Claims
- 1. An unsaturated linear polymer comprising: a reaction product comprising first residues of a first monomer, second residues of a second monomer and third residues of a third monomer, said first monomer being a diol having a molecular weight below about 200, said second monomer being selected from the group consisting of unsaturated dicarboxylic acids and diesters, and said third monomer being different from said second monomer and selected from the group consisting of aromatic dicarboxylic acids and diesters; a concentration of said second residues ranging from about 3 to about 15 wt. %, based on a total weight of the polymer, and a concentration of said third residues ranging from about 40 to about 50 wt. % based on a total weight of the polymer; said polymer having a glass transition temperature ranging from about 52.degree. C. to about 61.degree. C.
- 2. The polymer according to claim 1, wherein the weight average molecular weight, M.sub.w, is in the range of about 5,000 to 20,000 and the number average molecular weight, M.sub.n, is in the range of about 2,000 to 6,000.
- 3. The polymer according to claim 1, wherein the glass transition temperature ranges from about 57.degree. C. to about 59.degree. C.
- 4. The polymer according to claim 1, wherein the concentration of second residues in the polymer ranges from about 5 wt. % to about 8 wt. %, based on the total weight of the polymer.
- 5. The polymer according to claim 1, wherein the concentration of first residues in the polymer ranges from about 42 wt. % to about 78 wt. %, based on the total weight of the polymer.
- 6. The polymer according to claim 4, wherein the first residue concentration ranges from about 50 wt. % to about 65 wt. % based on the total weight of the polymer.
- 7. The polymer according to claim 4, wherein the first residue concentration ranges from about 55 wt. % to about 60 wt. % based on the total weight of the polymer.
- 8. The polymer according to claim 1, wherein the first monomer is selected from the group consisting of 1,2-propane diol, 1,3-butane diol, ethylene glycol, 1,4-butane diol, diethylene glycol, neopentyl glycol, dipropylene glycol, dibromo neopentyl glycol, 2,2,4-trimethyl pentane-1,3-diol, 1,4-butane diol and mixtures thereof.
- 9. The polymer according to claim 1, wherein the second monomer is selected from the group consisting of maleic acid, maleic anhydride, fumaric acid, chloromaleic acid, itaconic acid, citraconic acid, mesaconic acid and esters and anhydrides thereof.
- 10. The polymer according to claim 1, wherein the third monomer is selected from the group consisting of terephthalic acid, isophthalic acid, phthalic acid, benzophenone-4-4'-dicarboxylic acid, 1,2-diphenoxyethane-p,p'-dicarboxylic acid, naphthalene dicarboxylic acid, tetrahydrophthalic acid, phthalic anhydride, chlorendic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, endomethylene tetrahydrophthalic anhydride, tetrachlorophthalic anhydride, tetrabromo phthalic anhydride and esters thereof.
- 11. The polymer according to claim 1, wherein the first monomer is 1,2-propane diol, the second monomer is diethyl fumarate and the third monomer is dimethyl terephthalate.
- 12. The polymer according to claim 1, wherein the polymer is cross-linked to form a polyester toner resin consisting essentially of high density cross-linked microgel particles and linear polymer.
- 13. The polymer according to claim 1, wherein the polyester toner resin is substantially free of sol.
- 14. The polymer according to claim 1, further comprising from about 1 to about 20 mole percent, based on a total diol residue in the polymer, of fourth residues derived from a fourth monomer being a diol having a higher molecular weight than said first monomer.
- 15. The polymer according to claim 14, wherein the fourth monomer is selected from the group consisting of propoxylated bisphenol A, ethoxylated bisphenol-A, tetrabromo bisphenol dipropoxy ether, and mixtures thereof.
- 16. The polymer according to claim 14, wherein the first monomer is 1,2-propane diol, the second monomer is diethyl fumarate, the third monomer is dimethyl terephthalate and the fourth monomer is propoxylated bisphenol A.
- 17. The polymer according to claim 14, wherein the first monomer is 1,2-propane diol, the second monomer is dimethyl fumarate, the third monomer is dimethyl terephthalate and the fourth monomer is 1,3-butane diol.
- 18. The polymer according to claim 14, wherein the first monomer is 1,2-ethane diol, the second monomer is dimethyl fumarate, the third monomer is dimethyl terephthalate and the fourth monomer is 1,2-propane diol.
- 19. An unsaturated, linear polymer comprising:
- a reaction product of monomer comprising a low molecular weight diol having a molecular weight below about 200 and at least two different monomers selected from the group consisting of carboxylic diacids and diesters, said polymer having a glass transition temperature ranging from about 52.degree. C. to about 61.degree. C.
- 20. A polymer according to claim 19, wherein said monomers further comprise an aromatic diol different from said low molecular weight diol.
- 21. A polymer according to claim 19, wherein said monomers comprise 1,2-propane diol, dialkyl fumarate and dialkyl terephthalate.
- 22. A polymer according to claim 21, wherein said monomers further comprise propoxylated bisphenol A.
- 23. A process for preparing unsaturated linear polymer comprising a reaction product comprising first residues of a first monomer, second residues of a second monomer and third residues of a third monomer, comprising the step of:
- polymerizing a first monomer, having a molecular weight less than 200, a second monomer selected from the group consisting of an unsaturated dicarboxylic acids, diesters and anhydrides thereof, and a third monomer selected from the group consisting of aromatic dicarboxylic acids and diesters thereof, for a reaction time and at a reaction temperature to form the unsaturated linear polymer.
- 24. The process according to claim 23, wherein the reaction product further comprises fourth residues of a fourth monomer.
- 25. The process according to claim 23, wherein the polymerizing occurs under a vacuum to remove reaction by-products.
- 26. The process according to claim 23, wherein the reaction temperature ranges from about 150.degree. C. to about 250.degree. C.
- 27. The process according to claim 23, wherein the reaction time ranges from about 1 hour to about 5 hours.
- 28. The process according to claim 23, further comprising, adding a catalyst to promote transesterification.
- 29. The process according to claim 28, wherein the catalyst is selected from the group consisting of tetraisopropyl orthotitanate, tetrabutyl orthotitanate, monobutyl tin oxide and dibutyl tin oxide.
Parent Case Info
This is a division of application Ser. No. 08/159,176 filed Nov. 30, 1993, now U.S. Pat. No. 5,407,772.
US Referenced Citations (11)
Divisions (1)
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Number |
Date |
Country |
Parent |
159176 |
Nov 1993 |
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