Claims
- 1. An improved process for the preparation of polyphenylene ether-polyamide compositions wherein the improvement comprises precompounding from about 0.05 to about 4% by weight, based on the total composition, of one or more aliphatic polycarboxylic acid represented by the formula:
- (R.sup.I O).sub.m R(COOR.sup.II).sub.n (CONR.sup.III R.sup.IV).sub.s
- or derivatives thereof wherein R is a linear or branched chain, saturated aliphatic hydrocarbon of from 2 to 20 carbon atoms; R.sup.I is selected from the group consisting of hydrogen or an alkyl, aryl, acyl or carbonyl dioxy group of from 1 to 10 carbon atoms; each R.sup.II is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 20 carbon atoms; each R.sup.III and R.sup.IV is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 10 carbon atoms; m is equal to 1 and (n+s) is greater than or equal to 2, and n and s are each greater than or equal to 0; and wherein (OR.sup.I) is alpha or beta to a carbonyl group and at least 2 carbonyl groups are separated by 2 to 6 carbon atoms, with the polyphenylene ether and a modifier resin prior to compounding with the polyamide in order to enhance the impact strength of the final composition; said modifier resin having been derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
- 2. The process of claim 1 wherein the polycarboxylic acid is represented by the formula:
- (R.sup.I O).sub.m R(COOR.sup.II).sub.n (CONR.sup.III R.sup.IV).sub.s
- or derivative thereof wherein R is a linear or branched chain, saturated aliphatic hydrocarbon of from 2 to 10 carbon atoms; R.sup.I is selected from the group consisting of hydrogen or an alkyl, aryl, acyl or carbonyl dioxy group of from 1 to 6 carbon atoms; each R.sup.II is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 10 carbon atoms; each R.sup.III and R.sup.IV is independently selected from the group consisting essentially of hydrogen or an alkyl or aryl group of from 1 to 6 carbon atoms; m is equal to 1 and (n+s) is equal to 2 or 3, and n and s are each greater than or equal to 0 and wherein (OR.sup.I) is alpha to the carbonyl group.
- 3. The process of claim 1 wherein the polycarboxylic acid is represented by the formula:
- (R.sup.I O).sub.m R(COOR.sup.II).sub.n
- or derivative thereof wherein R is a linear or branched saturated aliphatic hydrocarbon of 2 to 10 carbon atoms, R.sup.I is selected from the group consisting of hydrogen or an alkyl, acyl or carbonyldioxy group of from 1 to 6 carbon atoms, R.sup.II is selected from the group consisting of hydrogen or an alkyl group of from 1 to 20 carbon atoms; m is equal to 1 and n is equal to 2 or 3 and wherein (OR.sup.I) is alpha to the carbonyl group.
- 4. The process of claim 1 wherein the polycarboxylic acid is selected from the group consisting essentially of citric acid, malic acid and salts thereof.
- 5. The process of claim 1 wherein the amount of polycarboxylic acid employed is from about 0.1 to about 2% by weight based on the weight of the total composition.
- 6. The process of claim 1 wherein the ratio of polyphenylene ether to polyamide is from 30 to 70% by weight of the former to 70 to 30% by weight of the latter.
- 7. The process of claim 1 wherein the polyphenylene ether is a homoplymer or a copolymer having units with the repeating structural formula: ##STR3## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next joining unit, and n is a positive integer and is at least 50, and each Q is independently a monovalent substituent selected from a group consisting of hydrogen, halogen, hydrocarbon and hydrocarbonoxy groups free of a tertiary alpha-carbon atom and halohydrocarbon and halohydrocarbonoxy groups free of a tertiary alpha-carbon atom and having at least 2 carbon atoms between the halogen atom and the phenyl nucleus.
- 8. The process of claim 1 wherein the polyphenylene ether is poly(2,6 dimethyl-1,4-phenylene)ether.
- 9. The process of claim 1 wherein the polyamide is selected from the group consisting of polyamide 6; polyamide 6,6; polyamide 12 and polyamide 6/10.
- 10. The process of claim 1 wherein the polyamide is polyamide 6/6.
- 11. The process of claim 1 which further comprises admixing therewith up to 3% by weight of a primary or secondary amine.
- 12. The process of claim 11 wherein the amine is precompounded with the polyphenylene ether and the polycarboxylic acid.
- 13. The process of claim 11 wherein the amine is prereacted with the polycarboxylic acid prior to precompounding.
- 14. An improved process for the preparation of polyphenylene ether-polyamide compositions wherein the improvement comprises precompounding one or more aliphatic polycarboxylic acid represented by the formula:
- (R.sup.I O).sub.m R(COOR.sup.II).sub.n (CONR.sup.III R.sup.IV).sub.s
- or derivatives thereof wherein R is a linear of branched chain, saturated aliphatic hydrocarbon of from 2 to 20 carbon atoms; R.sup.I is selected from the group consisting of hydrogen or an alkyl, aryl, acyl or carbonyl dioxy group of from 1 to 10 carbon atoms; each R.sup.II is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 20 carbon atoms; each R.sup.III and R.sup.IV is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 10 carbon atoms; m is equal to 1 and (n+s) is greater than or equal to 2, and n and s are each greater than or equal to 0; and wherein (OR.sup.I) is alpha or beta to a carbonyl group and at least 2 carbonyl groups are separated by 2 to 6 carbon atoms in an amount sufficient to enhance the impact strength of the polyphenylene ether-polyamide composition, with the polyphenylene ether and a modifier resin prior to compounding with the polyamide, said modifier resin having been derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
- 15. A process for the preparation of polyphenylene ether-polyamide compositions, said composition being derived from citric acid, a polyphenylene ether, a modifier resin and a polyamide, said process comprising precompounding said citric acid with said polyphenylene ether and said modifier resin prior to compounding with said polyamide, said modifier resin being selected from the group consisting of polymer resins derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
- 16. The process of claim 15, wherein said polyamide is polyamide 6,6.
- 17. The process of claim 15, wherein said polyphenylene ether is poly(2,6 dimethyl-1,4-phenylene)ether.
- 18. The process of claim 15 wherein said modifier resin is selected from the group consisting of
- polystyrene-polybutadiene;
- polystyrene-polyisoprene;
- poly(alpha-methylstyrene)-polybutadiene;
- polystyrene-polybutadiene-polystyrene;
- polystyrene-polyisoprene-polystyrene;
- poly(alpha-methylstyrene)-polybutadiene-poly-(alpha-methylstyrene); and
- poly(alpha-methylstyrene)-polyisoprene-poly-(alpha-methystyrene).
- 19. A process for the preparation of polyphenylene ether-polyamide composition, said composition being derived from citric acid, a polyphenylene ether, a modifier resin and a polyamide, said process comprising precompounding said citric acid with said polyphenylene ether and said modifier resin prior to compounding with said polyamide, said polyphenylene ether being poly(2,6 dimethyl-1,4-phenylene)-ether, said modifier resin being polystyrene-polybutadiene-polystyrene triblock copolymer, said polyamide being polyamide 6,6, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
- 20. A process for the preparation of polyphenylene ether-polyamide composition, said composition being derived from citric acid, a polyphenylene ether, a modifier resin and a polyamide, said process comprising precompounding said citric acid with said polyphenylene ether and said modifier resin prior to compounding with said polyamide, said polyphenylene ether being poly(2,6 dimethyl-1,4-phenylene)ether, said modifier resin being polystyrene-polybutadiene-polystyrene triblock copolymer, said polyamide being polyamide 6,6, wherein said polyphenylene ether is present at a level of about 45 percent by weight of said composition, said polyamide is present at a level of about 45 percent by weight of said composition, and said citric acid is present at a level of about 0.7 percent by weight of said composition.
- 21. A process for the preparation of a composition derived from melt blending polyphenylene ether resin, polyamide resin, citric acid and a modifier resin derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter, the citric acid being present at a level of from 0.05 to 4 percent by weight based on the total composition, said modifier resin being present at a level of from 5 to 50 parts by weight based on 100 parts by weight of the combined weight of polyphenylene ether and polyamide, said process comprising:
- (a) precompounding the citric acid with polyphenylene ether;
- (b) compounding polyamide with the precompounded citric acid/polyphenylene ether.
- 22. The process of claim 21 wherein said citric acid is a citric acid ester.
- 23. The process of claim 21 wherein said modifier resin is a styrene-butadiene-styrene triblock copolymer.
- 24. The process of claim 21 wherein the blending ratio of polyphenylene ether to polyamide is 30 to 70 percent by weight of the former to 70 to 30 percent by weight of the latter.
Parent Case Info
This is a continuation of application Ser. No. 736,490 filed May 20, 1985, now abandoned, which is a continuation-in-part of application Ser. No. 612,369 filed May 21, 1984.
US Referenced Citations (8)
Foreign Referenced Citations (3)
Number |
Date |
Country |
0046040 |
Feb 1982 |
EPX |
117250 |
Jul 1983 |
JPX |
59-66452 |
Apr 1984 |
JPX |
Continuations (1)
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Number |
Date |
Country |
Parent |
736490 |
May 1985 |
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
612389 |
May 1984 |
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