Claims
- 1. A liquid toner which is comprised of (a) a polymer which is comprised of repeat units which are derived from a vinyl aromatic monomer and a second monomer selected from the group consisting of conjugated diene monomers and an acrylate monomer selected from the group consisting of alkyl acrylate monomers and alkyl methacrylate monomers, (b) a residual amount of a diacid cycloaliphatic emulsifier, (c) a pigment and (d) a carrier liquid.
- 2. A liquid toner as specified in claim 1 wherein said liquid toner is further comprised of a charge control agent.
- 3. A liquid toner as specified in claim 1 wherein the toner resin does not contain residual levels of rosin acid soaps and wherein the toner resin does not contain residual levels of fatty acid soaps.
- 4. A liquid toner as specified in claim 3 wherein the polymer is prepared by a process which comprises (1) emulsion copolymerizing a vinyl aromatic monomer and a second monomer selected from the group consisting of conjugated diene monomers and an acrylate monomer selected from the group consisting of alkyl acrylate monomers and alkyl methacrylate monomers in the presence of a diacid cycloaliphatic emulsifier to produce the polymer and (2) recovering the polymer from the aqueous emulsion.
- 5. A liquid toner as specified in claim 4 wherein from about 0.5 phm to about 6 phm of the diacid cycloaliphatic emulsifier is present during the copolymerization.
- 6. A liquid toner as specified in claim 1 wherein the vinyl aromatic monomer is styrene.
- 7. A liquid toner as specified in claim 6 wherein the second monomer is 1,3-butadiene.
- 8. A liquid toner as specified in claim 6 wherein the second monomer is selected from the group consisting of N-butyl acrylate and 2-ethylhexyl acrylate.
- 9. A liquid toner as specified in claim 7 wherein the repeat units in the polymer are derived from about 80 weight percent to about 95 weight percent styrene and from about 5 weight percent to about 20 weight percent 1,3-butadiene based upon total monomers.
- 10. A liquid toner as specified in claim 7 wherein the repeat units in the polymer are derived from about 85 weight percent to about 95 weight percent styrene and from about 8 weight percent to about 15 weight percent 1,3-butadiene based upon total monomers.
- 11. A liquid toner as specified in claim 8 wherein the repeat units in the polymer are derived from about 70 weight percent to about 95 weight percent styrene and from about 5 weight percent to about 30 weight percent of a member selected from the group consisting of N-butyl acrylate and 2-ethylhexyl acrylate.
- 12. A liquid toner as specified in claim 8 wherein the repeat units in the polymer are derived from about 85 weight percent to about 90 weight percent styrene and from about 10 weight percent to about 15 weight percent N-butyl acrylate based upon total monomers.
- 13. A liquid toner as specified in claim 4 wherein from about 1 phm to about 2 phm of the diacid cycloaliphatic emulsifier is present during the polymerization.
- 14. A liquid toner as specified in claim 4 wherein said copolymerization is initiated with a free radical initiator.
- 15. A liquid toner as specified in claim 14 wherein said free radical initiator is a persulfate initiator.
- 16. A liquid toner as specified in claim 14 wherein the free radical initiator is hydrogen peroxide.
- 17. A liquid toner as specified in claim 4 wherein said copolymerization is conducted at a temperature which is within the range of about 37.degree. C. to about 93.degree. C.
- 18. A liquid toner as specified in claim 17 wherein the polymer is recovered from the aqueous emulsion by coagulation with sulfuric acid.
- 19. A liquid toner as specified in claim 18 wherein said coagulation is carried out without utilizing salts or amines as coagulating agents.
- 20. A liquid toner as specified in claim 19 wherein water is removed from the polymer recovered by syneresis.
- 21. A toner resin which is comprised of (a) a polymer which is comprised of repeat units which are derived from a vinyl aromatic monomer and a second monomer selected from the group consisting of conjugated diene monomers and an acrylate monomer selected from the group consisting of alkyl acrylate monomers and alkyl methacrylate monomers and (b) a residual amount of a diacid cycloaliphatic emulsifier, wherein said toner resin has a glass transition temperature which is within the range of about 45.degree. C. to about 80.degree. C.
- 22. A toner resin as specified in claim 21 wherein the toner resin does not contain residual levels of rosin acid soaps or fatty acid soaps.
- 23. A toner which is comprised of (a) a polymer which is comprised of repeat units which are derived from a vinyl aromatic monomer and a second monomer selected from the group consisting of conjugated diene monomers and an acrylate monomer selected from the group consisting of alkyl acrylate monomers and alkyl methacrylate monomers, wherein said polymer has a glass transition temperature which is within the range of about 45.degree. C. to about 80.degree. C., (b) a residual amount of a diacid cycloaliphatic emulsifier and (c) a pigment.
- 24. A toner as specified in claim 23 which is further comprised of a charge control agent.
- 25. A toner as specified in claim 24 which is further comprised of a wax.
- 26. A toner resin as specified in claim 22 wherein the vinyl aromatic monomer is styrene.
- 27. A toner resin as specified in claim 26 wherein the second monomer is 1,3-butadiene.
- 28. A toner resin as specified in claim 26 wherein the second monomer is selected from the group consisting of N-butyl acrylate and 2-ethylhexyl acrylate.
- 29. A toner resin as specified in claim 27 wherein the repeat units are derived from about 80 weight percent to about 95 weight percent styrene and from about 5 weight percent to about 20 weight percent 1,3-butadiene, based upon total monomers.
- 30. A toner resin as specified in claim 27 wherein the repeat units are derived from about 85 weight percent to about 95 weight percent styrene and from about 8 weight percent to about 15 weight percent 1,3-butadiene, based upon total monomers.
- 31. A toner resin as specified in claim 28 wherein the repeat units are derived from about 70 weight percent to about 95 weight percent styrene and from about 5 weight percent to about 30 weight percent of a member selected from the group consisting of N-butyl acrylate and 2-ethylhexyl acrylate.
- 32. A toner resin as specified in claim 28 wherein the repeat units are derived from about 85 weight percent to about 90 weight percent styrene and from about 10 weight percent to about 15 weight percent N-butyl acrylate, based upon total monomers.
- 33. A toner as specified in claim 24 wherein the vinyl aromatic monomer is styrene.
- 34. A toner as specified in claim 33 wherein the second monomer is 1,3-butadiene.
- 35. A toner as specified in claim 33 wherein the second monomer is selected from the group consisting of N-butyl acrylate and 2-ethylhexyl acrylate.
- 36. A toner as specified in claim 34 wherein the repeat units are derived from about 80 weight percent to about 95 weight percent styrene and from about 5 weight percent to about 20 weight percent 1,3-butadiene, based upon total monomers.
- 37. A toner as specified in claim 34 wherein the repeat units are derived from about 85 weight percent to about 95 weight percent styrene and from about 8 weight percent to about 15 weight percent 1,3-butadiene, based upon total monomers.
- 38. A toner as specified in claim 35 wherein the repeat units are derived from about 70 weight percent to about 95 weight percent styrene and from about 5 weight percent to about 30 weight percent of a member selected from the group consisting of N-butyl acrylate and 2-ethylhexyl acrylate.
- 39. A toner as specified in claim 35 wherein the repeat units are derived from about 85 weight percent to about 90 weight percent styrene and from about 10 weight percent to about 15 weight percent N-butyl acrylate, based upon total monomers.
- 40. A toner as specified in claim 39 wherein the polymer has a glass transition temperature which is within the range of about 55.degree. C. to about 70.degree. C.
- 41. A toner as specified in claim 39 wherein the polymer has a glass transition temperature which is within the range of about 60.degree. C. to about 65.degree. C.
- 42. A toner resin as specified in claim 31 wherein the polymer has a glass transition temperature which is within the range of about 55.degree. C. to about 70.degree. C.
Parent Case Info
This application claims the benefit of U.S. Provisional Patent Application Serial No. 60/085,277, filed on May 13, 1998.
US Referenced Citations (7)