This application is based upon and claims the benefit of priority of the prior Japanese Patent Application No. 2015-215007, filed on Oct. 30, 2015, the entire contents of which are incorporated herein by reference.
The embodiments discussed herein are directed to a compound semiconductor device and a method of manufacturing the same.
Characteristics can be improved by providing a layer in which Fe is introduce at a position under a channel layer in a high electron mobility transistor (HEMT) which contains a gallium nitride (GaN)-based material. Fe forms a deep acceptor level in the vicinity of valence band of GaN, and an electron is captured in the acceptor level, so that leakage current in a thickness direction is suppressed, and pinch-off characteristics are improved.
However, Fe may be diffused from the layer doped with Fe to a region in which two-dimensional electron gas (2DEG) exists in the channel layer, and in this case, mobility of electron is lowered. A structure is proposed for the purpose of suppressing the reduction in the mobility of electron as above, in which a layer of AlN or AlGaN whose Al composition exceeds 40% is disposed between the layer doped with Fe and the GaN channel layer. However, even with this structure, it is not possible to obtain sufficient characteristics.
Patent Literature 1: Japanese Laid-Open Patent Publication No. 2010-182872
Patent Literature 2: Japanese Laid-Open Patent Publication No. 2010-232297
Patent Literature 3: Japanese Laid-Open Patent Publication No. 2008-288474
Patent Literature 4: Japanese Laid-Open Patent Publication No. 2008-251966
According to an aspect of the embodiments, a compound semiconductor device includes: a first layer of nitride semiconductor, the first layer being doped with Fe; a channel layer of nitride semiconductor above the first layer; and a barrier layer of nitride semiconductor above the channel layer, wherein the channel layer includes: a two-dimensional electron gas region in which the two-dimensional electron gas exists; and an Al-containing region between the two-dimensional electron gas region and the first layer, an Al concentration in the Al-containing region being 5×1017 atoms/cm3 or more and less than 1×1019 atoms/cm3.
According to another aspect of the embodiments, a method of manufacturing a compound semiconductor device includes: forming a channel layer of nitride semiconductor above a first layer of nitride semiconductor, the first layer being doped with Fe; and forming a barrier layer of nitride semiconductor above the channel layer, wherein the forming the channel layer includes forming an Al-containing region between a two-dimensional electron gas region in which the two-dimensional electron gas exists and the first layer, an Al concentration in the Al-containing region being 5×1017 atoms/cm3 or more and less than 1×1019 atoms/cm3.
The object and advantages of the invention will be realized and attained by means of the elements and combinations particularly pointed out in the claims.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are not restrictive of the invention.
The inventors of the present application repeatedly conducted earnest studies for finding out the reason why it is not possible to obtain the sufficient characteristics even with the conventional technique. As a result, it was clarified that dislocation due to a large difference in lattice constant between a layer of AlN or AlGaN whose Al composition exceeds 40% and a GaN channel layer, exists in the GaN channel layer in a high density, and leakage current flows via the dislocation or an electron is trapped by the dislocation. As a result of further earnest studies repeatedly conducted by the inventors of the present application based on such findings, the inventors of the present application arrived at the following various embodiments.
Hereinafter, embodiments will be concretely described while referring to the attached drawings.
First, a first embodiment will be described. The first embodiment relates to an example of a compound semiconductor device with HEMT.
As illustrated in
The substrate 101 is, for example, a sapphire substrate, a Si substrate, or a SiC substrate. The substrate 101 is preferably a high-resistance substrate in order to suppress leakage current in a thickness direction. The buffer layer 102 is, for example, a GaN layer, an AlN layer, an AlGaN layer, or an InAlGaN layer, and a thickness of the buffer layer 102 is about 5 nm to 500 nm, for example. The buffer layer 102 may include a plurality of AlGaN layers whose composition changes stepwise, it may include a periodical structure of GaN thin film and AlN thin film (superlattice structure), and it may include a composition in which a proportion of Al continuously changes from AlN to GaN. The first layer 103 contains a nitride semiconductor such as GaN or AlGaN doped with Fe. An Fe concentration in the first layer 103 is 1×1016 atoms/cm3 to 1×1018 atoms/cm3, and a thickness of the first layer 103 is about 100 nm to 400 nm. The first layer 103 is, for example, a GaN layer with an Fe concentration of 3×1017 atoms/cm3, and a thickness of about 300 nm.
The channel layer 104 is, for example, a GaN layer including an Al concentration of 5×1017 atoms/cm3 or more and less than 1×1019 atoms/cm3, and the GaN layer has not been intentionally doped with impurity other than Al. A thickness of the channel layer 104 is about 1000 nm, for example. The barrier layer 105 is of a material which generates two-dimensional electron gas in the vicinity of an upper surface of the channel layer 104, and is an AlGaN layer whose thickness is about 20 nm, for example. The cap layer 106 is, for example, a GaN layer with a thickness of about 5 nm.
An element isolation region 110 demarcating an element region is formed in the stack of the cap layer 106, the barrier layer 105, and the channel layer 104. A source electrode 111 and a drain electrode 112 are formed on the cap layer 106 in the element region.
An insulating film 121 covering the source electrode 111 and the drain electrode 112 is formed on the cap layer 106. An opening 122 is formed between the source electrode 111 and the drain electrode 112 in the insulating film 121, and a gate electrode 113 is formed which is in contact with the cap layer 106 via the opening 122. An insulating film 123 covering the gate electrode 113 is formed on the insulating film 121. A material of the insulating film 121 and the insulating film 123 is not particularly limited, and a silicon nitride film is used, for example.
The channel layer 104 includes a two-dimensional electron gas (2DEG) region 131 in which two-dimensional electron gas exists, and an Al-containing region 132 between the 2DEG region 131 and the first layer 103. An Al concentration in the Al-containing region 132 is 5×1017 atoms/cm3 or more and less than 1×1019 atoms/cm3. The 2DEG region 131 may contain Al at a concentration of 5×1017 atoms/cm3 or more and less than 1×1019 atoms/cm3. A maximum value of the Al concentration between the 2DEG region 131 and the first layer 103 is less than 1×1019 atoms/cm3.
The first embodiment includes the first layer 103, so that the leakage current in the thickness direction can be suppressed, resulting in that good pinch-off characteristics can be obtained. Since the Al-containing region 132 is disposed between the 2DEG region 131 and the first layer 103, it is possible to suppress diffusion of Fe from the first layer 103 to the 2DEG region 131. For example, the Fe concentration in the 2DEG region 131 is 5×1015 atoms/cm3 or less. The diffusion of Fe can be sufficiently suppressed even if the Al concentration in the Al-containing region 132 is 5×1017 atoms/cm3 or more and less than 1×1019 atoms/cm3. An Al composition of the Al-containing region 132 is less than 1% even when the Al concentration is 1×1019 atoms/cm3. Since the Al concentration in the Al-containing region 132 is 5×1017 atoms/cm3 or more and less than 1×1019 atoms/cm3, a dislocation density in the 2DEG region 131 is low. Therefore, the leakage current via the dislocation is difficult to flow, and the trap of electron by the dislocation is difficult to occur.
If the Al concentration in the Al-containing region 132 is less than 5×1017 atoms/cm3, it is not possible to sufficiently suppress the diffusion of Fe from the first layer 103. Therefore, the Al concentration in the Al-containing region 132 is 5×1017 atoms/cm3 or more. For example, even when an Al source is not supplied during formation of the channel layer 104, the channel layer 104 slightly contains Al diffused from the layers such as the buffer layer 102 and the barrier layer 105, but it is not possible to sufficiently suppress the diffusion of Fe with the diffused Al. If the Al concentration in the Al-containing region 132 is 1×1019 atoms/cm3 or more, the dislocation density in the 2DEG region 131 is too high.
Next, a method of manufacturing the compound semiconductor device according to the first embodiment will be described.
First, the substrate 101 is subjected to heat treatment in H2 atmosphere for a few minutes, and thereafter, as illustrated in
When these compound semiconductor layers are formed, mixed gas may be used of trimethylaluminum (TMA) gas being an Al source, trimethylgallium (TMG) gas being a Ga source, and ammonia (NH3) gas being an N source, for example. In accordance with the composition of the compound semiconductor layer to be grown, the presence/absence of supply and the flow rate of the trimethylaluminum gas and the trimethylgallium gas are appropriately controlled. Cp2Fe (cyclopentadienyl iron, ferrocene) may be used as a source of Fe, for example. H2 gas may be used as carrier gas, for example.
Then, as illustrated in
Thereafter, as illustrated in
Subsequently, as illustrated in
Then, as illustrated in
Thereafter, as illustrated in
Subsequently, a protective film, a wiring and the like are formed as necessary to thereby complete the compound semiconductor device 100.
The concentration of Fe contained in the first layer 103 is not particularly limited, and is preferably decided by taking factors such as the thickness of the channel layer 104, and the concentration of Al contained in the channel layer 104 into consideration.
The thicker the channel layer 104 is, the further difficult the influence of dislocation propagated from the layer under the channel layer 104 such as the first layer 103 is to be exerted on the 2DEG region 131, but the further difficult it is for a depletion layer to reach the substrate side during off-operation so that off-leakage characteristics deteriorate. Thus, the thickness of the channel layer 104 is preferably about 700 nm to 1200 nm, more preferably 1000 nm.
An Al composition of the barrier layer 105 is preferably 30% or less, from a viewpoint of suppressing the reduction in crystallinity due to the lattice mismatch.
Next, a second embodiment will be described. The second embodiment relates to an example of a compound semiconductor device with HEMT.
As illustrated in
The second embodiment can also achieve an effect similar to that of the first embodiment. Besides, since the 2DEG region is included in the undoped region 224 which has not been intentionally doped with impurity, further excellent electron mobility can be obtained.
In manufacturing the compound semiconductor device 200 according to the second embodiment, following the formation of the first layer 103, the supply of the Al source is continued but the supply of the Fe source is stopped so as to form the Al-doped region 214, for example. After the formation of the Al-doped region 214, the supply of the Al source is stopped so as to form the undoped region 224. The other processes are conducted in a manner similar to that of the first embodiment.
Next, a third embodiment will be described. The third embodiment relates to an example of a compound semiconductor device with HEMT.
As illustrated in
The third embodiment can also achieve an effect similar to that of the second embodiment. Besides, since dislocation propagated from the lower layer is annihilated by being bent at an interface between the Al-doped region 314 and the undoped region 334, it is expected that the dislocation density is decreased in the undoped region 324. Therefore, it is possible to obtain high 2DEG mobility which is equal to or higher than the 2DEG mobility in the second embodiment.
In manufacturing the compound semiconductor device 300 according to the third embodiment, following the formation of the first layer 103, the supply of the Fe source is stopped so as to form the undoped region 334, for example. After the formation of the undoped region 334, an Al source starts to be supplied so as to form the Al-doped region 314. After the formation of the Al-doped region 314, the supply of the Al source is stopped so as to form the undoped region 324. The other processes are conducted in a manner similar to that of the first embodiment.
Next, an experiment conducted by the inventors of the present application and results thereof will be described. The inventors of the present application examined whether the Fe concentration in the first layer being doped with Fe exerts an influence on the concentration gradient of Fe in the channel layer, and as a result, no significant influence on the concentration gradient of the Fe concentration was confirmed, as illustrated in
The inventors of the present application manufactured a compound semiconductor device according to the first embodiment, and a concentration profile of Fe and Al was measured. A GaN layer with a thickness of 300 nm was formed while supplying Cp2Fe so that the concentration of Fe became 3×1017 atoms/cm3 for the first layer 103. A GaN layer with a thickness of 1000 nm was formed while supplying TMA so that the concentration of Al became 5×1018 atoms/cm3 for the channel layer 104. Then, the concentration profile of Fe and Al was measured by secondary ion mass spectrometry (SIMS). For the comparison, similar measurement was performed also on a reference example in which a channel layer 404 of GaN was formed without being intentionally doped with Al instead of the channel layer 104, as illustrated in
As illustrated in
Next, a fourth embodiment is described. The fourth embodiment relates to a discrete package of a compound semiconductor device which includes a nitride semiconductor HEMT.
In the fourth embodiment, as illustrated in
The discrete package may be manufactured by the procedures below, for example. First, the HEMT chip 1210 is bonded to the land 1233 of a lead frame, using a die attaching agent 1234 such as solder. Next, with the wires 1235g, 1235d and 1235s, the gate pad 1226g is connected to the gate lead 1232g of the lead frame, the drain pad 1226d is connected to the drain lead 1232d of the lead frame, and the source pad 1226s is connected to the source lead 1232s of the lead frame, respectively, by wire bonding. The molding with the molding resin 1231 is conducted by a transfer molding process. The lead frame is then cut away.
Next, a fifth embodiment is described. The fifth embodiment relates to a PFC (power factor correction) circuit equipped with a compound semiconductor device which includes a nitride semiconductor HEMT.
A PFC circuit 1250 has a switching element (transistor) 1251, a diode 1252, a choke coil 1253, capacitors 1254 and 1255, a diode bridge 1256, and an AC power source (AC) 1257. The drain electrode of the switching element 1251, the anode terminal of the diode 1252, and one terminal of the choke coil 1253 are connected with each other. The source electrode of the switching element 1251, one terminal of the capacitor 1254, and one terminal of the capacitor 1255 are connected with each other. The other terminal of the capacitor 1254 and the other terminal of the choke coil 1253 are connected with each other. The other terminal of the capacitor 1255 and the cathode terminal of the diode 1252 are connected with each other. A gate driver is connected to the gate electrode of the switching element 1251. The AC 1257 is connected between both terminals of the capacitor 1254 via the diode bridge 1256. A DC power source (DC) is connected between both terminals of the capacitor 1255. In the embodiment, the compound semiconductor device according to any one of the first to third embodiments is used as the switching element 1251.
In the method of manufacturing the PFC circuit 1250, for example, the switching element 1251 is connected to the diode 1252, the choke coil 1253 and so forth with solder, for example.
Next, a sixth embodiment is described. The sixth embodiment relates to a power supply apparatus equipped with a compound semiconductor device which includes a nitride semiconductor HEMT.
The power supply apparatus includes a high-voltage, primary-side circuit 1261, a low-voltage, secondary-side circuit 1262, and a transformer 1263 arranged between the primary-side circuit 1261 and the secondary-side circuit 1262.
The primary-side circuit 1261 includes the PFC circuit 1250 according to the fifth embodiment, and an inverter circuit, which may be a full-bridge inverter circuit 1260, for example, connected between both terminals of the capacitor 1255 in the PFC circuit 1250. The full-bridge inverter circuit 1260 includes a plurality of (four, in the embodiment) switching elements 1264a, 1264b, 1264c and 1264d.
The secondary-side circuit 1262 includes a plurality of (three, in the embodiment) switching elements 1265a, 1265b and 1265c.
In the embodiment, the compound semiconductor device according to any one of first to third embodiments is used for the switching element 1251 of the PFC circuit 1250, and for the switching elements 1264a, 1264b, 1264c and 1264d of the full-bridge inverter circuit 1260. The PFC circuit 1250 and the full-bridge inverter circuit 1260 are components of the primary-side circuit 1261. On the other hand, a silicon-based general MIS-FET (field effect transistor) is used for the switching elements 1265a, 1265b and 1265c of the secondary-side circuit 1262.
Next, a seventh embodiment is explained. The seventh embodiment relates to an amplifier equipped with the compound semiconductor device which includes a nitride semiconductor HEMT.
The amplifier includes a digital predistortion circuit 1271, mixers 1272a and 1272b, and a power amplifier 1273.
The digital predistortion circuit 1271 compensates non-linear distortion in input signals. The mixer 1272a mixes the input signal having the non-linear distortion already compensated, with an AC signal. The power amplifier 1273 includes the compound semiconductor device according to any one of the first to third embodiments, and amplifies the input signal mixed with the AC signal. In the embodiment, the signal on the output side may be mixed, upon switching, with an AC signal by the mixer 1272b, and may be sent back to the digital predistortion circuit 1271. The amplifier may be used as a high-frequency amplifier or a high-output amplifier.
According to the above-described compound semiconductor device and the like, since the channel layer includes the appropriate Al-containing region, it is possible to suppress the reduction in characteristics due to the diffusion of Fe from the first layer being doped with Fe.
All examples and conditional language provided herein are intended for the pedagogical purposes of aiding the reader in understanding the invention and the concepts contributed by the inventor to further the art, and are not to be construed as limitations to such specifically recited examples and conditions, nor does the organization of such examples in the specification relate to a showing of the superiority and inferiority of the invention. Although one or more embodiments of the present invention have been described in detail, it should be understood that the various changes, substitutions, and alterations could be made hereto without departing from the spirit and scope of the invention.
Number | Date | Country | Kind |
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2015-215007 | Oct 2015 | JP | national |