Patent Application
20160091803
The present disclosure relates to optical elements designed to operate in environments in which they are subject to contamination and wear. An example of such an environment is the vacuum chamber of an apparatus for generating extreme ultraviolet (“EUV”) radiation from a plasma created through discharge or laser ablation of a source material. In this application, the optical elements are used, for example, to collect and direct the radiation for utilization outside of the vacuum chamber, e.g., for semiconductor photolithography.
Extreme ultraviolet light, e.g., electromagnetic radiation having wavelengths of around 50 nm or less (also sometimes referred to as soft x-rays), and including light at a wavelength of about 13.5 nm, can be used in photolithography processes to produce extremely small features in substrates such as silicon wafers.
Methods for generating EUV light include converting a target material from a liquid state into a plasma state. The target material preferably includes at least one element, e.g., xenon, lithium or tin, with one or more emission lines in the EUV range. In one such method, often termed laser produced plasma (“LPP”), the required plasma can be produced by using a laser beam to irradiate a target material having the required line-emitting element.
One LPP technique involves generating a stream of target material droplets and irradiating at least some of the droplets with laser light pulses. In more theoretical terms, LPP light sources generate EUV radiation by depositing laser energy into a target material having at least one EUV emitting element, such as xenon (Xe), tin (Sn), or lithium (Li), creating a highly ionized plasma with electron temperatures of several 10's of eV.
The energetic radiation generated during de-excitation and recombination of these ions is emitted from the plasma in all directions. In one common arrangement, a near-normal-incidence mirror (often termed a “collector mirror” or simply a “collector”) is positioned to collect, direct (and in some arrangements, focus) the light to an intermediate location. The collected light may then be relayed from the intermediate location to a set of scanner optics and ultimately to a wafer.
In the EUV portion of the spectrum it is generally regarded as necessary to use reflective optics for the collector. At the wavelengths involved, the collector is advantageously implemented as a multi-layer mirror (“MLM”). As its name implies, this MLM is generally made up of alternating layers of material over a foundation or substrate.
The optical element must be placed within the vacuum chamber with the plasma to collect and redirect the EUV light. The environment within the chamber is inimical to the optical element and so limits its useful lifetime, for example, by degrading its reflectivity. An optical element within the environment may be exposed to high energy ions or particles of source material. The particles of source material can contaminate the optical element's exposed surface. Particles of source material can also cause physical damage and localized heating of the MLM surface. The source materials may be particularly reactive with a material making up at least one layer of the MLM, e.g., molybdenum and silicon. Temperature stability, ion-implantation and diffusion problems may need to be addressed even with less reactive source materials, e.g., tin, indium, or xenon.
There are techniques which may be employed to increase optical element lifetime despite these harsh conditions. For example, protective layers or intermediate diffusion barrier layers may be used to isolate the MLM layers from the environment. The collector may be heated to an elevated temperature of, e.g., up to 500° C., to evaporate debris from its surface. The collector surface may be cleaned using hydrogen radicals. An etchant may be employed e.g., a halogen etchant, to etch debris from the collector surfaces and create a shielding plasma in the vicinity of the reflector surfaces. These latter two techniques can remove contaminating source material from the collector surface, but they are generally ineffective to remove damaged original collector material from the surface of the collector. There remains a need to extend collector lifetime by cleaning the collector surface and removing damaged collector material from the collector surface, all preferably without having to remove the collector from its operating environment. With this in mind, applicant discloses arrangements for in-situ cleaning and repair of the surfaces of optical elements.
The following presents a simplified summary of one or more embodiments in order to provide a basic understanding of the embodiments. This summary is not an extensive overview of all contemplated embodiments, and is not intended to identify key or critical elements of all embodiments nor delineate the scope of any or all embodiments. Its sole purpose is to present some concepts of one or more embodiments in a simplified form as a prelude to the more detailed description that is presented later.
According to one aspect, the invention is a method of repairing an optical element disposed in a vacuum chamber comprising the steps of cleaning an exposed surface of the optical element while the optical element is in the vacuum chamber to remove at least some of a contaminant on the exposed surface to produce a cleaned exposed surface, and exposing the cleaned exposed surface while the optical element is in the vacuum chamber to an ion flux generated by an ion gun to remove at least some areas of the surface that have been damaged by exposure to the environment within the vacuum chamber. The cleaning step may be performed by subjecting the exposed surface to hydrogen radicals and may remove substantially all of the contaminant from the exposed surface.
The exposing step may remove substantially all areas of the surface that have been damaged by exposure to the environment within the vacuum chamber. The exposing step may comprise the additional steps of generating the ion flux using an ion gun and directing the ion gun to cause ions to strike at least some areas of the surface that have been damaged by exposure to the environment within the vacuum chamber, or all of the surface.
Another aspect of the invention is a method of repairing a multilayer mirror in a system for producing EUV light for semiconductor photolithography, the multilayer mirror being disposed in a vacuum chamber in which a source material is vaporized to produce the EUV light, comprising the steps of cleaning an exposed surface of the multilayer mirror while the multilayer mirror is in the vacuum chamber to remove at least some source material on the exposed surface to produce a cleaned exposed surface and exposing the cleaned exposed surface while the multilayer mirror is in the vacuum chamber to an ion flux to remove at least some areas of the surface that have been damaged by exposure to the environment within the vacuum chamber.
Yet another aspect of the invention is an apparatus comprising a vacuum chamber, an optical element disposed within the vacuum chamber, an ion source disposed within the vacuum chamber, and an actuator mechanically coupled to the ion source and arranged to aim the ion source toward at least a portion of the exposed surface of the optical element in response to a control signal.
Still another aspect of the invention is apparatus for producing EUV light for semiconductor photolithography, the apparatus comprising a vacuum chamber in which a source material is vaporized to produce the EUV light, a multilayer mirror disposed in the vacuum chamber, an ion source disposed within the vacuum chamber, and an actuator mechanically coupled to the ion source and arranged to aim the ion source toward at least a portion of the exposed surface of the optical element in response to a control signal.
Various embodiments are now described with reference to the drawings, wherein like reference numerals are used to refer to like elements throughout. In the following description, for purposes of explanation, numerous specific details are set forth in order to promote a thorough understanding of one or more embodiments. It may be evident in some or all instances, however, that any embodiment described below can be practiced without adopting the specific design details described below. In other instances, well-known structures and devices are shown in block diagram form in order to facilitate description of one or more embodiments.
With initial reference to
The EUV light source 20 also includes a target delivery system 24 for delivering target material in the form of liquid droplets or a continuous liquid stream. The target material may be made up of tin or a tin compound, although other materials could be used. The target delivery system 24 introduces the target material into the interior of a chamber 26 to an irradiation region 28 where the target material may be irradiated to produce plasma. In some cases, an electrical charge is placed on the target material to permit the target material to be steered toward or away from the irradiation region 28. It should be noted that as used herein an irradiation region is a region where target material irradiation may occur, and is an irradiation region even at times when no irradiation is actually occurring.
Continuing with
As described above, one of the technical challenges in the design of an optical element such as the collector 30 is extending its lifetime. The surface of the collector, which is usually a coating, becomes contaminated with source material, e.g., tin. In-situ cleaning using hydrogen radicals in a known manner can be used to remove this contamination from the collector surface. In-situ collector cleaning is very desirable because it dramatically reduces both tool downtime and the expense of collector replacement. Hydrogen radical—based cleaning does not, however, repair damage to the collector surface. This type of damage can be quite severe, as can be seen in
Thus, the surface damage of the collector coating is still present after cleaning has been performed. This surface damage can lead to accelerated degradation of collector reflectivity after the cleaning. In order to improve collector lifetime after cleaning so that reflectivity approaches that of a new collector, the collector surface damage needs to be repaired in-situ. As used herein, “repair” and its cognates refer to removing some or all of the collector material that has been damaged by exposure to the conditions in the chamber environment.
To achieve this end, in one embodiment, the present invention is a method of in-situ cleaning and repairing of a collector surface. The method will now be described in conjunction with
In a first step S1 the system is cleaned using a prior art hydrogen radical—based technique or any other suitable technique. The cleaning step S1 is carried out until it is determined in step S2 that a predetermined amount, e.g., preferably substantially all, of the tin has been removed. The determination on whether enough tin has been removed can be made using any desirable method. For example, the completion of step S1 can be determined by measurement, for example, by measuring the amount of residual tin, or simply continuing to perform step S1 for an amount of time that has been determined to be sufficient to remove enough of the tin residue.
Once it is determined in step S2 that enough of the tin has been removed from the collector surface, an ion source or gun such as ion gun 100 as shown in
As shown in
The vacuum chamber 26 is maintained at vacuum using a pump 120, which is preferably a high-throughput turbo-molecular pump (>500 L/sec pumping speed).
The ion gun 100 can be positioned near the primary focus of the collector 30 and pointed towards the collector surface. It creates a flux of ions towards the collector, with the cross-section size of the beam at the collector surface preferably in the range of 2-50 cm depending on the particular design of the ion gun 100. The ion beam can be scanned over the collector surface by aiming or tilting the ion gun 100 under the control of scanning control system 130. The scanning control system 130 can control the ion gun to repair the entire surface of the collector 30 or just the selected areas of the surface of collector 30. The scanning control system 130 accomplishes this by aiming the ion gun 100, for example, by tilting the head of ion gun 100 by controlling an actuator 140 that is mechanically coupled to the ion gun 100. As used herein, an actuator is any device for causing motion in response to a control signal. The scanning control system 130 may be implemented by any device that can generate control signals such as in response to user input or a control program, for example a processor suitably programmed in a manner that will be readily apparent to one having ordinary skill in the art.
The ion gun 100 bombards the selected areas of the surface of the collector 30 until a predetermined amount of the surface has been removed. This can be accomplished by measuring a parameter which depends on the amount of removed material, e.g., reflectivity. It can also be accomplished by bombarding the selected area of the surface with ions for an amount a time that has been determined to be sufficient to ensure removal of enough material.
The above description includes examples of one or more embodiments. It is, of course, not possible to describe every conceivable combination of components or methodologies for purposes of describing the aforementioned embodiments, but one of ordinary skill in the art may recognize that many further combinations and permutations of various embodiments are possible. Accordingly, the described embodiments are intended to embrace all such alterations, modifications and variations that fall within the spirit and scope of the appended claims. Furthermore, to the extent that the term “includes” is used in either the detailed description or the claims, such term is intended to be inclusive in a manner similar to the term “comprising” as “comprising” is construed when employed as a transitional word in a claim. Furthermore, although elements of the described aspects and/or embodiments may be described or claimed in the singular, the plural is contemplated unless limitation to the singular is explicitly stated. Additionally, all or a portion of any aspect and/or embodiment may be utilized with all or a portion of any other aspect and/or embodiment, unless stated otherwise.
| Number | Date | Country | |
|---|---|---|---|
| Parent | 13650778 | Oct 2012 | US |
| Child | 14964319 | US |
