Mass spectrometer and mass spectrometry

Abstract

A mass spectrometer capable of measuring under switching two ion sources at different pressure levels in which a sample gas separated by GC column is branched, and separately introduced to a first ion source (for example, APCI ion source) and a second ion source (for example, EI ion source) at a pressure level lower than that of the first ion source respectively. Preferably, the flow rate of the sample gas introduced to the APCI ion source is made more than the flow rate of the sample gas introduced to the EI ion source, so that the pressure for each of the ion sources can be maintained and analysis can be conducted by each ionization at a good balance in view of the sensitivity.

Description

DESCRIPTION OF THE ACCOMPANYING DRAWINGS

FIG. 1 is a schematic view showing an example of the constitution for a mass spectrometer according to the invention;

FIG. 2 is a view showing an example of the constitution with a differential pumping part being omitted between an APCI ion source and an EI ion source;

FIG. 3 is a view showing an example of the constitution in which the length of a GC column for introducing a sample to the APCI ion source and that to the EI ion source are different;

FIG. 4 is a view showing an example of analysis where APCI ionization and EI ionization are switched;

FIG. 5 is a view showing an example of analysis where APCI ionization and EI ionization are switched;

FIG. 6 is a flow chart for explaining an example of a measuring sequence;

FIG. 7 is a view showing an example of analysis where APCI ionization and EI ionization are switched;

FIG. 8 is a view showing an example of analysis where APCI ionization and EI ionization are switched;

FIG. 9 is a constitutional view for the inside of an APCI ion source; and

FIG. 10 is a view showing an example of the constitution for making time difference between APCI ionization and EI ionization.

Claims

1. A mass spectrometer comprising: a first sample ion source;a second sample ion source disposed to the downstream of the first sample ion source relative to the moving direction of the ions of the first sample ion source and at a pressure lower than that of the first sample ion source; andmass spectrometric part disposed downstream of the second sample ion source to the moving direction of the ions of the second sample ion source, wherein a first sample introduction port branched from a sample introduction channel is disposed to the first sample ion source and a second sample introduction port branched from the sample introduction channel is disposed to the second sample ion source.

2. A mass spectrometer according to claim 1, comprising a controller for controlling the ionization of the sample by the first sample ion source and ionization of the sample by the second sample ionization source, wherein the controller selectively operates the first sample ion source and the second sample ion source.

3. A mass spectrometer according to claim 1, wherein the flow rate of the sample introduced from the first sample introduction port to the first sample ion source is more than the flow rate of the sample introduced from the second sample introduction port to the second sample ion source.

4. A mass spectrometer according to claim 1, wherein the flow rate of the sample introduced from the first sample introduction port to the first sample ion source is twice or more than the flow rate of the sample introduced from the second sample introduction port to the second sample ion source.

5. A mass spectrometer according to claim 1, wherein the sample introduction channel is connected with a gas chromatographic column.

6. A mass spectrometer according to claim 1, wherein the first sample ionization source generates sample ions by atmospheric chemical ionization and the second sample ion source generates sample ions by electron impact ionization.

7. A mass spectrometer according to claim 6, wherein the first sample ion source has a needle electrode for generating corona discharge and a lead-out electrode having an aperture and opposing to the needle electrode, and the first sample introduction port situates downstream of the lead-out electrode in the moving direction of the ions.

8. A mass spectrometer according to claim 5, wherein a difference is provided between the length from the branch part of the sample introduction channel to the first sample introduction port and the length to the second sample introduction port, so that a sample ingredient eluted from the first sample introduction port is eluted from the second sample introduction port with a time delay by more than the peak width separated by gas chromatographic column.

9-16. (canceled)