This disclosure relates to a method of simultaneously polishing a front surface and a back surface of a silicon wafer.
A process for producing a silicon wafer mainly includes a single crystal pulling step for forming a single crystal ingot and a step of processing the formed single crystal ingot. This processing step typically includes a slicing step, a lapping step, a beveling step, an etching step, a polishing step, a cleaning step, etc., and through these steps, a silicon wafer having a mirror-finished surface is produced.
In the polishing step, chemical mechanical polishing (CMP) is typically used, in which a silicon wafer and a polishing cloth are relatively rotated and rubbed against each other. As is known, in CMP, the mechanical polishing action of abrasive grains in a polishing agent and the chemical polishing action of the polishing agent (alkaline aqueous solution) are combined, thus excellent smoothness is obtained. In this polishing step, the polishing is performed in multiple stages of for example, a double-side polishing step (rough grinding step) of simultaneously polishing the front and back surfaces of a silicon wafer using a double-side polishing apparatus as illustrated in
Rough grinding in an initial stage is performed with a view to polishing a silicon wafer to a desired thickness. Double-side polishing is performed by polishing under a condition of a relatively high polishing rate using a hard polishing cloth for example made of polyurethane thereby obtaining a planarized silicon wafer with reduced variation in thickness. Finish polishing in a final stage is performed with a view to reducing the roughness of the surface of the silicon wafer. Single-side polishing is performed using a soft polishing cloth like suede and fine free abrasive grains thereby reducing the surface roughness of minute irregularities on the silicon wafer surface, such as nanotopography or haze.
JP 5754659 B (PT1—see Claims 1 and 2, Example 1, etc.) discloses a method for polishing silicon wafers comprising: a rough polishing step of simultaneously polishing a front surface and a rear surface of the silicon wafer; and a finish polishing step of finish polishing the rough polished surface after the rough polishing, wherein the rough polishing includes a first-step polishing of eliminating a native oxide film using a polishing liquid containing free abrasive grains, and a second-step polishing of polishing the front and rear surfaces of the silicon wafer from which the native oxide films have been eliminated using a polishing liquid in which a water-soluble polymer is added to an amine aqueous solution with no free abrasive grains so that the polishing amount of the silicon water is 5 μm to 10 μm one side after the first-step polishing. In addition, in Example 1, the second-step polishing is performed using a double-side polishing apparatus used in the first-step polishing.
PTL 1: JP 5754659 B
The two-stage rough polishing described in PTL 1 is performed based on the design concept as described below That is, in the rough polishing step using a double-side polishing apparatus, the amount of polishing is likely larger in a peripheral portion of a wafer as compared with the center thereof, and this results in a problem of roll-off of the peripheral portion of the wafer. To address this problem, in PTL 1, the rough polishing is performed using a polishing liquid containing a water-soluble polymer with no abrasive grains, and the roll off amount (ROA) of the peripheral portion of the wafer is reduced by the action of the water-soluble polymer. Further, in most cases, a native oxide film with a thickness of around 5 angstrom to 20 angstrom is formed on the silicon wafer before the rough polishing step, and the native oxide film is hardly removed by a polishing liquid with no abrasive grains. This being the case, the native oxide film is removed by performing a first-step polishing using a polishing liquid containing abrasive grains. In Example 1 of PTL 1, the first-step polishing including the removal of the native oxide film with an amount of polishing of 0.5 μm for one side (1 μm for both surfaces) and second-step polishing with an amount of polishing of 5 μm for one side (10 μm for both surfaces) are performed.
However, in the double-side polishing method described in PTL 1, switching of the polishing liquids between the first-step polishing using the polishing liquid containing abrasive grains and the second-step polishing using the polishing liquid containing no abrasive grains in the case of performing the first-step polishing and the second-step polishing using a common double-side polishing apparatus is not discussed. The studies made by the inventors of this disclosure demonstrated that the carrier plate was oscillated at the start of the second-step polishing depending on how the switching of the polishing agents is performed, and the oscillation caused micro scratches on the front and back surfaces of the silicon wafer during polishing.
In light of the above problems, it could be helpful to provide a method of double-side polishing a silicon wafer, which can prevent the formation of micro scratches on the front and back surfaces of the silicon wafer during polishing.
The inventors of this disclosure have conducted diligent studies to solve the above problems and found the following. In double-side polishing, the used polishing agent is typically recovered into a polishing agent supply tank and recycled to be repeatedly used as a polishing agent. In this regard, when first-stage polishing and second-stage polishing are performed using a common double-side polishing apparatus, a method of supplying pure water to polishing cloths at the same time as the termination of the supply of a polishing agent to the polishing cloths after the end of the first-stage polishing in order to prevent mixing of the polishing agent used in the first-stage polishing and the polishing agent used in the second-stage polishing thus removing the abrasive grains attached to the wafer and the carrier plate and cleaning the polishing cloths with pressurized water can be conceived. However, in such a case, the carrier plate was found to be oscillated along with the generation of noise from the carrier plate at the start of the second-stage polishing. Since the rotation of the upper and lower plates is resumed in the absence of abrasive grains, the pressing force from the polishing cloths is directly applied to the carrier plate. Accordingly, the frictional resistance between the wafer along with the carrier plate and the polishing cloths increases, thus the oscillation is considered to be caused due to the increased pressure load on the wafer from the upper and lower plates. In view of the above, the inventors studied techniques to switch the polishing agents without resuming the rotation of the upper and lower plates in the absence of abrasive grains. They contemplated reducing the oscillation of the carrier plate by establishing a transition period during which polishing is performed in the presence of both the polishing agent used in the first-stage polishing and the polishing agent used in the second-stage polishing being deliberately mixed instead of preventing mixing of the polishing agents and experimentally demonstrated that the idea was right.
This disclosure is based on the above findings, and we propose the following features.
(1) A method of double-side polishing a silicon wafer using a double-side polishing apparatus including a carrier plate having one or more retainer openings for retaining the silicon wafer, and an upper plate and a lower plate which each have a surface provided with a polishing cloth and are situated to face each other with the carrier plate therebetween, for simultaneously polishing a front surface and a back surface of the silicon wafer by relatively rotating the upper plate and the lower plate with respect to the carrier plate in rotation with the polishing cloths of the upper plate and the lower plate being in contact with the front surface and the back surface of the silicon wafer loaded in each retainer opening, respectively, comprising in succession:
a first polishing step of performing double-side polishing while supplying a first polishing agent that is an alkaline aqueous solution containing abrasive grains to the polishing cloths;
subsequent to the first polishing step, a polishing agent switching step of stopping the supply of the first polishing agent and starting the supply of a second polishing agent that is an alkaline aqueous solution containing a water-soluble polymer with no abrasive grains, with the polishing cloths of the upper plate and the lower plate being in contact with the front surface and the back surface of the silicon wafer, respectively and with the upper plate and the lower plate being continuously rotated; and
a second polishing step of performing double-side polishing while supplying the second polishing agent to the polishing cloths after the polishing agent switching step.
(2) The method of double-side polishing a silicon wafer, according to (1) above,
wherein with respect to surface pressure applied to the front surface and the back surface of the silicon wafer by the upper plate and the lower plate,
in the first polishing step, the double-side polishing is performed at a first surface pressure and the surface pressure is reduced in a last stage of the first polishing step to a second surface pressure that is lower than the first surface pressure at the end of the first polishing step, and
the double-side polishing is performed at the second surface pressure in the second polishing step.
(3) The method of double-side polishing a silicon wafer, according to (2) above,
wherein the second surface pressure is lower than the first surface pressure by 5% to 40%.
(4) The method of double-side polishing a silicon wafer, according to any one of (1) to (3) above,
wherein in the first polishing step, the double-side polishing is performed to achieve a polishing amount of 80% to 99.5% with respect to a total polishing amount of the first and second polishing steps, and
in the second polishing step, the double-side polishing is performed in a polishing amount of 0.05 μm to 0.5 μm on each surface.
(5) The method of double-side polishing a silicon wafer, according to any one of (1) to (4) above,
wherein in the first polishing step, the first polishing agent having been used is recovered and then resupplied to the polishing cloths, and
in the second polishing step, the polishing agent having been used is recovered and then disposed of.
The method of double-side polishing a silicon wafer can prevent the formation of micro scratches on the front and back surfaces of the silicon wafer during polishing.
In the accompanying drawings:
First, referring to
A polishing agent is supplied through a polishing agent supply line 26 to the space between the upper and lower plates 14 and 16 via a channel extending through the upper plate 14 in the vertical direction. The details of a supply/recovery system for the polishing agent will be described hereafter.
With the double-side polishing apparatus 100, the plurality of silicon wafers W loaded in the plurality of openings 12 are sandwiched between the upper plate 14 and the lower plate 16, and the sun gear 22 and the internal gear 24 are rotated to relatively rotate the upper plate 14 and lower plate 16 with respect to the carrier plate 10 in rotation, with the front surface and the back surface of each silicon wafer W being contact with the polishing cloths 18 and 20, respectively while supplying a polishing agent to the polishing cloths 18 and 20. Thus, the front surface and the back surface of the plurality of silicon wafers W can be simultaneously polished.
It should be noted that the structure of a double-side polishing apparatus that can be used in a method of double-side polishing a silicon wafer according to this disclosure is not limited to the structure described above, and a sun gear (planetary gear) type or a sun-gearless type in which the carrier plate is circularly moved without rotation can be used.
In this embodiment, for rough grinding of a silicon wafer, a first polishing step of performing double-side polishing while supplying a first polishing agent that is an alkaline aqueous solution containing abrasive grains to the polishing cloths 18 and 20 is performed first, and a second polishing step of performing double-side polishing while supplying a second polishing agent that is an alkaline aqueous solution containing a water-soluble polymer with no abrasive grains to the polishing cloths 18 and 20 is then performed using the double-side polishing apparatus 100 used in the first polishing step.
The first polishing step in this embodiment is performed with a view to removing a natural oxide layer having a thickness of around 5 angstrom to 20 angstrom formed on a surface layer of each silicon wafer W and polishing the silicon wafer W to a substantial target thickness, using a polishing agent containing abrasive grains.
The total polishing amount of the first and second polishing steps is set within a range of roughly 2.5 μm to 10 μm for each surface. In the first polishing step, the double-side polishing is performed to achieve a polishing amount of 80% to 99.5% with respect to the total polishing amount of the first and second polishing steps. When the polishing amount of the first polishing step is less than 80% of the total polishing amount, the second polishing step of a lower polishing rate is required to be performed for a longer time to achieve a target thickness, resulting in reduced productivity. Meanwhile, when the polishing amount of the first polishing step exceeds 99.5% of the total polishing amount, the amount of removal by polishing in the second polishing is too small, thus the effect of reducing the roll off amount of the peripheral portion of the wafer is insufficient.
On the other hand, the second polishing step in this embodiment is performed with a view to reducing the roll off amount of the peripheral portion of the wafer by slightly polishing both surfaces of the silicon wafers W using a polishing agent containing a water-soluble polymer with no abrasive grains. Specifically, in the second polishing step, the double-side polishing is performed to achieve a polishing amount of 0.05 μm to 0.5 μm for each surface. When the polishing amount for each surface is less than 0.05 μm, the effect of reducing the roll off amount of the peripheral portion of the wafer is insufficient. On the other hand, since the polishing agent containing a water-soluble polymer with no abrasive grains has a low polishing rate, a polishing amount exceeding 0.5 μm results in reduced productivity.
In PTL 1, since the first-step polishing using a polishing liquid containing abrasive grains is mainly aimed at removing a native oxide film, its polishing amount is 0.5 μm for each surface, and the target thickness is achieved by performing double-side polishing of 5 μm to 10 μm for each surface by the second-step polishing using a polishing liquid containing a water-soluble polymer with no abrasive grains. By contrast, in this embodiment, the first-stage polishing at a high polishing rate is mainly performed to achieve the target thickness, thereby obtaining high productivity. On the other hand, when a polishing amount of 0.05 μm or more for each surface is ensured in the second-stage polishing, the roll off amount of the peripheral portion of the wafer can be sufficiently reduced.
The pH of either the first polishing agent or the second polishing agent is preferably adjusted to a range of 9 to 12. When the pH is less than 9, the etching action is too weak, and defects due to processing, such as scratches and flaws are easily formed on the surfaces of the silicon wafers. When the pH exceeds 12, the handling of the solution itself is difficult. Further, as an alkaline agent, an alkaline aqueous solution in which any one of a basic ammonium salt, a basic potassium salt, and a base sodium salt is added; an alkali carbonate aqueous solution; or an alkaline aqueous solution in which amine is added is preferably used. Alternatively, an aqueous solution of hydrazine or amines can be used, and amine is desirably used in particular in terms of increasing the polishing rate.
In the first polishing agent, the abrasive grains used may be made of silica, alumina, diamond, etc.; and the abrasive grains preferably contain SiO2 particles for reasons of low cost, dispersibility in the polishing agent, and the ease of controlling the particle diameter of the abrasive grains, etc. The mean primary particle diameter of the abrasive grains can be set to 30 nm to 100 nm when measured by the BET method.
In the second polishing agent, one or more water-soluble polymers selected from nonionic water-soluble polymers are preferably used. Examples include hydroxyethyl cellulose (HEC), polyethylene glycol (PEG), and polypropylene glycol (PPG). The concentration of the water-soluble polymer is preferably 1 ppm or more, more preferably 10 ppm or more in terms of sufficiently reducing the roll off amount of the peripheral portion of the wafers. Further, with a view to preventing the reduction of the productivity due to a significantly reduced polishing rate, the concentration is preferably 200 ppm or less, more preferably 100 ppm or less.
For the polishing cloths 18 and 20, a polishing cloth made of polyester non-woven cloth and a polyurethane polishing cloth can be given as examples, and a foamed polyurethane polishing cloth excellent in the minor-polishing precision on the polished surfaces of the silicon wafers is desirably used in particular. For the polishing cloths 18 and 20, a Shore D hardness of 70 to 90 according to JIS K 6253-1997/ISO 7619, a compressibility of 1% to 5%, especially 2% to 3% are preferred.
The polishing rate in the first polishing step is preferably 0.1 μm/min to 1.0 μm/min, and the polishing rate in the second polishing step is preferably 0.03 μm/min to 0.5 μm/min.
The rotation speed of the upper and lower plates, the rotation speed of the silicon wafers, the surface pressure, and the polishing agent supply amount may appropriately be set to achieve the above polishing rates. The rotation speed of the upper and lower plates may be set to a range of 5 rpm to 40 rpm through the first and second polishing steps. The surface pressure may be set within a range of 50 g/cm2 to 300 g/cm2. In the second polishing step, since the polishing agent with no abrasive grains is used, the frictional resistance is high; therefore, the surface pressure in the second polishing step is desirably set lower than the surface pressure in the first polishing by 5% to 40%.
Here, this embodiment is characterized in the technique of switching the first polishing agent and the second polishing agent when performing the first polishing step and the second polishing step using the common double-side polishing apparatus 100. To explain the technical significance of this embodiment, double-side polishing methods according to Comparative Examples 1 are 2 are first described with reference to
Referring to
Next, referring to
However, in both Comparative Examples 1 and 2, at the start of the second polishing step (Step S6), the oscillation of the carrier plate occurs. Since the rotation of the upper and lower plates is resumed in the absence of abrasive grains, the frictional resistance between the wafer along with the carrier plate and the polishing cloths increases, thus the oscillation is considered to be caused due to the increased pressure load on the wafer from the upper and lower plates.
On the other hand, referring to
Note that, in the second polishing step, the first polishing agent containing abrasive grains and the second polishing agent with no abrasive grains are mixed for a certain time period from the start of the second polishing step. Therefore, the recovery, circulation, and reuse of the polishing agent are preferably avoided. In this respect, as illustrated in
A supply/recovery system for polishing agents, with which such a method of processing a used polishing agent is implemented is described with reference to
In the first polishing step, while the first polishing agent containing abrasive grains is supplied through the first polishing agent supply line 30 by controlling the switching valve 28, the used first polishing agent is recovered into the recovery tank 42 by controlling the switching valve 40 and is reused. In the second polishing step, while the second polishing agent is supplied through the second polishing agent supply line 34 by controlling the switching valve 28, the used polishing agent is disposed of through the waste liquid line 46 by controlling the switching valve 40.
Next, the second polishing step is performed using the second polishing agent with no abrasive grains, thus the frictional resistance between the wafers along with the carrier plate and the polishing cloths easily increases. To address this, with respect to the surface pressure applied to the surfaces of the silicon wafers by the upper and lower plates, the second polishing step is preferably performed at a surface pressure that is lower than the surface pressure in the first polishing step. This can reliably prevent the oscillation of the carrier plate. As a result, the formation of micro scratches on the front and back surfaces of the silicon wafers during polishing can be sufficiently reduced. In this regard, in this embodiment, since the first polishing step and the second polishing step are performed in succession, the surface pressure is reduced in the last stage of the first polishing step, and the surface pressure is reduced to the surface pressure of the second polishing step at the end of the first polishing step as illustrated in
With the use of the double-side polishing apparatus depicted in
With the use of the double-side polishing apparatus depicted in
With the use of the double-side polishing apparatus depicted in
As illustrated in
<Evaluation of Micro Scratches>
The back surface of each wafer having been double-side polished was observed using a surface defect inspection system manufactured by KLA-Tencor Corporation: Surfscan SP2, in DWO mode (Darkfield Composite Oblique mode), and the number of light point defects (LPDs) having a defect size of 160 nm or more, observed in the wafer surfaces, was counted as the number of micro scratches formed. The results are given in Table 1.
As described above, many micro scratches were formed in Comparative Examples 1 and 2, whereas micro scratches were reduced in Example 1, and micro scratches were reduced more in Example 2 than in Example 1.
<Wafer Flatness Evaluation>
The ESFQR (Edge Site Front least sQuares Range) of each silicon wafer double-polished in Examples 1 and 2 was evaluated using a flatness measurement system (WaferSight manufactured by KLA-Tencor Corporation). The ESFQR is an evaluation index for the flatness of the edge, of which flatness is easily reduced (site flatness), and indicates the degree of the edge roll-off amount. The ESFQR is defined as the difference between the maximum value and the minimum value of the deviation from the reference plane (Site Best Fit Surface) found by the least square method from the thickness distribution of each site that is a unit area obtained by equally dividing a ring-shaped region along the wafer edge in the circumferential direction. Here, the ESFQR of the 72 sites obtained by dividing a ring-shaped peripheral region set in a range of 2 mm to 32 mm from the outermost periphery of the wafer (sector length: 30 mm) was measured, and the average for all the sites: ESFQR_mean was determined.
As a result, silicon wafers having high flatness with an average ESFQR: ESFQR_mean of 30 nm or less achieved by reducing the edge roll-off were found to be obtained in both Examples 1 and 2.
The method of double-side polishing a silicon wafer prevents the formation of micro scratches on the front and back surfaces of the silicon wafer during polishing.
Filing Document | Filing Date | Country | Kind |
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PCT/JP2017/031496 | 8/31/2017 | WO | 00 |