The invention relates to an electronic structure that comprises a topological insulator layer located adjacent to at least one layer of a negative capacitance material (such as a ferroelectric material). These structures have particular application as low-voltage field effect transistors.
In transistors, a large fraction of power dissipation occurs due to irreversible charging and discharging of the gate capacitor to turn conduction on and off. Its efficiency is characterized by the sub-threshold swing, such that a transistor with a small sub-threshold swing transitions rapidly between its on (high current) and off (low current) states. The sub-threshold swing is the fundamental critical parameter determining the operation of a transistor in low-power applications such as switches.
In a conventional field-effect transistor, a voltage Vg applied to the gate raises an energy barrier Eg in the channel which impedes conduction, realizing a switch. The effective sub-threshold swing S* is given by S*=e[dEg/dVg]−1. and it is well-known that thermal activation of carriers in the channel forces S*≥1, often termed “Boltzmann's tyranny”. In a topological quantum field-effect transistor, a voltage difference Vg between two gates produces an electric field, and induces a sublattice potential difference λv which opens a gap Eg, which acts as a barrier to conduction. The effective sub-threshold swing S* for a topological transistor is given by S*=e[dEg/dλv]−1, and λv≤Vg, S*=1 corresponds to Boltzmann's limit. In the simplest models the gap equates to the potential difference established by the gates λv, and one expects S*≥1. However, Rashba spin-orbit coupling can result in S*<1 in a topological quantum field-effect transistor, making this device promising for low-voltage applications. Potential shortcomings, however, are that λv may be substantially less than Vg dues to screening in the topological channel material, and the strength of Rashba spin-orbit coupling is limited.
It is therefore desirable to further reduce the subthreshold swing in topological transistor devices to reduce power dissipation and improve the efficiency of these devices.
It is an object of the invention to address one or more shortcomings of the prior art and/or provide a useful alternative.
Reference to any prior art in the specification is not an acknowledgment or suggestion that this prior art forms part of the common general knowledge in any jurisdiction or that this prior art could reasonably be expected to be understood, regarded as relevant, and/or combined with other pieces of prior art by a skilled person in the art.
In a first aspect of the invention there is provided a structure comprising: a top gate electrode and a bottom gate electrode, a channel layer formed from a channel material with a band gap modulable by electric field, the channel layer being electrically insulated from the top gate electrode and the bottom gate electrode and being located adjacent to at least one layer of a negative capacitance material.
In an embodiment, the combined capacitance between the top and bottom gate electrodes is greater than 0. The purpose of balancing the negative capacitance of the negative capacitance material and the positive capacitance of the channel material is to get a net positive capacitance. The net positive capacitance ensures that there is no spontaneous and hysteretic polarization of the negative capacitance material which is undesirable, particularly in transistors.
In a second aspect of the invention there is provided a structure comprising:
In an embodiment of the first or second aspects, the top gate electrode and the bottom gate electrode are operable to apply an electric field across the channel layer.
In an embodiment of the first or second aspects, the top gate electrode and the bottom gate electrode are operable independently of one another.
In an embodiment, the structure is a layered structure comprising or consisting of the following sequential layered arrangement: the first insulating layer, the planar channel layer, and the second insulating layer; wherein the top gate electrode is in electrical contact with the first insulating layer and the bottom gate electrode is in electrical contact with the second insulating layer.
In an embodiment, both of the first insulating layer and the second insulating layers are formed from the ferroelectric material. The first and second insulating layers may be formed from the same ferroelectric material or different ferroelectric materials. However, it is preferred that the first and second insulating layers are formed from the same ferroelectric material.
In an embodiment of the first and second aspects, the negative capacitance material is a ferroelectric material. Preferably, the ferroelectric material is selected from the group consisting of: Hf0.5Zr0.5O2, La-doped HfO2, BiFeO3, BaTiO3, PbTiO3, Pb[ZrxTi1-x]O3, and In2Se3.
In an embodiment, the negative capacitance material exhibits negative capacitance and wherein the channel material exhibits positive capacitance, and the combined capacitance of the channel layer, the first insulating layer, and second insulating layer is greater than 0. As discussed above, the net positive capacitance ensures that there is no spontaneous and hysteretic polarization of the ferroelectric which is undesirable, particularly in transistors. In more detail, the electric field-polarization E-P relationship for the ferroelectric layers may be expressed as E=2αFEP+4βFEP3+O(P5), where αFE and βFE are parameters, and O(P5) indicates additional terms in powers of P greater than or equal to 5. The condition αFE<0 indicates that the layer has a negative capacitance. Then the total thickness of the ferroelectric layers tFE should be chosen to be as small as practicable but larger than (2|αFE|CTI)−1, where CTI is the capacitance per area of the channel layer.
In an embodiment, the first insulating layer is adjacent to the channel layer. Preferably, the first insulating layer has a first planar side adjacent to the channel layer, and an opposite facing second planar side adjacent to the top gate electrode.
In an embodiment, the second insulating layer is adjacent to the channel layer. Preferably, the second insulating layer has a first planar side adjacent to the channel layer, and an opposite facing second planar side adjacent to the top gate electrode.
In an embodiment, the first insulating layer and the second insulating layer are each in physical contact with the planar channel layer, the first insulating layer being arranged on a first side of the planar channel layer and the second insulating layer being arranged on a second side of the planar channel layer.
In an embodiment of the first and second aspects, the structure further comprises a source electrode in electrical contact with the planar channel layer, and a drain electrode spaced apart from the source electrode and in electrical contact with the planar channel layer.
In one form of the above embodiment, the source electrode is in electrical contact with the planar channel layer via a doped semiconductor material, and/or the drain electrode is in electrical contact with the planar channel layer via a doped semiconductor material.
In one form of the above embodiment, the source electrode is formed from a doped semiconductor material and/or the drain electrode is formed from a doped semiconductor material.
In an embodiment of the first and second aspects, the top gate electrode and/or the bottom gate electrode are formed from a metal.
In an embodiment of the first and second aspects, the top gate electrode and the bottom gate electrode are configured to apply an electric field across the channel layer in a direction perpendicular to a plane of the channel layer.
In an embodiment of the first and second aspects, the channel material is selected from the group consisting of: few-layer graphene (preferably bilayer or ABC-stacked trilayer graphene), a two-dimensional semiconductor (preferably monolayer or bilayer blue phosphorene or black phosphorene), a topological material (such as a two-dimensional topological material, where “two-dimensional topological material” refers to the topological material being electronically two-dimensional).
In one form of the above embodiment where the channel material is a topological material, the topological material is in the form of a thin film with a thickness of two unit cells or less.
In one form of the above embodiment where the channel material is a topological material, the topological material exhibits a topological phase transition between a trivial state and a non-trivial state at a critical electric field strength.
In one form of the above embodiment where the channel material is a topological material, the topological material has a staggered honeycomb lattice structure. Preferably, lattice atoms of the staggered honeycomb lattice structure comprise one or more atoms selected from the group consisting of: As, Sb, Bi. Preferably, the staggered honeycomb lattice is of the form X, XY, or XYZ, where X is selected from the group consisting of As, Sb, Bi, and Y and Z are each independently selected from the group consisting of H, Cl, Br, or F.
In one form of the above embodiment where the channel material is a topological material, the topological material is a topological Dirac semimetal. Preferably, the topological Dirac semimetal is selected from the group consisting of: a material of the form A3Bi where A is an alkali metal, Cd3As2.
In one form of the above embodiment where the channel material is a topological material, the topological material is a topological insulator. Preferably, the topological insulator is selected from the group consisting of: a material of the form A3Bi where A is an alkali metal, HgTe, Bi2Se3.
In an embodiment of the first and second aspects, the channel layer is in the form of a thin film having a thickness of less than 10 nm.
In an embodiment of the first and second aspects, the structure is a field effect transistor or a component thereof.
In a third aspect of the invention, there is provided a method of operating a structure according to the first aspect of the invention, the second aspect of the invention, and/or embodiments thereof, and/or forms thereof, the method comprising:
In an embodiment, altering the bandgap of the channel layer further comprises switching the channel material between a trivial state and a non-trivial or topological state.
In a fourth aspect of the invention, there is provided use of a structure according to the first aspect of the invention, the second aspect of the invention, and/or embodiments thereof, and/or forms thereof in an electrical device.
In a fifth aspect of the invention, there is provided an electrical device comprising the structure according to the first aspect of the invention, the second aspect of the invention, and/or embodiments thereof, and/or forms thereof.
As used herein, except where the context requires otherwise, the term “comprise” and variations of the term, such as “comprising”, “comprises” and “comprised”, are not intended to exclude further additives, components, integers or steps.
Further aspects of the present invention and further embodiments of the aspects described in the preceding paragraphs will become apparent from the following description, given by way of example and with reference to the accompanying drawings.
The invention broadly relates to a structure comprising: a top gate electrode and a bottom gate electrode, a channel layer formed from a channel material with a band gap modulable by electric field (such as a topological material), the channel layer being electrically insulated from the top gate electrode and the bottom gate electrode and being located adjacent to at least one layer of a negative capacitance material.
The inventors have found that this structure can be used to form a topological quantum field effect transistor (TQFET) with reduced sub-threshold swing as compared with a similar transistor without the negative capacitance material.
In particular, TQFETs are electric-field effect transistors, where the barrier to conduction is created through an electric field, rather than raising an existing potential barrier in the channel as per conventional metal-oxide-semiconductor field-effect transistors (MOSFET). Thus, a TQFET can take full advantage of electric field amplification by negative capacitance, whereas this is not possible with a conventional MOSFET since the electric field is zero in the channel in the subthreshold region.
In more detail, a conventional MOSFET has a capacitance between channel and gate which is large compared to other parasitic capacitances to the channel. In the subthreshold regime, the capacitance between channel and gate is large compared to the quantum capacitance of the channel. Under these conditions, when a gate voltage is applied, i.e. an electrochemical potential difference between gate and channel, this raises the chemical potential of the channel by the same amount, while hardly changing the electrostatic potential of the channel (the electrochemical potential difference is the sum of these two). Thus, the electrostatic potential difference between gate and channel is minimal, and there is very little electric field induced by the gate voltage. Thus, in a conventional MOSFET, because the electric field is near zero in the subthreshold regime, the device cannot benefit from amplification of the electric field through the use of a negative capacitance in series with a positive capacitance.
In contrast, in a TQFET, electric field is used to modify the bandgap of a channel material. In the subthreshold regime, the increased bandgap will act as an increased activation barrier to electron flow. This is completely different to a MOSFET: rather than using the chemical potential change to create a barrier in a semiconductor with a fixed bandgap, the electric field changes the bandgap in a channel with a fixed chemical potential.
The inventors have found that TQFET devices can benefit from amplification of the electric field through the use of a negative capacitance in series with a positive capacitance. This can be accomplished by nearly balancing the positive capacitance of the channel itself with the negative capacitance of a ferroelectric to produce a net positive capacitance (noting that the net positive capacitance ensures that there is no spontaneous and hysteretic polarization of the negative capacitance material). The electric field amplification becomes very large when this balance is near perfect. Advantageously, this amplification of the electric field means that the change in bandgap will be larger for a given change in gate voltage, and thus the subthreshold swing will be smaller.
The invention will be generally described below in relation to a preferred embodiment thereof in the form of a negative capacitance topological quantum field effect transistor (NC-TQFET).
The inventors have found that the combined structure of ferroelectric (negative capacitance) and 2D TI (positive capacitance) amplifies the electric field in the 2D TI layer as illustrated in
The NC-TQFET described above is ambipolar, turned off by either Vb>0, Vt<0 or Vb<0, Vt>0. Ideally an FET device should operate with a single gate as a unipolar transistor. This situation is realized by grounding one gate and applying a gate voltage to the other. Furthermore, if the NC-TQFET channel is connected to semiconducting source/drain leads, unipolar conduction results.
To estimate the electric field amplification in the device illustrated in
where α1=αFE/αTI and α2=(4βFE/αTI3)tFE2 where tFE is the ferroelectric total thickness (twice the thickness of top and bottom layer). The maximum electric field amplification is when αFE/αTI=−1 or tFE=(2|αFE|CTI)−1. Then Vg=((2βFECTI2)/(|αFE))*ψs3=((CTI2)/(Pr2))*ψs3 where Pr=sqrt(−α/(2β)) is the remanent polarization.
Modelling was conducted considering bilayer graphene (BLG) as the channel material since this BLG has an experimentally characterized electric-field-dependent bandgap. However, the skilled person will appreciate that the results of this modelling are applicable to a range of topological insulator materials. For the ferroelectric negative capacitance material, La-doped HfO2 was selected for which an assumed value of Pr=27.5 μC/cm2 was used. As above, the skilled addressee will appreciate that a range of other ferroelectric materials could be used, and particularly those based on HfO2/ZrO2.
For a material with negligible spin-orbit coupling such as bilayer graphene, S*=1. The electric field is reduced by dielectric screening in the BLG layer by a dielectric constant K. Furthermore, the separation of the atoms in the sublattice tv is smaller than the van der Waals thickness of the layer tTI, which further reduces the sublattice potential difference by an amount tv/tTI, such that λv=(tv/tTIκ)ψs, and dEg/dψs. For BLG, tv/tTI=0.5, κ=3.6, S*=1 predicts dEg/dψs=0.139 which is very close to experimentally measured values from optical spectroscopy and electronic transport. The BLG capacitance Cs=0.048 F/m2 (assuming κ=3.6, tTI=6.68 A) allows Eg(Vg) to be calculated for the ferroelectric/BLG/ferroelectric structure (see the solid lower curve in
Certain materials, such as honeycomb Xene lattices of heavy atoms, experience a strong Rashba spin-orbit interaction due to the gate electric field. As a result, S* can be less than 1. The inventors have found S*<0.75 in existing materials and estimate S* as low as 0.57 in functionalized Bi (see Table 1 below).
Modelling results for an NC-TQFET which is a strongly spin-orbit coupled version of BLG with similar screening properties but S*=0.57, equivalent to the spin-orbit parameters for bismuthene, yield an Eg(Vg) given by the solid upper curve in
For the purpose of the modelling, the inventors have further assumed that the NC-TQFET has a width F and gate length F=15 nm. The on-state occurs at zero bandgap, where the BLG is a massive Dirac semimetal with a conductivity approximately 4 e2/h and conductance 155 μS. Drain voltage Vd=Vg=0.030 V gives Ion=4.6 μA, similar to CMOS LV. The gate charge Q is 6.0×10−17 C=374 e, where e is the elemental charge, and the intrinsic switching energy Eint=(¼)QVg=0.45 aJ. The channel resistance R=6.45 kOhms, and gate capacitance C=Q/Vg=2000 aF, giving the switching time τ=(RC)=13 ps. The intrinsic switching energy of 0.45 aJ is almost an order of magnitude lower than CMOS LV.
As shown in
The NC-TQFET points to a general strategy to realize a new type of low-voltage transistor. The operating parameters of such a transistor are set by the materials parameters of the 2D TI and ferroelectric layers, and there appears to be no fundamental lower bound to the subthreshold swing for such a device.
It will be understood that the invention disclosed and defined in this specification extends to all alternative combinations of two or more of the individual features mentioned or evident from the text or drawings. All of these different combinations constitute various alternative aspects of the invention.
Number | Date | Country | Kind |
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2021903614 | Nov 2021 | AU | national |
Filing Document | Filing Date | Country | Kind |
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PCT/AU2022/051338 | 11/10/2022 | WO |