Claims
- 1. A method for non-intrusively identifying a target material enclosed within a container, comprising the steps of:measuring a total path length for a beam of radiation transmitted through the container enclosing the target material, along a selected, essentially linear transmission path, such that the measured total path length is approximately equal to an unknown path length of the beam through the container plus an unknown path length of the beam through the enclosed target material, referred to as the total path length relationship; transmitting a first beam of mono-energetic gamma radiation having a first energy through the container and target material along the selected transmission path, and measuring a first count rate of uncollided, unscattered gamma radiation transmitted through the container and target material, with an on-axis detector aligned with the selected transmission path; transmitting a second beam of mono-energetic radiation having a second energy through the container and target material along the selected transmission path, and measuring a second count rate of uncollided, unscattered gamma radiation transmitted through the container and target material, with the on-axis detector aligned with the transmission path; applying an algorithm to determine an estimated first relative and an estimated second relative linear attenuation coefficient for the chemical agent exposed to the first and second gamma radiation energies respectively and calculating a ratio of the first estimated relative linear attenuation coefficient to the second estimated relative linear attenuation coefficient; and identifying the target material by comparing the calculated ratio with a known linear relative attenuation ratio unique to candidate target materials and thus, determining the candidate target material.
- 2. The method according to claim 1, wherein the beam of radiation is a gamma-ray beam, the uncollided radiation particles are photons, and the parameter is a gamma-ray linear attenuation coefficient.
- 3. The method according to claim 1, wherein the algorithm rules for determining the respective relative linear attenuation coefficients and formulating the identifying relative ratio, comprise the steps of:formulating a first expression which is a function of a calibration constant for a detection device at the first energy level and of a count rate at the first energy level; formulating a second expression which is a function of the calibration constant for the detector at the second energy level and of the count rate at the second energy level; determining a total path length; establishing a first energy linear attenuation coefficient for a metal casing enclosing a unknown compound at the first energy level and establishing a second energy linear attenuation coefficient for the metal casing at the second energy level; employing an second algorithm to determine a first relative linear coefficient at the first energy level and using the same second algorithm to determine a second relative linear coefficient at the second energy level; and formulating the identifying relative ratio as a ratio of the first relative linear coefficient to the second relative linear coefficient; comparing the calculated relative ratio to a set of known measured ratios to determine the encapsulated material.
- 4. The method according to claim 1, wherein the target material is a liquid.
- 5. The method according to claim 1, wherein the target material is a chemical agent selected from the group consisting of Agent GA described as Dimethylphosphoramidocyanidic acid, ethyl ester; Agent GB described as Methylphosphonofluoridic acid (1-methylethyl) ester; and Agent GD described as Methylphosphonofluoridic acid, 1,2,3-trimethylpropyl ester; Agent VX described as Methylphosphonothioic acid, S-[2-(diethylamino)ethyl]O-2-methylpropyl ester; Agent H described as 1,1′Thiobis[2-chloroethane]; Agent L described as (2-Chloroethenyl)arsonous dichloride; and Agent T bis(2(2-chloroethylthio)ethyl) ester.
- 6. The method according to claim 1, wherein the container is comprised of steel.
- 7. The method according to claim 1, wherein the beams of radiation have energies in the range of between about 100 keV and about 1000 keV.
- 8. The method according to claim 1, wherein the steps of applying the algorithm and identifying the contained target material include utilizing a computer program and a computer database of candidate target material parameter values.
- 9. The method of claim 1 where said first and said second count rate are measured using a a scintillation detector as said on-axis detector.
Government Interests
The United States Government has right in this invention pursuant to Contract Number DE-AC07-94ID13223 between the United States Government and Idaho National Environmental and Engineering Laboratory, as represented by Lockheed Martin Idaho Technologies Company.
US Referenced Citations (15)
Non-Patent Literature Citations (1)
Entry |
Presentation entitled, “A Neutron Transmission Measurement to Identify chemical Agent in Chemical Munitions”, given by John L. Morrison in Mar. 1998. |