Information
-
Patent Grant
-
6227950
-
Patent Number
6,227,950
-
Date Filed
Monday, March 8, 199925 years ago
-
Date Issued
Tuesday, May 8, 200123 years ago
-
Inventors
-
Original Assignees
-
Examiners
- Hail, III; Joseph J.
- Nguyen; George
Agents
-
CPC
-
US Classifications
Field of Search
US
- 459 41
- 459 57
- 459 67
- 459 388
- 459 456
- 459 600
- 459 288
- 459 66
-
International Classifications
-
Abstract
The present invention provides a dual purpose workpiece handoff station for intermediately staging a semiconductor wafer, or other workpiece, being transferred between processing stations in, for example, a Chemical-Mechanical Planarization (CMP) machine. The handoff station includes a workpiece processing surface; such as a polishing pad or buffing pad, defining a plurality of apertures for applying fluids, including water, chemicals, slurry, or vacuum, to the surface of a workpiece. In operation, a workpiece carrier moves a polished wafer from a primary polishing surface to the handoff station, and polishes, buffs, or cleans the wafer in the handoff station by rotating the wafer and oscillating the wafer across the handoff station polishing surface while pressing the wafer thereon.
Description
FIELD OF THE INVENTION
The present invention relates to chemical mechanical polishing of workpieces. In particular, the present invention relates to a workpiece handoff station for staging workpieces between processing stations, the handoff station including a workpiece processing surface.
BACKGROUND ART AND TECHNICAL PROBLEMS
Recent rapid progress in semiconductor device integration demands smaller and smaller wiring patterns or interconnections, and narrower spaces between interconnections which connect active areas. One of the processes available for forming such interconnections is photolithography. Though the photolithographic process can form interconnections that are at most 0.5 microns wide, it requires that surfaces on which pattern images are to be focused by a stepper be as flat as possible because the depth of focus of the optical system is relatively small.
It is therefore necessary to make the surfaces of semiconductor wafers flat for photolithography. One customary way of flattening the surfaces of semiconductor wafers is by Chemical Mechanical Planarization (CMP), which is a process whereby semiconductor wafers are polished with a polishing apparatus.
Conventionally, a CMP polishing apparatus has a turntable and a wafer carrier which rotate at respective individual speeds. A polishing pad is attached to the upper surface of the turntable. A semiconductor wafer seated in the carrier is lowered into engagement with the polishing pad, and clamped between the carrier and the turntable, typically through the exertion of downward force by the carrier. An abrasive grain containing liquid (known as slurry) is deposited onto the polishing pad and retained on the polishing pad. During operation, the carrier exerts a certain pressure on the turntable, and the surface of the semiconductor wafer held against the polishing pad is therefore polished by a combination of chemical polishing and mechanical polishing to a flat mirror finish while the carrier and the turntable are rotated.
The semiconductor wafer that has been polished carries abrasive liquid and ground-off particles attached thereto. Therefore, after polishing, the semiconductor wafer is cleaned and dried in one or more cycles and then housed in a clean storage cassette. If the wafer is not cleaned immediately, the slurry and foreign particles applied to the lower surface of the wafer tend to solidify, becoming very difficult to remove. Also, the known standard cleaning processes, employing, for example, roller brush box type cleaners, are largely ineffective at removing submicron scratches left on the wafer surface by the polishing process.
Thus, additional processing is typically done prior to the wafer cleaning step. For example, a second polish turntable with a second carrier may be employed, using a relatively soft buffing pad in combination with a cleaning chemical, or ultra pure water alone. The buffing process can be effective at removing the residual slurry and buffing out the surface scratches left from the polishing process before cleaning the wafer. However, the effectiveness of the buffing process is also affected by the length of time that slurry sits on the wafer between the polish and buffing process. Unfortunately, adding the buffing process necessitates additional wafer handling and transferring capability, increased tool foot print, and often reduced wafer throughput as a result.
Alternatively, the slurry and surface scratches maybe removed through use of a Hydrofluoric (HF) acid etching process. In such a process, the wafer may be dipped in a bath of the HF acid solution and/or cleaned with an HF solution in a somewhat conventional brush box. However, HF acid poses serious health risks. Compliance with industry safety standards governing the use of HF acid adds substantially to the cost of the equipment and the facility which houses the equipment when employing these techniques.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide a method and apparatus for cleaning post polish slurry residue from the surface of a wafer without allowing time for the residue to significantly solidify.
It is another object of the present invention to provide a method and apparatus for buffing a wafer to remove post polish defects that minimizes the time between polishing and buffing and does not increase tool footprint.
It is still another object of the present invention to provide an alternative solution to HF acid etch for pre-cleaning removal of wafer surface particles and defects without employing a conventional buffing table.
The present invention achieves these objects by providing a dual purpose workpiece handoff station for intermediately staging a semiconductor wafer (or other workpiece) being transferred between processing stations in a CMP machine. The handoff station includes a workpiece processing surface such as a polishing pad or buffing pad which includes a plurality of apertures for applying fluids to the surface of a workpiece. A fluid delivery system is provided for selectively delivering water, chemicals, or slurry, for cleaning and polishing. In addition, the delivery system may provide vacuum for holding a wafer, or nitrogen for wafer blowoff.
In operation, a workpiece carrier moves a polished workpiece from a primary polishing surface to the handoff station, and polishes, buffs, or cleans the workpiece in the handoff station by rotating the workpiece and oscillating the workpiece across the handoff station polishing surface while pressing the workpiece thereon. Cleaning or buffing chemicals may be simultaneously applied to the workpiece. A robot, preferably track mounted, retrieves the wafer from the handoff station and transfers it to a subsequent station, for example to a second primary polish station, or to a cleaning station.
These and other objects, features and advantages of the present invention are specifically set forth in, or will become apparent from, the following detailed description of a preferred embodiment of the invention when read in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1
depicts a plan view of a polishing apparatus including the dual purpose handoff station of the present invention.
FIG. 2
depicts an exploded perspective view the dual-purpose handoff station of the present invention.
FIG. 3
depicts a cross-section view of the dual-purpose handoff station of FIG.
2
.
FIG. 4
depicts a schematic diagram of the fluid delivery system for the handoff station of the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
A polishing apparatus according to the present invention suitable for polishing silicon wafers, or other workpieces, will be described below with reference to
FIGS. 1 through 4
. First referring to
FIG. 1
, a polishing apparatus
10
comprises two generally rectangular polishing modules
12
, and
14
positioned adjacent one another. Each of the polishing modules
12
,
14
include a polishing surface
16
, a wafer carrier
18
movably supported by an arm
20
, and a wafer handoff station
22
. A polishing surface
16
generally comprises a polishing pad
17
positioned atop a support platform
21
. The pad
17
and platform
21
may take any of a variety of suitable known forms, for example, the pad and support platform may be circular as shown in
FIG. 1
, where the pad
17
is fixed for example by adhesive, to the upper surface of a rotatable or non-rotatable platform
21
. In another embodiment, pad
17
may comprise a movable continuous belt which slides across the top of a generally rectangular shaped support platform. Any of a variety of types of polish pads
17
suitable for use with or without slurry may also be utilized in conjunction with platform
21
. For example, polish pad
17
may comprise a two-layer IC-1000/Suba IV stack pad for CMP polishing available from Rodell Inc., a softer buffing type pad, or a slurry-less polishing pad containing fixed abrasive particles.
The arm
20
is suitably configured to provide the required structural support and movement capability for polishing a wafer on the polishing surface
16
, and to move carrier
18
back and forth from the polishing surface
16
to the handoff station
22
. Although depicted as a pivoting arm, any of a variety of suitable configurations providing the required motion and support, such as for example an overhead gantry and track arrangement (not shown) providing x-y motion capability, and the like, may be substituted for arm
20
. The carrier
18
includes a lower wafer holding surface
19
(see FIG.
3
), and is rotatable about a central axis for rotating a wafer
23
during polishing. Polishing modules
12
and
14
may further include a second polish arm
20
(not shown) positioned on the opposite side of polishing surface
16
, also with a corresponding carrier
18
and a second handoff station
22
(also not shown).
The polish modules
12
and
14
may be utilized to perform similar or different types of processes, by for example, varying the type of polishing pad
17
provided, or varyng the type of polishing slurry or other chemical applied thereon. A conventional utilization of polisher
10
involves a primary polish operation at polish module
12
using a CMP primary polish pad
17
with an abrasive polishing slurry, followed by a buffing process at module
14
using a softer pad
17
and deionized water, and finally a cleaning process, preferably including a Hydrofluoric (HF) acid cleaning step. As will be described in greater detail below, the present invention eliminates the second table buff process and HF acid cleaning step, thereby improving utilization of the polisher, tool safety, and wafer throughput.
The polishing apparatus
10
further includes a conveying unit
24
disposed alongside polishing modules
12
and
14
. Conveying unit
24
includes a wafer handling robot
26
slidably mounted atop a track
28
so as to be movable in the directions indicated by arrows F. Track
28
extends substantially the length of polish modules
12
and
14
, thereby providing robot
26
with access to load cups
22
of both polish modules
12
,
14
. Robot
26
includes an end effector
30
suitably configured to grip a wafer, and extendible in reach a sufficient amount to reach load cups
22
and retrieve or deposit a wafer thereon. End effector
30
may be any of a number of different commercially available types, such as the vacuum gripping type, or edge gripping type. An example of a suitable robot
26
and vacuum gripping type end effector
30
is disclosed in U.S. patent application Ser. No. 08/926,700 assigned to the assignee of this patent application, the relevant parts of which are hereby incorporated by reference.
The polishing apparatus
10
also includes a cleaning section
50
disposed alongside the conveyer module
24
opposite polish modules
12
and
14
. The cleaning section
50
includes a plurality of cleaning modules
52
that may be conventional cleaning devices such as brush scrubbers, spin dryers, and the like, or less conventional devices such as an HF acid etch station. The cleaning modules
52
are interconnected by suitable wafer transport devices such as a water track
54
for providing serial transport of wafers through cleaning modules
52
. Access into cleaning section
50
is provided for robot
26
to deposit a processed wafer onto a wafer-receiving portion
56
of water track
54
.
A front end module
60
positioned at the end of polisher
10
adjacent polish module
12
and cleaning section
50
provides retrieval and storage of dry wafers. The polisher
10
provides for dry-in/dry-out wafer processing, whereby a group of dry unprocessed wafers initially contained in a wafer storage pod
62
are polished, buffed, cleaned, and then returned to the same storage pod
62
. The front end module preferably includes at least three storage pods
62
, and a dry wafer handling robot
64
for transferring wafers to and from pods
62
and to and from the processing modules of the polisher
10
. A preferred well-known and commercially available type of storage pod
62
is the Front Opening Unload Pod (FOUP) type, which provides an enclosed mini-environment for the wafers. The FOUP type pod may be readily attached or detached from the front-end module
60
while providing an airtight seal thereto and maintaining the integrity of the wafer mini-environment. Turning now to
FIGS. 2 and 3
a workpiece handoff station
22
in accordance with the present invention will be described. The workpiece handoff station
22
generally includes a workpiece support platform
80
which sits atop a manifolding plate
82
and body portion
84
, and a polishing pad
88
affixed to the top of platform
80
. The polishing pad
88
may be formed of any suitable material, from soft cloth to a relatively stiff plastic, as required for a particular cleaning, buffing, or polish operation to be performed. The platform
80
and pad
88
include a plurality of co-aligned apertures
92
and
94
for application of pressurized fluids, or vacuum therethrough to an underside of a wafer
21
. The apertures
92
,
94
are connected via the manifolding plate
82
to an arrangement of conduits and valves which are in turn connected to separately accessible sources of pressurized fluids, chemicals, and vacuum. The handoff station also includes three workpiece centering fingers
86
positioned around the perimeter of platform
80
, and associated linkages
90
.
Referring now to the schematic diagram of
FIG. 4
, a preferred piping and valving arrangement is depicted. As indicated, fluid access to load cup
22
is provided by a single main fluid supply conduit
102
. Main fluid conduit
102
is connectable to a variety of fluid or gas sources to facilitate performance of various operations or processes on a wafer. In particular, main conduit
102
is coupled through valves
116
,
118
,
120
,
122
,
124
respectively to a vacuum source
106
, an ultra-pure water source
108
, a gaseous nitrogen source
110
, a liquid chemical source
112
, and an abrasive polishing slurry source
114
. Preferably, an inline pump
126
is provided for pumping either liquid chemical from source
112
or polishing slurry from source
114
, to load cup
22
.
The valves
116
-
124
are independently operable to allow for individually connecting the main conduit
102
to the sources
106
-
14
. Thus for example, simultaneously closing valves
118
-
124
while opening valve
116
, connects load cup
22
through main conduit
102
to the vacuum source
106
only. A different source may then be accessed by closing valve
116
and opening a different selected valve, and so on.
Returning now to
FIGS. 2 and 3
, the load cup main fluid supply conduit
102
is connected from the underside of manifolding plate
82
to an array of interconnected open channels
96
formed in the upper surface
83
of plate
82
. The channels
96
are covered by the undersurface of the platform
80
as assembled, thereby forming enclosed fluid passages. Mechanical pilots (not shown) are provided to position platform
80
angularly with respect to manifolding plate
82
such that the channels
96
align with the apertures
92
in platform
80
. An O-ring type gasket
98
is provided between manifolding plate
82
and platform
80
to prevent leakage of fluids therebetween. Thus, pressurized fluid introduced through conduit
102
is distributed evenly through channels
96
and forced upward and out through apertures
92
and
94
for application to a surface of a wafer. Similarly, vacuum may be applied through apertures
92
,
94
, and channels
96
for drawing a wafer
21
down against platform
80
.
Accordingly, a dual purpose workpiece handoff station is provided that serves both as a conventional wafer staging station, and as a wafer buffing, polishing or cleaning station. As a workpiece staging station, load cup
22
may be utilized, for example, to stage a wafer being transferred from the front end module
60
to the polishing surface
16
of polish module
12
. In such a procedure, a wafer is transferred by robot
64
from module
60
to load cup
22
and deposited thereon. The centering fingers
86
are then actuated simultaneously with application of vacuum, to both center the wafer and fix the wafer in load cup
22
. Next, arm
20
and carrier
18
are positioned directly over the load cup
22
and brought into contact with the upper surface of the wafer. The carrier
18
is caused to grip the wafer while, simultaneously, the load cup vacuum is stopped. The wafer is then transported by carrier
18
and arm
20
to polishing surface
16
for processing.
Load cup
22
may also serve as a staging station following wafer processing on polishing surface
16
. As an example of such a procedure, after being polished on polishing surface
16
, a wafer is transported by support arm
20
and carrier
18
to the load cup
22
and deposited thereon. Again, the centering fingers
86
are actuated simultaneously with application of vacuum to center and fix the wafer in load cup
22
. Next, end effector
30
of robot
26
is brought into gripping contact with the wafer while simultaneously stopping the application of the load cup vacuum. The wafer is then removed from load cup
22
, and transported by robot
26
to a desired subsequent station, such as receiving station
56
of cleaner module
50
, or load cup
22
of polishing module
14
. Load cup
22
may also be utilized as a cleaning or buff station to filter process a wafer, intermediate to the above-described conventional handoff procedures. In a first such example, a wafer having been processed with a primary polishing procedure on a polishing surface
16
is transported by support arm
20
and carrier
18
to load cup
22
. The carrier
18
is then lowered to bring the wafer into pressing engagement with the polishing pad
88
. Carrier
18
and the wafer attached thereto are simultaneously rotated about a central axis of carrier
18
, while the carrier is caused to oscillate laterally back and forth across polishing pad
88
. With respect to a pivoted polishing arm configuration such as shown in
FIG. 1
, the lateral oscillatory motion is obtainable by swinging arm
20
back and forth, whereby carrier
18
traces an arcuate path across polishing pad
17
.
At the same time the wafer is being rotated and translated back and forth, fluids may be applied to the undersurface of the wafer through the apertures
94
and
92
. For example, if a cleaning operation or light buff operation is being performed, ultra pure water, or a very dilute liquid chemical solution may be conveniently applied to the wafer. Preferably a softer cleaning or buffing type pad
88
is used in such a process. Alternatively, an abrasive slurry may be applied to the wafer, for example to perform a more aggressive post polish buff operation, or even a second-table type polish operation, preferably followed by application of ultra pure water to rinse slurry residue from the wafer. For such polishing type operations, a stiffer polish pad material is preferable, such as an IC-1000 series pad made by Rodel Industries.
Thus, the load cup of the present invention may be used to perform a buffing, polishing, or cleaning operation typically performed by other polish or buffing tables, or cleaning devices in prior art polishing tools. Accordingly, an advantage of the present invention is that one or more polishing or cleaning devices may be eliminated from a polish tool, thereby reducing tool foot print, weight, and cost. This advantage is of particular significance with regard to the advent of copper interconnect wires in micro-electronic device structures. Two and three table polishing processes have shown promising results in polishing copper layers. Still, standards for maximum allowable overall tool foot print demanded by device manufacturers have not relaxed as a result. Thus, the dual purpose load cup of the present invention provides the capability to perform an additional device polishing step without increasing tool footprint.
Because of the close proximity of the load cup
22
to the polish surface
17
, a wafer may be transported to the load cup
22
relatively quickly after polishing, as compared to prior art devices. Thus, the time between the polish operation on the main polish table
16
and the secondary operation performed in the load cup
22
is also reduced as compared to prior devices. For example, in a typical pnor art polishing tool, the wafer is transported by the carrier to a staging location after the initial polishing process. The staging location may be a single fixed cup or a number of cups on an indexing table of the type typically used in conjunction with multiple head polishers. In the case of an indexing table, the wafer stays in its cup until the index table has indexed completely around and all the cups contain a polished wafer. Next, the polished wafer, or wafers, are retrieved from the staging station and carried to a second staging station adjacent a second polishing or buffing table. Finally, a carrier at the second polishing table picks up the wafer from the second staging station and moves it to the second polishing surface for further work.
The dual purpose load cup of the present invention greatly reduces the time between the first polishing process and a second operation performed on the wafer by eliminating the above described intermediate wafer handling steps. Thus, a wafer is transported directly from a polishing operation to a subsequent polish, clean, or buff operation by a single motion of carrier arm
20
. An immediately apparent advantage realized by such a direct wafer transfer is the associated reduction of overall process time, and the corresponding increase in wafer throughput. Also as a direct result, the amount of time that polishing slurry residue is left sitting on the wafer surface is minimized. It is desirable to remove slurry residue as quickly as practical from a polished wafer because the longer it remains, the more it tends to set-up and the harder it is to remove. Thus in accordance with the present invention, the polishing slurry residue from a first polishing process may be advantageously removed from the surface of the wafer by a clean or buff process in the dual purpose load cup before it can begin to significantly set-up and adhere to the wafer.
It is also desirable to control or reduce the amount of time the device structure formed on the wafer is exposed to reactive chemicals in the slurry residue. In particular, copper interconnect wires are highly susceptible to corrosion from extended exposure to slurry residue. Accordingly, another advantage of the present invention is that the corrosive effects of slurry residue on copper wires of a polished device structure may be arrested by a subsequent cleaning of buff process in a more timely manner than possible with prior art polishing tools. It will be appreciated by one skilled in the art that a similar situation exists following a buff process in which certain reactive chemicals are utilized which may cause damage to the device structure if left sitting too long. In such a case, the present invention allows for quickly neutralizing the buffing chemicals with a subsequent cleaning operation before any significant damage to the device occurs.
It is further desirable to initiate a post polish buff process as quickly as possible to maximize the effectiveness of the buff process in removing defects left by the prior polishing process. Buffing processes in prior art polishing equipment have generally proved to be unsatisfactory at removing polishing defects. Accordingly, another advantage of the present invention is that the effectiveness of the buffing process is greatly improved by initiating the buffing process at the earliest opportunity after polish. As a result, the need for an HF acid process in the cleaning step for removing surface defects is substantially reduced or eliminated. Consequently, tool complexity is reduced and operator safety is greatly improved.
The following example illustrates the effectiveness of the dual purpose handoff station at removing particles from the surface of a semiconductor wafer. An experiment was performed wherein a 200 mm diameter unpatterned semiconductor wafer was cleaned by a conventional scrubbing process, and then buffed by a process simulating the process of the present invention. Measurements were taken of the clean wafer before and after the buff process to determine the number of particles present on the surface of the wafer at both times. All particle measurements were performed with a Tencor brand particle counting machine, model no. xxxxxxx.
The buffing process was performed on a Model no. SS-136 silicon wafer polishing machine, manufactured and sold by SpeedFam Ltd. of Japan. The SS-136 machine was operated in a such a way as to simulate the buffing process of the present invention by causing the wafer carrier to simultaneously rotate and oscillate while pressing the wafer against a fixed buffing pad. The process parameters for the experimental buffing process were as follows:
|
Carrier rotational velocity:
60 rpm
|
Carrier down force:
30 pounds
|
Oscillation radius:
1 inch
|
Oscillation pattern:
eliptical
|
Buffing time:
30 seconds
|
Buffing fluid:
deionized water
|
|
The wafer was pre-measured using the Tencor machine taking care to minimize handling of the wafer and maintain the cleaned condition, and post-measured after the above-described buffing process. A comparison of the pre and post measurements showed that after the buffing process there were on average 94 less particles (negative adders) of size greater than 0.2×10−6 m. present on the wafer than were detected by the pre-measurement. Particle count reductions of approximately 50 to 100 less particles are achievable by buffing similarly cleaned wafers using conventional second table buffing processes. Thus, the above described experiment demonstrates that the buffing process of the present invention provides buffing performance at least equivalent to that of conventional buffing processes.
Various modifications and alterations of the above described dual purpose load cup in addition to those already described will be apparent to those skilled in the art. For example, although the invention has been described generally in terms of processing semiconductor wafers, it is to be appreciated that the invention may be utilized with equal benefit for processing other workpieces, such as for example magnetic disks. Accordingly, the foregoing detailed description of the preferred embodiment of the invention should be considered exemplary in nature and not as limiting to the scope and spirit of the invention as set forth in the following claims.
Claims
- 1. An apparatus for polishing a surface of a workpiece, comprising:a first workpiece polishing surface for polishing a surface of a workpiece pressed thereon; a workpiece handoff station having a second workpiece processing surface for additionally polishing said surface of said workpiece pressed thereon; and a workpiece carrier for transporting said workpiece directly from said first polishing surface to said handoff station and into contact with said second polishing surface.
- 2. The apparatus of claim 1 further comprising a first workpiece handling device for accessing a workpiece in said handoff station.
- 3. The apparatus of claim 2 wherein said workpiece handling device comprises a moveably mounted robot.
- 4. The apparatus of claim 1 wherein said second processing surface comprises a pad positioned atop a workpiece support platform.
- 5. The apparatus of claim 4, wherein said pad comprises a relatively soft buffing pad.
- 6. The apparatus of claim 1, wherein said second workpiece processing surface defines a plurality of fluid apertures extending therethrough.
- 7. The apparatus of claim 6 wherein said apertures are in fluid communication with a vacuum source operable to draw air through said apertures to vacuum-hold a workpiece.
- 8. The apparatus of claim 6 wherein said apertures are in fluid communication with a pressurized fluid source operable to flow a fluid through said apertures and passages and against the surface of a workpiece contacting said second processing surface.
- 9. The apparatus of claim 8 wherein said fluid comprises a liquid chemical formulation.
- 10. The apparatus of claim 9 wherein said chemical formulation comprises water.
- 11. The apparatus of claim 8 wherein said fluid comprises an abrasive slurry.
- 12. The apparatus of claim 6, further comprising a plurality of fluid sources and a plurality of corresponding valves, said valves being operable to selectively connect said apertures to at least one of said fluid sources.
- 13. The apparatus of claim 6, further comprising:a vacuum source; at least one pressurized fluid source; and a valve operable to selectively independently connect at least one of said at least one pressurized fluid source and said vacuum source to said apertures.
- 14. The apparatus of claim 1 wherein said carrier is generally circular in shape and rotatable about an axis perpendicular to said second processing surface while maintaining said workpiece in pressing contact with said second processing surface.
- 15. The apparatus of claim 14, wherein said carrier is movable laterally in a direction parallel to said second processing surface while maintaining said workpiece in pressing contact thereon.
- 16. The apparatus of claim 15, wherein said second processing surface is wide enough to accommodate said relative lateral motion without said workpiece overhanging an edge of said second processing surface.
- 17. The apparatus of claim 1 further including centering means for centering a workpiece resting on said second processing surface.
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Foreign Referenced Citations (5)
Number |
Date |
Country |
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Mar 1997 |
EP |
0 774 323 A2 |
May 1997 |
EP |
0 792 721 A1 |
Sep 1997 |
EP |
0 842 738 A2 |
Nov 1997 |
EP |
WO 9926763 |
Jun 1999 |
WO |