The invention relates to a mirror, in particular for a microlithographic projection exposure apparatus, and to a method of production thereof.
Microlithography is used for producing microstructured components, for example integrated circuits or LCDs. The microlithography process is conducted in a so-called projection exposure apparatus, which comprises an illumination device and a projection lens. The image of a mask (=reticle) illuminated with the illumination device is projected via the projection lens onto a substrate (e.g. a silicon wafer) coated with a light-sensitive layer (=photoresist) and disposed in the image plane of the projection lens, in order to transfer the mask structure to the light-sensitive coating of the substrate.
In projection lenses designed for the extreme ultraviolet (EUV) range, which is to say at wavelengths of for example approximately 13 nm or approximately 7 nm, mirrors are used as optical components for the imaging process owing to the lack of availability of suitable light-transmissive refractive materials.
In this case, it is also known to configure one or more mirrors in an EUV system as an adaptive mirror with an actuator layer composed of a piezoelectric material, wherein an electric field having a locally varying strength is generated across this piezoelectric layer by an electrical voltage being applied to electrodes arranged on both sides with respect to the piezoelectric layer. In the case of a local deformation of the piezoelectric layer, the reflection layer system of the adaptive mirror also deforms, with the result that (possibly also temporally variable) imaging aberrations, for example, are compensated for at least in part through suitable driving of the electrodes.
During operation of an optical system comprising the mirror 10, applying an electrical voltage to the electrode arrangements 14 and 20 by way of the electric field that forms in the region of the piezoelectric layer 16 results in a deflection of said piezoelectric layer 16. In this way, it is possible to achieve an actuation of the mirror 10 (for instance for compensation of optical aberrations, for example as a result of thermal deformations in the case of EUV radiation incident on the optical effective surface 11). A mediator layer 17 is in direct electrical contact with the electrodes 20a, 20b, 20c, . . . (which are shown in plan view in
During the production of the adaptive mirror 10, ensuring that the reflection layer system 21 is applied while complying with the required specifications is a demanding challenge. One problem that occurs here in practice is, in particular, during the fabrication process before the reflection layer system 21 is applied, that of realizing interferometric measurements of the respective surface-processed layer without the measurement being influenced by the metallic structures of the electrode arrangement 20 and by the piezoelectric layer 16, since such influencing would result in a distortion of the interferometric measurement results and thus an inadequate usability for the material removals to be carried out in each case in the fabrication process.
In order to overcome the problem described above, again with reference to
By way of prior art, reference is made merely by way of example to DE 10 2017 213 900 A1, DE 10 2015 208 214 A1 and DE 10 2014 204 171 A1.
It is an object of the present invention to provide a mirror, in particular for a microlithographic projection exposure apparatus, and a method for production thereof, which make it possible to achieve higher surface quality than was possible with the prior art while still complying with the specifications required, for example in the EUV range.
This this and other objects are addressed according to the features of the independent patent claims.
A mirror according to one formulation of the invention, has an optical effective surface, and has:
The present invention is associated with the concept of ensuring, in a mirror with structures (for example electrodes) hidden in the mirror substrate thereof that have different refractive index from the remainder of the mirror substrate material, by provision of a suitable layer stack between the mirror substrate and reflection layer system, that, firstly, an interferometric figure measurement that is typically required, possibly repeatedly, during mirror manufacture can be conducted without the destructive influence of these structures hidden in the mirror substrate that was described at the outset, and, secondly, the smoothing process steps that are needed during mirror manufacture (e.g. polishing) can be conducted in a very optimal manner, meaning that corresponding optical processibility remains assured.
In the layer stack provided in accordance with the invention between mirror substrate and reflection layer system, the absorber layer achieves the effect that measurement radiation penetrating into the mirror during the interferometric figure measurement mentioned is at least largely absorbed (i.e. virtually no reflected measurement radiation that disrupts the figure measurement exits from the mirror), whereas the AR layer between smoothing layer and absorber layer achieves the effect that no significant reflections occur at the transition to the absorber layer either. At the same time, the functionalities of the absorber layer and of the AR layer that have been mentioned make it possible to configure the smoothing layer even without reference to the structures hidden in the substrate and the potentially disruptive influence thereof on the interferometric figure measurement and hence to optimize it rather with regard to the smoothing (polishing) processes to be conducted for mirror manufacture.
Overall, the layer stack of the invention not only does justice to the demands for smoothability that exist from a manufacturing point of view, but at the same time prevents, during the manufacturing process, occurrence of the influences or distortions described at the outset in the measurement results obtained in the interferometry analysis of the respectively surface-processed layer by virtue of the structures hidden in the mirror substrate (for instance in the adaptive mirror described at the outset by virtue of the electrodes of the electrode arrangement and by virtue of the piezoelectric layer).
In particular, it is not necessary in accordance with the invention to undertake any manipulation of the smoothing layer by appropriate doping, in order to ensure that, in the interferometry analysis, the aforementioned metallic structures of the electrode arrangement and of the piezoelectric layer are “invisible”, since the latter functionality is achieved by the further layers that are present in the layer stack of the invention, namely the AR layer and the absorber layer.
In one embodiment, the absorber layer has transmittance of less than 10−5 for at least one measurement wavelength in the range from 400 nm to 750 nm. The term “transmittance” here and hereinafter should be considered to mean transmittance in a double pass through the layer stack (i.e. after reflection of the electromagnetic radiation in question at the absorber layer).
In one embodiment, the absorber layer has a thickness in the range from 50 nm to 2 μm.
In one embodiment, the absorber layer includes at least one material from the group comprising amorphous silicon (a-Si), non-oxidic and non-nitridic a-Si compounds, and the metals tantalum (Ta), titanium (Ti), chromium (Cr), nickel (Ni), aluminum (Al) and alloys of those metals.
In one embodiment, the smoothing layer has been produced from a material from the group comprising silicon dioxide (SiO2), SiOx compounds, hafnium dioxide (HfO2), titanium dioxide (TiO2), amorphous silicon (a-Si) and crystalline silicon (c-Si).
In one embodiment, the AR layer has an average refractive index between the average refractive index of the smoothing layer and the average refractive index of the absorber layer.
In one embodiment, the AR layer has a refractive index that rises or falls successively in stacking direction between the average refractive index of the absorber layer and the average refractive index of the smoothing layer.
In one embodiment, the AR layer has an alternating sequence of layers of comparatively low refractive index, especially of silicon dioxide (SiO2), and layers of comparatively high refractive index, especially of amorphous silicon (a-Si).
In one embodiment, the mirror has a piezoelectric layer which is disposed between mirror substrate and reflection layer system and which is subjectable via electrode arrangements to an electrical field for creation of a locally variable deformation.
In accordance with one embodiment, the mirror is designed for an operating wavelength of less than 30 nm, in particular less than 15 nm. However, the invention is not restricted thereto, and so in further applications the invention can also be implemented advantageously in an optical system having an operating wavelength in the VUV range (e.g. of less than 200 nm).
In accordance with one embodiment, the mirror is a mirror for a microlithographic projection exposure apparatus.
In accordance with a further aspect, the invention also relates to a method for producing a mirror, wherein the method comprises the following steps:
The mirror may be in particular a mirror for a microlithographic projection exposure apparatus. However, the invention is not restricted thereto. In further applications, a mirror of the invention can also be employed or utilized for example in an apparatus for mask metrology.
The invention further relates to an optical system, in particular an illumination device or a projection lens of a microlithographic projection exposure apparatus, comprising at least one mirror having the features described above, and also to a microlithographic projection exposure apparatus.
Further configurations of the invention will be apparent from the description and the dependent claims.
The invention is described in detail hereinafter with reference to working examples shown in the appended figures.
The figures show:
There follows a description, first, of the structure and mode of function of a mirror according to the invention using different embodiments with reference to the schematic illustrations or diagrams of
What is common to these embodiments is that, for avoidance of troublesome influencing of interferometry measurements conducted for figure measurement by structures present in the mirror substrate that have a refractive index different than the surrounding mirror substrate material, a layer stack atop the mirror substrate is provided in each case. The layer stack, in addition to a smoothing layer that ensures optical processibility, has an absorber layer (for absorbing the electromagnetic measurement radiation that penetrates the smoothing layer) and an AR layer (for avoiding reflections of this measurement radiation at the boundary to the absorber layer).
As a result, by virtue of the aforementioned functionalities of the absorber layer and of the AR layer, the smoothing layer itself can be configured without reference to these structures hidden in the substrate and the potentially disruptive influence thereof on the interferometric figure measurement and hence can be optimized rather with regard to the smoothing (e.g. polishing) processes to be conducted for mirror manufacture.
The mirror 100 may be in particular an EUV mirror of an optical system, in particular of the projection lens or of the illumination device of a microlithographic projection exposure apparatus. More particularly, the mirror 100 may be an adaptive mirror with an actuator layer composed of a piezoelectric material, where an electric field having locally varying strength is generated across the piezoelectric layer—as described at the outset with reference to
In this case, the structures 106 hidden in the mirror substrate 105 may especially be the electrodes or else the piezoelectric layer.
As a result of the abovementioned layer stack of the invention described in detail hereinafter with reference to different embodiments—by contrast with the conventional arrangement of
The absorber layer 110, for the measurement wavelength used (which is typically in the visible range between 400 nm and 750 nm and may, merely by way of example, be 532 nm or 633 nm), has a transmittance of less than 10−5 and a suitable thickness, depending on the material of the absorber layer 110, for example, in the range from 50 nm to 2 μm. Illustrative suitable materials of the absorber layer are amorphous silicon (a-Si), non-oxidic and non-nitridic a-Si compounds, and the metals tantalum (Ta), titanium (Ti), chromium (Cr), nickel (Ni), aluminum (Al) as well as alloys of those metals.
The smoothing layer 130 optimized with regard to the smoothing (polishing) processes to be conducted for the mirror manufacture may especially have been produced from pure silicon dioxide (SiO2). However, the invention is not limited thereto, and so, in further embodiments, depending on the smoothing optical processing operation to be conducted, other materials are also suitable for the smoothing layer, especially SiOx compounds, hafnium dioxide (HfO2), titanium dioxide (TiO2), amorphous silicon (a-Si) and crystalline silicon (c-Si).
The AR (anti-reflection) layer 120, for achievement of the above-described functionality, namely the avoidance of reflections at the boundary to the absorber layer 110, has an average refractive index between the average refractive index of the absorber layer 110 and the average refractive index of the smoothing layer 130.
In this regard,
By contrast with
In accordance with
The projection lens 610 serves for imaging the object field 605 into an image field 611 in an image plane 612. A structure on the reticle 607 is imaged on a light-sensitive layer of a wafer 613 arranged in the region of the image field 611 in the image plane 612. The wafer 613 is held by a wafer holder 614. The wafer holder 614 is displaceable by way of a wafer displacement drive 615, in particular in y direction. The displacement, firstly, of the reticle 607 by way of the reticle displacement drive 609 and, secondly, of the wafer 613 by way of the wafer displacement drive 615 can be synchronized with one another.
The radiation source 603 is an EUV radiation source. The radiation source 603 in particular emits EUV radiation, which is also referred to below as used radiation or illumination radiation. In particular, the used radiation has a wavelength in the range between 5 nm and 30 nm. The radiation source 603 can be for example a plasma source, a synchrotron-based radiation source or a free electron laser (FEL). The illumination radiation 616 emanating from the radiation source 603 is focused by a collector 617 and propagates through an intermediate focus in an intermediate focal plane 618 into the illumination optical unit 604. The illumination optical unit 604 comprises a deflection mirror 619 and, arranged downstream thereof in the beam path, a first facet mirror 620 (having schematically indicated facets 621) and a second facet mirror 622 (having schematically indicated facets 623).
The projection lens 610 comprises a plurality of mirrors Mi (i=1, 2, . . . ), which are consecutively numbered in accordance with their arrangement in the beam path of the projection exposure apparatus 601. In the example illustrated in
Even though the invention has been described on the basis of specific embodiments, numerous variations and alternative embodiments will be apparent to a person skilled in the art, for example through combination and/or exchange of features of individual embodiments. Accordingly, such variations and alternative embodiments are also encompassed by the present invention, and the scope of the invention is restricted only within the scope of the appended patent claims and equivalents thereof.
Number | Date | Country | Kind |
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10 2022 205 302.8 | May 2022 | DE | national |
This is a Continuation of International Application PCT/EP2023/062441 which has an international filing date of May 10, 2023, and the disclosure of which is incorporated in its entirety into the present Continuation by reference. This Continuation also claims foreign priority under 35 U.S.C. §119(a)-(d) to and also incorporates by reference, in its entirety, German Patent Application DE 10 2022 205 302.8 filed on May 25, 2022.
Number | Date | Country | |
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Parent | PCT/EP2023/062441 | May 2023 | WO |
Child | 18947058 | US |