The invention relates to an apparatus for coating a substrate and, particularly, to an apparatus according to the preamble of claim 1 for producing a liquid film from one or more liquid precursors onto the surface of a substrate in order to establish a coating, said apparatus being arranged to direct an aerosol flow against the surface of the substrate in a coating chamber. The present invention further relates to a method for coating a substrate and, particularly, to a method according to the preamble of claim 16 for producing a liquid film from one or more liquid precursors onto the surface of a substrate to establish a coating, the method comprising the atomization of one or more precursors into droplets in order to generate an aerosol flow, passing the thus generated aerosol flow into a coating chamber and directing the aerosol flow in the coating chamber onto the surface of a substrate to establish a liquid film. Additionally, the present invention relates to the use of the method in accordance with claim 22 for coating a substrate.
In the coating of different kinds of substrates, it is known to employ the application of a liquid layer onto the substrate surface. Herein, the substrate surface is covered with a liquid film that can be postprocessed in order to dry and cure the same. On such branch of conventional technology employing the application of a liquid layer on a substrate surface is manufacture of glass.
A glass substrate with an antireflection coating on its surface is used particularly in photovoltaic devices to improve the efficiency of solar cells. By virtue of reducing the reflection of solar radiation from the surface of the device, a larger portion of the solar energy can be passed to the active area of the solar cell, thus allowing a higher efficiency in converting solar energy into electrical energy. The antireflection coating must be as thin as possible to minimize absorption of solar energy therein. Furthermore, the refractive index of the antireflective material must be substantially smaller than the refractive index of the glass used as a substrate. The refractive index of glass is typically about 1.5.
Antireflection coatings cause interference between the wavefronts reflected from the bottom and top surfaces of the coating. When the reflected waves are suitably out-of-phase with each other, they tend to interfere subtractively thus substantially reducing the amount of reflected light. Optimal efficiency of antireflectivity is attained when the refractive index is adjusted to match that of the substrate glass material and, additionally, the thickness of the coating is set to one-quarter of the wavelength for which the antireflection coating intended. However, as solar radiation comprises a relatively wide band of wavelengths, conventionally a multilayer antireflection coating is employed to achieve maximal transmission efficiency. As to terms of practical embodiments with regard to production speed and costs, however, the most advantageous result is attained with a single-layer coating featuring a gradually changing refractive index from the glass surface to air. This arrangement minimizes reflection even for varying angles of incidence of solar radiation onto the surface of the solar cell. Such a situation occurs, e.g., when solar radiation is incident on a permanently fixed solar cell at different times of a day.
It is known in the art to coat a substrate by a coating material produced from a liquid precursor that after the application of the coating is cured into a solid state. Painting a substrate, for instance, fulfills the specifications of such a treatment. In applications that require a minimal thickness, advantageously less than 1 μm, and a high surface smoothness from the coating, conventional coating methods fail to provide a satisfactory result. Moreover, antireflective surfaces pose extreme demands with respect to the surface smoothness of the coating.
In patent publication U.S. Pat. No. 4,871,105, American Telephone and Telegraph Company, AT&T Bell Laboratories, Mar. 10, 1989, is described a method and an apparatus for applying a flux flow at the surface of a substrate. The apparatus comprises means for converting a liquid flow into a fog flow and then injecting the fog flow into a laminar gas flow, said laminar gas flow being directed at the bottom surface of the substrate being processed, whereby a portion of the flux droplet flow adheres to the substrate surface thus coating the substrate. The patent publication does not mention the size of fog flow droplets. However, it can be deduced from the components (Sono-Tek piezoelectric crystal, model 8700) used in the most preferred embodiment that the diameter of the fog droplet is greater than 10 μm. Hence, producing smooth, thin coatings applied by virtue of this kind of large-droplet fog flow is difficult.
As discussed above, a problem in prior-art embodiments is that conventional arrangements fail to produce a sufficiently thin and smooth liquid layer onto the surface of a substrate. A thick and uneven liquid layer results in an uneven coating. Moreover, a thick and uneven coating fails to give a maximally good antireflective coating.
It is an object of the invention to provided an apparatus and method such that are capable of overcoming the disadvantages of prior art. The goals of the present invention are achieved by virtue of an apparatus in accordance with the characterizing part of claim 1 specifying that the apparatus comprises a homogenizing nozzle for making an aerosol flow substantially homogeneous in the direction of the substrate surface plane prior to passing the flow into the coating chamber. The goals of the present invention are further achieved by virtue of a method in accordance with the characterizing part of claim 16 specifying that in the method the aerosol flow is made substantially homogeneous in the direction of the substrate surface plane prior to passing the flow into the coating chamber. Still further, the goals of the present method are achieved in accordance with claim 22 by the use of an elongated and tapering homogenizing nozzle for passing an aerosol flow uniformly into a coating chamber.
Preferred embodiments of the present invention are specified in the dependent claims.
The basic concept of the present invention is to produce droplets for an aerosol flow from at least one liquid precursor. Hereby, at least one precursor is advantageously converted into droplets having an average diameter less than 10 μm, advantageously less than 3 μm. The droplets are collected into an aerosol flow which is homogenized in a homogenizing nozzle according to the invention prior to passing the aerosol flow into a coating chamber. Most advantageously, the aerosol flow is set into a swirling or turbulent motion prior to its entry into the coating chamber. According to the invention, the aerosol flow can be directed by separate gas flows. The homogenizing nozzle is advantageously designed such that it homogenizes the aerosol flow substantially in the direction of the substrate surface. Accordingly, the homogenizing nozzle in one embodiment of the invention is implemented as an elongated channels that has a tapering cross section or height in the direction of the coating chamber.
By virtue of the homogenizing nozzle, the aerosol flow can be homogenized prior to passing the flow into the coating chamber and directing the same against the substrate surface. The aerosol flow comprising small droplets can be directed in a controlled fashion toward the substrate surface so as to apply a thin liquid layer of constant thickness thereon. Such a smooth and thin liquid layer the production of a thin and homogeneous coating on a substrate with the help of postprocessing the applied liquid layer.
Next some preferred exemplary embodiments of the invention are described in more detail with the help of preferred embodiments and making reference to appended drawings in which:
The present invention relates to an apparatus and method for coating a substrate, particularly a glass substrate with a liquid coating prior to the drying or curing steps of the coating, that is, prior to the postprocessing of the coating. Subsequent to the application of the coating layer, the postprocessing step can be carried out with the help of means specifically incorporated in the apparatus according to the invention for the purpose of subjecting the liquid coating to external energy such as, e.g., convective thermal energy or electromagnetic radiation such as infrared or ultraviolet radiation. In particular, the invention relates to coating a glass substrate with an antireflective coating.
In
As described above, atomizers 9 produce in a atomizing chamber 7 an aerosol flow 13 that may further be controlled with the help of a gas flow A ejected from a guide gas nozzle 11. The gas flow A ejected from guide gas nozzle 11 may contain in an evaporated state the same solvent as that used in the liquid precursor. Thus, a controlled atmosphere is created into the atomizing chamber 7 for evaporation of the solvent contained in the droplets of the aerosol flow 13. The guide gas nozzle 11 may also be used for passing into the atomizing chamber some gas, advantageously of a kind that is nonreactive with regard to the droplets of aerosol flow 13. A portion of aerosol flow 13 adheres in the atomizing chamber 7 onto the inner walls thereof and flows along the walls to the bottom of the atomizing chamber 7, wherefrom the excess coating material can be recirculated via a return nozzle 15. While the recirculating means are omitted from the drawings for greater clarity, they essentially comprise a pump and a recirculated material container, advantageously complemented with a filter for cleaning the recirculated material free from solid particles.
Along the flow path of atomizing chamber 7 is adapted a homogenizing nozzle 17, whereto the aerosol flow 13 is passed from atomizing chamber 7. Directing the aerosol flow 13 into the homogenizing nozzle 17 may augmented, e.g., by the material flow ejected from guide gas nozzle 11. As shown in
As shown in
In coating chamber 21 the aerosol flow 13 is directed against the surface 4 of the substrate 3 in order to establish a liquid layer 27 onto the surface 4 of substrate 3. In other words, the aerosol flow 13 is passed from the outlet opening 36 of the homogenizing nozzle 17 into the coating chamber 21 in the form of a substantially steady and homogenized aerosol flow 13. In accordance with the above description, the homogenizing nozzle 17 is implemented as a channel tapering toward the coating chamber. In the embodiment of
As shown in
Operating in conjunction with the homogenizing nozzle 17 or upstream thereof in the flow direction of aerosol flow 13 may furthermore be adapted a droplet trap (not shown in the to drawings) that serves to remove large droplets from the aerosol flow 13, whereby the size distribution of droplets being passed to the coating chamber can be controlled in a desired manner. Advantageously, the droplet trap is located to operate at the inlet opening 35 of the homogenizing nozzle 17 thus allowing separation of large droplets from the aerosol flow 13 prior to passing the flow to the homogenizing nozzle 17. The droplet trap may be, e.g., an impactor wherein large droplets of the aerosol flow 17 are removed by impacting them against the impaction plate of the impactor. In other words, the droplet trap can be implemented by way of placing an impaction plate at the inlet opening 35 of the homogenizing nozzle 17. Alternatively, a droplet trap can be placed into the atomizing chamber 7 or separation of large droplets can be implemented by directing the aerosol flow 13 in the atomizing chamber 7 to impinge on the wall of the atomizing chamber 7, whereby large droplets hit the wall of the atomizing chamber 7. Separation of large droplets from the aerosol flow 13 provides a more homogeneous aerosol flow 13 and thus allows the production of a more homogeneous coating.
In the embodiment of
In
With help of the grooved wheels 41 the substrate 2 can be transferred so that essentially only the cut edges of the glass substrate touch the transfer means. Hence, the use of grooved wheels 41 for moving the glass substrate 3 facilitates application of coating to both sides of the glass substrate without any risk of contaminating the glass substrate 3 during its transfer movement.
In the embodiment shown in
The apparatus 1 further comprises a barrier gas nozzle 25 and another barrier gas nozzle 29 for isolating the coating chamber 21 from the ambient atmosphere. In an alternative embodiment, the apparatus may comprise only one barrier gas nozzle or, alternatively, three or more barrier gas nozzles. In
The apparatus 1 further comprises a discharge channel 31 via which the portion of aerosol not adhered to the surface 4 of the substrates 3 is routed out from the coating chamber 21. By adjusting the differential pressure between the coating chamber 21 and the discharge channel 31, the retention time of the aerosol flow 13 can be controlled in the coating chamber 21.
In
As described above, the present invention makes it possible to deposit a liquid film 27 from one or more precursors onto the surface 4 of a substrate 3 for the purpose of producing a coating. Liquid precursors are atomized with the help of one or more atomizers 9 into droplets forming an aerosol flow 13. The thus formed aerosol flow is passed into a coating chamber 21, wherein the aerosol flow is directed to the surface 4 of a substrate in order to establish a liquid film 27. According to the invention, the aerosol flow 13 is homogenized substantially in the direction the substrate surface prior to passing the flow into the coating chamber 21. In accordance with the invention, the flow is homogenized with the help of an elongated and tapering homogenizing nozzle 17, by virtue of which the aerosol flow is passed steadily into the coating chamber in which the aerosol flow is directed to the surface 4 of the substrate 3 for establishing a liquid film 27 required to produce a coating. The homogenizing nozzle 17 is implemented as a channel extending along the direction of the surface 4 of the substrate 3 in a tapering fashion toward the coating chamber 21. More particularly, the homogenizing nozzle tapers in its height, that is, in a dimension orthogonal to the surface 4 of the substrate 3.
To a person skilled in the art it is obvious that with advances in the art, the spirit of the invention can be implemented in a plurality of different ways. Hence, the present invention and its embodiments shall not be limited to the examples described above, but rather can be varied within the scope of the appended claims.
Number | Date | Country | Kind |
---|---|---|---|
U20100005 | Jan 2010 | FI | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/FI2010/051096 | 12/29/2010 | WO | 00 | 6/15/2012 |