Nanocomposite refractory coatings and applications thereof

Information

  • Patent Grant
  • 9650714
  • Patent Number
    9,650,714
  • Date Filed
    Monday, December 8, 2014
    9 years ago
  • Date Issued
    Tuesday, May 16, 2017
    7 years ago
Abstract
In one aspect, articles are described comprising refractory coatings employing nanocomposite architectures. Articles having such refractory coatings, in some embodiments, are suitable for high wear and/or abrasion applications such as metal cutting operations. A coated article described herein comprises a substrate and a coating deposited by CVD adhered to the substrate, the coating including a refractory layer having a matrix phase comprising alumina and a nanoparticle phase contained within the matrix phase, the nanoparticles phase comprising crystalline nanoparticles formed of at least one of a carbide, nitride or carbonitride of a Group IVB metal.
Description
FIELD

The present invention relates to refractory coatings and, in particular, to refractory coatings deposited by chemical vapor deposition (CVD) for cutting tool applications.


BACKGROUND

Cutting tools, including cemented carbide cutting tools, have been used in both coated and uncoated conditions for machining various metals and alloys. In order to increase cutting tool wear resistance, performance and lifetime, one or more layers of refractory material have been applied to cutting tool surfaces. TiC, TiCN, TiN and/or Al2O3, for example, have been applied to cemented carbide substrates by CVD and by physical vapor deposition (PVD). While effective in inhibiting wear and extending tool lifetime in a variety of applications, refractory coatings based on single or multi-layer constructions of the foregoing refractory materials have increasingly reached their performance limits, thereby calling for the development of new coating architectures for cutting tools.


SUMMARY

In one aspect, articles are described comprising refractory coatings employing nanocomposite architectures. Briefly, a coated article described herein comprises a substrate and a coating deposited by CVD adhered to the substrate, the coating including a refractory layer having a matrix phase comprising alumina and a nanoparticle phase contained within the matrix phase, the nanoparticle phase comprising crystalline nanoparticles of at least one of a carbide, nitride and carbonitride of a Group IVB metal. The nanoparticles, in some embodiments, are imbedded within alumina grains of the matrix phase. Further, the nanoparticles can be dispersed throughout the matrix phase in a predetermined manner. In some embodiments, for example, the nanoparticles are distributed in the alumina matrix phase in one or more nanoparticle concentration bands. The nanoparticle concentration bands can exhibit periodic separation or aperiodic separation along the thickness of the refractory layer. In some embodiments, nanoparticle distribution in the alumina matrix phase is predetermined and controlled with CVD deposition parameters discussed herein.


These and other embodiments are described further in the detailed description which follows.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 illustrates a cutting tool substrate according to one embodiment described herein.



FIGS. 2(a)-(b) are cross-sectional transmission electron microscopy (TEM) images of a section of a nanocomposite refractory layer according to one embodiment described herein.



FIGS. 3(a)-(b) are TEM images of sections of a nanocomposite refractory layer according to one embodiment described herein.



FIGS. 4(a)-(b) are TEM images of sections of a nanocomposite refractory layer according to one embodiment described herein.



FIGS. 5(a)-(b) are TEM images of sections of a nanocomposite refractory layer according to one embodiment described herein.





DETAILED DESCRIPTION

Embodiments described herein can be understood more readily by reference to the following detailed description and examples and their previous and following descriptions. Elements, apparatus and methods described herein, however, are not limited to the specific embodiments presented in the detailed description and examples. It should be recognized that these embodiments are merely illustrative of the principles of the present invention. Numerous modifications and adaptations will be readily apparent to those of skill in the art without departing from the spirit and scope of the invention.


In one aspect, articles are described comprising refractory coatings employing nanocomposite architectures. Articles having such refractory coatings, in some embodiments, are suitable for high wear and/or abrasion applications such as metal cutting operations. A coated article described herein comprises a substrate and a coating deposited by CVD adhered to the substrate, the coating including a refractory layer having a matrix phase comprising alumina and a nanoparticle phase contained within the matrix phase, the nanoparticle phase comprising crystalline nanoparticles of at least one of a carbide, nitride and carbonitride of a Group IVB metal. The nanoparticles, in some embodiments, are imbedded within alumina grains of the matrix phase. In being imbedded in the alumina grains, the nanoparticles do not terminate alumina grain development or growth during deposition of the refractory layer. Therefore, a singular alumina grain can exhibit several regions of nanoparticle reinforcement. Further, the nanoparticles can be dispersed throughout the alumina matrix phase in a predetermined manner.


Turning now to specific components, coated articles described herein comprise a substrate. A coated article can comprise any substrate not inconsistent with the objectives of the present invention. For example, a substrate can be a cutting tool or tooling used in wear applications. Cutting tools include, but are not limited to, indexable cutting inserts, end mills or drills. Indexable cutting inserts can have any desired ANSI standard geometry for milling or turning applications. Substrates of coated articles described herein can be formed of cemented carbide, carbide, ceramic, cermet, steel or other alloy. A cemented carbide substrate, in some embodiments, comprises tungsten carbide (WC). WC can be present in a cutting tool substrate in an amount of at least about 80 weight percent or in an amount of at least about 85 weight percent. Additionally, metallic binder of cemented carbide can comprise cobalt or cobalt alloy. Cobalt, for example, can be present in a cemented carbide substrate in an amount ranging from 1 weight percent to 15 weight percent. In some embodiments, cobalt is present in a cemented carbide substrate in an amount ranging from 5-12 weight percent or from 6-10 weight percent. Further, a cemented carbide substrate may exhibit a zone of binder enrichment beginning at and extending inwardly from the surface of the substrate.


Cemented carbide substrates can also comprise one or more additives such as, for example, one or more of the following elements and/or their compounds: titanium, niobium, vanadium, tantalum, chromium, zirconium and/or hafnium. In some embodiments, titanium, niobium, vanadium, tantalum, chromium, zirconium and/or hafnium form solid solution carbides with WC of the substrate. In such embodiments, the substrate can comprise one or more solid solution carbides in an amount ranging from 0.1-5 weight percent. Additionally, a cemented carbide substrate can comprise nitrogen.


A cutting tool substrate can comprise one or more cutting edges formed at the juncture of a rake face and flank face(s) of the substrate. FIG. 1 illustrates a cutting insert substrate according to one embodiment described herein. As illustrated in FIG. 1, the substrate (10) has cutting edges (12) formed at junctions of the substrate rake face (14) and flank faces (16). The substrate (10) also comprises an aperture (18) for securing the substrate (10) to a tool holder.


As described herein, a coating adhered to the substrate includes a refractory layer having a matrix phase comprising alumina and a nanoparticle phase contained within the matrix phase, the nanoparticle phase comprising crystalline nanoparticles formed of at least one of a carbide, nitride and carbonitride of a Group IVB metal. Groups of the Periodic Table described herein are identified according to the CAS designation, where Group IVB includes titanium, zirconium and hafnium. Generally, the crystalline nanoparticles have an average size less than 100 nm in at least one dimension. In some embodiments, the crystalline nanoparticles have an average size less than 10 nm or less than 5 nm in one dimension. Further, the crystalline nanoparticles can exhibit an average size less than 20 nm in two or more dimensions. For example, the crystalline nanoparticles can have an average diameter selected from Table I and an average length selected from Table II.









TABLE I





Crystalline Nanoparticle


Average Diameter (nm)















≦100


≦5


1-5


1-3
















TABLE II





Crystalline Nanoparticle


Average Length (nm)















≦500


≦100


 5-500


10-100


20-250


 5-20 









Crystalline nanoparticles of a Group IVB metal nitride, carbide or carbonitride can exhibit a generally spherical shape, elliptical shape or rod-like shape. In some embodiments, the crystalline nanoparticles can have a rice-like shape or irregular shape. Moreover, crystalline nanoparticle shape can be substantially uniform throughout the refractory layer. Alternatively, crystalline nanoparticle shape can vary in the refractory layer.


Crystalline nanoparticles of at least one of a Group IVB metal nitride, carbide and carbonitride can have any desired distribution in the alumina matrix phase, including substantially uniform as well as heterogeneous distributions. The nanoparticles, for example, can be dispersed throughout the matrix phase in a predetermined manner. In some embodiments, for example, the nanoparticles are distributed in the alumina matrix phase in one or more nanoparticle concentration bands. Nanoparticle concentration bands can exhibit periodic separation or aperiodic separation along the thickness of the refractory layer. Separation distance(s) of nanoparticle concentration bands can be selected according to several considerations including, but not limited to, refractory layer thickness, concentration of the crystalline nanoparticle reinforcement and compositional identity of the crystalline nanoparticles. Nanoparticle concentration band separation can range from tens of nanometers to microns. In some embodiments, separation distance(s) of nanoparticle concentration bands are selected from Table









TABLE III





Nanoparticle Concentration


Band Separation Distance







≦5 μm


0.050 μm-1 μm


0.010 μm-0.5 μm


0.030 μm-0.3 μm


 0.1 μm-2 μm


 0.1 μm-1 μm










Further, individual nanoparticle concentration bands can have a thickness less than 50 nm.


Compositional identity of the crystalline nanoparticles can be substantially uniform throughout the refractory layer. Alternatively, compositional identity of the crystalline nanoparticles can be varied throughout the refractory layer. For example, nanoparticle concentration bands can be formed independent of one another permitting the Group IVB metal of the crystalline nanoparticles to be varied along the thickness of the refractory layer. When varied, the Group IVB metals can present any desired pattern in the nanocrystalline phase such as alternating or periodic distribution along the thickness of the refractory layer. Alternatively, the Group IVB metals can exhibit a random distribution. Additionally, the non-metallic component of the crystalline nanoparticles can vary along the thickness of the refractory layer. Group IVB metal nitrides, carbides or carbonitrides and/or their combinations can present any desired pattern in the nanocrystalline phase(s), including alternating or periodic distribution along the thickness of the refractory layer. The non-metallic component can also exhibit a random distribution. The ability independently vary metallic (Ti, Zr, Hf) components and non-metallic (C, N, CN) components of the crystalline nanoparticles across the thickness of the refractory layer permits freedom of design to meet a variety of wear applications and environments.


As described herein, the crystalline nanoparticle phase(s) is contained within an alumina matrix phase. Depending on CVD conditions, the alumina matrix phase can be α-alumina, κ-alumina or mixtures (α/κ) thereof. Importantly, the crystalline nanoparticles do not terminate alumina grain development during deposition of the refractory layer. For example, deposition of the crystalline nanoparticles on alumina grains of the refractory layer does not terminate growth of the alumina grains or require alumina renucleation to continue grain development. The continued growth of alumina grains following crystalline nanoparticle deposition can embed the nanoparticles within the alumina grains. Therefore, a singular alumina grain can serve as a substrate for several regions/cycles of crystalline nanoparticle reinforcement. Further, alumina grains of the refractory layer can have a generally columnar morphology on the micron or submicron scale. In some embodiments, for example, the alumina grains have a length in the growth direction ranging from 500 nm to greater than 1 am. The alumina grains, in some embodiments, have a length in the growth direction selected from Table IV.









TABLE IV





Columnar Alumina Grain Length







500 nm-5 μm


 1 μm-10 μm


 1 μm-5 μm


 2 μm-10 μm










FIGS. 2(a)-(b) are cross-sectional TEM images of a section of a nanocomposite refractory layer comprising an alumina matrix phase and a titanium nitride (TiN) crystalline nanoparticle phase according to one embodiment described herein. As illustrated in FIG. 2, TiN crystalline nanoparticles of rod-shaped morphology are imbedded in the alumina grains as nanoparticle concentration bands. The nanoparticle concentration bands are displayed as perforated lines in the alumina grains having periodic separation of about 50 nm. FIG. 3 provides (a) TEM bright field (BF) and corresponding (b) dark field (DF) images of the TiN—Al2O3 nanocomposite refractory layer detailing alumina grain morphology according to one embodiment. The highlighted alumina grain exhibits a columnar structure on the micron scale. As in FIG. 2, TiN crystalline nanoparticles of rod-shaped morphology are imbedded in the alumina grain as nanoparticle concentration bands.



FIGS. 4(a)-(b) are also cross-sectional TEM images of a section of a TiN—Al2O3 nanocomposite refractory layer according to another embodiment described herein. Similar to FIG. 2, the TiN crystalline nanoparticles are imbedded in the alumina grain as nanoparticle concentration bands. As illustrated in FIG. 4(b), the TiN nanoparticles are rod-shaped, generally having diameter of 5 nm and length of 10-20 nm. Further, the TiN nanoparticle concentration bands have periodic separation of about 40 nm.



FIGS. 5(a)-(b) are cross-sectional TEM images of a section of a TiC—Al2O3 nanocomposite refractory layer according to one embodiment described herein. The crystalline TiC nanoparticles are 2-5 nm in diameter and are distributed in concentration bands within the alumina grains. The TiC nanoparticle concentration bands exhibit periodic separation of about 50 nm.


In some embodiments, crystalline nanoparticles of one or more concentration bands can aggregate forming a continuous layer in the alumina matrix phase. In such embodiments, the continuous layer of aggregated crystalline nanoparticles can generally have a thickness of 5 nm to 50 nm. Further, in some embodiments, Group IVB metal can be present in the alumina matrix phase adjacent to regions of the crystalline nanoparticles, forming doped alumina phases such as TiAl2O3 and/or ZrAl2O3. As set forth in the CVD parameters described herein, transition between nanoparticle deposition and alumina matrix deposition can permit introduction of Group IVB metal into the alumina matrix. Additionally, the alumina matrix phase may also include a Group IVB metal oxide.


The refractory layer comprising the alumina matrix phase and nanoparticle phase embedded therein can be deposited directly on the substrate surface. Alternatively, a coating described herein can further comprise one or more inner layers between the nanocomposite refractory layer and the substrate. Inner layer(s), in some embodiments, comprise one or more metallic elements selected from the group consisting of aluminum and metallic elements of Groups IVB, VB and VIB of the Periodic Table and one or more non-metallic elements selected from Groups IIIA, IVA, VA and VIA of the Periodic Table. In some embodiments, one or more inner layers between the substrate and refractory layer comprise a carbide, nitride, carbonitride, oxycarbonitride, oxide or boride of one or more metallic elements selected from the group consisting of aluminum and metallic elements of Groups IVB, VB and VIB of the Periodic Table.


For example, one or more inner layers are selected from the group consisting of titanium nitride, titanium carbonitride, titanium oxycarbonitride, titanium carbide, zirconium nitride, zirconium carbonitride, hafnium nitride and hafnium carbonitride. Further, a layer of titanium oxycarbonitride can be employed as a bonding layer for the refractory layer and inner layers of the coating. Inner layer(s) of the coating can have any thickness not inconsistent with the objectives of the present invention. In some embodiments, a single inner layer can have a thickness of at least 1.5 μm. Alternatively, a plurality of inner layers can collectively achieve thickness of at least 1.5 μm.


The refractory layer comprising the alumina matrix phase and nanoparticle phase embedded therein can be the outermost layer of the coating. Alternatively, a coating described herein can comprise one or more outer layers over the refractory layer. Outer layer(s) can comprise one or more metallic elements selected from the group consisting of aluminum and metallic elements of Groups IVB, VB and VIB of the Periodic Table and one or more non-metallic elements selected from Groups IIIA, IVA, VA and VIA of the Periodic Table. Outer layer(s) over the refractory layer can comprise a carbide, nitride, carbonitride, oxycarbonitride, oxide or boride of one or more metallic elements selected from the group consisting of aluminum and metallic elements of Groups IVB, VB and VIB of the Periodic Table. For example, one or more outer layers are selected from the group consisting of titanium nitride, titanium carbonitride, titanium oxycarbonitride, titanium carbide, zirconium nitride, zirconium carbonitride, hafnium nitride, hafnium carbonitride and alumina and mixtures thereof.


Outer layers of coatings described herein can have any thickness not inconsistent with the objectives of the present invention. A coating outer layer, in some embodiments, can have a thickness ranging from 0.2 μm to 5 μm.


Coatings described herein can be subjected to post-coat treatments. Coatings, for example, can be blasted with various wet and/or dry particle compositions. Post coat blasting can be administered in any desired manner. In some embodiments, post coat blasting comprises shot blasting or pressure blasting. Pressure blasting can be administered in a variety of forms including compressed air blasting, wet compressed air blasting, pressurized liquid blasting, wet blasting and steam blasting. Wet blasting, for example, is accomplished using a slurry of inorganic and/or ceramic particles, such as alumina, and water. The alumina particle slurry can be pneumatically projected at a surface of the coated cutting tool body to impinge on the surface of the coating. The alumina particles can generally range in size between about 20 μm and about 100 μm.


Blasting parameters include pressure, angle of impingement, distance to the part surface and duration. In some embodiments, angle of impingement can range from about 10 degrees to about 90 degrees, i.e., the particles impinge the coating surface at an angle ranging from about 10 degrees to about 90 degrees. Suitable pressures can range from 30-55 pounds per square inch (psi) at a distance to the coated surface of 1-6 inches. Further, duration of the blasting can generally range from 1-10 seconds or longer. Blasting can be generally administered over the surface area of the coating or can be applied to select locations such as in a workpiece contact area of the cutting tool. A workpiece contact area can be a honed region of the cutting tool.


In other embodiments, a coating is subjected to a polishing post-coat treatment. Polishing can be administered with paste of appropriate diamond or ceramic grit size. Grit size of the paste, in some embodiments, ranges from 1 μm to 10 μm. In one embodiment, a 5-10 μm diamond grit paste is used to polish the coating. Further, grit paste can be applied to the CVD coating by any apparatus not inconsistent with the objectives of the present invention, such as brushes. In one embodiment, for example, a flat brush is used to apply grit paste to the CVD coating in a workpiece contact area of the cutting tool.


A coating described herein can be blasted or polished for a time period sufficient to achieve a desired surface roughness (Ra) and/or other parameters such as reducing residual tensile stress in the coating. In some embodiments, a coating subjected to post-coat treatment has a surface roughness (Ra) selected from Table V.









TABLE V





Post-Coat Surface Roughness (Ra)


Coating Surface Roughness (Ra)-nm







≦500


≦250


≦200


10-250


50-175


25-150










Coating surface roughness can be determined by optical profilometry using WYKO® NT-Series Optical Profilers commercially available from Veeco Instruments, Inc. of Plainview, N.Y.


Further, a post-coat treatment, in some embodiments, does not remove one or more outer layers of the coating. In some embodiments, for example, a post-coat treatment does not remove an outer layer of TiN, TiCN and/or TiOCN. Alternatively, a post-coat treatment can remove or partially remove one or more outer layers, such as TiN, TiCN and TiOCN.


A coating described herein comprising a refractory layer having an alumina matrix phase and a nanoparticle phase therein can have nanohardness of at least 25 GPa or at least 30 GPa. In some embodiments, the coating has nanohardness of 25 GPa to 35 GPa. Coating nanohardness can be in the as-deposited state. Alternatively, the nanohardness can reflect a blasted or polished condition of the coating. Coating nanohardness values recited herein were determined from nano-indentation testing conducted with a Fischerscope HM2000 in accordance with ISO standard 14577 using a Vickers indenter. Indentation depth was set to 0.2 μm.


As described herein, the nanocomposite refractory layer is deposited by CVD. The alumina matrix can be deposited from a gaseous mixture of AlCl3, H2, CO2, HCl and optionally H2S. General CVD processing parameters for depositing the alumina matrix are provided in Table VI.









TABLE VI







Alumina Matrix CVD Processing Parameters
















Process
H2
AlCl3
CO2
CO
H2S
HCl
Temperature
Pressure
Time


Step
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
° C.
mbar
min.





Al2O3
Bal.
1-5
0.5-6

0.05-0.6
0.05-5
950-1050
50-120
3-500










The crystalline nanoparticles formed of at least one of a carbide, nitride and carbonitride of a Group IVB metal are deposited on alumina grains of the matrix phase by the pulsed introduction into the reactor of a gaseous mixture including reactants suitable for forming the crystalline nanoparticles. Importantly, each deposition of crystalline nanoparticles on the alumina matrix phase can be independent of any prior nanoparticle deposition. Therefore, gaseous reactants for nanoparticle deposition can vary over the duration of refractory layer synthesis. Group IVB metal nitride nanocrystals can be deposited from a gaseous mixture comprising H2, N2, HCl and gaseous reactant containing the Group IVB metal. In some embodiments, the gaseous reactant is metal chloride, such as MCl4, wherein M is a Group IVB metal. General CVD processing parameters for Group IVB metal nitride nanocrystals are provided in Table VII.









TABLE VII







Group IVB Metal Nitride Nanocrystal CVD Processing Parameters



















Temper-




Process
H2
N2
MCl4

ature
Pressure
Time


Step
vol. %
vol. %
vol. %
HCl
° C.
mbar
min.





MN*
Bal.
12-20
0.2-2
0-5
900-1050
50-200
3-60


Nano-


crystals





*M = Group IVB metal







Group IVB metal carbide nanocrystals can be deposited from a gaseous mixture comprising H2, CH4, HCl and gaseous reactant containing the Group IVB metal. In some embodiments, the gaseous reactant is metal chloride, such as MCl4, wherein M is a Group IVB metal. General CVD processing parameters for Group IVB metal carbide nanocrystals are provided in Table VIII.









TABLE VIII







Group IVB Metal Carbide Nanocrystal


CVD Processing Parameters















H2
CH4
MCl4
HCl
Temper-
Pres-



Process
vol.
vol.
vol.
vol.
ature
sure
Time


Step
%
%
%
%
° C.
mbar
min.





MC*
Bal.
1-5
0.1-2
0-5
900-1050
50-200
3-60


Nano-


crystals










Group IVB metal carbonitride nanocrystals can be deposited from a gaseous mixture comprising H2, CH4, HCl, N2 and gaseous reactant containing the Group IVB metal. In some embodiments, the gaseous reactant is metal chloride, such as MCl4, wherein M is a Group IVB metal. General CVD processing parameters for Group IVB metal carbonitride nanocrystals are provided in Table IX.









TABLE IX







Group IVB Metal Carbonitride Nanocrystal CVD Processing Parameters















Process
H2
N2
CH4
MCl4

Temperature
Pressure
Time


Step
vol. %
vol. %
vol. %
vol. %
HCl
° C.
mbar
min.





MCN*
Bal.
10-15
1-5
1-5
0-5
900-1050
50-200
3-60


Nano-


crystals










As described herein, nanoparticle deposition by pulsed introduction of suitable reactant gasses does not terminate alumina grain development or require alumina renucleation to continue alumina grain development/growth during deposition of the refractory layer. Therefore, alumina grain growth is resumed after pulsed nanoparticle deposition by reintroduction of the reactant gas mixture of Table VI. Continued alumina grain growth embeds the nanoparticle phase in the grain architecture as illustrated in FIGS. 2-5 herein.


The refractory layer can be deposited directly on the substrate surface. Alternatively, a plurality of coating inner layers can reside between the substrate and refractory layer. General CVD deposition parameters for various inner layers are provided in Table X.









TABLE X







CVD Parameters for Inner layer Deposition











Base Layer
Gas
Temperature
Pressure
Duration


Composition
Mixture
° C.
mbar
min.





TiN
H2, N2, TiCl4
800-900 
 60-100
10-90 


MT-TiCN
H2, N2, TiCl4, CH3CN
750-900 
 65-100
50-400


HT-TiCN
H2, N2, TiCl4, CH4
900-1050
 60-160
30-200


TiOCN
H2, N2, TiCl4, CH4, CO
900-1050
200-550
30-70 










The foregoing general CVD parameters for inner layer deposition, in some embodiments, can be applied for deposition of one or more outer layers over the refractory layer.


These and other embodiments are further illustrated in the following non-limiting examples.


Example 1
Coated Cutting Tools

Coated cutting tools described herein were produced by placing cemented tungsten carbide (WC—Co) cutting insert substrates [ANSI standard geometry CNMG432RN] into an axial flow hot-wall CVD reactor. The cutting inserts comprised 6 wt. % cobalt binder with the balance WC grains of size 1-5 μm. A coating including a refractory layer comprising a matrix phase of alumina and crystalline TiN nanoparticle phase was deposited on the cutting inserts according to Tables XI and XII. The crystalline TiN nanoparticles were distributed in ninety-six (96) nanoparticle concentration bands along the thickness of the refractory layer, the 96 nanoparticle concentration bands corresponding to 96 cycles of TiN deposition according to Table XI. The nanocomposite refractory layer morphology was consistent with the cross-sectional TEM images provided in FIGS. 2 and 3 discussed above. An outer layer of TiN was deposited over the nanocomposite refractory layer to complete the coating. Alternatively, if desired, an outer layer of TiOCN can be deposited over the nanocomposite refractory layer to complete the coating.









TABLE XI







CVD Deposition of Coating


















H2
N2
TiCl4
CH3CN
CH4
AlCl3
CO2
CO
HCl
H2S


Process Step
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %




















TiN
Bal.
18.40
0.95









MT-TiCN
Bal.
27.8
1.31
0.001




1.40



HT-TiCN
Bal.
16.69
0.76

3.70







TiOCN
Bal.
17.50
1.08

2.52


1.10
1.10



Al2O3
Bal.




4.84
2.42

3.00
0.10


TiN Nano-
Bal.
18.00
0.95





Opt.



reinforcement*


TiN
Bal.
25.70
0.76





0.69



(Outer Layer)


TiOCN**
Bal.
38.00
0.99

2.6


1.12
1.00



(Outer Layer)





*Periodic introduction onto alumina layer to form TiN nanophase reinforcement


**Alternative to TiN outer layer













TABLE XII







CVD Deposition Steps











Temperature
Pressure
Time


Process Step
° C.
mbar
min.





TiN
850-960 
 60-90 
10-90 


MT-TiCN
900-940 
 70-100
50-400


HT-TiCN
900-1050
 60-150
30-200


TiOCN
950-1050
200-500
30-70 


Al2O3
950-1050
 50-120
10-500


TiN Nano-
900-1050
 50-200
 3-60 


reinforcement*


(per reinforcement





deposition)


TiN (Outer Layer)
900-1050
 50-200
30-180


TiOCN (Outer Layer)**
950-1050
200-500
30-200





*Periodic introduction onto alumina layer to form TiN nanophase reinforcement.


**Alternative to TiN outer layer







The resulting coating exhibited the properties provided in Table XIII.









TABLE XIII







Properties of CVD Coating










Coating Layers
Thickness (μm)














TiN
0.5



MT-TiCN
10.5



HT-TiCN
0.8



Al2O3-[TiN]96
9.0



TiN
1.6










Example 2
Coated Cutting Tools

WC—Co cutting insert substrates consistent with the substrates described in Example 1 were placed into an axial flow hot-wall CVD reactor. A coating including a refractory layer comprising a matrix phase of alumina and crystalline TiC nanoparticle phase was deposited on the cutting inserts according to Tables XIV and XV. The crystalline TiC nanoparticles were distributed in ninety-six (96) nanoparticle concentration bands along the thickness of the refractory layer, the 96 nanoparticle concentration bands corresponding to 96 cycles of TiC deposition according to Table XIV. The nanocomposite refractory layer morphology was consistent with the cross-sectional TEM images provided in FIG. 4 discussed above. An outer layer of TiN was deposited over the nanocomposite refractory layer to complete the coating. Alternatively, if desired, an outer layer of TiOCN can be deposited over the nanocomposite refractory layer to complete the coating.









TABLE XIV







CVD Deposition of Coating


















H2
N2
TiCl4
CH3CN
CH4
AlCl3
CO2
CO
HCl
H2S


Process Step
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %




















TiN
Bal.
18.40
0.95









MT-TiCN
Bal.
27.8
1.31
0.001




1.40



HT-TiCN
Bal.
16.69
0.76

3.70







TiOCN
Bal.
17.50
1.08

2.52


1.10
1.10



Al2O3
Bal.




4.84
2.42

3.00
0.10


TiC Nano-
Bal.

0.50

2.30



2.50



reinforcement*


TiN
Bal.
25.70
0.76





0.69



(Outer Layer)


TiOCN**
Bal.
38.00
0.99

2.6


1.12
1.00



(Outer Layer)





*Periodic introduction onto alumina layer to form TiN nanophase reinforcement.


**Alternative to TiN outer layer













TABLE XV







CVD Deposition Steps











Temperature
Pressure
Time


Process Step
° C.
mbar
min.





TiN
850-960 
 60-90 
10-90 


MT-TiCN
900-940 
 70-100
50-400


HT-TiCN
900-1050
 60-150
30-200


TiOCN
950-1050
200-500
30-70 


Al2O3
950-1050
 50-120
10-500


TiC Nano-
900-1050
 50-200
 3-60 


reinforcement*


(per reinforcement





deposition)


TiN (Outer Layer)
900-1050
 50-200
30-180


TiOCN (Outer Layer)**
950-1050
200-500
30-200





*Periodic introduction onto alumina layer to form TiC nanophase reinforcement.


**Alternative to TiN outer layer







The resulting coating exhibited the properties provided in Table XVI.









TABLE XVI







Properties of CVD Coating










Coating Layers
Thickness (μm)














TiN
0.4



MT-TiCN
11.6



HT-TiCN
0.9



Al2O3-[TiN]96
9.3



TiN
1.7










Example 3
Coated Cutting Tools

WC—Co cutting insert substrates consistent with the substrates described in Example 1 were placed into an axial flow hot-wall CVD reactor. A coating including a refractory layer comprising a matrix phase of alumina and crystalline TiCN nanoparticle phase was deposited on the cutting inserts according to Tables XVII and XVIII. The crystalline TiCN nanoparticles were distributed in ninety-six (96) nanoparticle concentration bands along the thickness of the refractory layer, the 96 nanoparticle concentration bands corresponding to 96 cycles of TiCN deposition according to Table XVII. An outer layer of TiN was deposited over the nanocomposite refractory layer to complete the coating. Alternatively, if desired, an outer layer of TiOCN can be deposited over the nanocomposite refractory layer to complete the coating.









TABLE XVII







CVD Deposition of Coating


















H2
N2
TiCl4
CH3CN
CH4
AlCl3
CO2
CO
HCl
H2S


Process Step
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %
vol. %




















TiN
Bal.
18.40
0.95









MT-TiCN
Bal.
27.8
1.31
0.001




1.40



HT-TiCN
Bal.
16.69
0.76

3.70







TiOCN
Bal.
17.50
1.08

2.52


1.10
1.10



Al2O3
Bal.




4.84
2.42

3.00
0.10


TiCN Nano-
Bal.
11.62
2.45

1.98



2.35



reinforcement*


TiN
Bal.
25.70
0.76





0.69



(Outer Layer)


TiOCN**
Bal.
38.00
0.99

2.6


1.12
1.00



(Outer Layer)





**Periodic introduction onto alumina layer to form TiCN nanophase reinforcement


**Alternative to TiN outer layer













TABLE XVIII







CVD Deposition Steps











Temperature
Pressure
Time


Process Step
° C.
mbar
min.





TiN
850-960 
 60-90 
10-90 


MT-TiCN
900-940 
 70-100
50-400


HT-TiCN
900-1050
 60-150
30-200


TiOCN
950-1050
200-500
30-70 


Al2O3
950-1050
 50-120
10-500


TiCN Nano-
900-1050
 50-200
 3-60 


reinforcement*


(per reinforcement





deposition)


TiN (Outer Layer)
900-1050
 50-200
30-180


TiOCN (Outer Layer)**
950-1050
200-500
30-200





*Periodic introduction onto alumina layer to form TiCN nanophase reinforcement.


**Alternative to TiN outer layer







The resulting coating exhibited the properties provided in Table XIX.









TABLE XIX







Properties of CVD Coating










Coating Layers
Thickness (μm)














TiN
0.4



MT-TiCN
10.1



HT-TiCN
0.9



Al2O3-[TiCN]96
11.6



TiN
1.8










Example 4
Coating Hardness

Coated cutting tools of Examples 1-3 were subjected to nanohardness testing. Nanohardness was determined from nano-indentation testing conducted with a Fischerscope HM2000 in accordance with ISO standard 14577 using a Vickers indenter. Indentation depth was set to 0.2 μm. Nanohardness was determined for coated cutting tools of Examples 1-3 in the as-deposited state and blasted state. Post-coat blasting was administered with an alumina particle slurry for 3-5 seconds with three nozzles. The nozzles provided angles of impingement of 10, 40 and 80 degrees. Blasting removed the outermost TiN layer of the coating. Nanohardness was also determined for comparative cutting inserts of identical ANSI geometry having a CVD coating detailed in Table XX (Comparative 1).









TABLE XX







Comparative Cutting Insert CVD Coating










Coating Layers
Thickness (μm)














TiN
0.5



MT-TiCN
10.5



HT-TiCN
1.0



α-Al2O3
8.4



TiN
1.5











Nanohardness was determined for Comparative 1 cutting inserts in the as-deposited state and blasted state. Blasting conditions for Comparative 1 cutting inserts were the same as that employed for the cutting inserts of Examples 1-3. The results of the nanohardness testing are provided in Table XXI.









TABLE XXI







CVD Coating Nanohardness









Cutting
Nanohardness (GPa)-
Nanohardness (GPa)-


Insert
As deposited
Wet Blasted





Example 1
29.5
33.5


Example 2
30.5
28.8


Example 3
28.5
28.7


Comparative 1
25.8
27.0









Example 5
Metal Cutting Testing

Coated cutting inserts of Examples 1-3 and Comparative 1 were subjected to continuous turning testing according to the parameters below. Comparative 1 exhibited the CVD coating architecture in Table XX above. For the turning testing, three separate cutting inserts were tested for each coating architecture of Examples 1-3 and Comparative 1 to generate repetition 1, repetition 2, repetition 3 and mean cutting lifetime.


Turning Parameters


Workpiece: 1045 Steel


Speed: 1000 sfm


Feed Rate: 0.012 ipr


Depth of Cut: 0.08 in


Lead Angle: −5°


Coolant—Flood


End of Life was registered by one or more failure modes of:


Uniform Wear (UW) of 0.012 inches


Max Wear (MW) of 0.012 inches


Nose Wear (NW) of 0.012 inches


Depth of Cut Notch Wear (DOCN) of 0.012 inches


Trailing Edge Wear (TW) of 0.012 inches


The results of the continuous turning testing are provided in Table XXII.









TABLE XXII







Continuous Turning Testing Results












Coated
Repetition 1
Repetition 2
Repetition 3
Mean Cutting
Relative Tool


Cutting
Lifetime
Lifetime
Lifetime
Lifetime
Life vs.


Insert
min.
min.
min.
min.
Comparative 1















Example 1
10.2
14.5
16.4
13.7
145%


Example 2
19.9
19.9
16.9
18.9
199%


Example 3
16.3
12.3
18.6
15.7
166%


Comparative
9.9
8.0
10.5
9.5



1















As provided in Table XXII, each of the coated cutting inserts of Examples 1-3 exhibited dramatic improvements in cutting lifetime relative to Comparative 1.


Various embodiments of the invention have been described in fulfillment of the various objects of the invention. It should be recognized that these embodiments are merely illustrative of the principles of the present invention. Numerous modifications and adaptations thereof will be readily apparent to those skilled in the art without departing from the spirit and scope of the invention.

Claims
  • 1. A coated article comprising: a substrate; anda coating deposited by chemical vapor deposition (CVD) adhered to the substrate, the coating including a refractory layer having a matrix phase comprising alumina and a nanoparticle phase dispersed throughout the matrix phase, the nanoparticle phase comprising crystalline nanoparticles formed of at least one of a carbide, nitride and carbonitride of a Group IVB metal.
  • 2. The coated article of claim 1, wherein the crystalline nanoparticles have an average size less than 20 nm in at least one dimension.
  • 3. The coated article of claim 1, wherein the crystalline nanoparticles are substantially spherical or elliptical.
  • 4. The coated article of claim 3, wherein the substantially spherical or elliptical crystalline nanoparticles have an average size of less 5 nm in at least one dimension.
  • 5. The coated article of claim 1, wherein the crystalline nanoparticles are rod-shaped.
  • 6. The coated article of claim 5, wherein the rod-shaped crystalline nanoparticles have an average diameter less than 5 nm and an average length of 10 nm to 500 nm.
  • 7. The coated article of claim 1, wherein the crystalline nanoparticles are dispersed throughout the matrix phase in a predetermined manner.
  • 8. The coated article of claim 1, wherein the crystalline nanoparticles are distributed in the matrix phase in one or more nanoparticle concentration bands.
  • 9. The coated article of claim 8, wherein the nanoparticle concentration bands are separated by a periodic distance.
  • 10. The coated article of claim 9, wherein the periodic distance ranges from 10 nm to 5 μm.
  • 11. The coated article of claim 9, wherein the periodic distance ranges from 10 nm to 500 nm.
  • 12. The coated article of claim 8, wherein distances between the nanoparticle concentration bands vary along thickness of the refractory layer in a predetermined manner.
  • 13. The coated article of claim 1, wherein composition of the crystalline nanoparticles varies with thickness of the refractory layer.
  • 14. The coated article of claim 8, wherein composition of the crystalline nanoparticles varies between the nanoparticle concentration bands.
  • 15. The coated article of claim 8, wherein the nanoparticle concentration bands each have a thickness less than 50 nm.
  • 16. The coated article of claim 8, wherein the crystalline nanoparticles of at least one nanoparticle concentration band are aggregated forming a continuous layer in the matrix phase.
  • 17. The coated article of claim 16, wherein the continuous layer has a thickness of 5 to 50 nm.
  • 18. The coated article of claim 1, wherein alumina grains of the matrix phase are columnar having a size greater than 1 μm.
  • 19. The coated article of claim 1, wherein the alumina grains of the matrix phase are columnar having a size less than 1 μm.
  • 20. The coated article of claim 1, wherein the alumina matrix phase is a substrate for the nanoparticle phase.
  • 21. The coated article of claim 1, wherein the matrix phase further comprises a Group IVB metal dopant.
  • 22. The coated article of claim 1, wherein the refractory layer has thickness of 0.05 μm to 20 μm.
  • 23. The coated article of claim 1, wherein the CVD coating has nanohardness greater than 30 GPa.
  • 24. The coated article of claim 1, wherein the CVD coating has nanohardness of 25 GPa to 35 GPa.
  • 25. The coated article of claim 1 further comprising one or more inner layers between the refractory layer and the substrate, an inner layer comprising one or more metallic elements selected from the group consisting of aluminum and metallic elements of Groups IVB, VB and VIB of the Periodic Table and one or more non-metallic elements of Groups IIIA, VI, VA and VIA of the Periodic Table.
  • 26. The coated article of claim 1, wherein the substrate is cemented carbide, carbide, cermet or steel.
  • 27. A coated article comprising: a substrate; anda coating deposited by chemical vapor deposition (CVD) adhered to the substrate, the coating including a refractory layer having a matrix phase comprising alumina and a nanoparticle phase contained within the matrix phase, the nanoparticle phase comprising crystalline nanoparticles formed of at least one of a carbide, nitride and carbonitride of a Group IVB metal, wherein composition of the crystalline nanoparticles varies with thickness of the refractory layer.
  • 28. The coated article of claim 27, wherein the crystalline nanoparticles are distributed in the matrix phase in one or more nanoparticle concentration bands.
  • 29. The coated article of claim 28, wherein the nanoparticle concentration bands are separated by a periodic distance.
  • 30. The coated article of claim 28, wherein the nanoparticle concentrations bands exhibit aperiodic separation.
  • 31. The coated article of claim 27, wherein the crystalline nanoparticles of at least one nanoparticle concentration band are aggregated forming a continuous layer in the matrix phase.
  • 32. The coated article of claim 31, wherein the matrix phase further comprises a Group IVB metal dopant.
  • 33. A coated article comprising: a substrate; anda coating deposited by chemical vapor deposition (CVD) adhered to the substrate, the coating including a refractory layer having a matrix phase comprising alumina and a nanoparticle phase contained within the matrix phase, the nanoparticle phase comprising crystalline nanoparticles formed of at least one of a carbide, nitride and carbonitride of a Group IVB metal, wherein the matrix phase further comprises at least one Group IVB metal dopant.
  • 34. The coated article of claim 33, wherein the CVD coating has nanohardness of 25 GPa to 35 GPa.
  • 35. The coated article of claim 33, wherein the refractory layer has thickness of 0.05 μm to 20 μm.
  • 36. The coated article of claim 33, wherein the crystalline nanoparticles are distributed in the matrix phase in one or more nanoparticle concentration bands.
  • 37. The coated article of claim 36, wherein the nanoparticle concentration bands exhibit periodic separation.
US Referenced Citations (80)
Number Name Date Kind
4112148 Fonzi Sep 1978 A
4180400 Smith et al. Dec 1979 A
4576836 Colmet et al. Mar 1986 A
4701384 Sarin et al. Oct 1987 A
4702970 Sarin et al. Oct 1987 A
4745010 Sarin et al. May 1988 A
4746563 Nakano et al. May 1988 A
4749629 Sarin et al. Jun 1988 A
4751109 Sarin et al. Jun 1988 A
4844951 Sarin et al. Jul 1989 A
5310607 Schulz et al. May 1994 A
5447804 Schulz et al. Sep 1995 A
5770261 Nakamura et al. Jun 1998 A
5827570 Russell Oct 1998 A
5871850 Moriguchi et al. Feb 1999 A
5879823 Prizzi et al. Mar 1999 A
5972495 Ishii et al. Oct 1999 A
5985427 Ueda et al. Nov 1999 A
6156383 Ishii et al. Dec 2000 A
6183846 Moriguchi et al. Feb 2001 B1
6284356 Kiriyama Sep 2001 B1
6333103 Ishii et al. Dec 2001 B1
6426137 Oshika et al. Jul 2002 B1
6436519 Holzschuh Aug 2002 B2
6599062 Oles et al. Jul 2003 B1
6641939 Lee et al. Nov 2003 B1
6660371 Westphal et al. Dec 2003 B1
6689422 Warnes et al. Feb 2004 B1
6713172 Ljungberg et al. Mar 2004 B2
6726987 Kathrein et al. Apr 2004 B2
6756111 Okada et al. Jun 2004 B1
6849132 Warnes et al. Feb 2005 B2
6869668 Martensson Mar 2005 B2
6902764 Ljungberg et al. Jun 2005 B2
7011867 Martensson Mar 2006 B2
7090914 Yamagata et al. Aug 2006 B2
7094447 Ruppi Aug 2006 B2
7163735 Ruppi Jan 2007 B2
7241492 Kohara et al. Jul 2007 B2
7273665 Hayahi et al. Sep 2007 B2
7276301 Tsushima et al. Oct 2007 B2
7326461 Sottke et al. Feb 2008 B2
7378158 Richter et al. May 2008 B2
7396581 Ruppi Jul 2008 B2
7410707 Fukui et al. Aug 2008 B2
7416778 Westergren et al. Aug 2008 B2
7442433 Honma et al. Oct 2008 B2
7498089 Omori et al. Mar 2009 B2
7531212 Kohara et al. May 2009 B2
7531213 Bjormander May 2009 B2
7597511 Tomita et al. Oct 2009 B2
7597951 Bjormander et al. Oct 2009 B2
7597970 Fukano et al. Oct 2009 B2
7691496 Park et al. Apr 2010 B2
7803464 Okada et al. Sep 2010 B2
7820310 Bjormander Oct 2010 B2
7901788 Warnes et al. Mar 2011 B2
7906230 Watanabe et al. Mar 2011 B2
7923101 Ruppi Apr 2011 B2
7928028 Nawa et al. Apr 2011 B2
7939181 Ramm et al. May 2011 B2
7967533 Omori et al. Jun 2011 B2
7968182 Trinh et al. Jun 2011 B2
7972714 Okada et al. Jul 2011 B2
8012611 Okada et al. Sep 2011 B2
8025991 Schier Sep 2011 B2
8071211 Koike et al. Dec 2011 B2
8080312 McNerny et al. Dec 2011 B2
8097332 Omori et al. Jan 2012 B2
8119226 Reineck et al. Feb 2012 B2
8119227 Reineck et al. Feb 2012 B2
8129040 Quinto et al. Mar 2012 B2
8152971 Quinto et al. Apr 2012 B2
8221838 Gates, Jr. et al. Jul 2012 B2
8288019 Nagano et al. Oct 2012 B2
20010006724 Holzschuh Jul 2001 A1
20020114945 Greenberg et al. Aug 2002 A1
20060029813 Kutilek et al. Feb 2006 A1
20070289280 Marquardt Dec 2007 A1
20120003452 Tomita et al. Jan 2012 A1
Foreign Referenced Citations (26)
Number Date Country
102581324 Jul 2012 CN
2736982 Mar 1979 DE
56152962 Nov 1981 JP
57158372 Sep 1982 JP
5921586 Feb 1984 JP
5985860 May 1984 JP
04-256503 Sep 1992 JP
0516031 Jan 1993 JP
4195518 Jul 1998 JP
2000-218409 Aug 2000 JP
4019244 Jun 2002 JP
2003039207 Feb 2003 JP
2005-279825 Oct 2005 JP
2006219739 Aug 2006 JP
4645983 Oct 2006 JP
2006289556 Oct 2006 JP
2008019489 Jan 2008 JP
2008019498 Jan 2008 JP
4822120 Feb 2008 JP
5019255 Jan 2009 JP
5099490 Apr 2009 JP
5099500 Jul 2009 JP
2011057529 Mar 2011 JP
2011127165 Jun 2011 JP
2011184295 Sep 2011 JP
2012143825 Aug 2012 JP
Non-Patent Literature Citations (9)
Entry
X. Feng et al., “Converting Ceria Polyhedral Nanoparticles into Single-Crystal Nanospheres”, Science Magazine, vol. 312, Jun. 9, 2006, pp. 1504-1508.
Z. Yu et al., “Atomic-resolution observation of Hf-doped alumina grain boundaries”, SciVerse ScienceDirect, Scripta Materialia 68 (2013) pp. 703-706.
N. Shibata et al., “Atomic-scale imaging of individual dopant atoms in a buried interface”, Nature Materials, vol. 8, 2009, pp. 654-658.
J. P. Buban et al., “Grain Boundary Strengthening in Alumina by Rare Earth Impurities”, Science Magazine, vol. 311, Jan. 13, 2006, pp. 212-215.
Z. Li et al., “Nanodomain formation and distribution in Gd-doped ceria”, SciVerse ScienceDirect, Materials Research Bulletin 47 (2012) pp. 763-767.
C. Bjormander, “CVD deposition and characterization of coloured Al2O3/ZrO2 multilayers”, ScienceDirect, Surface & Coatings Technology 201 (2006) pp. 4032-4036.
D. Hochauer et al., “Titanium doped CVD alumina coatings”, ScienceDirect, Surface & Coatings Technology 203 (2008) pp. 350-356.
W. C. Russell et al., “Wear Characteristics and Performance of Composite Alumina-Zirconia CVD Coatings”, Int. J. of Refractory Metals & Hard Materials 14 (1996) pp. 51-58.
S. Taylor, “Grain Boundary Structure and Solute Segregation in Titanium-Doped Sapphire Bicrystals”, Disseeration, University of California, Berkley, Spring 2002, pp. 1-222.
Related Publications (1)
Number Date Country
20160160347 A1 Jun 2016 US