This application claims priority from Korean Patent Application No. 10-2013-0103428, filed on Aug. 29, 2013, in the Korean Intellectual Property Office, the disclosure of which is incorporated herein in its entirety by reference.
1. Field
The present disclosure relates to transistors, methods of manufacturing the same, and/or electronic devices including the transistors.
2. Description of the Related Art
Transistors are widely used as switching devices or driving devices in electronic devices. In particular, since a thin film transistor (TFT) may be manufactured on a glass substrate or a plastic substrate, TFTs are used in display apparatuses such as organic light-emitting display apparatuses or liquid crystal display apparatuses. The performance of a TFT may mostly depend on properties of a channel layer (semiconductor layer).
Most commercially available display apparatuses use a TFT including a channel layer formed of amorphous silicon (hereinafter, referred to as an amorphous silicon TFT) or a TFT including a channel layer formed of polycrystalline silicon (hereinafter, referred to as a polycrystalline silicon TFT). An amorphous silicon TFT generally presents a disadvantage in that because the charge mobility of the TFT is about 0.5 cm2/Vs or so, which is a low charge mobility, it is difficult to increase an operating speed of a display apparatus. A polycrystalline silicon TFT also presents a disadvantage in that since crystallization, impurity doping, and activation processes are required, a manufacturing process is more complex and manufacturing costs are higher than manufacturing costs of an amorphous silicon TFT. Also, the polycrystalline silicon TFT presents a disadvantage in that, since it is difficult to ensure uniformity of a polycrystalline silicon layer, image quality is reduced when the polycrystalline silicon layer is used as a channel layer of a large-size display apparatus.
In order to realize a next generation high-performance/high-resolution/large-size display apparatus, a TFT having excellent performance may be preferred. In this regard, research has been conducted on an oxide TFT using an oxide semiconductor having a high carrier mobility as a material of a channel layer. However, manufacturing a transistor (TFT) that ensures excellent switching characteristics (ON/OFF characteristics) and high reliability as well as having high mobility is difficult.
Provided are transistors including a channel having a multi-layer structure, according to at least one example embodiment.
Provided are transistors having a high mobility and excellent switching characteristics, according to at least one example embodiment.
Provided are transistors having a low OFF current level, according to at least one example embodiment.
Provided are transistors having an adjusted threshold voltage, according to at least one example embodiment.
Provided are transistors which reliability is improved by reducing (or, alternatively, suppressing) degradation of a channel layer, according to at least one example embodiment.
Provided are methods of manufacturing the transistors, according to at least one example embodiment.
Provided are electronic devices (e.g., display apparatuses) including the transistors according to at least one example embodiment.
Additional example embodiments will be set forth in part in the description which follows and, in part, will be apparent from the description, or may be learned by practice of the presented embodiments.
According to an example embodiment, a transistor includes: a channel layer that has a multi-layer structure; a source and a drain that respectively contact first and second regions of the channel layer; a gate that corresponds to the channel layer; and a gate insulating layer that is disposed between the channel layer and the gate, wherein the channel layer includes first and second layers, wherein the first layer is disposed closer to the gate than the second layer, wherein the first and second layers include a semiconductor material including zinc, oxygen, and nitrogen; and wherein the second layer has an electrical resistance that is higher than an electrical resistance of the first layer.
An oxygen content of the second layer may be higher than an oxygen content of the first layer.
The second layer may further include fluorine.
The first layer may not include fluorine.
The first and second layers may further include fluorine, and a fluorine content of the second layer may be higher than a fluorine content of the first layer.
At least one of the first and second layers may further include an additional element X, and the additional element X may include at least one cation from among boron (B), aluminum (Al), gallium (Ga), indium (In), tin (Sn), titanium (Ti), zirconium (Zr), hafnium (Hf), and silicon (Si), at least one anion from among fluorine (F), chlorine (CI), bromine (Br), iodine (I), sulfur (S), and selenium (Se), or a combination thereof.
A content of the additional element X of the first layer and a content of the additional element X of the second layer may be different from each other.
The additional X included in the first layer and the additional element X included in the second layer may be the same.
The additional element X included in the first layer and the additional element X included in the second layer may be different from each other.
The second layer may be configured to reduce an OFF current of the transistor.
The second layer may be configured to increase a threshold voltage of the transistor in a positive (+) direction.
The gate may be disposed below the channel layer.
The transistor may further include an etch-stop layer that is disposed on the channel layer.
The gate may be disposed above the channel layer.
According to another example embodiment, a display apparatus includes the transistor.
The display apparatus may be an organic light-emitting display apparatus or a liquid crystal display apparatus.
The transistor may be used as a switching device or a driving device.
According to another example embodiment, a transistor includes: a channel layer that has a multi-layer structure; a source and a drain that respectively contact first and second regions of the channel layer; a gate that corresponds to the channel layer; and a gate insulating layer that is disposed between the channel layer and the gate, wherein the channel layer includes first and second layers, wherein the first layer is disposed closer to the gate than the second layer is; wherein at least one of the first and second layers is formed of a semiconductor material including zinc fluoronitride, and wherein the second layer has an electrical resistance that is higher than an electrical resistance of the first layer.
The first layer may include zinc fluoronitride, and the second layer may include one of zinc oxide, zinc oxynitride, and zinc fluorooxynitride.
Both of the first and second layers may include zinc fluoronitride, wherein a fluorine content of the second layer is higher than a fluorine content of the first layer.
An oxygen content of the second layer may be higher than an oxygen content of the first layer.
At least one of the first and second layers may further include an additional element X, and wherein the additional element X may include at least one cation from among boron (B), aluminum (Al), gallium (Ga), indium (In), tin (Sn), titanium (Ti), zirconium (Zr), hafnium (Hf), and silicon (Si), at least one anion from among fluorine (F), chlorine (CI), bromine (Br), iodine (I), sulfur (S), and selenium (Se), or a combination thereof.
A content of the additional element X of the first layer and a content of the additional element X of the second layer may be different from each other.
The additional element X included in the first layer and the additional element X included in the second layer may be the same.
The additional element X included in the first layer and the additional element X included in the second layer may be different from each other.
The second layer may be configured to reduce an OFF current of the transistor.
The second layer may be configured to increase a threshold voltage of the transistor in a positive (+) direction.
The gate may be disposed below the channel layer.
When the gate is disposed under the channel layer, the transistor may further include an etch-stop layer that is disposed on the channel layer.
The gate may be disposed above the channel layer.
According to another example embodiment, a display apparatus includes the transistor.
The display apparatus may be an organic light-emitting display apparatus or a liquid crystal display apparatus.
The transistor may be used as a switching device or a driving device. According to at least one example embodiment, a transistor includes a gate disposed on a substrate, a gate insulating layer disposed on the gate, a channel layer disposed on the gate insulating layer, the channel layer including at least a first semiconductor layer and a second semiconductor layer, the first and second semiconductor layers including at least one of a plurality of elements having respective concentrations, a source and a drain respectively contacting a first region and a second region of the channel layer. According to at least one example embodiment, a combination of the elements and of the respective concentrations of the elements result in an electrical resistance of the second semiconductor layer being greater than an electrical resistance of the first semiconductor layer
These and/or other example embodiments will become apparent and more readily appreciated from the following description of the example embodiments, taken in conjunction with the accompanying drawings of which:
Various example embodiments will now be described more fully with reference to the accompanying drawings in which example embodiments are shown.
It will be understood that when an element is referred to as being “connected” or “coupled” to another element, it can be directly connected or coupled to the other element or intervening elements may be present. In contrast, when an element is referred to as being “directly connected” or “directly coupled” to another element, there are no intervening elements present. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items. Expressions such as “at least one of,” when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.
It will be understood that, although the terms “first”, “second”, etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer or section from another element, component, region, layer or section. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the teachings of example embodiments.
Spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as “below” or “beneath” other elements or features would then be oriented “above” the other elements or features. Thus, the example term “below” can encompass both an orientation of above and below. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of example embodiments. As used herein, the singular forms “a,” “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
Example embodiments are described herein with reference to cross-sectional illustrations that are schematic illustrations of idealized embodiments (and intermediate structures) of example embodiments. As such, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, are to be expected. Thus, example embodiments should not be construed as limited to the particular shapes of regions illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. For example, an implanted region illustrated as a rectangle will, typically, have rounded or curved features and/or a gradient of implant concentration at its edges rather than a binary change from implanted to non-implanted regions. Likewise, a buried region formed by implantation may result in some implantation in the region between the buried region and the surface through which the implantation takes place. Thus, the regions illustrated in the figures are schematic in nature and their shapes are not intended to illustrate the actual shape of a region of a device and are not intended to limit the scope of example embodiments.
Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which example embodiments belong. It will be further understood that terms, such as those defined in commonly-used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
Reference will now be made in detail to embodiments, examples of which are illustrated in the accompanying drawings. Widths and thicknesses of layers or regions illustrated in the drawings are exaggerated for clarity. The same reference numerals denote the same elements throughout.
Referring to
According to an example embodiment, the channel layer C10 may be disposed on the gate insulating layer GI10. The channel layer C10 may be disposed over the gate electrode G10 to face the gate electrode G10. A width of the channel layer C10 in an X-axis direction may be greater than a width of the gate electrode G10 in the X-axis direction. However, in some cases, a width of the channel layer C10 may be similar to or less than a width of the gate electrode G10. The channel layer C10 may have a multi-layer structure including at least two semiconductor layers. For example, the channel layer C10 may have a double-layer structure including a first semiconductor layer (hereinafter, referred to as a first layer) 10 and a second semiconductor layer (hereinafter, referred to as a second layer) 20. The first layer 10 that is disposed closer to the gate electrode G10 than the second layer 20 is may act as a main channel. The second layer 20 that is disposed farther away from the gate electrode G10 than the first layer 10 is may act as a sub-channel. The first layer 10 may be referred to as a front channel, and the second layer 20 may be referred to as a back channel. Materials and properties of the first layer 10 and the second layer 20 will be explained later in detail. The characteristics, performance, and reliability of the transistor may be improved due to the channel layer C10, which will be explained later in detail.
According to an example embodiment, a source electrode S10 and a drain electrode D10 that respectively contact first and second regions (for example, both ends) of the channel layer C10 may be disposed on the gate insulating layer GI10. Each of the source electrode S10 and the drain electrode D10 may have a single-layer structure or a multi-layer structure. Each of the source electrode S10 and the drain electrode D10 may be formed of a metal, an alloy, conductive metal oxide, conductive metal nitride, or the like. A material of each of the source electrode S10 and the drain electrode D10 may be the same as or similar to a material of the gate electrode G10. Each of the source electrode S10 and the drain electrode D10 may be formed of the same material as the gate electrode G10, or a different material than the gate electrode G10. Shapes and positions of the source electrode S10 and the drain electrode D10 may be changed.
According to an example embodiment, a passivation layer P10 that covers the channel layer C10, the source electrode S10, and the drain electrode D10 may be disposed on the gate insulating layer GI10. The passivation layer P10 may be a silicon oxide layer, a silicon oxynitride layer, a silicon nitride layer, or an organic layer, or may have a structure in which at least two of the silicon oxide layer, the silicon oxynitride layer, the silicon nitride layer, and the organic layer are stacked. For example, the passivation layer P10 may have a single-layer structure formed of silicon oxide or silicon nitride, or a multi-layer structure including a silicon oxide layer and a silicon nitride layer that is disposed on the silicon oxide layer. Also, the passivation layer P10 may have a multi-layer structure including three or more layers. In this case, the passivation layer P10 may include a silicon oxide layer, a silicon oxynitride layer, and a silicon nitride layer that are sequentially stacked. A configuration of the passivation layer P10 may be changed in various ways. Thicknesses of the gate electrode G10, the gate insulating layer GI10, the source electrode S10, the drain electrode D10, and the passivation layer P10 may respectively range from about 50 to about 300 nm, from about 50 to about 400 nm, from about 10 to about 200 nm, from about 10 to about 200 nm, and from about 50 to about 1200 nm. However, thickness ranges may be changed, if necessary.
Materials and properties of the first and second layers 10 and 20 of the channel layer C10 will now be explained in detail below.
According to an example embodiment, the first layer 10 may be formed of a first semiconductor material including zinc (Zn), oxygen (O), and nitrogen (N), and the second layer 20 may be formed of a second semiconductor material including zinc, oxygen, and nitrogen. An electrical resistance of the second layer 20 may be higher than an electrical resistance of the first layer 10. For example, the first layer 10 may include a zinc oxynitride (ZnON)-based semiconductor material, and the second layer 20 may also include a ZnON-based semiconductor material. In this case, an oxygen content of the second layer 20 may be higher than an oxygen content of the first layer 10. Due to such a difference in an oxygen content, the second layer 20 may have a higher electrical resistance than the first layer 10.
According to an example embodiment, when each of the first layer 10 and the second layer 20 includes a ZnON-based semiconductor, at least one of the first layer 10 and the second layer 20 may further include fluorine (F). For example, the second layer 20 may further include fluorine, and the first layer 10 may not include fluorine. In this case, the second layer 20 may include a zinc fluorooxynitride (ZnONF)-based semiconductor, and the first layer 10 may include a ZnON-based semiconductor. As such, when only the second layer 20 from among the first layer 10 and the second layer 20 includes fluorine, due to the fluorine, an electrical resistance of the second layer 20 may be increased to be higher than an electrical resistance of the first layer 10. Alternatively, both of the first layer 10 and the second layer 20 may include fluorine. That is, both of the first layer 10 and the second layer 20 may include a ZnONF-based semiconductor. In this case, a fluorine content of the second layer 20 may be higher than a fluorine content of the first layer 10. Due to such a difference in a fluorine content, the second layer 20 may have a higher electrical resistance than the first layer 10.
According to an example embodiment, when each of the first layer 10 and the second layer 20 includes a ZnON-based semiconductor, at least one of the first layer 10 and the second layer 20 may further include an additional element X. The additional element X may include at least one cation from among boron (B), aluminum (Al), gallium (Ga), indium (In), tin (Sn), titanium (Ti), zirconium (Zr), hafnium (Hf), and silicon (Si), at least one anion from among fluorine (F), chlorine (CI), bromine (Br), iodine (I), sulfur (S), and selenium (Se), or a combination of the at least one cation and the at least one anion. A content (content ratio) of the additional element X of the first layer 10 and a content (content ratio) of the additional element X of the second layer 20 may be different from each other. Electrical resistances of the first layer 10 and the second layer 20 may be controlled by a content (content ratio) of the additional element X. For example, as an aluminum content of the second layer 20 increases, an electrical resistance of the second layer 20 may increase. Accordingly, an electrical resistance of the second layer 20 may be increased to be higher than an electrical resistance of the first layer 10 by selectively adding aluminum only to the second layer 20 or by increasing an aluminum content of the second layer 20 to be higher than an aluminum content of the first layer 10. Also, when both the first layer 10 and the second layer 20 include the additional element X, the additional element X of the first layer 10 and the additional element X of the second layer 20 may be the same or different from each other. That is, the first layer 10 and the second layer 20 may include the same additional element X or different additional elements X. Electrical resistances of the first layer 10 and the second layer 20 may be controlled by a type of the additional element X as well as a content (content ratio) of the additional element X.
Alternatively, according to an example embodiment, at least one of the first layer 10 and the second layer 20 may be formed of a semiconductor material including zinc fluoronitride (ZnNF). Here, the second layer 20 may have a higher electrical resistance than the first layer 10. For example, the first layer 10 may include ZnNF, and the second layer 20 may include any one of zinc oxide (ZnO), ZnON, and ZnONF. In this case, the second layer 20 may be formed of a material (compound) including oxygen, and the first layer 10 may not include oxygen or may include little oxygen. Accordingly, an oxygen content of the second layer 20 may be higher than an oxygen content of the first layer 10. In this regard, an electrical resistance of the second layer 20 may be higher than an electrical resistance of the first layer 10. Alternatively, both of the first layer 10 and the second layer 20 may be formed of a semiconductor material including ZnNF. In this case, a fluorine content of the second layer 20 may be higher than a fluorine content of the first layer 10. Due to such a difference in a fluorine content, the second layer 20 may have a higher electrical resistance than the first layer 10.
According to an example embodiment, when at least one of the first layer 10 and the second layer 20 is formed of a semiconductor material including ZnNF, at least one of the first layer 10 and the second layer 20 may further include an additional element X. The additional element X may include at least one cation from among B, Al, Ga, In, Sn, Ti, Zr, Hf, and Si, at least one anion from among F, Cl, Br, I, S, and Se, or a combination of the at least one cation and the at least one anion. However, when the first layer 10 and/or the second layer 20 already includes fluorine, fluorine may be excluded from examples of the additional element X. A content (content ratio) of the additional element X of the first layer 10 and a content (content ratio) of the additional element X of the second layer 20 may be different from each other. Electrical resistances of the first layer 10 and the second layer 20 may be controlled by a content (content ratio) of the additional element X. For example, as a content (content ratio) of aluminum of the second layer 20 increases, an electrical resistance of the second layer 20 may increase. Also, when both the first layer 10 and the second layer 20 include the additional element X, the additional element X of the first layer 10 and the additional element X of the second layer 20 may be the same or different from each other. Electrical resistances of the first layer 10 and the second layer 20 may be controlled by a type of the additional element X as well as a content (content ratio) of the additional element X.
As described above, according to an example embodiment, an electrical resistance of the second layer 20 may be higher than an electrical resistance of the first layer 10. In other words, an electrical conductivity of the second layer 20 may be lower than an electrical conductivity of the first layer 10. Also, a carrier density of the second layer 20 may be lower than a carrier density of the first layer 10. A Hall mobility of the second layer 20 may be lower than a Hall mobility of the first layer 10. A leakage current in an OFF state may be reduced (or, alternatively, suppressed) by increasing an electrical resistance of the second layer 20 that is disposed far away from the gate electrode G10, and thus an OFF current level of the transistor may be reduced. In other words, when the second layer 20 that is a back channel region has a relatively high electrical resistance, an OFF current through the back channel region may be reduced or, alternatively, suppressed (prevented). If an OFF current level of the transistor is reduced, various effects may be obtained. Assuming that a display apparatus using a transistor having a high OFF current is manufactured, when a panel is driven, it may be difficult to express a gray scale due to a leakage current and it may difficult to maintain a node potential. However, according to the present example embodiment, since an OFF current level of the transistor may be reduced, when the transistor is applied to a display apparatus, a grayscale may be effectively expressed and switching characteristics may be improved.
According to an example embodiment, a threshold voltage of the transistor may shift in a positive (+) direction due to the second layer 20 having a relatively high electrical resistance. When a threshold voltage of the transistor has a high value in a negative (−) direction (that is, a high negative value), a voltage (an absolute value) of an input signal may be increased, and thus power consumption may be increased. However, according to the present example embodiment, since a threshold voltage of the transistor increases in a positive (+) direction due to the second layer 20, the transistor may be easily operated and power consumption may be reduced.
Also, in the present example embodiment, the first channel 10 that is a main channel may be protected by the second layer 20. When the transistor is manufactured, the channel layer C10 may be exposed during a plasma process or a wet process, and thus characteristics of the channel layer C10 may be changed or degraded. In particular, when a ZnON or ZnNF-based semiconductor is used, characteristics may be easily degraded during a plasma process or a wet process, thereby reducing the reliability of the transistor including the semiconductor. However, according to the present example embodiment, since the second layer 20 that has a relatively high electrical resistance and has a high resistance against plasma or a wet process is disposed on the first layer 10, the first layer 10 that is a main channel layer may be prevented from being degraded, thereby improving the reliability of the transistor. Also, when the second layer 20 is disposed on the first layer 10, the transistor may be manufactured without forming an etch-stop layer for protecting the channel layer C10. In this case, a process may be simplified.
According to an example embodiment, the reliability of the transistor with regard to a negative bias stress may be improved due to the second layer 20. As a hole concentration of a channel layer increases, the reliability of a transistor with regard to a negative bias stress may be reduced. In the present example embodiment, however, since a hole concentration of the second layer 20 may be reduced due to oxygen or fluorine, a hole concentration of the second layer 20 may be lower than a hole concentration of the first layer 10. Accordingly, the reliability of the transistor with regard to a negative bias stress may be improved due to the second layer 20.
According to an example embodiment, the transistor of the present example embodiment may have a high field-effect mobility due to the first layer 10 that has a relatively low electrical resistance and a high Hall mobility. Accordingly, the transistor may have a high mobility (high field-effect mobility), a low OFF current, and high reliability.
According to an example embodiment, a TFT including an oxynitride (e.g., ZnON) channel layer having a single-layer structure may have problems in that an OFF current is relatively high, a threshold voltage has a high negative value, and characteristics of the channel layer are easily degraded. Also, since the oxynitride channel layer has a high hole concentration, the TFT including the oxynitride channel layer having the single-layer structure may have low reliability with respect to a negative bias voltage. However, according to the present example embodiment, since the channel layer C10 having a multi-layer structure including two or more layers is used, the transistor may avoid the afore-described problems, and have excellent performance and high reliability.
According to an example embodiment, a semiconductor material of the channel layer C10 may include an amorphous phase, a crystalline phase, or a combination thereof. Also, the semiconductor material may have a plurality of nanocrystals (nanocrystalline phase) in an amorphous matrix. A thickness of the channel layer C10 may range from about 5 to about 300 nm, for example, from about 10 to about 200 nm. A thickness of the first layer 10 that is a main channel may range from about 5 to about 100 nm. A thickness of the second layer 20 that is a sub-channel may range from about 5 to about 100 nm. However, thickness ranges of the first layer 10 and the second layer 20 and a total thickness range of the channel layer C10 may be changed.
Additionally, in each of ZnON, ZnONF, and ZnNF used herein, only elements are listed and a composition ratio of the elements is neglected. For example, the term ‘ZnON’ used herein represents a material (compound) composed of zinc, oxygen, and nitrogen of various possible relative compositions. The same principle applies to ZnONF, and ZnNF. Also, since ZnON, ZnONF, or ZnNF may be a “compound” or a “material including a compound”, the ZnON, ZnONF, or ZnNF may be referred to as a compound semiconductor material or a semiconductor material including a compound. Accordingly, the terms “compound semiconductor material” and “semiconductor material including a compound” used herein are to be interpreted broadly.
Alternatively, the transistor of
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According to an example embodiment, positions of the channel layer C20, and the source electrode S20 and the drain electrode D20 in
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According to an example embodiment, a stacked structure SS30 in which a gate insulating layer GI30 and the gate electrode G30 are sequentially stacked may be disposed on the channel region C30 of the active layer A30. A source region S30 and a drain region D30 may be disposed in the active layer A30 at both sides of the stacked structure SS30. Each of the source region S30 and the drain region D30 may have a higher electrical conductivity than the channel region C30. The source region S30 and the drain region D30 may be conductive regions. The source region S30 and the drain region D30 may be regions treated (processed) with plasma. For example, the source region S30 and the drain region D30 may be regions treated (processed) with plasma including hydrogen (H). When the active layer A30 on both sides of the stacked structure SS30 is treated (processed) with plasma of a gas including hydrogen, the source region S30 and the drain region D30 having conductive property may be formed. In this case, the gas including the hydrogen may be NH3, H2, SiH4, or the like. When both end portions of the active layer A30 are treated (processed) with the plasma of the gas including the hydrogen, the hydrogen may act as a carrier by entering the active layer A30. Also, the plasma of the hydrogen may remove an anion (oxygen or the like) of the active layer A30, and thus an electrical conductivity of a plasma-treated region may be increased. Thus, the source region S30 and the drain region D30 may each include a region whose anion (oxygen or the like) concentration is relatively low. In other words, the source region S30 and the drain region D30 may each include a region whose cation concentration is relatively high, for example, a zinc-rich region.
According to an example embodiment, an interlayer insulating layer ILD30 that covers the gate electrode G30, the source region S30, and the drain region D30 may be disposed on the substrate SUB30. First and second electrodes E31 and E32 that are respectively electrically connected to the source region S30 and the drain region D30 may be disposed on the interlayer insulating layer ILD30. The source region S30 and the first electrode E31 may be connected to each other through a first conductive plug PG31, and the drain region D30 and the second electrode E32 may be connected to each other through a second conductive plug PG32. The first and second electrodes E31 and E32 may be respectively referred to as a source electrode and a drain electrode. Alternatively, the source region S30 and the drain region D30 themselves may be referred to as a source electrode and a drain electrode. A passivation layer (not shown) that covers the first and second electrodes E31 and E32 may be further disposed on the interlayer insulating layer ILD30.
According to an example embodiment, the transistor of
Referring to
Methods of manufacturing transistors according to example embodiments will now be explained below.
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The channel layer C10 may be deposited by using physical vapor deposition (PVD) such as sputtering, according to an example embodiment. The sputtering may be reactive sputtering. Also, the sputtering may be performed by using a single target or a plurality of targets. The single target or at least one of the plurality of targets may include zinc. Also, the single target and or at least one of the plurality of targets may further include another element, for example, fluorine, aluminum, gallium, or the like. During the sputtering, a nitrogen gas (N2) and an oxygen gas (O2) may be used as a reactive gas, and additionally, an argon (Ar) gas may be further used. When the first layer 10 and the second layer 20 are formed, used targets or composition of reactive gases may be different from each other. For example, a flow rate of an oxygen gas may be different, or sputtering power for a target including fluorine may be different. Due to such a change in a process condition, materials and properties of the first layer 10 and the second layer 20 may be different from each other.
The example method of forming the channel layer C10 may be changed in various example ways. For example, the channel layer C10 may be formed by using a method other than the sputtering, for example, metal organic chemical vapor deposition (MOCVD). Alternatively, the channel layer C10 may be formed by using another method such as chemical vapor deposition (CVD), atomic layer deposition (ALD), or evaporation.
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The example method of
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Next, as shown in
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The example method of
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Table 1 shows properties of a transistor according to an example embodiment and a comparative transistor. The transistor according to the example embodiment is the same as the transistor of
Referring to Table 1, the comparative transistor has an OFF current that is about 1.6 times greater than an OFF current of the transistor according to an example embodiment. In other words, the transistor according to the example embodiment has a much lower OFF current than the comparative transistor. Meanwhile, a threshold voltage of the transistor according to the example embodiment is higher by about 5.3 V than a threshold voltage of the comparative transistor. Thus, it is found that according to the example embodiment, an OFF current of a transistor decreases and a threshold voltage thereof shifts in a positive (+) direction.
Transistors according to example embodiments may be applied as a switching device or a driving device to a display apparatus such as an organic light-emitting display apparatus or a liquid crystal display apparatus. As described above, since the transistor according to the example embodiment has a high mobility, a low OFF current, excellent switching characteristics (ON/OFF characteristics), and high reliability, the performance of a display apparatus may be improved when the transistor is applied to the display apparatus. Accordingly, the transistor according to the example embodiment may be effectively used to realize a next generation high-performance/high-resolution/large-size display apparatus. Also, the transistor according to the example embodiment may be applied for various purposes to other electronic devices such as a memory device or a logic device as well as a display apparatus. For example, the transistor according to the example embodiment may be used as a transistor constituting a peripheral circuit of a memory device or a selection transistor.
Referring to
While the example embodiments have been particularly shown and described, it will be understood by one of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the example embodiments as defined by the following claims. For example, it will be understood by one of ordinary skill in the art that elements and structures of the transistors of
Number | Date | Country | Kind |
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10-2013-0103428 | Aug 2013 | KR | national |