The present invention generally relates to circuitry for driving reflective display devices and in particular, electrochemical display devices.
Reflective display devices are fundamentally different than today's typical display devices. Reflective display devices reflect incident light whereas typical display devices selectively mask a light source. Typical display devices include cathode ray tubes (CRT), liquid crystal displays (LCD), and plasma displays. In all of these examples of typical display devices a light source is selectively masked or colored to create an image. Reflective displays, on the other hand, selectively reflect incident light to create an image. Examples of reflective displays include electrochromic displays, electrophoretic displays, electrowetting displays, dielectrophoresis displays, and anisotropically rotating ball displays. Reflective displays do not require backlighting, produce excellent contrast ratios, and are easily viewable in bright ambient light, such as outdoors.
Electrochromic compounds exhibit a reversible color change when the compounds gain or lose electrons. Single segment electrochromic devices that exploit the inherent properties of electrochromic compounds find application in large area static displays and automatically dimming mirrors, and are well known. Multiple segment electrochromic display devices create images by selectively modulating light that passes through a controlled region containing an electrochromic compound. A multitude of controlled electrochromic regions may individually function as pixels to collectively create a high resolution image. Typically, these display devices contain a reflective layer underneath the electrochromic compound, respective to the viewer, for reflecting light allowed to pass beyond the electrochromic region. Simply put, the electrochromic pixel acts as a shutter either blocking light or allowing light to pass through to the underlying reflective layer.
A typical prior art electrochromic display device 10, as shown in
A second substrate 50, which is transparent, supports a transparent conductor layer 60, which may be a layer of FTO or ITO. A nano-structured film 70 having a redox chromophore 75, typically a 4,4′-bipyridinium derivative compound, adsorbed thereto is deposited on the transparent conductor 60, by way of a self-assembled mono-layer deposition from solution.
The base substrate 10 and the second substrate 50 are then assembled with an electrolyte 80 placed between the ion-permeable reflective layer 40 and the nano-structured film 70 having an adsorbed redox chromophore 75. A potential applied across the cathode electrode 90 and the anode electrode 100 reduces the adsorbed redox chromophore 75, thereby producing a color change. Reversing the polarity of the potential reverses the color change. When the redox chromophore 75 is generally black or very deep purple in a reduced state, a viewer 110 perceives a generally black or very deep purple color. When the redox chromophore 75 is in an oxidized state and generally clear, a viewer 110 will perceive light reflected off of the ion-permeable reflective layer 40, which is generally white. In this manner, a black and white display is realized by a viewer 110.
Electrochromic display devices such as the one described above are described in greater detail in U.S. Pat. No. 6,301,038 and U.S. Pat. No. 6,870,657, both to Fitzmaurice et al., which are herein incorporated by reference.
The electrochromic display 10 shown in
To reduce the complexity of providing each pixel with its own direct drive routing track, an active matrix may be used. In an active matrix, each pixel has an active component for electrically isolating each pixel from all other pixels and for matrix addressing of each pixel.
To write data to a desired pixel 260, for example the pixel 260 at the intersection of row R2 and column C2, a row signal is applied to row R2 to activate the active device 210, while a different row signal is applied to all other rows (i.e. rows R1, R3, and R4) to ensure active devices 210 in these rows are kept inactive. A column signal is then applied on column C2 to write data to the pixel 210. Typically, an entire row of pixels will be updated simultaneously by writing data to each pixel in a selected row at the same time. In this manner, a large number and high density of pixels may be individually controlled while maintaining electrical isolation of each pixel.
Typically, an active matrix is constructed from thin film transistors (TFTs). The fabrication of TFTs is well known in the art and includes the deposition of opaque metal layers on an insulative substrate. Therefore, TFTs are not transparent or translucent. Furthermore, in order to achieve optimal switching times and performance in an electrochromic display of the kind described above, the drain of each TFT must be on the cathode side of the display (i.e. on the side contained the nano-structured film with adsorbed viologen). Achieving active control of pixels A, B, and C in the electrochromic display 10 therefore requires placement of opaque TFTs on the front plane of the display, with respect to the viewer 110. This is disadvantageous as opaque TFTs diminish the reflectivity of the display, reduce pixel aperture, and adversely affect contrast ratio and apparent brightness of the display.
In addition to reducing pixel aperture, prior art electrochromic device drive circuitry produces slow switching times of the electrochromic pixel, lacks the capability to provide multiple levels of coloration, and is incapable of driving an electrochromic pixel without first bleaching the pixel. Typically, prior art driving circuitry is powered by a single DC potential. Accordingly, the driving circuitry simply provides an on or off signal to the pixel without the ability to provide intermediate voltages. Prior art driving circuitry also lacks the ability to compensate for the instantaneous pixel state and for non-uniformities in the driving circuitry.
Therefore, driving circuitry for active matrix reflective displays that overcomes the above disadvantages is desired.
The present invention is a driving circuit for use with reflective display devices and in particular, electrochromic devices. In a preferred embodiment, an electrochromic display device is a pixilated, active matrix device. The inventive circuit includes a sampling capacitor and a plurality of inverters.
The sampling circuit quickly stores a data voltage. Addressing of a plurality of electrochromic pixels in an active matrix is thereby accelerated. The plurality of inverters is coupled to a relatively high and low power source for quickly driving the electrochromic pixel to the stored data voltage. The circuit of the present invention permits rapid refreshing of electrochromic pixels in an active matrix and achieves color gradients without bleaching and recharging the electrochromic pixel.
A more detailed understanding of the invention may be had from the following description, given by way of example and to be understood in conjunction with the accompanying drawings, wherein:
Referring to
The circuit 300 uses a sampling capacitor thereby allowing a data voltage to be programmed into the circuit when its associated electrochromic pixel 340 is selected. The electrochromic pixel 340 may then be charged while it is deselected and the remaining pixels of the display device are addressed. This allows the entire display to be updated at much faster refresh rates than previously achieved in the prior art.
In order to address a given electrochromic pixel 340, a selection electrode 355 of a matrix is selected. In order to write data to the given electrochromic pixel 340, the data electrode 355 provides a data voltage Vdata to the electrochromic pixel 340. The voltage difference at transistor M1, which is an n-type transistor, switches the transistor M1. Node 1 is therefore charged with the data voltage of Vdata. The sampling capacitor 320, C1 is likewise charged to the data voltage Vdata.
During the addressing phase, transistor M3 is switched on and conducting, thereby holding the first stage of the inverter 330 (i.e. transistors M4 and M5) in a metastable state between the high voltage source Vhi and the low voltage source Vlow. Transistor M2 is off during the row address period, thereby isolating the electrochromic pixel 340 from Node 1.
When the selection electrode 350 is deselected, Node 1 becomes isolated from the data electrode 355 and is now coupled through the transistor M2 to the electrochromic pixel 340. Capacitor C2 is selected such that the capacitance of the electrochromic pixel 340 is much larger than that of the capacitor C2. The voltage at Node 1 therefore is approximately equivalent to the voltage stored in the electrochromic pixel 340. Transistor M3 no longer couples the input and output of the first inverter (i.e. M4 and M5) and the voltage change at Node 1 is coupled through C2 to the input of the first inverter (i.e. M4 and M5). The first inverter (i.e. M4 and M5) and the second inverter (i.e. M6 and M7) apply a voltage gain to the coupled signal such that the third inverter (i.e. M8 and M9) are driven into saturation. The specific transistor of the third inverter, either M8 or M9 that is driven into saturation depends on the voltage difference between Vdata(t−1) and Vdata(t), where t is a given time sample.
The high and low source voltages Vhi and Vlow are preferably relatively high and low voltages sources with respect to the typical driving voltage of the electrochromic pixel. When the third inverter is driven into saturation with the appropriate voltage, the electrochromic pixel 340 is charged at a faster rate than by simply charging the pixel 340 directly with Vdata.
As the voltage on the electrochromic pixel 340 changes, the change is coupled through capacitor C2 to the input of the first inverter (i.e. M4 and M5) forcing it back towards its original meta-stable point. The inputs of the second inverter (i.e. M6 and M7) and the third inverter (i.e. M8 and M9) are also forced to the meta-stable voltage point. In the case where the working voltage range of the electrochromic pixel 340 is relatively close to the meta-stable voltage, the static state position of the circuit will ensure minimum static power consumption.
The circuit 300 minimizes image artifacts due to transistor non-uniformity as the final state on the electrochromic pixel 340 is independent of the threshold and the mobility of the transistors M1 through M9. The feedback loop design of the circuit 300 forces the inverters 330 to stop charging the electrochromic pixel 340 when the desired voltage level has been reached on the pixel's 340 electrode.
Preferably, during non-addressing periods, for example when the electrochromic pixel 340 is in a bistable mode, the high and low voltage sources Vhi and Vlow are brought to the meta-stable voltage, thereby minimizing power consumption. In a preferred embodiment, the metastable voltage is selected to be zero (0) volts.
In the event that data to be written to the electrochromic pixel 340 does not change over a certain time period, no voltage will be coupled through capacitor C2 and the circuit 300 will remain static. In this scenario, there is no need for bleaching stages or for power consuming charging as is required with prior art driving circuits.
Preferably, the threshold voltages of n-type and p-type transistors M1 through M9 are asymmetric about the mean operating point. In this embodiment, a new operating voltage range for the electrochromic pixel 340 may be chosen that minimizes the static power consumption in the circuit. In another embodiment, capacitor C1 is omitted altogether, as the voltage will be stored at Node 1.
As part of the driving scheme, the charge injection of transistor M3 may be accounted for by incorporating a voltage offset on the voltage signal Vdata. This principle may also be used to adjust for any charge injection effects from the switching of M1. These techniques will help reduce the required size of the sampling capacitor C1. This voltage offset will preferably be performed in gamma adjustment circuitry, or elsewhere in the driving signal path.
It is noted that P-type and N-type transistors may be interchanged while maintaining the fundamental principle of operation of the circuit 300. Implementations with solely n-type or solely p-type devices may be used. Preferably, the transistors are a combination of n-channel metal-oxide-semiconductor field-effect (NMOS) TFTs and p-channel metal-oxide-semiconductor field effect (PMOS) TFTs, collectively known as complementary metal-oxide-semiconductor field effect (CMOS) TFTs. Alternatively, organic TFTs, or any other type of active device may be used. Capacitor and transistor non-uniformity will mean that the time required to charge the electrochromic pixel 340 will vary slightly from pixel to pixel. However, the minimum charging time and the transistor sizes may be specified as a function of the minimum transistor performance by fabrication. Therefore, minimum acceptable performance is guaranteed with a given refresh period.
In an alternative embodiment, an additional transistor (not shown) is added across the input and output of the 1st inverter 330. This additional transistor is preferably a P-type transistor and assists in counteracting the charge injection due to the switching of transistor M3. The additional transistor includes a gate signal coupled to the inverse signal of the selection electrode 350.
In a preferred embodiment, referring to
An insulating layer 415 is deposited on the driving circuits 405. The insulating layer 415 is substantially impermeable to the electrolyte 420, thereby protecting the driving circuits 405 from the possible corrosive effects of the electrolyte 420. Preferably, the insulating layer 415 is a spin-coated glass or polymer, such as polyimide. The insulating layer 415 may be a single, monolithic layer, or it may comprise multiple layers of identical or different materials having desired properties to achieve a desired three dimensional structure. In a preferred embodiment, the insulating layer 415 is reflective. The reflective property of the insulating layer 415 may be inherent in the material that comprises the layer, or reflective particles may be interspersed in the insulating layer 415.
An operable connection 425, known in the art as a via, is provided in the insulating layer for electrically connecting the driving circuits 405 to a conductor 430. Preferably, the operable connection 425 is created via photolithographic techniques, which are well known to those skilled in the art. Each operable connection, or via, 425 extends generally upwardly through the insulating layer 415 and is in electrical contact with a respective conductor 430, which preferably covers the bottom and the sides of a plurality of wells 435 formed or etched into the insulating layer 415. The operable connection 425 (i.e. via) and conductor 430 are preferably both transparent, and are preferably FTO, ITO or a conductive polymer.
The wells 435 are preferably etched in the insulating layer 415 using photolithographic techniques. Alternatively, the wells 435 are formed by mechanically embossing a deposited planar film or by application of a film containing a preformed waffle-type structure defining the wells 435.
Partitions 440 maintain electrical isolation of each well 435, and also allow the wells 435 to act as receptacles for ink-jet deposited materials. Partitions 440 may further act as a spacer between the cathode 445 and anode 450 of the electrochromic device 400, and serve to reduce ionic crosstalk between pixels through the electrolyte 420. The partitions 440 further serve the purpose of a visual boundary between each well 435, and may be sized as desired to achieve optimal appearance of each well 435. It should be noted that although the partitions are shown as greatly extended generally above the wells 435, they may alternatively be generally flush with the top of the wells 435.
A semiconducting layer 460 having an adsorbed electrochromophore is deposited on the conductor 430. Preferably, the semiconducting layer 460 is a nano-structured metallic oxide semiconducting film, as described hereinbefore. The semiconducting metallic oxide may be an oxide of any suitable metal, such as, for example, titanium, zirconium, hafnium, chromium, molybdenum, tungsten, vanadium, niobium, tantalum, silver, zinc, strontium, iron (Fe2+ or Fe3+) or nickel or a perovskite thereof. TiO2, WO3, MoO3, ZnO, and SnO2 are particularly preferred. Most preferably, the nano-structured film is titanium dioxide (TiO2), and the adsorbed electrochromophore is a compound of the general formulas I-III:
R1 is selected from any of the following:
R2 is selected from C1-10 alkyl, N-oxide, dimethylamino, acetonitrile, benzyl, phenyl, benzyl mono- or di-substituted by nitro; phenyl mono- or di-substituted by nitro. R3 is C1-10 alkyl and R4, R5, R6, and R7 are each independently selected from hydrogen, C1-10 alkyl, C1N0 alkylene, aryl or substituted aryl, halogen, nitro, and an alcohol group. X is a charge balancing ion, and n=1-10.
Compounds of the formulae I-III are well known and may be prepared as described in Solar Energy Materials and Solar Cells, 57, (1999), 107-125 which is hereby incorporated by reference in its entirety. In a preferred embodiment, the adsorbed electrochromophore is bis-(2-phosphonoethyl)-4,4′-bipyridinium dichloride.
In an alternative embodiment, the reflective insulating layer 415 may be generally flat and electrical isolation of each pixel's D, E, F, and G transparent conductor 430 and semiconducting layer 460 is achieved by spatial separation, an additional isolating layer, or other isolating means. The corrosive effects of the electrolyte 420 on the driving circuits 405 are still prevented by the insulating layer 415 in this alternative configuration. Optionally, selectively sized spacer beads 455 may be used to maintain a desired spacing between the cathode 445 and the anode 450.
A frontplane substrate 465, which is substantially transparent, supports a substantially transparent conductor 470. The substrate 465 may be any suitable transparent material, such as glass or plastic. The material may be rigid or flexible. FTO, ITO, or any other suitable transparent conductor may be used for the transparent conductor 470.
A semiconducting layer 475 is deposited on the transparent conductor 470. Preferably, the semiconducting layer 475 is a nano-structured metallic oxide semiconducting film comprising Sb doped SnO2. In an alternative embodiment, the semiconducting layer 475 includes an adsorbed redox promoter for assisting oxidation and reduction of electrochromic compounds adsorbed to the semiconducting layer 460 of the cathode 445.
The electrochromic display 400 is assembled by placing the anode electrode 450 onto the cathode electrode 445, ensuring that the two electrodes 445, 450 do not touch. Preferably, a flexible seal is formed around the perimeter, ensuring that the electrodes 445, 450 do not touch. Alternatively, physical separation of the cathode electrode 445 and the anode electrode 450 may be ensured by first depositing spacer beads 455 or other spacer structures as mentioned herein. The partitions 440 formed on the insulating layer 415 may also act to maintain a separation between the cathode electrode 445 and anode electrode 450. It should be noted that the anode electrode 450 covers the entire area of the pixels D, E, F, and G and is not segmented into individual areas corresponding to the area of the pixels D, E, F, and G. An electrolyte 420 is provided between the electrodes 445, 450, preferably by back-filling in a vacuum chamber.
An electric potential applied across the cathode electrode 445 and the anode electrode 450 induces the flow of electrons in the semiconducting layer 460 having adsorbed electrochromophores. Upon oxidation and reduction, the adsorbed electrochromophores change color. Preferably, the adsorbed electrochromophores are substantially black in a reduced state and generally transparent in an oxidized state. A viewer 480 perceives a pixel containing a reduced adsorbed electrochromophore as a generally black pixel. Viewer 480 perceives a pixel containing an oxidized adsorbed electrochromophore (i.e. a transparent adsorbed electrochromophore) as the color of the underlying reflective insulating layer 415. In this manner, an active matrix electrochromic display is realized.
Alternatively, each well 435 may contain a semiconducting layer 460 having adsorbed electrochromophores that exhibit different color properties. For example, adsorbed electrochormophores that appear red, green, and blue in a reduced state and transparent in an oxidized state may be used. In this alternative embodiment, reflective insulating layer 415 is preferably white. By selectively applying a potential to each pixel, the appearance of each pixel D, E, F, and G may be switched between the colored state of the electrochromophore and the color of the underlying reflective insulating layer 415.
While the above embodiments have been described in combination with an electrochromic display device, this is merely exemplary. The inventive driving circuit may be used with any type of reflective display device, such as electrophoretic displays, electrowetting displays, dielectrophoresis displays, anisotropically rotating ball displays, and other types of reflective display devices.
Although the features and elements of the present invention are described in the preferred embodiments in particular combinations, each feature or element can be used alone without the other features and elements of the preferred embodiments or in various combinations with or without other features and elements of the present invention.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/US08/01863 | 2/13/2008 | WO | 00 | 2/12/2010 |
Number | Date | Country | |
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60889667 | Feb 2007 | US |