This patent application is being concurrently filed with commonly owned U.S. patent application entitled SHIELDING FOR INTEGRATED CAPACITORS by Patrick J. Quinn; and with commonly owned U.S. patent application entitled INTEGRATED CAPACITOR WITH INTERLINKED LATERAL FINS by Patrick J. Quinn; and with commonly owned U.S. patent application entitled INTEGRATED CAPACITOR WITH CABLED PLATES by Patrick J. Quinn; and with commonly owned U.S. patent application entitled INTEGRATED CAPACITOR WITH ARRAY OF CROSSES by Patrick J. Quinn; and with commonly owned U.S. patent application entitled INTEGRATED CAPACITOR WITH ALTERNATING LAYERED SEGMENTS by Jan L. de Jong et al., the disclosures of which are each hereby incorporated by reference in their entireties for all purposes.
The present invention relates to capacitors formed in integrated circuits (“ICs”) commonly referred to as “integrated capacitors”.
Methods of fabricating ICs typically include a front-end sequence of processing, in which various electrical devices such as transistors are formed in a semiconductor substrate, and a back-end sequence of processing, generally including forming alternating layers of dielectric material and patterned conductive material (typically metal) with conductive vias or other techniques being used to interconnect the metal layers to form a three-dimensional wiring structure that connects electrical devices to other electrical devices and to terminals of the IC.
Capacitors are used in IC systems for a variety of purposes. In many instances, it is desirable to incorporate (integrate) a capacitor in the IC chip. A simple approach is to form two conductive plates with an intervening dielectric; however, this consumes a relatively large area for the capacitance obtained. One technique for increasing the capacitance of a given area is to use multiple conductive plates, each conductive plate separated from the proximate plate(s) by dielectric. Further techniques use conducting strips, also called conductive lines, conductive fingers, or conductive traces that are alternately connected to the first and second capacitor terminals (nodes). Sidewall coupling between the conductive strips provides capacitance. Layers of conducting strips, either offset or arranged in vertical congruency, can be added to further increase the capacitance of an integrated capacitor structure.
One capacitor has a number of conductive strips in successive layers connected to the first node alternating with an equal number of conductive strips connected to the second node of the integrated capacitor. The conductive strips are offset a half cell on successive layers, so that a conductive strip connected to the first node has conductive strips connected to the second node above and on both sides of it. Providing an equal number of conductive strips in a layer for each node balances the coupling of each node to the substrate, which is desirable in some applications, but undesirable in others, such as switching applications where it is desirable to have less coupling at one node. In order to reduce coupling to the substrate, a thick layer of silicon dioxide is used between the substrate and the first layer of conductive strips. This may be difficult to integrate in a standard CMOS fabrication sequence, and might require additional steps to be added to the standard process flow. The overlapping parallel conductive strips are connected at their ends using buss strips that consume additional surface area.
Another approach to providing an integrated capacitor is to have conductive strips in a layer connected to alternate nodes of the capacitor with overlapping conductive strips connected to the same node. This forms essentially a curtain of conductive strips and interconnecting vias connected to the first node of the capacitor with adjacent curtains of conductive strips and interconnecting vias connected to the second node. Overlapping conductive strips connected to the same node avoids the lost surface area associated with buss strips; however, inter-layer capacitance is reduced because the upper strip is connected to the same node as the lower strip. This effect is somewhat obviated because, as critical dimensions shrink, inter-strip capacitance becomes more dominant than inter-layer capacitance. In other words, the dielectric layer separation between successive metal layers becomes increasingly greater than the dielectric separation between conductive strips with decreasing critical dimension.
Thus, integrated capacitors overcoming the disadvantages of prior art are desired. It is further generally desired that integrated capacitors have high capacitance per unit area, low loss (resistance), and low self-inductance, which improves high-frequency applications by increasing self-resonant frequency and the quality of capacitor circuits. In some applications, it is further desirable to shield integrated capacitors from electrical noise.
A capacitor in an IC has a first layer of conductive strips extending along a first direction. A first plurality of conductive strips in the first layer forms a first portion of a first node of the capacitor and alternates with a second plurality of conductive strips forming a first portion of a second node of the capacitor. A plate layer adjacent to the first layer has a third plurality of conductive strips forming a second portion of the first node. The strips in the plate layer extend along a second direction orthogonal to the first direction. A first via electrically connects a first conductive strip in the first plurality of conductive strips in the first layer to a second conductive strip in the plate layer.
Accompanying drawing(s) show exemplary embodiment(s) in accordance with one or more aspects of the invention; however, the accompanying drawing(s) should not be taken to limit the invention to the embodiment(s) shown, but are for explanation and understanding only.
The feedback capacitor 102 has a top node 110 shielded by an optional bottom node shield 122, and by an optional reference shield 124. The reference shield 124 is connected to a relatively stable reference voltage present in the IC, such as analog ground, digital ground, or VDD. The reference shield 124 essentially surrounds the bottom node shield 120 and shields the bottom node from substantially coupling to more than one voltage reference (e.g., the bottom node couples to VDD or ground, but not both). In other embodiments, a reference shield partially surrounds a bottom node shield. The reference shield has a gap allowing electrical contact to be made to the bottom node, as described above.
The terms “top” node and “bottom” node do not necessarily relate to the physical orientation of the nodes relative to the IC or other structure, but are used as terms of convenience. In some circuit applications, the top node of a capacitor indicates the node that is connected to a high-impedance or high-gain port of an amplifier or other device. In a system-on-chip (“SoC”), the accuracy on an analog-to-digital converter (“ADC”) is dependent on the ratio of the parasitic capacitance at the top node (Ctop) to all other nodes except the bottom node and the capacitance (Csig) that is the useful floating signal capacitance between both nodes. It is desirable to shield the top plate from ground currents or voltage supply fluctuations so that Ctop remains low. Using the bottom node to essentially surround the top node isolates the top node from coupling with other nodes in the circuit by essentially forming a portion of Faraday shell around the top node, and in some embodiments, distancing the top node from other conductive elements in the IC. It is understood by those of skill in the art that electrical connection to the top node is made through the bottom node shield, and therefore the bottom node shield does not completely surround the top node.
In some embodiments, some sides of the top node are left unshielded. For example, an end of the top node that is physically distant from other nodes might be left unshielded. In other embodiments, integrated capacitors are used as design cells, and adjacent integrated capacitors are connected in parallel to obtain a higher total capacitance. In some embodiments, the portions of the bottom node shield of adjacent commonly-connected integrated capacitors are omitted, allowing higher packing density. In yet other applications, such as high-frequency analog circuits in MGTs (multi-gigabit transceivers) of an FPGA (field programmable gate array), a node shield is omitted to maintain balance between the plates of the capacitor. Capacitors are generally useful in a wide variety of integrated circuits and in a wide variety of applications. For instance, one or more capacitors may be useful for a switched capacitor network, such as in an analog-to-digital converter, or as a decoupling or filtering capacitor for AC signaling (e.g., in an MGT). In general, the capacitor structure described herein may be useful in any application requiring capacitance.
Complex ICs, such as programmable logic devices, often have several patterned metal layers separated by layers of dielectric material formed over a semiconductor substrate that are used for wiring connections and other functions commonly called the “backend” of the IC. Some embodiments of the invention are adaptable to existing CMOS process sequences by using masks that form the desired patterns in the appropriate metal layers and vias through the inter-metal dielectric (“IMD”) layers or inter-layer dielectric (“ILD”) in the backend of the IC. The vias are formed using any of several known techniques, such as contact plug, damascene, or dual damascene techniques. Similarly, the conductive strips are formed using any of several known techniques, such as thin-film metal etch, thin-film metal lift-off, damascene, and dual damascene techniques. In some embodiments, one of the conductive layers is a polysilicon or silicide layer. In a further embodiment, a conductive well in the semiconductor substrate forms a portion of a capacitor plate or a shield.
A plate layer is a layer in which the strips in a layer are adjacent to each other and connected to a node to essentially form a conductive plate or a layer of polysilicon or silicide. The bottom node in this embodiment is the capacitor node that is less susceptible to electronic noise than the top node when the capacitor is used in a particular circuit application. A top plate conductive matrix 212 is overlain by the first bottom plate layer B and underlain by the second bottom plate layer B′, which forms a partial Faraday shield around the core capacitor formed by the top plate layer T and the transverse interleaved layers above and below the top plate layer T. The strips in the top plate layer T are connected to the top node and are adjacent (at least on one side) to a strip also connected to the top node. The optional bottom plate shield reduces noise coupled to the top plate conductive matrix and increases specific capacitance of the integrated capacitor by capacitively coupling to the top plate conductive matrix.
The first bottom plate layer is made up of strips, rather than a continuous sheet, because of design layout rules familiar to those of skill in the art of IC fabrication, and forms a pattern reminiscent of a tartan plaid fabric with the other metal layers. Generally, each metal layer has minimum and maximum metal line widths and minimum separations. Polysilicon and silicide layers typically have different design and process rules than patterned metal layers, which allows forming the bottom plate layer as a contiguous sheet of poly when the poly layer is used. Similarly, large conductive areas can be formed in the semiconductor substrate (e.g., an N-well or a P-well) to form a continuous conductive sheet. In an alternative embodiment, the second bottom plate layer is formed in a conductive well of the substrate. The conductive well is separated from the poly layer by a relatively thin dielectric layer, providing good electrical performance even though the N-well is generally less conductive than a metal layer or poly layer. Using a conductive well to form part of a shield is further desirable because a moat can be formed around the portion of the substrate in which the N-well or P-well is formed, which electrically isolates that portion of the substrate from stray currents in other portions of the substrate and provides a low-noise element. Use of a conductive well in a shield is also desirable because the well is surrounded in a fairly symmetrical fashion by metal, leading to symmetrical current flow through the well portion of the shield.
The conductive strips 204, 206 in the upper bottom plate layer B are electrically connected through vias (not shown, see, e.g., via 214) to transverse (i.e., generally orthogonal) conductive strips (e.g., B4) in the lower layer so that interconnection between conductive strips 204, 206 in the metal layer of the first bottom plate layer B is not necessary. Alternatively, conductive cross members (cross-connects between strips in the metal layer) are optionally included in the first bottom plate layer to connect conductive strips in the layer, which improves shielding.
Similarly, a top plate layer T is made up of a plurality of conductive strips 216, 218 connected to the top node of the integrated capacitor. The conductive strips in the top plate layer T are transverse to conductive strips T1, T2, T3, T4, T5 above the top plate layer T and transverse to conductive strips T6, T7, T8, T9, T10 below the top plate layer, and conductive strips in the top plate layer T are electrically connected to each other through vias and transverse conductive strips above and below the top plate layer T. In other words, the conductive strips in the top plate layer T extend along the X-direction and the conductive strips in the interleaved layers above and below the top plate layer T extend along the Z-direction.
In some embodiments, the conductive strips (e.g. T1, B1) are made from a minimum-width metal line and are commonly referred to as “conductive filaments” or “metal filaments” and provide high line densities and high lateral capacitance. Lateral capacitance between conductive strips in the plate layers does not contribute to the specific capacitance of the integrated capacitor because the metal strips are connected to the same node, and conductive strips in the plate layers are often wider than minimum metal line width.
The plate layers B, T, B′ do not have alternating conductive strips, but rather all the conductive strips in these layers are connected to either the top node or the bottom node of the integrated capacitor. The configuration of a capacitor according to
Integrated capacitors according to alternative embodiments include additional metal layers. The integrated capacitor includes an optional reference shield, which in this embodiment is a reference shield connected to VDD. The reference shield includes a shield plate 224 made up of a conductive well (Nwell), formed in the semiconductor substrate 226 of the IC, a top shield plate 225 formed in the M5 metal layer, and conductive curtains 240, 242.
A polishing step often follows deposition and patterning of a metal layer to provide a flat, smooth surface for forming and patterning the next metal layer. Stacking several layers of conductive strips directly over each other might result in an undulating surface in the upper layers due to the cumulative effects of having multiple layers of metal strips directly over several other layers of metal strips. The intervening top plate layer T, with strips transverse to the strips in the metal layers directly above and below the plate layer, mitigates the effects of having the conductive strips in the M3 layer directly over the conductive strips in the M1 layer, for example.
The shield capacitor portion 203 forms a conductive sheath around the core capacitor portion 201, which has interleaved top and bottom node conductive filaments that provide high specific capacitance in the M1 and M3 metal layers. The shield capacitor portion adds additional capacitance by coupling to the top node conductive elements. In a typical embodiment, each layer of interleaved filaments will have hundreds of filaments and the lateral coupling between the filaments is a significant portion of the total capacitance of the integrated capacitor.
The second bottom plate layer B′ is formed in the poly layer of the IC. In an alternative embodiment, the second bottom plate layer is formed as strips in a metal layer, such as M1 or M2, in a backend stack that has additional metal layers. Utilizing the poly layer for the second bottom plate layer allows a shielded integrated capacitor (without the optional VDD shield) to be formed in a four-metal-layer IC. In an alternative embodiment, a conductive well formed in the semiconductor substrate is used as the second bottom plate layer, allowing an embodiment to be fabricated in three metal layers of an IC, or allowing additional metal layers for increasing the specific capacitance of a capacitor of a given area. The dielectric layer above the substrate and poly layer (not separately shown) is commonly called an inter-layer dielectric (“ILD”), and the conductive element 228 connecting the poly layer to the N+ conductive area 230 of the substrate is commonly called a contact, as opposed to a via. A gate dielectric layer (not separately shown) between the poly and the N-well is typically much thinner than the ILD layer.
The optional reference shield includes a first shield layer 225 and the shield plate 224 formed in the N-well that are connected through a series of vias, metal, poly, and contacts. The vias, metal, poly, and contacts form a first shield curtain and a second shield curtain that are basically the right and left vertical portions of the reference shield. In a further embodiment, third and fourth conductive curtains of the bottom plate conductive matrix enclose the as-viewed front and back planes of the bottom node shield and core capacitor. These features are not shown for purposes of clarity of illustration, as they would be understood by one of ordinary skill in the art in light of the conductive and shield curtains illustrated in side view.
The reference shield is connected to a stable voltage reference, such as VDD or ground, to reduce coupling of the bottom node to more than one voltage node. For example, the bottom node matrix couples essentially only to the top node and to VDD. Negligible coupling of the other nodes of the IC to the bottom node occurs. Similarly, if the shield were connected to ground instead of VDD, the bottom node would only couple to the top node and ground.
It is generally undesirable for the bottom node to couple to VDD and ground simultaneously because the bottom node would then act as a bridge between ground and VDD, and could couple undesirable switching currents between the two nodes, for example. However, in some embodiments, limited coupling to both VDD and ground is acceptable, particularly if coupling of the bottom node shield to a reference shield is limited to conductive elements connected to an isolated portion of the substrate, or if the ground node is an analog ground node that is reasonably well isolated from a digital ground node.
A gap or similar feature (not shown, see
A first bottom plate layer B is connected to a second bottom plate layer B′ through conductive curtains 302, 304. A top plate layer T is connected to conductive strips T1, T5 through vias 306, 308. Conductive strips T1, T2, T3, T4 connected to the top node of the integrated capacitor are interleaved with conductive strips B1, B2, B3, B4 connected to the bottom node of the integrated capacitor to form a first interleaved layer between the first bottom plate layer B and the top plate layer T. Conductive strips T5, T6, T7, T8, T9 are connected to the top node of the integrated capacitor and are interleaved with conductive strips B5, B6, B7, B8 connected to the bottom node of the integrated capacitor to form a second interleaved layer between the top plate layer T and the second bottom plate layer B′. Dielectric material between the conductive elements is present but not separately shown for clarity of illustration of the conductive matrices of the integrated capacitor.
Conductive curtain 302 has conductive strips B12, B13, B14 extending along the direction orthogonal to the plane of the sheet of illustration interconnected with vias 310, 312, 314 to the second bottom plate B′.
Note that the types of and number of layers described are merely examples, and in some embodiments other suitable layers may be used, and any number of layers may be used. For example, the layers used may depend on the types and numbers of layers that are available in the manufacturing process, and other arrangements will be apparent to those of skill in the art. In general, any suitable layer, and an arbitrary number of layers may be used in accordance with embodiments of the present invention.
The FPGA architecture includes a large number of different programmable tiles including multi-gigabit transceivers (MGTs 501), configurable logic blocks (CLBs 502), random access memory blocks (BRAMs 503), input/output blocks (IOBs 504), configuration and clocking logic (CONFIG/CLOCKS 505), digital signal processing blocks (DSPs 506), specialized input/output blocks (I/O 507) (e.g., configuration ports and clock ports), and other programmable logic 508 such as digital clock managers, analog-to-digital converters, system monitoring logic, and so forth. Some FPGAs also include dedicated processor blocks (PROC 510).
In some FPGAs, each programmable tile includes a programmable interconnect element (INT 511) having standardized connections to and from a corresponding interconnect element in each adjacent tile. Therefore, the programmable interconnect elements taken together implement the programmable interconnect structure for the illustrated FPGA. The programmable interconnect element (INT 511) also includes the connections to and from the programmable logic element within the same tile, as shown by the examples included at the top of
For example, a CLB 502 can include a configurable logic element (CLE 512) that can be programmed to implement user logic plus a single programmable interconnect element (INT 511). A BRAM 503 can include a BRAM logic element (BRL 513) in addition to one or more programmable interconnect elements. Typically, the number of interconnect elements included in a tile depends on the height of the tile. In the pictured embodiment, a BRAM tile has the same height as four CLBs, but other numbers (e.g., five) can also be used. A DSP tile 506 can include a DSP logic element (DSPL 514) in addition to an appropriate number of programmable interconnect elements. An 10B 504 can include, for example, two instances of an input/output logic element (IOL 515) in addition to one instance of the programmable interconnect element (INT 511). As will be clear to those of skill in the art, the actual I/O pads connected, for example, to the I/O logic element 515 are manufactured using metal layered above the various illustrated logic blocks, and typically are not confined to the area of the input/output logic element 515. In the pictured embodiment, a columnar area near the center of the die (shown shaded in
Some FPGAs utilizing the architecture illustrated in
Note that
While the foregoing describes exemplary embodiment(s) in accordance with one or more aspects of the present invention, other and further embodiment(s) in accordance with the one or more aspects of the present invention may be devised without departing from the scope thereof, which is determined by the claim(s) that follow and equivalents thereof. Claim(s) listing steps do not imply any order of the steps. Trademarks are the property of their respective owners.
Number | Name | Date | Kind |
---|---|---|---|
1899176 | Bailey | Feb 1933 | A |
3593319 | Barber | Jul 1971 | A |
4156249 | Koo | May 1979 | A |
4249196 | Durney et al. | Feb 1981 | A |
4409608 | Yoder | Oct 1983 | A |
4427457 | Carlson et al. | Jan 1984 | A |
4470096 | Guertin | Sep 1984 | A |
4470099 | Sawairi | Sep 1984 | A |
4571543 | Raymond et al. | Feb 1986 | A |
4639686 | Beckenbach et al. | Jan 1987 | A |
4700457 | Matsukawa | Oct 1987 | A |
4731696 | Himes et al. | Mar 1988 | A |
4827323 | Tigelaar et al. | May 1989 | A |
4831431 | Hanlon | May 1989 | A |
4878151 | Gallichio | Oct 1989 | A |
4914546 | Alter | Apr 1990 | A |
4937649 | Shiba et al. | Jun 1990 | A |
4994688 | Horiguchi et al. | Feb 1991 | A |
5005103 | Kwon et al. | Apr 1991 | A |
5021920 | Smith | Jun 1991 | A |
5077225 | Lee | Dec 1991 | A |
5083184 | Eguchi | Jan 1992 | A |
5089878 | Lee | Feb 1992 | A |
5117114 | Street et al. | May 1992 | A |
5119169 | Kozono et al. | Jun 1992 | A |
5142639 | Kohyama et al. | Aug 1992 | A |
5155658 | Inam et al. | Oct 1992 | A |
5166858 | Frake et al. | Nov 1992 | A |
5172299 | Yamada et al. | Dec 1992 | A |
5177410 | Hashiguchi et al. | Jan 1993 | A |
5189594 | Hoshiba | Feb 1993 | A |
5208725 | Akcasu | May 1993 | A |
5275974 | Ellul et al. | Jan 1994 | A |
5583359 | Ng et al. | Dec 1996 | A |
5712813 | Zhang | Jan 1998 | A |
5868388 | Wood et al. | Feb 1999 | A |
5939766 | Stolmeijer et al. | Aug 1999 | A |
6037621 | Wilson | Mar 2000 | A |
6064108 | Martinez | May 2000 | A |
6066537 | Poh | May 2000 | A |
6297524 | Vathulya et al. | Oct 2001 | B1 |
6303456 | Pricer et al. | Oct 2001 | B1 |
6303457 | Christensen et al. | Oct 2001 | B1 |
6383858 | Gupta et al. | May 2002 | B1 |
6385033 | Javanifard et al. | May 2002 | B1 |
6410954 | Sowlati et al. | Jun 2002 | B1 |
6417556 | Long et al. | Jul 2002 | B1 |
6542351 | Kwang | Apr 2003 | B1 |
6570210 | Sowlati et al. | May 2003 | B1 |
6597562 | Hu et al. | Jul 2003 | B1 |
6625006 | Aram et al. | Sep 2003 | B1 |
6653681 | Appel | Nov 2003 | B2 |
6661079 | Bikulcius | Dec 2003 | B1 |
6690570 | Hajimiri et al. | Feb 2004 | B2 |
6737698 | Paul et al. | May 2004 | B1 |
6747307 | Vathulya et al. | Jun 2004 | B1 |
6765778 | Du et al. | Jul 2004 | B1 |
6819542 | Tsai et al. | Nov 2004 | B2 |
6822312 | Sowlati et al. | Nov 2004 | B2 |
6880134 | Drennan | Apr 2005 | B2 |
6882015 | Bernstein et al. | Apr 2005 | B2 |
6897505 | Aton | May 2005 | B2 |
6903918 | Brennan | Jun 2005 | B1 |
6927125 | Jones et al. | Aug 2005 | B2 |
6933551 | Stribley et al. | Aug 2005 | B1 |
6949781 | Chang et al. | Sep 2005 | B2 |
6963122 | Soenen et al. | Nov 2005 | B1 |
6974744 | Aram et al. | Dec 2005 | B1 |
7009832 | Chen et al. | Mar 2006 | B1 |
7013436 | Morton et al. | Mar 2006 | B1 |
7027287 | Georgakos | Apr 2006 | B2 |
7038296 | Laws | May 2006 | B2 |
7050290 | Tang et al. | May 2006 | B2 |
7116544 | Sutardja | Oct 2006 | B1 |
7154734 | Schultz et al. | Dec 2006 | B2 |
7161228 | Pettit | Jan 2007 | B1 |
7170178 | Bely et al. | Jan 2007 | B2 |
7193263 | Barth | Mar 2007 | B2 |
7195971 | Bernstein et al. | Mar 2007 | B2 |
7202548 | Lee | Apr 2007 | B2 |
7259945 | Cleveland | Aug 2007 | B2 |
7259956 | Fong et al. | Aug 2007 | B2 |
7274085 | Hsu et al. | Sep 2007 | B1 |
7298001 | Liu | Nov 2007 | B1 |
7439570 | Anthony | Oct 2008 | B2 |
7485914 | Huang et al. | Feb 2009 | B2 |
7564675 | Chen et al. | Jul 2009 | B2 |
7663233 | Lim | Feb 2010 | B2 |
7768054 | Benetik | Aug 2010 | B2 |
20030202331 | Jessie et al. | Oct 2003 | A1 |
20050077581 | Chang et al. | Apr 2005 | A1 |
20050135042 | Chiu-Kit Fong et al. | Jun 2005 | A1 |
20050161725 | Da Dalt | Jul 2005 | A1 |
20060086965 | Sakaguchi et al. | Apr 2006 | A1 |
20060203424 | Chen et al. | Sep 2006 | A1 |
20070181973 | Hung et al. | Aug 2007 | A1 |
20070190760 | Coolbaugh et al. | Aug 2007 | A1 |
20070278551 | Anthony | Dec 2007 | A1 |
20070296013 | Chang et al. | Dec 2007 | A1 |
20090057826 | Kim et al. | Mar 2009 | A1 |
Number | Date | Country |
---|---|---|
25 48 563 | May 1977 | DE |
100 46 910 | Oct 2001 | DE |
1 149 569 | Apr 1969 | GB |
1 469 944 | Apr 1977 | GB |
57-106804 | Jul 1982 | JP |
58-051552 | Mar 1983 | JP |
59-91718 | Jun 1984 | JP |
61-259560 | Nov 1986 | JP |
61-263251 | Nov 1986 | JP |
63-070550 | Mar 1988 | JP |
01084616 | Mar 1989 | JP |
01096943 | Apr 1989 | JP |
01-313917 | Dec 1989 | JP |
02231755 | Sep 1990 | JP |
02-268439 | Nov 1990 | JP |
02-307275 | Dec 1990 | JP |
03-008360 | Jan 1991 | JP |
03-071612 | Mar 1991 | JP |
04-268756 | Sep 1992 | JP |
07-283076 | Oct 1995 | JP |
WO 03090280 | Oct 2003 | WO |