Patent Grant
10442161
The present application is the U.S. national stage of International Patent Application PCT/EP2016/069323 filed internationally on Aug. 15, 2016, which, in turn, claims priority to European Patent Application No. EP 15181016.5 filed on Aug. 14, 2015.
The invention relates to a composite pane, in particular a side window pane of a vehicle, with an illuminated border as well as a method for production thereof and use thereof.
Composite panes comprise at least one outer pane, one inner pane, and one adherable intermediate layer that areally bonds the outer pane to the the inner pane. Typical intermediate layers are polyvinyl butyral films, which have, in addition to their adhesive properties, high toughness and high acoustic damping. The intermediate layer prevents the disintegration of the composite glass pane in the event of damage. The composite pane merely cracks but remains dimensionally stable.
Composite panes have clear advantages compared to single-pane safety glass: High acoustic insulation can be obtained by means of a composite pane, which is, for example, particularly advantageous for the separation of motor vehicle interiors from their external environment. Consequently, in addition to windshields, side windows of motor vehicles are also increasingly made of composite glass. At the same time, a composite pane has greater penetration inhibition than a single-pane safety glass and is thus more stable against penetration of foreign bodies or break-in attempts.
The object of the present invention is to provide an improved composite pane with a border illuminable at least in sections. Integration of the illumination into the composite pane should be simple and cost-effective.
The object of the present invention is accomplished according to the invention by a composite pane according to this disclosure. Preferred embodiments are apparent from this disclosure.
The composite pane according to the invention comprises at least:
In an advantageous embodiment, the composite pane according to the invention is a laminated side pane that is intended for a, preferably openable, side window of a vehicle. The term “an openable side window” means a side window that can be opened and closed again by substantially vertical displacement of the side window into the vehicle door.
The terms “outer pane” and “inner pane” serve merely to distinguish a first pane and a second pane. In the case of use of the composite pane as a vehicle pane or as a building pane, the outer pane is preferably but not necessarily turned toward the exterior of the composite pane; and the inner pane, toward the interior.
The glass fiber according to the invention is a light-diffusing glass fiber that emits light by diffusion via its side wall over its extension length. Such glass fibers are usually made of at least a glass fiber core that is surrounded by one or a plurality of sheath-shaped layers arranged around the glass fiber core. The sheath layers usually have a large number of diffusion centers, for example, nanopores or nanoparticles. Suitable light-diffusing glass fibers are well known to the person skilled in the art. Merely by way of example, reference is made here to the glass fibers mentioned in US 2011/0122646 A1 or US 2015/0131955 A1. The thickness of the glass fiber is typically from 5 μm to 300 μm, preferably from 100 μm to 250 μm. Of course, as a result of suitable production or processing, the glass fiber can also have light-diffusing regions only in sections. The glass fiber has at least one glass fiber section or glass fiber region that is implemented such that, by diffusion, light can be emitted or is emitted over an extension length of the glass fiber section or glass fiber region. The glass fiber can, in particular, be implemented such that, over its entire extension length, light can be or is emitted via the sidewall. In the context of the present invention, the term “light-diffusing glass fiber” also means a bundle or braid of a plurality of individual glass fibers that are arranged as a unit in the region of the cutback.
The intermediate layer according to the invention has, at least in sections, a cutback relative to a side edge. Here, the term “cutback” means any offset or any shortening of the intermediate layer relative to the pane edge. This also means, in particular, an intermediate layer, produced by production technology such that it has an offset relative to the pane edge (without necessarily having to be cut). In an advantageous embodiment of the composite pane according to the invention, the width r of the cutback is from 0.1 μm to 2 mm and preferably from 0.1 mm to 1 mm. This is particularly advantageous, since in this manner good fixing of the glass fiber on the the composite pane is effected. If the side edge of the outer pane is not arranged flush with the side edge of the inner pane, the width r of the cutback is based on the side edge of the pane that is set back relative to the other pane.
In another advantageous embodiment of the composite pane according to the invention, the width r of the cutback is from 10% of the diameter d of the glass fiber to 400% of the diameter d and preferably from 50% of the diameter d to 200% of the diameter d, particularly preferably from 70% of the diameter d to 150% of the diameter d. This is particularly advantageous, since in this manner good fixing of the glass fiber on the composite pane is enabled. In particular, in the preferred range from r=70% d to 150% d, the glass fiber is almost completely protected by the outer pane and the inner pane. In particular, the width r of the cutback is from 100% d to 150% d such that the glass fiber is arranged completely in the region of the cutback.
In another advantageous embodiment of the composite pane according to the invention, the glass fiber is glued by an adhesive means into the region of the cutback and, in this manner, fixedly bonded to the interior-side surface II of the outer pane, the exterior-side surface III of the inner pane, and/or the side edge of the intermediate layer. This has the particular advantage that the glass fiber is fixedly bonded to the composite pane.
Particularly advantageous adhesive means are adhesives, particularly preferably acrylate adhesives, methyl methacrylate adhesives, cyanoacrylate adhesives, polyepoxides, silicone adhesives, and/or silane cross-linking polymeric adhesives, mixtures, and/or copolymers thereof.
In an alternative embodiment of the composite pane according to the invention, the glass fiber is fastened in the region of the cutback by clamping between the outer pane and the inner pane. This has the particular advantage that no adhesive means and no special process step is necessary for fixing the glass fiber in the composite pane.
The outer pane and/or the inner pane preferably contain glass, in particular soda lime glass, or plastics, preferably rigid plastics, in particular polycarbonate or polymethylmethacrylate. The thickness of the panes can vary greatly and thus be ideally adapted to the requirements in the individual case. Preferably, the thicknesses of the outer pane and of the inner pane are from 0.5 mm to 10 mm and preferably from 1 mm to 5 mm, most particularly preferably from 1.4 mm to 3 mm.
The outer pane, the inner pane, or the intermediate layer can be clear and colorless, but also tinted, frosted, or colored. The outer pane and the inner pane can be made of non-prestressed, partially prestressed, or prestressed glass.
The intermediate layer is formed by at least one thermoplastic bonding film. The thermoplastic bonding film contains at least one thermoplastic polymer, preferably ethylene vinyl acetate (EVA), polyvinyl butyral (PVB), or polyurethane (PU) or mixtures or copolymers or derivatives thereof. The thickness of the intermediate layer and, in particular, of the thermoplastic bonding film is preferably from 0.2 mm to 2 mm, particularly preferably from 0.3 mm to 1 mm, for example, 0.38 mm or 0.76 mm.
In another advantageous embodiment, the composite pane according to the invention has heating means for electrical heating of the composite pane. Preferred heating means are electrically conductive wires and/or one or a plurality of electrically heatable, transparent, electrically conductive layers.
The side pane according to the invention can have other functionalities besides the heating function effected by the heating means. In an advantageous embodiment, the composite pane has a reflecting coating for the infrared range. Such a coating can be applied on a surface of the outer pane or on a surface of the inner pane, preferably on a surface facing the intermediate layer, in order to protect the coating against corrosion and mechanical action. Alternatively, the coating can be introduced into the composite, in the form of a coated thermoplastic film, for example, made of polyethylene terephthalate (PET). In this case, the coated film is preferably arranged between a first and a second thermoplastic bonding film. IR-reflecting coatings typically have at least one electrically conductive layer. Additionally, the coating can have dielectric layers that serve, for example, to regulate the sheet resistance, to protect against corrosion, or to reduce reflection. The conductive layer preferably contains silver or an electrically conductive oxide (transparent conductive oxide, TCO) such as indium tin oxide (ITO). The conductive layer preferably has a thickness of 10 nm to 200 nm. To improve conductivity with simultaneously high transparency, the coating can have a plurality of electrically conductive layers that are separated from one another by at least one dielectric layer. The conductive coating can include, for example, two, three, or four electrically conductive layers. Typical dielectric layers contain oxides or nitrides, for example, silicon nitride, silicon oxide, aluminum nitride, aluminum oxide, zinc oxide, or titanium oxide. Of course, these electrically conductive, transparent coatings can also serve for the electrical heating of the pane. The coating preferably has a smaller surface area than the side pane such that a peripheral edge region with a width of preferably 0.5 mm to 10 mm is not provided with the coating. The conductive coating is thus protected inside the intermediate layer against contact with the surrounding atmosphere, which is advantageous in terms of the prevention of corrosion. The composite pane can also have other uncoated regions, for example, data transmission windows or communication windows.
Another aspect of the invention is a composite pane arrangement, at least comprising:
The lighting means is preferably arranged on one side edge of the composite pane. In the case of a movable composite pane, such as an openable side window pane, the lighting means is preferably connected to the composite pane and likewise arranged movably. Of course, the lighting means can also be installed independent of the composite pane and can be connected to the light-diffusing glass fiber according to the invention via a preferably non-light-diffusing glass fiber.
Advantageous lighting means are, for example, laser diodes, light-emitting diodes (LEDs), or incandescent bulbs, with the invention including any type of light source that is suitable for a respective use. The lighting means according to the invention also include lens systems, mirror systems, reflector systems, or other light guides that can serve for the coupling of the light into the glass fiber according to the invention.
The lighting means can be colored or white. The lighting means can also give off light in the ultraviolet range, so long as the glass fiber or its surroundings can convert the ultraviolet light into visible light. Preferred light colors are red (due to the pronounced signaling effect), green (due to the high sensitivity of the human eye for the green color spectrum), and blue (due to its particularly aesthetic and less dazzling effect).
Another aspect of the invention is a method for producing a composite pane according to the invention, at least comprising:
(a) Arranging a thermoplastic intermediate layer between an outer pane and an inner pane, wherein the intermediate layer has at least one cutback relative to the side edges of the pane,
(b) Bonding the outer pane to the inner pane via the intermediate layer by lamination,
(c) Gluing a light-diffusing glass fiber into a region of the cutback with an adhesive means.
Of course, the process steps b) and c) can also be reversed.
This method can be improved by the following alternative method for producing a composite pane according to the invention, which at least comprises:
(a) Arranging a thermoplastic intermediate layer between an outer pane and an inner pane,
(b) Bonding the outer pane to the inner pane via the intermediate layer by lamination,
(c) Cutting back, at least in sections, the thermoplastic intermediate layer between the outer pane and the inner pane with a cutting tool,
(d) Gluing a light-diffusing glass fiber into a region of the cutback with an adhesive means.
The production of the composite glass by lamination is done with customary methods known per se to the person skilled in the art, for example, autoclave methods, vacuum bag methods, vacuum ring methods, calender methods, vacuum laminators, or combinations thereof. The bonding of the outer pane and the inner pane is customarily done under the action of heat, vacuum, and/or pressure.
A cutting tool according to the invention is, for example, a blade of a knife, in particular, a V-shaped blade that is guided along the side edge between the outer pane and the inner pane and removes the intermediate layer in a narrow region in the form of a cutback.
A further aspect of the invention includes the use of the composite pane according to the invention in means of transportation for travel on land, in the air, or on water, in particular in trains, watercraft, and motor vehicles, for example, as a windshield, rear window, side window, and/or roof panel, in buildings, in particular in the access area, window area, roof area, or façade area, as a built-in component in furniture and appliances.
The composite pane according to the invention is particularly preferably a glazing that is frameless in sections, wherein the light-diffusing glass fiber according to the invention is arranged on the frameless side edges. The light-diffusing glass fiber can also be arranged on an inner side edge, for example, in the region of a cutout made in the glazing such as a skylight in a roof panel.
The composite pane according to the invention is preferably implemented as a stationary glazing, in other words, the glazing is arranged stationary relative to its surroundings and fixed, for example, by section-wise fastening, for example, as a windshield in a vehicle or as a glass partition in a building or in a piece of furniture.
The composite pane according to the invention is alternatively implemented as a movable glazing, in other words, the glazing is arranged movable relative to its surroundings, for example, as glazing arranged movably in a door, such as a side window pane in a vehicle door.
Another aspect of the invention includes the use of a lighting means according to the invention in a composite pane arrangement for the identification of an electrical function, preferably a heating function, a movement of the composite pane according to the invention, preferably of an opening or closing side window and/or as a warning function, preferably in the case of a frameless side window in an opened vehicle door.
In the following, the invention is explained in detail with reference to drawings and exemplary embodiments. The drawings are schematic depictions and not true to scale. The drawings in no way restrict the invention.
They depict:
The composite pane 10 according to the invention includes an outer pane 1 with an interior-side surface II, an inner pane 2 with an exterior-side surface III, and a thermoplastic intermediate layer 3 that bonds the interior-side surface 11 of the outer pane 1 to the exterior-side surface III of the inner pane 2 via the pane surface. The outer pane 1 and the inner pane 2 are made, for example, of soda lime glass and have, for example, a thickness of 2.1 mm in each case. The thermoplastic intermediate layer 3 is, for example, a film made of polyvinyl butyral (PVB) with a thickness of 0.76 mm. Of course, other glass panes or polymeric panes can also be used as the outer pane and inner pane. Furthermore, the thickness of the outer pane 1 and inner pane 2 can be adapted to the respective use.
The thermoplastic intermediate layer 3 is cut back in the region of the side edge 6 compared to the outer pane 1 or the inner pane 2. A light-diffusing glass fiber 4 is glued into the cut-back region 7, for example, with an adhesive means 5 made of cyanoacrylate adhesive. The light-diffusing glass fiber 4 has a diameter d of 200 μm. The width r of the cutback is, for example, 250 μm. The width r of the cutback corresponds here roughly to the diameter d of the light-diffusing glass fiber 4. A lighting means 20 is arranged on one end of the glass fiber 4. The lighting means 20 consists, for example, of a laser diode, which can, for example, couple light into the glass fiber 4 via a reflector. Upon application of a voltage to the laser diode, light is coupled into the glass fiber 4. The glass fiber 4 diffuses the light on its surface along its entire extension length such that the glass fiber 4 lights up over its entire extension length.
By means of the arrangement of the light-diffusing glass fiber 4 in the cutback 7, the glass fiber 4 is particularly well protected against mechanical stresses. In addition, the glass fiber 4 is hardly visible in the non-illuminated state, which is particularly advantageous from an aesthetic standpoint.
The composite pane 10 is, for example, a side pane of a vehicle door of a passenger car. The border of the side pane in the vehicle door is, for example, frameless, such that the side pane is guided and inserted into the vehicle door only at its lower side. Here, the lighting means 20 is, for example, a high-performance light-emitting diode.
In
The composite pane arrangement 100 produced with this composite pane 10 is, for example, configured such that, upon opening of the vehicle door, the lighting means 20 is activated and the glass fiber 4 is illuminated. This has the particular advantage that the vehicle door is illuminated in the opened state and is particularly well discernible by other road users. The visibility of the composite pane 10 thus illuminated is particularly increased in the darkness—in particular since the composite pane 10 in this example is frameless and is fastened in the vehicle door only at its lower side edge. The side edge of the composite pane 10 illuminated by the glass fiber 4 is thus freely visible without obstruction.
The lighting means 20 can be monochromatic or can identify different states by different colors. Thus, the warning function is particularly high for a red lighting means, since a red color is commonly associated with danger. Green lighting means are readily discerned in the dark since the human eye has particularly high sensitivity for the green color spectrum.
In another exemplary embodiment, the lighting means 20 has, for example, a red light-emitting diode and a blue light-emitting diode. In that case, the composite pane arrangement 100 is connected, for example, to the vehicle's electronic system such that when the composite pane 10 is opened by an electrical window lifter, the glass fiber 4 is illuminated with blue light; and when the composite pane 10 is closed, the glass fiber 4 is illuminated with red light. This has the particular advantage that the direction of movement of the composite pane 10 relative to the doorframe thus becomes visible and individuals can quickly recognize the danger of entrapment of body parts or objects in the closing window. Of course, other colors or white light can also be used for the illumination of the glass fiber 4. Furthermore, other functions can also be indicated by the illumination of the composite pane 10 or particularly aesthetic lighting can be realized.
Composite panes 10 according to the invention can optionally have an additional electrical function and, for example, an electrical heating function. For example, heating means (not shown here), such as heating wires or heating layers can be arranged in the region between the outer pane 1 and the inner pane 2. Such heating wires are made, for example, of copper or tungsten and have a thickness of, for example, 30 μm. Transparent, electrically conductive coatings, as described above, are, for example, known as heating layers. Heating wires and heating layers can be formed, for example, by busbars, for example, strips of a copper foil with a thickness of, for example, 100 μm and a width of, for example, 7 mm. When a voltage is applied to the busbars, a current flows through the heating wires or heating layer, by which means the heating effect is produced. The voltage can be the usual automobile on-board voltage of 14 V, or even a voltage of, for example, 42 V or 48 V. Of course, the voltage can also be a customary supply voltage of, for example, 110 V or 220 V, in particular with the use of a composite pane 10 according to the invention in building technology, such as a transparent heater. The corresponding level of heating of the composite pane 10 can, again, be indicated by the illumination of the glass fiber 4 by the lighting means 20.
| Number | Date | Country | Kind |
|---|---|---|---|
| 15181016 | Aug 2015 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2016/069323 | 8/15/2016 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2017/029254 | 2/23/2017 | WO | A |
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| Number | Date | Country | |
|---|---|---|---|
| 20180194113 A1 | Jul 2018 | US |
