Patent Application
20070298162
The present invention relates to a method and apparatus for manufacturing a protective layer which is disposed on a substrate. The invention more particularly relates to a method and apparatus for manufacturing a good-quality protective layer which can be suitably used to coat a dielectric layer in a plasma display panel.
A plasma display panel (hereinafter, PDP) includes a front panel and a back panel oppositely disposed to each other and sealed at their periphery with a sealing member. The front panel and the back panel have a discharge space therebetween filled with a discharge gas including neon (Ne) and xenon (Xe).
The front panel includes a glass substrate; display electrode pairs; a dielectric layer; and a protective layer. The display electrode pairs each consist of a scan electrode and a sustain electrode formed in a stripe pattern on the glass substrate. The dielectric layer coats the display electrode pairs, and the protective layer coats the dielectric layer. Each of the display electrode pair consists of a transparent electrode and a metal bus electrode formed thereon.
On the other hand, the back panel includes a glass substrate; address electrodes; an base dielectric layer; barrier ribs; and phosphor layers of red, green, and blue. The address electrodes are formed in a stripe pattern on the glass substrate. The base dielectric layer coats the address electrodes. The barrier ribs are formed in a strip pattern on the base dielectric layer so as to partition the discharge space in correspondence with the address electrodes. The phosphor layers are formed on the base dielectric layer between the barrier ribs and also on side surfaces of the barrier ribs.
The front panel and the back panel are oppositely disposed to each other so that the display electrode pairs and the address electrodes can be at right angles to each other and have discharge cells at their intersections. The discharge cells are arranged in a matrix where three adjacent discharge cells having red, green, and blue phosphor layers arranged in the direction of the display electrode pairs form a pixel for color display. In a PDP, a predetermined voltage is applied between the scan electrodes and the address electrodes and between the scan electrodes and the sustain electrodes so as to generate a gas discharge. The gas discharge generates ultraviolet light which excites the phosphor layers, allowing them to emit light so as to display color images.
In a PDP thus structured, the protective layer is required to have a high resistance to sputtering and a large secondary electron emission coefficient. For this reason, a protective layer of magnesium oxide (MgO) is widely used. The sputtering resistance and secondary emission characteristics can protect the dielectric layer from sputtering and reduce the discharge voltage.
The protective layer, which can be formed by electron beam deposition or using a plasma gun, can have very different film properties depending on the method and conditions of its formation. Japanese Patent Unexamined Publication No. 2005-50804 shows an example of stably manufacturing a protective layer having excellent film properties in the following manner. When the protective layer is formed by electron beam deposition of magnesium oxide (MgO), the partial pressures of various gases including oxygen present in the evaporation chamber are controlled in a certain range.
The protective layer of magnesium oxide (MgO) can significantly change film properties due to oxygen deficiency or impurity incorporation during its formation. In a widely used film-forming apparatus of substrate transfer type, a glass substrate finished up to the dielectric layer is placed on a tray and applied with the protective layer in a film-forming chamber. When the glass substrate passes through the film-forming chamber, the magnesium oxide (MgO) film pieces can adhere to the tray and the mask. When the glass substrate is taken out into the atmosphere from the film-forming chamber, the magnesium oxide (MgO) adhering to the tray and the mask absorbs moisture in the atmosphere. When another magnesium oxide (MgO) film is formed on the next glass substrate that is being transferred into the film-forming chamber using the same tray and mask, the moisture absorbed in the tray and the mask is released into the film-forming chamber. Part of the moisture is dissociated into hydrogen and oxygen in the film-forming chamber. These gases cause a change in the partial pressures in the film-forming chamber, thereby causing variations in the film properties of the magnesium oxide (MgO) film.
As a way to stabilize the partial pressures so as to reduce the amount of water brought into the film-forming chamber, in a film-forming apparatus of substrate transfer type, different trays and different masks are used inside and outside the film-forming chamber. However, as the substrate size becomes larger and more diverse, the transfer mechanism becomes more complicated. As a result, the apparatus has a lower reliability and a higher cost.
As another way to stabilize the partial pressures so as to reduce the amount of water brought into the film-forming chamber, the atmosphere during the transfer of the substrate is made low in dew point and water content. This method requires a plurality of pumps such as cryopumps or turbomolecular pumps having a high exhausting capacity. In addition, it is necessary to vary the exhaust velocity by changing the opening of a conductance valve disposed between the film-forming chamber and the pumps or the number of the pumps. The problem is that this approach causes variation in the exhaust velocity not only of the water but also of the other gases, making it difficult to keep the partial pressures in the film-forming chamber constant. On the other hand, in the case where the exhaust velocity is varied by changing the speed of the turbomolecular pumps, a change in the compression ratio causes a change in the component ratio of the exhaust gas, making it impossible to control the partial pressure of water independently.
In a method for manufacturing a protective layer according to the present invention, when the protective layer is formed in a film-forming chamber, the partial pressure of water in the film-forming chamber is controlled by the exhaust velocity of the water in the film-forming chamber, with the total pressure in the film-forming chamber kept constant.
This method allows the protective layer, which is susceptible to the partial pressure of water to be always formed under the same conditions. As a result, the protective layer having excellent properties can be formed in a stable manner without being influenced by outside humidity, the moisture adhering to a substrate jig, or the like.
A method and apparatus for manufacturing a protective layer according to an embodiment of the present invention is described as follows with reference to drawings.
The protective layer manufactured using the method and apparatus for manufacturing a protective layer according to the present invention is useful to protect the dielectric layer of a PDP. Therefore, first, a PDP in which the protective layer is used is described as follows.
Back panel 200 includes back glass substrate 16; M address electrodes 17; base dielectric layer 18; barrier ribs 19; and phosphor layers 20. M address electrodes 17 are formed on a main surface of back glass substrate 16. Base dielectric layer 18 coats address electrodes 17. Barrier ribs 19 are formed between address electrodes 17 on base dielectric layer 18. Phosphor layers 20 are applied between barrier ribs 19.
Front panel 100 and back panel 200 are oppositely disposed to each other so as to make display electrode pairs 12 and address electrodes 17 at right angles to each other with barrier ribs 19 therebetween. The image display region is sealed at its periphery with a sealing member. Front panel 100 and back panel 200 have discharge space 21 therebetween filled with a discharge gas such as a mixture of neon (Ne) and xenon (Xe) at a pressure of 45 to 80 kPa. The intersections of display electrode pairs 12 and address electrodes 17 function as discharge cells.
The following is a description of the manufacture of protective layer 14 of front panel 100 using the method and apparatus for manufacturing a protective layer according to the embodiment of the present invention.
The apparatus for manufacturing a protective layer shown in
Film-forming chamber 32 includes evaporation hearths 41 each with evaporation material 40 inside and electron guns 42, and is connected to a plurality of exhaust pumps 43 which are a first exhaust part to evacuate the chamber to high vacuum. Also, substrate preheating chamber 31 and substrate cooling chamber 33 each include exhaust pumps (unillustrated) to depressurize these chambers. Film-forming chamber 32 further includes gas analyzer 49 such as a quadrupole mass analyzer (QMS), which is a partial pressure measuring part to measure the partial pressures of various gases during the film formation. Film-forming chamber 32 further includes gas inlets 47, which are a gas inlet part to introduce at least oxygen thereinto.
In film-forming chamber 32, exhaust pumps 43 as the first exhaust part bring film-forming chamber 32 to high vacuum, and the electron beams emitted from electron guns 42 heat evaporation materials 40. The resulting vapor is deposited on front glass substrate 11 so as to form a magnesium oxide (MgO) film. Film-forming chamber 32 is provided with shutters 46 below front glass substrate 11 so as to control the scope of the vapor to front glass substrate 11.
As shown in
Next, the process of forming a magnesium oxide (MgO) film as protective layer 14 of the PDP is described as follows. First, front panel 100 that is finished up to dielectric layer 13 is placed on tray 48 and transferred into substrate receiving chamber 30. Front panel 100 is then transferred into substrate preheating chamber 31 and heated there by a heater while being evacuated to vacuum. Then, front panel 100 is transferred into film-forming chamber 32 in the direction of arrow “A”. In film-forming chamber 32, while front panel 100 is being transferred at a constant speed, protective layer 14 is formed on dielectric layer 13. When the formation of protective layer 14 is over, front panel 100 is transferred with tray 48 into substrate cooling chamber 33, cooled to a predetermined temperature under vacuum, and then transferred into substrate removing chamber 34 so as to be removed there, thereby completing the series of operations.
In film-forming chamber 32, electron beams 44 emitted from electron guns 42 are deflected and focused onto a plurality of impingment points 45 so as to be irradiated to evaporation materials 40 of MgO particle aggregates on evaporation hearths 41. As a result, evaporation materials 40 are heated and evaporated so as to deposit a magnesium oxide (MgO) film as protective layer 14 on dielectric layer 13 of front panel 100 traveling above it. Evaporation hearths 41 slowly rotate so that evaporation materials 40 can be evenly heated by electron beams 44, thereby preventing the local evaporation of the material.
The magnesium oxide (MgO) film as protective layer 14 thus formed changes physical properties due to oxygen deficiency or impurity incorporation during its formation. The physical properties have been found to be susceptible to water in film-forming chamber 32 and to hydrogen dissociated from the water. For example, when the magnesium oxide (MgO) film has an oxygen deficiency or impurities such as H, OH, or C incorporated therein, it disrupts the bonds between Mg atoms and O atoms on the magnesium oxide (MgO) film surface. This results in a dangling bond not involved in the bonds, thereby degrading the secondary emission characteristics. The degradation of the secondary emission characteristics increases a starting voltage and variations in the electron emission characteristics in the plane of the PDP panel, thereby causing variations in display or display defects in the plane of the PDP panel. Such a display quality of PDPs that is susceptible to changes in film properties is a serious issue as well as an increase in screen size and an improvement in definition of PDPs.
The water that greatly affects the properties of the MgO film seems to be the water absorbed in the magnesium oxide (MgO) film pieces adhering to tray 48 transferred into film-forming chamber 32 together with front panel 100. In order to reduce the water, different trays 48 are used between atmosphere and vacuum as described earlier, or tray 48 is made to pass through an atmosphere in a dry environment with a low a dew point. However, these measures are not enough to completely prevent the water from being brought into film-forming chamber 32.
In the embodiment of the present invention, film-forming chamber 32 uses turbomolecular pumps as main exhaust pumps 43. As shown in
On the other hand,
Consequently, this method allows the partial pressure of water during the film formation to be in a certain range.
The gases in film-forming chamber 32 are analyzed by gas analyzer 49. The ratio of the partial pressure of hydrogen to the partial pressure of oxygen can be kept constant by changing the cooling temperature of cryotrap 51 with the total pressure kept constant. For example, the cooling temperature of cryotrap 51 can be set to a relatively high temperature at first and then lowered with an increase in the amount of water brought into film-forming chamber 32 by the magnesium oxide (MgO) film pieces adhering to tray 48 or the like. This allows the partial pressure of the water in film-forming chamber 32 to be kept in a certain range with the total pressure kept constant. A typical cryotrap 51 does not have a function of performing high-precision temperature control. For this reason, cryotrap 51 used in the present invention is provided on its surface with at least one thermocouple as temperature controller 54. Cryotrap 51 controls the performance of freezer 53 while monitoring the temperature measured by the thermocouple.
The following method is sometimes used to keep the ratio of the partial pressure of hydrogen to the partial pressure of oxygen in film-forming chamber 32 in a certain range. During the film formation, oxygen is introduced into film-forming chamber 32 from gas inlets 47 as a gas inlet part so as to control the internal atmosphere. This is done because of the following reason. When the partial pressure of water increases, even if the introduction amount of oxygen is changed while varying the exhaust velocity by changing the opening of the valve or by other methods, it is difficult to keep the ratio of the partial pressures of hydrogen to oxygen in a certain range. This is due to the difference in the exhaust velocity of various gases.
However, as described above, according to the embodiment of the present invention, the partial pressures of water, oxygen, and hydrogen can be kept in a certain range by the following method, with the total pressure in film-forming chamber 32 kept constant. The principle of the method is to control the following three parameters based on the partial pressure information detected by the quadrupole mass analyzer (QMS) of gas analyzer 49. The three parameters are the introduction amount of oxygen from gas inlets 47; the amount of exhaust from exhaust pumps 43; and the amount of exhaust of cryotrap 51 which discharges water independent of exhaust pumps 43.
The configuration of the apparatus for manufacturing a protective layer is not limited to the one described above. For example, it is possible to dispose more than one substrate preheating chamber 31 between substrate receiving chamber 30 and film-forming chamber 32 depending on the setting conditions for the temperature profiles. It is also possible to dispose more than one substrate cooling chamber 33 between film-forming chamber 32 and substrate removing chamber 34. The formation of the magnesium oxide (MgO) film in film-forming chamber 32 can be performed with the front panel 100 either still or moving.
The numbers of evaporation hearths 41, electron guns 42, and exhaust pumps 43 placed in film-forming chamber 32 are dependent on the transfer speed of the substrate and the size of front panel 100, and therefore can be different from the numbers shown in
In the aforementioned description, protective layer 14 is formed by depositing a magnesium oxide (MgO) film.
Alternatively, besides magnesium oxide (MgO), other metal oxides such as a calcium oxide (CaO) or a strontium oxide (SrO) can be used to obtain the same advantages of the present invention.
The method and apparatus according to the present invention allows a protective layer or the like to be formed with the partial pressure of water kept constant and always under the same conditions. Therefore, the present invention is useful as a method and apparatus for manufacturing not only a protective layer for PDPs but also an electronic component or a display device.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2005-266557 | Sep 2005 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP06/17966 | 9/11/2006 | WO | 4/30/2007 |
