The present invention relates to an interconnect structure which realizes highly reliable interconnect, and a method for fabricating the same.
A maximum current density at a contact hole of an LSI multilevel interconnect structure is significantly increasing with scaling down in design rules. Therefore, it is conceivable that copper interconnects conventionally used in multilevel interconnect structures cannot achieve required long-life reliability (see, e.g., IEICE TRANS. ELECTRON., Vol. E89-C, No. 11, p. 1499 (2006)). According to ITRS (International Technology Roadmap for Semiconductors), the maximum current density is expected to exceed the order of 1×107 A/cm2 in a generation of structures where a half pitch (hp) as a design rule index is 22 nm (commercial node: 16 nm). Since a maximum sustainable current density of Cu is on the order of 1×106 A/cm2, the copper interconnects used in the multilevel interconnect structures are approaching their limits.
In this respect, replacement of copper used at the contact hole of the multilevel interconnect structure with carbon nanotube has been proposed (see, e.g., Proc. IEEE 2004 International Interconnect Technology Conference). The carbon nanotube is known as a material which endures a current density on the order of 1×109 A/cm2 and allows ballistic transport. Therefore, intensive researches have been made on the carbon nanotube as a candidate for next-generation interconnect materials. The carbon nanotube, which is formed by thermal CVD or plasma CVD using a Co catalyst, is expected to achieve low resistance, high reliability interconnects comparable to or superior to the copper interconnects.
However, forming carbon nanotubes in a nanometer order size contact hole at a sufficiently high density, such as on the order of 1012 nanotubes/cm2, is quite difficult. At present, it is confirmed that the carbon nanotubes can be formed at a density on the order of 1011 nanotubes/cm2 in the minute contact hole, and that they have a resistance value nearly equal to that of tungsten (see, e.g., IEICE TRANS. ELECTRON., Vol. E89-C, No. 11, p. 1499 (2006)). When only the carbon nanotubes are formed in the contact hole according to a conventional method, a resistance value at the contact hole becomes higher than that when copper is filled in the contact hole. Therefore, power consumption of the LSI may increase. To cope with this problem, there is another proposal to form the carbon nanotubes and metal such as copper together in the contact hole (see, e.g., Published Japanese Patent Application No. 2005-109465). However, when the carbon nanotubes and copper are formed together in the contact hole, a problem of increase in contact resistance arises (see, e.g., MSC2006 Research Conference Proceeding D3).
In view of the foregoing, a goal of the present invention is to provide an interconnect structure which realizes highly reliable interconnect, and a method for fabricating the same.
To reach the above-described goal, the present invention discloses, in one aspect thereof, an interconnect structure including: an interlayer insulating film formed on a lower metal layer; a contact hole formed in the interlayer insulating film to expose the lower metal layer; a plurality of carbon nanotubes formed on a bottom of the contact hole; an wiring metal filled in the contact hole to fill gap between the plurality of carbon nanotubes; and an upper wiring formed above the contact hole, wherein an upper metal layer made of a Ti layer at the bottom of Cu wiring is formed between the plurality of carbon nanotubes and the upper wiring.
The present invention discloses, in one aspect thereof, an interconnect structure further including: a lower metal layer which is made of a Ti layer on Cu wiring and formed on at least the bottom of the contact hole to present between the lower metal layer and bottom ends of the plurality of carbon nanotubes.
The present invention discloses, in one aspect thereof, an interconnect structure, wherein the upper metal layer is formed on at least top ends of the plurality of carbon nanotubes.
The present invention discloses, in one aspect thereof, an interconnect structure, wherein the upper metal layer is connected to at least the top ends of the plurality of carbon nanotubes and covers a bottom surface of the upper wiring.
The present invention discloses, in one aspect thereof, an interconnect structure including: an interlayer insulating film formed on a lower metal layer; a contact hole formed in the interlayer insulating film to expose the lower metal layer; a lower metal layer made of a Ti layer on Cu wiring and formed on at least a bottom of the contact hole; a plurality of carbon nanotubes formed on the lower metal layer on the bottom of the contact hole; and an wiring metal filled in the contact hole to fill gap between the plurality of carbon nanotubes.
The present invention discloses, in one aspect thereof, an interconnect structure, wherein the carbon nanotubes have a multiwall structure.
The present invention discloses, in one aspect thereof, an interconnect structure, wherein the wiring metal is copper.
The present invention discloses, in one aspect thereof, a method for fabricating an interconnect structure including: (a) forming an interlayer insulating film on a lower metal layer; (b) forming a contact hole in the interlayer insulating film to expose the lower metal layer; (c) forming a plurality of carbon nanotubes on a bottom of the contact hole, and filling with a wiring metal in the contact hole to fill gap between the plurality of carbon nanotubes; and (d) forming an upper wiring above the contact hole after the formation (c); wherein an upper metal layer made of a Ti layer at the bottom of Cu wiring is formed between the plurality of carbon nanotubes and the upper wiring.
The present invention discloses, in one aspect thereof, a method for fabricating an interconnect structure further including: (e) forming a lower metal layer made of a Ti layer on Cu wiring on at least the bottom of the contact hole between the forming the contact hole and the forming the plurality of carbon nanotubes and filling with the wiring metal.
The present invention discloses, in one aspect thereof, a method for fabricating an interconnect structure, wherein the forming the plurality of carbon nanotubes and filling with the wiring metal includes: forming the plurality of carbon nanotubes so that top ends thereof do not protrude from the contact hole; forming the upper metal layer on at least top ends of the plurality of carbon nanotubes; and then filling with the wiring metal.
The present invention discloses, in one aspect thereof, a method for fabricating an interconnect structure, wherein the forming the plurality of carbon nanotubes and filling with the wiring metal includes: forming the plurality of carbon nanotubes so that top ends thereof protrude from the contact hole; and then filling with the wiring metal; and the method further includes: (f) removing part of the top ends of the plurality of carbon nanotubes protruding from the contact hole to planarize a top of the contact hole between the forming the plurality of carbon nanotubes and filling with the wiring metal and the forming the upper wiring; and (g) forming the upper metal layer on the contact hole to be connected to the plurality of carbon nanotubes after the removing the part of the top ends of the plurality of carbon nanotubes and the forming the upper wiring.
The present invention discloses, in one aspect thereof, a method for fabricating an interconnect structure including: (a) forming an interlayer insulating film on a lower metal layer; (b) forming a contact hole in the interlayer insulating film to expose the lower metal layer; (c) forming a lower metal layer made of a Ti layer on Cu wiring on at least a bottom of the contact hole; and (d) forming a plurality of carbon nanotubes on the lower metal layer on the bottom of the contact hole, and then filling with an wiring metal in the contact hole to fill gap between the plurality of carbon nanotubes.
The present invention discloses, in one aspect thereof, a method for fabricating an interconnect structure, wherein the carbon nanotubes have a multiwall structure.
The present invention discloses, in one aspect thereof, a method for fabricating an interconnect structure, wherein the wiring metal is copper.
In an interconnect structure including a lower metal layer and an upper wiring connected through a structure constituted of carbon nanotubes and a copper film formed in a contact hole, the Ti layer can be formed between the carbon nanotubes and the upper wiring according to the interconnect structure of the present invention and the method for fabricating the same. Therefore, increase in contact resistance to the upper wiring can be suppressed. Further, since the Ti layer is formed between the carbon nanotubes and the lower metal layer, increase in contact resistance to the lower metal layer can be suppressed.
As described above, the present invention is useful for fabricating high reliability, low resistance metal interconnects.
Hereinafter, an interconnect structure according to Embodiment 1 of the present invention and a method for fabricating the same will be described with reference to the accompanying drawings.
First, as shown in
Then, as shown in
Then, as shown in
Then, as shown in
Then, as shown in
Then, as shown in
Then, as shown in
Then, as shown in
Then, as shown in
Then, as shown in
As described above, in the interconnect structure including the lower metal layer and the upper wiring connected through a structure constituted of the carbon nanotubes 8 and the copper film 11 formed in the contact hole 5, the Ti layer 9 can be formed on the top ends of the carbon nanotubes 8 according to the interconnect structure and the fabrication method of the present embodiment. Therefore, increase in contact resistance to the upper wiring can be suppressed. Further, since the Ti layer 6b is connected to the bottom ends of the carbon nanotubes 8, increase in contact resistance to the lower metal layer can be suppressed.
Since the carbon nanotubes 8 and the copper film 11 coexist in the contact hole 5, reduction in resistance and improvement in reliability of the contact hole 5 can be both achieved even when the carbon nanotubes 8 are formed at a low density. Specifically, the resistance of the contact hole 5 is parallel resistance constituted of resistance of the copper film and resistance of the carbon nanotubes 8, and the carbon nanotubes 8 allow ballistic transport. Therefore, the coexistence of the copper film and the carbon nanotubes 8 in the contact hole 5 allows further reduction in resistance of the contact hole 5 as compared with the case where only the copper film is formed in the contact hole 5. Moreover, the carbon nanotubes 8 present in the contact hole 5 remain in the contact hole 5 even when copper migration occurs. Therefore, breaking of metal wire at the contact hole 5 can significantly be suppressed.
In the above-described embodiment, Co is used as a catalyst metal for forming the carbon nanotubes. However, other metals such as Ni and Fe can also be used. Further, copper used as the interconnect material may be replaced with aluminum, silver, or gold.
In the interconnect structure of the above-described embodiment, the barrier metal film 6b made of the Ti layer is formed below the carbon nanotubes 8, and the Ti layer 9 is formed on the top ends of the carbon nanotubes 8. However, from a viewpoint of suppressing the increase in contact resistance at the contact hole 5, it is needless to say that the Ti layer is formed on at least one of the top ends and the bottom ends of the carbon nanotubes 8.
Hereinafter, an interconnect structure according to Embodiment 2 of the present invention and a method for fabricating the same will be described with reference to the accompanying drawings.
First, as shown in
Then, as shown in
Then, as shown in
Then, as shown in
Then, as shown in
Then, a copper film 11 is deposited by electroplating to fill the contact hole 5 as shown in
Then, as shown in
Then, as shown in
Then, as shown in
Then, as shown in
As described above, in the interconnect structure including the lower metal layer and the upper wiring connected through a structure constituted of the carbon nanotubes 8 and the copper film 11 formed in the contact hole 5, the barrier metal film 15a made of the Ti layer can be connected to the top ends of the carbon nanotubes 8 according to the interconnect structure and the fabrication method of the present embodiment. Therefore, increase in contact resistance to the upper wiring can be suppressed. Further, since the Ti layer 6b is connected to the bottom ends of the carbon nanotubes 8, increase in contact resistance to the lower wiring can be suppressed.
Since the carbon nanotubes 8 and the copper film 11 coexist in the contact hole 5, reduction in resistance and improvement in reliability of the contact hole 5 can be both achieved even when the carbon nanotubes 8 are formed at a low density. Specifically, the resistance of the contact hole 5 is parallel resistance constituted of resistance of the copper film and resistance of the carbon nanotubes 8, and the carbon nanotubes 8 allow ballistic transport. Therefore, the coexistence of the copper film and the carbon nanotubes 8 in the contact hole 5 allows further reduction in resistance of the contact hole 5 as compared with the case where only the copper film is formed in the contact hole 5. Moreover, the carbon nanotubes 8 present in the contact hole 5 remain in the contact hole 5 even when copper migration occurs. Therefore, breaking of metal wire at the contact hole 5 can significantly be suppressed.
In the above-described embodiment, Co is used as a catalyst metal for forming the carbon nanotubes. However, other metals such as Ni and Fe can also be used. Further, copper used as the interconnect material may be replaced with aluminum, silver, or gold.
In the interconnect structure of the above-described embodiment, the barrier metal film 6b made of the Ti layer is formed below the carbon nanotubes 8, and the barrier metal film 15a made of the Ti layer is formed on the top ends of the carbon nanotubes 8. However, from a viewpoint of suppressing the increase in contact resistance, it is needless to say that the Ti layer is formed on at least one of the top ends and the bottom ends of the carbon nanotubes 8.
As described above, the present invention is useful for fabricating high reliability, low resistance metal interconnects.
Number | Date | Country | Kind |
---|---|---|---|
2007-288491 | Nov 2007 | JP | national |
Number | Date | Country | |
---|---|---|---|
Parent | PCT/JP2008/002542 | Sep 2008 | US |
Child | 12476794 | US |