Electric discharge protection for surface mounted and embedded components

Information

  • Patent Grant
  • 9320135
  • Patent Number
    9,320,135
  • Date Filed
    Friday, February 25, 2011
    13 years ago
  • Date Issued
    Tuesday, April 19, 2016
    8 years ago
Abstract
Printed circuit boards including voltage switchable dielectric materials (VSDM) are disclosed. The VSDMs are used to protect electronic components, arranged on or embedded in printed circuit boards, against electric discharges, such as electrostatic discharges or electric overstresses. During an overvoltage event, a VSDM layer shunts excess currents to ground, thereby preventing electronic components from destruction or damage.
Description
BACKGROUND

1. Field of the Invention


This application relates generally to the protection of electronic devices against surge events, and more specifically to the application of voltage switchable dielectric materials for circuit boards to protect surface mounted and embedded electronic components thereof against electric discharge events.


2. Description of Related Art


Electric discharge, such as electrostatic discharge (ESD), and electrical overstress (EOS) are among the leading causes of failure in electronic components and devices. The continuing trend to miniaturize electronic devices and the integration of increasingly smaller-scaled components into circuits causes an increase in ESD susceptibility problems. Consequently, these failures commonly lead to performance reduction or destruction of electronic devices due to unwanted overvoltage and/or overcurrent influence.


Various solutions have become available to protect electronic devices from ESD and EOS effects. To address ESD issues, engineers commonly use different capacitor based arrangements, Zener diodes, transient voltage suppression (TVS) diodes, multilayer varistors, Schottky diodes, and so forth. However, the aforementioned devices need to be mounted on circuit boards and, therefore, require additional space, in addition to increasing the complexity of the design. Moreover, most integrated circuits cannot be completely protected with existing ESD solutions.


SUMMARY OF THE CLAIMED INVENTION

Various embodiments relate to the use of voltage switchable dielectric materials in printed circuit boards to provide techniques for shunting currents to ground in case of an overvoltage and/or overcurrent event, thereby preventing damage to electronic components


In one embodiment, a printed circuit board is provided including at least one non-conductive layer, a conductor, a voltage switchable dielectric material (VSDM) applied to the conductor, and an electronic component having at least one lead, wherein the at least one lead is electrically coupled to the VSDM layer. The VSDM switches from being dielectric to being conductive when a voltage applied to the material exceeds a characteristic voltage level. The electronic component may be an embedded component or a surface mounted component. The electronic component may be a passive component such as a resistor, an inductor, or a capacitor. The electronic component may be an active component such as a diode, a transistor, a semiconductor device, a circuit, a chip, or an integrated circuit.


In another embodiment, a printed circuit board is provided including at least one non-conductive layer, a conductor, a voltage switchable dielectric material (VSDM) applied to the at least one non-conductive layer, and an electronic component having at least one lead, wherein the at least one lead is electrically coupled to the VSDM layer. The VSDM switches from being dielectric to being conductive when a voltage applied to the material exceeds a characteristic voltage level. The electronic component may be an embedded component or a surface mounted component. The electronic component may be a passive component such as a resistor, an inductor, or a capacitor. The electronic component may be an active component such as a diode, a transistor, a semiconductor device, a circuit, a chip, or an integrated circuit.





BRIEF DESCRIPTION OF THE DRAWINGS

Embodiments are illustrated by way of example and not limitation in the figures of the accompanying drawings, in which like references indicate similar elements.



FIG. 1 illustrates an exemplary VSDM, according to an exemplary embodiment.



FIG. 2 illustrates a stackup incorporating a VSDM layer and a surface mounted electronic component, according to an exemplary embodiment.



FIG. 3 illustrates a stackup incorporating a VSDM layer and a surface mounted electronic component, according to an exemplary embodiment.



FIGS. 4-8 illustrate stackups incorporating VSDM layers and embedded electronic components, according to various exemplary embodiments.



FIGS. 9A-C illustrate several circuits incorporating a VSDM element.





DETAILED DESCRIPTION

In some exemplary embodiments, protection against ESD or EOS may include using a VSDM. A VSDM may behave as an insulator at a lower voltage and a conductor at a higher voltage. A VSDM may have a specific switching voltage, which is a range between the states of low and high conductivity. The VSDM may provide a shunt to ground that protects a circuit and/or electronic component against voltage values above the switching voltage by allowing currents at the higher voltage values to pass to ground through the VSDM, rather than through the device or component being protected.


In this document, the terms “a” or “an” are used, as is common in patent documents, to include one or more than one. In this document, the term “or” is used to refer to a nonexclusive “or,” such that “A or B” includes “A but not B,” “B but not A,” and “A and B,” unless otherwise indicated. Furthermore, all publications, patents, and patent documents referred to in this document are incorporated by reference herein in their entirety, as though individually incorporated by reference. In the event of inconsistent usages between this document and those documents so incorporated by reference, the usage in the incorporated reference(s) should be considered supplementary to that of this document; for irreconcilable inconsistencies, the usage in this document controls.


The word “exemplary” is used herein to mean “serving as an example, instance, or illustration.” Any embodiment described herein as “exemplary” is not to be construed as preferred or advantageous over other embodiments. Likewise, the term “embodiments” does not require that all embodiments include the discussed feature, advantage or mode of operation.


As used herein, the term printed circuit board (PCB) relates to a printed wiring board, an etched wiring board or similar substrate. PCBs are used to mechanically support and electrically connect discrete electronic components using conductive leads, wires, lines, pathways, tracks or signal traces laminated or attached onto a non-conductive substrate. In some cases, metallic leads may be included (e.g., as a layer of Cu which is subsequently etched) to provide electrical connectivity among various attached electronic components. According to some embodiments disclosed herein, the PCB can be implemented as a single substrate or a multi-layer substrate having the same or different conductivity at different layers.


As used herein, the term electronic component may refer to a passive component and/or an active component, and includes but is not limited to a resistor, an inductor, a capacitor, a diode, a transistor, a semiconductor device, a circuit, a chip, an integrated circuit, or the like. Typically, electronic components have conductive leads used for electrical connection thereof to other components or pathways. According to embodiments disclosed herein, electronic components include surface mounted components and embedded components. Electronic components can be implemented as discrete elements or as thin films (e.g. a resistive layer, a capacitance layer, etc.) and deposited or sputtered on substrates or layers of PCB.


As used herein, VSDM relates to any composition, or combination of compositions that has a characteristic of being dielectric or non-conductive, unless a field or voltage that exceeds a specific value is applied to the material, in which case the material becomes conductive. Thus, the VSDM is a dielectric unless voltage (or field) exceeding the value associated with the material (e.g. such as provided by ESD or EOS events) is applied to the material, in which case the VSDM switches to a conductive state.


The VSDM may further be defined as a nonlinear resistance material. In many applications, the characteristic voltage of VSDM ranges in values that exceed the operational voltage levels of the circuit or device several times over. Such voltage levels may be of the order of transient conditions (e.g., produced by electric charges, such as electrostatic discharge), although embodiments may include use of planned electrical events. Furthermore, one or more embodiments provide a VSDM that behaves similarly to a non-conductive or dielectric material in the absence of the voltage exceeding the characteristic voltage.


According to embodiments disclosed herein, the VSDM is a polymer-based material and may include filled polymers. The filled polymers may include a mixture of insulator, conductor, and semiconductor materials. Examples of insulative materials include but are not limited to silicone polymers, epoxy, polyimide, polyethylene, polypropylene, polyphenylene oxide, polysulphone, solgel materials, creamers, silicone dioxide, aluminum oxide, zirconia oxide, and other metal oxide insulators. Examples of conductive materials include metals, such as copper, aluminum, nickel, stainless steel, or the like. Examples of semiconductive materials include both organic and inorganic semiconductors. Some inorganic semiconductors include silicon, silicon carbide, boron nitride, aluminum nitride, nickel oxide, zinc oxide, and zinc sulfide. Examples of organic semiconductors include poly-3-exylthiophene, pentacene, perylene, carbon nanotubes, fullerenes, or the like. A specific formulation and composition may be selected for mechanical and electrical properties well suited to the particular application of the VSDM.


Additionally, one or more embodiments disclosed herein incorporate a VSDM layer over a PCB. The VSDM layer may provide a shunt to ground that protects a circuit and/or electronic component against voltages above the switching voltage by allowing currents at these voltages to pass to ground through the VSDM layer, rather than through the circuit and/or electronic component being protected.



FIG. 1 illustrates an exemplary VSDM 100. The VSDM 100 may include a conductive phase 110 and an insulating and/or semiconducting phase 120. At low voltages, VSDM 100 may behave as an insulator. At voltages above a switching voltage (e.g., above a trigger voltage, above a clamp voltage, etc.), VSDM 100 may behave as a conductor. Typically, VSDM 100 may be connected to an electrical ground, and may shunt current to ground during the protection of a device.



FIG. 2 illustrates an exemplary stackup 200 incorporating a VSDM layer. The stackup 200 includes a non-conductive substrate 202 (e.g., a PCB and/or a layer thereof, such as a prepreg layer or the like). The stackup 200 also includes a VSDM layer 210, which may include any or all of a coating, a layer, a line, and a via. The VSDM may be of any shape, and may be connected to a conductor 220. Certain conductors 220 may be electrically connected to ground such that current is shunted through the VSDM layer to ground during an overvoltage event. The conductor may include a conductive layer, wire, pathline, via, connector, or the like.


An electronic component 230 that is to be protected (e.g., a resistor, inductor, capacitor, diode, transistor, circuit, chip, and the like) may be mounted on the VSDM layer 210. In some cases, the electronic component 230 may be a surface mounted device. According to another embodiment, the electronic component 230 may be a substantially planar device deposited directly on the VSDM layer 210 (e.g., as resistive ink). Furthermore, the electronic component 230 may include one or more leads 240 (e.g., Cu leads). During an overvoltage event (e.g., an ESD or EOS event) involving the electronic component 230, current may be shunted from the leads 240 (and/or the component 230) through the VSDM layer 210 to the conductor 220. The current may bridge a gap 250 between the component 230 and/or the lead 240 and a conductive pad 260, which may be electrically connected to the conductor 220 by a via 270.


The electronic component 230 may be characterized by one or more specifications such as a resistance, an inductance, a capacitance, or the like. In some cases, the ability to withstand an overvoltage and/or overcurrent event may not be specified. For example, a resistor may be designed to provide a resistance of 1 ohm during normal use (e.g., at voltages up to 10 volts) but may be damaged by higher voltages, and a similar resistor designed to be damage resistant may be too large in scale for a given application. Protecting a smaller resistor using a VSDM may allow the use of smaller components, which may be advantageous in packages such as PCB assemblies. While larger resistors such as 0603 and 0402 resistors may be large enough to withstand an overvoltage or overcurrent event, smaller resistors such as 0201 and 01005 resistors may require protection to maintain the integrity of the circuit.


Any of the VSDM layer 210, the conductor 220, and the electronic component 230 may be disposed on the surface of the substrate 202, or be inside (e.g., embedded in) the substrate 202. In some embodiments, the VSDM layer 210 and the electronic component 230 are embedded in a PCB (e.g., fabricated as layers in a PCB stackup). The stackup 200 may be embedded by adding and processing additional PCB components (e.g., additional layers of prepreg).



FIG. 3 illustrates an exemplary stackup 300 incorporating a VSDM layer. In this example, the stackup 300 may include a non-conductive substrate 202 (such as a printed circuit board and/or a layer thereof) and/or other assembly. A VSDM layer 210 may include a coating, a layer, a line, a via, and/or be of any other shape, and may generally be connected to a conductor 220. An electronic component 230 being protected (surface mounted or embedded) may be mounted onto or incorporated into the VSDM layer 210. During an overvoltage event (e.g., an ESD event) involving the component 230, current may be shunted from the leads (and/or the component 230 itself) through the VSDM layer 210 to the conductor 220. In some cases, an active volume may be associated with the portion of the VSDM layer 210 located in a gap 350 between leads 240 and/or component 230 and conductor 220. An active volume may be associated with a thickness of the VSDM layer and an area (e.g., of bounding conductors), and may predominantly describe a volume through which current passes during an overvoltage event. The stackup 300 may be embedded by adding and processing additional PCB components (e.g., additional layers of prepreg, or the like).



FIG. 4 illustrates a cross section of an exemplary stackup 400. As shown, the stackup 400 may include one or more non-conductive substrates 202 and at least one VSDM layer 210. The VSDM layer 210 may be implemented as a coating, film, line, via, wire, pathline, and/or be of any other appropriate shape according to the specific application. The VSDM layer 210 may generally be connected to ground via one or more conductors 220, a pad 260, a via 270, or a combination thereof. An electronic component 430 (e.g., a thin film resistive layer 432 and associated leads 440) being protected may be deposited, sputtered, or otherwise formed onto the VSDM layer 210.


During an overvoltage event (e.g., an ESD or EOS event) involving the component 430, excess current may be shunted to ground, rather than passing through the component 430 at a level that damages the component 430. The current may be shunted by passing through the VSDM layer 210, which may include a gap 450. In some cases, additional layers (e.g., a film associated with the component 430) may be present in a condition that does not deleteriously affect the ESD/EOS protection capabilities of the VSDM layer 210 (e.g., a resistive film may be particularly thin, so the resistive layer 432 may be disposed beneath the leads 440 when the resistive layer 432 is particularly thin).



FIG. 5 illustrates a cross section of a stackup 500. In this example, the stackup 500 may include at least one non-conductive substrate 202 and a VSDM layer 210. The VSDM layer 210 may be implemented as a coating, film, line, via, wire, pathline, and/or be of any other appropriate shape according to the specific application. The VSDM layer 210 may generally be connected to ground via one or more conductors 220 disposed on the surface of the stackup 500, and also by means of a pad 260, a via 270, or a combination thereof. An electronic component 430 being protected may be deposited, sputtered or otherwise formed onto the VSDM layer 210. The electronic component 430 may be implemented as a thin film resistive layer 432 and include associated conductive leads 440, which may also be deposited or sputtered onto the resistive layer 432 and/or one of the stackup layers.


In case of an overvoltage event related to an ESD or EOS involving the component 430, overcurrent may be shunted to ground, rather than passing through the electronic component 430. The excess current may be shunted by passing through the VSDM layer 210, which may include a gap 550.



FIG. 6 illustrates a cross section of an exemplary stackup 600. According to this embodiment, the stackup 600 may include a non-conductive VSDM layer 210 protecting a plurality of regions of an electronic component 430. The VSDM layer 210 may generally be connected to ground via one or more conductors 220 arranged in the stackup 600, and by means of a pad 260, a via 270, or a combination thereof. The electronic component 430 being protected may be deposited, sputtered, or otherwise formed onto the VSDM layer 210. The electronic component 430 may be implemented as a thin film (e.g. resistive layer) and include at least one associated conductive lead 440. In the stackup 600, a first gap 650 and a second gap 652 define substantially separate regions of the VSDM layer 210 through which current may pass during an overvoltage event.



FIG. 7 illustrates a cross section of an exemplary stackup 700. In this embodiment, the stackup 700 may provide for a VSDM layer 210 with one or more non-conductive substrates 202 between the VSDM layer and the electronic component 430 being protected. The stackup 700 may also include one or more conductors 220, one or more vias 270, and one or more pads 260, each of which may be interconnected between each other and to ground.


The VSDM layer 210 may include a gap 750. During an overvoltage event involving the electronic component 430, excess current may be shunted to ground via the gap 750 of the VSDM layer 210, rather than passing through the component 430 itself, thereby protecting component 430 from damage or destruction.



FIG. 8 illustrates a cross section of an exemplary stackup 800. As shown, the stackup 800 may include at least two non-conductive substrates 202, a VSDM layer 210 disposed between the substrates 202, an electronic component 430 including one or more conductive leads 440, and a plurality of connection elements, such as a conductor 220, a via 270, pads 260, or a combination thereof. The electronic component 430 may be arranged on a first substrate 202, and may not have a direct contact with the VSDM layer 210, but rather an electrical contact accomplished by the plurality of connection elements. The VSDM layer 210 may include a gap 850, which may be associated with an active region of current passage (e.g., between pads 260 on either side of the gap 850) during an overvoltage event.



FIGS. 9A-C illustrate several circuit schemes incorporating a VSDM element. In these illustrations, a VSDM element 900 is shown schematically as an electrical valve with a lightning bolt symbol. In these examples, the VSDM element 900 is connected to a conductor that may be connected to ground, and is electrically (and sometimes physically) connected to an electronic device or electronic component to be protected.



FIG. 9A illustrates a VSDM 900 protecting a resistor 910, which may be a surface mounted or an embedded resistor. In this example, the VSDM 900 is electrically connected to a lead of the resistor 910. An overvoltage event, such as ESD or EOS capable of damaging the resistor 910, may result in shunting excess current to ground via the VSDM element 900.



FIG. 9B illustrates a VSDM element 900 protecting a capacitor 920, which may be a surface mounted or an embedded capacitor. In this example, the VSDM element 900 is connected to leads on both sides of the capacitor 920. An overvoltage event that might damage the capacitor 920 may result in shunting excess current to ground via at least one of the VSDM elements 900.



FIG. 9C illustrates a VSDM element 900 protecting an inductor 930, which may be an embedded inductor. In this example, the VSDM element 900 is connected to a lead of the inductor 930. In case of an overvoltage event that might damage inductor 930, excess current is shunted to ground via the VSDM element 900.


Some embodiments may include sensors to sense various parameters (e.g., current, voltage, power, resistance, resistivity, inductance, capacitance, thickness, strain, temperature, stress, concentration, depth, length, width, switching voltage and/or voltage density (between insulating and conducting), trigger voltage, clamp voltage, off-state current passage, dielectric constant, time, date, and other characteristics). Various apparatuses may monitor various sensors, and systems may be actuated by automated controls (solenoid, pneumatic, piezoelectric, and the like). Some embodiments may include a computer-readable storage medium coupled to a processor and memory. Executable instructions stored on the computer readable storage medium may be executed by the processor to perform, control or monitor various methods of operating and/or protecting electronic components arranged in PCBs. Sensors and actuators may be coupled to the processor, providing input and receiving instructions associated with various methods. Certain instructions may be provided for closed-loop control of various parameters via coupled sensors providing input and coupled actuators receiving instructions to adjust parameters. Various embodiments may include different electronic devices such as telephones (e.g., cell phones), Universal Serial Bus (USB)-devices (e.g., a USB-storage device), personal digital assistants (PDAs), laptop computers, netbook computers, tablet Personal Computer (PC), light emitting diodes (LEDs), and the like.


The foregoing description is provided to enable any person skilled in the art to make or use specific embodiments. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the scope of the disclosure. Thus, the present disclosure is not intended to be limited to the embodiments described herein but is to be accorded the widest scope consistent with the principles disclosed herein.

Claims
  • 1. A printed circuit board, comprising: at least one conductor;a voltage switchable dielectric material (VSDM) layer applied to the at least one conductor;an electronic component having at least one lead and disposed on the VSDM layer, wherein the at least one lead is electrically coupled to the VSDM layer;a via; anda conductive pad connected to the conductor by the via,wherein the VSDM layer comprises an active volume defined by a gap between the at least one lead and the conductive pad, wherein the active volume to pass current through to a ground during an overvoltage event.
  • 2. The printed circuit board of claim 1, wherein the electronic component is a surface mounted component.
  • 3. The printed circuit board of claim 2, wherein the surface mounted component includes one or more of a resistor, an inductor, and a capacitor.
  • 4. The printed circuit board of claim 2, wherein the surface mounted component includes one or more of a diode, a transistor, a semiconductor device, a circuit, a chip, and an integrated circuit.
  • 5. The printed circuit board of claim 1, wherein the VSDM layer is incorporated within a non-conductive layer.
  • 6. The printed circuit board of claim 1, wherein the VSDM layer is disposed between at least two non-conductive layers.
  • 7. The printed circuit board of claim 1, wherein the electronic component comprises a thin film resistive layer.
  • 8. A printed circuit board, comprising: at least one non-conductive layer;at least one conductor;a voltage switchable dielectric material (VSDM) layer applied to one of the at least one non-conductive layer;an electronic component having at least one lead and is mounted to the VSDM layer, wherein the at least one lead is electrically coupled to the VSDM layer; anda via; anda conductive pad connected to the conductor by the via,wherein the VSDM layer comprises an active volume defined by a gap between the at least one lead and the conductive pad, wherein the active volume to pass current through to a ground during an overvoltage event.
  • 9. The printed circuit board of claim 8, wherein the electronic component is a surface mounted component.
  • 10. The printed circuit board of claim 9, wherein the surface mounted component includes one or more of a resistor, an inductor, and a capacitor.
  • 11. The printed circuit board of claim 9, wherein the surface mounted component includes one or more of a diode, a transistor, a semiconductor device, a circuit, a chip, and an integrated circuit.
  • 12. The printed circuit board of 8, wherein the VSDM layer is incorporated within the at least one non-conductive layer.
  • 13. The printed circuit board of claim 8, wherein the VSDM layer is disposed between at least two non-conductive layers.
  • 14. The printed circuit board of claim 8, wherein the electronic component comprises a thin film resistive layer.
CROSS-REFERENCE TO RELATED APPLICATIONS

This nonprovisional patent application claims the priority benefit of U.S. provisional application No. 61/308,825 filed on Feb. 26, 2010, titled “Protecting Embedded Components,” which is hereby incorporated by reference in its entirety.

US Referenced Citations (254)
Number Name Date Kind
3347724 Schneble, Jr. et al. Oct 1967 A
3685026 Wakabayashi et al. Aug 1972 A
3685028 Wakabayashi et al. Aug 1972 A
3723635 Smith Mar 1973 A
3808576 Castonguay et al. Apr 1974 A
3926916 Mastrangelo Dec 1975 A
3977957 Kosowsky et al. Aug 1976 A
4113899 Henry et al. Sep 1978 A
4133735 Afromowitz et al. Jan 1979 A
4252692 Taylor et al. Feb 1981 A
4269672 Inoue May 1981 A
4331948 Malinaric et al. May 1982 A
4359414 Mastrangelo Nov 1982 A
4405432 Kosowsky Sep 1983 A
4439809 Weight et al. Mar 1984 A
4506285 Einzinger et al. Mar 1985 A
4591411 Reimann May 1986 A
4642160 Burgess Feb 1987 A
4702860 Kinderov et al. Oct 1987 A
4714952 Takekawa et al. Dec 1987 A
4726877 Fryd et al. Feb 1988 A
4726991 Hyatt et al. Feb 1988 A
4799128 Chen Jan 1989 A
4888574 Rice et al. Dec 1989 A
4892776 Rice Jan 1990 A
4918033 Bartha et al. Apr 1990 A
4928199 Diaz et al. May 1990 A
4935584 Boggs Jun 1990 A
4977357 Shrier Dec 1990 A
4992333 Hyatt Feb 1991 A
4996945 Dix, Jr. Mar 1991 A
5068634 Shrier Nov 1991 A
5092032 Murakami Mar 1992 A
5095626 Kitamura et al. Mar 1992 A
5099380 Childers et al. Mar 1992 A
5142263 Childers et al. Aug 1992 A
5148355 Lowe et al. Sep 1992 A
5167778 Kaneko et al. Dec 1992 A
5183698 Stephenson et al. Feb 1993 A
5189387 Childers et al. Feb 1993 A
5246388 Collins et al. Sep 1993 A
5248517 Shrier et al. Sep 1993 A
5252195 Kobayashi et al. Oct 1993 A
5260848 Childers Nov 1993 A
5262754 Collins Nov 1993 A
5278535 Xu et al. Jan 1994 A
5282312 DiStefano et al. Feb 1994 A
5294374 Martinez et al. Mar 1994 A
5295297 Kitamura et al. Mar 1994 A
5300208 Angelopoulos et al. Apr 1994 A
5317801 Tanaka et al. Jun 1994 A
5340641 Xu Aug 1994 A
5347258 Howard et al. Sep 1994 A
5354712 Ho et al. Oct 1994 A
5367764 DiStefano et al. Nov 1994 A
5378858 Bruckner et al. Jan 1995 A
5380679 Kano Jan 1995 A
5393597 Childers et al. Feb 1995 A
5403208 Felcman et al. Apr 1995 A
5404637 Kawakami Apr 1995 A
5413694 Dixon et al. May 1995 A
5416662 Kurasawa et al. May 1995 A
5440075 Kawakita et al. Aug 1995 A
5444593 Allina Aug 1995 A
5476471 Shifrin et al. Dec 1995 A
5481795 Hatakeyama et al. Jan 1996 A
5483407 Anastasio et al. Jan 1996 A
5487218 Bhatt et al. Jan 1996 A
5493146 Pramanik et al. Feb 1996 A
5501350 Yoshida et al. Mar 1996 A
5502889 Casson et al. Apr 1996 A
5510629 Karpovich et al. Apr 1996 A
5550400 Takagi et al. Aug 1996 A
5557136 Gordon et al. Sep 1996 A
5654564 Mohsen Aug 1997 A
5669381 Hyatt Sep 1997 A
5685070 Alpaugh et al. Nov 1997 A
5708298 Masayuki et al. Jan 1998 A
5714794 Tsuyama et al. Feb 1998 A
5734188 Murata et al. Mar 1998 A
5744759 Ameen et al. Apr 1998 A
5781395 Hyatt Jul 1998 A
5802714 Kobayashi et al. Sep 1998 A
5807509 Shrier et al. Sep 1998 A
5808351 Nathan et al. Sep 1998 A
5834160 Ferry et al. Nov 1998 A
5834824 Shepherd et al. Nov 1998 A
5834893 Bulovic et al. Nov 1998 A
5848467 Khandros et al. Dec 1998 A
5856910 Yurchenco et al. Jan 1999 A
5865934 Yamamoto et al. Feb 1999 A
5869869 Hively Feb 1999 A
5874902 Heinrich et al. Feb 1999 A
5906042 Lan et al. May 1999 A
5910685 Watanabe et al. Jun 1999 A
5926951 Khandros et al. Jul 1999 A
5940683 Holm et al. Aug 1999 A
5946555 Crumly et al. Aug 1999 A
5955762 Hively Sep 1999 A
5956612 Elliott et al. Sep 1999 A
5962815 Lan et al. Oct 1999 A
5970321 Hively Oct 1999 A
5972192 Dubin et al. Oct 1999 A
5977489 Crotzer et al. Nov 1999 A
6013358 Winnett et al. Jan 2000 A
6023028 Neuhalfen Feb 2000 A
6064094 Intrater et al. May 2000 A
6108184 Minervini et al. Aug 2000 A
6114672 Iwasaki Sep 2000 A
6130459 Intrater Oct 2000 A
6160695 Winnett et al. Dec 2000 A
6172590 Shrier et al. Jan 2001 B1
6184280 Shituba Feb 2001 B1
6191928 Rector et al. Feb 2001 B1
6198392 Hahn et al. Mar 2001 B1
6211554 Whitney et al. Apr 2001 B1
6239687 Shrier et al. May 2001 B1
6251513 Rector et al. Jun 2001 B1
6310752 Shrier et al. Oct 2001 B1
6316734 Yang Nov 2001 B1
6340789 Petritsch et al. Jan 2002 B1
6351011 Whitney et al. Feb 2002 B1
6373719 Behling et al. Apr 2002 B1
6407411 Wojnarowski Jun 2002 B1
6433394 Intrater Aug 2002 B1
6448900 Chen Sep 2002 B1
6455916 Robinson Sep 2002 B1
6468593 Iazawa Oct 2002 B1
6512458 Kobayashi et al. Jan 2003 B1
6534422 Ichikawa et al. Mar 2003 B1
6542065 Shrier et al. Apr 2003 B2
6549114 Whitney et al. Apr 2003 B2
6570765 Behling et al. May 2003 B2
6593597 Sheu Jul 2003 B2
6621172 Nakayama et al. Sep 2003 B2
6628498 Whitney et al. Sep 2003 B2
6642297 Hyatt et al. Nov 2003 B1
6657532 Shrier et al. Dec 2003 B1
6677183 Sakaguchi et al. Jan 2004 B2
6693508 Whitney et al. Feb 2004 B2
6709944 Durocher et al. Mar 2004 B1
6741217 Toncich et al. May 2004 B2
6797145 Kosowsky Sep 2004 B2
6882051 Majumdar et al. Apr 2005 B2
6903175 Gore et al. Jun 2005 B2
6911676 Yoo Jun 2005 B2
6916872 Yadav et al. Jul 2005 B2
6981319 Shrier Jan 2006 B2
7034652 Whitney et al. Apr 2006 B2
7049926 Shrier et al. May 2006 B2
7053468 Lee May 2006 B2
7064353 Bhat Jun 2006 B2
7067840 Klauk Jun 2006 B2
7132697 Weimer et al. Nov 2006 B2
7132922 Harris et al. Nov 2006 B2
7141184 Chacko et al. Nov 2006 B2
7173288 Lee et al. Feb 2007 B2
7183891 Harris et al. Feb 2007 B2
7202770 Harris et al. Apr 2007 B2
7205613 Fjelstand et al. Apr 2007 B2
7218492 Shrier May 2007 B2
7279724 Collins et al. Oct 2007 B2
7320762 Greuter et al. Jan 2008 B2
7341824 Sexton Mar 2008 B2
7417194 Shrier Aug 2008 B2
7446030 Kosowsky Nov 2008 B2
7488625 Knall Feb 2009 B2
7492504 Chopra et al. Feb 2009 B2
7528467 Lee May 2009 B2
7535462 Spath et al. May 2009 B2
7585434 Morita Sep 2009 B2
7593203 Dudnikov et al. Sep 2009 B2
7609141 Harris et al. Oct 2009 B2
7692270 Subramanyam et al. Apr 2010 B2
7872251 Kosowsky et al. Jan 2011 B2
7923844 Kosowsky Apr 2011 B2
8045312 Shrier Oct 2011 B2
20020004258 Nakayama et al. Jan 2002 A1
20020050912 Shrier et al. May 2002 A1
20020061363 Halas et al. May 2002 A1
20030010960 Greuter et al. Jan 2003 A1
20030025587 Whitney et al. Feb 2003 A1
20030071245 Harris, VI Apr 2003 A1
20030079910 Kosowsky May 2003 A1
20030151029 Hsu Aug 2003 A1
20030218851 Harris et al. Nov 2003 A1
20040000725 Lee Jan 2004 A1
20040062041 Cross et al. Apr 2004 A1
20040063839 Kawate et al. Apr 2004 A1
20040095658 Buretea et al. May 2004 A1
20040154828 Moller et al. Aug 2004 A1
20040160300 Shrier Aug 2004 A1
20040201941 Harris et al. Oct 2004 A1
20040211942 Clark et al. Oct 2004 A1
20040241894 Nagai et al. Dec 2004 A1
20040262583 Lee et al. Dec 2004 A1
20050026334 Knall Feb 2005 A1
20050039949 Kosowsky Feb 2005 A1
20050057867 Harris et al. Mar 2005 A1
20050083163 Shrier Apr 2005 A1
20050106098 Tsang et al. May 2005 A1
20050121653 Chacko Jun 2005 A1
20050175938 Casper et al. Aug 2005 A1
20050184387 Collins et al. Aug 2005 A1
20050218380 Gramespacher et al. Oct 2005 A1
20050255631 Bureau et al. Nov 2005 A1
20050274455 Extrand Dec 2005 A1
20050274956 Bhat Dec 2005 A1
20050275070 Hollingsworth Dec 2005 A1
20060060880 Lee et al. Mar 2006 A1
20060069199 Charati et al. Mar 2006 A1
20060142455 Agarwal Jun 2006 A1
20060152334 Maercklein et al. Jul 2006 A1
20060166474 Vereecken et al. Jul 2006 A1
20060167139 Nelson et al. Jul 2006 A1
20060181826 Dudnikov, Jr. et al. Aug 2006 A1
20060181827 Dudnikov, Jr. et al. Aug 2006 A1
20060193093 Bertin Aug 2006 A1
20060199390 Dudnikov, Jr. et al. Sep 2006 A1
20060211837 Ko et al. Sep 2006 A1
20060214156 Pan et al. Sep 2006 A1
20060234127 Kim Oct 2006 A1
20060291127 Kim et al. Dec 2006 A1
20070114640 Kosowsky May 2007 A1
20070116976 Tan et al. May 2007 A1
20070123625 Dorade et al. May 2007 A1
20070126018 Kosowsky Jun 2007 A1
20070139848 Harris et al. Jun 2007 A1
20070146941 Harris et al. Jun 2007 A1
20070208243 Gabriel et al. Sep 2007 A1
20070241458 Ding et al. Oct 2007 A1
20080045770 Sigmund et al. Feb 2008 A1
20080047930 Blanchet et al. Feb 2008 A1
20080073114 Kosowsky et al. Mar 2008 A1
20080144355 Boeve et al. Jun 2008 A1
20080223603 Kim et al. Sep 2008 A1
20080278873 Leduc et al. Nov 2008 A1
20080313576 Kosowsky et al. Dec 2008 A1
20090044970 Kosowsky Feb 2009 A1
20090309074 Chen et al. Dec 2009 A1
20090310265 Fukuoka et al. Dec 2009 A1
20100038119 Kosowsky Feb 2010 A1
20100038121 Kosowsky Feb 2010 A1
20100040896 Kosowsky Feb 2010 A1
20100044079 Kosowsky Feb 2010 A1
20100044080 Kosowsky Feb 2010 A1
20100047535 Kosowsky et al. Feb 2010 A1
20100187006 Kosowsky et al. Jul 2010 A1
20100243302 Kosowsky et al. Sep 2010 A1
20100270588 Kosowsky et al. Oct 2010 A1
20110061230 Kosowsky Mar 2011 A1
20110062388 Kosowsky et al. Mar 2011 A1
20110211289 Kosowsky et al. Sep 2011 A1
20110317318 Fleming et al. Dec 2011 A1
Foreign Referenced Citations (29)
Number Date Country
663491 Dec 1987 CH
3040784 May 1982 DE
10115333 Jan 2002 DE
102004049053 May 2005 DE
102006047377 Apr 2008 DE
0790758 Aug 1997 EP
0930623 Jul 1999 EP
1003229 May 2000 EP
1245586 Oct 2002 EP
1542240 Jun 2005 EP
1580809 Sep 2005 EP
1990834 Nov 2008 EP
56091464 Jul 1981 JP
63 195275 Aug 1988 JP
2000062076 Feb 2000 JP
WO8906859 Jul 1989 WO
WO9602922 Feb 1996 WO
WO9602924 Feb 1996 WO
WO9726665 Jul 1997 WO
WO9823018 May 1998 WO
WO9924992 May 1999 WO
WO02103085 Dec 2002 WO
WO2005100426 Oct 2005 WO
WO2006130366 Dec 2006 WO
WO2007062170 May 2007 WO
WO2007062171 May 2007 WO
WO2008016858 Feb 2008 WO
WO2008016859 Feb 2008 WO
WO2008153584 Dec 2008 WO
Non-Patent Literature Citations (12)
Entry
Breton et al., “Mechanical properties of multiwall carbon nanotubes/epoxy composites: influence of network morphology,” Carbon Elsevier UK, vol. 42, No. 5-6, pp. 1027-1030 (2004).
Celzard, A., et al., “Conduction Mechanisms in Some Graphite-polymer Composites: The Effect of a Direct-current Electric Field”, Journal of Physics: Condensed Matter, 9 (1997) pp. 2225-2237.
Facchetti, Antonio, “Semiconductors for Organic Transistors”, Materials Today, vol. 10, No. 3, pp. 28-37.
Fullerene Chemistry—Wikipedia, http://en.wikipedia.org/wiki/Fullerene/chemistry, 6 pages, printed Apr. 8, 2010.
Granstrom et al., “Laminated fabrication of polymeric photovoltaic diodes,” Nature, vol. 395, pp. 257-260 (1998).
Guo et al., “Block Copolymer Modified Novolac Epoxy Resin,” Polymer Physics, vol. 41, No. 17, pp. 1994-2003 (2003).
Levinson et al. “The Physics of Metal Oxide Varistors,” J. App. Phys. 46 (3): 1332-1341 (1975).
Modine, F.A. and Hyatt, H.M. “New Varistor Material”, Journal of Applied Physics, 64 (8), Oct. 15, 1988, pp. 4229-4232.
Onoda et al., “Photoinduced Charge Transfer of Conducting Polymer Compositions,” IEICE Trans. Electronics, vol. E81-C(7), pp. 1051-1056 (1998).
Raffaelle et al., “Nanomaterial Development for Polymeric Solar Cells,” IEEE 4th World Conf on Photovoltaic energy Conversion, pp. 186-189 (2006).
Reese, Colin and Bao, Zhenan, “Organic Single-Crystal Field-Effect Transistors”, Materials Today, vol. 10, No. 3, pp. 20-27.
Saunders et al., “Nanoparticle-polymer photovoltaic cells,” Adv. Colloid Int. Sci., vol. 138, No. 1, pp. 1-23 (2007).
Related Publications (1)
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20110211319 A1 Sep 2011 US
Provisional Applications (1)
Number Date Country
61308825 Feb 2010 US