Apparatus and method for rapid cooling of large area substrates in vacuum

Abstract
The present invention is directed to an apparatus and method for rapid cooling of a large substrate in a vacuum environment. A first cooled plate is brought into close proximity with one surface of a flat substrate. The spatial volume between the first cooling plate and the substrate is sealed and brought to a higher pressure than the surrounding vacuum level to increase the cooling efficiency. A second cooled plate is brought into close proximity with the opposite surface of the flat substrate. A second spatial volume between the second cooling plate and the substrate is sealed and the gas pressure is equalized to the gas pressure in the first spatial volume. The equalization of the gas pressure on both sides of the flat substrate eliminates deflection of the substrate and bending stress in the substrate.
Description

BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a cross-sectional elevation view of the cooling apparatus of the present invention.



FIG. 2 is a plot of temperature versus time illustrating the measured cooling rates of a soda lime glass substrate for various gas pressures in a sealed gas volume utilizing the cooling apparatus of the present invention and also illustrating a plot of an estimated cooling rate utilizing prior art radiation cooling.





DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

Referring now to FIG. 1, there is shown a schematic cross-sectional elevation view of the preferred embodiment of the substrate cooling apparatus of the present invention. The cooling apparatus is enclosed in a surrounding conventional vacuum chamber (not shown). A planar soda lime glass substrate 1 is supported on two metal substrate transport belts 2. These metal transport belts 2 may be of the type described in U.S. Pat. No. 6,423,565 and do not form part of the present invention. Rather, they are shown only for purposes of clarity. The metal transfer belts 2 extend out of the plane of FIG. 1. Upper and lower metal cooling plates 3, 8 are provided above and below substrate 1 and in close proximity to the flat upper and lower surfaces thereof. Upper and lower sealed gas volumes 5, 9 are contained and sealed by o-ring seals 6, 10. Sealed gas volumes 5, 9 are formed between upper and lower cooling plates 3, 8 and above and below substrate 1, respectively. Two gas supply tubes 4, 11 are provided to admit gas under controlled pressure from an external source to each of the sealed gas volumes 5, 9. Two cooling medium supply tubes 7, 12 are connected between an external source of coolant and cavities within each of cooling plates 3, 8 to facilitate controlled cooling of the cooling plates 3, 8. The cooling supply tube 7 passes through the top cooling plate 3 and the cooling supply tube 11 passes through the lower cooling plate 8 so that there are two ends to the cooling supply tubes 7, 11. The cooling plates 3, 8 are adapted to be moved vertically to allow close contact with substrate 1 and to also allow them to be moved away from substrate 1 to facilitate unimpeded horizontal movement of the substrate 1 through the vacuum chamber or other enclosure. A control valve (not shown) is provided in connection with each of the gas supply tubes 4, 11 so that the gas flow may be shut off when the cooling plates 3, 8 are moved away from the substrate 1. Multiple substrates 1 may be passed between the cooling plates 3, 8 to facilitate continuous processing of substrates. When the cooling plates 3, 8 are brought together in close proximity to the upper and lower surfaces of substrate 1, the o-ring seals 6, 10 are compressed to provide the seal necessary to admit gas through the gas supply tubes 4, 11 in order to bring the sealed gas volumes 5, 9 to a higher pressure than that of the surrounding ambient vacuum.


The lower cooling plate 8 must not be in direct contact with the lower surface of substrate 1 since this would harm the thin semiconductor films on that surface. Since the lower cooling plate 8 must be spaced further away from the substrate 1, the cooling rate due to the lower cooling plate 8 will not be as great as the cooling rate from the top cooling plate 3. However, the pressure in the lower sealed gas volume 9 is critical since the pressure in the lower gas volume 9 eliminates any deflection of large area substrates 1 away from the surface of the top cooling plate 3. If there is any deflection of large area substrates 1 away from the top cooling plate 3 the cooling rate will drop significantly. Pressures in the sealed gas volumes 5, 9 are equalized to eliminate the possibility of breaking the glass substrate 1 due to a pressure differential between the upper and lower surfaces thereof.


Any of a number of known cooling mediums can be passed through supply tubes 7, 12 including water. These cooling mediums may be conventionally cooled using chillers or brine baths, for example. The cooling rate of substrate 1 and the end point temperature of the cooling curve are determined by the temperatures of cooling plates 3, 8. These temperatures can be controlled by utilizing conventional PID control methods with a thermocouple control point. The gas pressure in the sealed gas volumes 5, 9 can also be measured and controlled using methods well understood in the art.


It has been found possible to improve the cooling rate of substrate 1 in a vacuum environment by enhancing the conduction cooling mechanism. Thermal conduction may be accomplished through solid contact or through gas phase conduction. This may be shown by placing the cooling plates 3, 8 in close proximity to the substrate 1 and increasing the ambient gas pressure in the sealed gas volumes 5, 9 between the cooling plates 3, 8 and the substrate 1. The heat transfer away from substrate 1 may be optimized in any of several ways. First, the cooling plates 3, 8 are preferably constructed of a material having high thermal conductivity, such as copper, so that excess heat is transferred away quickly. The surfaces of the cooling plates 3, 8 that face substrate 1 are preferably polished so that the surface roughness of the cooling plates 3, 8 is low. The spacing between the cooling plates 3, 8 and substrate 1 should be as small as possible. Preferably, the upper cooling plate 3 is in direct contact with the upper surface of substrate 1, with the average distance being approximately 0.005 inches or less. In this way, for any microscopically rough surface, the high points will be in contact and increase the probability of contact conduction. The lower cooling plate 8 of FIG. 1 must not be in direct contact with the lower surface of substrate 1 since this would harm the thin semiconductor films on that surface. As the ambient gas pressure in the sealed gas volumes 5, 9 is increased, the distance between the gas atoms decreases, and the probability of a collision between the gas atoms and the surrounding walls increases. These collisions of the gas atoms or molecules with the hot substrate 1 and the cold cooling plates 3, 8 increase the heat transfer from the substrate 1. The heat transfer due to the gas collisions are a form of conduction heat transfer through the gas phase in a confined space. In this case, there will be no convection currents or fluid flow in the gas, only random collisions of the gas atoms or molecules.


In order to illustrate the thermal efficiency of the present invention, a prototype test fixture was used to demonstrate that a soda lime glass substrate can be cooled from 170° C. to 37° C. in a two-minute time period and to 29° C. in a four-minute time period. The measured cooling rates of a soda lime glass substrate are shown in FIG. 2. The topmost curve in FIG. 2 is a predicted cooling rate for thermal radiation cooling of a glass substrate calculated by a finite difference analysis. The other three curves in FIG. 2 show the effect of increasing the gas pressure intervening space between the single top cooling plate 3 and a substrate 1. In this test prototype no o-ring seals 6 were used. In this prototype no deflection or stress was introduced so the lower cooling plate 8 was not required. As the gas pressure was increased from 40 mTorr to 1 Torr, the cooling rate increased significantly. The following parameters produced the test results shown in FIG. 2: 1) the distance between the cooling plate 3 and the substrate 1 was at most 0.005 in., with the surfaces thereof being in direct contact at some points; and 2) the temperature of the cooling plate 3 was approximately 20° C. The results shown in FIG. 2 demonstrate the efficiency of the current invention compared to thermal radiation cooling alone. In the working system the cooling rate can be increased by decreasing the temperature of the cooling plates 3, 8 below 20° C. and by using a combination of both cooling plates 3, 8. Another way to increase the cooling rate is to increase the pressure in the sealed gas volumes 5, 9 to pressures on the order of 10 Torr.

Claims
  • 1. A process for rapidly cooling a substrate in a vacuum environment, comprising: positioning a planar substrate having upper and lower surfaces in the vacuum environment, the lower surface of the substrate having one or more adherent films thereon;positioning an upper cooling plate above said substrate such that a lower surface of said upper cooling plate is in close proximity to said upper surface of said substrate, thereby forming an upper spatial volume between said lower surface of said upper cooling plate and said upper surface of said substrate;positioning a lower cooling plate below said substrate such that an upper surface of said lower cooling plate is in close proximity to said lower surface of said substrate, thereby forming a lower spatial volume between said upper surface of said lower cooling plate and said lower surface of said substrate;sealing said upper and lower spatial volumes;admitting a gas under controlled pressure into said upper and lower spatial volumes, the pressure of the gas in the upper spatial volume being substantially equal to the pressure of the gas in the lower spatial volume; andcontrollably cooling said upper and lower cooling plates.
  • 2. A process as in claim 1, wherein said upper and lower cooling plates are controllably cooled by circulating a cooling medium from an external source through one or more cavities in each of said upper and lower cooling plates.
  • 3. A process as in claim 2, wherein said cooling medium comprises cooled water.
  • 4. A process as in claim 1, wherein said substrate comprises a soda lime glass substrate.
  • 5. A process as in claim 1, wherein said upper cooling plate is positioned to directly contact said upper surface of said substrate at one or more points thereon.
  • 6. A process as in claim 1, wherein said lower cooling plate is positioned to avoid direct contact with said lower surface of said substrate.
  • 7. A process as in claim 1, wherein a distance between said lower surface of said upper cooling plate and said upper surface of said substrate is smaller than a distance between said upper surface of said lower cooling plate and said lower surface of said substrate.
  • 8. Apparatus for cooling a planar substrate positioned in a vacuum enclosure, the apparatus comprising: support means for supporting said substrate within said vacuum enclosure, said substrate having a first surface and an opposite second surface, said second surface having one or more adherent films thereon;a first cooling plate positioned proximate said first surface of said substrate, a first spatial volume being formed between said first cooling plate and said first surface of said substrate;a second cooling plate positioned proximate said second surface of said substrate, a second spatial volume being formed between said second cooling plate and said second surface of said substrate;means for sealing said first and second spatial volumes from an ambient pressure environment within said vacuum enclosure;means for admitting a gas under controlled pressure conditions from an external source into said first and second spatial volumes such that the pressure of the gas in said first spatial volume is substantially equal to the pressure of the gas in said second spatial volume; andmeans for controllably cooling said first and second cooling plates.
  • 9. Apparatus as in claim 8, wherein: said support means is operative for supporting said substrate in a horizontal position such that said first surface of said substrate comprises an upper surface and said second surface comprises a lower surface;said first cooling plate has a lower horizontal surface positioned proximate said upper surface of said substrate; andsaid second cooling plate has an upper horizontal surface positioned proximate said lower surface of said substrate.
  • 10. Apparatus as in claim 8, wherein a distance between said first surface of said substrate and said first cooling plate is smaller than a distance between said second surface of said substrate and said second cooling plate.
  • 11. Apparatus as in claim 8, wherein said first cooling plate is positioned to directly contact said first surface of said substrate at one or more points thereon.
  • 12. Apparatus as in claim 8, wherein said second cooling plate is positioned to avoid direct contact with said second surface of said substrate.
  • 13. Apparatus as in claim 8, further comprising: a coolant cavity formed within each of said first and second cooling plates; andcoolant supply means coupled between said cooling cavities and an external source of coolant for circulating said coolant through said coolant cavities.
  • 14. Apparatus as in claim 8, wherein said substrate comprises a soda lime glass substrate.
  • 15. Apparatus as in claim 8, wherein said means for sealing said first and second spatial volumes comprises a pair of o-ring seals.
  • 16. Apparatus as in claim 13, wherein said coolant comprises water.
  • 17. Apparatus as in claim 8, wherein said first and second cooling plates comprise a thermally conductive material.
  • 18. Apparatus as in claim 9, wherein said lower horizontal surface of said first cooling plate and said upper horizontal surface of said second cooling plate are polished.
GOVERNMENT SUPPORT

This invention was made with Government support under grants awarded by the National Renewable Energy Laboratory. The Government has certain rights in this invention.