, deposition may be performed while the substrate 400 and the thin film deposition assembly 900 are moved relative to each other.
In particular, in the conventional FMM deposition method, the size of the FMM has to be equal to the size of a substrate. Thus, the size of the FMM has to be increased when performing deposition on a larger substrate. However, it is difficult to manufacture a large FMM and to extend an FMM to be accurately aligned with a pattern.
In order to overcome this problem, in the thin film deposition assembly 900 according to the current embodiment of the present invention, deposition may be performed while the thin film deposition assembly 900 and the substrate 400 are moved relative to each other. In other words, deposition may be continuously performed while the substrate 400, which is disposed such as to face the thin film deposition assembly 900, is moved in a Y-axis direction. In other words, deposition is performed in a scanning manner while the substrate 400 is moved in a direction of an arrow A in
Thus, in the thin film deposition assembly 900 according to the current embodiment of the present invention, the patterning slit sheet 950 may be significantly smaller than an FMM used in a conventional deposition method. In other words, in the thin film deposition assembly 900 according to the current embodiment of the present invention, deposition is continuously performed, i.e., in a scanning manner while the substrate 400 is moved in the Y-axis direction. Thus, lengths of the patterning slit sheet 950 in the X-axis and Y-axis directions may be significantly less than the lengths of the substrate 400 in the X-axis and Y-axis directions. As described above, since the patterning slit sheet 950 may be formed to be significantly smaller than an FMM used in a conventional deposition method, it is relatively easy to manufacture the patterning slit sheet 950 used in an embodiment of the present invention. In other words, using the patterning slit sheet 950, which is smaller than an FMM used in a conventional deposition method, is more convenient in all processes, including etching and subsequent other processes, such as precise extension, welding, moving, and cleaning processes, compared to the conventional deposition method using the larger FMM. This is more advantageous for a relatively large display device.
In order to perform deposition while the thin film deposition assembly 900 or the substrate 400 is moved relative to each other as described above, the thin film deposition assembly 900 and the substrate 400 may be separated from each other by a predetermined distance. This will be described later in detail.
The deposition source 910 that contains and heats the deposition material 915 is disposed in an opposite side of the chamber to that in which the substrate 400 is disposed. As the deposition material 915 contained in the deposition source 910 is vaporized, the deposition material 915 is deposited on the substrate 400.
In particular, the deposition source 910 includes a crucible 911 that is filled with the deposition material 915, and a heater 912 that heats the crucible 911 to vaporize the deposition material 915, which is contained in the crucible 911, towards a side of the crucible 911, and in particular, towards the deposition source nozzle unit 920.
The deposition source nozzle unit 920 is disposed at a side of the deposition source 910, and in particular, at the side of the deposition source 910 facing the substrate 400. The deposition source nozzle unit 920 includes a plurality of deposition source nozzles 921 arranged at equal intervals in the Y-axis direction, i.e., the scanning direction of the substrate 400. The deposition material 915 that is vaporized in the deposition source 910, passes through the deposition source nozzle unit 920 towards the substrate 400. As described above, when the plurality of deposition source nozzles 921 are formed on the deposition source nozzle unit 920 in the Y-axis direction, that is, the scanning direction of the substrate 400, a size of the pattern formed by the deposition material 915 that is discharged through each of patterning slits 951 in the patterning slit sheet 950 is only affected by the size of one deposition source nozzle 921, that is, it may be considered that one deposition nozzle 921 exists in the X-axis direction, and thus there is no shadow zone on the substrate. In addition, since the plurality of deposition source nozzles 921 are formed in the scanning direction of the substrate 400, even there is a difference between fluxes of the deposition source nozzles 921, the difference may be compensated and deposition uniformity may be maintained constantly.
The patterning slit sheet 950 and a frame 955 in which the patterning slit sheet 950 is bound are disposed between the deposition source 910 and the substrate 400. The frame 955 may be formed in a lattice shape, similar to a window frame. The patterning slit sheet 950 is bound inside the frame 955. The patterning slit sheet 950 includes a plurality of patterning slits 951 arranged in the X-axis direction. The deposition material 915 that is vaporized in the deposition source 910, passes through the deposition source nozzle unit 920 and the patterning slit sheet 950 towards the substrate 400. The patterning slit sheet 950 may be manufactured by etching, which is the same method as used in a conventional method of manufacturing an FMM, and in particular, a striped FMM. Here, the total number of patterning slits 951 may be greater than the total number of deposition source nozzles 921.
The deposition source 910 (and the deposition source nozzle unit 920 coupled to the deposition source 910) and the patterning slit sheet 950 may be formed to be separated from each other by a predetermined distance. Alternatively, the deposition source 910 (and the deposition source nozzle unit 920 coupled to the deposition source 910) and the patterning slit sheet 950 may be connected to each other by a connection member 935. That is, the deposition source 910, the deposition source nozzle unit 920, and the patterning slit sheet 950 may be formed integrally with each other by being connected to each other via the connection member 935. The connection member 935 guides the deposition material 915, which is discharged through the deposition source nozzles 921, to move straight, not to flow in the X-axis direction. In
As described above, the thin film deposition apparatus 900 according to the current embodiment of the present invention performs deposition while being moved relative to the substrate 400. In order to move the thin film deposition apparatus 900 relative to the substrate 400, the patterning slit sheet 950 is separated from the substrate 400 by a predetermined distance.
In particular, in a conventional deposition method using an FMM, deposition is performed with the FMM in close contact with a substrate in order to prevent formation of a shadow zone on the substrate. However, when the FMM is used in close contact with the substrate, the contact may cause defects. In addition, in the conventional deposition method, the size of the mask has to be the same as the size of the substrate since the mask cannot be moved relative to the substrate. Thus, the size of the mask has to be increased as display devices become larger. However, it is not easy to manufacture such a large mask.
In order to overcome this and/or other problems, in the thin film deposition apparatus 900 according to the current embodiment of the present invention, the patterning slit sheet 950 is disposed to be separated from the substrate 400 by a predetermined distance.
As described above, according to the aspects of the present invention, a mask is formed to be smaller than a substrate, and deposition is performed while the mask is moved relative to the substrate. Thus, the mask can be easily manufactured. In addition, defects caused due to the contact between a substrate and an FMM, which occurs in the conventional deposition method, may be prevented. In addition, since it is unnecessary to use the FMM in close contact with the substrate during a deposition process, the manufacturing speed may be improved.
In this regard, in the thin film deposition apparatus 900 according to the current embodiment of the present invention, the first and second blocking members 961 and 962 are disposed to move along with the substrate 400 and screen the first and second non-deposition regions 401 and 402 of the substrate 400 so that a deposition material 915 is prevented from being deposited on the first and second non-deposition regions 401 and 402 of the substrate 400. Since this has been described with reference to the previous embodiment, the description thereof will not be repeated herein.
In the current embodiment of the present invention, the plurality of deposition source nozzles 921 formed on the deposition source nozzle unit 920 are tilted at a predetermined angle. In particular, the deposition source nozzles 921 may include deposition source nozzles 921a and 921b which are arranged in two rows, which are alternately arranged with each other. Here, the deposition source nozzles 921a and 921b may be tilted at a predetermined angle on an X-Z plane.
Therefore, in the current embodiment of the present invention, the deposition source nozzles 921a and 921b are arranged in tilted states at a predetermined angle. Here, the deposition source nozzles 921a in a first row may be tilted at the predetermined angle toward the deposition nozzles 921b in a second row, and the deposition source nozzles 921b in the second row may be tilted at the predetermined angle toward the deposition source nozzles 921a in the first row. That is, the deposition source nozzles 921a arranged in the row at the left side of the patterning slit sheet 950 are arranged to face the right side of the patterning slit sheet 950, and the deposition source nozzles 921b arranged in the row at the right side of the patterning slit sheet 950 are arranged to face the left side of the patterning slit sheet 950.
Therefore, the deposition amount of the deposition material may be adjusted so that a thickness difference between the center portion and end portions of the deposition film formed on the substrate may be reduced and the entire thickness of the deposition film may be constant, and moreover, the efficiency of utilizing the deposition material may be improved.
In this regard, in the thin film deposition apparatus 900 according to the current embodiment of the present invention, the first and second blocking members 961 and 962 are disposed to move along with the substrate 400 and screen the first and second non-deposition regions 401 and 402 of the substrate 400 so that an deposition material 915 is prevented from being deposited on the first and second non-deposition regions 401 and 402 of the substrate 400. Since this has been described with reference to the previous embodiment, the description thereof will not be repeated herein.
As described above, the thin film deposition apparatus according to the aspects of the present invention may be easily manufactured and may be simply applied to produce large substrates on a mass scale. The thin film deposition apparatus may improve manufacturing yield and deposition efficiency and may allow deposition materials to be reused.
Although a few embodiments of the present invention have been shown and described, it would be appreciated by those skilled in the art that changes may be made in this embodiment without departing from the principles and spirit of the invention, the scope of which is defined in the claims and their equivalents.
Number | Date | Country | Kind |
---|---|---|---|
10-2009-0081979 | Sep 2009 | KR | national |
10-2010-0014276 | Feb 2010 | KR | national |
Number | Name | Date | Kind |
---|---|---|---|
4687939 | Miyauchi et al. | Aug 1987 | A |
4901667 | Suzuki et al. | Feb 1990 | A |
6045671 | Wu et al. | Apr 2000 | A |
6091195 | Forrest et al. | Jul 2000 | A |
6274198 | Dautartas | Aug 2001 | B1 |
6280821 | Kadunce et al. | Aug 2001 | B1 |
6371451 | Choi | Apr 2002 | B1 |
6579422 | Kakinuma | Jun 2003 | B1 |
6749906 | Van Slyke | Jun 2004 | B2 |
6878209 | Himeshima et al. | Apr 2005 | B2 |
6946783 | Kim | Sep 2005 | B2 |
7006202 | Byun et al. | Feb 2006 | B2 |
8188476 | Takagi et al. | May 2012 | B2 |
8193011 | Kang et al. | Jun 2012 | B2 |
20010006827 | Yamazaki et al. | Jul 2001 | A1 |
20010019807 | Yamada et al. | Sep 2001 | A1 |
20010026638 | Sangu et al. | Oct 2001 | A1 |
20020017245 | Tsubaki et al. | Feb 2002 | A1 |
20020076847 | Yamada et al. | Jun 2002 | A1 |
20020168577 | Yoon | Nov 2002 | A1 |
20030101932 | Kang | Jun 2003 | A1 |
20030101937 | Van Slyke et al. | Jun 2003 | A1 |
20030118950 | Chao et al. | Jun 2003 | A1 |
20030168013 | Freeman et al. | Sep 2003 | A1 |
20030221614 | Kang et al. | Dec 2003 | A1 |
20030221620 | Yamazaki | Dec 2003 | A1 |
20030232563 | Kamiyama et al. | Dec 2003 | A1 |
20040029028 | Shimizu | Feb 2004 | A1 |
20040056244 | Marcus et al. | Mar 2004 | A1 |
20040086639 | Grantham et al. | May 2004 | A1 |
20040115338 | Yoneda | Jun 2004 | A1 |
20040115342 | Shigemura | Jun 2004 | A1 |
20040127066 | Jung | Jul 2004 | A1 |
20040134428 | Sasaki et al. | Jul 2004 | A1 |
20040142108 | Atobe et al. | Jul 2004 | A1 |
20040144321 | Grace et al. | Jul 2004 | A1 |
20040183435 | Ohshita | Sep 2004 | A1 |
20040194702 | Sasaki et al. | Oct 2004 | A1 |
20040195530 | Kwak et al. | Oct 2004 | A1 |
20040216673 | Sakata et al. | Nov 2004 | A1 |
20050016461 | Klug et al. | Jan 2005 | A1 |
20050031836 | Hirai | Feb 2005 | A1 |
20050037136 | Yamamoto | Feb 2005 | A1 |
20050072361 | Yang et al. | Apr 2005 | A1 |
20050110400 | Nakamura | May 2005 | A1 |
20050129489 | Quan et al. | Jun 2005 | A1 |
20050153472 | Yotsuya | Jul 2005 | A1 |
20050166842 | Sakamoto | Aug 2005 | A1 |
20050229848 | Shinriki et al. | Oct 2005 | A1 |
20050263074 | Masuda et al. | Dec 2005 | A1 |
20060011136 | Yamazaki et al. | Jan 2006 | A1 |
20060022590 | Aziz et al. | Feb 2006 | A1 |
20060090705 | Kim | May 2006 | A1 |
20060110544 | Kim et al. | May 2006 | A1 |
20060113907 | Im et al. | Jun 2006 | A1 |
20060144325 | Jung et al. | Jul 2006 | A1 |
20060174829 | An et al. | Aug 2006 | A1 |
20060205101 | Lee et al. | Sep 2006 | A1 |
20060272572 | Uematsu et al. | Dec 2006 | A1 |
20070022955 | Bender et al. | Feb 2007 | A1 |
20070054044 | Shimosaki et al. | Mar 2007 | A1 |
20070077358 | Jeong et al. | Apr 2007 | A1 |
20070148337 | Nichols et al. | Jun 2007 | A1 |
20070157879 | Yotsuya | Jul 2007 | A1 |
20070163497 | Grace et al. | Jul 2007 | A1 |
20070178708 | Ukigaya | Aug 2007 | A1 |
20070231460 | Ukigaya | Oct 2007 | A1 |
20080018236 | Arai et al. | Jan 2008 | A1 |
20080100201 | Wei et al. | May 2008 | A1 |
20080115729 | Oda et al. | May 2008 | A1 |
20080129194 | Abe et al. | Jun 2008 | A1 |
20080131587 | Boroson et al. | Jun 2008 | A1 |
20080145521 | Guo et al. | Jun 2008 | A1 |
20080174235 | Kim et al. | Jul 2008 | A1 |
20080216741 | Ling et al. | Sep 2008 | A1 |
20080238294 | Xu et al. | Oct 2008 | A1 |
20090017192 | Matsuura | Jan 2009 | A1 |
20090208754 | Chu et al. | Aug 2009 | A1 |
20090220691 | Kim | Sep 2009 | A1 |
20090229524 | Kim et al. | Sep 2009 | A1 |
20090232976 | Yoon et al. | Sep 2009 | A1 |
20090277386 | Takagi et al. | Nov 2009 | A1 |
20100001301 | Karg et al. | Jan 2010 | A1 |
20100055810 | Sung et al. | Mar 2010 | A1 |
20100192856 | Sung et al. | Aug 2010 | A1 |
20100196607 | Carlson et al. | Aug 2010 | A1 |
20100271602 | Hanazaki | Oct 2010 | A1 |
20100297349 | Lee et al. | Nov 2010 | A1 |
20110220019 | Lee et al. | Sep 2011 | A1 |
20120009328 | Ryu et al. | Jan 2012 | A1 |
20120145077 | Chang et al. | Jun 2012 | A1 |
Number | Date | Country |
---|---|---|
1 413 644 | Apr 2004 | EP |
1 418 250 | May 2004 | EP |
1 518 940 | Mar 2005 | EP |
57-194252 | Nov 1982 | JP |
4-272170 | Sep 1992 | JP |
05-230628 | Sep 1993 | JP |
08-027568 | Jan 1996 | JP |
09-095776 | Apr 1997 | JP |
2000-68054 | Mar 2000 | JP |
2001-52862 | Feb 2001 | JP |
2001-93667 | Apr 2001 | JP |
2002-075638 | Mar 2002 | JP |
2002-175878 | Jun 2002 | JP |
2003-3250 | Jan 2003 | JP |
2003-77662 | Mar 2003 | JP |
2003-157973 | May 2003 | JP |
2003-297562 | Oct 2003 | JP |
2003-197531 | Nov 2003 | JP |
2003-321767 | Nov 2003 | JP |
2004-035964 | Feb 2004 | JP |
2004-43898 | Feb 2004 | JP |
2004-076150 | Mar 2004 | JP |
2004-103269 | Apr 2004 | JP |
2004-103341 | Apr 2004 | JP |
2004-137583 | May 2004 | JP |
2004-169169 | Jun 2004 | JP |
2004-199919 | Jul 2004 | JP |
2004-349101 | Dec 2004 | JP |
2005-44592 | Feb 2005 | JP |
2005-122980 | May 2005 | JP |
2005-165015 | Jun 2005 | JP |
2005-174843 | Jun 2005 | JP |
2005-206939 | Aug 2005 | JP |
2005-235568 | Sep 2005 | JP |
2005-293968 | Oct 2005 | JP |
2005-296737 | Oct 2005 | JP |
2006-028583 | Feb 2006 | JP |
2006-172930 | Jun 2006 | JP |
2006-176809 | Jul 2006 | JP |
2006-210038 | Aug 2006 | JP |
2006-275433 | Oct 2006 | JP |
2006-292955 | Oct 2006 | JP |
2007-47293 | Feb 2007 | JP |
2007-186740 | Jul 2007 | JP |
2007-291506 | Nov 2007 | JP |
2008-108628 | May 2008 | JP |
2008-121098 | May 2008 | JP |
2008-521165 | Jun 2008 | JP |
2009-19243 | Jan 2009 | JP |
2009-024208 | Feb 2009 | JP |
2009-081165 | Apr 2009 | JP |
2009-87910 | Apr 2009 | JP |
2010-261081 | Nov 2010 | JP |
10-0257219 | Feb 2000 | KR |
10-2000-0019254 | Apr 2000 | KR |
10-2000-0023929 | May 2000 | KR |
10-2001-0024652 | Mar 2001 | KR |
10-2001-0059939 | Jul 2001 | KR |
10-2001-0092914 | Oct 2001 | KR |
10-2001-0093666 | Oct 2001 | KR |
20-0257218 | Dec 2001 | KR |
10-2002-0000201 | Jan 2002 | KR |
10-2002-0001555 | Jan 2002 | KR |
10-2002-0050922 | Jun 2002 | KR |
10-2002-0090934 | Dec 2002 | KR |
10-2003-0001745 | Jan 2003 | KR |
10-2003-0034730 | May 2003 | KR |
10-2003-0046090 | Jun 2003 | KR |
2003-0069684 | Aug 2003 | KR |
10-0405080 | Oct 2003 | KR |
10-2003-0091947 | Dec 2003 | KR |
10-2003-0093959 | Dec 2003 | KR |
2003-0094033 | Dec 2003 | KR |
10-2004-0014258 | Feb 2004 | KR |
10-2004-0034537 | Apr 2004 | KR |
10-2004-0050045 | Jun 2004 | KR |
10-2004-0069281 | Aug 2004 | KR |
10-2004-0084747 | Oct 2004 | KR |
10-2004-0087142 | Oct 2004 | KR |
10-0463212 | Dec 2004 | KR |
10-2005-0062853 | Jun 2005 | KR |
10-0520159 | Sep 2005 | KR |
10-2006-0008602 | Jan 2006 | KR |
10-2006-0018745 | Mar 2006 | KR |
10-2006-0020050 | Mar 2006 | KR |
10-2006-0049050 | May 2006 | KR |
10-2006-0056706 | May 2006 | KR |
10-2006-0058459 | May 2006 | KR |
10-2006-0059068 | Jun 2006 | KR |
10-2006-0065978 | Jun 2006 | KR |
10-2006-0073367 | Jun 2006 | KR |
10-2006-0080475 | Jul 2006 | KR |
10-2006-0080481 | Jul 2006 | KR |
10-2006-0080482 | Jul 2006 | KR |
10-2006-0083510 | Jul 2006 | KR |
10-2006-0092387 | Aug 2006 | KR |
10-2006-0098755 | Sep 2006 | KR |
10-2006-0104288 | Oct 2006 | KR |
10-2006-0104675 | Oct 2006 | KR |
10-2006-0104677 | Oct 2006 | KR |
10-2006-0109627 | Oct 2006 | KR |
10-0635903 | Oct 2006 | KR |
10-2006-0114462 | Nov 2006 | KR |
10-0645719 | Nov 2006 | KR |
10-0646160 | Nov 2006 | KR |
10-2006-0123944 | Dec 2006 | KR |
10-0687007 | Feb 2007 | KR |
10-2007-0025164 | Mar 2007 | KR |
10-0696547 | Mar 2007 | KR |
10-0696550 | Mar 2007 | KR |
10-0697663 | Mar 2007 | KR |
10-0698033 | Mar 2007 | KR |
10-0700466 | Mar 2007 | KR |
10-2007-0035796 | Apr 2007 | KR |
10-0711885 | Apr 2007 | KR |
10-2007-0050793 | May 2007 | KR |
10-0723627 | May 2007 | KR |
10-0726132 | Jun 2007 | KR |
10-0739309 | Jul 2007 | KR |
10-2007-0078713 | Aug 2007 | KR |
10-2007-0080635 | Aug 2007 | KR |
10-2007-0101842 | Oct 2007 | KR |
10-2007-0105595 | Oct 2007 | KR |
10-0768212 | Oct 2007 | KR |
10-0770653 | Oct 2007 | KR |
10-2007-0112668 | Nov 2007 | KR |
10-0787457 | Dec 2007 | KR |
10-2008-0001184 | Jan 2008 | KR |
10-2008-0003720 | Jan 2008 | KR |
10-0797787 | Jan 2008 | KR |
10-0800125 | Jan 2008 | KR |
10-0815265 | Mar 2008 | KR |
10-2008-0036983 | Apr 2008 | KR |
10-0823508 | Apr 2008 | KR |
10-0827760 | Apr 2008 | KR |
10-2008-0044775 | May 2008 | KR |
10-2008-0048653 | Jun 2008 | KR |
10-2008-0055124 | Jun 2008 | KR |
10-0839380 | Jun 2008 | KR |
10-2008-0060400 | Jul 2008 | KR |
10-2008-0061132 | Jul 2008 | KR |
10-2008-0061666 | Jul 2008 | KR |
10-2008-0061774 | Jul 2008 | KR |
10-2008-0062212 | Jul 2008 | KR |
10-2008-0109559 | Dec 2008 | KR |
10-2009-0038733 | Apr 2009 | KR |
10-2009-0040618 | Apr 2009 | KR |
10-2009-0052155 | May 2009 | KR |
10-2009-0053417 | May 2009 | KR |
10-2009-0066996 | Jun 2009 | KR |
10-0908232 | Jul 2009 | KR |
10-2009-0093161 | Sep 2009 | KR |
10-2009-0097453 | Sep 2009 | KR |
10-2010-0000128 | Jan 2010 | KR |
10-2010-0000129 | Jan 2010 | KR |
10-2010-0026655 | Mar 2010 | KR |
10-2010-0047796 | May 2010 | KR |
10-2010-0090070 | Aug 2010 | KR |
10-2010-0099806 | Sep 2010 | KR |
10-2010-0126125 | Dec 2010 | KR |
10-2011-0101767 | Sep 2011 | KR |
10-2012-0006324 | Jan 2012 | KR |
10-2012-0065789 | Jun 2012 | KR |
WO 9925894 | May 1999 | WO |
WO 2008004792 | Jan 2008 | WO |
Entry |
---|
Patent Abstracts of Japan and English machine translation of Japanese Publication 2004-349101 listed above, (11 pages). |
Patent Abstracts of Japan, and English machine translation of Japanese Publication 2009-024208 listed above, (30 pages). |
KIPO Office action dated Aug. 1, 2011 for Korean Patent application 10-2009-0074001, (3 pages). |
KIPO Office action dated Feb. 1, 2012 for Korean Patent application 10-2010-0014272, (4 pages). |
KIPO Office action dated Feb. 6, 2012 for Korean Patent application 10-2010-0021835, (4 pages). |
KIPO Office action dated Apr. 2, 2012 for Korean Patent application 10-2010-0066993, (4 pages). |
KIPO Notice of Allowance dated Aug. 24, 2012 for Korean Patent application 10-2010-0066993, (5 pages). |
KIPO Notice of Allowance dated Sep. 28, 2011 for Korean Patent application 10-2009-0052357, (5 pages). |
KIPO Notice of Allowance dated Nov. 25, 2011 for Korean Patent application 10-2010-0014277, (5 pages). |
KIPO Office action dated Feb. 1, 2012 for Korean Patent application 10-2010-0011196, (4 pages). |
KIPO Office action dated Feb. 1, 2012 for Korean Patent application 10-2010-0013848, (4 pages). |
KIPO Office action dated Jan. 13, 2012 for Korean Patent application 10-2009-0056529, (5 pages). |
KIPO Notice of Allowance dated Jul. 20, 2012 for Korean Patent application 10-2010-0003545, (5 pages). |
KIPO Notice of Allowance dated Apr. 30, 2012 for Korean Patent application 10-2010-0066992, (5 pages). |
Japanese Office action dated Aug. 21, 2012 for Japanese Patent application 2010-145075, (5 pages). |
KIPO Office action dated Sep. 1, 2012 for Korean Patent application 10-2010-0010136, (5 pages). |
KIPO Notice of Allowance dated Sep. 1, 2012 for Korean Patent application 10-2010-0014276, (5 pages). |
KIPO Office action dated Aug. 28, 2012 for Korean Patent application 10-2010-0014274, (5 pages). |
KIPO Notice of Allowance dated Sep. 1, 2012 for Korean Patent application 10-2010-0013848, (5 pages). |
KIPO Notice of Allowance dated Sep. 1, 2012 for Korean Patent application 10-2010-0009160, (5 pages). |
Japanese Office action dated Sep. 4, 2012 for Japanese Patent application 2010-152846, (4 pages). |
U.S. Office action dated Sep. 12, 2012 for cross reference U.S. Appl. No. 12/815,673, (26 pages). |
U.S. Office action dated Dec. 17, 2012 for cross reference U.S. Appl. No. 12/873,556, (37 pages). |
U.S. Office action dated Dec. 20, 2012 for cross reference U.S. Appl. No. 12/984,289, ( 20 pages). |
KIPO Office action dated Feb. 6, 2012, for Korean Patent application 10-2010-0014274, 9 pages. |
U.S. Appl. No. 12/873,556, filed Sep. 1, 2010, Young-Mook Choi, et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/784,774, filed May 21, 2010, Choong-Ho Lee, et al., Samsung Mobile Display Co., Ltd. |
KIPO Office action dated Aug. 1, 2011, for Korean Patent application 10-2009-0073523, 3 pages. |
U.S. Appl. No. 13/031,756, filed Feb. 22, 2011, Yong Sup Choi et al., Samsung Mobile Display Co., Ltd. |
English-language abstract of Korean Publication No. KR 10-2002-0034272. |
English-language abstract of Korean Publication No. KR 10-2002-0056238. |
English-language abstract of Korean Publication No. KR 10-2002-0088662. |
English-language abstract of Korean Publication No. KR 10-2005-0045619. |
English-language abstract of Korean Publication No. KR 10-2006-0126267. |
English-language abstract of Korean Publication No. KR 10-2008-0038650. |
U.S. Appl. No. 12/784,774, filed May 21, 2010, Choong-Ho Lee et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 13/014,225, filed Jan. 26, 2011, Jong-Won Hong et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/797,858, filed Jun. 10, 2010, Choong-Ho Lee et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/836,760, filed Jul. 15, 2010, Jong-Heon Kim, et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/784,804, filed May 21, 2010, Choong-Ho Lee, et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/849,193, filed Aug. 3, 2010, Ji-Gook Oh et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/979,193, filed Dec. 28, 2010, Hyun Sook Park et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/820,355, filed Jun. 22, 2010, Yong-Sup Choi et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/950,361, filed Nov. 19, 2010, Choong-Ho Lee, et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/795,896, filed Jun. 8, 2010, Jung-Min Lee, et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/856,942, filed Aug. 16, 2010, Yun-Mi Lee et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/814,816, filed Jun. 14, 2010, Jung-Min Lee et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/868,099, filed Aug. 25, 2010, Hee-Cheol Kang, et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/862,153, filed Aug. 24, 2010, Hee-Cheol Kang, et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/869,830, filed Aug. 27, 2010, Chang-Mog Jo, et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/849,092, filed Aug. 3, 2010, Choong-Ho Lee et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/815,673, filed Jun. 15, 2010, Jung-Min Lee, Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/794,093, filed Jun. 4, 2010, Jung-Min Lee et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/862,125, filed Aug. 24, 2010, Jae-Kwang Ryu et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/795,001, filed Jun. 7, 2010, Choong-Ho Lee et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/813,786, filed Jun. 11, 2010, Choong-Ho Lee et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/820,270, filed Jun. 22, 2010, Jung-Min Lee et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/907,396, filed Oct. 19, 2010, Yong-Sup Choi, et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/987,569, filed Jan. 10, 2011, Yun-Mi Lee et al., Samsung Mobile Display Co., Ltd. |
U.S. Appl. No. 12/984,289, filed Jan. 4, 2011, Jung-Yeong Kim et al., Samsung Mobile Display Co., Ltd. |
KIPO Registration Determination Certificate dated Oct. 31, 2011, for Korean priority Patent application 10-2010-0014273, corresponding to cross reference U.S. Appl. No. 12/849,092, 5 pages. |
Korean Patent Abstracts for Korean Publication 10-2007-0097218 dated Oct. 4, 2007, corresponding to Korean Patent 10-0768212 dated Oct. 18, 2007 listed above. |
U.S. Office action dated Dec. 26, 2012, for cross reference U.S. Appl. No. 12/815,673, (21 pages). |
U.S. Office action dated Jan. 25, 2013, for cross reference U.S. Appl. No. 13/015,357, (21 pages). |
U.S. Office action dated May 24, 2013, for cross reference U.S. Appl. No. 12/849,092, (31 pages). |
U.S. Office action dated Jul. 5, 2013, for cross reference U.S. Appl. No. 12/873,556, (17 pages). |
U.S. Office action dated Aug. 7, 2013, for cross reference U.S. Appl. No. 13/015,357, (30 pages). |
U.S. Office action dated Feb. 26, 2013, for cross reference U.S. Appl. No. 12/794,093, (31 pages). |
U.S. Office action dated Apr. 1, 2013, for cross reference U.S. Appl. No. 12/784,774, (44 pages). |
U.S. Notice of Allowance dated Mar. 18, 2013, for cross reference U.S. Appl. No. 12/795,001, (29 pages). |
U.S. Office action dated Mar. 18, 2013, for cross reference U.S. Appl. No. 12/984,231, (29 pages). |
U.S. Office action dated Mar. 22, 2013, for cross reference U.S. Appl. No. 12/987,569, (12 pages). |
U.S. Office action dated Mar. 15, 2013, for cross reference U.S. Appl. No. 12/813,786, (33 pages). |
U.S. Office action dated Mar. 19, 2013, for cross reference U.S. Appl. No. 13/194,759, (36 pages). |
U.S. Office action dated May 7, 2013, for cross reference U.S. Appl. No. 12/820,270, (37 pages). |
U.S. Office action dated Jun. 11, 2013 for cross reference U.S. Appl. No. 12/862,125, (37 pages). |
U.S. Office action dated Jun. 26, 2013 for cross reference U.S. Appl. No. 12/794,093, (20 pages). |
U.S. Office action dated Aug. 13, 2013 for cross reference U.S. Appl. No. 13/194,759, (28 pages). |
U.S. Office action dated Jul. 17, 2013, for cross reference U.S. Appl. No. 12/984,231, (18 pages). |
Number | Date | Country | |
---|---|---|---|
20110048320 A1 | Mar 2011 | US |