This application relates to a method and apparatus for collimating a beam.
The fabrication of microscale and nanoscale devices such as semiconductor dies, quantum computing devices and optical waveguide structures, will typically involve building up a substrate through the deposition of multiple layers of material in different patterns over a wafer. The overall process will involve multiple steps as the different layers are built up. Though the terminology is not always used consistently in the art, for the present purposes the “wafer” will be taken herein to refer to the base layer, and the “substrate” will refer to the wafer and any additional layers which may have been added to the wafer up to the present point in the fabrication process.
For example, in the fabrication of a traditional semiconductor device, the wafer comprises a semiconductor such as silicon with differently doped n- and p-type regions. The material being deposited at any given subsequent layer may then for example be a conductor, a further layer of semiconductor, or a dielectric or other insulator (with different kinds of material typically being deposited at different respective layers). In the case of fabricating a quantum electronic device such as a quantum computing device, the wafer may be a semiconductor or an insulator, and the deposited materials may be conductors, insulators, semiconductors and/or superconductors. For instance, as a basis for a quantum circuit, lines of semiconductor are formed over an insulating substrate, and then a coating of superconductor is formed over the semiconductor lines to form a network of semiconductor-superconductor nanowires.
Vacuum deposition refers to fabrication techniques whereby a layer of material is deposited onto a substrate while in vacuum within a vacuum chamber. The material may for example be deposited in the form of a molecular or atomic beam flux (directional). The material is initially deployed in its source form (e.g. liquid or solid) in a source cell, which is located in the vacuum chamber or has an opening into the vacuum chamber. The material is then energized in the source cell such as through heating or ionization, causing it to be projected from the source cell through the vacuum toward the substrate, which is also deployed in the vacuum chamber. For instance, one form of vacuum deposition is molecular beam epitaxy. In this case a source cell is arranged to heat the source material, causing it to evaporate or sublime. The source cell is arranged to eject the evaporated or sublimated molecules or atoms through the vacuum toward the substrate in the form of a molecular or atomic beam. The particles then condense on the substrate in a crystalline form. Other forms of vacuum deposition are also known, such as chemical beam epitaxy, or thin film deposition systems (e.g. E-beam evaporation, thermal evaporation or Ion milling). Various forms of vacuum deposition and the various material that can be deposited to form various kinds of structure will, in themselves, be familiar to a person skilled in the art.
To form the desired pattern, the traditional approach is lithography which uses a photo resist as a mask. A patterned photo resist, i.e. a photo mask, is deposited on the substrate and then a pattern is defined by shining light (UV) through the photo resist. The illuminated areas react by changing their chemical composition. Openings are then washed out after chemically developing the resist. These openings can be used either to etch the underlying material through them or deposit subsequent materials. Thus, photoresist acts as a kind of mask. After that the photo resist is removed using solvents.
Other, less conventional techniques may employ a shadow mask as a separate object (not a layer or structure deposited on the substrate). In this case the mask comprises a pattern of perforations defining a structure to be formed on the underlying substrate. Such a mask may also be referred to as a stencil type mask, as opposed to a photo mask. The material is projected from the source through the mask onto the substrate, so as to be deposited only where the mask is perforated (i.e. only where the gaps or holes are). The material then solidifies on the underlying substrate and thus grows a structure on the substrate, with a pattern corresponding to that of the perforations in the mask. On another point of terminology, note that “over” or such like herein does not necessarily mean with respect to gravity, but rather is to be understood in the sense of covering the wafer (or at least part thereof) on the side being worked, i.e. the side upon which the deposition is currently being performed. In the case of the mask this means between the wafer and the source (though not necessarily in physical contact with the wafer). A reciprocal interpretation should also be given to terms such as “underlying”.
The inventors have identified the problem of realising small structures such as nano-size structures with little line broadening due to the geometry and setup of the fabrication system. The distance between the substrate and the opening angle subtended by the source from the perforations in the mask determine the broadening of features in the prior art. The dependency of the accuracy of the nanostructures produced to these dimensions presents challenges for fabricating defined features accurately.
The inventors have devised a stencil mask comprising two mask layers which collimate the incoming beam of atoms, thus making the line broadening dependent on the geometry of the stencil mask instead of the geometry of the overall fabrication setup.
According to one aspect disclosed herein there is provided a method for collimating a beam of material being deposited on a substrate at a deposition area of the substrate, the method comprising: masking the substrate with a stencil mask located at a mask distance from the substrate, the mask distance being the distance between a top face of the substrate and an outer face of the mask facing the substrate; and projecting the beam from a source cell located at a source distance from the mask, the source distance being the distance between the source cell and an outer face of the mask facing the source cell; wherein the stencil mask comprises two mask layers separated by a layer separation distance which is great than zero, each layer comprising a slit, the slits of the two layers having a width being aligned in a plane of the substrate.
According to a second aspect disclosed herein, there is provided a stencil mask comprising: two mask layers; a separation layer which separates the two mask layers by a layer separation distance which is greater than zero; wherein each mask layer comprises a slit, the slits being aligned in a plane of the mask; wherein the separation layer comprises a void which is aligned with the slits in the plan of the mask and is wider than the slits.
According to a third aspect of the present disclosure, there is provided a method for fabricating the stencil mask, the method comprising: growing a first of the two mask layers on a first wafer; patterning said first mask layer; growing a second of the two mask layers on a second wafer; patterning said second mask layer; and affixing the two wafers together, such that the two mask layers are separated by the two wafer layers, the two wafer layers having a combined thickness equal to the layer separation distance.
For better understanding of the present invention, and to show how embodiments may be carried into effect, reference is made, by way of example only, to the following figures.
As described above, stencil masks may be used to produce semiconductor-superconductor (SE/SU) elements for use in, for example, quantum computing. During the fabrication process, a deposition material is deposited on a substrate. The substrate may comprise a silicon wafer with semiconducting nanowires on it, for example. The wafer may be an insulating GaAs wafer, or it may be a silicon wafer. The nanowires may be grown using selective area growth (SAG). The nanowires may, for example, be made of InAs.
The deposition material is deposited in a desired pattern on the substrate in order to form the required features on the substrate. Such features may include contacts for wires, superconducting (SU) elements, or a SU coating. The deposition material may be a superconductor, such as aluminium. The apparatus and method described herein may also be used to produce dielectric elements, where a dielectric deposition material is used. It could also be used when the deposition material is a metal or a semiconductor. The fabrication processes described herein may be performed in a vacuum.
The source cell 12 contains the deposition material to be deposited on the substrate 13 in its source from. In order for the material to be deposited, the deposition material at the source is energised. This can be achieved by heating the material, for example via resistive or indicative heating, so that the material evaporates or sublimes. Alternatively, the source material may be ionised. Once the source material has been energised, it can be released from the source cell 12 as a beam 20 and projected towards the substrate 13. The source cell has a width A which is defined as the width from which the energised deposition material bean 20 is projected.
The stencil mask 15 is positioned between the source cell 12 and the substrate 13, so masking the substrate from some of the deposition material projected from the source cell 12. It comprises a single mask layer 10 formed on a wafer 14. The mask layer 10 contains a slit 11, through which the deposition material in the beam 20 passes. The slit 11 is, therefore, used to define an incident area on the substrate 13 at which the beam 20 is incident. In material deposition, the incident area may also be referred to as a deposition area 17. The material in the beam 20 is deposited at the deposition area 17, where it condenses to form a crystalline structure.
Using the set-up shown in
The stencil mask 16 comprises two mask layers 10a, 10b. The two mask layers 10a, 10b are separated by a layer separation distance D which is greater than zero. There is a separation layer between the two mask layers 10a, 10b. In this example, the separation layer comprises two wafers 14a, 14b, which may be, for example, silicon wafers. It will be appreciated that the separation layer may comprise a single layer or multiple layers. It may be made of silicone or a different material. The layers within the separation layer may be made of the same material as each other, or they may be different materials. In the example of
The mask layers 14a, 14b each contain a slit 11a, 11b. These slits 11a, 11b are aligned in a plane of the substrate. It will be appreciated that the slits 11a, 11b are also aligned in the plane perpendicular to the beam, such that the beam 20 of deposition material passes through both slits 11a, 11b to reach the substrate 13. The slits 11a, 11b in the two layers need not be identical in size, however there is an improved collating effect if the slits 11a, 11b are the same size or if the slit 11b closest to the source cell 12 is smaller than the slit 11a closest to the substrate 13. It will be appreciated that there may be more than one slit in each mask layer 10a, 10b, as shown in the example mask layer 10 of
The use of the double-layered stencil mask 16 provides a means for collimating the beam 20.
It should be noted that the source cell 12 projects deposition material from its entire width A, but only material projected from the reduced effective source cell width A′ is deposited on the substrate 13.
On passing through the first slit 11b, the beam has a first opening angle 19a. This angle is a function of the width of the first slit 11b and the source distance B. The second slit 11a through which the beam passes has the effect of reducing the opening angle of the beam exiting the stencil mask 16 to a second opening angle 19b. This second opening angle 19b is a function of the layer separation distance and the width of the second slit 11a. The deposition area 17 is a function of the second opening angle 19b. The second slit 11a effectively removes the dependency of the deposition area 17 on the source distance B and the mask distance C.
The advantage of the double-layered stencil mask 16 over the stencil mask 15 shown in
The source distance B may be between 20 cm and 1 m. The mask distance C may be between 1 μm and 10 μm. The source cell width A may be between 5 mm and 50 mm. For a given source cell width A, source distance B, mask distance C, and slit width, the deposition area 17 is smaller when the double-layered stencil mask 16 is used instead of the single-layered stencil mask 15.
It can be seen from
It will be appreciated that, although the stencil mask 16 illustrated in
Using the materials discussed above, the resulting structure is a SE/SU component. It will be appreciated that the stencil mask 16 and the methodology described above may be used to produce other types of components when different materials are used as the substrate 13 and the deposition material. For example, the stencil mask 16 may be used to fabricate optical devices. Examples of such devices include waveguides, optical resonators, and diffraction gratings.
The stencil mask 16 may be fabricated via the following steps.
On a blank wafer 14a for use as one of the layers of the separation layer, the mask layer 10a is grown to its desired thickness. The mask layer 10a may be grown via low pressure chemical vapour deposition (LPCVD). The mask layer 10a is then patterned with the desired pattern of the apertures of the stencil mask 16. Patterning may be achieved using etching or a lithographic technique, such as photolithography. Other techniques such as mechanical patterning may be used to define and produce the pattern of apertures in the mask layer 10a.
The second mask layer 10b is grown on a second blank wafer 14b for use as the second layer of the separations layer. The mask layer 10b may be grown using the same techniques as the first mask layer 10a, or a different technique may be used. The second mask layer 10b is patterned. Again, this may be using the same technique or a different technique to that used for the first mask layer 10a.
Once both mask layers 10a, 10b have been patterned, the two halves of the stencil mask 16 are fixed together such that the mask layers 10a, 10b are on the outside of the stencil mask 16. That is, the exposed faces of the wafers 14a, 14b are affixed. Methods for affixing two silicon wafers are known in the art. The two wafers 14a, 14b form the separation layer of the stencil mask 16, such that the total thickness of the two wafers is equal to the layer separation distance D.
For a stencil mask 16 which comprises more than two layers, the steps of growing the mask layer on a wafer and patterning the mask layer are performed for the additional layers. These are then affixed to the double-layered stencil mask to form a stencil mask comprising more than two mask layers 10.
In some embodiments, there may be more than two wafers forming the separation layer of the stencil mask 16. Additional wafers may be introduced to increase the separation distance. A third wafer may, for example, be affixed to the exposed faces of the two wafers 14a, 14b such that the separation layer is formed of three wafers. It will be appreciated that any number of additional wafers may be introduced between the wafers 14a, 14b on which the mask layers 10a, 10b have been grown.
In the above embodiments, the source cell 12 has produced a beam 20 of the deposition material, such that the deposition of the material is directional. Directional deposition of the deposition material is preferable, however, any physical vapour deposition (PVD) method may be used. Other material projection methods may be used which project the deposition material at the substrate in a multi-directional manner. For example, plasma-enhanced chemical vapour deposition (PECVD) or sputter deposition may be used to project the deposition material. The disadvantage of using a multi-directional deposition method is that the there is an increase of the rate at which material is deposited on the side walls of the apertures in the stencil mask compared to when a beam deposition method is used. This decreases the reusability of the stencil mask, and, in some cases, the apertures may become blocked at a rate which is too high for the stencil mask to be used in practice. Thus, the use of multi-directional material deposition in the fabrication process may reduce the scalability of fabrication of the resultant components.
The portions of semiconductor 4 are formed over the wafer 2 by any suitable known deposition technique. Although not shown, there may be a coating of ferromagnetic insulator grown at least partially on each of some or all of the semiconductor portions 4. This layer may be grown by means of epitaxy.
Optionally one or more further layers may be formed over semiconductor 4.
In some cases, the oxide layer 8 may be used only in samples during experimentation stages, or as an intermediate step in the fabrication, but may not remain in the final product.
In further examples, there could be other alternative or additional layers formed over the semiconductor 4, such as conductive vias between the semiconductors 4, and/or between the semiconductors 4 and one or more other components. As another example, an upper protective layer of plastic or wax may be formed over the whole structure.
Note that the
Contacts 402 of the quantum circuit 400 have been added to the SE//SU nanowires, to allow electrical connection therewith. Sidegates 404 are shown which are formed of a gating material. These sidegates are designed for manipulating the SE//SU nanowires, and—in the context of topological quantum computing, for example—for manipulating Majorana zero modes hosted by the SE//SU nanowires, in order to perform quantum computations.
As discussed above, the disclosed technique may be used to deposit a number of different materials on the substrate 13. It will be appreciated that the substrate 13 shown in
In some embodiments, the above described technique may be used to deposit the semiconducting material, which will form the SE//SU nanowire, on the substrate 13.
The disclosed technique may also be used to deposit the gating material used to form the sidegates 404. In such a use, the deposition material may be a metal.
Additionally or alternatively, the deposition material may be a superconductor or metal for forming the contacts 402 of the quantum circuit 400.
Some structures require multiple layers of material to be deposited on the substrate 13. These layers may be formed of the same deposition material or they may be formed of different materials. The same set-up and method as described above can be used to deposit these additional layers of deposition material on the substrate 13. If the same deposition areas 17 are required for subsequent depositions, the same stencil mask 16 can be used. If a different deposition pattern, that is the pattern created by the deposition areas 17 when using a stencil mask 16, are required, then the stencil mask 16 can be replaced with a second stencil mask 16 which has a different pattern of apertures, so creates a different deposition pattern on the substrate 13.
It will be appreciated that the above embodiments have been described by way of example only.
More generally, according to one aspect disclosed herein there is provided a method for collimating a beam of material being deposited on a substrate at a deposition area of the substrate, the method comprising: masking the substrate with a stencil mask located at a mask distance from the substrate, the mask distance being the distance between a top face of the substrate and an outer face of the mask facing the substrate; and projecting the beam from a source cell located at a source distance from the mask, the source distance being the distance between the source cell and an outer face of the mask facing the source cell; wherein the stencil mask comprises two mask layers separated by a layer separation distance which is great than zero, each layer comprising a slit, the slits of the two layers having a width being aligned in a plane of the substrate.
In some embodiments, a first opening angle may be a function of the source distance and a width of the slit in a first of the two mask layers, and the slit in the second of the two mask layers may reduce the opening angle to a second opening angle which is a function of the layer separation distance and the width of the slit in the second of the two mask layers, wherein the deposition area may be a function of the second opening angle.
In some embodiments, for a given source cell width, source distance, and mask distance, the deposition area may be smaller when using the stencil mask than the deposition area when using a single mask layer of the stencil mask.
In some embodiments, the stencil mask may prevent the beam projected from the extremities of the source cell from being deposition on the substrate, such that the beam deposition on the substrate is projected from an effective source cell width which is smaller than the width of the source cell.
In some embodiments, the layer separation distance may be between 100 μm and 1 mm.
In some embodiments, the source cell may have a width of between 5 mm and 50 mm.
In some embodiments, the mask distance may be between 1 μm and 10 μm.
In some embodiments, the source distance may be between 20 cm and 1 m.
In some embodiments, each mask layer may have a thickness of between 20 nm and 200 nm.
In some embodiments, the stencil mask may comprise a separation layer which separates the two mask layers by the separation distance.
In some embodiments, the separation layer may comprise a void, the void being disposed between the slits in the two mask layers in the plane perpendicular to the beam and being wider than said slits.
In some embodiments, the source cell may comprise a deposition material and the beam may be a beam of the deposition material, wherein the deposition material is deposited at the deposition area of the substrate.
In some embodiments, the deposition material may be deposited on the substrate via directional deposition.
In some embodiments, the deposition material may be a superconductor.
In some embodiments, the separation layer may comprise one or more silicon wafers.
In some embodiments, the two mask layers may be made of silicon nitrite or silicon.
In some embodiments, the substrate may comprise a silicon wafer.
According to a second aspect disclosed herein, there is provided a stencil mask comprising: two mask layers; a separation layer which separates the two mask layers by a layer separation distance which is greater than zero; wherein each mask layer comprises a slit, the slits being aligned in a plane of the mask; wherein the separation layer comprises a void which is aligned with the slits in the plan of the mask and is wider than the slits.
In some embodiments, there may be provided a system for collimating a beam, the system comprising: the stencil mask; and a source cell for projecting a beam, the source cell being located at a source distance from the stencil mask, the source distance being the distance between the source cell and an outer face of the mask facing the source cell.
In some embodiments, the source cell may comprise a deposition material and the beam may be a beam of the deposition material; and the system may comprise a substrate on which the deposition material is deposited, the substrate being located at a mask distance, the mask distance being the distance between a top face of the substrate and an outer face of the mask facing the substrate, wherein the deposition material may be deposited at a deposition area of the substrate.
According to a third aspect of the present disclosure, there is provided a method for fabricating the stencil mask, the method comprising: growing a first of the two mask layers on a first wafer; patterning said first mask layer; growing a second of the two mask layers on a second wafer; patterning said second mask layer; and affixing the two wafers together, such that the two mask layers are separated by the two wafer layers, the two wafer layers having a combined thickness equal to the layer separation distance.
In some embodiments, the mask layer may be made of silicon nitride and the wafer may be made of silicon, wherein the mask layer may be grown on the wafer via low pressure chemical vapour deposition.
In some embodiments, the mask layer may be patterned using a lithographical technique.
Other variations and applications of the disclosed techniques may become apparent to the person skilled in the art once given the disclosure herein. The scope of the present disclosure us not limited by the above-described embodiments, but only by the accompanying claims.
Filing Document | Filing Date | Country | Kind |
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PCT/EP2019/070387 | 7/29/2019 | WO |