Integrated circuits are formed on a semiconductor wafer. Photolithographic patterning processes use ultraviolet light to transfer a desired mask pattern to a photoresist on a semiconductor wafer. Etching processes may then be used to transfer to the pattern to a layer below the photoresist. This process is repeated multiple times with different patterns to build different layers on the wafer substrate and make a useful device.
Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
Numerical values in the specification and claims of this application should be understood to include numerical values which are the same when reduced to the same number of significant figures and numerical values which differ from the stated value by less than the experimental error of conventional measurement technique of the type described in the present application to determine the value. All ranges disclosed herein are inclusive of the recited endpoint.
The term “about” can be used to include any numerical value that can vary without changing the basic function of that value. When used with a range, “about” also discloses the range defined by the absolute values of the two endpoints, e.g. “about 2 to about 4” also discloses the range “from 2 to 4.” The term “about” may refer to plus or minus 10% of the indicated number.
The present disclosure relates to structures which are made up of different layers. When the terms “on” or “upon” are used with reference to two different layers (including the substrate), they indicate merely that one layer is on or upon the other layer. These terms do not require the two layers to directly contact each other, and permit other layers to be between the two layers. For example all layers of the structure can be considered to be “on” the substrate, even though they do not all directly contact the substrate. The term “directly” may be used to indicate two layers directly contact each other without any layers in between them.
The present disclosure relates to various methods for improving the performance of an integrated circuit by reducing leakage current, especially leakage current through a continuous poly on diffusion edge (CPODE) structure. In this regard, a CPODE structure or pattern may be used as an electrically insulating or dielectric feature on the wafer. This provides electrical isolation between neighboring active device regions, such as transistors. This may be useful in reducing parasitic capacitance between active device regions, which increases processing speed. A CPODE structure can also be used as a vertically-oriented capacitor.
In this regard, the leakage path through the CPODE structure may be present below a shallow trench isolation (STI) layer or region. The CPODE structure is formed by etching away a pair of fins and forming a pair of trenches in the substrate where the pair of fins was originally located. The leakage path may be present in the area between the pair of fins, as will be further explained. The removal of the fins and substrate to form the trenches is performed by cycling continuously between two different etchants, a fin etchant and a plasma etch. The fin etchant removes the fins and the substrate to form the trenches. Byproducts of the fin etch may form a protective layer on the exposed fins and substrate, reducing the efficacy of continuous fin etching. The use of the plasma etch removes any byproducts that may be formed during the fin etch, enhancing subsequent fin etching.
Referring first to
In
Continuing, a shallow trench isolation (STI) region or layer 220 is present above the substrate 202 between the fin pairs 204, 206, 208 and between the fins 210 themselves. The dielectric material in the STI layer is commonly silicon dioxide, although other dielectric materials can also be used such as undoped polysilicon, silicon oxide (e.g. SiO2), silicon nitride, silicon oxynitride, fluoride-doped silicate glass, or other low-k dielectric material. The deposition can be done using physical vapor deposition (PVD) or chemical vapor deposition (CVD) or spin-on processes known in the art, or can be grown via oxidation. If desired, the dielectric material can be deposited to a level above that of the fins, then recessed back down to the desired height by etching (prior to removal of the hard mask which protects the fins from such etching).
Next, an I/O oxide layer 230 is present, which covers the fins 210 above the STI layer and the STI layer 220 itself. This can be applied using ALD, CVD, or other deposition processes. The I/O oxide layer is commonly made from a silicon oxide.
Neighboring pairs of fins are separated by a vertically-oriented isolation dielectric structure 232.
Referring now to
The source/drain electrodes 234 are located below interlayer dielectric (ILD) regions 236. The ILD regions electrically separate the source/drain regions from the final gate terminals or electrodes. The ILD regions may be formed from any dielectric material, and do not need to be a high-k dielectric material. Suitable dielectrics could include silicon nitride, a silicon oxide (e.g. SiO2), phosphosilicate glass (PSG), fluorosilicate glass (FSG), undoped silicate glass (USG), high-stress undoped silicate glass (HSUSG), borosilicate glass (BSG), or any combination thereof. The ILD can be deposited using any appropriate method, for example CVD. The ILD regions 236 are surrounded on three sides by a continuous etch stop layer (CESL) 238. The CESL is commonly made from silicon nitride.
Located between ILD regions are dummy gate regions 240. The dummy gate region is typically formed from polysilicon, and is used to define the shape of the final gate terminal or electrode. The vertical surfaces of the dummy gate regions 240 are covered with a low-k dielectric layer 250 having a dielectric constant equal to or less than that of silicon nitride (˜7). Suitable materials may include various nitrides or oxides. CPODE structures are typically formed where a dummy gate region is located. The Y-axis views of
Finally, a hard mask layer 260 is present and covers the surface of the substrate. Silicon nitride is commonly used as the hard mask layer. As indicated in
The structure illustrated in
Next, the low-k dielectric layers 250 are applied to the exposed vertical surfaces of the polysilicon layer within the large channels. This could be done either by deposition and etch or by thermal oxidation or other suitable process. Ion implantation is subsequently performed to form the source/drain regions 234. The CESL 238 is then applied to the large channels to cover the exposed surfaces. A dielectric material is then applied to fill the large channels and form the ILD regions 236. The PR layer is then removed. Planarization may be performed, and the hard mask layer 260 is then applied.
Referring now to
In optional step 105, the hard mask layer 260 is removed. This can be done by etching or chemical-mechanical planarization (CMP). The resulting structure is shown in
In optional step 110, a new hard mask layer 266 having thickness 267 is applied upon the dummy gate regions 240 and the ILD regions 236. The resulting structure is shown in
Next, referring to
Next, in step 125, a photoresist (PR) layer 256 is applied and patterned. The photoresist layer may be applied, for example, by spin coating, or by spraying, roller coating, dip coating, or extrusion coating. The photoresist can be baked or cured to remove solvent and harden the photoresist layer. The photoresist is then exposed to patterned light, and then developed to obtain the patterned photoresist layer. In particular embodiments, extreme ultraviolet (EUV) light having a wavelength of about 13.5 nm is used for patterning, as this permits smaller feature sizes to be obtained. Referring again to
Next, in optional step 127, dry etching is performed to etch through the middle layer 254 and the bottom layer 252 using appropriate etchants. In step 130, dry etching is performed to etch through the hard mask layer 266 and expose the dummy gate region 242. This may be referred to as Hard Mask Open (HMO).
Generally, any dry etching step used herein may be performed using plasma etching processes such as reactive ion etching (RIE) or inductively coupled plasma (ICP), or combinations thereof, as appropriate. The etching may be anisotropic. Depending on the material, etchants may include carbon tetrafluoride (CF4), hexafluoroethane (C2F6), octafluoropropane (C3F8), fluoroform (CHF3), difluoromethane (CH2F2), fluoromethane (CH3F), trifluoromethane (CHF3), carbon fluorides, nitrogen (N2), hydrogen (H2), oxygen (O2), argon (Ar), xenon (Xe), xenon difluoride (XeF2), helium (He), carbon monoxide (CO), carbon dioxide (CO2), fluorine (F2), chlorine (Cl2), oxygen (O2), hydrogen bromide (HBr), hydrofluoric acid (HF), nitrogen trifluoride (NF3), sulfur hexafluoride (SF6), boron trichloride (BCl3), ammonia (NH3), bromine (Br2), nitrogen trifluoride (NF3), or the like, or combinations thereof in various ratios.
In step 135, the PR layer 256 is removed. In optional step 140, the middle layer 254 is removed. In optional step 145, the bottom layer 252 is removed. The resulting structure is shown in
In optional step 150, wet cleaning is performed. The cleaning solution will depend on the etch recipe and the exposed layers. Examples of cleaning solutions may include deionized water, dilute HF, and other conventional solutions.
Next, in step 155, the exposed dummy gate region 242 is removed by etching. Referring back to
In optional step 160, wet cleaning is performed again. In step 165, the I/O oxide layer is removed from the exposed portions 216 of the pair of fins. The resulting structure is shown in
Next, referring to
The first etchant can be referred to as a fin etchant, and is selective for the material from which the fins and the substrate are made. In some embodiments, the fin etchant is selective for silicon. Such etchants may include HBr, NF3, O2, CF3Br, BCl3, and/or Cl2, in appropriate combinations and ratios. During etching with the first etchant, many different byproducts can be formed which can be redeposited upon the exposed portions of the fins and the substrate and act as a protective layer, stopping the etching process. Thus, the second etchant is used to remove the deposited byproducts and re-expose the fins and the substrate. In particular embodiments, the second etchant comprises argon, and may also include other gases for removing the byproducts, such as other fluoride-containing molecules like CF4.
As illustrated in
In optional step 185, wet cleaning is performed again. In step 190, the pair of trenches 270 and the empty gate volume 244 are filled with a dielectric material 280 to form the CPODE structure 284. Any low-k dielectric material having a dielectric constant equal to or less than that of silicon nitride (˜7) can be used. In some particular embodiments, the dielectric material comprises silicon nitride, a silicon oxide, or combinations thereof. The dielectric material can be deposited using CVD, PVD, or ALD, although CVD is commonly used due to the high aspect ratio needed for the deposition. The dielectric material may also form a dielectric layer 282 over the hard mask layer 266.
In step 195, the integrated circuit is planarized to remove the hard mask layer 266. If present, the dielectric layer 282 is also removed. This planarization may be performed, for example, using CMP.
The substrate may be further processed to obtain the desired integrated circuit. For example, the various dummy gate regions may be removed and then filled with, for example, a metal gate.
The depth 275 of the trench is typically measured from the peak 212 of the fin 210, because the fin must be etched away before the trench can be etched. The fin is shown here in dotted line. In some particular embodiments, the depth 275 of the trench is from about 145 nanometers to about 185 nm.
Continuing, the portion of the STI layer 222 located between the trenches 270 has a bottom width 223. The extra material 214 located between the fins should also be considered part of the substrate 202, and has a top width 291. During the etching that forms the trenches, the sides of the extra material 214 are also etched away. Thus, in some embodiments, the bottom width 223 of the STI layer located between the trenches is greater than the top width 291 of the substrate between the trenches 270. These two values are measured where the STI layer and the substrate meet.
As previously mentioned, the extra material 214 can form a leakage path for leakage current. Due to the presence of the trenches and the dielectric material therein, the extra material 214 becomes a depletion region due to diffusion of charge carriers into the source/drain regions and out of the extra material. As a result, leakage current through this path is reduced or eliminated.
The thickness of the substrate between the pair of trenches is indicated with reference numeral 293. The thickness of the substrate outside the pair of trenches is indicated with reference numeral 295. The difference between these two values may be referred to as the depth of the substrate between the pair of trenches, and is indicated with reference numeral 297. In particular embodiments, the depth of the substrate between the pair of trenches is from about 5 nm to about 16 nm. This depth may also be referred to as the STI-Si gap.
Initially, referring to
In optional step 310, wet cleaning is performed. Next, in step 315, the exposed dummy gate region 242 is removed by etching. The resulting structure is shown in
In optional step 320, wet cleaning is performed again. In step 325, the I/O oxide layer is removed from the exposed portions 216 of the pair of fins. The resulting structure is shown in
Next, in step 335, a first etch is performed using a fin etchant to etch away the exposed portions 216 of the fin. Then, in step 340, a second etch is performed with plasma to remove any byproducts of the first etch. In particular embodiments, the first etch is a silicon etch and the second etch is an argon plasma etch. Referring to
In optional step 350, wet cleaning is performed again. In step 355, the trenches 270 are filled with a dielectric material 280 to form the CPODE structure. The empty gate volume 244 is also filled. The resulting structure is shown in
In step 360, planarization is performed to remove the hard mask layer 266. The dummy gate regions 240 and the ILD regions 236 are also exposed for further processing. The resulting structure is shown in
Initially, the method begins with the wafer substrate as shown in
Next, in step 420, the middle layer, the bottom layer, and the hard mask layer are etched through to expose a dummy gate region 242. In step 425, the PR layer, the middle layer, and the bottom layer are removed. The resulting structure is seen in
In optional step 430, wet cleaning is performed. Next, in step 435, the exposed dummy gate region 242 is etched to expose portions 216 of a pair of fins 210. The resulting structure is shown in
In optional step 440, wet cleaning is performed again. In step 445, an oxide layer is removed from the exposed portions 216 of the pair of fins. The resulting structure is shown in
Next, in step 455, the exposed portions 216 of the pair of fins are etched until a pair of trenches 270 is created in the substrate 202 in the same location as the exposed portions of the pair of fins. The resulting structure is shown in
In optional step 460, wet cleaning is performed again. In step 465, the trenches 270 and the etched dummy gate region 242 are filled with a dielectric material 280 to form the CPODE structure. The resulting structure is shown in
Finally, in step 470, planarization is performed to remove the hard mask layer 266. The resulting structure is shown in
Referring back to
Some embodiments of the present disclosure thus relate to methods for reducing leakage current in an integrated circuit. A hard mask layer is patterned to expose a dummy gate region located above a pair of fins and between two isolation dielectric regions. The dummy gate region between the two isolation dielectric regions is removed to expose portions of the pair of fins and form a gate volume. An oxide layer on the exposed portions of the pair of fins is removed. The pair of fins are removed to create a pair of trenches in a substrate below an STI layer. Extra material located between the pair of fins and below the STI layer is also removed. This is done by cycling between etching with a substrate etchant and etching with argon plasma. The pair of trenches and the gate volume are then filled with a dielectric material such that the dielectric material either partially or completely separates the substrate from the STI layer.
Other embodiments of the present disclosure also relate to methods for isolating a depletion region below a shallow trench isolation (STI) region. A first etch is performed with an etchant to etch away exposed portions of a pair of fins located on opposite sides of the leakage path. A second etch is performed with plasma to remove any byproducts of the first etch. Cycling between the first etch and the second etch continues until a pair of trenches is formed in a substrate, wherein the trenches extend below the depletion region. The pair of trenches is then filled with a dielectric material to isolate the depletion region from the STI region.
Other embodiments of the present disclosure also relate to methods for forming a CPODE structure. A bottom layer and a middle layer are applied over a hard mask layer. A photoresist layer is applied over the middle layer and patterned. Etching through the middle layer, the bottom layer, and the hard mask layer is performed to expose a dummy gate region. The dummy gate region is etched to expose portions of a pair of fins. The exposed portions of the pair of fins are dry etched until a pair of trenches is created in a substrate in the same location as the exposed portions of the pair of fins. The dry etching is performed by cycling between a first etchant that is selective for the fins and a second different etchant for removing byproducts produced by the first etchant. The pair of trenches and the etched dummy gate region are filled with a dielectric material.
The present disclosure also relates to a wafer substrate or integrated structure or semiconductor device that includes a CPODE structure. The CPODE structure includes a pair of trenches extending into the substrate that surrounds a leakage path or depletion region running along an X-axis. The leakage path or depletion region is located below an STI region located between the pair of trenches. The CPODE structure also includes a gate volume that runs in the Y-axis and is located above the substrate and above the pair of trenches. The pair of trenches and the gate volume are filled with a dielectric material. The dielectric material also fills a volume below the STI layer, or in other words between the STI layer and the substrate. The dielectric material can completely replace the depletion region, joining the pair of trenches together in the volume below the STI layer.
The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.
This application claims priority to U.S. Provisional Patent Application Ser. No. 63/434,702, filed on Dec. 22, 2022, which is incorporated by reference in its entirety.
Number | Date | Country | |
---|---|---|---|
63434702 | Dec 2022 | US |