Claims
- 1. A plasmatron fuel converter for producing a hydrogen rich gas, comprising:
a first electrode comprising an electrically conductive structure; a second electrode so disposed with respect to the first electrode as to create at least two boundaries of a plasma discharge volume; a power supply connected to the first and second electrodes to provide voltage and current sufficient to generate a plasma discharge within the plasma discharge volume to initiate a reaction of an injected reactive mixture; and means for establishing a fluid flow through the plasma discharge volume;
wherein the fluid flow continually stretches and extinguishes the plasma discharge generated within the plasma discharge volume; and wherein the plasma discharge is continually and substantially reestablished randomly across the plasma discharge volume.
- 2. The plasmatron fuel converter of claim 1 wherein rapid establishment, extinction and reestablishment of the plasma discharge produces a quasi-continuous plasma discharge that is substantially equally distributed throughout the plasma discharge volume.
- 3. The plasmatron fuel converter of claim 2 wherein the quasi-continuous plasma discharge initiates chemical reactions substantially throughout the plasma discharge volume.
- 4. The plasmatron fuel converter of claim 1 wherein the plasma discharge is restablished after extinction in a time of less than 100 nanoseconds.
- 5. The plasmatron fuel converter of claim 1 further comprising an injection mechanism for injecting said injected reactive mixture into said plasma discharge volume.
- 6. The plasmatron fuel converter of claim 5 wherein said injection mechanism comprises:
means for providing fuel; means for providing air assist to mix with said fuel and to form a fuel/oxidant mixture; and a nozzle for controlling injection of said fuel/oxidant mixture into said plasma discharge volume.
- 7. The plasmatron fuel converter of claim 1 wherein a flow direction of said injected reactive mixture is perpendicular to a flow direction of said fluid flow.
- 8. The plasmatron fuel converter of claim 1 wherein said injected reactive mixture and said fluid flow are the same flow.
- 9. The plasmatron fuel converter of claim 1 wherein the fluid flow comprises an oxidant.
- 10. The plasmatron fuel converter of claim 9 wherein the oxidant comprises air.
- 11. The plasmatron fuel converter of claim 9 wherein the oxidant comprises an exhaust gas containing free oxygen.
- 12. The plasmatron fuel converter of claim 1 wherein the fluid flow comprises a fuel/oxidant mixture.
- 13. The plasmatron fuel converter of claim 1 wherein said injected reactive mixture comprises a fuel/oxidant mixture.
- 14. The plasmatron fuel converter of claim 1 wherein said injected reactive mixture comprises fuel.
- 15. The plasmatron fuel converter of claim 1 wherein the current provided by the power supply is limited so as to prevent non-arcing-to-arc breakdown.
- 16. The plasmatron fuel converter of claim 1 wherein said power supply is an adjustable frequency power supply.
- 17. The plasmatron fuel converter of claim 16 wherein said adjustable frequency power supply is adapted to be adjusted from 100 Hz to 2 MHz.
- 18. The plasmatron fuel converter of claim 1 wherein said power supply provides voltage in the range of approximately 300 volts to 60 kilovolts and current in the range of approximately 10 milliamperes to 2 amperes to generate said plasma discharge within the plasma discharge volume.
- 19. The plasmatron fuel converter of claim 1 wherein said first electrode and said second electrode are hollow cylindrical electrodes disposed to form a channel containing the plasma discharge volume.
- 20. The plasmatron fuel converter of claim 1 wherein said first electrode and said second electrode are ring electrodes positioned in a vertical configuration.
- 21. The plasmatron fuel converter of claim 1 wherein said first electrode and said second electrode are rod electrodes positioned in a horizontal configuration.
- 22. The plasmatron fuel converter of claim 1 wherein said first electrode and said second electrode are cylinders positioned in a co-axial configuration.
- 23. The plasmatron fuel converter of claim 1 wherein the fluid flow is introduced upstream from the plasma discharge volume.
- 24. The plasmatron fuel converter of claim 1 wherein said fluid flow is adapted to provide an enlarged volumetric contact of said plasma discharge and said injected reactive mixture within said plasma discharge volume.
- 25. The plasmatron fuel converter of claim 5 wherein said injection mechanism and said fluid flow are adapted to provide an enlarged volumetric contact of said plasma discharge and said injected reactive mixture within said plasma discharge volume.
- 26. The plasmatron fuel converter of claim 1 further comprising:
a reactor having a reaction extension region adapted to receive an ignited reactive mixture from said plasma discharge volume.
- 27. The plasmatron fuel converter of claim 26 wherein the reactor is a metallic or ceramic cylinder.
- 28. The plasmatron fuel converter of claim 26 wherein an interior of the reactor is covered with thermal insulation.
- 29. The plasmatron fuel converter of claim 26 wherein an exterior of the reactor is covered with thermal insulation.
- 30. The plasmatron fuel converter of claim 26 wherein the reaction extension region contains a catalytic structure.
- 31. The plasmatron fuel converter of claim 30 wherein the catalytic structure is a metallic or ceramic honeycomb catalytic structure.
- 32. The plasmatron fuel converter of claim 30 wherein the catalytic structure is coated with one or more catalyst selected from the group consisting of ruthenium, rhodium, cobalt, iron, nickel, palladium, rhenium, osmium, and platinum.
- 33. The plasmatron fuel converter of claim 26 wherein a turbulizer is disposed within the reaction extension region to receive and deflect the ignited reactive mixture exiting the plasma discharge volume.
- 34. The plasmatron fuel converter of claim 26 further comprising:
a heat exchanger adapted to receive the hydrogen rich gas output from said reactor.
- 35. The plasmatron fuel converter of claim 34 wherein the heat exchanger is adapted to preheat the injected reactive mixture or said fluid flow.
- 36. The plasmatron fuel converter of claim 1 wherein the injected reactive mixture is selected for operation between stoichiometric partial oxidation and full oxidation.
- 37. The plasmatron fuel converter of claim 3 wherein the chemical reactions are partial oxidation reactions selected for operation between stoichiometric partial oxidation and full combustion.
- 38. The plasmatron fuel converter of claim 1 wherein an oxygen to carbon ratio of the injected reactive mixture is between 1.2 and 2.0.
- 39. The plasmatron fuel converter of claim 1 wherein said oxygen to carbon ratio of the reactive mixture is less than 1.2.
- 40. A method of plasma fuel conversion for producing a hydrogen-rich gas, comprising the steps of:
positioning a first electrode and a second electrode such that a gap exists between them and a plasma discharge volume is formed; injecting a reactive mixture into said discharge volume; supplying power so as to provide voltage and current sufficient to generate a plasma discharge within the discharge volume and produce an ignited reactive mixture; introducing a fluid flow into said discharge volume to stretch and deform said plasma discharge.
- 41. The method of claim 40 wherein rapid establishment, extinction and reestablishment of the plasma discharge produces a quasi-continuous plasma discharge that is substantially equally distributed throughout the plasma discharge volume.
- 42. The method of claim 41 wherein the quasi-continuous plasma discharge initiates chemical reactions substantially throughout the plasma discharge volume.
- 43. The method of claim 40 wherein the plasma discharge is restablished after extinction in a time of less than 100 nanoseconds.
- 44. The method of claim 40 wherein a flow direction of said injected reactive mixture is perpendicular to a flow direction of said fluid flow.
- 45. The method of claim 40 wherein said injected reactive mixture and said fluid flow are the same flow.
- 46. The method of claim 40 wherein the fluid flow comprises an oxidant.
- 47. The method of claim 46 wherein the oxidant comprises air.
- 48. The method of claim 46 wherein the oxidant comprises an exhaust gas containing free oxygen.
- 49. The method of claim 40 wherein the fluid flow comprises a fuel/oxidant mixture.
- 50. The method of claim 40 wherein said injected reactive mixture comprises a fuel/oxidant mixture.
- 51. The method of claim 40 wherein said injected reactive mixture comprises fuel.
- 52. The method of claim 40 wherein the current provided by the power supply is limited so as to prevent non-arcing-to-arc breakdown.
- 53. The method of claim 40 wherein said power supply is an adjustable frequency power supply.
- 54. The method of claim 53 wherein said adjustable frequency power supply is adapted to be adjusted from 100 Hz to 2 MHz.
- 55. The method of claim 40 wherein said power supply provides voltage in the range of approximately 300 volts to 60 kilovolts and current in the range of approximately 10 milliamperes to 2 amperes to generate said plasma discharge within the plasma discharge volume.
- 56. The method of claim 40 wherein said step of introducing said fluid flow provides an enlarged volumetric contact of said plasma discharge and said injected reactive mixture within said plasma discharge volume.
- 57. The method of claim 40 wherein said step of introducing said fluid flow and said step of injecting said reactive mixture provide an enlarged volumetric contract of said plasma discharge and said injected reactive mixture within said plasma discharge volume.
- 58. The method of claim 40, further comprising the step of:
introducing said ignited reactive mixture into a reactor having a reaction extension region.
- 59. The method of claim 58, further comprising the step of:
turbulizing the ignited reactive mixture.
- 60. The method of claim 58, further comprising the step of:
providing a catalyst in said reaction extension region.
- 61. The method of claim 58, further comprising the step of:
recycling the hydrogen rich gas output from said reactor to preheat said fluid flow.
- 62. The method of claim 58, further comprising the step of:
recycling the hydrogen rich gas output from said reactor to preheat said injected reactive mixture.
- 63. The method of claim 40 wherein electrical power consumption is between 0.3% to 10% of the thermal power content of the hydrogen rich gas produced.
- 64. The method of claim 40 wherein an oxygen to carbon ratio of the reactive mixture is between 1.2 and 2.0.
- 65. The method of claim 40 wherein said oxygen to carbon ratio of the reactive mixture is less than 1.2.
GOVERNMENT SUPPORT
[0001] This invention was made with government support under Grant Nos. DE-FG07-98ID13601 and DE-FG04-95AL88002 awarded by the Department of Energy. The United States Government has certain rights in the invention.