Patent Application
20070235643
The field of the invention relates to microanalytics and more particularly to gas pumps.
Presently available gas pumps for microanalytics are relatively large and use mechanical actuators that are subject to wear and limited service life. The use of mechanical actuators creates undesirable flow pulsations that can only be reduced through bulky buffer volumes. The difficulty of fabricating and assembling such mechanical pumps is significant and contributes to their high price.
Ion drag pumps overcome many of the deficiencies of mechanical pumps. Ion drag pumps first ionize a gas and then use an electric field to attract the ions. As ions are pulled along by the electric field, they also drag along other neutral gas molecules.
As the ions progress away from the point of ionization, the ions tend to recombine. However, by that time other ions have been created at the point of ionization that continue to push the recombined ions along, thereby continuing the flow of gas.
While ion drag pumps are an improvement over mechanical pumps, they are still relatively inefficient because of the rapid rate of recombination. Accordingly, a need exists for improved pumping methods for microanalytic devices.
A method and apparatus are provided for pumping a gas. The method includes the steps of ionizing the gas, separating the ionized gas into groups of positive and negative ions using positive and negative electric fields and separately pulling the groups of positive and negative ions along a channel using the negative and positive electric fields.
In general, pumping within the pump 10 occurs within a pumping channel 26 of appropriate length (e.g., 1-10 cm) and diameter (e.g., 10-100 microns) bounded by a semiconductor substrate (e.g., silicon) 12, 14. The semiconductor substrates 12, 14 may have insulating layers 16, 18 that separate the channel 26 from the semiconductor substrate 12, 14.
Disposed on the insulating layers 16, 18 within the channel 26 is a repeating set of electrodes 20, 22, 24 at an appropriate width (in the direction of flow 32) and inter-electrode spacing (e.g., 1-20 microns). The electrodes extend across diameter of the channel 26 perpendicular to a direction 32 of gas flow within the pump 10.
The electrodes 20, 22, 24 may supply an appropriate electrical gradient (e.g., 10 kV/cm) along the channel 26 from an n-phase power supply 28 operating at an appropriate frequency (e.g., less than 20 kHz). The connection of the n-phase power supply 28 to the repeating set of electrodes creates a traveling quadrupole electric field 34 within the channel 26.
In general, gas enters the pump 10 through an entry aperture 38 and drifts past an ionizer (e.g., an ionizing device) 30. The ionizer 30 may be any of a number of different devices (e.g., a corona discharge electrode, ionizing radiation source, etc.). Where the ionizing device 30 is an electrode, the device 30 may receive its ionizing voltage from the power supply 28.
As the gas drifts past the ionizing device, the gas becomes ionized into positive and negative ions 36, 38. Since the positive and negative ions 36, 38 are proximate the traveling electric field 34, the positive ions 36 are attracted and drawn into a positive ion trap formed by a negative electrode 20, 22, 24 of the traveling electric field 34 and the negative ions 38 are drawn towards and into a negative ion trap formed by a positive electrodes 20, 22, 24 of the electric field 34.
Since the electric field 34 is moving along the channel 26, the ions 36, 38 are drawn along with the electric field 34 in the direction of flow 32. Since the positive and negative electrodes of the traveling electric field are spatially separated, the positive ions 36 and negative ions 38 also remain separated as they are being pulled along by the traveling electric field 34. Since the positive ions 36 and negative ions 38 are kept separated, there is no recombination of ions 36, 38 as the ionized gas flows along the channel 26. Also, since the ions 36, 38 are all urged along in a single direction, the cumulative effect of the attractive forces on the ions 36, 38 by the succession of electrodes 20, 22, 24 causes compression of the gas along a length of the channel 26.
In another illustrated embodiment, the pump 10 may be combined with other pumps 10 in a series/parallel relationship to form a pump assembly 100 (
For example and as shown in
As shown in
In still further alternate embodiments, the pump 10 may be used as a valve. In this case, the number of electrodes 20, 22, 24 is chosen to oppose and balance an external pressure (e.g., to facilitate valve-less injection of a preconcentrated analyte from a sample gas #1 such as air into a carrier gas stream #2, such as hydrogen.
The pumps 10, 100 eliminate flow pulsations and the need for buffer volumes. Since the pumps 10, 100 rely upon an electric field for pumping, there is no mechanical noise and no mechanical wear.
A specific embodiment of an electronic pump has been described for the purpose of illustrating the manner in which one possible alternative of the invention is made and used. It should be understood that the implementation of other variations and modifications of embodiments of the invention and its various aspects will be apparent to one skilled in the art, and that the various alternative embodiments of the invention are not limited by the specific embodiments described. Therefore, it is contemplated to cover all possible alternative embodiments of the invention and any and all modifications, variations, or equivalents that fall within the true spirit and scope of the basic underlying principles disclosed and claimed herein.
