Method for providing a continuous motion sequential lateral solidification for reducing or eliminating artifacts in edge regions, and a mask for facilitating such artifact reduction/elimination

Information

  • Patent Grant
  • 8476144
  • Patent Number
    8,476,144
  • Date Filed
    Friday, April 9, 2010
    14 years ago
  • Date Issued
    Tuesday, July 2, 2013
    10 years ago
Abstract
An arrangement, process and mask for implementing single-scan continuous motion sequential lateral solidification of a thin film provided on a sample such that artifacts formed at the edges of the beamlets irradiating the thin film are significantly reduced. According to this invention, the edge areas of the previously irradiated and resolidified areas which likely have artifacts provided therein are overlapped by the subsequent beamlets. In this manner, the edge areas of the previously resolidified irradiated areas and artifacts therein are completely melted throughout their thickness. At least the subsequent beamlets are shaped such that the grains of the previously irradiated and resolidified areas which border the edge areas melted by the subsequent beamlets grow into these resolidifying edges areas so as to substantially reduce or eliminate the artifacts.
Description
FIELD OF THE INVENTION

The present invention relates to a method, system and mask for processing a thin-film semiconductor material, and more particularly to forming large-grained, grain-shaped and grain-boundary-location controlled semiconductor thin films from amorphous or polycrystalline thin films on a substrate by continuous motion-scanning the entire sample or at least one portion thereof using a sequential lateral solidification technique so as to reduce or even eliminate artifacts, e.g., that may be formed in overlapped irradiated, melted and resolidifying regions of a sample or in the portion(s) thereof.


BACKGROUND INFORMATION

In the field of semiconductor processing, a number of techniques have been described to convert thin amorphous silicon films into polycrystalline films. For example, in James Im et al., “Crystalline Si Films for Integrated Active-Matrix Liquid-Crystal Displays,” 11 MRS Bulletin 39 (1996), an overview of conventional excimer laser annealing technology is described. In such conventional system, an excimer laser beam is shaped into a beam having an elongated cross-section which is typically up to 30 cm long and 500 micrometers or greater in width. The shaped beam is stepped over a sample of amorphous silicon (i.e., by translating the sample) to facilitate melting thereof and to effectuate the formation of grain-shape and grain boundary-controlled polycrystalline silicon upon the re-solidification of the sample. Such techniques has been referred to as sequential lateral solidification (“SLS”) of the melted portions of the sample to effectuate the growth of longer grain boundaries therein so as to achieve, e.g., uniformity among other thing.


Various techniques, processes, masks and samples have been previously described which utilize various SLS techniques, to effectively process the sample. For example, International Publication No. 02/086954 describes a method and system for providing a single-scan, continuous motion sequential lateral solidification of melted sections of the sample being irradiated by beam pulses. In this publication, an accelerated sequential lateral solidification of the polycrystalline thin film semiconductors provided on a simple and continuous motion translation of the semiconductor film are achieved, without the necessity of “microtranslating” the thin film, and re-irradiating the previously irradiated region in the direction which is the same as the direction of the initial irradiation of the thin film while the sample is being continuously translated.


One problem that may arise during SLS processing of a thin film provided on a sample is microstructural artifacts, e.g., grain misalignment. For example, these artifacts may be formed in the area of beamlet overlap. Such areas in which artifacts may form may be tail areas of the newest beamlet(s) irradiating the sample which overlap front or head areas of the previously irradiated and resolidified portion of the sample. These artifacts may arise because the edge of the beam (e.g., rounded or square-shaped), which is reproduced in the molten portion, leads to lateral growth of grains extending in from the edges at angles that are skewed to the desired direction of the lateral growth.


OBJECT AND SUMMARY OF THE INVENTION

An object of the present invention is to provide techniques for forming large-grained, grain-shaped and grain-boundary-location controlled polycrystalline thin film semiconductors using a sequential lateral solidification (“SLS”) process, and to reduce or eliminate artifacts.


According to the present invention, an arrangement, process and mask are provided for implementing single-scan continuous motion sequential lateral solidification of a thin film situated on a sample such that artifacts are reduced or eliminated. For example, according to the present invention artifacts that may be formed at the edges of the beamlets irradiating the thin film are significantly reduced. According to this invention, the edge areas of the previously irradiated and resolidified areas which likely have artifacts provided therein are overlapped by the subsequent beamlets. In this manner, the edge areas of the previously resolidified irradiated areas and artifacts therein are completely melted throughout their thickness. At least the subsequent beamlets are shaped such that the grains of the previously irradiated and resolidified areas which border the edge areas melted by the subsequent beamlets grow into these resolidifying edges areas so as to substantially reduce or eliminate the artifacts.


In one exemplary embodiment of the present invention, an arrangement, process and mask can be provided for processing at least one portion of a thin film sample on a substrate. In particular, an irradiation beam generator can be controlled to emit successive irradiation beam pulses at a predetermined repetition rate. The exemplary mask may receive thereon each of the irradiation beam pulses. Such mask can include a beam pattern which, when the beam pulses irradiate therethrough, defines one or more first beamlets and one or more second beamlets, with each of the first and second beamlets having two opposite edge sections and a center section. The first beamlets can irradiate one or more first areas of the film sample so that the first areas are melted throughout their thickness.


At least one first section of the first areas irradiated by at least one particular beamlet of the first beamlets is allowed to re-solidify and crystallize thereby having grains grown therein. The first section includes at least one first resolidified area irradiated by the one of the edge sections of the particular beamlet, the first resolidified area including artifacts therein. After the one or more first areas are irradiated, the second beamlets irradiate one or more second areas of the film sample so that the second areas are melted throughout their thickness. At least one second section of the second areas irradiated by the subsequent beamlet is allowed to re-solidify and crystallize thereby having grains grown therein. The second section includes at least one second resolidified area irradiated by the at least one of the edge sections of the subsequent beamlet which overlaps the artifacts provided in the first resolidified area. In this manner, the artifacts can thus be substantially reduced or even eliminated upon the resolidification of the second section of the second area.


According to another exemplary embodiment of the present invention, the edge sections of each of the first and second beamlets are a front section and a rear section. The first resolidified area can be irradiated by the rear section of the particular beamlet, and the second resolidified area may be irradiated by the front section of the subsequent beamlet. The rear section of at least one particular beamlet has a width for a substantial length thereof which is smaller than a width of the center section of the particular beamlet. In addition, the front section of at least one subsequent beamlet of the second beamlets has a width for a substantial length thereof which is smaller than a width of the center section of the subsequent beamlet.


In yet another exemplary embodiment of the present invention, the rear section of the particular beamlet and the front section of the subsequent beamlet have substantially straight edges in which the straight edges slope toward one another and away from the center section of the respective one of the particular and subsequent beamlets. Also, the rear section of the particular beamlet and the front section of the subsequent beamlet can have a triangular shape. For example, each of the front and rear sections has three apexes, and one of the apexes of each of the front and rear sections points away from the central section of a respective one of the particular and subsequent beamlets. In yet another exemplary embodiment, the rear section of the particular beamlet and the front section of the subsequent beamlet have a trapezoid shape. Thus, the trapezoid-shaped rear section of the particular beamlet may have a first conceptual side extending for a width of the central section of the particular beamlet and a second side provided at an edge of the rear section away from the central section, with the first side being greater than the second side. The trapezoid-shaped front section of the subsequent beamlet can have a third conceptual side extending for a width of the central section of the subsequent beamlet, and a fourth side provided at an edge of the front section away from the central section. The third side is preferably greater than the fourth side. In another embodiment of the present invention, upon the resolidification of the second section of the second area, at least most of the grains from the resolidified first section of the first area that are adjacent to the second section grow into the solidifying second section in a direction which is approximately perpendicular to a direction of extension of the solidifying second section.





BRIEF DESCRIPTION OF THE DRAWINGS

Exemplary embodiments of the present invention will now be described in further detail with reference to the accompanying drawings in which:



FIG. 1 shows a diagram of an exemplary embodiment of a system for performing a single-scan, continuous motion sequential lateral solidification (“SLS”) according to the present invention which does not require a microtranslation of a sample for an effective large grain growth in a thin film, and effectuates a bi-directional grain growth within the irradiated and re-solidified area of the sample;



FIG. 2A shows an enlarged illustration of a first mask utilized by the conventional systems and methods having a rectangular shape, which facilitates the single-scan, continuous motion SLS as an intensity pattern generated thereby impinges the thin film on a substrate of the sample, and using which microstructural artifacts may possibly form;



FIG. 2B shows an enlarged view of the resolidified region of the sample irradiated by one exemplary beamlet shaped by the mask of FIG. 2A which overlaps a portion of the previously resolidified region, as well as artifacts formed at the overlapped area;



FIG. 2C show an exemplary sequential stage of the SLS processing of the sample using the mask of FIG. 2A and the grain structures on the resolidified areas of the sample which shows microstructural artifacts provided in the areas where the previously-irradiated and resolidified areas have been overlapped by the newly irradiated and resolidified areas;



FIG. 3A shows an enlarged illustration of a second mask having a round or curved edges that may be utilized by the conventional systems and methods which facilitates the single-scan, continuous motion SLS, and using which microstructural artifacts may possibly form;



FIG. 3B shows an enlarged view of the resolidified region of the sample irradiated by one exemplary beamlet shaped by the mask of FIG. 3A which overlaps a portion of the previously resolidified region, as well as the illustration of the artifacts formed at the overlapped area;



FIG. 4A shows an enlarged illustration of a first exemplary embodiment of the mask utilized by the system and method according to the present invention having a triangular shape at the edges thereof using which microstructural artifacts may be reduced or eliminated;



FIG. 4B shows an enlarged view of the resolidified region of the sample irradiated by one exemplary beamlet shaped by the mask of FIG. 4A which overlaps a portion of the previously resolidified region, and illustrates the reduction or elimination of the artifacts;



FIG. 4C show an exemplary sequential stage of the SLS processing of the sample using the mask of FIG. 3A and the grain structures on the resolidified areas of the sample which shows the reduction or elimination of the microstructural artifacts provided in the areas where the previously-irradiated and resolidified areas have been overlapped by the newly irradiated and resolidified areas; and



FIG. 5A shows an enlarged illustration of a second exemplary embodiment of the mask utilized by the system and method according to the present invention having a tapered shape at the edges thereof using which microstructural artifacts may be reduced or eliminated.



FIG. 5B shows an exemplary illustration of a sample irradiated by an exemplary beamlet shaped by the mask illustrated in FIG. 5A





DETAILED DESCRIPTION

Certain systems and methods for providing a single scan, continuous motion SLS are described in International Publication No. 02/086954 (the “'954 Publication”), the entire disclosure of which is incorporated herein by reference. The '954 Publication explicitly describes and illustrates the details of these systems and methods, and their utilization of microtranslations of a sample, which may have an amorphous silicon thin film provided thereon that can be irradiated by irradiation beam pulses so as to promote the sequential lateral solidification on the thin film, without the need to microtranslate the sample and/or the beam relative to one another to obtain a desired length of the grains contained in the irradiated and re-solidified areas of the sample. Similar to the system described in the '954 Publication, an exemplary embodiment of a system for carrying out the continuous motion SLS processing of amorphous silicon thin films and reduce or eliminate microstructural artifacts according to the present invention is illustrated in FIG. 1. The exemplary system includes a Lambda Physik model LPX-315I XeCl pulsed excimer laser 110 emitting an irradiation beam (e.g., a laser beam), a controllable beam energy density modulator 120 for modifying the energy density of the laser beam, a MicroLas two plate variable attenuator 130, beam steering mirrors 140, 143, 147, 160 and 162, beam expanding and collimating lenses 141 and 142, a beam homogenizer 144, a condenser lens 145, a field lens 148, a projection mask 150 which may be mounted in a translating stage (not shown), a 4×-6× eye piece 161, a controllable shutter 152, a multi-element objective lens 163 for focusing an incident radiation beam pulse 164 onto a sample 170 having a silicon thin film 52 to be SLS processed mounted on a sample translation stage 180, a granite block optical bench 190 supported on a vibration isolation and self-leveling system 191, 192, 193 and 194, and a computer 106 (e.g., a general purpose computer executing a program or a special-purpose computer) coupled to control the pulsed excimer laser 110, the beam energy density modulator 120, the variable attenuator 130, the shutter 152 and the sample translation stage 180.


The sample translation stage 180 may be controlled by the computer 106 to effectuate translations of the sample 40 in the planar X-Y directions and the Z direction. In this manner, the computer 106 controls the relative position of the sample 40 with respect to the irradiation beam pulse 164. The repetition and the energy density of the irradiation beam pulse 164 may also be controlled by the computer 106. It should be understood by those skilled in the art that instead of the pulsed excimer laser 110, the irradiation beam pulse can be generated by another known source of short energy pulses suitable for melting a semiconductor (or silicon) thin film. Such known source can be a pulsed solid state laser, a chopped continuous wave laser, a pulsed electron beam and a pulsed ion beam, etc. with appropriate modifications to the radiation beam path from the source 110 to the sample 170. In the exemplary embodiment of the system shown in FIG. 1, while the computer 106 controls translations of the sample 170 for carrying out the single-scan, continuous motion SLS processing of the thin film according to the present invention, the computer 100 may also be adapted to control the translations of the mask 150 and/or the excimer laser 110 mounted in an appropriate mask/laser beam translation stage (not shown for the simplicity of the depiction) to shift the intensity pattern of the irradiation beam pulses 164, with respect to the silicon thin film, along a controlled beam path. Another possible way to shift the intensity pattern of the irradiation beam pulse is to have the computer 100 control a beam steering mirror. The exemplary system of FIG. 1 may be used to carry out the single-scan, continuous motion SLS processing of the silicon thin film on the sample 170 in the manner using conventional masks, as well as those used according to the exemplary embodiments of the present invention. The details of such processing are set forth in further detail below.


An amorphous silicon thin film sample may be processed into a single or polycrystalline silicon thin film by generating a plurality of excimer laser pulses of a predetermined fluence, controllably modulating the fluence of the excimer laser pulses, homogenizing the intensity profile of the laser pulse plane, masking each homogenized laser pulses to define beamlets, irradiating the amorphous silicon thin film sample with the beamlets to effect melting of portions thereof that were irradiated by the beamlets, and controllably and continuously translating the sample 170 with respect to the patterned beamlets. The output of the beamlets is controllably modulated to thereby process the amorphous silicon thin film provided on the sample 170 into a single or grain-shape, grain-boundary-location controlled polycrystalline silicon thin film by the continuous motion sequential translation of the sample relative to the beamlets, and the irradiation of the sample by the beamlets of masked irradiation pulses of varying fluence at corresponding sequential locations thereon. One of the advantages of the system, method and mask according to the present invention is that the ability to reduce or eliminate the microstructural artifacts that may be formed on the areas on the sample in which edges (e.g., rear edges) of the newly irradiated and solidifying region of the sample 170 partially overlap edges (e.g., front edges) of the previously resolidified region of the sample 170.



FIG. 2A shows an enlarged illustration of a first mask 150 that has rectangular-shaped slits, as used in conventional continuous motion SLS-type systems and processes. These slits shape the beam being passed therethrough to produce an intensity pattern that impinges the thin film provided on the sample 170, and to be in a shape that is substantially the same as the shape of the corresponding slit. In particular, the slits of the mask 150 allow the respective portions of the beam 149 to irradiate therethrough, while other sections of the mask 150 are opaque, and do not allow the portions of the beam 149 to be transmitted through these opaque sections. This mask 150 includes a first set of rectangular-shaped slits 210 situated at an offset from one another along a negative Y-axis, and a second set of rectangular-shaped slits 215 are also provided at an offset from one another along a negative Y-axis, but also distanced from the first slits. The positioning of the first and second slits with respect to one another is shown and described in further detail in the '954 Publication.



FIG. 2B shows an exemplary illustration of the irradiation of the sample 170 by a sample beamlet of the intensity pattern shaped by the mask of FIG. 2A. In operation, this beamlet is irradiated on the sample so as to partially cover a portion (e.g., a front portion 265) of the previously irradiated, melted and resolidified area of the sample with its own portion (e.g., a tail portion 270). For example, the front portion 265 of the previously-resolidified area may have the grains grown in the orientation that is approximately parallel to the direction of the translation of the sample 170 and/or the beam pulse 164. Upon the irradiation of the next sequential region by the subsequent beamlet, a part of the front portion 265 is overlapped by the tail portion 270 of such beamlet, so as to completely melt, resolidify and form respective portions of the subsequent region 250, including a new front portion 260 and the tail portion 270. The grains of the front portion 265 of the previously resolidified region extend at angles that are contrary to the desirable direction of grain growth.


For example, the grains may extend approximately along the relative translation direction of the sample, which is unfavorable for processing the sample according to the continuous motion SLS-techniques. Such undesired grain growth is shown for the new front portion 260, which illustrates that that grains grow from the edges of the irradiated and fully melted region 250, such that at least some of the grains extend along the length of the region 250, thus potentially producing undesirable effects. On the other end, the undesirable grains that exist in the portion of the previously resolidified region 265 (extending approximately along the length of such region) grow into the tail portion 270 of the newly irradiated, melted and resolidifying region. Accordingly, the tail portion 270 of the resolidifying region 250 may have undesirably-oriented grains provided therein.



FIG. 2C illustrates a section of the sample 170 which has been processed by one 610 two 620 and three 630 sequential intensity profiles produced by the mask of 150 of FIG. 2A. The undesired grain growth described above with reference to FIG. 2B is shown herein. In addition, the previously solidified region 275 (which has the head portion 265 with the grains extending in an undesired manner) has a bottom region 280 with grains that extend into a top portion 285 of a further resolidifying region by seeding the resolidifying portions thereof with the grains of the bottom region 280. This further region is melted by the beamlet that is produced by the slits (215 and 210) of the mask 150 of FIG. 2B. Such further region also includes a respective front portion 295 in which undesired grains are grown as described above.



FIG. 3A shows an enlarged illustration of a second mask 150 that has slits with rounded edges, as used in conventional continuous motion SLS-type systems and processes. It is also possible for the edges to have a circular shape as well in this mask 150. This mask 150 includes a first set of round-edge slits 310 situated at an offset from one another along a negative Y-axis, and a second set of round-edge slits 315 are also provided at an offset from one another along a negative Y-axis, but also distanced from the first slits. The positioning of the first and second slits 310, 315 with respect to one another is substantially similar to that of the first and second slits 210, 215.



FIG. 3B shows an exemplary illustration of the irradiation of the sample 170 by a sample beamlet of the intensity pattern shaped by the mask 150 of FIG. 3A. In this illustration and similarly to the illustration of FIG. 2B, the front portion 365 of the previously-resolidified area may have the grains grown in the orientation that is approximately parallel to the direction of the translation of the sample 170 and/or the beam pulse 164, even though the edges of the resolidifying portions are curved or rounded. Indeed, the fact that the edges of the slits 310, 315 have such shape may promote the undesired grain growth along the direction of the relative translation of the sample 170. Again, a part of the front portion 365 of this previously resolidified is overlapped by the tail portion 270 of the newly melted and solidifying region 350, and such region 250 also includes a new front portion 260 and the tail portion 370. The grains of the front portion 365 of the previously resolidified region extend at angles that are contrary to the desirable direction of grain growth, and producing the microstructural artifacts in the overlapped portions.


In order to reduce or eliminate artifacts, the exemplary mask, method and system according to the present invention are described herein. In particular, FIG. 4A shows an enlarged illustration of a first exemplary embodiment of the mask 150 according to the present invention which has slits with tapered areas on the ends thereof, that can be used with continuous motion SLS-type systems and processes according to the present invention. In this exemplary embodiment, both ends of each slit 412, 413 have triangular-shaped sections which point away from the respective slit. As described above with respect to the masks shown in FIGS. 2A and 2B, these slits shape the beam being passed therethrough to produce an intensity pattern that impinges the thin film provided on the sample 170, and to be in a shape that is substantially the same as the shape of the corresponding slit. The positioning of the first and second slits with respect to one another approximately similar to that of the first and second slits 210, 215.



FIG. 4B shows an exemplary illustration of the irradiation of the sample 170 by a sample beamlet of the intensity pattern shaped by the mask of FIG. 2A. In operation, this beamlet is irradiated on the sample so as to partially cover a portion (e.g., a front portion 465) of the previously irradiated, melted and resolidified area of the sample with its own portion (e.g., a tail portion 470). The front portion 465 of the previously resolidified region is produced by a section of the beamlet that is shaped by a triangular portion 412 of the slit 410. The tail portion 470 of the newly melted and resolidifying region 450 is produced by another section of the beamlet that is shaped by the reverse-triangular portion 413 of the slit 410. For example, the front portion 465 of the previously-resolidified area may have very few grains grown in the orientation that is approximately parallel to the direction of the translation of the sample 170 and/or the beam pulse 164. Indeed, because the portion 465 has a tapered (e.g., triangular) shape as shown in FIG. 4B, most of the grains grown therein, upon its resolidification, would grow in the direction that is approximately perpendicular to the translation direction of the sample 170 and/or that of the beam pulse 164.


Upon the irradiation of the next sequential region by the subsequent beamlet, a part of the front portion 465 is overlapped by the tail portion 470 of such beamlet, so as to completely melt, resolidify and form respective portions of the subsequent region 450, including a new front portion 460 and the tail portion 470. Such overlap by the tail portion 470 of the region 450 melts at least the very end areas of the front portion 465 of the previously resolidified region. Indeed, these end areas may contain the undesired grains which undesirably grew in the direction of the translation of the sample and/or that of the beam pulse 164. Thus, the properly oriented grains of the front portion 465 would be the primary grains that seed the resolidifying tail portion 470 of the region 450. Therefore, the grains of the resolidifying portion 450 at the tail portion 470 thereof which overlaps the front portion 450 would be oriented in a desired manner (e.g., oriented perpendicularly to the direction of translation of the sample 170 and/or of the beam pulse 164). Indeed, as shown in FIG. 4B, such grain growth minimizes, and possibly eliminates the microstructural artifacts that may exist in the overlapped portions of the resolidified regions.



FIG. 4C illustrates a section of the sample 170 which has been processed by one 710 two 720 and three 730 sequential intensity profiles produced by the mask of 150 of FIG. 4A. The desired grain growth in the overlapped portions of the resolidified regions described above with reference to FIG. 4B is shown herein. In addition, the previously solidified region 475 (which has the head portion 465 with the grains extending in a desired manner) has a bottom region 480 with grains that extend into a top portion 485 of a further resolidifying region by seeding the resolidifying portions thereof with the grains of the bottom region 480. This further region is melted by the beamlet that is produced by slits (410 and 415) of the mask 150 of FIG. 4B. Such further region also includes a respective front portion 495 in which the undesired grains are grown as described above, Similarly to the description above with reference to FIG. 2C, there is a multiplicity of the regions 450 with the orientation of the grains in the overlapping areas. Thus, the exemplary mask, method and system according to the present invention provides for the reduction and/or removal of microstructural artifacts in the overlapping portions of the resolidified regions.



FIG. 5A shows an enlarged illustration of another exemplary embodiment of the mask 150 that has slits with tapered cut-off edges for use with the continuous motion SLS-type systems and processes according to the present invention. This mask 150 includes a first set of tapered cut-off slits 510 situated at an offset from one another along a negative Y-axis, and a second set of tapered cut-off slits 515 are also provided at an offset from one another along a negative Y-axis, but also distanced from the first slits. The positioning of the first and second slits 510, 515 with respect to one another is substantially similar to that of the first and second slits 410, 415.



FIG. 5B shows an exemplary illustration of the irradiation of the sample 170 by a sample beamlet of the intensity pattern shaped by the mask 150 of FIG. 5A. In this illustration and similarly to the illustration of FIG. 4B, the front portion 565 is produced by the section of the beamlet that is shaped by a tapered portion 512 of the slit 510. This front portion 565 of the previously-resolidified area may have the desirable grains grown in the orientation that is approximately perpendicular to the direction of the translation of the sample 170 and/or the beam pulse 164, and the rear portion 570 that overlaps at least a section of the front portion 565 is produced by the section of the beamlet that is shaped by a tapered portion 513 of the slit 510. This front portion 565 of the previously-resolidified area may have the desirable grains grown in the orientation that is approximately perpendicular to the direction of the translation of the sample 170 and/or the beam pulse 164. Similarly to the description provided above for sequential irradiation of the sample 170 by the mask of FIG. 4A, the sections of the tail portion 470 of the region 550 that may have any undesired grains therein are overlapped the front portion 465 of the previously resolidified region, and thus the properly oriented grains seed the melted tail portion 570 of the region 550 such that the grains are desirably grown in the direction that is perpendicular to the direction of the translation of the sample and/or that of the beam pulse 164. In this manner, any existent microstructural artifacts provided in the overlapped portions of the resolidified regions are reduced or even eliminated.


The foregoing exemplary embodiments merely illustrate the principles of the present invention. Various modifications and alterations to the described embodiments will be apparent to those skilled in the art in view of the teachings herein without departing from the scope of the invention, as defined by the appended claims.

Claims
  • 1. A process for processing at least one portion of a thin film sample on a substrate, the method comprising the steps of: (a) controlling an irradiation beam generator to emit successive irradiation beam pulses at a predetermined repetition rate;(b) masking each of the irradiation beam pulses to define one or more first beamlets and one or more second beamlets, each of the first and second beamlets having two opposite edge sections and a center section;(c) irradiating one or more first areas of the film sample by the first beamlets so that the first areas are melted throughout their thickness, wherein at least one first section of the first areas irradiated by at least one particular beamlet of the first beamlets is allowed to re-solidify and crystallize thereby having grains grown therein, the at least one first section including at least one first resolidified area;(d) after step (c), irradiating one or more second areas of the film sample by the second beamlets of the irradiation beam pulses so that the second areas are melted throughout their thickness, wherein at least one second section of the second areas irradiated by at least one subsequent beamlet is allowed to re-solidify and crystallize thereby having grains grown therein, the at least one second section including at least one second resolidified area irradiated by at least one of the edge sections of the subsequent beamlet which overlaps the at least one first resolidified area, wherein artifacts are substantially reduced and eliminated upon the resolidification of the at least one second section of the second area;wherein the edge sections of each of the first and second beamlets are a front section and a rear section, wherein the at least one first resolidified area is irradiated by the rear section of the particular beamlet, and wherein the at least one second resolidified area is irradiated by the front section of the subsequent beamlet, andwherein the rear section of at least one particular beamlet has a width for a substantial length thereof which is smaller than a width of the center section of the at least one particular beamlet, and wherein the front section of at least one subsequent beamlet of the second beamlets has a width for a substantial length thereof which is smaller than a width of the center section of the subsequent beamlet.
  • 2. The process according to claim 1, wherein the rear section of the particular beamlet and the front section of the subsequent beamlet have substantially straight edges which slope toward one another and away from the center section of the respective one of the particular and subsequent beamlets.
  • 3. The process according to claim 1, wherein the rear section of the particular beamlet and the front section of the subsequent beamlet have a triangular shape.
  • 4. The process according to claim 3, wherein each of the front and rear sections has three apexes, and wherein one of the apexes of each of the front and rear sections points away from the central section of a respective one of the particular and subsequent beamlets.
  • 5. The process according to claim 1, wherein the rear section of the particular beamlet and the front section of the subsequent beamlet have a trapezoid shape.
  • 6. The process according to claim 5, wherein the trapezoid-shaped rear section of the particular beamlet has a first conceptual side extending for a width of the central section of the particular beamlet, and a second side provided at an edge of the rear section away from the central section, the first side being greater than the second side.
  • 7. The process according to claim 5, wherein the trapezoid-shaped front section of the subsequent beamlet has a third conceptual side extending for a width of the central section of the subsequent beamlet, and a fourth side provided at an edge of the front section away from the central section, the third side being greater than the fourth side.
  • 8. The process according to claim 1, wherein, upon the resolidification of the at least one second section of the second area, at least most of the grains from the at least one resolidified first section of the first area that are adjacent to the at least one second section grow into the at least one solidifying second section in a direction which is approximately perpendicular to a direction of extension of the at least one solidifying second section.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a divisional of U.S. patent application Ser. No. 11/370,000, filed Mar. 7, 2006, now U.S. Pat. No. 7,759,230 which is a continuation of International Application Ser. No. PCT/US04/030324, filed Sep. 16, 2004, published Mar. 31, 2005, which claims priority from U.S. Provisional application Ser. No. 60/503,409, filed Sep. 16, 2003, each of which are incorporated by reference in their entireties herein, and from which priority is claimed.

US Referenced Citations (294)
Number Name Date Kind
3632205 Marcy Jan 1972 A
4234358 Celler et al. Nov 1980 A
4309225 Fan et al. Jan 1982 A
4382658 Shields et al. May 1983 A
4456371 Lin Jun 1984 A
4514895 Nishimura May 1985 A
4639277 Hawkins Jan 1987 A
4691983 Kobayashi et al. Sep 1987 A
4727047 Bolzer et al. Feb 1988 A
4758533 Magee et al. Jul 1988 A
4793694 Liu Dec 1988 A
4800179 Mukai Jan 1989 A
4855014 Kakimoto et al. Aug 1989 A
4870031 Suguhara et al. Sep 1989 A
4940505 Schachameyer et al. Jul 1990 A
4970546 Suzuki et al. Nov 1990 A
4976809 Broadbent Dec 1990 A
4977104 Sawada et al. Dec 1990 A
5032233 Yu et al. Jul 1991 A
5061655 Ipposhi et al. Oct 1991 A
5076667 Stewart et al. Dec 1991 A
RE33836 Resor, III et al. Mar 1992 E
5145808 Sameshima et al. Sep 1992 A
5173441 Yu et al. Dec 1992 A
5204659 Sarma Apr 1993 A
5233207 Anzai Aug 1993 A
5247375 Mochizuki et al. Sep 1993 A
5281840 Sarma Jan 1994 A
5285236 Jain Feb 1994 A
5291240 Jain Mar 1994 A
5294811 Aoyama et al. Mar 1994 A
5304357 Sato et al. Apr 1994 A
5338959 Kim et al. Aug 1994 A
5373803 Noguchi et al. Dec 1994 A
5395481 McCarthy Mar 1995 A
5409867 Asano Apr 1995 A
5413958 Imahashi et al. May 1995 A
5417897 Asakawa et al. May 1995 A
5436095 Mizuno et al. Jul 1995 A
5453594 Konecny Sep 1995 A
5456763 Kaschmitter et al. Oct 1995 A
5466908 Hosoya et al. Nov 1995 A
5496768 Kudo Mar 1996 A
5512494 Tanabe Apr 1996 A
5523193 Nelson Jun 1996 A
5529951 Noguchi et al. Jun 1996 A
5534716 Takemura Jul 1996 A
5591668 Maegawa et al. Jan 1997 A
5614421 Yang Mar 1997 A
5614426 Funada et al. Mar 1997 A
5616506 Takemura Apr 1997 A
5620910 Teramoto Apr 1997 A
5643801 Ishihara et al. Jul 1997 A
5663579 Noguchi Sep 1997 A
5683935 Miyamato et al. Nov 1997 A
5696388 Funada et al. Dec 1997 A
5710050 Makita et al. Jan 1998 A
5721606 Jain Feb 1998 A
5736709 Neiheisel Apr 1998 A
5742426 York Apr 1998 A
5756364 Tanaka et al. May 1998 A
5766989 Maegawa et al. Jun 1998 A
5767003 Noguchi Jun 1998 A
5817548 Noguchi et al. Oct 1998 A
5844588 Anderson Dec 1998 A
5858807 Kawamura Jan 1999 A
5861991 Fork Jan 1999 A
5893990 Tanaka Apr 1999 A
5948291 Neylan et al. Sep 1999 A
5960323 Wakita Sep 1999 A
5981974 Makita Nov 1999 A
5986807 Fork Nov 1999 A
6002523 Tanaka Dec 1999 A
6014944 Russell et al. Jan 2000 A
6020224 Shimogaichi et al. Feb 2000 A
6045980 Edelkind et al. Apr 2000 A
6072631 Guenther et al. Jun 2000 A
6081381 Shalapenok et al. Jun 2000 A
6093934 Yamazaki et al. Jul 2000 A
6117301 Freudenberger et al. Sep 2000 A
6117752 Suzuki Sep 2000 A
6120976 Treadwell et al. Sep 2000 A
6130009 Smith et al. Oct 2000 A
6130455 Yoshinouchi Oct 2000 A
6136632 Higashi Oct 2000 A
6156997 Yamazaki et al. Dec 2000 A
6162711 Ma et al. Dec 2000 A
6169014 McCulloch Jan 2001 B1
6172820 Kuwahara Jan 2001 B1
6176922 Aklufi et al. Jan 2001 B1
6177301 Jung Jan 2001 B1
6184490 Schweizer Feb 2001 B1
6187088 Okumura Feb 2001 B1
6190985 Buynoski Feb 2001 B1
6193796 Yang Feb 2001 B1
6198141 Yamazaki et al. Mar 2001 B1
6203952 O'Brien et al. Mar 2001 B1
6222195 Yamada et al. Apr 2001 B1
6235614 Yang May 2001 B1
6242291 Kusumoto et al. Jun 2001 B1
6255146 Shimizu et al. Jul 2001 B1
6274488 Talwar et al. Aug 2001 B1
6285001 Fleming et al. Sep 2001 B1
6300175 Moon Oct 2001 B1
6313435 Shoemaker et al. Nov 2001 B1
6316338 Jung Nov 2001 B1
6320227 Lee et al. Nov 2001 B1
6322625 Im Nov 2001 B2
6326286 Park et al. Dec 2001 B1
6333232 Kunikiyo Dec 2001 B1
6341042 Matsunaka et al. Jan 2002 B1
6348990 Igasaki et al. Feb 2002 B1
6353218 Yamazaki et al. Mar 2002 B1
6358784 Zhang et al. Mar 2002 B1
6368945 Im Apr 2002 B1
6388146 Onishi et al. May 2002 B1
6388386 Kunii et al. May 2002 B1
6392810 Tanaka May 2002 B1
6393042 Tanaka May 2002 B1
6407012 Miyasaka et al. Jun 2002 B1
6410373 Chang et al. Jun 2002 B1
6429100 Yoneda Aug 2002 B2
6432758 Cheng et al. Aug 2002 B1
6437284 Okamoto et al. Aug 2002 B1
6444506 Kusumoto et al. Sep 2002 B1
6445359 Ho Sep 2002 B1
6448612 Miyazaki et al. Sep 2002 B1
6451631 Grigoropoulos et al. Sep 2002 B1
6455359 Yamazaki et al. Sep 2002 B1
6468845 Nakajima et al. Oct 2002 B1
6471772 Tanaka Oct 2002 B1
6472684 Yamazaki et al. Oct 2002 B1
6476447 Yamazaki et al. Nov 2002 B1
6479837 Ogawa et al. Nov 2002 B1
6482722 Kunii et al. Nov 2002 B2
6493042 Bozdagi et al. Dec 2002 B1
6495067 Ono Dec 2002 B1
6495405 Voutsas et al. Dec 2002 B2
6501095 Yamaguchi et al. Dec 2002 B2
6504175 Mei et al. Jan 2003 B1
6506636 Yamazaki et al. Jan 2003 B2
6511718 Paz de Araujo et al. Jan 2003 B1
6512634 Tanaka Jan 2003 B2
6516009 Tanaka Feb 2003 B1
6521473 Jung Feb 2003 B1
6521492 Miyasaka et al. Feb 2003 B2
6526585 Hill Mar 2003 B1
6528359 Kusumoto et al. Mar 2003 B2
6531681 Markle et al. Mar 2003 B1
6535535 Yamazaki et al. Mar 2003 B1
6555422 Yamazaki et al. Apr 2003 B1
6555449 Im et al. Apr 2003 B1
6562701 Ishida et al. May 2003 B2
6563077 Im May 2003 B2
6573163 Voutsas et al. Jun 2003 B2
6573531 Im et al. Jun 2003 B1
6577380 Farmiga et al. Jun 2003 B1
6582827 Im Jun 2003 B1
6590228 Voutsas et al. Jul 2003 B2
6599790 Yamazaki et al. Jul 2003 B1
6608326 Shinagawa et al. Aug 2003 B1
6621044 Jain et al. Sep 2003 B2
6635554 Im et al. Oct 2003 B1
6635932 Grigoropoulos et al. Oct 2003 B2
6660575 Zhang Dec 2003 B1
6667198 Shimoto et al. Dec 2003 B2
6693258 Sugano et al. Feb 2004 B2
6734635 Kunii et al. May 2004 B2
6741621 Asano May 2004 B2
6744069 Yamazaki et al. Jun 2004 B1
6746942 Sato et al. Jun 2004 B2
6750424 Tanaka Jun 2004 B2
6755909 Jung Jun 2004 B2
6767804 Crowder Jul 2004 B2
6770545 Yang Aug 2004 B2
6777276 Crowder et al. Aug 2004 B2
6784455 Maekawa et al. Aug 2004 B2
6830993 Im et al. Dec 2004 B1
6858477 Deane et al. Feb 2005 B2
6861328 Hara et al. Mar 2005 B2
6908835 Sposili et al. Jun 2005 B2
6916690 Chang Jul 2005 B2
6961117 Im Nov 2005 B2
6962860 Yamazaki et al. Nov 2005 B2
7049184 Tanabe May 2006 B2
7078281 Tanaka et al. Jul 2006 B2
7091411 Falk et al. Aug 2006 B2
7119365 Takafuji et al. Oct 2006 B2
7144793 Gosain et al. Dec 2006 B2
7164152 Im Jan 2007 B2
7172952 Chung Feb 2007 B2
7183229 Yamanaka Feb 2007 B2
7187016 Arima Mar 2007 B2
7192479 Mitani et al. Mar 2007 B2
7192818 Lee et al. Mar 2007 B1
7199397 Huang et al. Apr 2007 B2
7217605 Kawasaki et al. May 2007 B2
7259081 Im Aug 2007 B2
7297982 Suzuki et al. Nov 2007 B2
7300858 Im Nov 2007 B2
7303980 Yamazaki et al. Dec 2007 B2
7311778 Im et al. Dec 2007 B2
7318866 Im Jan 2008 B2
7319056 Im et al. Jan 2008 B2
7326876 Jung Feb 2008 B2
7341928 Im Mar 2008 B2
7384476 You Jun 2008 B2
7507645 You Mar 2009 B2
7560321 Kato et al. Jul 2009 B2
7645337 Im Jan 2010 B2
7700462 Tanaka et al. Apr 2010 B2
7804647 Mitani et al. Sep 2010 B2
20010001745 Im et al. May 2001 A1
20010030292 Brotherton Oct 2001 A1
20010041426 Im Nov 2001 A1
20020083557 Jung Jul 2002 A1
20020096680 Sugano et al. Jul 2002 A1
20020104750 Ito Aug 2002 A1
20020119609 Hatano et al. Aug 2002 A1
20020151115 Nakajima et al. Oct 2002 A1
20020197778 Kasahara et al. Dec 2002 A1
20030000455 Voutsas Jan 2003 A1
20030003242 Voutsas Jan 2003 A1
20030006221 Hong et al. Jan 2003 A1
20030013278 Jang et al. Jan 2003 A1
20030014337 Mathews et al. Jan 2003 A1
20030022471 Taketomi et al. Jan 2003 A1
20030029212 Im Feb 2003 A1
20030057418 Asano Mar 2003 A1
20030068836 Hongo et al. Apr 2003 A1
20030089907 Yamaguchi et al. May 2003 A1
20030096489 Im et al. May 2003 A1
20030119286 Im et al. Jun 2003 A1
20030148565 Yamanaka Aug 2003 A1
20030148594 Yamazaki et al. Aug 2003 A1
20030194613 Voutsas et al. Oct 2003 A1
20030196589 Mitani et al. Oct 2003 A1
20040040938 Yamazaki et al. Mar 2004 A1
20040041158 Hongo et al. Mar 2004 A1
20040053450 Sposili et al. Mar 2004 A1
20040061843 Im Apr 2004 A1
20040127066 Jung Jul 2004 A1
20040140470 Kawasaki et al. Jul 2004 A1
20040169176 Peterson et al. Sep 2004 A1
20040182838 Das et al. Sep 2004 A1
20040222187 Lin Nov 2004 A1
20040224487 Yang Nov 2004 A1
20050003591 Takaoka et al. Jan 2005 A1
20050032249 Im et al. Feb 2005 A1
20050034653 Im et al. Feb 2005 A1
20050059224 Im Mar 2005 A1
20050059265 Im Mar 2005 A1
20050112906 Maekawa et al. May 2005 A1
20050139830 Takeda et al. Jun 2005 A1
20050141580 Partlo et al. Jun 2005 A1
20050142450 Jung Jun 2005 A1
20050142451 You Jun 2005 A1
20050202654 Im Sep 2005 A1
20050235903 Im Oct 2005 A1
20050236908 Rivin Oct 2005 A1
20060030164 Im Feb 2006 A1
20060035478 You Feb 2006 A1
20060040512 Im Feb 2006 A1
20060102901 Im et al. May 2006 A1
20060125741 Tanaka et al. Jun 2006 A1
20060211183 Duan et al. Sep 2006 A1
20060254500 Im et al. Nov 2006 A1
20070007242 Im Jan 2007 A1
20070010074 Im Jan 2007 A1
20070010104 Im Jan 2007 A1
20070020942 Im Jan 2007 A1
20070032096 Im Feb 2007 A1
20070051302 Gosian et al. Mar 2007 A1
20070108472 Jeong et al. May 2007 A1
20070111349 Im May 2007 A1
20070184638 Kang et al. Aug 2007 A1
20070215942 Chen et al. Sep 2007 A1
20080035863 Im et al. Feb 2008 A1
20080124526 Im May 2008 A1
20080176414 Im Jul 2008 A1
20090001523 Im Jan 2009 A1
20090045181 Im Feb 2009 A1
20090137105 Im May 2009 A1
20090173948 Im et al. Jul 2009 A1
20090189164 Im et al. Jul 2009 A1
20090218577 Im Sep 2009 A1
20090242805 Im Oct 2009 A1
20090309104 Im Dec 2009 A1
20100024865 Shah et al. Feb 2010 A1
20100032586 Im et al. Feb 2010 A1
20100065853 Im Mar 2010 A1
20100099273 Im Apr 2010 A1
20100197147 Im Aug 2010 A1
20100233888 Im Sep 2010 A1
Foreign Referenced Citations (82)
Number Date Country
19839718 Mar 2000 DE
10103670 Aug 2002 DE
681316 Aug 1995 EP
655774 Jul 1996 EP
1067593 Oct 2001 EP
2338342 Dec 1999 GB
2338343 Dec 1999 GB
2338597 Dec 1999 GB
S57-027035 Feb 1982 JP
S62-160781 Jul 1987 JP
62181419 Aug 1987 JP
S62-216320 Sep 1987 JP
H01-256114 Oct 1989 JP
H02-081422 Mar 1990 JP
02283036 Nov 1990 JP
04033327 Feb 1992 JP
H04-167419 Jun 1992 JP
4279064 Oct 1992 JP
H04-282869 Oct 1992 JP
5 041519 Feb 1993 JP
H05-048190 Feb 1993 JP
06-011729 Jan 1994 JP
06252048 Sep 1994 JP
H06-260502 Sep 1994 JP
06283422 Oct 1994 JP
07176757 Jul 1995 JP
H08-078330 Mar 1996 JP
H09-007968 Jan 1997 JP
1997-171971 Jun 1997 JP
9260681 Oct 1997 JP
H09-270393 Oct 1997 JP
9321310 Dec 1997 JP
10 189998 Jul 1998 JP
H10-244390 Sep 1998 JP
11064883 Mar 1999 JP
11281997 Oct 1999 JP
H11-297852 Oct 1999 JP
11330000 Nov 1999 JP
2000-223425 Aug 2000 JP
2000-315652 Nov 2000 JP
2000-346618 Dec 2000 JP
2001023920 Jan 2001 JP
2002-203809 Jul 2002 JP
2002-353142 Dec 2002 JP
2002-353159 Dec 2002 JP
2003-031496 Jan 2003 JP
2003-100653 Apr 2003 JP
2003-523723 Aug 2003 JP
2004-031809 Jan 2004 JP
2000-0053428 Aug 2000 KR
464960 Nov 2001 TW
564465 Dec 2003 TW
569350 Jan 2004 TW
WO 9745827 Dec 1997 WO
WO 9824118 Jun 1998 WO
WO 9931719 Jun 1999 WO
WO 0014784 Mar 2000 WO
WO 0118854 Mar 2001 WO
WO 0118855 Mar 2001 WO
WO 0171786 Sep 2001 WO
WO0171791 Sep 2001 WO
WO 0173769 Oct 2001 WO
WO 0197266 Dec 2001 WO
WO 0231869 Apr 2002 WO
WO 0242847 May 2002 WO
WO 0286954 May 2002 WO
WO 02086955 Oct 2002 WO
WO 03018882 Mar 2003 WO
WO 03046965 Jun 2003 WO
WO 03084688 Oct 2003 WO
WO 2004017379 Feb 2004 WO
WO 2004017380 Feb 2004 WO
WO 2004017381 Feb 2004 WO
WO 2004017382 Feb 2004 WO
WO 2004030328 Sep 2004 WO
WO 2004075263 Sep 2004 WO
WO2005029546 Mar 2005 WO
WO2005029548 Mar 2005 WO
WO 2005029549 Mar 2005 WO
WO2005029550 Mar 2005 WO
WO2005029551 Mar 2005 WO
WO 2006055003 May 2006 WO
Non-Patent Literature Citations (133)
Entry
U.S. Appl. No. 60/253,256, filed Aug. 31, 2003, Im.
Im et al., “Controlled Super-Lateral Growth of Si Films for Microstructural Manipulation and Optimization”, Phys. Stat. Sol. (a), vol. 166, p. 603 (1998).
S.D. Brotherton et al., “Influence of Melt Depth in Laser Crystallized Poly-Si Thin Film Transistors,” 82 J. Appl. Phys. 4086 (1997).
J.S. Im et al., “Crystalline Si Films for Integrated Active-Matrix Liquid-Crystals Displays,” 21 MRS Bulletin 39 (1996).
Im et al., “Single-Crystal Si Films for Thin-Film Transistor Devices,” Appl. Phys. Lett., vol. 70 (25), p. 3434 (1997).
Sposili et al., “Sequential Lateral Solidification of Thin Silicon Films on SiO2”, Appl, Phys. Lett., vol. 69 (19), p. 2864 (1996).
Crowder et al., “Low-Temperature Single-Crystal Si TFT's Fabricated on Si Films processed via Sequential Lateral Solidification”, IEEE Electron Device Letter, vol. 19 (8), p. 306 (1998).
Sposili et al., “Single-Crystal Si Films via a Low-Substrate-Temperature Excimer-Laser Crystallization Method”, Mat. Res. Soc. Symp. Proc. vol. 452, pp. 953-958, 1997 Materials Reasearch Society.
C. E. Nebel, “Laser Interference Structuring of A-SI:h” Amorphous Silicon Technology—1996, San Francisco, CA Apr. 8-12, 1996, Materials Research Society Symposium Proceedings, vol. 420, Pittsburgh, PA.
J. H. Jeon et al., “Two-step laser recrystallization of poly-Si for effective control of grain boundaries”, Journal of Non Crystalline Solids, North-Holland Publishing Company, NL, vol. 266-269, May 2000, pp. 645-649.
H. Endert et al., “Excimer Laser: A New Tool for Precision Micromaching,” 27 Optical and Quantum Electronics, 1319 (1995).
“Overview of Beam Delivery Systems for Excimer Lasers,” Micro/Las Lasersystem GMBH. 1999.
K.H. Weiner et al., “Ultrashallow Junction Formation Using Projection Gas Immersion Laser Doping (PGILD),” A Verdant Technologies Technical Brief, Aug. 20, 1997.
Hau-Riege C.S. et al., “The Effects Microstructural Transitions at Width Transitions on interconnect reliabity,” Journal of Applied Physics, Jun. 15, 2000, vol. 87, No. 12, pp. 8467-8472.
McWilliams et al., “Wafer-Scale Laser Pantography: Fabrication of N-Metal-Oxide-Semiconductor Transistors and Small-Scale Integrated Circuits by Direct-Write Laser-Induced Pyrolytic Reactions,” Applied Physics Letters, American Institute of Physics, New York, US, vol. 43, No. 10, Nov. 1983, pp. 946-948.
Mariucci et al., “Grain boundary location control by patterned metal film in excimer laser crystallized polysilicon,” Proceedings of the Figth International COnference on Polycrystalline Semiconductors, Schwabisch Gmund, Germany, Sep. 13-18, 1998, vol. 67-68, pp. 175-180.
Broadbent et al., “Excimer Laser Processing of Al-1%Cu/TiW Interconnect Layers,” 1989 Proceedings, Sixth International IEEE VLSI Multilevel Interconnection COnference, Santa Clara, CA, Jun. 12-13, 1989, pp. 336-345.
H.J. Kim and James S. Im, “Grain Boundary Location-Controlled Poly-Si Films for TFT Devices Obtained Via Novel Excimer Laser Process,” Abstracts for Symposium of Materials Research Society, Nov. 27 to Dec. 2, 1994, p. 230.
S.D. Brotherton, “Polycrystalline Silicon Thin Film Transistors,” 10 Semicond. Sci. Tech., pp. 721-738 (1995).
H. Watanabe et al., “Crystallization Process of Polycrystalline Silicon by KrF Excimer Laser Annealing,” 33 Japanese J. of Applied Physics Part 1—Regular Papers Short Notes & Review Papers, pp. 4491-4498 (1994).
E. Fogarassy et al., “Pulsed Laser Crystallization of Hydrogen-Free a-Si Thin Films for High-Mobility Poly-Si TFT Fabrication,” 56 Applied Physics A—Solids and Surfaces, pp. 365-373 (1993).
Y. Miyata et al, “Low-Temperature Polycrystalline Silicon Thin-Film Transistors for Large-Area Liquid Crystal Display,” 31 Japanese J. of Applied Physics Part 1—Regular Papers Short Notes & Review Papers, pp. 4559-4562 (1992).
Im et al., “Phase Transformation Mechanisms Involved in Excimer Laser Crystallization of Amorphous Silicon Films,” Appl. Phys. Lett., vol. 63 (14), p. 1969 (1993).
Im et al., “On the Super Lateral Growth Phenomenon Observed in Excimer Laser-Induced Crystallization of Thin Si Films,” Appl. Phys. Lett., vol. 64 (17), p. 2303 (1994).
Brochure from MicroLas Lasersystem, GmbH, “UV Optics Systems for Excimer Laser Based Micromaching and Marking”. 1999.
Ishida et al., “Ultra-shallow boxlike profiles fabricated by pulsed ultraviolet-laser doping process”, J. Vac. Sci. Technol. B 12(1), p. 399-403, 1994. (No month).
Yoshimoto, et al., “Excimer-Laser-Produced and Two-Dimensionally Position-Controlled Giant Si Grains on Organic SOG Underlayer”, p. 285-286, AM-LCD 2000. No month.
Ozawa et al., “Two-Dimensionally Position-Controlled Exicer-Laser-Crystallization of Silicon Thin Films on Glassy Substrate”, Jpn. J. Appl. Phys. vol. 38, Part 1, No. 10, p. 5700-5705, (1999). No month.
I.W. Boyd, Laser Processing of Thin Films and Microstructures, Oxidation, Deposition, and Etching of Insulators (Springer—Verlag Berlin Heidelber 1987).
N. Yamamuchi and R. Reif, Journal of Applied Physics, “Polycrystalline silicon thin films processed with silicon ion implantation and subsequent solid-phase crystallization: Theory, experiments, and thin-film transistor applications”—Apr. 1, 1994—vol. 75, Issue 7, pp. 3235-3257.
T. Noguchi, “Appearance of Single-Crystalline Properties in Fine-Patterned Si Thin Film Transistors (TFTs) by Solid Phase Crystallization (SPC),” Jpn. J. Appl. Phys. vol. 32 (1993) L1584-L1587.
Ishihara et al., “A Novel Double-Pulse Exicem-Laser Crystallization Method of Silicon Thin-Films,” Japanese Journal of Applied Physics, Publication Office Japanese Journal of Applied Physics, Tokyo, Japan, vol. 34, No. 8A, Aug. 1995, pp. 3976-3981.
Kim, H. J., “Excimer-Laser-Induced Crystallization of Amorophus Silicon Thin Films”, Ph.D. Dissertation Abstract, Columbia University, 1996.
Bergmann, R. et al., Nucleation and Growth of Crystalline Silicon Films on Glass for Solar Cells, Phys. Stat. Sol., 1998, pp. 587-602, vol. 166, Germany.
Biegelsen, D.K., L.E. Fennell and J.C. Zesch, Origin of oriented crystal growth of radiantly melted silicon on SiO/sub 2, Appl. Phys. Lett. 45, 546 (1984).
Boyd, Laser Processing of Thin Films and Microstructures, Oxidation, Deposition, and Etching of Insulators (Springer—Verlag Berlin Heidelber 1987).
Brotherton, S.D., et al., Characterisation of poly-Si TFTs in Directionally Solidified SLS Si, Asia Display/IDS'01, p. 387-390.
Crowder et al., “Parametric investigation of SLS-processed poly-silicon thin films for TFT application,” Preparations and Characterization, Elsevier, Sequoia, NL, vol. 427, No. 1-2, Mar. 3, 2003, pp. 101-107, XP004417451.
Crowder et al., “Sequential Lateral Solidification of PECVD and Sputter Deposited a-Si Films”, Mat. Res. Soc. Symp. Proc. 621:Q.9.7.1-9.7.6, 2000.
Dassow, R. et al. Laser-Crystallized Polycrystalline Silicon on Glass for Photovoltaic Applications, Solid State Phenomena, pp. 193-198, vols. 67-68, Scitec Publications, Switzerland.
Dassow, R. et al. Nd:YVO4 Laser Crystallization for Thin Film Transistors with a High Mobility, Mat. Res. Soc. Symp. Proc., 2000, Q9.3.1-Q9.3.6, vol. 621, Materials Research Society.
Dassow, R. et al., Laser crystallization of silicon for high-performance thin-film transistors, Semicond. Sci. Technol., 2000, pp. L31-L34, vol. 15, UK.
Dimitriadis, C.A., J. Stoemenos, P.A. Coxon, S. Friligkos, J. Antonopoulos and N.A. Economou, Effect of pressure on the growth of crystallites of low-pressure chemical-vapor-deposited polycrystalline silicon films and the effective electron mobility under high normal field in thin-film transistors, J. Appl. Phys. 73, 8402 (1993).
Geis et al., “Crystallographic orientation of silicon on an amorphous substrate using an artificial surface-relief grating and laser crystallization,” Appl. Phys. Lett. 35(1) Jul. 1, 1979, 71-74.
Geis et al., “Silicon graphoepitaxy using a strip-heater oven,” Appl. Phys. Lett. 37(5), Sep. 1, 1980, 454-456.
Geis et al., “Zone-Melting recrystallization of SI Films with a moveable-strip heater oven” J. Electro-Chem. Soc., 129: 2812 (1982).
Gupta et al., “Numerical Analysis of Excimer-laser induced melting and solidification of Si Thin Films”, Applied Phys. Lett., 71:99, 1997.
Hau-Reige et al., “Microstructural Evolution Induced by Scanned Laser Annealing in Al Interconnects,” Appl. Phys. Lett., vol. 75, No. 10, p. 1464-1466, 1999.
Hawkins, W.G. et al., “Origin of lamellae in radiatively melted silicon films,” appl. Phys. Lett. 42(4), Feb. 15, 1983.
Hayzelden, C. and J.L. Batstone, Silicide formation and silicide-mediated crystallization of nickel-implanted amorphous silicon thin films, J. Appl. Phys. 73, 8279 (1993).
Im, J.S., Method and system for producing crystalline thin films with a uniform crystalline orientation, U.S. Appl. No. 60/503,419.
Jung, Y.H., et al., Low Temperature Polycrystalline Si TFTs Fabricated with Directionally Crystallized Si Film, Mat. Res. Soc. Symp. Proc. vol. 621, Z8.3.1-6, 2000.
Jung, Y.H., et al., The Dependence of Poly-Si TFT Characteristics on the Relative Misorientation Between Grain Boundaries and the Active Channel, Mat. Res. Soc. Symp. Proc. vol. 621, Q9.14.1-6, 2000.
Kahlert, H., “Creating Crystals”, OE Magazine, Nov. 2001, 33-35.
Kim, C. et al., Development of SLS-Based SOG Display, IDMC 2005, Thu-15-02, 252-255.
Kim, H. J. et al., “Excimer Laser Induced Crystallization of Thin Amorphous Si Films on SiO2: Implications of Crystallized Microstructures for Phase Transformation Mechanisms,” Mat. Res. Soc. Symp. Proc., vol. 283, 1993.
Kim, H.J. et al., “New Excimer-laser-crystallization method for producing large-grained and grain boundary-location-controlled Si Films for Thin Film Transistors”, Applied Phys. Lett., 68: 1513.
Kim, H.J. et al., “Multiple Pulse Irradiation Effects in Excimer Laser-Induced Crystallization of Amorphous Si Films,” Mat. Res. Soc. Sym. Proc., 321:665-670 (1994).
Kim, H.-J., et al., “The effects of dopants on surface-energy-driven secondary grain growth in silicon films,” J. Appl. Phys. 67 (2), Jan. 15, 1990.
Kimura, M. and K. Egami, Influence of as-deposited film structure on (100) texture in laser-recrystallized silicon on fused quartz, Appl. Phys. Lett. 44, 420 (1984).
Knowles, D.S. et al., “P-59: Thin Beam Crystallization Method: a New Laser Annealing Tool with Lower Cost and Higher Yield for LTPS Panels,” SID 00 Digest, pp. 1-3 , 2005.
Kohler, J.R. et al., Large-grained polycrystalline silicon on glass by copper vapor laser annealing. Thin Solid Films, 1999, pp. 129-132, vol. 337, Elsevier.
Kung, K.T.Y. and R. Reif, Implant-dose dependence of grain size and (110) texture enhancements in polycrystalline Si films by seed selection through ion channeling, J. Appl. Phys. 59, 2422 (1986).
Kung, K.T.Y., R.B. Iverson and R. Reif, Seed selection through ion channeling to modify crystallographic orientations of polycrystalline Si films on SiO/sub 2/:Implant angle dependence, Appl. Phys. Lett. 46, 683 (1985).
Kuriyama, H., T. Nohda, S. Ishida, T. Kuwahara, S. Noguchi, S. Kiyama, S. Tsuda and S. Nakano, Lateral grain growth of poly-Si films with a specific orientation by an excimer laser annealing method, Jpn. J. Appl. Phys. 32, 6190 (1993).
Kuriyama, H., T. Nohda, Y. Aya, T. Kuwahara, K. Wakisaka, S. Kiyama and S. Tsuda, Comprehensive study of lateral grain growth in poly-Si films by excimer laser annealing and its application to thin film transistors, Jpn. J. Appl. Phys. 33, 5657 (1994).
Lee, S.-W. and S.-K. Joo, Low temperature poly-Si thin-film transistor fabrication by metal-induced lateral crystallization, IEEE Electron Device Letters 17, 160 (1996).
Lee, S.-W., Y.-C. Jeon and S.-K. Joo, Pd induced lateral crystallization of amorphous Si thin films, Appl. Phys. Lett. 66, 1671 (1995).
Leonard, J.P. et al, “Stochastic modeling of solid nucleation in supercooled liquids”, Appl. Phys. Lett. 78:22, May 28, 2001, 3454-3456.
Limanov, A. et al., Single-Axis Projection Scheme for Conducting Sequential Lateral Solidification of Si Films for Large-Area Electronics, Mat. Res. Soc. Symp. Proc., 2001, D10.1.1-D10.1.7, vol. 685E, Materials Research Society.
Limanov, A. et al., The Study of Silicon Films Obtained by Sequential Lateral Solidification by Means of a 3-k-Hz Excimer Laser with a Sheetlike Beam, Russian Microelectronics, 1999, pp. 30-39, vol. 28, No. 1, Russia.
Limanov, A.B., et al., Development of Linear Sequential Lateral Solidification Technique to Fabricate Quasi-Single-Cyrstal Super-thin Si Films for High-Performance Thin Film Transistor Devices, Perspectives, Science, and Technologies for Novel Silicon on.
Mariucci et al., “Advanced excimer laser crystallization techniques,” Thin Solid Films, vol. 338, pp. 39-44, 2001.
Micro/Las Lasersystem, GmbH, “UV Optics Systems for Excimer Laser Based Micromaching and Marking” (1999).
Miyasaka, M., K. Makihira, T. Asano, E. Polychroniadis and J. Stoemenos, In situ observation of nickel metal-induced lateral crystallization of amorphous silicon thin films, Appl. Phys. Lett. 80, 944 (2002).
Nerding, M., S. Christiansen, R. Dassow, K. Taretto, J.R. Kohler and H.P. Strunk, Tailoring texture in laser crystallization of silicon thin-films on glass, Solid State Phenom. 93, 173 (2003).
Sato et al., “Mobility anisotropy of electrons in inversion layers on oxidized silicon surfaces” Physical Review B (State State) 4, 1950 (1971).
Smith, H.I. et al., “The Mechanism of Orientation in Si Graphoepitaxy by Laser or Strip Heater Recrystallization,” J. Electrochem. Soc.: Solid-State Science and Technology, Taiwan FPD, Jun. 11, 2005, pp. 1-12.
Song et al., “Single Crystal Si Islands on SiO2 Obtained Via Excimer Laser Irradiation of a Patterned Si Film”, Applied Phys. Lett., 68:3165, 1996.
Sposili et al., “Line-scan sequential lateral solidification of Si thin films”, Appl. Phys. A67, 273-6, 1998.
Thompson, C.V. and H.I. Smith, Surface-energy-driven secondary grain growth in ultrathin (<100 nm) films of silicon, Appl. Phys. Lett. 44, 603 (1984).
van der Wilt, “The Commercialization of the SLS Technology,” Taiwan FPD, Jun. 11, 2004, pp. 1-12.
Van Der Wilt, P.C., “State-of-the-Art Laser Crystallization of Si for Flat Panel Displays,” PhAST, May 18, 2004, pp. 1-34.
Van Der Wilt, P.C., “Textured poly-Si films for hybrid SLS,” Jul. 2004, pp. 1-5.
Voutsas, A. T., “Assessment of the Performance of Laser-Based Lateral-Crystallization Technology via Analysis and Modeling of Polysilicon Thin-Film-Transistor Mobility,” IEEE Transactions on Electronic Devices, vol. 50, No. 6, Jun. 2003.
Voutsas, A.T., A new era of crystallization: advances in polysilicon crystallization and crystal engineering, Applied Surface Science 250-262, 2003.
Voutsas, A.T., et al., Effect of process parameters on the structural characteristics of laterally grown, laser-annealed polycrystalline silicon films, Journal of Applied Physics, vol. 94, No. 12, p. 7445-7452, Dec. 15, 2003.
Weiner, K. H. et al. “Laser-assisted, Self-aligned Silicide Formation,” A Verdant Technologies technical brief, Aug. 7, 1997, 1-9.
Werner, J.H., et al. From polycrystalline to single crystalline silicon on glass, Thin Solid Films 383, 95-100, 2001.
White et al., “Characterization of thin-oxide MNOS memory transistors” IEEE Trans. Electron Devices ED-19, 1280 (1972).
Gosain et al., Formation of (100)-Textured Si Film Using an Excimer Laser on a Glass Substrate, Jpn. J. Appl. Phys., vol. 42 (2003) pp. L135-L137.
U.S. Appl. No. 11/370,000, filed Apr. 7, 2006.
U.S. Appl. No. 11/370,000; Mar. 2, 2009, Non-Final Rejection.
U.S. Appl. No. 11/370,000; Sep. 2, 2009, Response to Non-Final Rejection.
U.S. Appl. No. 11/370,000; Jan. 14, 2010, Notice of Allowance.
U.S. Appl. No. 13/273,687, filed Oct. 14, 2011.
U.S. Appl. No. 13/019,042, filed Feb. 1, 2011.
U.S. Appl. No. 11/373,772, Oct. 13, 2011 Response to Non-Final Office Action.
U.S. Appl. No. 11/373,772, Jul. 18, 2011 Non-Final Office Action.
U.S. Appl. No. 11/373,772, Aug. 24, 2010 Amendment and Request for Continued Examination (RCE).
U.S. Appl. No. 11/373,772, Jun. 11, 2010 Advisory Action.
U.S. Appl. No. 11/373,772, May 20, 2010 Response to Final Office Action.
U.S. Appl. No. 11/373,772, Feb. 24, 2010 Final Office Action.
U.S. Appl. No. 11/373,772, Oct. 26, 2009 Response to Non-Final Office Action.
U.S. Appl. No. 11/373,772, Jul. 27, 2009 Non-Final Office Action.
U.S. Appl. No. 11/372,161, Oct. 7, 2011 Amendment and Request for Continued Examination (RCE).
U.S. Appl. No. 11/372,161, Jul. 7, 2011 Final Office Action.
U.S. Appl. No. 11/372,161, Apr. 15, 2011 Response to Non-Final Office Action.
U.S. Appl. No. 11/372,161, Oct. 18, 2010 Non-Final Office Action.
U.S. Appl. No. 11/372,161, Mar. 8, 2010 Amendment and Request for Continued Examination (RCE).
U.S. Appl. No. 11/372,161, Jan. 26, 2010 Advisory Action.
U.S. Appl. No. 11/372,161, Jan. 7, 2010 Response to Final Office Action.
U.S. Appl. No. 11/372,161, Sep. 8, 2009 Final Office Action.
U.S. Appl. No. 11/372,161, Apr. 21, 2009 Response to Non-Final Office Action.
U.S. Appl. No. 11/372,161, Oct. 29, 2008 Non-Final Office Action.
U.S. Appl. No. 11/372,161, Aug. 11, 2008 Amendment and Request for Continued Examination (RCE).
U.S. Appl. No. 11/372,161, Apr. 11, 2008 Final Office Action.
U.S. Appl. No. 11/372,161, Jan. 18, 2008 Response to Non-Final Office Action.
U.S. Appl. No. 11/372,161, Jul. 20, 2007 Non-Final Office Action.
U.S. Appl. No. 12/402,208, Jun. 13, 2011 Amendment and Request for Continued Examination (RCE).
U.S. Appl. No. 12/402,208, Feb. 23, 2011 Final Office Action.
U.S. Appl. No. 12/402,208, Nov. 29, 2010 Response to Non-Final Office Action.
U.S. Appl. No. 12/402,208, Jun. 28, 2010 Non-Final Office Action.
U.S. Appl. No. 12/419,821, Sep. 2, 2011 Non-Final Office Action.
U.S. Appl. No. 12/419,821, Jun. 10, 2011 Response to Nn-Final Office Action.
U.S. Appl. No. 12/419,821, Mar. 22, 2011 Non-Final Office Action.
U.S. Appl. No. 12/567,414, Nov. 9, 2011 Non-Final Office Action.
Jeon et al., “New Excimer Laser Recrystallization of Poly-Si for Effective Grain Growth and Grain Boundary Arrangement,” Jpn. J. Appl. Phys. vol. 39 (Apr. 2000) pp. 2012-2014.
Bergmann et al., “The future of crystalline silicon films on foreign substrates,” Thin Solid Films 403-404 (2002) 162-169.
van der Wilt et al., “A hybrid approach for obtaining orientation-controlled single-crystal Si regions on glass substrates”, Proc. of SPIE vol. 6106, 61060B-1-B-15, (2006) XP009151485.
Andra et al., “Multicrystalline LLC-SI Thin Film Solar Cells on Low Temperature Glass”, 3rd World Conference on Photovoltaic Energy Conversion May 11-18, 2003, Osaka, Japan, Poster, pp. 1174-1177 (2003).
Andra et al., “A new technology for crystalline silicon thin film solar cells on glass based on laser crystallization”, Photovoltiac Specialists Conference, Conference Record of the Twenty-Eight IEEE, pp. 217-220 (2000).
Sinke et al., “Explosive crystallization of amorphous silicon: Triggering and propagation”, Applied Surface Science, 43:128-135 (1989).
Related Publications (1)
Number Date Country
20100233888 A1 Sep 2010 US
Provisional Applications (1)
Number Date Country
60503409 Sep 2003 US
Divisions (1)
Number Date Country
Parent 11370000 Mar 2006 US
Child 12757726 US
Continuations (1)
Number Date Country
Parent PCT/US2004/030324 Sep 2004 US
Child 11370000 US