The invention relates generally to the field of generating reactive gas containing ions, free radicals, atoms and molecules and to apparatus for and methods of providing power for igniting a plasma in a reactive gas generator.
Plasma discharges can be used to excite gases to produce reactive gas containing ions, free radicals, atoms and molecules. Reactive gases are used for numerous industrial and scientific applications including processing solid materials such as semiconductor wafers, powders, and other gases.
One example of a reactive gas is atomic fluorine, which can be used to clean chemical vapor deposition (CVD) chambers for deposition of thin films onto substrate surfaces. CVD chambers need to be routinely cleaned to remove the deposits that build up on the surfaces of chamber parts other than the substrate surfaces. Wet cleaning of a chamber is labor intensive and hazardous to workers, while cleaning the chamber with atomic fluorine generated by a plasma source allows the deposits to be removed without opening the chamber to atmosphere, improving tool productivity and working conditions. Typical source gases for atomic fluorine include perfluorocompounds (PFCs) such as NF3, CF4, CHF3, C2F6, and C4F8.
Another example of a reactive gas is atomic oxygen, which can be used for photoresist removal in microelectronics fabrication. After pattern generation, photoresist is removed by exposing the wafer surface to atomic oxygen generated by a plasma source. Atomic oxygen reacts rapidly and selectively with photoresist, allowing the process to be conducted in a vacuum and at relatively low temperature.
Plasma can be generated through inductive coupling of energy from a power supply into a gas that is capable of being transformed into a plasma. Known techniques for providing power to ignite and sustain a plasma include circuitry to prevent damage to power supply semiconductor devices upon plasma ignition. However, such techniques are generally costly and are not reliable.
The invention features methods and power supplies that provide power to ignite and sustain a plasma in a reactive gas generator. Advantages of particular embodiments include prevention of damage to power supply semiconductor devices at reduced cost and increased reliability and performance.
According to a first aspect of the invention, a power supply and a method of providing power for igniting a plasma in a reactive gas generator is provided that includes (i) coupling a series resonant circuit that comprises a resonant inductor and a resonant capacitor between a switching power source and a transformer having a transformer primary and a plasma secondary; (ii) providing a substantially resonant AC voltage from the resonant capacitor across the transformer primary, thereby inducing a substantially resonant current within the transformer primary to generate the plasma secondary; and (iii) upon generation of the plasma secondary, the resonant inductor limiting current flowing to the switching power supply.
Particular embodiments can further include providing a first AC voltage from the switching power source across the series resonant circuit, the first AC voltage having a frequency at a substantially resonant frequency of the series resonant circuit; in response to the first AC voltage, providing the substantially resonant AC voltage from the resonant capacitor across the transformer primary, thereby inducing the substantially resonant current within the transformer primary to generate the plasma secondary; and modulating the frequency of the first AC voltage from the switching power source to a frequency greater than the substantially resonant frequency of the series resonant circuit to further limit the current flowing to the switching power supply subsequent to generation of the plasma secondary.
Particular embodiments can include providing the series resonant circuit with one or more resonant inductors in series with the resonant capacitor, the resonant capacitor coupled in parallel to the transformer primary; and limiting the current flowing to the switching power supply through the one or more inductors upon generation of the plasma secondary. In such embodiments, the method can include providing a first AC voltage from the switching power source across the series resonant circuit, the first AC voltage having a frequency at a substantially resonant frequency of the series resonant circuit; in response to the first AC voltage, providing the substantially resonant AC voltage from the resonant capacitor across the transformer primary, thereby inducing the substantially resonant current within the transformer primary to generate the plasma secondary; and modulating the frequency of the first AC voltage from the switching power source to a frequency greater than the substantially resonant frequency of the series resonant circuit to further limit the current flowing through the one or more inductors to the switching power supply subsequent to generation of the plasma secondary.
Particular embodiments can also include providing the series resonant circuit further including a second capacitor being coupled in series between the one or more resonant inductors and the resonant capacitor or between the resonant capacitor and the transformer, the second capacitor being a DC blocking capacitor or a second resonant capacitor.
Particular embodiments can further include the steps of providing a plasma chamber for containing the plasma secondary; coupling flux from the transformer primary to the plasma secondary through a magnetic core surrounding a portion of the plasma chamber and the transformer primary; and flowing an inlet gas through the plasma secondary to convert the inlet gas into a reactive gas.
According to a second aspect of the invention, a power supply and a method of providing power for igniting a plasma in a reactive gas generator are provided that include (i) providing a transformer having a transformer primary, the transformer primary having a center tap or a substantially center tap; (ii) grounding the center tap of the transformer primary to provide a first lead and a second lead of the transformer primary; (iii) coupling the first lead to a first ignition electrode positioned at a first location about a plasma body and coupling the second lead to a second ignition electrode opposing the first ignition electrode at a second location about the plasma body; and (iv) applying a voltage of a first polarity to the first lead and a voltage of a second polarity to the second lead, resulting in electric field flux traversing a cross sectional area between the first and second electrode to generate the plasma body.
Particular embodiments can further include (v) providing a plasma chamber for containing the plasma secondary; (vi) coupling the first lead to the first ignition electrode on an outer surface of the plasma chamber and coupling the second lead to the second ignition electrode on the outer surface of the plasma chamber opposing the first ignition electrode; and (vii) applying the voltage of the first polarity to the first lead and the voltage of the second polarity to the second lead, resulting in electric field flux traversing a cross sectional area of the plasma chamber between the first and second electrode to generate the plasma body.
The foregoing and other objects, features and advantages of the invention will be apparent from the following more particular description of preferred embodiments of the invention, as illustrated in the accompanying drawings in which like reference characters refer to the same parts throughout the different views. The drawings are not necessarily to scale, emphasis instead being placed upon illustrating the principles of the invention.
The invention features methods and power supplies that provide power to ignite and sustain a plasma in a reactive gas generator. Advantages of particular embodiments include prevention of damage to power supply semiconductor devices at reduced cost and increased reliability and performance.
In order to ignite the plasma, the power supply 10 includes a transformer 30. The transformer primary includes a primary winding 32 wrapped about a portion of a magnetic core 34. Energy from the power supply 10 is inductively coupled via the transformer primary to the gas traveling through the chamber 20 to ignite, or generate, the plasma. The ignited plasma within the plasma chamber 20 serves as the transformer secondary. Specifically, the power supply 10 applies an excitation voltage of high magnitude across the primary winding 32 of the transformer. This high excitation voltage induces high voltage current in the winding 32, thereby generating an alternating magnetic field through the magnetic core 34 across a path of the gas. As a result, current is induced within the gas, causing its ignition into a plasma. Once the plasma is generated, the plasma can be used to excite other source gas, producing the desired reactive gas for specific applications.
Prior to plasma ignition, the inductance of primary winding 32 in
In order to limit the high circuit current after plasma ignition, the circuit of FIG. 2A includes a controllable relay 56 bridged across the resonant capacitor 54. In operation, the relay 56 is open during ignition of the plasma to couple the resonant capacitor 54 to the circuit and closed after plasma ignition to decouple the capacitor 54 from the circuit. By decoupling the capacitor 54 from the circuit, the resonant voltage VRES drops to the source excitation voltage Vs across the primary winding 32 resulting in a reduction in the current induced in the primary winding and the current flowing back to the power source 60. Also, the load is no longer capacitive, since the relay removes the capacitor from the active circuit. Thus, the likelihood of semiconductor damage within with switching power source is reduced.
Disadvantages of this power supply configuration, however, include the high cost associated with the circuit due to the need for the relay 56 and the time delays or potential failures of the relay 56 and plasma ignition detection circuitry (not shown). If detection of plasma ignition fails or is delayed, short circuit current IRES+ can return to the power source causing damage. This circuit requires very fast response of the electronics to avoid destructive damage to the power semiconductors providing the excitation voltage.
With respect to
By controlling the frequency of the source excitation voltage, this circuit can control the current through the primary winding 32 without the need for a relay. However, like the circuit of
The present invention features methods and power supplies that provide power to ignite and sustain a plasma in a reactive gas generator. Advantages of particular embodiments include prevention of damage to power supply semiconductor devices at reduced cost and increased reliability and performance.
In operation, the switching power source 60 can be a half bridge or full bridge power converter as known in the art or as described in U.S. patent application Ser. No. 11/077,555, entitled “Control Circuit for Switching Power Supply,” the entire contents of which are incorporated herein by reference. The power source 60 provides an AC excitation voltage Vs having a frequency at or substantially at the resonant frequency of the series resonant circuit. In one embodiment, the frequency of the excitation voltage is above the resonant frequency of the resonating inductance and capacitance. For higher current and power, the frequency is closer to the resonance. For lower current and power, the frequency is farther from it. Typically, the frequency shifts by less than 50% of the resonant frequency over the required range. For a Q factor of 10 for the circuit with no ignition, the current shifts a small fraction (much less than 10%) of the maximum value. In practice, the commanded value of resonant current during ignition is preferably 1.5 to 3 times the value needed for steady state plasma operation.
The excitation voltage Vs is applied across the series resonant circuit 100, causing the resonant circuit to provide a substantially resonant AC voltage VRES across the transformer primary, inducing a substantially resonant current IRES within the transformer primary to ignite the plasma.
The generated plasma 36 serves as the secondary of transformer 30. The plasma secondary can be represented with an equivalent circuit having an inductance L and a reactance Z. However, it should be understood that the plasma secondary 36 is actually a body of plasma traversing a volume within a plasma chamber. The plasma chamber 20 can be manufactured in the shape of a toroid or other shapes that provide a toroidal flow of the gas.
Once the plasma ignites, a short circuit current does not flow to the switching power source 60. Rather, although the inductance of the primary winding 32 of the transformer 30 is reduced after plasma ignition, the resonant inductor 110 of the series resonant circuit 100 continues to serve as a low pass filter limiting current through the primary winding 32 to a safe operating level for return to the switching power supply 60. Also, the effect of the reduced plasma impedance reflected through the transformer across the capacitor 120 results in an inductive load, avoiding the stressful hard transitions. Thus, damage to the constituent semiconductor devices in the power source 60 due to high current is substantially prevented. Advantages of this embodiment include reduced cost due to the lack of a relay component and increased reliability due to the circuit's ability to limit current regardless of whether plasma ignition is detected.
According to another embodiment, the power supplies of
For example, once the gas ignites into a plasma, the inductance of the transformer is reduced driving additional current through the primary winding. This condition is detected by a current sensor at points A or B which feeds back to the controller 140 to shift the frequency away from the resonant frequency to a frequency for maintenance of the plasma flow and safe operation of the power supply. The frequency is increased, reducing the amount of current by the action of the resonant inductors. This provides a means of regulating the current or power flow by sensing this parameter anywhere in the circuit and adjusting the frequency to achieve the desired level of excitation of the gas. Alternately or in conjunction with frequency modulation, pulse width modulation (PWM) can be used to adjust the duty cycle of the switching power source to achieve a broader dynamic range of regulation. According to a particular embodiment, low output current can be regulated with pulse width modulation (PWM) while power can be regulated with pulse frequency modulation (PFM), or vice versa. This combined use of PFM and PWM results in a broader dynamic range of regulation for the entire power conversion system. Another advantage of the combined use of PFM and PWM is reduced reverse recovery stress on the body diode of MOSFETs in the switching power source at low current or power, as opposed to regulating with PFM alone in which the modulating frequencies must approach the Megahertz range.
According to another aspect of the invention, bipolar high voltage ignition electrodes can be used in conjunction with inductive energy coupling to aid in plasma ignition. Preferably, the ignition electrodes are arranged in or about the plasma chamber for capacitively coupling energy to the gas flowing within the chamber to ignite and sustain a plasma. The voltages impressed upon the ignition electrodes to ignite and sustain a plasma are typically controlled by a high voltage ignition controller. Once the plasma is generated, the energy coupled through inductance, as previously described in
When the high voltage ignition controller 200 directs the relay 220 to connect the ignition electrodes, the voltage at the second lead 210b is applied to both electrodes 230, generating a spatially limited electric field between ignition electrodes 230 and ground electrodes 240 as shown. This limited electric field, or fringe field, can fail to ignite a plasma under certain gas flow and pressure conditions within the chamber, or can fail to propagate the ignition into the bulk of the plasma. Thus, in those instances, a stronger electric field is required in order to ignite the plasma. Prior art techniques involve higher voltages being applied to the ignition electrodes 230 to generate the requisite electric flux, resulting in increased insulation and its related cost.
A second aspect of the invention addresses this issue through the use of a central ground tap that is connected to the secondary primary winding. The use of a central ground tap results in the leads that extend from the secondary primary winding being bipolar and, thus, enables the generation of positive ignition electrodes and negative ignition electrodes. By placing the positive and negative ignition electrodes such that they oppose one another, an increase in the amount of electric flux that can be realized across the plasma chamber or channel. This results in less voltage to ground being required to generate the requisite amount of electric flux to ignite the plasma gas.
For example, when the power supply 10 provides an excitation voltage across the primary winding 32, a current is induced within the secondary primary winding 310, such that a negative polarity voltage −V can be applied to the first lead 310a and a positive polarity voltage +V can be applied to the second lead 310b. Both the first lead 310a and the second lead 310b are switchably connected to a respective ignition electrode 330a, 330b through relays 320a, 320b, if this is desired for example to extend electrode life.
In this illustrated embodiment, the first lead 310a is coupled to the first ignition electrode 330a on an outer surface of the plasma chamber 350 and the second lead 310b is coupled to the second ignition electrode 330b on the outer surface of the plasma chamber 350 opposing the first ignition electrode 330a. Ground electrodes 240a, 240b can also be positioned on opposing sides of the plasma chamber or channel 300 at an offset between the ignition electrodes 330a, 330b.
During plasma ignition, the relays 320a, 320b of the controller 300 are closed so that the positive voltage of the first lead 310a and the negative voltage of the second lead 310b are applied to the respective ignition electrodes 330a, 330b, resulting in a strong electric field flux traversing a cross sectional area of the plasma chamber or channel 350 between the first and second electrodes to generate the plasma secondary. Once the plasma ignites, the relays 320a, 320b can be opened, disabling the capacitive discharge.
Although embodiments of the invention have been described with respect to exemplary circuit diagrams, the invention is not so limited. Furthermore, other embodiments of the invention may include alternative implementation details, including the use of hybrid circuits, discrete circuits, MOSFETs, IGBTs and others known to those skilled in the art.
While this invention has been particularly shown and described with references to preferred embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the scope of the invention encompassed by the appended claims.
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