The invention relates to a method for producing a pyrolysis compatible component for a cooking appliance, the cooking appliance being configured to carry out a pyrolysis operation, in which method a base element of the component is provided and coated. The invention also relates to a pyrolysis compatible component for a cooking appliance.
With cooking appliances such as ovens it is known to provide support frames for holding food holders such as grill pans, baking sheets or grill shelves in the cooking compartment. Pull-out apparatuses such as telescopic rails for example can also be provided, on which such food holders can be positioned. In ovens which allow a pyrolysis operation, very high temperatures prevail during said pyrolysis operation, acting on the components in the cooking compartment. Conventional components, which can be left in the cooking compartment during the pyrolysis operation are coated with enamel but these are very complex to produce and therefore also expensive. Also they lose their typical stainless steel appearance over time. Enameled components are also easily damaged by impact so the enamel coating can be chipped.
The object of the present invention is to create a method for producing a pyrolysis compatible component for a cooking appliance and such a component, with which less wear results in respect of effect during a pyrolysis operation.
This object is achieved by a method having the features as claimed in claim 1 and a component having the features as claimed in claim 12.
With an inventive method for producing a pyrolysis compatible component for a cooking appliance, which is configured to carry out a pyrolysis operation, a base element of the component is provided and coated. A silicon dioxide coating is generated on the base part by PECVD (plasma-enhanced chemical vapor deposition) deposition. Such a specific type of application of such a specific material coating means that the pyrolysis compatibility of the component is significantly improved. The robustness and wear resistance of such components in respect of effects during pyrolysis can be substantially increased. In particular such an embodiment allows the staining and heat discoloration that occur with conventional components to be prevented during pyrolysis. The metallic character of the component is also maintained.
In particular it is possible for such a pyrolysis compatible component to be coated without using enamel, thereby preventing the occurrence of chipping.
Provision is preferably made for the silicon dioxide coating to be generated by high-rate PECVD deposition, in which the coating is generated at a speed faster than 0.5 μm/min, in particular around 1 μm/min. Such a procedure is particularly advantageous as the silicon dioxide coating can be applied in a particularly solid and stable manner.
This coating method is particularly resource-efficient compared with enameling, as high stoving temperatures are not required.
Provision is preferably made for the silicon dioxide coating to be generated with a thickness smaller than or equal to 10 μm, in particular between 50 nm and 2000 nm Such a thin silicon dioxide coating on the in particular metallic base part is sufficient to be able to achieve the abovementioned advantages and improvements perfectly. It also allows an extremely material-efficient coating method to be achieved.
Provision is preferably made for a microwave-induced plasma to be generated at 2.45 GHz during PECVD deposition. This allows protection against heat discoloration and chemical attack by food residues on the component to be particularly advantageously achieved.
The silicon dioxide coating is preferably generated in the vacuum using the abovementioned microwave-induced plasma. The plasma thus generated excites the so-called precursor (for example hexamethyldisiloxane) so that a highly adhesive, pore-free coating, which is very dense compared with those produced using normal plasma procedures, is generated on the component.
Provision is preferably made for impurity atoms to be introduced into a coating structure encompassing the silicon dioxide coating. By varying the process parameters during deposition it is possible to incorporate these impurity atoms in the coating composite so that gradient coatings are generated. This for example allows compensation for different thermal expansion coefficients between the base part and the coating or variation of the surface energy of the coating.
Provision is preferably made for carbon and/or hydrogen to be introduced as the impurity atoms. This allows the abovementioned properties to be achieved in a particularly precise and permanent manner.
Provision is preferably made for the coating structure to be configured with a first coating which comprises silicon, oxygen, carbon and hydrogen, and for it to be configured as the coating next to the base part. This first coating is preferably a SiOxCyHz coating (where 0≦x,y,z≦2).
Provision is preferably made for the coating structure to be configured with a second coating which comprises silicon and carbon and is configured on the first coating, the concentration of carbon in the second coating being lower than in the first coating. A concentration gradient is therefore established in respect of the two coatings, with regard in particular to the carbon atoms and oxygen atoms. This can improve the abovementioned advantages with regard to the equalization of the thermal expansion coefficients or the variation of the surface energy.
It is also possible for the coating structure to be configured with a second coating which comprises silicon, oxygen, carbon and hydrogen and is configured on the first coating, the concentration of oxygen, carbon and hydrogen in the second coating being different from in the first coating. A concentration gradient is therefore established in respect of the two coatings, with regard in particular to the hydrogen atoms, carbon atoms and oxygen atoms. This can improve the abovementioned advantages with regard to the equalization of the thermal expansion coefficients or the variation of the surface energy.
Provision is preferably made for the silicon dioxide coating to be configured in the manner of a third coating on the second coating.
Such a coating structure is particularly expedient in respect of the abovementioned advantages and improvements.
Provision can be made for each of the three coatings of the coating structure to be configured with the same coating thickness. However provision can also be made for the three coatings to be generated with different coating thicknesses.
The base part is preferably configured from metal.
The invention also relates to a pyrolysis compatible component for a cooking appliance, having a base part that is coated. A silicon dioxide coating is configured as the coating, being applied by PECVD deposition, in particular by high-rate PECVD deposition, to the base part.
The component is preferably a grill shelf or food holder or a telescopic pull-out apparatus for holding a food holder. The food holder provided can be for example a grill shelf, baking sheet or grill pan. The support frame for holding a food holder can be configured for example from bars as a grill frame and can be inserted into and removed again from the cooking compartment reversibly in a non-destructive manner.
Provision is preferably made for a coating composite to be configured on the base part, comprising a first coating containing silicon, carbon, oxygen and hydrogen, on which a second coating containing silicon and carbon is configured, the concentration of carbon in the second coating being lower than in the first coating, and the silicon dioxide coating being configured outward on the second coating.
Provision is preferably made for a coating composite to be configured on the base part, comprising a first coating containing silicon, carbon, oxygen and hydrogen, on which a second coating containing silicon, oxygen, carbon and hydrogen is—optionally—configured, the concentration of oxygen, carbon and hydrogen in the second coating being different from in the first coating, and the silicon dioxide coating being configured outward on the second coating.
Exemplary embodiments of the invention are described in more detail below with reference to schematic drawings, in which:
Identical elements or those of identical function are shown with identical reference characters in the figures.
A sectional diagram through the bar 8 is shown in
The coatings 15 to 17 are also applied using a high-rate PECVD deposition procedure, the coatings being generated at a speed of up to around 6 μm/min (preferably 0.5-1μm/min) A microwave-induced plasma is generated at 2.45 GHz in the process. The silicon dioxide coating 17 is generated in the vacuum using said microwave-induced plasma.
1 Support frame
2, 3 Retaining bars
4, 5, 6, 7 Insertion guides
8, 9 Guide bars
10 Telescopic pull-out apparatus
11, 12 Rails
13 Base part
14 Outside
15, 16, 17 Coatings
Number | Date | Country | Kind |
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10 2010 063 887.0 | Dec 2010 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2011/073115 | 12/16/2011 | WO | 00 | 6/11/2013 |