This application claims the benefit of German Patent Application No. 103 27 613.0, filed on Jun. 18, 2003, which application is hereby incorporated herein by reference.
The invention relates to a method for forming a preferably square opening on an alternating phase shift mask, the opening having two subregions, which apply a different phase shift to a light beam which is incident on them.
The invention relates in particular to a method for producing square openings on alternating phase shift masks, which can be used to pattern contact holes on semiconductor wafers in a lithographic projection step. The invention relates also, inter alia, to the formation of rim-type phase shift masks.
The lithographic patterning of contact hole levels to fabricate integrated circuits represents one of the major requirements involved in optical lithography. By way of example, in the case of memory products, contact connections for memory cells are to be produced on a very small surface area with a high positional accuracy and particularly small feature sizes. Within the memory cell arrays, the contact-hole openings that are to be formed in a layer on the wafer for this purpose take the form of a dense, regular grid, whereas, for example in the peripheral regions of a memory module, semi-isolated or fully isolated contact holes are to be formed in at times irregular arrangements.
Imaging errors, which may be caused, for example, by inaccuracies in the lens system, the lens aberration, lead to the imaging performance often differing with dense and isolated arrangements of contact-hole openings of very small feature sizes, which are formed jointly on a mask. In individual cases, for a given density of openings the projection system can be successfully adapted to the prevailing conditions, but imaging of isolated and dense structures at the same time results in a reduction in the size of what is known as the process window, in particular the depth of focus.
This particularly affects the imaging of the isolated contact-hole openings, especially since the settings of the projection system are often matched to the extremely critical contact-hole openings within dense arrays on the mask.
A solution has been discovered involving the use of attenuated phase shift masks for the imaging of contact-hole levels. The phase difference which is present as a result in each case at the transition from transparent regions to substantially opaque regions on the mask in this case advantageously increases the imaging contrast and therefore approximates the imaging behavior of dense contact-hole openings to that of isolated or semi-isolated contact-hole openings.
However, if attenuated phase shift masks are used, the problem arises whereby higher-order lens aberrations, such as for example the three-leaf clover effect, can lead to undesirable secondary effects.
Moreover, the problem of what is known as side lobe printing should be mentioned in this context, which problem can give rise to structure-forming secondary maxima in the image plane in the immediate vicinity of a structure, which is actually to be imaged.
Therefore, there has been a move toward the use of chromium-free or alternating phase shift masks to form contact holes. The contrast amplification at the edge of a contact hole is in this case effected by a narrow rim-like, phase-shifting region at the edge of the contact-hole opening. The basic principle is known from rim-type phase masks.
The width of the rim-like, phase-shifting region is matched, during the formation of the contact hole, to the result, which is to be achieved on the wafer during the imaging. This result in turn depends on the specific conditions (numerical aperture, exposure wavelength, resist properties, etc.) in the exposure apparatus used for the wafer exposure. Conventional methods provide for the rim to be formed with the aid of a mask writer. The minimum width of rim, which can be achieved is therefore dependent on the resolution limit of the mask writer.
In one aspect, the present invention allows the production of contact-hole levels by means of alternating phase shift masks, wherein the differently phase-shifting subregions on the mask can be formed within an opening with a high degree of dimensional accuracy and preferably in sublithographic dimensions.
The preferred embodiment provides a method for forming a preferably square opening on an alternating phase shift mask, the opening having two subregions, which apply a different phase shift to a light beam which is incident on them, comprising the steps of providing a transparent substrate having a surface, an opaque layer arranged on the surface and at least a second layer, which is arranged on the opaque layer and in an etching process has a selective property with respect to the opaque layer in order to form an etching mask, forming an opening in the second layer, etching so as to transfer the opening into the opaque layer so that a first subregion on the surface of the transparent substrate is uncovered, further etching to transfer the opening from the opaque layer into the substrate down to a predetermined depth, which represents the difference in the phase shift, widening the opening in the second layer, etching so as to transfer the widened opening in the second layer into the opaque layer so that a second subregion, which adjoins the recess formed by the first subregion on the surface of the transparent substrate is uncovered, removing the second layer.
According to the preferred embodiment of the invention, the use of what is known as the spacer technique or an isotropic etching step makes it possible to produce a rim-like edge region in an opening on a mask, which is intended, for example, to form contact holes. By means of these techniques, an opening, which has already been formed in advance for the purpose of a first etching operation into a layer below, (e.g. quartz substrate and/or chromium) is widened in a controlled manner for a subsequent etching operation. The widening involves increasing the size of the opening in directions parallel to the layer planes on the mask. The length of the widening corresponds to the width of the rim, which is subsequently etched.
The second layer, which is arranged on the opaque layer, may be a resist layer or a layer of another material, which has a high etching selectivity with respect to the material of the opaque layer. The opaque layer preferably comprises chromium.
If the second layer is not a resist layer, it may in particular be a layer comprising silicon nitride, which has a sufficient etching selectivity with respect to the chromium of the opaque layer and with respect to the quartz. A resist layer, which can be used for lithographic patterning of the second layer, is once again to be provided on an etching-selective layer of this type.
The subregions of the opening to be produced that are to be uncovered in, or even etched into the substrate are defined by patterning of this second layer with subsequent transferal of the pattern into the opaque layer and—optionally—into the substrate. Therefore, the size of the subregions is in particular not defined in the chromium layer, as is the case in the prior art. It is preferable for only transferring, anisotropic etching steps to be carried out on the chromium layer.
The first subregion, which represents a recess to be etched into the quartz substrate, may, for example, be defined by means of a mask writer (e.g. electron beam or laser writer) in a resist layer, as second layer, arranged on the opaque layer. Alternatively, the region may also be exposed in a further resist layer arranged as oxide layer on the second layer and then transferred into the second layer in an etching step.
One significant step in the preferred embodiment of the invention involves widening the opening. Widening is achieved either by isotropic etching of the second layer or by removal of a spacer which was previously formed inside the edge of the opening in the second layer. In both cases, the diameter of the opening, as was present at the instant of a first etching step into the opaque layer, is subsequently increased. The variant involving forming and subsequently removing the spacer offers the particular advantage that the spacer material can be removed selectively over the material of the second layer, so that a steep edge profile without major degradation of the second layer is ensured. In the case of the isotropic etch, by contrast, it should be borne in mind that the second layer is also thinned at the same time, and consequently under unfavorable circumstances the border at the edge of the opening may also be degraded.
The widened opening offers the advantage that the uncovered opaque layer beneath it can then be removed in a dimensionally stable manner in an anisotropic etching step, with the result that this substrate surface is likewise uncovered by the corresponding etching step. The opening has then been formed in the second layer and in the opaque layer, and has as its basic area a central, recessed subregion and a rim-like, superficial subregion in the substrate. The difference in depth in the substrate corresponds to the desired phase difference, which is usually 180°.
The invention offers the particular advantage that both the spacer thickness and the removal of material in the isotropic etching operation can be controlled accurately in the respective deposition or etching process. However, both variables produce precisely the width of the rim, which is formed around the recess of the first subregion (or according to an advantageous configuration as an elevated region around a recess in the substrate). However, in this case in particular, deposition thicknesses or etching depths can be defined so accurately in their processes that it is even possible to achieve sublithographic structures with the aid of the spacer or etching technique.
It is therefore, possible to provide openings on masks for the production of contact holes with rim-like, phase-shifted edge regions, the width of which is less than the resolution limit defined by the respective lithographic exposure system used, i.e., the mask writer.
One particular advantage of the method consists in relaxing the required resolution of the mask writer by precisely double the width of the rim. Therefore, the mask writer only has to define the area of the first subregion.
According to a further aspect of the present invention, there is provision for the recessed subregion and the superficial subregion to be formed in an inverted arrangement, i.e., for the opening to be formed firstly as a rim in the second layer, then transferred into the opaque layer and into the quartz substrate. Only afterward is the material introduced retrospectively into the rim, as well as the opaque layer beneath it, removed in the region of the second layer within the region, which has been opened up in the form of a rim, so that a central, superficial region is uncovered on the substrate. This aspect is described in more detail in an exemplary embodiment.
According to this aspect too, the narrow, preferably sublithographic rim is formed using spacer technology, so that it is possible to achieve sublithographic dimensions for the width. However, the spacers are in this case not removed in order to widen the opening, but rather—as described—the opening inside the spacer is filled with a further filling material. Only then are the spacers removed, so as to uncover the rim of the opening.
The invention is now to be explained in more detail on the basis of an exemplary embodiment and with the aid of a drawing, in which:
a-4f show an exemplary embodiment relating to the production of the opening in accordance with the prior art;
a-5g show a first exemplary embodiment of the method according to the invention for producing the opening;
a-6f show a second exemplary embodiment of the method according to the invention for producing the opening; and
a-7h show a third exemplary embodiment of the method according to the invention for producing the opening using the spacer technique.
The making and using of the presently preferred embodiments are discussed in detail below. It should be appreciated, however, that the present invention provides many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed are merely illustrative of specific ways to make and use the invention, and do not limit the scope of the invention.
One example of a square opening on the mask in order to form a contact hole on a wafer, which includes a phase-shifting region at the edge, is illustrated in
A cross-sectional profile on line AB indicated in
The lower part of
It can be seen from
A method which can be used to produce the described contact-hole opening on an alternating phase mask is known, for example, from Yanagishita, Y., Ishiwata, N., Tabata, Y., Nakagawa, K., and Shigematsu, K., “Phase-Shifting Photolithography applicable to real IC Patterns”, SPIE VOL. 1463 Optical/Laser Microlithography IV (1991)/207. The method steps given in that document are illustrated in simplified form in
a shows an alternating phase mask 1, comprising a substrate 18, on which an opaque layer 10, for example of chromium, is arranged. An opening 30 has already been formed in the opaque layer 10 during a lithographic patterning method.
Then, a photosensitive resist layer 22 is applied to the opaque layer 10 and into the opening 30, and back-surface floodlighting is carried out through the transparent substrate 18. The resist layer 22 on the front surface is not exposed in regions 23, on account of the shadowing action of the opaque layer 10, but is exposed in regions 24 inside and in front of the opening 30, as can be seen from
c shows the state after a developing step has been carried out, in which the exposed components 24 of the resist layer 22 have been removed.
d shows how a recess is etched into the substrate 18 using the unexposed but developed resist components 23 as an etching mask for a quartz etching step 60.
e shows the result of an isotropically executed etching process 70, which selectively removes the material of the opaque layer 10 in a direction parallel to the surface of the glass substrate 18.
A method of this type has drawbacks, in that the floodlighting from the back surface means that the resist 22 on the front surface of the mask may not be exposed in a dimensionally stable manner, on account of reflections. In particular, however, the drawback arises whereby the opaque layer 10 cannot be etched back very deeply during the step of isotropic etching of the opaque layer 10 from the layer stack between the substrate 18 and the resist 22 without the resist layer 22 with the overhangs which are formed becoming unstable and possibly breaking off. Therefore, the cross-sectional profile of the opaque layer 10 cannot be controlled very successfully in a process sequence of this type.
A method for producing an opening in accordance with the present invention will now be discussed with respect to
Referring first to
b shows the state after exposure of part of the resist layer 34, developing of the exposed part and transferring of the opening defined in this way into the Si3N4 layer 32.
c shows how a further layer 36 has been deposited conformally in the opening and on the Si3N4 layer 32 after removal of the exposed but as yet undeveloped parts of the resist 34. The further layer 36 comprises a material, which has a high selectivity in an etching process both with respect to the Si3N4 layer 32 and with respect to the opaque layer 10, e.g, the chromium. This material may, for example, be a doped oxide such as BSG (borosilicate glass) or an equivalent material.
The structure illustrated in
d shows how, after the further layer 36 has been etched back in an anisotropic etching process, all that remains of this layer is the spacers 38 comprising the BSG material at the edge of the opening.
As shown in
f shows the state after removal of the spacer 38, for example in a selective etching process with respect to the material of the opaque layer 10 (chromium) and of the second layer 32 (BSG). The etching process may be isotropic or anisotropic. On account of this removal of the spacers 38, the opening is widened again. At the height of the second layer 32, the opening now has a larger diameter than the diameter of the opening in the opaque layer 10.
In a further anisotropic etching step 46, the widened opening is transferred into the chromium layer or opaque layer 10 until the surface of the substrate 18 is reached. The second layer 32 is then removed (
A second exemplary embodiment is illustrated in
After the isotropic etching step, which on the Si3N4 layer 32 is carried out selectively with respect to the opaque layer 10 and the glass substrate 18, has been implemented. The Si3N4 layer 32 firstly loses thickness, and secondly the opening formed therein is widened further, since the edge of the opening, in the etching step 48, is displaced back in the horizontal direction, i.e., parallel to the layer surfaces on the mask 1.
As shown in
The spacer technique is once again to be employed in this exemplary embodiment. Therefore, analogously to the process steps illustrated in
As illustrated in
The latter offers benefits in particular if the opaque layer comprises chromium. In this case, the person skilled in the art will naturally also consider the alternative option of forming a chromium layer 39 which is particularly thick compared to the chromium layer 10 (with the same thickness as the Si3N4 layer) as filler material 39, with the result that the chromium layer 10 is only removed beneath the position of what previously formed the spacers.
The surface is planarized back in order for the Si3N4 layer 32 and the spacers 38 to be uncovered again. The material of the spacer 38 is then etched out selectively, and the material of the Si3N4 layer 32 and the filler material 39 comprising chromium are used as etching mask for an anisotropic etching process 47 into the opaque layer 10, as illustrated in
g shows the continuation of the anisotropic etching step into the quartz substrate. As a result, a rim-like, first subregion 12 is formed in the glass substrate.
h shows the state after removal of the filler material 39, so that the opening is then widened inward in order, after an etching step 46 has been carried out, for removal of the opaque layer 10 on the surface of the substrate 18 inside the opening. The substrate surface, which is then uncovered, defines the second subregion 14, which has a phase shift difference of 180° with respect to the etched-in, narrow, rim-like subregions 12 when light is radiated onto them. To emphasize that the subregions 12 and 14 have been swapped over compared to the previous examples, in this case reference symbols A′ and B′ have been employed. They correspond to a
Which of the two subregions is etched into the quartz and which merely superficially uncovers the substrate 18 is of only subordinate importance to the imaged intensity profile as shown in
Although the present invention and its advantages have been described in detail, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the invention as defined by the appended claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 103 27 613.0 | Jun 2003 | DE | national |