The present invention relates to a method for manufacturing a solar cell, and more specifically to bonding a component of the solar cell onto a substrate, using an ultrasonic vibration bonding method.
Thin-film solar cells each formed with a power generation layer and an electrode layer on a glass substrate have conventionally been used as solar cells. Typically, each of the thin-film solar cells includes solar cells connected in series.
Furthermore, in the structures of the thin-film solar cells, electricity generated by each of the solar cells is collected by a collecting electrode (bus bar) formed in the vicinity of both sides of the glass substrate. Then, the electricity collected by the collecting electrode is derived from a lead (leader line). In other words, the lead is connected to the collecting electrode, and also to a terminal of a terminal box. The connection configuration allows the lead to derive the electricity collected by the collecting electrode to the terminal box.
Here, the collecting electrode is electrically connected to the electrode layer formed on the glass substrate in the solar cell, and the lead is not directly connected to the solar cell (specifically, the lead is electrically connected to the solar cell through the collecting electrode, but the solar cell is insulated from the lead).
The conventional techniques related to the present invention (specifically, the conventional techniques for connecting a collecting electrode or others to a substrate, using ultrasonic vibration bonding) have already existed (Patent Documents 1, 2, 3, 4, and 5).
Patent Document 1: International Publication WO2010/150350
Patent Document 2: Japanese Unexamined Patent Application Publication No. 2011-9261
Patent Document 3: Japanese Unexamined Patent Application Publication No. 2011-9262
Patent Document 4: Japanese Unexamined Patent Application Publication No. 2012-4280
Patent Document 5: Japanese Unexamined Patent Application Publication No. 2012-4289
Solar cells (solar-cell laminated films) are formed on substrates, and strip-shaped collecting electrodes are disposed on the solar cells. The ultrasonic vibration bonding is performed on the collecting electrodes. Accordingly, the electrode layer included in each of the solar cells is electrically connected to the collecting electrode, and the collecting electrode is bonded onto the substrate.
In the ultrasonic vibration bonding, ultrasonic vibration tools abut on the collecting electrodes, and apply pressure thereto. During application of the pressure, the ultrasonic vibration tools are ultrasonically vibrated in a horizontal direction. In recent years, it has been desired to bond the collecting electrodes onto the substrates at lower peel strength (bonding strength). The reason is as follows.
To increase the peel strength (bonding strength) of the collecting electrodes with respect to the substrates, the ultrasonic vibration tools are strongly pressed against the collecting electrodes. Then, the solar cells under the collecting electrodes are damaged, and the damaged solar cells do not generate electricity. Thus, it is desired to bond the collecting electrodes onto the substrates at lower peel strength (bonding strength) to prevent the solar cells from being damaged while the collecting electrodes are continuously bonded (fixed) onto the substrates. Even when the peel strength of the collecting electrodes is reduced, the collecting electrodes need to be fixed to the substrates on which the solar cells are formed.
Furthermore, when the strip-shaped collecting electrodes are bonded onto the substrates, the ultrasonic vibration bonding is performed on points (hereinafter referred to as process execution points) of the collecting electrodes along the strips. Here, it is not desired that the peel strengths (bonding strengths) of a collecting electrode greatly vary among the process execution points on the collecting electrode. This is because when the collecting electrodes are bonded onto the substrates at lower peel strength (bonding strength) and variations in the peel strength (bonding strength) are wide, at some of the process execution points, the collecting electrodes cannot be bonded onto the substrates at all, and the solar cells are damaged due to application of extremely high pressure to the collecting electrodes.
An object of the present invention is to provide an electrode bonding apparatus and an electrode bonding method that are capable of reducing variations in the peel force among points of a collecting electrode, even when the collecting electrode is bonded onto a substrate at a lower peel force by performing the ultrasonic vibration bonding on points of the collecting electrode.
In order to achieve the object, the electrode bonding apparatus according to the present invention is an electrode bonding apparatus that bonds an electrode onto a substrate on which a solar cell is formed, along a side of the substrate, the substrate being rectangular, the electrode bonding apparatus including: a table on which the substrate is mounted; an ultrasonic vibration tool that performs ultrasonic vibration bonding on the electrode disposed along the side, on the solar cell; and two pressure parts that press the substrate, the pressure parts being vertically movable, wherein the substrate has a first side, and a second side facing the first side, one of the pressure parts presses the substrate along the first side, in a first predetermined region of the substrate between the first side and an arrangement position of the electrode, and the other of the pressure parts presses the substrate along the second side, in a second predetermined region of the substrate between the second side and an arrangement position of the electrode.
Furthermore, the electrode bonding method according to the present invention is an electrode bonding method including: (A) mounting, on a table (11), a substrate (1) on which a solar cell (ST1) is formed, the substrate being rectangular; (B) disposing an electrode (20A, 20B) along a side (L1, L2) of the substrate, on the solar cell; (C) pressing the substrate along the side, in a region of the substrate between the side and an arrangement position of the electrode; and (D) bonding the electrode on the substrate by performing ultrasonic vibration bonding on the substrate during the step (C).
According to the present invention, the following bonding is performed on an electrode disposed along a side of a substrate on a solar cell. Specifically, the substrate is pressed along a side in a region of the substrate between the side and an arrangement point of an electrode, that is, a region of the substrate having a width from a point of the side to the arrangement position of the electrode. During application of the pressure, the ultrasonic vibration bonding is performed on the electrode to bond the electrode onto the substrate.
Even when the electrode is bonded onto the substrate 1 at a lower peel strength (bonding strength), variations in the peel strength (bonding strength) among points of the electrode can be reduced.
The objects, features, aspects and advantages of the present invention will become more apparent from the following detailed description and the accompanying drawings of the present invention.
The present invention employs the ultrasonic vibration bonding method (ultrasonic vibration bonding) in bonding a collecting electrode to be disposed on a solar cell. The ultrasonic vibration bonding method is a technique (process) for bonding an object (collecting electrode) onto a to-be-bonded object (solar cell substrate) by horizontally applying ultrasonic vibrations to the object while vertically applying pressure thereto. The following will specifically describe the present invention based on the drawings depicting the embodiments of the present invention.
A substrate 1 (hereinafter “glass substrate 1”) that is transparent and rectangular is first prepared. Then, each of a surface electrode layer, a power generation layer, and a back electrode layer is formed onto a predetermined pattern on a first principal surface of the glass substrate 1. These processes produce a fundamental structure of a thin-film solar cell. An insulating protective film may be laminated on the first principal surface to cover all the surface electrode layer, the power generation layer, and the back electrode layer. The following description does not include the protective film for the sake of simplification.
The entire structure formed by laminating in order the surface electrode layer, the power generation layer, and the back electrode layer on the first principal surface of the glass substrate 1 will be hereinafter referred to as a solar-cell laminated film ST1 or a solar cell ST1.
The surface electrode layer, the power generation layer, and the back electrode layer are laminated in order, and each of the surface electrode layer and the back electrode layer is electrically connected to the power generation layer. Furthermore, the glass substrate 1 is, for example, a thin-film substrate with a thickness of approximately less than or equal to several millimeters. Furthermore, the surface electrode layer includes a transparent conductive film, and can be made from, for example, ZnO, ITO, or SnO2. Furthermore, the surface electrode layer has, for example, a thickness of approximately several tens of nanometers.
Furthermore, the power generation layer is a photoelectric conversion layer that can convert incident light into electricity. The power generation layer is a thin layer having a thickness of approximately several micrometers (for example, 3 μm). Furthermore, the power generation layer, for example, contains silicon. Furthermore, the back electrode layer can be made from, for example, a conductive film containing silver. Furthermore, the back electrode layer has, for example, a thickness of approximately several tens of nanometers.
Next, the following names are defined to simplify the description hereinafter.
The glass substrate 1 is rectangle in a planar view. Thus, the first principal surface of the glass substrate 1 has sides L1, L2, L3, and L4 as illustrated in
In the structure exemplified in
Next, a structure of an electrode bonding apparatus 100 according to the present invention will be described.
The electrode bonding apparatus 100 includes an ultrasonic vibration tool, a controller, a table 11, and substrate fixing parts 12.
The table 11 includes a plate part, and the glass substrate 1 is mounted on the plate part. Furthermore, each of the substrate fixing part 12 includes a pressure part 12A and a driver 12B as illustrated in
The substrate fixing parts 12 are devices capable of fixing the glass substrate 1 to the table 11 by pressing the glass substrate 1 mounted on the table 11. One of the substrate fixing parts 12 is disposed on one of the sides of the table 11, and the other of the substrate fixing parts 12 is disposed on the other of the sides of the table 11. The substrate fixing parts 12 can vertically and horizontally move as illustrated in
Each of the drivers 12B includes, for example, an air cylinder, and operates vertically and horizontally in
The pressure parts 12A are rodlike parts that are L-shaped in a cross-sectional view (specifically, L-shaped rods) as illustrated in
As described above, each of the substrate fixing parts 12 includes the two drivers 12B, and one of the pressure parts 12A that is fixed by the two drivers 12B.
The controller is a device that controls the operation of the substrate fixing parts 12. Specifically, the controller can variably control the pressure applied by the pressure pans 12A, and also the vertical and horizontal movement of the pressure parts 12A in
For example, the pressure applied by the pressure parts 12A against the glass substrate 1 needs to be changed, according to a material and a thickness of the collecting electrode, a material and a thickness of each film included in the solar cell ST1, and the conditions of the ultrasonic vibration bonding. Thus, the controller variably controls the pressure applied by the pressure parts 12A, according to an instruction from the user. Furthermore, upon receipt of each information item (a material and a thickness of the collecting electrode, a material and a thickness of each film included in the solar cell ST1, and the conditions of the ultrasonic vibration bonding), the controller may control the pressure parts 12A according to a predefined table and the pressure determined by the information item. The table uniquely defines the pressure for each of the information items.
Next, operations of bonding the collecting electrode onto the glass substrate 1 using the electrode bonding apparatus 100 will be described.
First, the glass substrate 1 on which the solar cell ST1 is formed is prepared. Then, the glass substrate 1 is mounted on a planar part of the table 11. The dimensions of the table 11 in a direction in which the substrate fixing parts 12 face each other (hereinafter referred to as “facing direction”) are smaller than those of the glass substrate 1 in the facing direction. Furthermore, when the glass substrate 1 is mounted on the table 11 the surface of the glass substrate 1 on which the solar cell ST1 is formed is the top surface.
Next, when the drivers 12B operate under control adjusted by the controller, the substrate fixing parts 12 horizontally move as in
Then, the surfaces of the pressure parts 12A facing the side surfaces of the glass substrate 1 are in contact with the side surfaces of the glass substrate 1. Then, the pressure parts 12A hold the glass substrate 1 from the both sides. Here, each of the substrate fixing parts 12 is horizontally adjusted and moves under control adjusted by the controller. The control is performed according to an instruction from the user. In other words, the position of the glass substrate 1 on the table 11 is determined according to an instruction from the user.
The adjustment herein means positioning the table 11 on which the glass substrate 1 is mounted. In other words, the adjusted movement of each of the substrate fixing parts 12 can position the glass substrate 1 on the table 11. As described above, the dimensions of the table 11 in the facing direction are smaller than those of the glass substrate 1 in the same direction. Thus, it is possible to prevent the pressure parts 12A from being in contact with the side surfaces of the table 11 in the positioning, and positioning of the glass substrate 1 using the pressure part 12A from being interfered with.
After the completion of the positioning, by operating the drivers 12B under control by the controller, the substrate fixing parts 12 move downward in
Then, the surfaces of the pressure parts 12A facing the top surface of the glass substrate 1 are in contact with the solar cell ST1 formed on the glass substrate 1. Then, each of the pressure parts 12A presses the glass substrate 1 from above. Here, each of the substrate fixing parts 12 moves downward under control by the controller. The control is performed according to an instruction from the user. In other words, the pressure applied on the glass substrate 1 by the pressure parts 12A is determined according to an instruction from the user.
As illustrated in
As illustrated in
Furthermore,
Next, collecting electrodes 20A and 20B are disposed in predetermined positions on the solar cell ST1 (along the sides L1 and L2 of the glass substrate 1) in the glass substrate 1 disposed on the table 11. Here, the collecting electrodes 20A and 20B are strip-shaped conductors, and conductors containing copper, aluminum, or copper and aluminum can be used as the collecting electrodes 20A and 20B.
As illustrated in
Thus, one of the pressure parts 12A that is an L-shaped rod presses the glass substrate 1 along the first side L1 (specifically, along the length of the first side L1), in a first region of the glass substrate 1 between the first side L1 and an arrangement position of the collecting electrode 20A. Furthermore, the other of the pressure parts 12A that is also an L-shaped rod presses the glass substrate 1 along the second side L2 (specifically, along the length of the second side L2), in a second region of the glass substrate 1 between the second side L2 and an arrangement position of the collecting electrode 20B. The width of each of the first region and the second region (specifically, each distance from the first side L1 to an arrangement position of the collecting electrode 20A and from the second side L2 to an arrangement position of the collecting electrode 20B) is, for example, approximately several millimeters.
After the glass substrate 1 is fixed by the substrate fixing parts 12, the collecting electrodes 20A and 20B are disposed on the glass substrate 1 herein. However, the collecting electrodes 20A and 20B may be disposed on the glass substrate 1 after the glass substrate 1 is mounted on the table 11, and then the glass substrate 1 may be fixed by the substrate fixing parts 12.
After the collecting electrodes 20A and 20B are disposed on the solar-cell laminated film ST1, the ultrasonic vibration bonding is performed in places on the top surfaces of the collecting electrodes 20A and 20B. Specifically, the ultrasonic vibration bonding to be described hereinafter is performed on the collecting electrodes 20A and 20B when the glass substrate 1 is fixed on the table 11 by the substrate fixing parts 12.
With reference to
The controller determines conditions of the ultrasonic vibration bonding based on an input operation of the user, and controls the ultrasonic vibration tool 14 under the determined conditions. What is selected herein is the conditions of the ultrasonic vibration bonding under which the peel strengths (bonding strengths) of the collecting electrodes 20A and 20B have been reduced, that is, the conditions under which the collecting electrodes 20A and 20B can be bonded onto the glass substrate 1 without damaging the solar cell ST1 located below the collecting electrodes 20A and 20B (the collecting electrodes 20A and 20B can be electrically bonded onto the electrode layer without damaging the power generation layer).
The ultrasonic vibration bonding allows the collecting electrodes 20A and 20B to be directly electrically connected (bonded) to the solar cell ST1. The electrical bonding of the collecting electrodes 20A and 20B onto the solar cell ST1 allows the collecting electrodes 20A and 20B to function as bus bar electrodes that are collecting electrodes that conduct the electricity generated by the solar cell ST1. For example, the collecting electrode 20A that is one of the collecting electrodes 20A and 20B functions as a cathode, and the collecting electrode 20B that is the other of the collecting electrodes 20A and 20B functions as an anode.
As described above, the electrode bonding apparatus 100 (electrode bonding method) according to the embodiment performs the following bonding on the collecting electrodes 20A and 20B disposed along the sides L1 and L2 on the glass substrate 1, respectively, on the solar cell ST 1. In other words, the glass substrate 1 is pressed along the side L1 in a region of the glass substrate 1 between the side L1 and an arrangement position of the collecting electrode 20A, and along the side L2 in a region of the glass substrate 1 between the side L2 and an arrangement position of the collecting electrode 20B. During application of the pressure, the ultrasonic vibration bonding is performed on the collecting electrodes 20A and 20B to bond the collecting electrodes 20A and 20B onto the glass substrate 1.
Thus, even when the collecting electrodes 20A and 20B are bonded onto the glass substrate 1 at a lower peel strength (bonding strength), variations in the peel strength among points can be reduced.
The Inventors performed the ultrasonic vibration bonding on the collecting electrodes 20A and 20B by pressing and fixing the sides L1 and L2 using the substrate fixing parts 12 (a first case). Furthermore, the Inventors performed the ultrasonic vibration bonding on the collecting electrodes 20A and 20B without pressing and fixing the sides L1 and L2 using the substrate fixing parts 12 (a second case). In the first and second cases, the ultrasonic vibration bonding was performed in places on the strip-shaped collecting electrodes 20A and 20B several times, along a direction in which the collecting electrodes 20A and 20B extend. Furthermore, the conditions (pressure, the number of vibrations, and amplitude of the ultrasonic vibration tool 14) of the ultrasonic vibration bonding in the first case are the same as those in the second case.
In the first and second cases, the peel forces of the collecting electrodes 20A and 20B were measured in each point on which the ultrasonic vibration bonding has been performed.
As illustrated in
In contrast, as a result of the ultrasonic vibration bonding performed to have the weaker peel force in the second case, variations in the peel strength (bonding strength) among the processing points are wide. For example, even when the ultrasonic vibration bonding is performed by targeting the peel force of 200 g (target value), some of the processing points are not bonded or are subject to the peel force approximately five times as large as the target value. In other words, the collecting electrodes 20A and 20B in the second case commonly have the processing points that are not bonded and damage the solar cell ST1.
As illustrated in
Furthermore, the Inventors have found the following facts as a result of various experiments. Specifically, the collecting electrodes 20A and 20B are disposed along the sides L1 and L2 of the glass substrate 1, respectively. Then, the glass substrate 1 is pressed along the sides L1 and L2 in the vicinity of the sides L1 and L2 (specifically, in a region of the glass substrate 1 between the side L1 and an arrangement position of the collecting electrode 20A, and in a region of the glass substrate 1 between the side L2 and an arrangement position of the collecting electrode 20B) (see
For example, the collecting electrodes 20A and 20B are disposed along the sides L1 and L2 of the glass substrate 1, respectively. Then, the glass substrate 1 is pressed along the sides L1 and L2 in the vicinity of the sides L1 and L2 (specifically, in a region of the glass substrate 1 between the side L1 and an arrangement position of the collecting electrode 20A, and in a region of the glass substrate 1 between the side L2 and an arrangement position of the collecting electrode 20B) (see
Furthermore, the collecting electrodes 20A and 20B are disposed along the sides L1 and L2 of the glass substrate 1, respectively. Then, the glass substrate 1 is pressed along the sides L3 and L4 in the vicinity of the sides L3 and L4. During application of the pressure (specifically, while the sides L3 to L4 are pressed), the ultrasonic vibration bonding is performed on the collecting electrodes 20A and 20B. In this case, the Inventors have found that variations in the peel strength (bonding strength) among the points cannot be reduced as done in the first case, even when the collecting electrodes 20A and 20B are bonded onto the glass substrate 1 at a lower peel force. Furthermore, the collecting electrodes 20A and 20B are disposed along the sides L1 and L2 of the glass substrate 1, respectively. Then, the glass substrate 1 is pressed in places in the vicinity of the sides L1 and L2 (specifically, in a region of the glass substrate 1 between the side L1 and an arrangement position of the collecting electrode 20A, and in a region of the glass substrate 1 between the side L2 and an arrangement position of the collecting electrode 20B). During application of the pressure (specifically, while each point in the vicinity of the sides L1 and L2 is pressed), the ultrasonic vibration bonding is performed on the collecting electrodes 20A and 20B. In this case, the Inventors have found that variations in the peel strength (bonding strength) among the points are wide even when the collecting electrodes 20A and 20B are bonded onto the glass substrate 1 at a lower peel force.
Furthermore, the pressure parts 12A are L-shaped in the cross-sectional view. Furthermore, the substrate fixing parts 12 (pressure parts 12A) can also horizontally move with the drivers 12B. Thus, the glass substrate 1 can be positioned on the table 11 using the pressure parts 12A.
Furthermore, the portions of the pressure parts 12A that abut on the solar cell ST1 are softer than the portions of the pressure parts 12A that abut on the side surfaces of the glass substrate 1. Thus, the pressure parts 12A can be softly pressed to the glass substrate 1, and such pressing can prevent the solar cell ST1 from being damaged. Furthermore, since the portions of the pressure parts 12A that abut on the side surfaces of the glass substrate 1 are not soft, the glass substrate 1 can be positioned with high precision.
The portions of the pressure parts 12A that press the glass substrate 1 may be round.
Furthermore, the controller variably controls the pressure applied by the pressure parts 12A and the conditions of the ultrasonic vibration bonding performed by the ultrasonic vibration tool 14. Thus, the pressure applied by the pressure parts 12A and the conditions of the ultrasonic vibration bonding performed by the ultrasonic vibration tool 14 can be freely changed according to, for example, the thickness and the material of each of the glass substrate 1 and the collecting electrodes 20A and 20B.
Although the present invention is described in detail above, the description does not limit the present invention but exemplifies the present invention in all aspects. It is therefore understood that numerous modifications and variations that have not yet been exemplified can be devised without departing from the scope of the invention.
1 glass substrate, L1 to L4 side, ST1 solar cell, 11 table, 12 substrate fixing part, 12A pressure part, 12B driver, 12C elastic part, 14 ultrasonic vibration tool, 20A and 20B collecting electrode, 25 indentation, 100 electrode bonding apparatus.
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/JP2013/079985 | 11/6/2013 | WO | 00 |