Confocal spectrometer with astigmatic aperturing

Abstract
A confocal spectrometer provides astigmatic optics which supply a monochromator or spectrograph with the image of a sample, with the astigmatic optics thereby providing separate first and second (tangential and sagittal) focal planes for the image. The monochromator/spectrograph has an entrance slit oriented along one of the focal planes, and this slit defines the spectral resolution of the monochromator/spectrograph and the field of view of the sample in one direction (in one focal plane). A supplemental slit is situated outside the monochromator/spectrograph adjacent the entrance slit, with the supplemental slit being oriented along the other focal plane. The supplemental slit therefore defines the field of view of the sample in a perpendicular direction (in the other focal plane). By varying the width of the supplemental and/or entrance slits, one may easily achieve the desired field of view.
Description

BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a perspective view of selected components of a spectrometer arrangement 100, wherein the image of a sample 102 is directed through an astigmatic optical element 118 (e.g., a toroidal lens), causing the image to be directed along perpendicular focal planes having spaced focal points (better shown in FIGS. 1C-1D), with a pair of slit-type apertures 132 and 120 each being situated at a respective focal point of one of the planes. Additionally, the first aperture 132 is schematically depicted as being replaceable by a series of differently-sized substitute first apertures 132A, 132, and 132C, and the second aperture 120 is depicted as defining the entrance aperture to a spectrograph 112 (which includes a collimating reflector 122, a diffraction grating 124, a second mirror 126, and a photosensitive detector array 116).



FIG. 1B provides a top plan view of the arrangement of FIG. 1A, wherein the spectrograph 112 is more specifically indicated with a phantom/dashed line boundary.



FIG. 1C illustrates the image beam exiting the (schematically depicted) astigmatic optical element 118 to enter the first and second apertures 132 and 120, wherein the rays of the image beam are depicted in a vertical (sagittal) focal plane as solid lines converging at a first focal point 128, and the rays in a horizontal (tangential) focal plane are depicted as dashed/phantom lines converging at a second focal point 130. Additionally, the size (width) of the second aperture 120 is depicted as being continuously variable by altering the spacing of the opposing masks of the second aperture 120.



FIG. 1D illustrates the image beam exiting the (schematically depicted) astigmatic optical element 118 to enter the first and second apertures 132 and 120, wherein the rays of the image beam are depicted in a horizontal (tangential) focal plane as solid lines converging at a second focal point 130, and the rays in a vertical (sagittal) focal plane are depicted as dashed/phantom lines converging at a first focal point 128. Additionally, the size (width) of the first aperture 132 is depicted as being continuously variable by altering the spacing of the opposing masks of the first aperture 132.





DETAILED DESCRIPTION OF PREFERRED VERSIONS OF THE INVENTION

To review the invention in further detail, it should be understood that the invention can be incorporated in any appropriate preexisting spectrometer arrangement. In particular, the astigmatic optical element 118 and the dual apertures 120 and 132 can be readily implemented in preexisting spectrometer arrangements which utilize Czerny-Turner spectrographs with spherical mirrors (e.g., the Oriel MS125 spectrograph provided by Newport Corporation, Stratford, Conn.). Since the configuration of the spectrometer may vary, it should be understood that the components and arrangement of the sample mount 102, light source 104, the optical elements such as the collection lens 106, mirror 108, objective lens 110, etc., and the monochromator 114 and detector 116 may vary widely (and some of these elements may be omitted, may be replaced by functionally similar elements, and/or may be comprised of several individual elements). Additional components may be present as well, with an obvious example being a housing which includes mountings for the components illustrated in the drawings (with no such housing or mountings being shown in the drawings). Additional optical elements are also readily accommodated, e.g., beam-folding mirrors which alter the path of the image so that the overall arrangement of the spectrometer 100 may be made more compact, or may otherwise better fit some desired configuration.


The astigmatic optical element 118 may be any optical element which provides different focal lengths in different planes, and can be a lens (such as the toroidal lens 118 of FIGS. 1A-1B), a reflector, or combinations of lenses and/or reflectors. This is illustrated by the spectrometer 200 of FIG. 2, wherein the image of a sample mount 202 (and more particularly of any sample thereon) is reflected from an astigmatic optical element 218 (depicted as an off-axis spherical mirror) and through first and second apertures 232 and 220, with the second aperture 220 defining the entrance to a spectrograph 212, before ultimately reaching the detector 216. Further, the astigmatic optical element may be formed of combinations of optical elements, e.g., a combination of a cylindrical lens and a spherical lens, a combination of a cylindrical mirror and a spherical mirror, etc. It is notable that the invention is particularly easily implemented in spectrometers which primarily operate at or near infrared wavelengths, and which thereby make extensive use of reflective optical elements rather than refractive optical elements (owing to low transmission of infrared through conventional glass refractive optical elements). Since such spectrometers often utilize off-axis reflectors to achieve beam focusing and other objectives, and such reflectors inherently introduce some degree of astigmatism, the dual-aperture scheme described in this document can often be readily implemented at minimal cost, and with the benefit of substantial added versatility.


The drawings (particularly FIGS. 1A and 1C-1D) illustrate varying the size of the first aperture 132 in a discrete fashion by replacing the first aperture 132 with substitute first apertures 132A, 132B, and 132C having different aperture sizes. In contrast, FIGS. 1C and 1D illustrate continuously varying the sizes of the apertures 132 and 120 by varying the width of their slits (i.e., by varying the spacing between their opposing masks). It should be understood that either or both of these size variation techniques may be implemented in either or both of the first and second apertures 132 and 120.


In practice, the spectrometer 100 may be used with both apertures 132 and 120 installed (and narrowed) to present an effective pinhole aperture for confocal imaging of the sample 102. Alternatively, if a larger area of the sample 102 is to be analyzed, one of the apertures 132 and 120 may be adapted so that it does not interfere with the image beam (i.e., it may be enlarged about the beam or moved from the beam path). As a result, the detector 116 will receive (and generate measurements from) a slit image rather than a pinhole image. If desired, the other aperture may also be adapted as well, as by slightly narrowing or enlarging it, to vary the resolution of the measurements.


In the foregoing arrangement, it is preferred that the second aperture 120 remain as the entrance to the spectrograph 112, and that the first aperture 132 be insertable/removable and/or respaceable outside the spectrograph 112 to avoid interference with the image beam. In this manner, the spectrograph 112 and/or its monochromator 114 may be constructed, installed, and removed for maintenance as a unit, with the second aperture 120 being held in a fixed location with respect to the diffraction grating 124 (as well as with respect to the collimating reflector 122, second reflector 126, and detector 116). This is beneficial since maintaining the second aperture 120 in a substantially fixed location with respect to the spectrograph 112 (in particular the diffraction grating 124) substantially reduces or eliminates many of the misalignment difficulties that arise in prior arrangements wherein the entrance aperture of the spectrograph was repositionable with respect to the remaining spectrograph components.


The invention is not intended to be limited to the preferred versions described above, but rather is intended to be limited only by the claims set out below. Thus, the invention encompasses all different versions that fall literally or equivalently within the scope of these claims.

Claims
  • 1. A spectrometer comprising: a. a sample mount;b. an astigmatic optical element receiving an image of the sample mount, the astigmatic optical element delivering the image along perpendicular focal planes having spaced focal points;c. elongated first and second apertures, each being: (1) situated in both of the focal planes,(2) oriented with its length coincident with a respective one of the focal planes,(3) situated at least substantially coincident with the focal point of a respective one of the focal planes, andwherein at least one of the apertures is movable about at least one of the focal planes.
  • 2. The spectrometer of claim 1 wherein at least one of the apertures has an adjustable aperture width oriented perpendicular to its aperture length.
  • 3. The spectrometer of claim 1 wherein the first aperture has an adjustable aperture width oriented perpendicular to its aperture length.
  • 4. The spectrometer of claim 1: a. wherein the first aperture is removably mounted within the focal planes; andb. further comprising a set of substitute first apertures, all having varying aperture sizes different from the aperture size of the first aperture, wherein each of the substitute first apertures is replaceably mountable within the focal planes in place of the first aperture.
  • 5. The spectrometer of claim 1 further comprising a diffraction grating receiving the image from at least one of the first and second apertures.
  • 6. The spectrometer of claim 5 wherein: a. the first aperture is movable into and out of at least one of the focal planes; andb. the second aperture receives the image from the first aperture and provides the image to the diffraction grating.
  • 7. The spectrometer of claim 1 wherein the second aperture: a. the second aperture receives the image from the first aperture, andb. the second aperture defines the entrance of a spectrograph.
  • 8. The spectrometer of claim 1 further comprising a photosensitive detector receiving the image from at least one of the first and second apertures.
  • 9. The spectrometer of claim 1: a. wherein the first aperture provides the image to the second aperture, andb. further comprising a linear array detector, wherein the linear array detector and the first aperture are oriented along the same focal plane.
  • 10. The spectrometer of claim 1 wherein the astigmatic optical element includes at least one of: a. a lens, andb. a reflector.
  • 11. The spectrometer of claim 10 wherein the astigmatic optical element includes an of-axis reflector.
  • 12. A spectrometer comprising: a. a sample mount;b. an objective lens imaging the sample mount;c. an optical element receiving the image of the sample mount from the objective lens, the optical element delivering the image along first and second focal planes having spaced focal points;d. an elongated first aperture: (1) oriented along the first focal plane, and(2) being situated at least substantially coincident with the focal point of the first focal plane,the first aperture receiving the image from the optical element;e. an elongated second aperture: (1) oriented along the second focal plane, and(2) being situated at least substantially coincident with the focal point of the second focal plane,the second aperture receiving the image from the first aperture;f. a monochromator receiving the image from at least the second aperture.
  • 13. The spectrometer of claim 12 wherein the first aperture is movable away from the focal point of the first focal plane.
  • 14. The spectrometer of claim 12 wherein at least the first aperture has an adjustable aperture width oriented perpendicular to its aperture length.
  • 15. The spectrometer of claim 12 wherein the monochromator includes a linear array detector extending coincidently along the first focal plane.
  • 16. The spectrometer of claim 12 wherein: a. the monochromator has a diffraction grating therein, andb. the diffraction grating and second aperture are connected whereby they may be removed from the spectrometer as a unit while maintaining a fixed relationship between the diffraction grating and second aperture.
  • 17. The spectrometer of claim 12 wherein the optical element includes an off-axis reflector.
  • 18. The spectrometer of claim 12 wherein the optical element includes an astigmatic lens.
  • 19. A spectrometric analysis method comprising: a. providing an image of a sample mount to an astigmatic optical element, the astigmatic optical element delivering the image to elongated first and second apertures along perpendicular focal planes having spaced focal points, wherein each aperture is: (1) situated at the focal point of a respective one of the focal planes, and(2) oriented with its length along a respective one of the focal planes,b. moving the first aperture out of at least one of the focal planes; andc. thereafter repeating step a. with only the second aperture being situated in both of the focal planes.
  • 20. The method of claim 19 further comprising the step of enlarging the first aperture.
  • 21. The method of claim 20 wherein the first aperture is interposed between the astigmatic optical element and the second aperture when the image is delivered from the astigmatic optical element to both of the apertures.
  • 22. The method of claim 19: a. wherein a diffraction grating receives the image from the second aperture; andb. further comprising the step of simultaneously removing the second aperture and the diffraction grating from the astigmatic optical element and the first aperture, with the second aperture and the diffraction grating being removed as a connected unit.
  • 23. The method of claim 19: a. wherein a photosensitive detector receives at least a portion of the image from at least one of the first and second apertures;b. further comprising the step of obtaining a reading of light intensity from the detector.
  • 24. The method of claim 23 further comprising a monochromator interposed between the detector and at least one of the first and second apertures.