Patent Grant
8089084
The invention relates to light emitting devices and more particularly to light emitting devices including at least one light-emitting diode and phosphor, the phosphor including lead and/or copper doped chemical compounds and converting the wavelength of light.
Light emitting devices (LEDs), which used to be used for electronic devices, are now used for automobiles and illumination products. Since light emitting devices have superior electrical and mechanical characteristics, demands for light emitting devices have been increased. In connection to this, interests in white LEDs are increasing as an alternative to fluorescent lamps and incandescent lamps.
In LED technology, solution for realization of white light is proposed variously. Normally, realization of white LED technology is to put the phosphor on the light-emitting diode, and mix the primary emission from the light emitting diode and the secondary emission from the phosphor, which converts the wavelength. For example, as shown in WO 98/05078 and WO 98/12757, use a blue light emitting diode, which is capable of emitting a peak wavelength at 450-490 nm, and YAG group material, which absorbs light from the blue light emitting diode and emits yellowish light (mostly), which may have different wavelength from that of the absorbed light
However, in such a usual white LED, color temperature range is narrow which is between about 6,000-8,000K, and CRI (Color Rendering Index) is about 60 to 75. Therefore, it is hard to produce the white LED with color coordination and color temperature that are similar to those of the visible light. It is one of the reasons why only white light color with a cold feeling could be realized. Moreover, phosphors which are used for white LEDs are usually unstable in the water, vapor or polar solvent, and this unstableness may cause changes in the emitting characteristics of white LED.
A light emitting device can be characterized as including a light emitting diode configured to emit light and a phosphor configured to change a wavelength of the light. The phosphor includes a compound having a host material. Divalent copper ions and oxygen are components of the host material.
Further aspects of the invention may be apparent upon consideration of the following detailed description, taken in conjunction with the accompanying drawings, in which like reference characters refer to like parts throughout, and in which:
Refer to the attached drawing, the wavelength conversion light emitting device is going to be explained in detail, and the light emitting device and the phosphor are separately explained for easiness of explanation as below.
(Light Emitting Device)
Light emitting diodes may emit light with a wide range of wavelengths, for example, from ultraviolet light to visible light. In one embodiment consistent with this invention, a UV light emitting diode and/or blue light emitting diode may be use.
Phosphor, i.e., a phosphorescent substance, 3 may be placed on the top and side faces of the light emitting diode 6. The phosphor in consistent with this invention may include lead and/or copper doped aluminate type compounds, lead and/or copper doped silicates, lead and/or copper doped antimonates, lead and/or copper doped germanates, lead and/or copper doped germanate-silicates, lead and/or copper doped phosphates, or any combination thereof. Phosphor 3 converts the wavelength of the light from the light emitting diode 6 to another wavelength or other wavelengths. In one embodiment consistent with this invention, the light is in a visible light range after the conversion. Phosphor 3 may be applied to light emitting diode 6 after mixing phosphor 3 with a hardening resin. The hardening resin including phosphor 3 may also be applied to the bottom of light emitting diode 6 after mixing phosphor 3 with electrically conductive paste 9.
The light emitting diode 6 mounted on substrate 1 may be sealed with one or more sealing materials 10. Phosphor 3 may be placed on the top and side faces of light emitting diode 6. Phosphor 3 can also be distributed in the hardened sealing material during the production. Such a manufacturing method is described in U.S. Pat. No. 6,482,664, which is hereby incorporated by reference in its entirety.
Phosphor 3 may comprise lead and/or copper doped chemical compound(s). Phosphor 3 may include one or more single chemical compounds. The single compound may have an emission peak of, for example, from about 440 nm to about 500 nm, from about 500 nm to about 590 nm, or from about 580 nm to 700 nm. Phosphor 3 may include one or more single phosphors, which may have an emission peak as exemplified above.
In regard to light emitting device 40, light emitting diode 6 may emit primary light when light emitting diode 6 receives power from a power supply. The primary light then may stimulate phosphor(s) 3, and phosphor(s) 3 may convert the primary light to a light with longer wavelength(s) (a secondary light). The primary light from the light emitting diode 6 and the secondary light from the phosphors 3 are diffused and mixed together so that a predetermined color of light in visible spectrum may be emitted from light emitting diode 6. In one embodiment consistent with this invention, more than one light emitting diodes that have different emission peaks can be mounted together. Moreover, if the mixture ratio of phosphors is adjusted properly, specific color of light, color temperature, and CRI can be provided.
As described above, if the light emitting diode 6 and the compound included in phosphor 3 are properly controlled then desired color temperature or specific color coordination can be provided, especially, wide range of color temperature, for example, from about 2,000K to about 8,000K or about 10,000K and/or color rendering index of greater than about 90. Therefore, the light emitting devices consistent with this invention may be used for electronic devices such as home appliances, stereos, telecommunication devices, and for interior/exterior custom displays. The light emitting devices consistent with this invention may also be used for automobiles and illumination products because they provide similar color temperatures and CRI to those of the visible light.
In top-type package light emitting device 50, more than one light emitting diodes can be mounted. Each of such light emitting diodes may have a different peak wavelength from that of others. Phosphor 3 may comprise a plurality of single compounds with different emission peak. The proportion of each of such plurality of compounds may be regulated. Such a phosphor may be applied to the light emitting diode and/or uniformly distributed in the hardening material of the reflector 31. As explained more fully below, the phosphor in consistent with this invention may include lead and/or copper doped aluminate type compounds, lead and/or copper doped silicates, lead and/or copper doped antimonates, lead and/or copper doped germanates, lead and/or copper doped germanate-silicates, lead and/or copper doped phosphates, or any combination thereof.
In one embodiment consistent with this invention, the light emitting device of the
Regular volume of phosphor 3, which may be mixed in the epoxy resin, may be provided in diode holder 53. As explained more fully below, phosphor 3 may include lead and/or copper doped components.
Moreover, the diode holder may include the light emitting diode 6 and the phosphor 3 may be sealed with hardening material such as epoxy resin or silicon resin.
In one embodiment consistent with this invention, the lamp type package light emitting device may have more than one pair of electrode pair leads.
One or more light emitting diodes may be mounted one lead frame 74, and an electrode of the light emitting diode 6 and another lead frame 74 may be connected via electrically conductive wire. Electrically conductive plate 9 may be provided between light emitting diode 6 and lead frame 74. The phosphor 3 may be placed on top and side faces of light emitting diode 6.
Light emitting device for high power 80 may have housing 63, which may contain light emitting diodes 6, 7, phosphor 3 arranged on the top and side faces of light emitting diodes 6, 7, one or more heat sinks 61, 62, and one or more lead frames 64. The lead frames 64 may receive power from a power supplier and may protrude from housing 63.
In the light emitting devices for high power 70, 80 in the
In a light emitting device for high power consistent with this invention, one or more light emitting diodes can be used selectively and the phosphor can be regulated depending on the light emitting diode. As explained more fully below, the phosphor may include lead and/or copper doped components.
A light emitting device for high power consistent with this invention may have a radiator (not shown) and/or heat sink(s). Air or a fan may be used to cool the radiator.
The light emitting devices consistent with this invention is not limited to the structures described above, and the structures can be modified depending on the characteristics of light emitting diodes, phosphor, wavelength of light, and also applications. Moreover, new part can be added to the structures.
An exemplary phosphor consistent with this invention is as follows.
(Phosphor)
Phosphor in consistence with this invention may include lead and/or copper doped chemical compounds. The phosphor may be excited by UV and/or visible light, for example, blue light. The compound may include Aluminate, Silicate, Antimonate, Germanate, Germanate-silicate, or Phosphate type compounds.
Aluminate type compounds may comprise compounds having formula (1), (2), and/or (5)
a(M′O)·b(M″2O)·c(M″X)·dAl2O3·e(M′″O)·f(M″″2O3)·g(M′″″oOp)·h(M″″″xOy) (1)
wherein M′ may be Pb, Cu, and/or any combination thereof; M″ may be one or more monovalent elements, for example, Li, Na, K, Rb, Cs, Au, Ag, and/or any combination thereof; M′″ may be one or more divalent elements, for example, Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and/or any combination thereof; M″″ may be one or more trivalent elements, for example, Sc, B, Ga, In, and/or any combination thereof; M′″″ may be Si, Ge, Ti, Zr, Mn, V, Nb, Ta, W, Mo, and/or any combination thereof; M″″″ may be Bi, Sn, Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and/or any combination thereof; X may be F, Cl, Br, J, and/or any combination thereof; 0<a≦2; 0≦b≦2; 0≦c≦2; 0≦d≦8; 0<e≦4; 0≦f≦3; 0≦g≦8; 0<h≦2; 1≦o≦2; 1≦p≦5; 1≦x≦2; and 1≦y≦5.
a(M′O)·b(M″2O)·c(M″X)·4−a−b−c(M′″O)·7(Al2O3)·d(B2O3)·e(Ga2O3)·f(SiO2)·g(GeO2)·h(M″″xOy) (2)
wherein M′ may be Pb, Cu, and/or any combination thereof; M″ may be one or more monovalent elements, for example, Li, Na, K, Rb, Cs, Au, Ag, and/or any combination thereof; M′″ may be one or more divalent elements, for example, Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and/or any combination thereof; M″″ may be Bi, Sn, Sb, Sc, Y, La, In, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and any combination thereof; X may be F, Cl, Br, J, and any combination thereof; 0<a≦4; 0≦b≦2; 0≦c≦2; 0≦d≦1; 0≦e≦1; 0≦f≦1; 0≦g≦1; 0<h≦2; 1≦x≦2; and 1≦y≦5.
The preparation of copper as well as lead doped luminescent materials may be a basic solid state reaction. Pure starting materials without any impurities, e.g. iron, may be used. Any starting material which may transfer into oxides via a heating process may be used to form oxygen dominated phosphors.
Examples of Preparation:
Preparation of the luminescent material having formula (3)
Cu0.02Sr3.98Al14O25:Eu (3)
Starting materials: CuO, SrCO3, Al(OH)3, Eu2O3, and/or any combination thereof.
The starting materials in the form of oxides, hydroxides, and/or carbonates may be mixed in stoichiometric proportions together with small amounts of flux, e.g., H3BO3. The mixture may be fired in an alumina crucible in a first step at about 1,200° C. for about one hour. After milling the pre-fired materials a second firing step at about 1,450° C. in a reduced atmosphere for about 4 hours may be followed. After that the material may be milled, washed, dried and sieved. The resulting luminescent material may have an emission maximum of about 494 nm.
Preparation of the luminescent material having formula (4)
Pb0.5Sr3.95Al14O25:Eu (4)
Starting materials: PbO, SrCO3, Al2O3, Eu2O3, and/or any combination thereof.
The starting materials in form of very pure oxides, carbonates, or other components which may decompose thermically into oxides, may be mixed in stoichiometric proportion together with small amounts of flux, for example, H3BO3. The mixture may be fired in an alumina crucible at about 1,200° C. for about one hour in the air. After milling the pre-fired materials a second firing step at about 1,450° C. in air for about 2 hours and in a reduced atmosphere for about 2 hours may be followed. Then the material may be milled, washed, dried, and sieved. The resulting luminescent material may have an emission maximum of from about 494.5 nm.
a(M′O)·b(M″O)·c(Al2O3)·d(M′″2O3)·e(M″″O2)·f(M′″″xOy) (5)
wherein M′ may be Pb, Cu, and/or any combination thereof; M″ may be Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and/or any combination thereof; M′″ may be B, Ga, In, and/or any combination thereof; M″″ may be Si, Ge, Ti, Zr, Hf, and/or any combination thereof; M′″″ may be Bi, Sn, Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and/or any combination thereof; 0<a≦1; 0≦b≦2; 0<c≦8; 0≦d≦1; 0≦e≦1; 0<f≦2; 1≦x≦2; and and 1≦y≦5.
Example of Preparation:
Preparation of the luminescent material having formula (6)
Cu0.05Sr0.95Al1.9997Si0.0003O4:Eu (6)
Starting materials: CuO, SrCO3, Al2O3, SiO2, Eu2O3, and/or any combination thereof.
The starting materials in the form of, for example, pure oxides and/or as carbonates may be mixed in stoichiometric proportions together with small amounts of flux, for example, AlF3. The mixture may be fired in an alumina crucible at about 1,250° C. in a reduced atmosphere for about 3 hours. After that the material may be milled, washed, dried and sieved. The resulting luminescent material may have an emission maximum of about 521.5 nm.
Preparation of the luminescent material having formula (7)
Cu0.12BaMg1.88Al16O27:Eu (7)
Starting materials: CuO, MgO, BaCO3, Al(OH)3, Eu2O3, and/or any combination thereof.
The starting materials in the form of, for example, pure oxides, hydroxides, and/or carbonates may be mixed in stoichiometric proportions together with small amounts of flux, for example, AlF3. The mixture may be fired in an alumina crucible at about 1,420° C. in a reduced atmosphere for about 2 hours. After that the material may be milled, washed, dried, and sieved. The resulting luminescent material may have an emission maximum of about 452 nm.
Preparation of the luminescent material having formula (8)
Pb0.1Sr0.9Al2O4:Eu (8)
Starting materials: PbO, SrCO3, Al(OH)3, Eu2O3, and/or any combination thereof.
The starting materials in form of, for example, pure oxides, hydroxides, and/or carbonates may be mixed in stoichiometric proportions together with small amounts of flux, for example, H3BO3. The mixture may be fired in an alumina crucible at about 1,000° C. for about 2 hours in the air. After milling the pre-fired materials a second firing step at about 1,420° C. in the air for about 1 hour and in a reduced atmosphere for about 2 hours may be followed. After that the material may be milled, washed, dried and sieved. The resulting luminescent material may have an emission maximum of about 521 nm.
Results obtained in regard to copper and/or lead doped aluminates are shown in table 7.
A lead and/or copper doped silicates having formula (9)
a(M′O)·b(M″O)·c(M′″X)·d(M′″2O)·e(M″″2O3)·f(M′″″oOp)·g(SiO2)·h(M″″″xOy) (9)
wherein M′ may be Pb, Cu, and/or any combination thereof; M″ may be Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and/or any combination thereof; M′″ may be Li, Na, K, Rb, Cs, Au, Ag, and/or any combination thereof; M″″ may be Al, Ga, In, and/or any combination thereof; M′″″ may be Ge, V, Nb, Ta, W, Mo, Ti, Zr, Hf, and/or any combination thereof; M″″″ may be Bi, Sn, Sb, Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and/or any combination thereof; X may be F, Cl, Br, J, and any combination thereof; 0<a≦2; 0<b≦8; 0≦c≦4; 0≦d≦2; 0≦e≦2; 0≦f≦2; 0≦g≦10; 0<h≦5; 1≦o≦2; 1≦p≦5; 1≦x≦2; and 1≦y≦5.
Example of Preparation:
Preparation of the luminescent material having formula (10)
Cu0.05Sr1.7Ca0.25SiO4:Eu (10)
Starting materials: CuO, SrCO3, CaCO3, SiO2, Eu2O3, and/or any combination thereof.
The starting materials in the form of pure oxides and/or carbonates may be mixed in stoichiometric proportions together with small amounts of flux, for example, NH4Cl. The mixture may be fired in an alumina crucible at about 1,200° C. in an inert gas atmosphere (e.g., N2 or noble gas) for about 2 hours. Then the material may be milled. After that, the material may be fired in an alumina crucible at about 1,200° C. in a slightly reduced atmosphere for about 2 hours. Then, the material may be milled, washed, dried, and sieved. The resulting luminescent material may have an emission maximum at about 592 nm.
Preparation of the luminescent material having formula (11):
Cu0.2Ba2Zn0.2Mg0.6Si2O7:Eu (11)
Starting materials: CuO, BaCO3, ZnO, MgO, SiO2, Eu2O3, and/or any combination thereof.
The starting materials in the form of very pure oxides and carbonates may be mixed in stoichiometric proportions together with small amounts of flux, for example, NH4Cl. In a first step the mixture may be fired in an alumina crucible at about 1,100° C. in a reduced atmosphere for about 2 hours. Then the material may be milled. After that the material may be fired in an alumina crucible at about 1,235° C. in a reduced atmosphere for about 2 hours. Then that the material may be milled, washed, dried and sieved. The resulting luminescent material may have an emission maximum at about 467 nm.
Preparation of the luminescent material having formula (12)
Pb0.1Ba0.95Sr0.95Si0.998Ge0.002O4:Eu (12)
Starting materials: PbO, SrCO3, BaCO3, SiO2, GeO2, Eu2O3, and/or any combination thereof
The starting materials in the form of oxides and/or carbonates may be mixed in stoichiometric proportions together with small amounts of flux, for example, NH4Cl. The mixture may be fired in an alumina crucible at about 1,000° C. for about 2 hours in the air. After milling the pre-fired materials a second firing step at 1,220° C. in air for 4 hours and in reducing atmosphere for 2 hours may be followed. After that the material may be milled, washed, dried and sieved. The resulting luminescent material may have an emission maximum at about 527 nm.
Preparation of the luminescent material having formula (13)
Pb0.25Sr3.75Si3O8Cl4:Eu (13)
Starting materials: PbO, SrCO3, SrCl2, SiO2, Eu2O3, and any combination thereof.
The starting materials in the form of oxides, chlorides, and/or carbonates may be mixed in stoichiometric proportions together with small amounts of flux, for example, NH4Cl. The mixture may be fired in an alumina crucible in a first step at about 1,100° C. for about 2 hours in the air. After milling the pre-fired materials a second firing step at about 1,220° C. in the air for about 4 hours and in a reduced atmosphere for about 1 hour may be followed. After that the material may be milled, washed, dried and sieved. The resulting luminescent material may have an emission maximum at about 492 nm.
Results obtained with respect to copper and/or lead doped silicates are shown in table 12.
With lead and/or copper doped antimonates having formula (14)
a(M′O)·b(M″2O)·c(M″X)·d(Sb2O5)·e(M′″O)·f(M″″xOy) (14)
wherein M′ may be Pb, Cu, and/or any combination thereof; M″ may be Li, Na, K, Rb, Cs, Au, Ag, and/or any combination thereof; M′″ may be Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and/or any combination thereof; M″″ may be Bi, Sn, Sc, Y, La, Pr, Sm, Eu, Tb, Dy, Gd, and/or any combination thereof; X may be F, Cl, Br, J, and/or any combination thereof; 0<a≦2; 0≦b≦2; 0≦c≦4; 0<d≦8; 0≦e≦8; 0≦f≦2; 1≦x≦2; and 1≦y≦5.
Examples of Preparation:
Preparation of the luminescent material having formula (15)
Cu0.2Mg1.7Li0.2Sb2O7:Mn (15)
Starting materials: CuO, MgO, Li2O, Sb2O5, MnCO3, and/or any combination thereof.
The starting materials in the form of oxides may be mixed in stoichiometric proportion together with small amounts of flux. In a first step the mixture may be fired in an alumina crucible at about 985° C. in the air for about 2 hours. After pre-firing the material may be milled again. In a second step the mixture may be fired in an alumina crucible at about 1,200° C. in an atmosphere containing oxygen for about 8 hours. After that the material may be milled, washed, dried and sieved. The resulting luminescent material may have an emission maximum at about 626 nm.
Preparation of the luminescent material having formula (16)
Pb0.006Ca0.6Sr0.394Sb2O6 (16)
Starting materials: PbO, CaCO3, SrCO3, Sb2O5, and/or any combination thereof
The starting materials in the form of oxides and/or carbonates may be mixed in stoichiometric proportions together with small amounts of flux. In a first step the mixture may be fired in an alumina crucible at about 975° C. in the air for about 2 hours. After pre-firing the material may be milled again. In a second step the mixture may be fired in an alumina crucible at about 1,175° C. in the air for about 4 hours and then in an oxygen-containing atmosphere for about 4 hours. After that the material may be milled, washed, dried and sieved. The resulting luminescent material may have an emission maximum at about 637 nm.
Results obtained in respect to copper and/or lead doped antimonates are shown in table 15.
Lead and/or copper doped germanates and/or a germanate-silicates having formula (17)
a(M′O)·b(M″2O)·c(M″X)·dGeO2·e(M′″O)·f(M″″2O3)·g(M′″″oOp)·h(M″″″xOy) (17)
wherein M′ may be Pb, Cu, and/or any combination thereof; M″ may be Li, Na, K, Rb, Cs, Au, Ag, and/or any combination thereof; M′″ may be Be, Mg, Ca, Sr, Ba, Zn, Cd, and/or any combination thereof; M″″ may be Sc, Y, B, Al, La, Ga, In, and/or any combination thereof; M′″″ may be Si, Ti, Zr, Mn, V, Nb, Ta, W, Mo, and/or any combination thereof; M″″″ may be Bi, Sn, Pr, Sm, Eu, Gd, Dy, and/or any combination thereof; X may be F, Cl, Br, J, and/or any combination thereof; 0<a≦2; 0≦b≦2; 0≦c≦10; 0<d≦10; 0≦e≦14; 0≦f≦14; 0≦g≦10; 0≦h≦2; 1≦o≦2; 1≦p≦5; 1≦x≦2; and 1≦y≦5.
Example of Preparation:
Preparation of the luminescent material having formula (18)
Pb0.004Ca1.99Zn0.006Ge0.8Si0.2O4:Mn (18)
Starting materials: PbO, CaCO3, ZnO, GeO2, SiO2, MnCO3, and/or any combination thereof,
The starting materials in the form of oxides and/or carbonates may be mixed in stoichiometric proportions together with small amounts of flux, for example, NH4Cl. In a first step the mixture may be fired in an alumina crucible at about 1,200° C. in an oxygen-containing atmosphere for about 2 hours. Then, the material may be milled again. In a second step the mixture may be fired in an alumina crucible at about 1,200° C. in oxygen containing atmosphere for about 2 hours. After that the material may be milled, washed, dried and sieved. The resulting luminescent material may have an emission maximum at about 655 nm.
Preparation of the luminescent material having formula (19)
Cu0.46Sr0.54Ge0.6Si0.4O3:Mn (19)
Starting materials: CuO, SrCO3, GeO2, SiO2, MnCO3, and/or any combination thereof
The starting materials in the form of oxides and/or carbonates may be mixed in stoichiometric proportions together with small amounts of flux, for example, NH4Cl. In a first step the mixture may be fired in an alumina crucible at about 1,100° C. in an oxygen-containing atmosphere for about 2 hours. Then, the material may be milled again. In a second step the mixture may be fired in an alumina crucible at about 1,180° C. in an oxygen-containing atmosphere for about 4 hours. After that the material may be milled, washed, dried and sieved. The resulting luminescent material may have an emission maximum at about 658 nm.
Lead and/or copper doped phosphates having formula (20)
a(M′O)·b(M″2O)·c(M″X)·dP2O5·e(M′″O)·f(M″″2O3)·g(M′″″O2)·h(M″″″xOy) (20)
wherein M′ may be Pb, Cu, and/or any combination thereof; M″ may be Li, Na, K, Rb, Cs, Au, Ag, and/or any combination thereof; M′″ may be Be, Mg, Ca, Sr, Ba, Zn, Cd, Mn, and/or any combination thereof; M″″ may be Sc, Y, B, Al, La, Ga, In, and/or any combination thereof; M′″″ may be Si, Ge, Ti, Zr, Hf, V, Nb, Ta, W, Mo, and/or any combination thereof; M″″″ may be Bi, Sn, Pr, Sm, Eu, Gd, Dy, Ce, Tb, and/or any combination thereof; X may be F, Cl, Br, J, and/or any combination thereof; 0<a≦2; 0≦b≦12; 0≦c≦16; 0<d≦3; 0≦e≦5; 0≦f≦3; 0≦g≦2; 0<h≦2; 1≦x≦2; and 1≦y≦5.
Examples of Preparation:
Preparation of the luminescent material having formula (21)
Cu0.02Ca4.98(PO4)3Cl:Eu (21)
Starting materials: CuO, CaCO3, Ca3(PO4)2, CaCl2, Eu2O3, and/or any combination thereof,
The starting materials in the form of oxides, phosphates, and/or carbonates and chlorides may be mixed in stoichiometric proportions together with small amounts of flux. The mixture may be fired in an alumina crucible at about 1,240° C. in reducing atmosphere for about 2 hours. After that the material may be milled, washed, dried and sieved. The luminescent material may have an emission maximum at about 450 nm.
Meanwhile, the phosphor of the light emitting device consistent with this invention can comprise aluminate, silicate, antimonate, germanate, phosphate type chemical compound, and any combination thereof.
In such an embodiment, part of the initial about 405 nm wavelength emission light from the light emitting diode is absorbed by the phosphor, and it is converted to longer 2nd wavelength. The 1st and 2nd light is mixed together and the desire emission is produced. As the shown
The phosphor is composed of Cu0.05Sr1.7Ca0.25SiO4:Eu which may have peak wavelength at about 592 nm, Pb0.1Ba0.95Sr0.95Si0.998Ge0.002O4:Eu which may have peak wavelength at about 527 nm, and Cu0.05Li0.002Sr1.5Ba0.448SiO4:Gd, Eu which may have peak wavelength at about 557 nm.
In such an embodiment, part of the initial about 455 nm wavelength emission light from the light emitting diode is absorbed by the phosphor, and it is converted to longer 2nd wavelength. The 1st and 2nd light is mixed together and the desire emission is produced. As the shown
The phosphor of the light emitting device according to the invention can be applied by single chemical compound or mixture of plurality of single chemical compound besides the embodiments in relation to
According to the description above, light emitting device with wide range of color temperature about 2,000K or about 8,000K or about 10,000K and superior color rendering index more than about 90 can be realized by using the lead and/or copper doped chemical compounds containing rare earth elements.
In such a wavelength conversion light emitting device is capable of applying on mobile phone, note book and electronic devices such as home appliance, stereo, telecommunication products, but also for custom display's key pad and back light application. Moreover, it can be applied for automobile, medical instrument and illumination products.
According to the invention, it is also able to provide a wavelength conversion light emitting device with stability against water, humidity, vapor as well as other polar solvents.
In the foregoing described embodiments, various features are grouped together in a single embodiment for purposes of streamlining the disclosure. This method of disclosure is not to be interpreted as reflecting an intention that the claimed invention requires more features than are expressly recited in each claim. Rather, as the following claims reflect, inventive aspects lie in less than all features of a single foregoing disclosed embodiment. Thus, the following claims are hereby incorporated into this Detailed Description of Embodiments, with each claim standing on its own as a separate preferred embodiment of the invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2004-042396 | Jun 2004 | KR | national |
This application is a continuation of application Ser. No. 11/024,702, filed on Dec. 30, 2004, now pending. This application also claims priority of Korean Patent Application No. 2004-042396, filed on Jun. 10, 2004, the contents of which are incorporated herein by reference in their entirety.
| Number | Name | Date | Kind |
|---|---|---|---|
| 2110162 | Leverenz | Mar 1938 | A |
| 2402760 | Leverenz | Jun 1946 | A |
| 2570136 | Lyon | Oct 1951 | A |
| 2617773 | Nagy et al. | Nov 1952 | A |
| 2719128 | Kressin et al. | Sep 1955 | A |
| 2780600 | Wollentin | Feb 1957 | A |
| 3143510 | Wanmaker et al. | Aug 1964 | A |
| 3598752 | Sisneros et al. | Aug 1971 | A |
| 3644212 | McAllister et al. | Feb 1972 | A |
| 3893939 | De Kalb et al. | Jul 1975 | A |
| 3905911 | Kelsey, Jr. et al. | Sep 1975 | A |
| 4215289 | De Hair et al. | Jul 1980 | A |
| 4770950 | Ohnishi | Sep 1988 | A |
| 4972086 | Bryan et al. | Nov 1990 | A |
| 5032316 | Takahashi et al. | Jul 1991 | A |
| 5433295 | Murphy | Jul 1995 | A |
| 5472636 | Forster et al. | Dec 1995 | A |
| 5518808 | Bruno et al. | May 1996 | A |
| 5770110 | Schrell et al. | Jun 1998 | A |
| 5770111 | Moriyama et al. | Jun 1998 | A |
| 5853614 | Hao et al. | Dec 1998 | A |
| 5952681 | Chen | Sep 1999 | A |
| 5965192 | Potter | Oct 1999 | A |
| 5998925 | Shimizu et al. | Dec 1999 | A |
| 6045722 | Leblans et al. | Apr 2000 | A |
| 6066861 | Hohn et al. | May 2000 | A |
| 6373184 | Suh et al. | Apr 2002 | B1 |
| 6472765 | Sano et al. | Oct 2002 | B1 |
| 6482664 | Lee | Nov 2002 | B1 |
| 6565771 | Ono et al. | May 2003 | B1 |
| 6670751 | Song et al. | Dec 2003 | B2 |
| 6686691 | Mueller | Feb 2004 | B1 |
| 6842664 | Harada | Jan 2005 | B2 |
| 6982045 | Menkara et al. | Jan 2006 | B2 |
| 6982048 | Atwater et al. | Jan 2006 | B1 |
| 6987353 | Menkara et al. | Jan 2006 | B2 |
| 7019335 | Suenaga | Mar 2006 | B2 |
| 7029602 | Oshio | Apr 2006 | B2 |
| 7045078 | Choi | May 2006 | B2 |
| 7138770 | Uang et al. | Nov 2006 | B2 |
| 7189340 | Shimomura et al. | Mar 2007 | B2 |
| 7206507 | Lee et al. | Apr 2007 | B2 |
| 7229571 | Ezuhara et al. | Jun 2007 | B2 |
| 7244965 | Andrews et al. | Jul 2007 | B2 |
| 7332746 | Takahashi et al. | Feb 2008 | B1 |
| 7468147 | Shida et al. | Dec 2008 | B2 |
| 7554129 | Roth et al. | Jun 2009 | B2 |
| 7608200 | Seto et al. | Oct 2009 | B2 |
| 7679101 | Ota et al. | Mar 2010 | B2 |
| 7679281 | Kim et al. | Mar 2010 | B2 |
| 20020015013 | Ragle | Feb 2002 | A1 |
| 20030038295 | Koda | Feb 2003 | A1 |
| 20030168636 | Dobson | Sep 2003 | A1 |
| 20040051111 | Ota et al. | Mar 2004 | A1 |
| 20040104391 | Maeda et al. | Jun 2004 | A1 |
| 20040135504 | Tamaki et al. | Jul 2004 | A1 |
| 20040136891 | Kijima et al. | Jul 2004 | A1 |
| 20040206970 | Martin | Oct 2004 | A1 |
| 20040251809 | Shimomura et al. | Dec 2004 | A1 |
| 20050001225 | Yoshimura et al. | Jan 2005 | A1 |
| 20050001537 | West et al. | Jan 2005 | A1 |
| 20050029927 | Setlur et al. | Feb 2005 | A1 |
| 20050117334 | Lee | Jun 2005 | A1 |
| 20050139846 | Park et al. | Jun 2005 | A1 |
| 20050141048 | Mizutani | Jun 2005 | A1 |
| 20050239227 | Aanegola et al. | Oct 2005 | A1 |
| 20050264161 | Oaku et al. | Dec 2005 | A1 |
| 20050274930 | Roth et al. | Dec 2005 | A1 |
| 20050274972 | Roth et al. | Dec 2005 | A1 |
| 20060076883 | Himaki et al. | Apr 2006 | A1 |
| 20060158090 | Wang et al. | Jul 2006 | A1 |
| 20060261309 | Li et al. | Nov 2006 | A1 |
| 20060261350 | Kawazoe et al. | Nov 2006 | A1 |
| 20060267042 | Izuno et al. | Nov 2006 | A1 |
| 20070029526 | Cheng et al. | Feb 2007 | A1 |
| 20070247051 | Kuze et al. | Oct 2007 | A1 |
| 20070284563 | Lee et al. | Dec 2007 | A1 |
| 20080036364 | Li et al. | Feb 2008 | A1 |
| 20080067472 | Roth et al. | Mar 2008 | A1 |
| 20080067920 | Roth et al. | Mar 2008 | A1 |
| 20090050847 | Xu et al. | Feb 2009 | A1 |
| 20090050849 | Lee et al. | Feb 2009 | A1 |
| 20090134413 | Roth et al. | May 2009 | A1 |
| 20090152496 | Roth et al. | Jun 2009 | A1 |
| 20090262515 | Lee et al. | Oct 2009 | A1 |
| 20090303694 | Roth | Dec 2009 | A1 |
| 20100002454 | Lee et al. | Jan 2010 | A1 |
| 20100165645 | Lee et al. | Jul 2010 | A1 |
| 20100207132 | Lee et al. | Aug 2010 | A1 |
| Number | Date | Country |
|---|---|---|
| 410266 | Mar 2003 | AT |
| 1218084 | Jun 1999 | CN |
| 1289454 | Mar 2001 | CN |
| 1317537 | Oct 2001 | CN |
| 1344777 | Apr 2002 | CN |
| 1434521 | Aug 2003 | CN |
| 1707819 | Dec 2005 | CN |
| 10233050 | Feb 2004 | DE |
| 10259946 | Jul 2004 | DE |
| 0094132 | Nov 1983 | EP |
| 0382295 | Aug 1993 | EP |
| 0862794 | Sep 1998 | EP |
| 0 896 994 | Feb 1999 | EP |
| 1249873 | Oct 2002 | EP |
| 1605030 | Dec 2005 | EP |
| 2031038 | Mar 2009 | EP |
| 1336053 | Nov 1973 | GB |
| 2016034 | Sep 1979 | GB |
| 31-1118 | Feb 1956 | JP |
| 33-8177 | Apr 1956 | JP |
| 38-6082 | May 1963 | JP |
| 39-8803 | May 1964 | JP |
| 47-6258 | Apr 1972 | JP |
| 49-38994 | Oct 1974 | JP |
| 55-135190 | Oct 1980 | JP |
| 55135190 | Oct 1980 | JP |
| 57109886 | Jul 1982 | JP |
| 61-258892 | Nov 1986 | JP |
| 61258892 | Nov 1986 | JP |
| 62-197487 | Jan 1987 | JP |
| 5-78659 | Mar 1993 | JP |
| 05-078659 | Mar 1993 | JP |
| 9-40946 | Feb 1997 | JP |
| 9153644 | Jun 1997 | JP |
| 2001-308393 | Feb 2001 | JP |
| 2001-115157 | Apr 2001 | JP |
| 2001-524163 | Nov 2001 | JP |
| 2002-50795 | Feb 2002 | JP |
| 2002-057376 | Feb 2002 | JP |
| 2002094122 | Mar 2002 | JP |
| 2002-97466 | Apr 2002 | JP |
| 2002173677 | Jun 2002 | JP |
| 2002335019 | Nov 2002 | JP |
| 2002359403 | Dec 2002 | JP |
| 2002368277 | Dec 2002 | JP |
| 2003-064358 | Mar 2003 | JP |
| 2003-152229 | May 2003 | JP |
| 2003183649 | Jul 2003 | JP |
| 2003224306 | Aug 2003 | JP |
| 2003-321675 | Nov 2003 | JP |
| 200321675 | Nov 2003 | JP |
| 20046582 | Jan 2004 | JP |
| 2004010786 | Jan 2004 | JP |
| 2004-505470 | Feb 2004 | JP |
| 2004-71807 | Mar 2004 | JP |
| 2004071726 | Mar 2004 | JP |
| 2004-134699 | Apr 2004 | JP |
| 2004127988 | Apr 2004 | JP |
| 2004192833 | Jul 2004 | JP |
| 2005167177 | Jun 2005 | JP |
| 2006-073656 | Mar 2006 | JP |
| 2006-173433 | Jun 2006 | JP |
| 2007-186674 | Jul 2007 | JP |
| 2009-007545 | Jan 2009 | JP |
| 10-232395 | Dec 1999 | KR |
| 1020010032450 | Apr 2001 | KR |
| 2001-50839 | Jun 2001 | KR |
| 1020010101910 | Nov 2001 | KR |
| 2002-835 | Jan 2002 | KR |
| 2002-0053975 | Jul 2002 | KR |
| 1020020079513 | Oct 2002 | KR |
| 10-0392363 | Jul 2003 | KR |
| 1020030063211 | Jul 2003 | KR |
| 2003-82395 | Oct 2003 | KR |
| 10-426034 | Jul 2004 | KR |
| 1020040088418 | Oct 2004 | KR |
| 1020050008426 | Jan 2005 | KR |
| 1020050070349 | Jul 2005 | KR |
| 2005-98462 | Oct 2005 | KR |
| 1020050106945 | Nov 2005 | KR |
| 10-2005-0117165 | Dec 2005 | KR |
| 1020050117164 | Dec 2005 | KR |
| 10-2006-0034056 | Apr 2006 | KR |
| 10-0626272 | Sep 2006 | KR |
| 10-2006-0134728 | Dec 2006 | KR |
| 10-2007-0016900 | Feb 2007 | KR |
| 10-2008-0046789 | May 2008 | KR |
| 93140901 | Aug 2010 | TW |
| WO9632457 | Oct 1996 | WO |
| WO9805078 | Feb 1998 | WO |
| WO9812757 | Mar 1998 | WO |
| 9839805 | Sep 1998 | WO |
| 9842798 | Oct 1998 | WO |
| 0019546 | Apr 2000 | WO |
| 0141215 | Jun 2001 | WO |
| 02-054502 | Jul 2002 | WO |
| 02-054503 | Jul 2002 | WO |
| 02089219 | Nov 2002 | WO |
| 03021691 | Mar 2003 | WO |
| 2004085570 | Oct 2004 | WO |
| 2004111156 | Dec 2004 | WO |
| 2005068584 | Jul 2005 | WO |
| 2005-109532 | Nov 2005 | WO |
| 2005-112137 | Nov 2005 | WO |
| 2006-043682 | Apr 2006 | WO |
| 2006068359 | Jun 2006 | WO |
| 2006081803 | Aug 2006 | WO |
| 2006109659 | Oct 2006 | WO |
| 2007-035026 | Mar 2007 | WO |
| 2007-055538 | May 2007 | WO |
| 2007-069869 | Jun 2007 | WO |
| 2007-114614 | Nov 2007 | WO |
| 2009-028818 | Mar 2009 | WO |
| Number | Date | Country | |
|---|---|---|---|
| 20080224163 A1 | Sep 2008 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 11024702 | Dec 2004 | US |
| Child | 12098263 | US |
