1. Field of the Invention
The present invention relates to an aperture mask, a manufacturing method thereof, a charged beam lithography apparatus, and a charged beam lithography method.
2. Background Art
As a technique for patterning an integrated circuit and the like, a laser beam lithography scheme using a laser beam is currently being widely used. On the other hand, an electron beam lithography scheme using an electron beam has appeared recently due to the need for super fine patterning (Japanese Patent Laid-Open No. 2005-183530, Japanese Patent Laid-Open No. 2003-297715, Japanese Patent Laid-Open No. 2003-163149 and the like). The electron beam lithography scheme is classified into a type using an aperture mask (stencil mask) and a type not using any aperture mask. Specific examples of the electron beam lithography scheme using an aperture mask include a VSB scheme (variable shaped beam scheme), a CP scheme (character projection scheme), and a collective projection scheme (Japanese Patent Laid-Open No. H08-22941, Japanese Patent Laid-Open No. H09-205058, “I. Amemiya et al., Photomask and X-Ray Mask Technology IV, vol. 3096, p. 251, 1997 (SPIE)” and the like). Each of the VSB scheme and the CP scheme usually uses a first aperture mask for shaping a rectangular beam and a second aperture mask for shaping a patterning beam.
According to the electron beam lithography scheme using an aperture mask, an electron beam is irradiated onto the aperture mask, and the electron beam is shaped by the aperture mask. Electrons which have been shot into the aperture mask by irradiation of the electron beam, remain on the surface of an insulating film which constitutes the aperture mask, and have an adverse effect on the track of a subsequent electron beam which passes through the aperture mask. As a technique for preventing this, there is a known technique such as sputtering the aperture mask to coat it with a conductive layer, when manufacturing the aperture mask. This allows electrons shot into the aperture mask to be mostly removed.
However, when sputtering the aperture mask, the surface of the aperture mask is easily coated, whereas the side wall surface of the aperture formed in the aperture mask is hard to be coated. Therefore, electrons which have been shot into the aperture mask by irradiation of an electron beam and which have remained slightly on the surface of the insulating film that constitutes the aperture mask, have an adverse effect, from the vicinity of the exposed surface of the insulating film exposed to the side wall surface of the aperture, on the track of a subsequent electron beam which passes through the vicinity of the side wall surface of the aperture. This effect is often insignificant when a highly accelerated electron beam on the order of 50 to 100 keV are used, but the effect often cannot be ignored when a lowly accelerated electron beam on the order of 1 to 5 keV are used.
The present invention relates to charged beam lithography using an aperture mask for the charged beam lithography, and it is an object of the present invention to prevent charges shot into the aperture mask from having an adverse effect on the track of a subsequent charged beam which passes through the aperture mask.
An aspect of the present invention is an aperture mask for charged beam lithography, the aperture mask including: a mask substrate having a first semiconductor layer, an insulating film formed on the first semiconductor layer, and a second semiconductor layer formed on the insulating film, and provided with an aperture which penetrates the first semiconductor layer, the insulating film, and the second semiconductor layer; and a conductive layer which coats a surface of the mask substrate and a side wall surface of the aperture formed in the mask substrate, and which coats an exposed surface of the insulating film exposed to the side wall surface of the aperture.
Another aspect of the present invention is an aperture mask for charged beam lithography, the aperture mask including: a mask substrate having an insulating film, and provided with an aperture which penetrates the insulating film; and a conductive layer which coats an exposed surface of the insulating film exposed to a side wall surface of the aperture.
Another aspect of the present invention is a method of manufacturing an aperture mask for charged beam lithography, the method including: forming, in a mask substrate having a first semiconductor layer, an insulating film formed on the first semiconductor layer, and a second semiconductor layer formed on the insulating film, an aperture which penetrates the first semiconductor layer, the insulating film, and the second semiconductor layer; and forming a conductive layer which coats a surface of the mask substrate and a side wall surface of the aperture formed in the mask substrate, and which coats an exposed surface of the insulating film exposed to the side wall surface of the aperture.
Another aspect of the present invention is a method of manufacturing an aperture mask for charged beam lithography, the method including: forming, in a mask substrate having an insulating film, an aperture which penetrates the insulating film; and forming a conductive layer which coats an exposed surface of the insulating film exposed to a side wall surface of the aperture.
Another aspect of the present invention is a charged beam lithography apparatus including: the above-described aperture mask or an aperture mask manufactured by the above-described method.
Another aspect of the present invention is a charged beam lithography method including: performing charged beam lithography using the above-described aperture mask or an aperture mask manufactured by the above-described method.
The aperture mask 101 in
The semiconductor substrate 111 is a silicon substrate here. The insulating film 112 is formed on the semiconductor substrate 111. The insulating film 112 is a silicon oxide film here, but may also be a silicon nitride film. The semiconductor layer 113 is formed on the insulating film 112. The semiconductor layer 113 is a silicon film here. The SOI substrate 121 is manufactured by forming the insulating film 112 and the semiconductor layer 113 on the semiconductor substrate 111 here, but the SOI substrate 121 may also be manufactured by bonding a semiconductor substrate and another semiconductor substrate together via an insulating film. The SOI substrate 121 has the semiconductor substrate 111, the insulating film 112, and the semiconductor layer 113 here, but it may also be provided with an additional layer.
The conductive layer 131 is a tungsten film here, but it may also be an iridium film, a platinum film, or a titanium film. The material for forming the conductive layer 131 is preferably a metallic material whose electric resistance is hardly changed by oxidation. This is because when the material for forming the conductive layer 131 is a metallic material whose electric resistance is drastically changed by oxidation, the performance of the conductive layer 131 for removing shot-in electrons is weakened by oxidation of the conductive layer 131 with long-term use of the aperture mask 101. The aperture mask 101 is used in a condition that the conductive layer 131 is connected to ground potential. Electrons which are shot into the aperture mask 101 are removed from the conductive layer 131 to the ground.
The conductive layer 131 is formed by a metal CVD (chemical vapor deposition) method here. When the conductive layer 131 is formed by a sputtering method as in a conventional case, the surface of the SOI substrate 121 can be easily coated, whereas the side wall surface of the aperture 141 formed in the SOI substrate 121 is hard to be coated. On the contrary, when the conductive layer 131 is formed by a metal CVD method, not only the surface of the SOI substrate 121 is preferably coated, but also the side wall surface of the aperture 141 formed in the SOI substrate 121 is preferably coated. Therefore, the exposed surface of the insulating film 112 which is exposed to the side wall surface of the aperture 141 is coated with the conductive layer 131. As a method of forming the conductive layer 131, any method other than the metal CVD method capable of preferably coating the side wall surface of the aperture 141 may also be adopted. The metal CVD method has an advantage over the sputtering method and the like that a layer to be formed becomes flat, and also has an advantage over a plating method and the like that no seed is required to form a layer. When seed processing is performed, a charge source which may have an adverse effect on the track of an electron beam is generated.
With regard to the surface of the SOI substrate 121 (substrate surface), an upper surface 201 corresponds to the surface of the semiconductor layer 113, and a lower surface 202 corresponds to the surface of the semiconductor substrate 111. The conductive layer 131 coats the upper surface 201 of the SOI substrate 121, the lower surface 202 of the SOI substrate 121, and a side wall surface 203 of the aperture 141 formed in the SOI substrate 121. The side wall surface 203 of the aperture 141 includes an exposed surface 211 of the semiconductor substrate 111, an exposed surface 212 of the insulating film 112, and an exposed surface 213 of the semiconductor layer 113. The conductive layer 131 coats these exposed surfaces 211, 212, and 213.
Such a conductive layer 131 is realized by performing a process of depositing the conductive layer 131 twice. That is, first as shown in
On the side wall surface 203 of the aperture 141, the first conductive layer 131A and the second conductive layer 131B are deposited. Therefore, the size of the aperture 141 is reduced by the thicknesses of the conductive layer 131A and the conductive layer 131B. Therefore, the design value of the size of the aperture of the SOI substrate 121 is set to be greater than the design value of the size of the aperture of the aperture mask 101, by the thicknesses of the conductive layer 131A and the conductive layer 131B. Of course, the difference of these design values in a region where one of the conductive layer 131A and the conductive layer 131B is deposited, is different from the difference of these design values in a region where both of the conductive layer 131A and the conductive layer 131B are deposited. In
Hereinafter, the functions of the conductive layer 131 will be explained in detail.
Electrons which have been shot into the aperture masks 101 in
However, the aperture mask 101 in
Therefore, in the aperture mask 101 in
However, the aperture mask 101 in
First, as shown in
The semiconductor substrate 111 is made of Si here, and the thickness of the semiconductor substrate 111 is 0.5 mm here. The semiconductor substrate 111 constitutes the lower surface of the SOI substrate 121.
The insulating film 112 is made of SiO2 here, and the thickness of the insulating film 112 is 0.5 μm here. The insulating film 112 is used as an etching stop film.
The semiconductor layer 113 is made of Si here, and the thickness of the semiconductor layer 113 is 15 μm here. The semiconductor layer 113 constitutes the upper surface of the SOI substrate 121.
Next, as shown in
Next, as shown in
Next, as shown in
Next, as shown in
Next, as shown in
The aperture mask 101 in
When the forming temperature of the conductive layer 131 is too high, the conductive layer 131 is contracted substantially between the time of forming the layer and the time after forming the layer, and this causes the “peeling off”. Conversely, when the forming temperature of the conductive layer 131 is too low, the conductive layer 131 is not formed. Therefore, the forming temperature of the conductive layer 131 is preferably slightly higher than the temperature at which the reactant gas activates.
When the concentration of the carrier gas is too high, the film of the conductive layer 131 becomes sparse, that is, the quality of the film of the conductive layer 131 degrades. Conversely, when the concentration of the carrier gas is too low, the forming speed of the conductive layer 131 decreases. Therefore, the concentration of the carrier gas is preferably set in consideration of the balance between the film quality and the forming speed.
It is preferable to use the same material for forming the conductive layer 131A and the conductive layer 131B rather than to use different materials. This is because using different materials causes both layers to be peeled off from each other more easily, for the reason that coefficients of expansion of both layers are different. When different materials are used for forming the conductive layer 131A and the conductive layer 131B, the coefficients of expansion of both layers are preferably as close as possible to each other.
In
Each of the first shaping aperture mask 322 and the second shaping aperture mask 332 corresponds to the aperture mask 101 shown in
The electron beam lithography apparatus 301 in
As shown above, the embodiment of the present invention relates to charged beam lithography using an aperture mask for the charged beam lithography, and makes it possible to prevent charges shot into the aperture mask from having an adverse effect on the track of a subsequent charged beam which passes through the aperture mask.