Claims
- 1. A method of making a (β-diketonate)InR2 compound, by the reaction: wherein each R may be same or different and is independently selected from C6-C10 aryl, C6-C10 fluoroaryl, C6-C10 perfluoroaryl, C1-C6 alkyl, C1-C6 fluoroalkyl, or C1-C6 perfluoroalkyl, with the proviso that R substituents in InR3 are not all methyl or all butyl;M is selected from Li, Na and K; and X is selected from F, Cl, Br, and I.
- 2. The method of claim 1, wherein the reaction comprises:
- 3. The method of claim 1, wherein each R may be same or different and is independently selected from C1-C6 alkyl, C1-C6 fluoroalkyl, or C1-C6 perfluoroalkyl.
- 4. The method of claim 1, wherein each R may be same or different and is independently selected from C1-C6 alkyl.
- 5. The method of claim 1, wherein each R may be same or different and is independently selected from C1-C6 fluoroalkyl.
- 6. The method of claim 1, wherein each R may be same or different and is independently selected from C1-C6 perfluoroalkyl.
- 7. The method of claim 1 wherein R is methyl and β-diketonate is 1,1,1,5,5,5-hexafluoroacetylacetonate.
- 8. A method of making a (β-diketonate)InR2 compound, by the reaction: wherein each R may be same of different and is independently selected from C6-C10 aryl, C6-C10 fluoroaryl, C6-C10 perfluoroaryl, C1-C6 alkyl, C1-C6 fluoroalkyl, or C1-C6 perfluoroalkyl;M is selected from Li, Na and K; and X is selected from F, Cl, Br, and I.
- 9. A method of making a (carboxylate)InR2 compound, by the reaction: wherein:each R may be same or different and is independently selected from C6-C10 aryl, C6-C10 fluoroaryl, C6-C10 perfluoroaryl, C1-C6 alkyl, C1-C6 fluoroalkyl, and C1-C6 perfluoroalkyl, with the proviso that R substituents in InR3 are not all methyl or all butyl; M is selected from Li, Na and K; and X is selected from F, Cl, Br, and I.
- 10. The method of claim 9, wherein each R may be same or different and is independently selected from C1-C6 alkyl, C1-C16 fluoroalkyl, or C1-C6 perfluoroalkyl.
- 11. The method of claim 9, wherein each R may be same or different and is independently selected from C1-C6 alkyl.
- 12. The method of claim 9, wherein each R may be same or different and is independently selected from C1-C6 fluoroalkyl.
- 13. The method of claim 9, wherein each R may be same or different and is independently selected from C1-C6 perfluoroalkyl.
Parent Case Info
This is a division of U.S. application Ser. No. 09/609,516, filed Jul. 3, 2000, which is a division of U.S. application Ser. No. 09/218,992, filed on Dec. 22, 1998 now U.S. Pat. No. 6,204,402.
GOVERNMENT RIGHTS IN INVENTION
The invention hereof was made with Government funding assistance under Contract No. DMI - 9660730 awarded by the National Science Foundation. The Government has certain rights in the invention.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
5840897 |
Kirlin et al. |
Nov 1998 |
A |
6126996 |
Kirlin et al. |
Oct 2000 |
A |
Non-Patent Literature Citations (3)
Entry |
Clark et al., J. Organomet. Chem., vol. 8, No. 3, pp. 427-434 (1967).* |
Chung, et al., Can. J. Chem., vol. 52, pp. 3944-3949. |
Nomura, et al., Polyhedron, vol. 6, No. 3, pp. 507-512. |