1. Field of the Invention
The present invention relates to methods of producing an oscillator by wet etching, and wet etching apparatuses for producing an oscillator by wet etching.
2. Related Background Art
In a process of producing an oscillator by wet etching, detection of a terminal time point of the wet etching is one of the important technical considerations. Conventionally, such detection is executed by a method of managing the etching time. Further, as illustrated in FIG. 8A, a thickness sensor 51 is arranged, and the etching process is performed while monitoring the thickness of an etched portion of a semiconductor wafer 41 by the thickness sensor 51 (see JP 2001-144068 A). In FIG. 8A, k designates a predetermined measurement point, B designates a light beam of infrared radiation or the like, 41a designates a lower surface of a circuit substrate 41 or the like, 41b designates an etching surface, 42a designates a concave portion, and 43 designates a mask formed on the etching surface 41b.
Furthermore, there has also been proposed a method of executing etching while monitoring the operating characteristics of an object to be etched, as illustrated in FIG. 8B (see JP 2007-115939 A). This method uses a dry etching apparatus having a dry etching unit 1 and a housing 4, and a quartz oscillator 2 is placed so as to be etched under the same condition as a material 5 to be etched. A thickness control apparatus 3 monitors the frequency of the quartz oscillator 2 during the etching process. The apparatus 3 obtains a weight removed from the quartz oscillator 2 based on a change in its frequency, and stops the etching process when the removed weight is found to reach a predetermined value.
However, in the method disclosed in JP 2001-144068 A, the thickness of the etched portion is merely monitored during the etching process. Further, in the method disclosed in JP 2001-144068 A, the amount of etched weight of the material can be indirectly monitored, and the amount can be accurately controlled. However, in a case where the material 5 is an oscillator, it is not easy to regulate the resonance frequency of the oscillator.
According to one aspect of the present invention, there is provided a method of producing an oscillator, which includes a first step, a second step and a third step. In the first step, an oscillator is formed in a substrate immersed in an etchant, by wet etching. In the second step, the wet etching is stopped. In the third step, the oscillation of the oscillator in the etchant is excited, and the oscillating condition of the excited oscillator relevant to a target frequency of the oscillator is detected. The third step is performed at least once prior to the second step.
According to another aspect of the present invention, there is provided a wet etching apparatus for producing an oscillator, which includes an etching bath for storing an etchant, an exciting portion for exciting the oscillation of an object to be etched, and a detecting portion. The detecting portion detects the oscillating condition of the object excited by the exciting portion in the etchant.
According to the present invention, when the oscillator is formed by processing the object using the wet etching, the oscillating condition of the object excited in the etchant is detected. Accordingly, the terminal point of the etching process can be readily determined by detecting a target oscillating condition. Thus, invariable maintenance of the oscillation characteristics, particularly the resonance frequency, of the oscillator can be readily achieved with accuracy.
The fundamental embodiment of an oscillator producing method of this invention includes a first step of wet-etching an oscillator in a substrate immersed in an etchant or etching liquid, a second step of stopping the wet etching, and a third step. The third step is performed at least once before the second step. In the third step, the oscillation of the oscillator being formed in the etchant is excited, and the oscillating condition, such as amplitude, resonance frequency or the like, of the oscillator relevant to a target frequency of the oscillator in the etchant is detected. Thus, the oscillating condition of the oscillator can be detected during the etching process.
Accordingly, even in a case where there exist variations in thickness and the like of the substrate and an invariable control of the oscillation characteristics of the oscillator is hard to attain even if the etching amount of the oscillator is accurately controlled, it is relatively easy to form the oscillator with uniformly maintained oscillation characteristics. Thus, in the present invention, the etching process can be executed so that the resonance condition of the oscillator is achieved at the target frequency.
More specifically, the following configurations can also be adopted. In the third step in a first configuration, the oscillating condition of the oscillator is detected by using the exciting unit and a detecting unit for detecting the oscillating condition of the oscillator caused by the exciting unit. In the second step, the wet etching is stopped at the time when the detecting unit detects that the oscillating condition of the oscillator has reached the resonance condition at the target frequency in the third step. In this configuration, the oscillator is actually oscillated in the etchant, and its oscillating condition is detected. Thus, the etching process can be surely stopped at the time the resonance condition of the oscillator exactly occurs at the target frequency.
In another configuration, the excited frequency of the oscillation in the third step is set equal to the target frequency. In this configuration, the oscillator is excited and oscillated at the target frequency at all times. Therefore, there is no need of detecting the frequency of the oscillator. When the detecting portion detects that the amplitude of the oscillator has reached the maximal extreme value, it can judge that the oscillator has reached the resonance condition at the target frequency. Accordingly, the etching process can be readily stopped at an appropriate point of time.
In another configuration, the frequency of the oscillation excited in the third step is set to periodically change in a range including the target frequency. In this configuration, a change in the resonance frequency of the oscillator can be detected at any time during the etching process, and the etching proceeding condition of the oscillator can be detected. Therefore, the etching process only needs to be stopped at the time it is judged that the oscillator has reached the resonance condition at the target frequency. Hence, the etching process can be readily stopped exactly at an appropriate point of time.
In the third step in another configuration, energy for exciting the oscillation of the oscillator is transmitted to the oscillator through a medium of the etchant. In this configuration, both the oscillator and the etchant can be simultaneously oscillated, and the etchant can be stirred. Therefore, the oscillator can be accurately etched in a relatively short time.
In the third step in yet another configuration, energy for exciting the oscillation of the oscillator is transmitted to the oscillator through a medium of a supporting unit for supporting the oscillator. In this configuration, the oscillation energy can be efficiently transmitted to the oscillator in the etchant without adverse influence of the flow of the etchant, and the amplitude of the oscillation of the oscillator can be enlarged. Therefore, the oscillating condition of the oscillator can be readily detected with accuracy.
The etchant can be an alkaline solution. In this configuration, an accurate etching process can be achieved using crystallographically anisotropic etching. The oscillator can be readily etched with accuracy.
The etchant can be a mixture acid of hydrofluoric acid and nitric acid. The etching rate of this mixture acid is relatively fast. Therefore, the oscillator can be processed in a relatively short time. The oscillator can be provided at relatively low cost.
Further, the oscillator can be fabricated by the following wet etching apparatus for producing an oscillator. The apparatus can include an etching bath for storing an etchant, an exciting portion for exciting the oscillation of an object to be etched, and a detecting portion. The detecting portion detects the oscillating condition of the object excited by the exciting portion in the etchant. Such an etching apparatus can readily produce an oscillator with high performance and preferable oscillation characteristics at relatively low cost.
Preferred embodiments of the present invention will be hereinafter described with reference to the drawings.
A first embodiment of an oscillator producing method and wet etching apparatus 100 will be described with reference to
As illustrated in
When the oscillator 112 oscillates in the torsional manner, the amplitude of this torsional movement of the oscillator 112 can be made larger than those of the other oscillation modes. Accordingly, the detecting unit 105 can readily detect the oscillating condition of the oscillator 112 with accuracy. Thus, when the support unit 103 excites the back and forth oscillation about the axis of the elastic supporting hinge, the torsional oscillation of the oscillator 112 can be efficiently generated. Under the resonance condition at the target frequency, the oscillator 112 largely oscillates in the torsional manner. Thereby, the resonance condition can be surely detected. In this embodiment, the oscillating frequency of the exciting unit 104 is an etching stop frequency fs that is, for example, in a range between 1000 Hz and 20000 Hz. The etching stop frequency fs (i.e., the target frequency) can be theoretically obtained by simulation on the basis of a final target resonance frequency that the oscillator 112 with a magnet and the like attached thereto should finally attains, for example.
A method of detecting the frequency and amplitude by the detecting unit 105 will be described.
When the light beam impinges on the photodetector 105b, the output of the photodetector 105b changes. Where TS is sufficiently short (this condition is normally satisfied), frequency f and amplitude θA of the oscillator 112 can be represented by the following equations (1-1) and (1-2). Accordingly, when the detecting unit 105 needs the frequency and amplitude of the oscillator 112, it can calculate the frequency and amplitude using the time signal detected by the photodetector 105b and equations (1-1) and (1-2).
Method of detecting the resonance condition and method of stopping the etching process will be described.
As the etching of the oscillator 112 advances, the size or shape of the oscillator 112 changes. Accordingly, the resonance frequency of the oscillator 112 changes as illustrated in
In this embodiment, the detecting unit 105 executes the above detection by calculating the amplitude of the oscillator 112 from the time detected by the photodetector 105b and equation (1-2). In this embodiment, since the constant frequency f of the oscillator 112 is known, only the amplitude needs to be detected. When the amplitude reaches the maximal extreme value, the detecting unit 105 recognizes that the oscillator 112 is under its resonance condition. Thus, the detecting unit 105 can readily perform the judgment with accuracy.
To terminate the etching process, the substrate 111 supported by the supporting unit 103 is swiftly lifted up from the etchant 102 by some appropriate means and washed, for example. The resonance frequency of the thus-produced oscillator 112 can be accorded to the etching stop frequency fs by detecting the amplitude of the oscillator 112 without directly detecting its resonance frequency.
In the above-discussed producing method, even when there are variations in the thickness and the like of the substrate 111, an oscillator with a predetermined resonance frequency can be surely produced.
In this embodiment, the oscillation of the oscillator in the etchant is excited, and the oscillating condition is detected. The time when the resonance condition is attained is treated as the etching terminal point. When the etching terminal point is detected in the above manner, there is no need of pulling out the object from the etchant on the way of etching. The etching proceeding condition of the object staying in the etchant can be accurately judged and controlled. Accordingly, the etching process can be simplified, and the etching accuracy can be enhanced.
A second embodiment of an oscillator producing method and etching apparatus 200 will be described with reference to
In this embodiment, plural oscillators 112 are formed in the substrate 111. The exciting unit 104 is arranged on the etching bath 101. The exciting unit 104 oscillates to transmit the oscillation to the etchant 102, and the oscillation is transmitted from the etchant 102 to the oscillators 112. Thus, the oscillators 112 oscillate. That is, the exciting unit 104 transmits the oscillation to the oscillators 112 through the etchant 102. When the exciting unit 104 is arranged as closely to the oscillators 112 as possible, the oscillation of the exciting unit 104 can be efficiently transmitted to the oscillators 112. The oscillator 112 can be efficiently oscillated with large amplitude. Further, the etchant 102 around the oscillators 112 can be effectively stirred, and the etching process can be accelerated.
When the thickness is uniform over the entire substrate 111, etching processes of the plural oscillators 112 can be regulated by monitoring only the oscillating condition of one of the oscillators 112 in the substrate 111. The exciting unit 104 can be comprised of a speaker or the like that can output sound waves or oscillation waves at appropriate frequencies.
A method of detecting the oscillating condition in the second embodiment will be described. In this method, sandwiching an appropriate oscillator 112 in the substrate 111 supported by the supporting unit 103, the detecting unit 105 for detecting the oscillating condition is arranged facing the exciting unit 104.
For example, fmin is 1000 Hz, fmax is 20000 Hz, and the period T is ten seconds. Since oscillations of the oscillators 112 are excited by the exciting unit 104, the oscillators 112 oscillate at the same frequency as the exciting unit 104, as illustrated in
In the second embodiment, a change in the resonance frequency of the oscillators 112 during the etching process can be accurately detected, and the etching process can be surely stopped at the time when the resonance frequency of the oscillators 112 has reached the etching stop frequency fs. Accordingly, resonance frequencies of the oscillators after the etching process can be made accurately equal to each other.
A third embodiment of an oscillator producing method and etching apparatus 200 will be described with reference to
In this embodiment, the exciting unit 104 oscillates to transmit the oscillation to the etchant 102, and the oscillation is transmitted from the etchant 102 to the oscillators 112. Thus, the oscillators 112 oscillate. That is, the exciting unit 104 transmits the oscillation to the oscillators 112 through the etchant 102. Further, the exciting unit 104 oscillates at plural frequencies. The detecting unit 105 detects the oscillation of the etchant 102. The exciting unit 104 can be comprised of a speaker or the like that can output sound waves or oscillation waves at appropriate frequencies. The detecting unit 105 can be comprised of a microphone or the like that can receive sound waves or oscillation waves.
A method of detecting the oscillating condition of the oscillators 112 by the exciting unit 104 and the detecting unit 105 will be described. In the method of the third embodiment, oscillation energy output from the exciting unit 104 is transmitted to the oscillators 112 through a medium of the etchant 102. The oscillators 112 receive the oscillation energy from the etchant 102, and resonate at a certain resonance frequency. Then, the oscillators 112 absorb the oscillation energy from the etchant 102. Accordingly, the oscillation in the resonance frequency band of the oscillators 112 attenuates in the oscillation of the etchant 102. The detecting unit 105 detects the oscillation of the etchant 102. The detecting unit 105 compares the detected frequency band with the frequency band output from the exciting unit 104, and recognizes the attenuated frequency band as the resonance frequency of the oscillators 112.
As the etching process advances, the thus-detected resonance frequency of the oscillators 112 gradually changes and approaches the etching stop frequency fs. Thus, the detecting unit 105 detects the resonance frequency of the oscillators 112, and the detecting unit 105 stops the etching process when the resonance frequency of the oscillators 112 coincides with the etching stop frequency fs. The etching process can be stopped as described in the first embodiment.
In the third embodiment, a change in the resonance frequency of the oscillators 112 during the etching process can be accurately detected, and the etching process can be surely stopped at the time when the resonance frequency of the oscillators 112 has reached the etching stop frequency fs. Further, the resonance frequency of the oscillators 112 can be detected even when it is difficult to use the optical detecting unit as described in the first and second embodiments. Accordingly, resonance frequencies of the oscillators after the etching process can be made accurately equal to each other.
A fourth embodiment will be described. In this embodiment, an oscillator 300 illustrated in
In the oscillator 300, an oscillation plate 201 is movably supported by a supporting frame 203 through a pair of torsional springs 202. The oscillation plate 201 is integrally formed with a substrate 211. The substrate 211 is formed of single crystal silicon. The single crystal silicon has preferable mechanical characteristics, such as large Young's modulus, small specific gravity, non-plastic deformability and the like. It is therefore possible to obtain the oscillation plate 201 with a large resonance frequency. The oscillation plate 201 can also be supported by a single torsional spring in a cantilever manner.
A permanent magnet 214 is mounted on the oscillation plate 201. The oscillation plate 201 can be driven by the permanent magnet 214 and an electromagnet (not shown) fixed at an appropriate position facing the permanent magnet 214. A plurality of permanent magnets 214 can be arranged on both opposite surfaces of the oscillation plate 201, for example. As discussed above, the etching stop frequency fs is determined considering the oscillator with the permanent magnet(s) mounted thereto. Accordingly, the final resonance frequency of the oscillator with the permanent magnet(s) can be surely adjusted to a final target value.
A method of producing the oscillator 300 will be described.
On the silicon nitride 216 on a top surface of the substrate 211, resist of novolac type is deposited to a thickness of about 1 μm, and a resist mask is formed by photolithography. After that, reactive ion etching (RIE) is performed using fluorine-contained gas, such as CF4, to etch the silicon nitride 216 and form a mask of the silicon nitride 216. The resist mask is then removed. Similarly, a mask of the silicon nitride 216 is formed on a bottom surface of the substrate 211 (
As described above, the substrate 211 is immersed in the alkaline water solution to perform the etching process of the substrate 211. Thus, the oscillation plate 201, torsional springs 202 (not shown in
Thereafter, it is possible to slightly perform isotropic etching using the mixture acid used in the first embodiment, or the like. The viscosity of the mixture acid is larger than that of the alkaline water solution. In this case, the etching terminal point can be determined in this isotropic etching step.
Then, RIE is performed using a fluorine-contained gas, such as CF4, to remove the silicon nitride 216 (
In the method of producing the oscillator according to this invention, even if the shape of the oscillator slightly differs from an ideal one, the shape is acceptable so long as the target resonance frequency is achieved. In this invention, paying attention to this critical point, the etching terminal point is determined by monitoring the oscillating condition of the oscillator at least once during the etching process. It is thereby possible to surely produce an oscillator with a target resonance frequency. Further, even if an achieved resonance frequency slightly differs from the target one, the difference amount is minute and can be within an adjustable range. The resonance frequency with a minute difference within the adjustable range can be readily adjusted to the target resonance frequency by a slight adjustment process.
While the present invention has been described with reference to exemplary embodiments, it is to be understood that the invention is not limited to the disclosed exemplary embodiments. The scope of the following claims is to be accorded the broadest interpretation so as to encompass all such modifications and equivalent structures and functions.
This application claims the benefit of Japanese Patent Application No. 2008-144353, filed Jun. 2, 2008, which is hereby incorporated by reference herein in its entirety.
Number | Date | Country | Kind |
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2008-144353 | Jun 2008 | JP | national |