The invention relates to artificial turf and methods for the manufacture of artificial turf infill.
Artificial turf or artificial grass is surface that is made up of fibers which is used to replace grass. The structure of the artificial turf is designed such that the artificial turf has an appearance which resembles grass. Typically artificial turf is used as a surface for sports such as soccer, American football, rugby, tennis, golf, for playing fields, or exercise fields. Furthermore artificial turf is frequently used for landscaping applications.
Artificial turf may be manufactured using techniques for manufacturing carpets. For example artificial turf fibers which have the appearance of grass blades may be tufted or attached to a backing. Often times artificial turf infill is placed between the artificial turf fibers. Artificial turf infill is a granular material that covers the bottom portion of the artificial turf fibers. The use of artificial turf infill may have a number of advantages. For example, artificial turf infill may help the artificial turf fibers stand up straight. Artificial turf infill may also absorb impact from walking or running and provide an experience similar to being on real turf. The artificial turf infill may also help to keep the artificial turf carpet flat and in place by weighting it down.
European patent application EP 1 416 009 B1 describes a loose, free flowing rubber particles as litter material for artificial turf. The particles have an average size between 0.4 mm and 4.0 mm and their complete surface is covered with a permanently elastic and pigmenting coating.
European patent application EP1201388 B1 discloses a method of manufacturing colored rubber chips: To 100 parts by weight of crushued rubber chips having a particle size of from 1 to 10 mm or fibrous rubber chips having a fibrous length of 30 mm or below are added a film forming material, which contains a pigment and 10 to 100 parts by weight of a one-pack type or two-pack type polyurethane resin which gels at least from a liquid state in 60 seconds or more and cures through the gelling process, and they are stirred for mixing. When the polyurethane resin starts to gel and the rubber chips start to aggregate, stirring is further continued for mixing in spite of heavy load on the mixer so to loosen the aggregation of the rubber chips. By configuring as described above, A manufacturing method which can form a thick colored film without requiring a complex procedure and can inexpensively obtain colored rubber chips which have a remarkable color keeping property and a pyramid shape with edges similar to those formed when crushed is provided. The particle size is desired to have almost the same size as the thickness of the film. And if it is excessively larger or smaller than that size it does not meet the objective of completely covering the rubber chips. The film thickness in the present invention is about 0.8 mm maximum and the particle sizes is also about the same accordingly.
International patent application WO 2010/081632 A1 discloses a method for producing coated particles made of rubber granulate, the coating, the particles coated with said coating, and the uses of the coated particles. The coating contains no solvents.
The invention provides for a method of manufacturing artificial turf infill, a method of manufacturing artificial turf, artificial turf infill, and artificial turf. Embodiments are given in the dependent claims.
In one aspect the invention provides for a method of manufacturing artificial turf infill. Artificial turf infill as used herein, encompasses a granular material that is spread out on an artificial turf carpet in between the fibers. Artificial turf infill may be used to modify an artificial turf carpet to have more earth like properties. For example the artificial turf infill may provide a surface which is able to absorb impacts in a manner similar to real turf.
The method comprises providing an initial composition comprising a granulate, at least one first type of pigment, and a fluid binding agent. The fluid binding agent comprises at least one type of polymer component. The method further comprises mixing the initial composition. The method further comprises adding water and a catalyst to the initial composition during the mixing of the initial composition to cure the fluid binding agent and the at least one type of pigment into an initial coating of the granulate.
The method further comprises providing a subsequent composition comprising the granulate with the initial coating, the at least one second type of pigment and the fluid binding agent. The method further comprises mixing the subsequent composition. The method further comprises adding water and the catalyst to the subsequent composition during the mixing of the subsequent composition to cure the fluid binding agent and the at least one type of pigment into a subsequent coating of the granulate.
The at least one second type of pigment and the at least one first type of pigment may be identical or they may be different. If they are the same then the coating of the granulate will be of a uniform color. If the at least one second type of pigment and the at least one first type of pigments are different colors then the two colors can be chosen so that the resulting artificial turf infill has a more natural and earth like appearance.
The method further comprises providing the granulate with the subsequent coating as artificial turf infill.
The coating of the granulate in at least two steps as described above, may be beneficial because it may provide for better coating of the granulate For example, during the mixing of the initial composition individual grains of the granulate will touch and interact with each other as the initial coating on each of the grains forms. The physical contact between different grains will however cause defects. By coating the granulate particles a second time with the subsequent coating, much higher coverage of the granulate can be achieved.
As a hypothetical example, during the formation of the initial coating or the subsequent coating the coverage is each only 90% of the surface of the granulate. After the initial coating has been deposited, roughly 10% of each granule of the granulate would be uncoated. There would be small surface defects. Deposition of the subsequent coating would then also cover 90% of the surface. As the interaction between the grains or particles of the granulate is essentially a random process, one can expect that 90% of the defects that were exposed after the deposition of the initial coating are coated in this case. The result of doing two coatings is then an artificial turf infill that is 99% coated with only minor amounts of defects, where the granulate is not coated with either the initial coating or the subsequent coating.
Improving the coverage of the granulate may be beneficial in several different situations. For example, it may be desirable to color the artificial turf infill the same or a similar color as fibers or tufts, which are used to manufacture an artificial turf carpet. This may provide a more realistic-looking play surface or playfield. Another advantage is that the elastomeric granulate may be better coated and may therefore have superior wear qualities or may even be better isolated from the environment.
In an embodiment, the granulate comprises an elastomeric or elastic granulate.
In different embodiments the granulate is an elastomeric material based on elastomers like synthetic rubbers as e.g. styrene butadiene rubber, polybutadiene rubber, styrene-ethylene-butadiene-styrene copolymer (SEBS), ethylene-propylene-diene monomer rubber (EPDM), acryl nitrile butadiene rubber. In other embodiments a cis-1,4-polyisoprene, as natural rubber and trans 1,4-polyisoprene as gutta-percha based granulate can be used.
In another embodiment the granulate comprises a compression resistant granulate or a rigid granulate.
In another embodiment the granulate comprises any one of the following: natural latex, cork, linoleum, composites made from solidified vegetable oils and wood flour or a hydrogel of methyl-cellulose.
In another embodiment the curing of the initial coating and the curing of the subsequent coating is a polymerization process. Within the claims, the term ‘cure’ or ‘curing’ may be replaced with polymerization.
In another embodiment the subsequent coating at least partially covers the initial coating.
In another embodiment the initial coating only partially covers the granulate.
In another embodiment the subsequent coating only partially covers the initial coating.
In another embodiment, the initial coating and the subsequent coating each have a thickness of less than any one of the following: 0.1 mm, 0.075 mm, 0.05 mm, and 0.01 mm. This embodiment may be beneficial because it may provide a means of reducing the amount of fluid binding agent necessary to coating the granulate.
In another embodiment the initial coating comprises gaps. The subsequent coating also comprises gaps. The gaps in the initial and subsequent coatings may be distributed randomly on the surface of the granulate. As the gaps in both coatings are distributed randomly, it is unlikely that the gaps will line up. The result will be that there will be few if any portions of the underlying granulate exposed.
It is possible that some of the gaps in the initial and subsequent coatings may line up. However, all or the vast majority of the surface of the granulate will be coated. Using the double coating may greatly reduce the amount of fluid binding agent necessary to coat the granulate.
In another embodiment, the granulate with the initial coating and the subsequent coating is re-coated at least one time by performing the following sequence. The first step in the sequence is provide a subsequent composition by adding at least one additive and the fluid binding agent to the granulate that has already been coated with the initial coating and the subsequent coating. The next step in the sequence is to mix the subsequent composition. The next step in the sequence is to add water and the catalyst to the subsequent composition during the mixing of the subsequent composition to cure the fluid binding agent and the at least one additive into a further coating. The granulate with the further coating is provided then as the artificial turf infill. This embodiment may be beneficial because an additional coating or layer may be put on the granulate. If the at least one first and/or second type of pigment is used again then the granulate may be coated a third or more times to improve the coverage and the coating of the granulate. This embodiment may also be beneficial because it may enable the deposition of so-called functional layers or additives, which may add to the utility or wear or usefulness of the artificial turf infill.
In another embodiment, the further coating has a thickness of less than any one of the following: 0.1 mm, 0.075 mm, 0.05 mm, and 0.01 mm. This embodiment may be beneficial because it may provide a means of reducing the amount of fluid binding agent necessary for coating the granulate.
In another embodiment the PU catalyst is partially or completely water soluble and is of the group: secondary amine, tertiary amine, a metal organo catalyst.
In another embodiment the liquid PU component is based on an NCO terminal polymer which might be a pre-polymer, a polymeric isocyanate, an oligomeric isocyanate, a monomer and a mixture hereof.
In another embodiment the liquid PU component is based on an aromatic diisocyanate of the group toluene diisocyanate or methylene-2,2-diisocyanate,
In another embodiment the liquid PU component is based on an aliphatic diisocyanate of the group hexamethylene disiocyanate, isophorone diisocyanate and 1,4-cyclohexyldisiocyanate.
In preferred embodiment the liquid PU component is based on methylenediphenyl-isocyanate isomer mixture.
In another embodiment the hydroxyl component for the production of the PU is out of the group polyether polyol or polyester polyol.
In another embodiment the hydroxyl component is based on a polyetherpolyol of the molecular weight 500 to 10000. In a preferred embodiment the polyetherpolyol has a molecular weight of 1500-6000. In a very preferred embodiment the molecular weight is in the range of 2000-4000.
In another embodiment the at least one additive comprises the at least one first and/or second type of pigment.
In another embodiment the at least one additive further comprises a flame retardant like aluminum trihydrate, magnesium hydroxide turning a by itself burnable or flammable elastomeric material into a flame retardant infill material.
In another embodiment this flame retardant additives creates an intumescent coating and is based on intumescent component comprising ammonium polyphosphate or exfoliated graphite or a mixture hereof.
In another embodiment the at least one additive further comprises zeolite. The addition of zeolite may be beneficial because then the surface of the artificial turf infill may be able to absorb or de-absorb water. For example before a football game, which is scheduled to be held in the sun or in hot conditions, water may be sprayed onto the artificial turf and the zeolite may absorb an amount of water. As the sun or hot air heats the artificial turf infill during the game, the evaporation of water may cool the playing surface for the players and make the use of the artificial turf more pleasant.
In another embodiment the at least one additive further comprises methylcellulose, which may be beneficial in a similar way like zeolite for absorbing and desorbing of water, rendering a cooling effect at hot climatic conditions.
In another embodiment the at least one additive further comprises an antibacterial agent.
In another embodiment the at least one additive further comprises silver. Silver may be beneficial as an antibacterial agent.
In another embodiment the at least one additive further comprises chitosan, showing natural antibacterial properties.
In another embodiment the at least one additive further comprises an IR reflective pigment. The use of the IR reflective pigments as mixed metal oxides may be beneficial because it may reflect infrared light. This may reduce the heating of the artificial turf infill. A specific advantage may be that in this case the comparably expensive and precious pigments are merely on the surface of the infill granulates, where they are fully effective and not in the complete core of the elastic material In another embodiment the elastomeric granulate is a rubber granulate.
In another embodiment the elastomeric granulate comprises any one of the following: rubber, an elastomeric polymer, Metallocene Butadiene Rubber, nitrile rubber granulate, natural rubber granulate, styrene-butadiene rubber granulate, ethylene propylene diene monomer rubber granulate, black crumb rubber granulate, acrylonitrile butadiene rubber, a thermoplastic polymer, Styrene Ethylene Butylene Styrene, Styrene Block Copolymers, and combinations thereof.
In a further embodiment the granulate is an elastic foam.
In a further embodiment the granulate is an elastic PU foam
In another embodiment the granulate has an average diameter between 0.1 mm and 3.0 mm.
In another embodiment the granulate has a maximum diameter of less than 5.0 mm.
In another embodiment the at least one first and/or second type of pigment comprises an inorganic pigment, an organic pigment or mixtures hereof.
In another embodiment the at least one first and/or second type of pigment comprises any one of the following: iron oxide, iron oxide hydroxide, chromium(III) oxide, a copper phythalocyanine pigment, a nickel azopigment, titanium oxide and combinations thereof.
In another embodiment the at least one type of additive is hindered amine light stabilizer (HALS) which is able to protect the PU coating as well as the elastic and/or compression resilient granulate against UV degradation.
In another embodiment the at least one type of additive is a thermostabilizing agent, protecting the elastic and/or compression resilient granulate against thermal degradation.
In another embodiment the at least one type of additive is an anti-freeze/deicing additive of the group: sodium chloride, potassium chloride, calcium chloride, sodium formiate, potassium formiate or a mixture hereof. The additive is migrating into the neighborhood of the granulate and by this inhibits the formation of ice by freezing humidity between the infill granulate particles.
In another embodiment the fluid binding agent further comprises any one of the following: a surfactant, a polyurethane aliphatic isocyanate, a polyurethane aromatic isocyanate, zeolite, an antibacterial agent, silver, IR reflective pigment, and combinations thereof.
In another embodiment the polymer component comprises any one of the following: at least one type of monomer, at least one type of partially polymerized polymer, and combinations thereof.
In another embodiment the polymer component is cured into at least one type of polyurethane by the water and the catalyst.
For example the polymer component could be methylene diphenyl diisocyanate. The polymer component could also comprise polyols.
In another embodiment the catalyst comprises any one of the following: an amine catalyst and a metal organic catalyst.
In another embodiment the method further comprises drying the subsequent composition before providing the granulate as the artificial turf infill.
It may also be possible to dry the initial composition after coating the granulate with the initial coating; however, it is not necessary. The water, which is leftover from the formation of the initial coating on the elastic and/or compression resilient granulate may be used in the reaction of the subsequent composition.
In another embodiment the method is at least partially performed in a flow reactor. In the flow reactor the granulate is slowly moved along a linear sequential path, where the granulates are generally mixed and moved along. The benefit of using a flow reactor is that the artificial turf infill may be produced on a continuous basis.
In another embodiment the method is at least partially performed as a batch process. The initial coating is formed on the granulate during an initial batch and the subsequent coating is formed on the granulate during a subsequent batch. Forming the initial coating and the subsequent coating in separate batches may be beneficial because it may enable precise control over the formation of the initial and subsequent coatings.
In another aspect the invention provides for a method of manufacturing artificial turf. The method comprises installing an artificial turf carpet. The artificial turf carpet comprises multiple artificial turf fiber tufts. For example, the artificial turf carpet may be a tufted artificial turf carpet. There may be a backing which has tufts of artificial grass fibers tufted into it. The method further comprises providing the artificial turf by spreading a layer of artificial turf infill between the multiple artificial turf fiber tufts. The artificial turf infill comprises a granulate. The granulate comprises at least two outer coatings. Each of the two outer coatings comprises at least one first and/or second type of pigment and a binding agent. The binding agent comprises at least one type of polyurethane polymer. This method may be beneficial because the artificial turf infill may be more completely covered with the two outer coatings. This may for instance provide superior optical appearance of the artificial turf infill. It may also provide better wear and longevity of the artificial turf infill.
In another embodiment, the two outer coatings each have a thickness of less than any one of the following: 0.1 mm, 0.075 mm, 0.05 mm, and 0.01 mm. This embodiment may be beneficial because it may provide a means of reducing the amount of fluid binding agent necessary for coating the granulate.
In another embodiment, the at least two outer coatings each comprise gaps. In other words the at least two outer coatings each incompletely covers the granulate and each of the two outer coatings has gaps.
The gaps in the at least two outer coatings may be distributed randomly on the surface of the granulate. Some of the gaps in the at least two outer coatings may line up. However, many of the gaps in the at least two outer coatings will be at different locations on the surface of the granulate. The result is that there will likely be a few places where the underlying granulate is exposed. However the majority of the surface of the granulate will be coated. Using the double coating may greatly reduce the amount of fluid binding agent necessary to coat the granulate.
In another embodiment the method further comprises manufacturing the artificial turf infill according to an embodiment.
In another embodiment the granulate comprises at least two outer coatings. Each of the two outer coatings comprises at least one first and/or second type of pigment and a binding agent. The binding agent comprises at least one type of polyurethane polymer. This artificial turf infill may have the benefit that the use of the two outer coatings enables more complete coverage of the grains or particles of the artificial turf infill.
In another aspect, the invention provides for an artificial turf. The artificial turf comprises an artificial turf carpet. The artificial turf carpet comprises multiple artificial turf fiber tufts. The artificial turf further comprises artificial turf infills spread between the multiple artificial fiber tufts. The artificial turf infill comprises a granulate. The granulate comprises at least two outer coatings. Each of the two outer coatings comprises at least one first and/or second type of pigment and a binding agent. The binding agent comprises at least one type of polyurethane polymer.
The use of the artificial turf infill with the two outer coatings may provide superior wear or longevity of the artificial turf. It may also provide superior optical appearance as the artificial turf infill may be more uniformly pigmented if the pigments in the two layers are identical. The pigments can also be selected so that the artificial turf infill has a patch work of different colors. This may make the artificial turf infill look more natural and earth-like.
In another embodiment, the two outer coatings each have a thickness of less than any one of the following: 0.1 mm, 0.075 mm, 0.05 mm, and 0.01 mm. This embodiment may be beneficial because it may provide a means of reducing the amount of fluid binding agent necessary to coating the granulate.
In another embodiment, the at least two outer coatings each comprise gaps. In other words the at least two outer coatings each incompletely covers the granulate and each of the two outer coatings has gaps.
The gaps in the at least two outer coatings may be distributed randomly on the surface of the granulate. Some of the gaps in the at least two outer coatings may line up. However, many of the gaps in the at least two outer coatings will be at different locations on the surface of the granulate. The result is that there will likely be a few places where the underlying granulate is exposed. However the majority of the surface of the granulate will be coated. Using the double coating may greatly reduce the amount of fluid binding agent necessary to coat the granulate.
In another embodiment the granulate has an average diameter between 0.45 mm and 2.0 mm.
In another embodiment the granulate has a maximum diameter of less than 4 mm.
In another embodiment, the artificial turf fiber tufts are arranged in rows. The artificial turf fibers have a row of space in between 0.5 cm and 1.95 cm. This corresponds approximately to ⅜″ to ¾″.
In another embodiment the artificial turf covering has a pile height between 2.5 cm and 7.5 cm. The pile height is the length of the artificial turf fibers above the backing or base of the artificial turf carpet.
It is understood that one or more of the aforementioned embodiments of the invention may be combined as long as the combined embodiments are not mutually exclusive.
In the following embodiments of the invention are explained in greater detail, by way of example only, making reference to the drawings in which:
Like numbered elements in these figures are either equivalent elements or perform the same function. Elements which have been discussed previously will not necessarily be discussed in later figures if the function is equivalent.
It is also possible to perform further coatings on the grain 100 or granule 100.
If it were desired to ensure that there are no gaps in the coatings the at least one pigment could be used again. In other cases additional additives may be added to form a functional further coating 400. For example a flame retardant such as polyurethane oliphatic isocyanates could be added. To provide for the absorption and de-absorption of water, to cool the carpet a zeolite could be added. Also various antibacterial or antifungal agents could be added too. In other examples an infrared reflection agent such as EPDM may be used to reduce the amount of heat absorbed by the artificial turf infill and/or also to help protect it from sunlight.
The apparatus depicted in
As the initial composition 1120 is transported further along the flow reactor 1100 fluid binding agent and at least one pigment cure into the initial coating 200 such as depicted in
The subsequent composition 1122 is mixed and transported underneath the second inlet for water and catalyst 1116. The water and catalyst are then mixed with the subsequent composition 1122 and over time are further transported to the end of the flow reactor 1100. By the time the subsequent composition 1122 has reached the end of the flow reactor 1100 the subsequent coating 300 has formed on the grains or particles of the granulate 1006 such as depicted in
It is clear from
Number | Date | Country | Kind |
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16159975.8 | Mar 2016 | EP | regional |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2017/054964 | 3/2/2017 | WO | 00 |