Claims
- 1. A method of displacing a first fluid from a well bore with an incompatible second fluid comprising the steps of:
placing a spacer fluid between said first and second fluids to separate said first and second fluids and to remove said first fluid from the walls of said well bore, said spacer fluid comprising water, a weighting material, a dispersing agent, a suspending agent and friction reducer, and fibers; and displacing said first fluid and said spacer fluid from said well bore with said second fluid.
- 2. The method of claim 1 wherein said water is selected from the group consisting of fresh water and salt water.
- 3. The method of claim 1 wherein said weighting material is selected from the group consisting of barium sulfate, hematite, manganese tetraoxide and calcium carbonate.
- 4. The method of claim 1 wherein said weighting material is barium sulfate.
- 5. The method of claim 1 wherein said weighting material is present in said spacer fluid in an amount in the range of from about 0 pounds to about 745 pounds per barrel of said water therein.
- 6. The method of claim 1 wherein said dispersing agent is selected from the group consisting of naphthalene sulfonate condensed with formaldehyde, sodium polyacrylate, a terpolymer of acrylic acid, alkyloxybenzene sulfonate and methally sulfonate, formaldehyde, acetone, bisulfate condensate, melamine sulfonate formaldehyde condensate, and mixtures thereof.
- 7. The method of claim 1 wherein said dispersing agent is naphthalene sulfonate condensed with formaldehyde.
- 8. The method of claim 1 wherein said dispersing agent is present in said spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of said water therein.
- 9. The method of claim 1 wherein said suspending agent and friction reducer is selected from the group consisting of sepiolite, whelan gum, xanthan gum, hydroxyethyl cellulose, bentonite, attapulgite, and mixtures thereof.
- 10. The method of claim 1 wherein said suspending agent and friction reducer is xanthan gum.
- 11. The method of claim 1 wherein said suspending agent and friction reducer is present in said spacer fluid in an amount in the range of from about 2 pounds to about 10 pounds per barrel of said water therein.
- 12. The method of claim 1 wherein said fibers are selected from the group consisting of polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, and other polyolefin fibers.
- 13. The method of claim 1 wherein said fibers are hydrophilic polypropylene fibers.
- 14. The method of claim 1 wherein said fibers are present in said spacer fluid in an amount in the range of from about ¼ pound to about {fraction (1/4)} pound per barrel of spacer fluid.
- 15. The method of claim 1 wherein said spacer fluid further comprises a well bore wall scouring material selected from the group consisting of diatomaceous earth, crystalline silica, amorphous silica, and mixtures thereof.
- 16. The method of claim 15 wherein said scouring material is amorphous silica.
- 17. The method of claim 15 wherein said scouring material is present in said spacer fluid in an amount in the range of from about 10 pounds to about 80 pounds per barrel of said water therein.
- 18. The method of claim 1 wherein said spacer fluid further comprises a defoamer.
- 19. The method of claim 18 wherein said defoamer comprises oil and silica.
- 20. The method of claim 18 wherein said defoamer is present in said spacer fluid in an amount in the range of from about 0.5% to about 2% by weight of said water therein.
- 21. The method of claim 1 wherein said spacer fluid further comprises a spacer mixing aid blend.
- 22. The method of claim 21 wherein said spacer mixing aid blend comprises xanthan gum, mineral oil, olephilic clay, nonylphenol with three moles of ethylene oxide, and a naphthalene sulfonate condensed with formaldehyde dispersing agent.
- 23. The method of claim 1 wherein said spacer fluid further comprises a foaming and foam stabilizing surfactant and a gas whereby said spacer fluid is foamed.
- 24. The method of claim 23 wherein said foaming and foam stabilizing surfactant is a mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant.
- 25. The method of claim 23 wherein said foaming and foam stabilizing surfactant is present in said foamed spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of said water therein.
- 26. The method of claim 23 wherein said gas is nitrogen.
- 27. The method of claim 23 wherein said gas is present in said foamed spacer fluid in an amount in the range of from about 5% to about 80% by volume of said water therein.
- 28. The method of claim 1 wherein said first fluid is a drilling fluid.
- 29. The method of claim 28 wherein said drilling fluid is selected from the group consisting of water based drilling fluids, oil based drilling fluids and foamed water based or oil based drilling fluids.
- 30. The method of claim 1 wherein said second fluid is a hydraulic cement slurry comprising water and cement.
- 31. The method of claim 30 wherein said hydraulic cement is selected from the group consisting of Portland cements, slag cements, pozzolana cements, gypsum cements, aluminous cements, silica cements and alkaline cements.
- 32. The method of claim 30 wherein said cement is Portland cement.
- 33. The method of claim 30 wherein said water is selected from the group consisting of fresh water and salt water.
- 34. A method of displacing drilling fluid from a well bore with a hydraulic cement slurry comprising the steps of:
placing a foamed spacer fluid between said drilling fluid and said hydraulic cement slurry to separate said drilling fluid from said hydraulic cement slurry and to remove drilling fluid and filter cake from the walls of said well bore, said foamed spacer fluid comprising water, a weighting material, a dispersing agent, a suspending agent and friction reducer, fibers, a foaming and foam stabilizing surfactant, and a gas whereby said spacer fluid is foamed; and displacing said drilling fluid and said foamed spacer fluid from said well bore with said hydraulic cement slurry.
- 35. The method of claim 34 wherein said water is selected from the group consisting of fresh water and salt water.
- 36. The method of claim 34 wherein said weighting material is selected from the group consisting of barium sulfate, hematite, manganese tetraoxide and calcium carbonate.
- 37. The method of claim 34 wherein said weighting material is barium sulfate.
- 38. The method of claim 34 wherein said weighting material is present in said spacer fluid in an amount in the range of from about 0 pounds to about 745 pounds per barrel of said water therein.
- 39. The method of claim 34 wherein said dispersing agent is selected from the group consisting of naphthalene sulfonate condensed with formaldehyde, sodium polyacrylate, a terpolymer of acrylic acid, alkyloxybenzene sulfonate and methally sulfonate, formaldehyde, acetone, bisulfate condensate, melamine formaldehyde condensate, and mixtures there.
- 40. The method of claim 34 wherein said dispersing agent is naphthalene sulfonate condensed with formaldehyde.
- 41. The method of claim 34 wherein said dispersing agent is present in said spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of said water therein.
- 42. The method of claim 34 wherein said suspending agent and friction reducer is selected from the group consisting of sepiolite, whelan gum, xanthan gum, hydroxyethyl cellulose, bentonite, attapulgite, and mixtures thereof.
- 43. The method of claim 34 wherein said suspending agent and friction reducer is xanthan gum.
- 44. The method of claim 34 wherein said suspending agent and friction reducer is present in said spacer fluid in an amount in the range of from about 2 pounds to about 10 pounds per barrel of said water therein.
- 45. The method of claim 34 wherein said fibers are selected from the group consisting of polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, and other polyolefin fibers.
- 46. The method of claim 34 wherein said fibers are hydrophilic polypropylene fibers.
- 47. The method of claim 34 wherein said fibers are present in said spacer fluid in an amount in the range of from about {fraction (1/16)} pound to about {fraction (1/4)} pound per barrel of spacer fluid.
- 48. The method of claim 34 wherein said foaming and foam stabilizing surfactant is a mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant.
- 49. The method of claim 34 wherein said foaming and foam stabilizing surfactant is present in said foamed spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of said water therein.
- 50. The method of claim 34 wherein said gas is nitrogen.
- 51. The method of claim 34 wherein said gas is present in said foamed spacer fluid in an amount in the range of from about 5% to about 80% by volume of said water therein.
- 52. The method of claim 34 wherein said drilling fluid is selected from the group consisting of water based drilling fluids, oil based drilling fluids and foamed water based or oil based drilling fluids.
- 53. The method of claim 34 wherein said hydraulic cement is selected from the group consisting of Portland cements, slag cements, pozzolana cements, gypsum cements, aluminous cements, silica cements and alkaline cements.
- 54. The method of claim 34 wherein said cement is Portland cement.
- 55. The method of claim 34 wherein said water in said slurry is said water is selected from the group consisting of fresh water and salt water.
- 56. A spacer fluid comprising:
water; a weighting material; a dispersing agent; a suspending agent and friction reducer; and fibers.
- 57. The spacer fluid of claim 56 wherein said water is selected from the group consisting of fresh water and salt water.
- 58. The spacer fluid of claim 56 wherein said weighting material is selected from the group consisting of barium sulfate, hematite, manganese tetraoxide and calcium carbonate.
- 59. The spacer fluid of claim 56 wherein said weighting material is barium sulfate.
- 60. The spacer fluid of claim 56 wherein said weighting material is present in said spacer fluid in an amount in the range of from about 0 pounds to about 745 pounds per barrel of said water therein.
- 61. The spacer fluid of claim 56 wherein said dispersing agent is selected from the group consisting of naphthalene sulfonate condensed with formaldehyde, sodium polyacrylate, a terpolymer of acrylic acid, alkyloxybenzene sulfonate and methally sulfonate, formaldehyde, acetone, bisulfate condensate, melamine sulfonate formaldehyde condensate, and mixtures thereof.
- 62. The spacer fluid of claim 56 wherein said dispersing agent is naphthalene sulfonate condensed with formaldehyde.
- 63. The spacer fluid of claim 56 wherein said dispersing agent is present in said spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of said water therein.
- 64. The spacer fluid of claim 56 wherein said suspending agent and friction reducer is selected from the group consisting of sepiolite, whelan gum, xanthan gum, hydroxyethyl cellulose, bentonite, attapulgite, and mixtures thereof.
- 65. The spacer fluid of claim 56 wherein said suspending agent and friction reducer is xanthan gum.
- 66. The spacer fluid of claim 56 wherein said suspending agent and friction reducer is present in said spacer fluid in an amount in the range of from about 2 pounds to about 10 pounds per barrel of said water therein.
- 67. The spacer fluid of claim 56 wherein said fibers are selected from the group consisting of polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, and other polyolefin fibers.
- 68. The spacer fluid of claim 56 wherein said fibers are hydrophilic polypropylene fibers.
- 69. The spacer fluid of claim 56 wherein said fibers are present in said spacer fluid in an amount in the range of from about {fraction (1/16)} pound to about {fraction (1/4)} pound per barrel of spacer fluid.
- 70. The spacer fluid of claim 56 wherein said spacer fluid further comprises a well bore wall scouring material selected from the group consisting of diatomaceous earth, crystalline silica, amorphous silica, and mixtures thereof.
- 71. The spacer fluid of claim 56 wherein said scouring material is amorphous silica.
- 72. The spacer fluid of claim 56 wherein said scouring material is present in said spacer fluid in an amount in the range of from about 10 pounds to about 80 pounds per barrel of said water therein.
- 73. The spacer fluid of claim 56 wherein said spacer fluid further comprises a defoamer.
- 74. The spacer fluid of claim 56 wherein said defoamer comprises oil and silica.
- 75. The spacer fluid of claim 56 wherein said defoamer is present in said spacer fluid in an amount in the range of from about 0.5% to about 2% by weight of said water therein.
- 76. A foamed spacer fluid comprising:
water; a weighting material; a dispersing agent; a suspending agent and friction reducer; fibers; a foaming and foam stabilizing surfactant; and a gas.
- 77. The foamed spacer fluid of claim 76 wherein said water is selected from the group consisting of fresh water and salt water.
- 78. The foamed spacer fluid of claim 76 wherein said weighting material is selected from the group consisting of barium sulfate, hematite, manganese tetraoxide and calcium carbonate.
- 79. The foamed spacer fluid of claim 76 wherein said weighting material is barium sulfate.
- 80. The foamed spacer fluid of claim 76 wherein said weighting material is present in said spacer fluid in an amount in the range of from about 0 pounds to about 745 pounds per barrel of said water therein.
- 81. The foamed spacer fluid of claim 76 wherein said dispersing agent is selected from the group consisting of naphthalene sulfonate condensed with formaldehyde, sodium polyacrylate, a terpolymer of acrylic acid, alkyloxybenzene sulfonate and methally sulfonate, formaldehyde, acetone, bisulfate condensate, melamine sulfonate formaldehyde condensate, and mixtures thereof.
- 82. The foamed spacer fluid of claim 76 wherein said dispersing agent is naphthalene sulfonate condensed with formaldehyde.
- 83. The foamed spacer fluid of claim 76 wherein said dispersing agent is present in said spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of said water therein.
- 84. The foamed spacer fluid of claim 76 wherein said suspending agent and friction reducer is selected from the group consisting of sepiolite, whelan gum, xanthan gum, hydroxyethyl cellulose, bentonite, attapulgite, and mixtures thereof.
- 85. The foamed spacer fluid of claim 76 wherein said suspending agent and friction reducer is xanthan gum.
- 86. The foamed spacer fluid of claim 76 wherein said suspending agent and friction reducer is present in said spacer fluid in an amount in the range of from about 2 pounds to about 10 pounds per barrel of said water therein.
- 87. The foamed spacer fluid of claim 76 wherein said fibers are selected from the group consisting of polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, and other polyolefin fibers.
- 88. The foamed spacer fluid of claim 76 wherein said fibers are hydrophilic polypropylene fibers.
- 89. The foamed spacer fluid of claim 76 wherein said fibers are present in said spacer fluid in an amount in the range of from about {fraction (1/16)} pound to about {fraction (1/4)} pound per barrel of said spacer fluid.
- 90. The foamed spacer fluid of claim 76 wherein said spacer fluid further comprises a well bore wall scouring material selected from the group consisting of diatomaceous earth, crystalline silica, amorphous silica, and mixtures thereof.
- 91. The foamed spacer fluid of claim 76 wherein said scouring material is amorphous silica.
- 92. The foamed spacer fluid of claim 76 wherein said scouring material is present in said spacer fluid in an amount in the range of from about 10 pounds to about 80 pounds per barrel of said water therein.
- 93. The foamed spacer fluid of claim 76 wherein said foaming and foam stabilizing surfactant is a mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant.
- 94. The foamed spacer fluid of claim 76 wherein said foaming and foam stabilizing surfactant is present in said foamed spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of said water therein.
- 95. The foamed spacer fluid of claim 76 wherein said gas is nitrogen.
- 96. The foamed spacer fluid of claim 76 wherein said gas is present in said foamed spacer fluid in an amount in the range of from about 5% to about 80% by volume of said water therein.
- 97. A method of displacing fluids in a well bore comprising:
placing a foamed spacer fluid comprising fibers between first and second fluids; and displacing said first fluid and said spacer fluid from the well bore with said second fluid.
- 98. The method of claim 97 wherein said spacer fluid comprises water selected from the group consisting of fresh water and salt water.
- 99. The method of claim 97 wherein said spacer fluid comprises a weighting material selected from the group consisting of barium sulfate, hematite, manganese tetraoxide and calcium carbonate.
- 100. The method of claim 99 wherein said weighting material is present in said spacer fluid in an amount in the range of from about 0 pounds to about 745 pounds per barrel of said water therein.
- 101. The method of claim 97 wherein said spacer fluid comprises a dispersing agent selected from the group consisting of naphthalene sulfonate condensed with formaldehyde, sodium polyacrylate, a terpolymer of acrylic acid, alkyloxybenzene sulfonate and methally sulfonate, formaldehyde, acetone, bisulfate condensate, melamine sulfonate formaldehyde condensate, and mixtures thereof.
- 102. The method of claim 101 wherein said dispersing agent is present in said spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of said water therein.
- 103. The method of claim 97 wherein said spacer fluid comprises a suspending agent and friction reducer selected from the group consisting of sepiolite, whelan gum, xanthan gum, hydroxyethyl cellulose, bentonite, attapulgite, and mixtures thereof.
- 104. The method of claim 103 wherein said suspending agent and friction reducer is present in said spacer fluid in an amount in the range of from about 2 pounds to about 10 pounds per barrel of said water therein.
- 105. The method of claim 97 wherein said spacer fluid comprises fibers selected from the group consisting of polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, hydrophilic polypropylene fibers, and other polyolefin fibers.
- 106. The method of claim 105 wherein said fibers are present in said spacer fluid in an amount in the range of from about ¼ pound to about {fraction (1/4)} pound per barrel of spacer fluid.
- 107. The method of claim 97 wherein said spacer fluid further comprises a well bore wall scouring material selected from the group consisting of diatomaceous earth, crystalline silica, amorphous silica, and mixtures thereof.
- 108. The method of claim 107 wherein said scouring material is amorphous silica.
- 109. The method of claim 107 wherein said scouring material is present in said spacer fluid in an amount in the range of from about 10 pounds to about 80 pounds per barrel of said water therein.
- 110. The method of claim 97 wherein said spacer fluid further comprises a defoamer.
- 111. The method of claim 110 wherein said defoamer comprises oil and silica.
- 112. The method of claim 110 wherein said defoamer is present in said spacer fluid in an amount in the range of from about 0.5% to about 2% by weight of said water therein.
- 113. The method of claim 97 wherein said spacer fluid further comprises a spacer mixing aid blend.
- 114. The method of claim 113 wherein said spacer mixing aid blend comprises xanthan gum, mineral oil, olephilic clay, nonylphenol with three moles of ethylene oxide, and a naphthalene sulfonate condensed with formaldehyde dispersing agent.
- 115. The method of claim 97 wherein said spacer fluid further comprises a foaming and foam stabilizing surfactant and a gas whereby said spacer fluid is foamed.
- 116. The method of claim 115 wherein said foaming and foam stabilizing surfactant is a mixture of an ethoxylated alcohol ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant and an alkyl or alkene amidopropyl dimethyl amine oxide surfactant.
- 117. The method of claim 115 wherein said foaming and foam stabilizing surfactant is present in said foamed spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of said water therein.
- 118. The method of claim 115 wherein said gas is nitrogen.
- 119. The method of claim 115 wherein said gas is present in said foamed spacer fluid in an amount in the range of from about 5% to about 80% by volume of said water therein.
- 120. The method of claim 97 wherein said first fluid is a drilling fluid.
- 121. The method of claim 120 wherein said drilling fluid is selected from the group consisting of water based drilling fluids, oil based drilling fluids and foamed water based or oil based drilling fluids.
- 122. The method of claim 97 wherein said second fluid is a hydraulic cement slurry comprising water and cement.
- 123. The method of claim 122 wherein said hydraulic cement is selected from the group consisting of Portland cements, slag cements, pozzolana cements, gypsum cements, aluminous cements, silica cements and alkaline cements.
- 124. The method of claim 122 wherein said water is selected from the group consisting of fresh water and salt water.
- 125. A well completion fluid comprising a foamed spacer fluid containing fibers.
- 126. The fluid of claim 125 wherein said spacer fluid comprises water selected from the group consisting of fresh water and salt water.
- 127. The fluid of claim 125 wherein said spacer fluid comprises a weighting material selected from the group consisting of barium sulfate, hematite, manganese tetraoxide and calcium carbonate.
- 128. The fluid of claim 127 wherein said weighting material is present in said spacer fluid in an amount in the range of from about 0 pounds to about 745 pounds per barrel of said water therein.
- 129. The fluid of claim 125 wherein said spacer fluid comprises a dispersing agent selected from the group consisting of naphthalene sulfonate condensed with formaldehyde, sodium polyacrylate, a terpolymer of acrylic acid, alkyloxybenzene sulfonate and methally sulfonate, formaldehyde, acetone, bisulfate condensate, melamine sulfonate formaldehyde condensate, and mixtures thereof.
- 130. The fluid of claim 129 wherein said dispersing agent is present in said spacer fluid in an amount in the range of from about 0.5% to about 5% by weight of said water therein.
- 131. The fluid of claim 125 wherein said spacer fluid comprises a suspending agent and friction reducer selected from the group consisting of sepiolite, whelan gum, xanthan gum, hydroxyethyl cellulose, bentonite, attapulgite, and mixtures thereof.
- 132. The fluid of claim 131 wherein said suspending agent and friction reducer is present in said spacer fluid in an amount in the range of from about 2 pounds to about 10 pounds per barrel of said water therein.
- 133. The fluid of claim 125 wherein said fibers are selected from the group consisting of polyester fibers, polyamide fibers, polyethylene fibers, polypropylene fibers, hydrophilic polypropylene fibers, and other polyolefin fibers.
- 134. The fluid of claim 125 wherein said fibers are present in said spacer fluid in an amount in the range of from about {fraction (1/16)} pound to about {fraction (1/4)} pound per barrel of spacer fluid.
- 135. The fluid of claim 125 wherein said spacer fluid further comprises a well bore wall scouring material selected from the group consisting of diatomaceous earth, crystalline silica, amorphous silica, and mixtures thereof.
- 136. The fluid of claim 135 wherein said scouring material is amorphous silica.
- 137. The fluid of claim 135 wherein said scouring material is present in said spacer fluid in an amount in the range of from about 10 pounds to about 80 pounds per barrel of said water therein.
- 138. The fluid of claim 125 wherein said spacer fluid further comprises a defoamer.
- 139. The fluid of claim 138 wherein said defoamer comprises oil and silica.
- 140. The fluid of claim 138 wherein said defoamer is present in said spacer fluid in an amount in the range of from about 0.5% to about 2% by weight of said water therein.
CROSS REFERENCE TO RELATED APPLICATIONS
[0001] This application is a continuation-in-part of U.S. application Ser. No. 10/393,965 filed on Mar. 21, 2003.
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
10393965 |
Mar 2003 |
US |
Child |
10740189 |
Dec 2003 |
US |