The present invention relates to a thin film transistor and a method for production thereof. The thin film transistor is of the stacked type which is made of polycrystalline silicon. It finds use as an element to drive the liquid crystal display or organic electroluminescence (EL for short hereinafter) of active matrix type.
A display device of active matrix type is provided with thin film transistors (TFT) as driver elements. TFT's are classed into that of stacked type and that of planar structure. The former has an active layer separate from the source-drain region, and the latter has a channel section of the same semiconductor layer as the source-drain region. The TFT of stacked type offers the advantage of requiring less masks in its manufacturing process, which is mentioned in the following.
The stacked TFT of bottom gate type produced as mentioned above has the channel formed at the interface between the gate insulating film 103 and the active layer 104a. In addition, this active layer 104a may function as the electric field relaxation region if its impurity concentration is kept below 1017/cm3. (For more detail about the foregoing, refer to the Patent Document 1.)
[Patent Document 1]
Japanese Patent Laid-Open No. 2001-102584 (
[Patent Document 2]
Japanese Patent No. 275919
Among flat panel displays with TFT driver elements, the organic EL display is composed of selfluminous elements (or organic EL elements). The organic EL element has many important features, such as good color reproducibility, wide viewing angle, high-speed response, and high contrast. The organic EL elements used for the organic EL display are of the current driven type. Therefore, they should preferably be driven by pixel transistors such as polycrystalline silicon TFT's using polycrystalline silicon which are superior in current driving capability. For this reason, the above-mentioned stacked TFT has the active layer and the source/drain formed from polycrystalline silicon, so that it exhibits the high current driving capability.
The conventional process for producing TFT's of polycrystalline silicon is characterized in that the amorphous silicon film is irradiated with excimer laser for conversion into polycrystalline silicon film by melting and recrystallization. However, it suffers the disadvantage of requiring an additional step for recrystallization and resulting in TFT's varying in properties due to fluctuating laser energy.
Moreover, the conventional process employs an ion doping apparatus or an ion implantation apparatus to form the source and drain. Ion doping or ion implantation is followed by thermal annealing or lamp annealing to activate impurities. Unfortunately, these apparatus are applicable only to substrates no larger than approximately 730 by 920 mm2 (or substrates of the fourth generation). This is a primary factor that makes it difficult to realize large-sized displays.
It is an object of the present invention to provide a thin film transistor and a method for production thereof. The thin film transistor works at a higher speed owing to polycrystalline semiconductor film, permits its driving current to be increased, and exhibits uniform characteristic properties. The manufacturing method is practicable with a less number of steps and is applicable to larger substrates than before.
According to an aspect of the present invention, there is provided a method for producing a thin film transistor including:
According to another aspect of the present invention, there is provided a method for producing a thin film transistor which including:
According to still another aspect of the present invention, there is provided a thin film transistor including a gate electrode, a gate insulating film, an active layer of semiconductor thin film, and source and drain regions formed sequentially, in ascending or descending order mentioned, on a substrate, wherein
As mentioned above, the present invention provides a method for producing a thin film transistor. This manufacturing method is characterized in forming the active layer and the source-drain layer by the reactive heat CVD process. Therefore, it eliminates the steps for crystallizing the semiconductor thin film and introducing impurities into the source-drain layer, and it gives rise to a polycrystalline semiconductor thin film which works at a higher speed. The stacked thin film transistor obtained in this manner permits the driving current, or ON current, to be increased. With this manufacturing method, it is possible to simplify production process, reduce production cost, and eliminate quality variation due to crystallization. Without steps for crystallization and doping, it is possible to form uniform thin film transistors on a larger substrate. This, in turn, helps realize a large-sized display unit with thin film transistors.
The stacked thin film transistor obtained by the above-mentioned manufacturing method is characterized in that the active layer and the source-drain layer are formed from a polycrystalline semiconductor thin film deposited by the reactive heat CVD process. Therefore, it works at a higher speed. Moreover, the source and drain regions are formed such that they overlap the gate electrode in a specific manner. This helps increase the driving current.
The above and other objects, features and advantages of the present invention will become apparent from the following description and the appended claims, taken in conjunction with the accompanying drawings in which like parts or elements denoted by like reference symbols.
The embodiment of the present invention will be described below with reference to the accompanying drawings. The following description is divided into three sections—the manufacturing apparatus and process and the resulting thin film transistor.
Manufacturing Apparatus
These chambers 2 and 3 are connected to evacuating means, such as tube molecular pump (TMP), and automatic pressure control (APC) means (both not shown), so that they maintain a desired internal pressure.
In addition, the chambers 2 and 3 each have the lower electrode 5 and the upper electrode 6, which are opposite to each other. The lower electrode 5 functions also as substrate supporting means. The upper electrode 6 functions also as gas diffusing means. The lower and upper electrodes 5 and 6 in the chamber 2 are connected to the radio frequency (RF) power source 7, and the lower electrode 5 (which functions as substrate supporting means) is provided with heating means 8. The heating means 8 may be an electric heater, which keeps the substrate W placed on the lower electrode 5 at 200 to 600° C.
The upper electrode 6 (which functions as gas diffusing means) is connected to gas supply means 9 which supplies more than one species of gas to the chamber 2. The gas supply means 9 is connected to as many lines (not shown) as gases necessary for film forming, so that the chambers 2 and 3 are supplied with the film forming gas G composed of raw material gases and diluent gases in a desired ratio. The film forming gas G includes silane (SiH4), ammonia (NH3), oxygen dinitride (N2O), disilane (Si2H6), fluorine (F2), germaniums tetrafluoride (GeF4), phosphine (PH3), diborane (B2H6), arsine (AsH3), nitrogen (N2), oxygen (O2), helium (He), argon (Ar), and hydrogen (H2). Each of the gas supply means 9 is provided with a mass flow controller (MFG) 9a, which controls separately the gas supply to the chambers 2 and 3.
The radio frequency power source (RF) 7, the power source of the heating means 8, and the mass flow controller 9a are under control by a sequence controller 10 connected thereto.
The manufacturing apparatus 1 constructed as mentioned above works in the following way to form an insulating film of silicon nitride or silicon oxide or the like. First, the gas supply means 9 introduces the film forming gas G including SiH4, NH3, N2O, O2, and so forth into the chamber 2. Then, the radio frequency (RF) power source 7 applies high frequencies across the lower electrode 5 and the upper electrode 6. In this way an insulating film is formed by plasma CVD on the substrate W which is placed on the lower electrode 5.
Further, the manufacturing apparatus 1 works as follows to form a semiconductor thin film such as silicon thin film. First, the gas supply means 9 introduces the film forming gas G including Si2H6, F2, Ar, and so forth into the chambers 2 and 3. Then, the lower electrode 5 is heated to about 450° C., without high frequencies being applied across the lower electrode 5 and the upper electrode 6. Under this condition, the raw material gases react with one another to excite and decompose themselves, thereby depositing a polycrystalline silicon film through reactive heat CVD on the substrate W which is placed on and heated by the lower electrode 5. In addition, to form an N-type doped silicon thin film, the gas supply means 9 introduces the film forming gas G including Si2H6, F2, Ar, PH3, and so forth into the chambers 2 and 3. Likewise, to form a P-type doped silicon thin film, the gas supply means 9 introduces the film forming gas G including Si2H6, F2, Ar, B2H6, and so forth into the chambers 2 and 3. Under this condition, a polycrystalline silicon film containing specific dopants is formed by reactive heat CVD.
The reactive heat CVD process that employs Si2H6 and F2 involves the oxidation reduction reaction, in which Si2H6 is oxidized into Si by F2. This reaction system gives rise to a hydrogen-free polycrystalline film having a crystal grain size ranging from 10 to 100 nm. P atoms and B atoms as dopants are caught into silicon lattices during film forming, and hence they are self-activated. Thus, a low-resistance N-type or P-type polycrystalline silicon film is obtained at the time of film forming without the necessity for activation annealing.
The above-mentioned film forming process is accomplished continuously in the chambers 2 and 3 as the species of gas in the film forming gas G which is supplied from the gas supply means 9 are switched. The procedure for a series of steps is controlled by the sequence controller 10.
A description is given below of the method for producing a thin film transistor by means of the above-mentioned apparatus 1.
First Embodiment
The first step is to prepare an insulating substrate 21 as shown in
On the substrate 21 are sequentially formed a silicon nitride (SiNx) film 22 as a buffer layer and a silicon oxide film (SiOx) 23, which have a thickness ranging from about 50 to 400 nm.
Then, on the silicon oxide film 23 is formed by the reactive heat CVD process a source-drain layer 24 from polycrystalline silicon or polycrystalline silicon-germanium containing an n-type (or p-type) impurity. The source-drain layer 24 may be a single-layer film or a laminate layer composed of a doped polycrystalline silicon film and a doped polycrystalline silicon-germanium film. It should be 10 to 200 nm thick, preferably 100 nm thick.
The procedure for reactive heat CVD process to form the source-drain layer 24 from n-type polycrystalline silicon starts with heating the substrate at 450 to 600° C. The chamber is supplied with a film forming gas, a dopant gas, and a diluent gas. The film forming gas includes disilane (Si2H6) and fluorine (F2). The dopant gas includes phosphine (PH3). The diluent gas is an inert gas, such as helium (He), nitrogen (N2), argon (Ar), and krypton (Kr), or hydrogen (H2). The flow rates of these gases are set up as follows.
The gas pressure is kept at about 600 Pa.
Under the above-mentioned condition, Si2H6 and F2 react with each other, thereby depositing n-type polycrystalline silicon at a rate of about 0.2 nm/s. The deposition of thin film is accompanied by crystallization, so that the activation of dopant takes place at the same time.
In the case where the source-drain layer 24 of p-type polycrystalline silicon is to be formed by the reactive heat CVD process, phosphine (PH3) as a dopant gas should be replaced by diborane (B2H6).
In the case where the source-drain layer 24 of n-type or p-type polycrystalline silicon-germanium is to be formed by the reactive heat CVD process, fluorine should be replaced by germanium tetrafluoride (GeF4). The resulting n-type or p-type polycrystalline silicon-germanium thin film varies in Si—Ge composition depending on the ratio of the flow rates of disilane (Si2H6) and germanium tetrafluoride (GeF4).
The doped polycrystalline source-drain layer 24 formed as mentioned above subsequently undergoes patterning to form a source region 24a and a drain region 24b.
Then, an active layer 25 of impurity-free polycrystalline silicon or polycrystalline silicon-germanium is formed by the reactive heat CVD process in such a way that it covers the source region 524a and the drain region 24b, as shown in
The active layer 25 undergoes patterning so that its edges overlap respectively with one edge of the source region 24a and one edge of the drain region 24b.
The substrate 1 is transferred to the other chamber for plasma CVD. A gate insulating film 26 of silicon oxide (SiOx) is formed, as shown in
A gate electrode 27 is formed above the patterned active layer 25, with the gate insulating film 26 interposed between them, as shown in
This patterning is accomplished in such a way that both edges of the gate electrode 27 overlap respectively with one edge of the source region 24a and one edge of the drain region 24b, with the gate insulating film 26 and the patterned active layer 25 interposed between them.
The overlapping sections are indicated by d1 and d2 in a plan view of
In the foregoing steps is formed a stacked TFT 28 of top gate type. Next, the TFT 28 is covered by a silicon oxide film 31 and a hydrogen-containing silicon nitride film 32, which are formed sequentially by the plasma CVD process, as shown in
Then, connecting holes are made in the silicon nitride film 32 and the silicon oxide film 31. Wiring electrodes 33 connecting respectively with the source region 24a and the drain region 24b are formed by sputtering with aluminum-silicon or the like and ensuing patterning, as shown in
The entire surface is coated with a planarized insulating film 34 of about 1 μm thick of acrylic organic resin or organic SOG. A connecting hole 34a reaching the wiring electrode 33 is made in the planarized insulating film 34. A film of Al, Cr, or Mo, or the like which fills the connecting hole 34a, is formed by sputtering. This film is patterned so as to form a pixel electrode 35.
The intermediate product undergoes annealing in a nitrogen atmosphere at about 220° C. for 30 minutes. On the pixel electrode 35 are sequentially formed a hole transport layer 36, an emitting layer 37, and an electron transport layer 38. On the top is formed a common electrode 39 which is a transparent conductive cathode. In this way, there is obtained an organic EL element 40 which is composed of an anode, or the pixel electrode 35, and a cathode, or the common electrode 39, and an organic layer held between them. The organic layer is composed of the hole transport layer 36, the emitting layer 37, and the electron transport layer 38.
Finally, a buffer layer that covers the organic EL element 40 is formed on the substrate 1. A glass plate is bonded to the substrate 1, with the organic EL element 40 interposed between them. (These steps are not shown.) Thus, a display device of top emission type is obtained. In other words, this display device has a top emission structure in which the device permits the organic EL element 40 to emit light through the transparent electrode 39 or the glass plate opposite to the substrate 1.
Incidentally, the display device is not restricted to that of top emission type but it may be of bottom emission type, in which the pixel electrode 35 is made of a transparent conductive material so that the organic EL element 40 emits light through the substrate 1. It is also possible to cause the pixel electrode 35 and common electrode 39 to function respectively as the cathode and anode. This is achieved by changing the arrangement of the hole transport layer 36, the emitting layer 37, and the electron transport layer 38.
The above-mentioned manufacturing method is characterized in that the source-drain layer 24 and the active layer 25 are formed by the reactive heat CVD process, as shown in
Moreover, the omission of steps for crystallization removes variations due to crystallization, which contributes to uniform characteristic properties. Moreover, forming a previously doped crystalline semiconductor thin film as the source-drain layer 24 eliminates the step of introducing an impurity after film formation.
As explained above with reference to
The above-mentioned manufacturing method according to the present invention produces the following effects.
The advantage of the large-sized display device as mentioned above is that selector switches are concentrated in peripheral circuits and hence connecting terminals for external circuits are greatly reduced. This helps realize a large-sized display device characterized by high reliability, low cost, and low power consumption. An example of the large-sized display device is a large electroluminescence display with a diagonal line in excess of 40 inches. Although the foregoing description has been made with reference to a display device based on organic EL elements, the present invention will be applicable to any other display devices based on inorganic EL elements, liquid crystal display elements, or the like.
Second Embodiment
Sectional views of
First, as shown in
Subsequently, as shown in
Then, an active layer 54 of impurity-free polycrystalline silicon or polycrystalline silicon-germanium is formed by the reactive heat CVD process. The active layer 54 should be about 20 to 100 nm thick. The active layer 54 should be formed in the same way as in forming the active layer 25 for the first embodiment explained above with reference to
A resist pattern 56 is formed on the silicon oxide film 55 by exposure from the back using the gate electrode 52 as a mask, as shown in
The silicon oxide thin film 55 undergoes etching through the resist pattern 56 as a mask, as shown in
Then, as shown in
After the foregoing steps, patterning and etching are performed on the source-drain layer 56 and the active layer 54 to form an island above the gate electrode 52. Then, the doped polycrystalline source-drain layer 56 is separated into two sections—the source region 56a and the drain region 56b—above the gate electrode 52. The result is shown in
In the step just mentioned above, the source-drain layer 56 should be separated above the etch stopper 55a such that both edges of the source region 56a and the drain region 56b overlap the gate electrode 52, with the active layer 54 interposed between them, as shown in a plan view of
Incidentally, in a sectional view of
After the foregoing steps, the stacked TFT 60 of bottom gate type is obtained.
Next, the stacked TFT 60 is covered by a silicon oxide film 57 of 100 to 400 nm thick and a hydrogen-containing silicon nitride film 58 of 100 to 400 nm thick, which are formed sequentially by the plasma CVD process, as shown in
Then, the step shown in
The TFT 60 according to the second embodiment, which has been produced by the above-mentioned steps, has the same advantage as that according to the first embodiment. It has the source-drain layer 56 and the active layer 54 formed by the reactive heat CVD process, as explained above with reference to
The above-mentioned manufacturing method according to the present invention produces the following effects.
The manufacturing method of the present invention may be applied to the stacked TFT of bottom gate type which is constructed such that the wiring electrodes 81 are formed directly above the source region 56a and the drain region 56b, as shown in
The stacked TFT 82 produced in this manner produces the same effect as the stacked TFT according to the second embodiment, if the source-drain layer 56 and the active layer 54 are formed by the reactive heat CVD process and the source region 56a and the drain region 56b are arranged such that their edges overlap both edges of the gate electrode 52 in the same way as in the second embodiment. Moreover, it produces an additional effect of reducing the number of masks as compared with the second embodiment.
While preferred embodiments of the present invention have been described using specific terms, such description is for illustrative purposes only, and it is to be understood that changes and variations may be made without departing from the spirit or scope of the following claims.
Number | Date | Country | Kind |
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P2003-336939 | Sep 2003 | JP | national |