Patent Application
20130139546
The present invention relates to a method and apparatus for separating air in which oxygen and nitrogen products are produced as co-products by rectifying compressed and purified air in a main distillation column to produce the nitrogen product and stripping crude liquid oxygen formed in the main distillation column within an auxiliary distillation column to produce the oxygen product.
Nitrogen is typically obtained at high purity by separating nitrogen from air within a cryogenic air separation plant often employing a single distillation column. In such a plant, air is compressed and then purified of higher boiling contaminants to produce a compressed and purified air stream. The compressed and purified air stream is then cooled to a temperature suitable for its cryogenic rectification within a main heat exchanger and then introduced into a single distillation column operating at about 3 bara or higher. The air, within the distillation column, is rectified to produce a nitrogen-rich vapor column overhead and an oxygen-rich liquid column bottoms known as crude liquid oxygen or kettle liquid. The oxygen-rich liquid is depressurized in an expansion valve and then introduced into a heat exchanger to condense a stream of the nitrogen-rich vapor column overhead and thereby produce liquid nitrogen to reflux the distillation column. The oxygen-rich liquid that is partially vaporized can be used to generate refrigeration for the plant or alternatively, refrigeration can be provided to the plant through liquid nitrogen addition to the main column or a stream entering the main heat exchanger.
In general, oxygen is not recovered from such single column nitrogen plants. However, there is an interest in also recovering oxygen from such plants. For example, float glass production typically requires nitrogen and low purity oxygen in a flow ratio of approximately 2:1. The oxygen is employed in the glass furnace to boost recovery and is typically required at a low purity of between 90 and 95 percent and at a pressure of between 10 and 20 psig. While such oxygen can be provided by a separate vacuum pressure swing adsorption plant or through the vaporization of delivered on-site liquid, the added expense is not justifiable. It is to be noted that both oxygen and nitrogen can be produced by a typical double column air separation plant having high and low pressure columns operatively associated in a heat transfer relationship. However, such a plant is not economical where, for example, float glass is to be produced because of the requirement of product compression and higher initial capital cost. The incremental modification of a small single column nitrogen plant to deliver both nitrogen and oxygen products can economically meet the requirements of processes such as float glass production where the nitrogen and oxygen products are required at pressure and at modest flow rate, for example less than 100 kcfh of nitrogen.
In the prior art, there are examples of single column nitrogen plants that have been modified to co-produce both nitrogen and oxygen products. For example, in U.S. Pat. No. 4,783,210, a stream of the crude liquid oxygen column bottoms is partially vaporized in a heat exchanger used in condensing a stream of the nitrogen-rich vapor column overhead produced in a distillation column. The resulting nitrogen rich liquid is used to reflux the column. A stream of the resulting liquid phase produced by the partial vaporization of the crude liquid oxygen is then stripped in a secondary or auxiliary distillation column to produce a column bottoms, rich in oxygen, that can be taken as an oxygen product. The auxiliary distillation column is reboiled with another stream of the nitrogen-rich vapor which condenses in the reboiling and can be taken as a liquid nitrogen product and also, used to reflux the distillation column.
U.S. Pat. No. 5,074,898 discloses a single column nitrogen generator with an auxiliary distillation column to produce an oxygen product. In this patent, a crude liquid oxygen stream generated in a main distillation column is stripped in an auxiliary distillation column. The auxiliary distillation column is reboiled with a stream of the nitrogen-rich vapor column overhead produced in the main distillation column. This condenses the nitrogen-rich vapor to produce reflux for the main distillation column. Residual liquid generated in the auxiliary distillation column can be taken as a liquid product along with part of the condensed nitrogen vapor.
In both of these patents, the column bottoms is being used to condense nitrogen, it necessarily must be at a lower pressure than the nitrogen to accomplish nitrogen condensation. As a result, the oxygen product is also at low pressure. Furthermore, since part of the column bottoms is being taken as a product, there will be less bottoms fluid to condense nitrogen. Consequently, nitrogen production is limited. As will be discussed, the present invention provides a method and apparatus for producing nitrogen and oxygen co-products, that among other advantages, may allow the oxygen product to be produced at elevated pressure. In another aspect of the present invention, the auxiliary column bottoms is subjected to a staged vaporization to enable a greater fraction of oxygen to be obtained at lower power relative those processes contemplated in the prior art.
The present invention relates to a method of separating air to produce oxygen and nitrogen co-products. In accordance with such method, a compressed and purified stream is cooled. The compressed and purified stream is at least partially condensed and rectified within a main distillation column to produce a nitrogen-rich vapor column overhead and crude liquid oxygen. A crude liquid oxygen stream, composed of the crude liquid oxygen, is depressurized and then stripped within an auxiliary distillation column with an ascending stripping gas to produce a column overhead and an oxygen-rich liquid. The oxygen-rich liquid is partially vaporized through indirect heat exchange with a nitrogen-rich vapor stream composed of the nitrogen-rich vapor column overhead, thereby producing a liquid nitrogen stream, the stripping gas and a residual oxygen-rich liquid.
The main distillation column is refluxed with at least part of the liquid nitrogen stream. The at least partial condensation of the compressed and purified stream is achieved through indirect heat exchange with a liquid oxygen enriched stream, produced from the residual oxygen-rich liquid. An oxygen product stream is formed, at least in part, from the liquid oxygen enriched stream, after having indirectly exchanged heat with the compressed and purified stream. A nitrogen product stream is formed from the nitrogen-rich vapor and a waste stream is formed from the auxiliary column overhead. The oxygen product stream, the nitrogen product stream and a waste stream are passed in indirect heat exchange with the compressed and purified stream.
As can be appreciated from the above discussion, since the oxygen product stream is formed from at least part of the liquid oxygen enriched stream that is in turn produced from the residual oxygen-rich liquid, the production of the oxygen product is no longer directly coupled to the production of reflux nitrogen to the main distillation column. This allows the liquid oxygen enriched stream to be at a higher pressure since it does not have to be at a sufficiently low pressure to condense the nitrogen. As such, the oxygen product can be produced at a higher pressure.
The oxygen-rich liquid can be collected within the auxiliary distillation column. The oxygen-rich liquid is partially vaporized by passing an oxygen-rich liquid stream and the at least part of the nitrogen-rich vapor through a once-through heat exchanger to form the stripping gas and the residual oxygen-rich liquid that collects as a column bottoms of the auxiliary distillation column and the liquid nitrogen stream. The term, “once-through heat exchanger” as used herein and in the claims means a heat exchanger, well known in the art, in which the nitrogen-rich vapor and the resulting nitrogen-rich liquid are introduced into heat exchange passages by means of headers and the oxygen-rich liquid stream is introduced into adjoining heat exchange passages, either in an up-flow or down-flow direction. The partially vaporized exit stream is allowed to disengage such that the stripping gas may ascend the auxiliary column and the liquid fraction can be collected as the liquid product oxygen stream. Unlike a thermosiphon heat exchanger, the heat exchange passages are not partially submerged in liquid, there can be a greater temperature difference between the condensing vapor and the vaporizing liquid. Consequently, the main distillation column can be operated at lower pressure and therefore require less compression of the incoming air thereby saving on energy cost.
The compressed and purified stream can be at least partially condensed in a condenser located in a main distillation column bottom region such that condensed air mixes with downcoming liquid produced by rectification to thereby produce the crude liquid oxygen as a column bottoms of the main distillation column.
A stream of the residual oxygen-rich liquid can be collected in a separation vessel and the liquid oxygen enriched stream can be formed of a liquid phase produced within the separation vessel. The liquid phase is partially vaporized in the condenser to produce a two-phase stream and liquid and vapor phases of the two phase stream are disengaged within the separation vessel to form a vapor phase and a liquid phase together with the stream of the residual oxygen-rich liquid collected in the separation vessel. The oxygen product stream is formed from a vapor phase stream composed of the vapor phase.
The liquid nitrogen reflux stream can be formed from part of the liquid nitrogen stream. A further part of the liquid nitrogen stream and the waste stream indirectly exchange heat with the crude liquid oxygen stream such that the crude liquid oxygen stream is subcooled prior to being depressurized. The further part of the liquid nitrogen stream is also warmed in indirect heat exchange with the compressed and purified stream.
The liquid oxygen enriched stream is pressurized such that the oxygen product stream is also pressurized. Additionally, in any embodiment of the present invention, a liquid nitrogen refrigeration stream can be introduced into the main distillation column to impart refrigeration.
The present invention also provides a method of separating air to produce oxygen and nitrogen co-products in which after the compressed and purified stream comprising the air is cooled, the compressed and purified stream is rectified within a main distillation column to produce a nitrogen-rich vapor column overhead and a crude liquid oxygen column bottoms. A crude liquid oxygen stream, composed of the crude liquid oxygen column bottoms, is depressurized and then stripped within an auxiliary distillation column with an ascending stripping gas to produce a column overhead and an oxygen-rich liquid. The oxygen-rich liquid can be collected and partially vaporized through indirect heat exchange with at least part of a nitrogen-rich vapor stream, composed of the nitrogen-rich vapor column overhead, in a once-through heat exchanger thereby producing a liquid nitrogen stream, the stripping gas and a residual oxygen-rich liquid.
Heat is indirectly exchanged between the residual oxygen-rich liquid and a gaseous stream having a nitrogen concentration no less than that of air. The heat exchange condenses the gaseous stream to produce a liquid condensate stream and partially vaporizes the residual oxygen-rich liquid into a liquid fraction and a vapor fraction. The main distillation column is refluxed with at least part of the liquid nitrogen stream and at least part of the liquid condensate stream is introduced into the main distillation column. An oxygen product stream is formed from the vapor fraction, a nitrogen product stream is formed from the nitrogen-rich vapor column overhead and a waste stream is formed from the column overhead produced in the auxiliary distillation column. The oxygen product stream, the nitrogen product stream and the waste stream are passed in indirect heat exchange with the compressed and purified stream.
In this forgoing aspect of the present invention since the oxygen-rich liquid is partially vaporized through indirect heat exchange with at least part of a first nitrogen-rich vapor stream, composed of the nitrogen-rich vapor column overhead, in a once-through heat exchanger, energy savings can be realized for reasons set forth above. The resulting first liquid nitrogen stream will, at least in part form reflux to the main distillation column and the liquid oxygen enriched stream can be used to produce both the product and a second liquid nitrogen stream that can at least in part be used in also refluxing the main distillation column. This staged condensation of the nitrogen vapor allows more reflux to be produced for the main distillation column and therefore, a greater throughput and consequent nitrogen production.
The gaseous stream can be composed of the nitrogen-rich vapor column overhead. The heat is indirectly exchanged between the residual oxygen-rich liquid and the gaseous stream by depressurizing a liquid oxygen enriched stream, composed of the residual oxygen-rich liquid, and the liquid oxygen enriched stream is passed in indirect heat exchange with the gaseous stream. The condensate stream is introduced into the main distillation column as reflux along with the liquid nitrogen stream.
The heat can be indirectly exchanged from the liquid oxygen enriched stream and the second nitrogen-rich vapor stream within a thermo-siphon reboiler and the liquid fraction and the vapor fraction collect in a shell of the thermo-siphon reboiler. The waste stream can pass in indirect heat exchange with the crude liquid oxygen stream prior to the depressurization of the crude liquid oxygen stream so that the crude liquid oxygen stream is subcooled.
The present invention also provides an apparatus for separating air to produce oxygen and nitrogen co-products. Such apparatus comprises a main heat exchanger configured to cool a compressed and purified stream comprising the air. A means is provided for at least partially condensing the compressed and purified stream along with a main distillation column configured to rectify the compressed and purified stream to produce a nitrogen-rich vapor column overhead. The compressed and purified stream and at least partial condensing means is connected to the main heat exchanger and operatively associated with the main distillation column such that the compressed and purified stream is rectified after having been cooled and at least partially condensed and crude liquid oxygen is produced from the at least partial condensing of the compressed and purified stream and the rectification of the compressed and purified stream.
An expansion valve is positioned between the main distillation column and an auxiliary distillation column such that a crude liquid oxygen stream composed of the crude liquid oxygen is depressurized prior to introduction into the auxiliary distillation column. The auxiliary distillation column is configured such that the crude liquid oxygen stream is stripped with an ascending stripping gas within the auxiliary distillation column to produce a column overhead and an oxygen-rich liquid. A means is provided for partially vaporizing the oxygen-rich liquid through indirect heat exchange with a nitrogen-rich vapor stream composed of the nitrogen-rich vapor column overhead and a liquid nitrogen stream, the stripping gas and a residual oxygen-rich liquid are thereby produced.
The oxygen-rich liquid partial vaporization means is connected to the main distillation column such that the main distillation column is refluxed with at least part of the liquid nitrogen stream. The compressed and purified at least partial condensing means is connected to the auxiliary distillation column such that the at least partial condensing of the compressed and purified stream is conducted by indirectly exchanging heat from the compressed and purified stream to a liquid oxygen enriched stream, composed of the residual oxygen-rich liquid. A means is provided for forming an oxygen product stream from the liquid oxygen enriched stream after having indirectly exchanged heat with the compressed and purified stream. The main heat exchanger is connected to the oxygen product stream forming means, the auxiliary distillation column and at least one of the oxygen-rich liquid partial vaporization means and the main distillation column such that the oxygen product stream, a nitrogen product stream, formed from the nitrogen-rich vapor column overhead, and a waste stream, composed of the column overhead of the auxiliary distillation column, pass within the main heat exchanger, in indirect heat exchange with the compressed and purified stream.
The auxiliary distillation column can have means for collecting the oxygen-rich liquid. The oxygen-rich liquid partial vaporization means can be a once-through heat exchanger connected to the oxygen-rich liquid collecting means such that the oxygen-rich liquid is partially vaporized within the once-through heat exchanger through passage of an oxygen-rich liquid stream composed of the oxygen-rich liquid and the residual oxygen-rich liquid collects as a column bottoms of the auxiliary distillation column. The main distillation column is connected to the once-through heat exchanger such that the nitrogen-rich vapor stream is condensed within the once-through heat exchanger.
The condenser can be located in a bottom region of the main distillation column such that condensed air mixes with downcoming liquid produced by the rectifying of the compressed and purified stream to produce the crude liquid oxygen as a column bottoms in the main distillation column.
The at least one oxygen product stream forming means can be a separation vessel connected to the auxiliary distillation column such that a stream of the residual oxygen-rich liquid is collected in a separation vessel. The separation vessel is connected to the condenser so that the liquid oxygen enriched stream is formed of a liquid phase produced within the separation vessel and is partially vaporized in the condenser to produce a two-phase stream that is introduced into the separation vessel. Liquid and vapor phases of the two phase stream are disengaged within the separation vessel to form a vapor phase and a liquid phase together with the stream of the residual oxygen-rich liquid collected in the separation vessel. The main heat exchanger is connected to the separation vessel so that the oxygen product stream is formed from a vapor phase stream composed of the vapor phase.
The once-through heat exchanger can be connected to the main distillation column such that the main distillation column is refluxed with a part of the liquid nitrogen stream. A subcooling heat exchanger is connected to the once-through heat exchanger, the auxiliary distillation column and the expansion valve such that a further part of the liquid nitrogen stream and the waste stream indirectly exchange heat with the crude liquid oxygen stream within the subcooling heat exchanger and the crude liquid oxygen stream is subcooled prior to passage through the expansion valve. The further part of the liquid nitrogen stream also passes through the main heat exchanger in indirect heat exchange with the compressed and purified stream.
The present invention also provides an apparatus for separating air to produce oxygen and nitrogen co-products in which a main heat exchanger is configured to cool a compressed and purified stream comprising the air and a main distillation column is connected to the main heat exchanger. The main distillation column is configured to rectify the compressed and purified stream to produce a nitrogen-rich vapor column overhead and a crude liquid oxygen column bottoms. An auxiliary distillation column is in flow communication with the main distillation column and configured to strip a crude liquid oxygen stream composed of the crude liquid oxygen column bottoms with an ascending stripping gas to produce a column overhead and an oxygen-rich liquid. The auxiliary distillation column has means for collecting the oxygen-rich liquid. An expansion valve is positioned between the auxiliary distillation column and the main distillation column to depressurize the crude liquid oxygen stream. A once-through heat exchanger is connected to the collection means and the main distillation column such that the oxygen-rich liquid is partially vaporized through indirect heat exchange with at least part of a nitrogen-rich vapor stream, composed of the nitrogen-rich vapor column overhead, thereby producing a liquid nitrogen stream, the stripping gas and a residual oxygen-rich liquid.
A means is provided for indirectly exchanging heat between the residual oxygen-rich liquid and a gaseous stream having a nitrogen concentration no less than that of the air. This condenses the gaseous stream to produce a liquid condensate stream and partially vaporizes the residual oxygen-rich liquid into a liquid fraction and a vapor fraction. The once-through heat exchanger and the indirect heat exchange means are in flow communication with the main distillation column such that the main distillation column is refluxed with at least part of the liquid nitrogen stream.
The main heat exchanger is also connected to the indirect heat exchange means, the main distillation column and the auxiliary distillation column such that an oxygen product stream, formed from the vapor fraction, a nitrogen product stream, formed from the nitrogen-rich vapor column overhead and a waste stream, formed from the column overhead produced in the auxiliary distillation column, pass within the main heat exchanger, in indirect heat exchange with the compressed and purified stream.
The indirect heat exchange means can be connected to the main distillation column so that the gaseous stream is composed of the nitrogen-rich vapor column overhead and the condensate stream is introduced into the main distillation column as reflux along with the liquid nitrogen stream. The once-through heat exchanger is connected to the auxiliary distillation column so that the residual oxygen-rich liquid collects within the auxiliary distillation column and the indirect heat exchange means is connected to the auxiliary column so that a liquid oxygen-enriched stream, composed of the residual oxygen-rich liquid, passes in indirect heat exchange with the gaseous stream. Another expansion valve is positioned between the auxiliary column and the indirect heat exchange means for depressurizing the liquid oxygen-enriched stream.
The indirect heat exchange means can be a thermo-siphon reboiler having a shell within which the liquid fraction and the vapor fraction collect. A subcooling heat exchanger can be positioned between the auxiliary distillation column, the main distillation column and the main heat exchanger such that the waste stream passes in indirect heat exchange with the crude liquid oxygen stream prior to the depressurization of the crude liquid oxygen stream and prior to the warming the waste stream in the main heat exchanger.
In any embodiment of the present invention, the main distillation column can be provided with a top inlet for introduction of a liquid nitrogen refrigeration stream to impart refrigeration.
While the present invention concludes with claims distinctly pointing out the subject matter that Applicants regard as their invention, it is believed that the present invention will be better understood when taken in connection with the accompanying drawings in which:
With reference to
A compressed and purified air stream 10 is cooled in a main heat exchanger 12 to a temperature suitable for its rectification at or near saturation. As can be appreciated, air separation plant 1 could be part of an installation requiring compressed air and as such, compressed and purified air stream 10 could be formed from part of the air produced in such installation. Alternatively, such stream could be generated by compressing the air, typically from between 70 psia to 90 psia, and then purifying the air of higher boiling contaminants that would solidify or concentrate at cryogenic temperatures; for instance, carbon dioxide, water vapor and hydrocarbons. Main heat exchanger 12 can be of conventional brazed aluminum plate fin construction. As would occur to those skilled in the art, main heat exchanger 12 could be formed from a plurality of units operating in parallel.
The compressed and purified air stream 10, after having been cooled, is introduced into a condenser 14 located in a bottom region 16 of a main distillation column 18. Distillation column 18 contains mass-transfer contacting elements such as trays, structured packing, random packing or a combination of such elements that are generally indicated by reference numeral 20. Preferably, the incoming air is partially condensed within condenser 14 to produce a vapor fraction 22 that ascends into the mass-transfer contacting elements 20 to contact a descending liquid phase that produces a nitrogen-rich vapor column overhead 23. Nitrogen-rich vapor column overhead 23 will typically be essentially pure nitrogen. The partial condensation of the air produces a liquid fraction 24 that constitutes about 20 percent of the incoming air and collects along with the liquid that has descending within elements 20 within the bottom region 16 of main distillation column 18 as crude liquid oxygen 26.
It is to be noted, alternative means for condensing the incoming air would be to locate condenser 14 outside of the main distillation column 18. In connection with such means, the liquid fraction 24 and the liquid having descended within distillation column 20 could be separately combined to form the crude liquid oxygen 26 or they could be subcooled and fed separately to column 34. In another such means, the compressed and purified air stream could be introduced directly into the main distillation column shell. The air would be allowed to mix with vapor within the column and the recirculated vapor 22 from the condenser 14. In such configuration, the condenser would have no condensing-side headering, namely, the gas would simply be induced to flow into the exchanger through condensation. As a further alternative, a portion of the cooled air stream 10 could be directed to the shell of column 18 and a portion piped directly to condenser 14. Such a configuration would allow a modulation of the product oxygen and nitrogen flows. Such a configuration would require additional valves and control means. A further means would be to employ a separate stream of air that could be further compressed. The separate air stream would be split at either the warm end, if further compressed, or if not so compressed, at the cold end. The stream would then be totally condensed within the condenser 14. The condensed air would then be introduced into an interstage location of the main distillation column 18 through suitable piping. The condensed air would not be collected in the sump of the column and instead, liquefied air would be fed several stages up from the bottom of the main distillation column 14.
A crude liquid oxygen stream 28 composed of the crude liquid oxygen 26 is then preferably subcooled within a subcooling heat exchanger 30 and depressurized within an expansion valve 32, positioned between the main distillation column 18 and the auxiliary column 34, to a pressure of preferably 15 to 25 psia. The crude liquid oxygen stream 28 is then stripped within an auxiliary distillation column 34 by contacting such stream with an ascending stripping gas stream 52 within mass transfer contacting elements 36 that could be trays, structured packing, random packing or a combination of such elements. The stripping produces a column overhead 38 that typically contains between 80 percent to 90 percent by volume of nitrogen and a residual oxygen-rich liquid 40 that typically contains 85 percent to 98 percent by volume of oxygen.
The oxygen-rich liquid 40 can be collected within a collection tray 42 or by similar means in which downcoming liquid is collected and rising vapor is allowed to pass through and into the mass transfer contacting elements 36. A stream of the oxygen-rich liquid 44, composed of the oxygen-rich liquid 40, is partially vaporized through indirect heat exchange with a nitrogen-rich vapor stream 46 composed of the nitrogen-rich vapor 23 within a once-through heat exchanger 48. As a result of the indirect heat exchange, a liquid nitrogen stream 50 is produced. The stream of the oxygen-rich liquid 44 is partially vaporized to produce the stripping gas 52 and a residual gas liquid stream 54 that collects in the bottom of the auxiliary distillation column 34 as a residual oxygen-rich liquid 56.
As an alternative means to the once-through heat exchanger 48 and the collection tray 42, a thermosiphon reboiler situated in the base of the auxiliary column 34 could be employed to partially vaporize the oxygen-rich liquid 40 falling from the mass-transfer contacting elements 36 into the base of the auxiliary column 34. The core of such reboiler would sit within the residual oxygen-rich liquid and produce the stripping gas through vaporization of the oxygen-rich liquid 40. This would not, however, be preferred given that such a heat exchanger would not operate with the temperature differences of a once-through heat exchanger; and consequently, the incoming air would have to be compressed to a higher pressure.
The liquid nitrogen stream 50, in its entirely, or a part thereof, as illustrated, can be introduced into the main distillation column 18 as a reflux stream 58. The remainder, as a further liquid nitrogen stream (depressurized through valve 63) and a column overhead stream 62, composed of the column overhead 38, can be first introduced into subcooling heat exchanger 30 in indirect heat exchange with the crude liquid oxygen stream 28 for purposes of the subcooling thereof and then passed in indirect heat exchange with the incoming compressed and purified air stream 10 to help cool the same within the main heat exchanger 12. Alternatively, stream 60 and stream 62 may be combined and warmed. After having been warmed, the further liquid nitrogen stream 60 would be discharged from main heat exchanger 12 as a gaseous nitrogen co-product (“N2”) and the column overhead stream 62 would be discharged as a waste stream (“Waste”). Such a waste stream could be used in the regeneration of adsorbents employed in a pre-purification unit used to pre-purify the incoming air and used in connection with air separation plant 1. Furthermore, it is also possible to recycle all or part of such stream by recompressing it and combining it with the incoming air. It should be noted that utilization of stream 60 is optional, the vaporization of liquid nitrogen stream 60 serves to provide additional subcooling too stream 28 and hence enables greater oxygen production.
It should be noted that liquid nitrogen reflux stream 60 could be extracted from an interstage location of column 20 prior to passage through valve 63.
It is to be noted that the subcooling heat exchanger 30 or 30′ to be discussed could be integrated with the main heat exchanger 12. It is equally possible that an embodiment of the present invention could be constructed without the use of such subcooling heat exchangers 30 or 30′. In any case, in the illustrated embodiment, the further liquid nitrogen stream 60 can be depressurized in an expansion valve 63 before passing through subcooling heat exchanger 30 and main heat exchanger 12.
The nitrogen co-product is obtained by warming a nitrogen-rich vapor stream 64, composed of the nitrogen-rich vapor column overhead 23, within the main heat exchanger 12, through indirect heat exchange with the incoming compressed and purified air stream 10 to also help cool the same. As illustrated, nitrogen-rich vapor stream 64 and nitrogen-rich vapor stream 46 are produced by dividing a nitrogen-rich vapor stream 66 removed from the top of main distillation column 18 into the two foregoing streams. However, the nitrogen-rich vapor stream 64 and the nitrogen-rich vapor stream 46 could be separately removed from the main distillation column 18. It is to be noted that since all of the liquid nitrogen stream 50 could be introduced into the main distillation column 18 as reflux, the nitrogen co-product could be formed solely from the warmed nitrogen-rich vapor stream 64.
The oxygen co-product is produced by removing a stream of the residual oxygen-enriched liquid 68, composed of the residual oxygen-rich liquid 56, and introducing such stream into a separation vessel 70. A liquid oxygen-enriched stream 72, composed of the liquid phase 74, is partially vaporized in the condenser 14 to produce a two-phase stream 76 through indirect heat exchange with the incoming compressed and purified air stream 10, thereby partially condensing the compressed and purified air stream 10. Liquid and vapor phases of the two phase stream 76 are disengaged within the separation vessel to form a vapor phase and the liquid phase 74 produced by the disengagement with the stream and addition of the residual oxygen-rich liquid 68. A control valve (not shown) may be employed to modulate the operating pressure of vessel 70. The oxygen product stream is formed from a vapor phase stream 80 composed of the vapor phase 78. A drain stream 82 that is passed through a valve 84 can optionally be collected as a liquid product (or directed as a contaminant drain vaporizer). Alternatively a portion of stream 68 may be extracted as liquid product and sent to suitable storage.
It is to be noted that the stream of the residual oxygen-rich liquid 68 can be pressurized as a result of the auxiliary distillation column 34 being situated at a height above the main distillation column 18. This results in a pressurized oxygen product. A yet further alternative, is to pressurize the stream of the residual oxygen-rich liquid by means of a mechanical pump or the use of the pump in connection with the liquid head produced by situating the auxiliary distillation column 34 above the main distillation column 18.
As illustrated, condenser 14 acts as a thermosiphon. As an alternative means for forming the oxygen product, it is possible that separation vessel 70 could be constructed to house the condenser 14. However, it is believed that the illustrated embodiment is more cost effective to such an arrangement. Additionally, if more than roughly 20 percent of the oxygen product were to be taken as a liquid product by way of drain stream 82, then it would be possible to reconfigure the condenser 14 as a once-through heat exchanger with a potential further savings in power consumption. In such an arrangement, the stream of the residual oxygen-rich liquid 68 would be piped directly to the condenser 14. The partially vaporized product would then be separated in a phase separation vessel and there would not be a return stream, such as oxygen-enriched liquid stream being introduced into the condenser 14.
With reference to
In air separation plant 2, the compressed and purified air stream 10 after having been cooled within main heat exchanger 12 is introduced into main distillation column 20 and rectified to produce a nitrogen-rich vapor column overhead 23 and a crude liquid oxygen column bottoms 26′. A crude liquid oxygen stream 28′ can optionally be subcooled in a subcooling unit 30′ and stripped within auxiliary distillation column 34 after having been depressurized within expansion valve 32. A first nitrogen-rich vapor stream 46′ is condensed in the once-through heat exchanger 48 to produce a first liquid nitrogen stream 50 and residual oxygen-rich liquid 56 in the manner described with respect to air separation plant 1. The resulting stream of the residual oxygen-rich liquid 68 produced in auxiliary distillation column 34 is introduced into a thermosiphon reboiler 86 after having been depressurized in an expansion valve 90. The stream of the residual oxygen-rich liquid 68 is partially vaporized through indirect heat exchange with a gaseous stream 92 that can be composed of the nitrogen-rich vapor column overhead 23 of main distillation column 18. Gaseous stream 92 passes into a core 94 located within a shell 96 of the thermosiphon reboiler 86 to accomplish the heat exchange. The gaseous stream 92 is condensed to produce a condensate stream 98 that is introduced into the main distillation column 18 as part of the reflux for such column. All of the liquid nitrogen stream 50, produced in the once-through heat exchanger 48, is introduced into the main distillation column 18 as column reflux. This staged condensation of the nitrogen-rich vapor column overhead will increase the liquid nitrogen reflux and therefore, the increased ability of the air separation plant 2 to produce the nitrogen product.
As can be appreciated, other means in place of thermosiphon reboiler 86 could be employed including a once-through heat exchanger if the drain stream 106 were of sufficient flow. Furthermore, although not illustrated, in place of the nitrogen-rich vapor, a stream having a nitrogen concentration no less than air could be introduced into the core 94 of the thermosiphon reboiler 86. For example, it is possible to compress an air stream and liquefy such stream in the main heat exchanger 12. Thereafter, it could be introduced into an intermediate location of the main distillation column 18. A gaseous stream having about the same composition as such liquid stream could then be passed into the core 94 of the thermosiphon reboiler 86 and condensed. The resulting condensate stream would be introduced into a location of the main distillation column at which the composition of the downcoming column liquid was the same or nearly the same as such condensate or introduced into the auxiliary distillation column 34 for stripping and production of the oxygen co-product.
The partial vaporization of the stream of the residual oxygen-rich liquid 68 creates a vapor phase 100 and a liquid phase 102. A vapor phase stream 104 composed of the vapor phase 100 is passed in indirect heat exchange with the incoming compressed and purified air stream 10, within main heat exchanger 12, to warm the vapor phase stream 100, to produce the oxygen product (“O2”) and to help cool the compressed and purified air stream 10. A drain stream 106 composed of the liquid phase 102 can be depressurized in a valve 108 and collected as a liquid oxygen product. In such embodiment, optionally, the waste stream 62 can be passed in indirect heat exchange with the crude liquid oxygen stream 28′ within the subcooling heat exchanger 30′. The waste stream 62 is also, subsequently passed in indirect heat exchange with the compressed and purified air stream 10, within main heat exchanger 12, to warm the waste stream 62 and help cool the compressed and purified air stream 10. The waste stream 62 could be recycled back into the incoming air. This may be accomplished after warming in exchanger 12 by direct mixing with feed air or after further compression. As in air separation plant 1, the nitrogen-rich vapor stream 64, composed of the nitrogen-rich vapor column overhead 23, is warmed within the main heat exchanger 12 through indirect heat exchange with the incoming compressed and purified air stream 10 to also help cool the same.
With reference to both
While the present invention has been described in reference to a preferred embodiments, as will occur to those skilled in the art, numerous changes, additions and omissions can be made without departing from the spirit and scope of the present invention as set forth in the appended claims.
