Thin film metal oxide bearing semiconductor material for single junction solar cell devices

Abstract

A structure for a single junction solar cell. The structure includes a substrate member having a surface region. The structure includes a first electrode structure overlying the surface region of the substrate member. A P absorber layer is formed overlying the first electrode structure. In a specific embodiment, the P absorber layer has a P− type impurity characteristics and a first optical absorption coefficient greater than 104 cm−1 in a wavelength range comprising 400 nm to 800 nm. An N+ layer is provided overlying the P absorber layer and an interface region formed within a vicinity of the P layer and the N+ layer. The structure also includes a high resistivity buffer layer overlying the N+ layer and a second electrode structure overlying the buffer layer.

Description

CROSS-REFERENCES TO RELATED APPLICATIONS

This application claims priority to provisional patent application Ser. No. 60/976,391; filed on Sep. 28, 2007; commonly assigned, and of which is hereby incorporated by reference for all purposes.

STATEMENT AS TO RIGHTS TO INVENTIONS MADE UNDER FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT

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REFERENCE TO A “SEQUENCE LISTING,” A TABLE, OR A COMPUTER PROGRAM LISTING APPENDIX SUBMITTED ON A COMPACT DISK

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BACKGROUND OF THE INVENTION

The present invention relates generally to photovoltaic materials. More particularly, the present invention provides a method and structure for manufacture of photovoltaic materials using a thin film process including Group IV materials (e.g., silicon, germanium) and metal oxides, such as copper oxide and the like. Merely by way of example, the present method and structure have been implemented using a single junction configuration, but it would be recognized that the invention may have other configurations.

From the beginning of time, human beings have been challenged to find way of harnessing energy. Energy comes in the forms such as petrochemical, hydroelectric, nuclear, wind, biomass, solar, and more primitive forms such as wood and coal. Over the past century, modern civilization has relied upon petrochemical energy as an important source. Petrochemical energy includes gas and oil. Gas includes lighter forms such as butane and propane, commonly used to heat homes and serve as fuel for cooking. Gas also includes gasoline, diesel, and jet fuel, commonly used for transportation purposes. Heavier forms of petrochemicals can also be used to heat homes in some places. Unfortunately, petrochemical energy is limited and essentially fixed based upon the amount available on the planet Earth. Additionally, as more human beings begin to drive and use petrochemicals, it is becoming a rather scarce resource, which will eventually run out over time.

More recently, clean sources of energy have been desired. An example of a clean source of energy is hydroelectric power. Hydroelectric power is derived from electric generators driven by the force of water that has been held back by large dams such as the Hoover Dam in Nevada. The electric power generated is used to power up a large portion of Los Angeles Calif. Other types of clean energy include solar energy. Specific details of solar energy can be found throughout the present background and more particularly below.

Solar energy generally converts electromagnetic radiation from our sun to other useful forms of energy. These other forms of energy include thermal energy and electrical power. For electrical power applications, solar cells are often used. Although solar energy is clean and has been successful to a point, there are still many limitations before it becomes widely used throughout the world. As an example, one type of solar cell uses crystalline materials, which form from semiconductor material ingots. These crystalline materials include photo-diode devices that convert electromagnetic radiation into electrical current. Crystalline materials are often costly and difficult to make on a wide scale. Additionally, devices made from such crystalline materials have low energy conversion efficiencies. Other types of solar cells use “thin film” technology to form a thin film of photosensitive material to be used to convert electromagnetic radiation into electrical current. Similar limitations exist with the use of thin film technology in making solar cells. That is, efficiencies are often poor. Additionally, film reliability is often poor and cannot be used for extensive periods of time in conventional environmental applications. These and other limitations of these conventional technologies can be found throughout the present specification and more particularly below.

From the above, it is seen that improved techniques for manufacturing photovoltaic materials and resulting devices are desired.

BRIEF SUMMARY OF THE INVENTION

According to the present invention, techniques including a structure and method for a single junction solar cell are provided. More particularly, embodiments according to the present invention provide a structure for a single junction solar cell using thin film metal oxide semiconductor material. But it should be recognized that the present invention has a broader range of applicability.

In a specific embodiment, a structure for a single junction solar cell is provided. The structure includes a substrate member having a surface region. The structure includes a first conductor layer overlying the surface region of the substrate member. The structure includes a P absorber layer overlying the conductor layer. In a specific embodiment, the P absorber layer has a P⁻ type impurity characteristics and a first optical absorption coefficient greater than 10⁴ cm⁻¹ in a wavelength range comprising 400 nm to 800 nm. The P absorber layer comprises a metal oxide semiconductor material in a specific embodiment. The structure also includes a N⁺ layer overlying the first absorber layer. The N⁺ layer is characterized by an N type impurity characteristics. The structure also include an interface region formed from the first absorber layer and the N⁺ layer. A buffer layer having a suitable resistance is provided overlying the N⁺ layer. The structure also includes a second conductor layer overlying the buffer layer.

In an alternative embodiment, a method for forming a single junction solar cell is provided. The method includes providing a substrate member having a surface region. A first conductor layer is formed overlying the surface region of the substrate member and a P absorber layer is formed overlying the conductor layer. In a specific embodiment, the P absorber layer has a P⁻ type impurity characteristics and a first optical absorption coefficient greater than 10⁴ cm⁻¹ in a wavelength range comprising 400 nm to 800 nm. The method forms a N⁺ layer overlying the P absorber layer and an interface region is formed from the P absorber layer and the N⁺ layer in a specific embodiment. The method includes forming a high resistivity buffer layer overlying the N⁺ layer and forming a second conductor layer overlying the buffer layer.

Depending on the embodiment, one or more of these features may be included. Embodiments according to the present invention provide a single junction solar cell structure using metal oxide semiconductor materials. The present structure can be provided using easy to use processes using convention equipment without further modifications. The metal oxide semiconductor materials may be nanostructured or in bulk depending on the embodiment. In a specific embodiment, the present solar cell structure provides a higher conversion efficiency in converting sunlight into electric energy. Depending on the embodiment, the conversion efficiency may be 15 percent to 20 percent or greater for the resulting single junction solar cell. Additionally, the present single junction solar cell structure can be provided using large scale manufacturing processes, which reduce cost in manufacturing of the photovoltaic devices. Depending on the embodiments, one or more of these benefits may be achieved. These benefits will be described more fully throughout the present specification, and particularly below.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a simplified diagram illustrating a single junction solar cell structure according to an embodiment of the present invention.

FIG. 2 is a simplified diagram illustrating a junction region for the single junction solar cell structure according to an embodiment of the present invention.

FIGS. 3-8 are simplified diagrams illustrating a method for fabricating the single junction solar cell using thin metal oxide semiconductor material in a specific embodiment

DETAILED DESCRIPTION OF THE INVENTION

According to embodiments of the present invention, techniques directed to photovoltaic cell structure are provided. More particularly, embodiments according to the present invention provide a single junction photovoltaic cell structure and resulting photovoltaic cell having a high conversion efficiency. But it would be recognize that embodiments according to the present invention have a much broader range of applicability.

FIG. 1 is a simplified diagram illustrating a single junction solar cell structure 100 according to an embodiment of the present invention. As shown, the single junction solar cell structure includes a substrate member 102 having a surface region. The substrate member can be made of an insulator material, a conductor material, or a semiconductor material, depending on the application. In a specific embodiment, the conductor material can be nickel, molybdenum, aluminum, or a metal alloy such as stainless steel and the likes. In a embodiment, the semiconductor material may include silicon, germanium, silicon germanium, compound semiconductor material such as III-V materials, II-VI materials, and others. In a specific embodiment, the insulator material can be a transparent material such as glass, quartz, fused silica. Alternatively, the insulator material can be a polymer material, a ceramic material, or a layer or a composite material depending on the application. The polymer material may include acrylic material, polycarbonate material, and others, depending on the embodiment. Of course, there can be other variations, modifications, and alternatives.

As shown in FIG. 1, the single junction solar cell structure includes a first conductor layer 104 overlying the surface region of the substrate member to form a first electrode structure. In a specific embodiment, the first electrode structure can be made of a suitable material or a combination of materials. The first electrode structure can be made from a transparent conductive electrode or materials that are light reflecting or light blocking depending on the embodiment. Examples of the optically transparent material can include indium tin oxide (ITO), aluminum doped zinc oxide, fluorine doped tin oxide and can be others. In a specific embodiment, the first electrode may be made from a metal material. The metal material can include gold, silver, nickel, platinum, aluminum, tungsten, molybdenum, a combination of these, or an alloy, among others. In a specific embodiment, the metal material may be deposited using techniques such as sputtering, electroplating, electrochemical deposition and others. Alternatively, the first electrode structure may be made of a carbon based material such as carbon or graphite. Yet alternatively, the first electrode structure may be made of a conductive polymer material, depending on the application. Of course there can be other variations, modifications, and alternatives.

Referring again to FIG. 1, the single junction solar cell structure includes an absorber layer 106 overlying the first electrode layer 104. In a specific embodiment, the absorber layer 106 is characterized by a P⁻ characteristics. That is, the absorber layer 106 absorbs electromagnetic radiation forming positively charged carriers within a thickness of the absorber layer 106. In a specific embodiment, the absorber layer 106 can comprise a first metal oxide semiconductor material. The first metal oxide semiconductor material may be provided in various spatial morphologies of different shapes and sizes. For example, the first metal oxide semiconductor material may be nanostructured, such as nanotubes, nanocolumns, nanocrystals, and the like. In other embodiments, the first metal oxide semiconductor material can be provided as bulk material. Of course there can be other variations, modifications, and alternatives.

In a specific embodiment, the first metal oxide semiconductor material has an optical absorption coefficient greater than about 10⁴ cm⁻¹ for electromagnetic radiation in a wavelength range of about 400 nm to about 800 nm. In an alternative embodiment, the first metal oxide semiconductor material can have an optical absorption coefficient greater than about 10⁴ cm⁻¹ for electromagnetic radiation in a wavelength range of about 450 nm to about 700 nm. Of course there can be other variations, modifications, and alternatives.

The first metal oxide semiconductor material is characterized by a carrier mobility. The carrier mobility of the first metal oxide semiconductor material can range from about 10⁻⁶ cm²/V−s to about 10⁶ cm²/V−s in a specific embodiment. In another embodiment, the carrier mobility of the first metal oxide semiconductor material can range from about 10⁻³ cm²/V−s to about 10³ cm²/V−s. In certain embodiments, the carrier mobility of the first metal oxide semiconductor material can range from about 10⁻³ cm²/V−s to about 10³ cm²/V−s. Of course there can be other variations, modifications, and alternatives.

The first metal oxide semiconductor material is characterized by a bandgap. In a specific embodiment, the first absorber layer has a bandgap of about 1.0 eV to about 2.2 eV. In an alternative embodiment, the first metal oxide semiconductor material can have a bandgap of about 1.0 eV to about 2.0 eV. In a preferred embodiment, the first metal oxide semiconductor material can have a bandgap of about 1.2 eV to about 1.8 eV. Of course there can be other variations, modifications, and alternatives depending on the application.

Referring to FIG. 1, a N⁺ layer 108 is formed overlying the absorber layer 106, which has a P⁻ characteristics. In a specific embodiment, the N⁺ layer 108 comprises a second metal oxide semiconductor material. Alternatively, the N⁺ layer 108 can comprise a metal sulfide material. Examples of the second metal oxide material can include one or more oxides of copper, zinc oxide, and the like. Examples of metal sulfide material can include zinc sulfide, iron sulfides and others. The N⁺ layer 108 may be provided in various spatial morphologies of different shapes and sizes. In a specific embodiment, the N⁺ layer 108 may comprise of suitable materials that are nanostructured, such as nanocolumn, nanotubes, nanorods, nanocrystals, and others. In an alternative embodiment, the N⁺ layer 108 may also be provided as other morphologies, such as bulk materials depending on the application. Of course there can be other variations, modifications, and alternatives.

In a specific embodiment, an interface region 120 is caused by the P absorber layer and the N⁺ layer as shown in FIG. 1. In a preferred embodiment, the interface layer 120 allows for the formation of a pn junction from the positively charged carriers and the negatively charged carriers. In a specific embodiment, the pn junction is characterized by a pn+ junction and a depletion region substantially in the absorber layer in the vicinity of the interface region. Of course there can be other variations, modifications, and alternatives.

In a specific embodiment, the single junction solar cell structure includes a buffer layer 110 overlying the second absorber layer. The buffer layer is a suitable material having desired characteristics. Of course there can be other variations, modifications, and alternatives.

Referring again to FIG. 1, a second conductor layer 112 is formed overlying the buffer layer to form a second electrode structure. In a specific embodiment, the second electrode structure can be made of a suitable material or a combination of materials. The second electrode structure can be made from a transparent conductive electrode or materials that are light reflecting or light blocking depending on the embodiment. Preferably the second electrode structure comprises an optically transparent material such as indium tin oxide (ITO), aluminum doped zinc oxide, fluorine doped tin oxide and others. In a specific embodiment, the second electrode structure may be made from a metal material. The metal material can include gold, silver, nickel, platinum, aluminum, tungsten, molybdenum, a combination of these, or an alloy, among others. In a specific embodiment, the metal material may be deposited using techniques such as sputtering, electroplating, electrochemical deposition and others. Alternatively, the second electrode structure may be made of a carbon based material such as carbon or graphite. Yet alternatively, the second electrode structure may be made of a conductive polymer material, depending on the application. Of course there can be other variations, modifications, and alternatives.

FIG. 2 is a more detailed diagram illustrating the interface region according to an embodiment of the present invention. As shown, a N⁺ layer 202 is formed overlying absorber layer 204 to form a pn junction. In a specific embodiment, the absorber layer is characterized by a P type impurity characteristic, and has optical absorption coefficient greater than about 10⁴ cm⁻¹ for electromagnetic radiation in the wavelength range of about 400 nm to 750 nm. Electron-hole pairs are generated in the absorber layer upon exposing to the electromagnetic radiation and a depletion region 206 is formed substantially in the absorber layer in a vicinity of an interface region. As merely an example, the absorber layer can be a first metal oxide semiconductor material having a bandgap of about 1.0 eV to about 2.0 eV. In a specific embodiment, the first metal oxide semiconductor material can include oxides of copper such as cupric oxide or cuprous oxide, oxides of iron such as ferrous oxide, ferric oxide, tungsten oxide and other suitable materials. The first metal oxide semiconductor material may be provided in various spatial configuration, for example, as nanostructure such as nanocolumn, nanotubes, nanorods, nanocrystals, and others. In an alternative embodiment, the first metal oxide semiconductor material may be provided as a bulk material depending on the application. Of course there can be other variations, modifications, and alternatives.

In a specific embodiment, the N⁺ layer may comprise a second metal oxide material, a metal sulfide material, a combination, or other suitable materials. In a specific embodiment, the N⁺ layer is characterized by a second bandgap ranging from 2.8 eV to 4.5 eV. Examples of the second metal oxide material may include zinc oxide or the like. The second metal oxide material may be provided in various spatial configuration, for example, as nanostructure, such as nanocolumn, nanotubes, nanocrystals, and others. The second metal oxide material may be provided as a bulk material depending on the application. Of course there can be other variations, modifications, and alternatives.

In a specific embodiment, the P layer is characterized by a first bandgap ranging from about 1.0 eV to about 2.0 eV. The N⁺ layer is characterized by a second bandgap ranging from about 2.8 eV to about 5.0 eV. In a specific embodiment, the second bandgap is greater than the first bandgap. As an example, the N⁺ layer may comprise of zinc oxide material having a bandgap of about 3.4 eV, the absorber layer can comprise of copper oxide having a bandgap of about 1.2 eV. Of course there can be other variations, modifications, and alternatives.

FIGS. 3-8 are simplified diagrams illustrating a method for fabricating a single junction solar cell using thin metal oxide semiconductor material in a specific embodiment. These diagrams are merely examples, which should not unduly limit the claims herein. One skilled in the art would recognize other variations, modifications, and alternatives. As shown in FIG. 3, a substrate member 302 is provided. The substrate member includes a surface region 304. The substrate member can be made of an insulator material, a conductor material, or a semiconductor material, depending on the application. In a specific embodiment, the conductor material can be nickel, molybdenum, aluminum, or a metal alloy such as stainless steel and the likes. In an embodiment, the semiconductor material may include silicon, germanium, silicon germanium, compound semiconductor material such as III-V materials, II-VI materials, and others. In a specific embodiment, the insulator material can be a transparent material such as glass, quartz, fused silica. Alternatively, the insulator material can be a polymer material, a ceramic material, or a layer or a composite material depending on the application. The polymer material may include acrylic material, polycarbonate material, and others, depending on the embodiment.

Referring to FIG. 4, the method includes forming a first electrode structure 402 overlying the surface region of the substrate member. In a specific embodiment, the first electrode structure can be made of a suitable material or a combination of materials. The first electrode structure can be made from a transparent conductive electrode or materials that are light reflecting or light blocking depending on the embodiment. Examples of the optically transparent conductive material can include indium tin oxide (ITO), aluminum doped zinc oxide, fluorine doped tin oxide and others. The transparent conductive material may be deposited using techniques such as sputtering, or chemical vapor deposition. In a specific embodiment, the first electrode may be made from a metal material. The metal material can include gold, silver, nickel, platinum, aluminum, tungsten, molybdenum, a combination of these, or an alloy, among others. In a specific embodiment, the metal material may be deposited using techniques such as sputtering, electroplating, electrochemical deposition and others. Alternatively, the first electrode structure may be made of a carbon based material such as carbon or graphite. Yet alternatively, the first electrode structure may be made of a conductive polymer material, depending on the application. Of course there can be other variations, modifications, and alternatives.

Referring to FIG. 5, the method includes forming an absorber layer 502 overlying the first electrode structure. The absorber layer has a P⁻ type impurity characteristics in a specific embodiment. Preferably, the absorber layer is characterized by an optical absorption coefficient greater than about 10⁴ cm⁻¹ in the wavelength ranging from about 400 nm to about 750 nm in a specific embodiment. In a specific embodiment, the absorber layer can be made of a first metal oxide semiconductor material having a bandgap ranging from about 1.0 eV to about 2.0 eV. As merely an example, the metal oxide semiconductor material can be oxides of copper (that is cupric oxide or cuprous oxide, or a combination) deposited by an electrochemical method or by chemical vapor deposition technique. Of course there can be other variations, modifications, and alternatives.

In a specific embodiment, the method includes forming a N⁺ layer 602 overlying the absorber layer, which has a P⁻ type impurity characteristics, as shown in FIG. 6. The N⁺ layer can comprise a second metal oxide semiconductor material in a specific embodiment. Alternatively, the N⁺ layer can comprise a metal sulfide material. Examples of the second metal oxide material can include one or more oxides of copper, zinc oxide, and the like. Examples of metal sulfide material can include zinc sulfide, iron sulfides and others. The N⁺ layer may be provided in various spatial morphologies of different shapes and sizes. In a specific embodiment, the N⁺ layer may comprise of suitable materials that are nanostructured, such as nanocolumn, nanotubes, nanorods, nanocrystals, and others. In an alternative embodiment, the N⁺ layer may also be provided as other morphologies, such as bulk materials depending on the application. Of course there can be other variations, modifications, and alternatives. Of course there can be other modifications, variations, and alternatives.

Referring to FIG. 7, the method for fabricating a single junction solar cell using thin metal oxide semiconductor material includes providing a buffer layer 702 overlying a surface region of the N⁺ layer. In a specific embodiment, the buffer layer comprises of a high resistivity material. Of course there can be other modifications, variations, and alternatives.

As shown in FIG. 8, the method includes forming a second conductor layer to form a second electrode structure 802 overlying the buffer layer. In a specific embodiment, the second electrode structure can be made of a suitable material or a combination of materials. The second electrode structure can be made from a transparent conductive electrode or materials that are light reflecting or light blocking depending on the embodiment. Examples of the optically transparent conductive material can include indium tin oxide (ITO), aluminum doped zinc oxide, fluorine doped tin oxide and others. The transparent conductive material may be deposited using techniques such as sputtering, or chemical vapor deposition. In a specific embodiment, the first electrode may be made from a metal material. The metal material can include gold, silver, nickel, platinum, aluminum, tungsten, molybdenum, a combination of these, or an alloy, among others. In a specific embodiment, the metal material may be deposited using techniques such as sputtering, electroplating, electrochemical deposition and others. Alternatively, the second electrode structure may be made of a carbon based material such as carbon or graphite. Yet alternatively, the second electrode structure may be made of a conductive polymer material, depending on the application. Of course there can be other variations, modifications, and alternatives.

It is also understood that the examples and embodiments described herein are for illustrative purposes only and that various modifications or changes in light thereof will be suggested to persons skilled in the art and are to be included within the spirit and purview of this application and scope of the appended claims.

Claims

1. A structure for a single junction solar cell, the structure comprising, a substrate member having a surface region, wherein the substrate comprises germanium;a first conductor layer overlying the surface region of the substrate member, the first conductor layer comprising a carbon-based material;a P absorber layer overlying the conductor layer, the P absorber layer having a P− type impurity characteristics and a first optical absorption coefficient greater than 104 cm−1 in a wavelength range comprising 400 nm to 800 nm, wherein the P absorber layer comprises a first metal oxide semiconductor material;a N+ layer overlying the P absorber layer;an interface region formed between the P absorber layer and of the N+ layer;a resistive buffer layer overlying the N+ layer; anda second conductor layer overlying the buffer layer,wherein the buffer layer is separate from the second conductor layer.

2. The structure of claim 1 wherein the P absorber layer comprises a nanostructured material.

3. The structure of claim 1 wherein the P absorber layer comprises a bulk material.

4. The structure of claim 1 wherein the P absorber layer is chosen from copper oxides (for example, CuO, Cu2O).

5. The structure of claim 4 wherein the P absorber layer has a first bandgap ranging from about 1.0 eV to about 2.0 eV.

6. The structure of claim 1 wherein the N+ layer comprises a second metal oxide material or a metal sulfide material.

7. The structure of claim 1 wherein the N+ layer has a bandgap ranging from about 2.5 eV to about 5.0 eV.

8. The structure of claim 6 wherein the second metal oxide material is provided in a nanostructured configuration.

9. The structure of claim 6 wherein the second metal oxide material is provided as a bulk material.

10. The structure of claim 6 wherein the metal sulfide material is chosen from zinc sulfide, iron sulfide, or others.

11. The structure of claim 6 wherein the metal sulfide material is provided as a nanostructured material.

12. The structure of claim 6 wherein the metal sulfide material is provided as a bulk material.

13. The structure of claim 1 wherein the interface region formed from the P absorber layer and the N+ layer comprises a pn junction.

14. The structure of claim 13 wherein the pn junction is a pn+ junction.

15. The structure of claim 1 wherein the first conductor layer comprises a transparent conducting material, for example, indium tin oxide, (ITO), aluminum doped zinc oxide, fluorine doped tin oxide and others.

16. The structure of claim 1 wherein the second conductor layer comprises a transparent conducting material, for example, indium tin oxide (ITO), aluminum doped zinc oxide, fluorine doped tin oxide and others.

17. The structure of claim 1 wherein the second conductor layer comprises a conductive polymer material or a carbon based conductor material.

18. A method for forming a single junction solar cell, the method comprising; providing a substrate member having a surface region, wherein the substrate member comprises quartz;forming a first conductor layer overlying the surface region of the substrate member;forming a P absorber layer overlying the conductor layer, the P absorber layer having a P− type impurity characteristics and a first optical absorption coefficient greater than 104 cm−1 in a wavelength range comprising 400 nm to 800 nm, wherein the P absorber layer comprises a first metal oxide semiconductor material;forming a N+ layer overlying the P absorber layer;forming an interface region between the P absorber layer and the N+ layer;forming a resistive buffer layer overlying the N+ layer; andforming a second conductor layer overlying the buffer layer, wherein the second conductor layer comprises a carbon-based material;wherein the buffer layer is separate from the second conductor layer.

19. A single junction solar cell comprising, a substrate member having a surface region, wherein the substrate member comprises fused silica;a first conductor layer overlying the surface region of the substrate member, wherein the first conductor layer comprises a conductive polymer material;an absorber layer overlying the conductor layer comprising a metal oxide semiconductor material;a nanostructured metal oxide layer overlying the absorber layer;a resistive buffer layer overlying the nanostructured metal oxide layer; anda second conductor layer overlying the buffer layer,wherein the buffer layer is separate from the second conductor layer and the nanostructured metal oxide layer.

20. The single junction solar cell of claim 19 wherein the nanostructured metal oxide layer comprises nanocolumns, nanotubes, nanorods, or nanocrystals.

21. The single junction solar cell of claim 19 wherein the second conductor layer comprises a carbon-based material.