This application claims priority from Korean Patent Application No. 10-2017-0015129, filed on Feb. 2, 2017, in the Korean Intellectual Property Office, the disclosure of which is incorporated herein in its entirety by reference.
1. Field
One or more exemplary embodiments relate to an optical device, and more particularly, to an optical filter and an optical spectrometer including the same.
2. Description of the Related Art
An optical spectrometer is an important device in sensors applied to various areas such as non-invasive medical sensing and internet of things (IoT) networks. There is an increasing demand for miniaturization of optical spectrometers for various applications of the optical spectrometers.
A filter configuration of a prism or a grating structure is generally used to provide an optical spectrometer. Various studies have been conducted to overcome limitations of optical angle-sensitivity and optical sensibility in order to realize the miniaturization of the optical spectrometer. Recently, a filter-type optical spectrometer using quantum dots has been studied. A method using quantum dots is to realize spectroscopy by changing the optical sensitivity per wavelength of light to quantum dots of various sizes.
One or more exemplary embodiments provide an absorption filter including a filter layer formed of perovskite material.
One or more exemplary embodiments provide a miniaturized optical spectrometer including an optical filter including filter layers having different composition ratios of a perovskite material from each other.
Additional aspects will be set forth in part in the description which follows and, in part, will be apparent from the description, or may be learned by practice of the exemplary embodiments.
According to an aspect of an exemplary embodiment, an optical filter may include: a base substrate including a transparent material; and a filter layer on the base substrate, wherein the filter layer includes a perovskite material.
The filter layer may include a plurality of filter layers and at least two filter layers formed of perovskite materials having different composition ratios from each other.
The at least two filter layers may have different optical absorption rates or different optical transmittances from each other.
The at least two filter layers may have band-gap characteristics in different optical wavelength ranges from each other in an optical absorption spectrum or an optical transmission spectrum.
The perovskite material may be represented as a chemical formula of ABX3, wherein A denotes ammonium salt or cesium (Cs), B denotes tin (Sn) or lead (Pb), and X denotes a halogen element. The halogen element may be chloride (Cl), bromide (Br), or indium (I).
The perovskite material may be CsPbBr3-xClx (0≤x≤3) or CsPbBr3-xIx (0≤x≤3), and the at least two filter layers may include the perovskite materials having different values of x from each other.
Widths of the at least two filter layers may be in a range of about 1 μm to several millimeters.
According to an aspect of another exemplary embodiment, an optical spectrometer may include: a light source; an optical filter on which a first optical signal irradiated from the light source is incident, directly or via an object; and a photodetector on which a second optical signal passing through the optical filter is incident, wherein the optical filter includes a filter layer and the filter layer includes a perovskite material.
The optical filter may include a transparent base substrate; and a filter layer on the base substrate, and the base substrate may be on the photodetector to form the optical filter and the photodetector in an integrated body.
According to an aspect of another exemplary embodiment, an optical spectrometer may include a light source; and an integrated body of an optical filter and a photodetector on which a first optical signal irradiated from the light source is incident, either directly or via an object, wherein the integrated body of the optical filter and the photodetector includes a p-n junction structure including an n-type layer formed on a bottom structure and a p-type layer formed on the n-type layer.
The p-type layer may include a perovskite material and the n-type layer may include metal oxides having the n-type characteristics such as zinc (Zn) oxides or titanium (Ti) oxides.
The above and/or other aspects will become apparent and more readily appreciated from the following description of exemplary embodiments, taken in conjunction with the accompanying drawings in which:
Reference will now be made in detail to exemplary embodiments, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to like elements throughout. In this regard, the exemplary embodiments may have different forms and should not be construed as being limited to the descriptions set forth herein. Accordingly, the exemplary embodiments are merely described below, by referring to the figures, to explain various aspects. Expressions such as “at least one of,” when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.
A detailed description is provided below with reference to the appended drawings showing a radiation detector and a radiographic apparatus including the same. Like reference numerals refer to like elements throughout the drawings. Sizes of elements in the drawings may be exaggerated for clarity and convenience of explanation.
In the case where a position relationship between two items is described with the terms “on ˜” or “on the top of ˜”, one item may be not only directly on the other item while being in contact with the other item but may also be on the other item without being in contact with the other item.
An expression used in the singular encompasses the expression of the plural, unless it has a clearly different meaning in the context. When a portion includes a composing element, the case may denote further including other composing elements without excluding other composing elements unless otherwise described.
Referring to
Referring to
The optical filter 20 may be a filter array formed by a plurality of filter elements in an array structure. The plurality of filter elements may be filter layers which are individually formed. The optical signal L12 incident on the optical filter 20 may be separated into second optical signals L2 with respect to the different wavelengths. When the second optical signals L2 which are different from each other with respect to the wavelengths are transferred to the photodetector (or optical detector) 30, original optical signals may be restored from the second optical signals L2. The second optical signals L2 incident on the photodetector 30 may be changed from optical signals to electrical signals and the electrical signals may be detected in the photodetector 30.
The detected electrical signals may be analyzed to obtain information about the object 12 via an arithmetic calculation in a signal processor 40. The information about the object 12 may include various information, and may include, for example but not limited to, information about an internal state, surface physical properties, a surface shape, the location, and a movement of the object 12. The information about the object 12 analyzed in the signal processor 40 may be transmitted to other devices or be visualized on display devices or be stored in separate information storage devices.
An optical accessory (not shown) which may change a path of the optical signal may be selectively arranged between the light source 10 and the object 12. In addition, an optical path changer (not shown) may be further arranged between the object 12 and the optical filter 20.
Referring to
According to an exemplary embodiment, the optical filter 20 may easily control a band-gap by using a perovskite material which is applied to an absorption filter of the optical spectrometer. At least two of the first and second filter layers 22a and 22b of the optical filter 20 may have different composition ratios from each other and optical absorbance thereof may be different from each other. Accordingly, light absorbance or light transmittance of the first and second filter layers 22a and 22b may be respectively different from each other, and light absorbance spectra or light transmittance spectra of the first and second filter layers 22a and 22b may be respectively different. In other words, the first and second filter layers 22a and 22b may include different composition ratios of the perovskite material, and may represent band-gap characteristics in different light wavelength ranges from each other in a light absorbance spectrum or light transmittance spectrum.
The number of respective first and second filter layers 22a and 22b on the optical filter 20 may not be limited, and may be variously determined depending on usage conditions. According to an exemplary embodiment, an incident direction of the first optical signal L1 incident on the optical filter 20 may not necessarily be perpendicular to the surface of the optical filter 20 and dependence on the light incident angle of the optical filter 20 may not be high.
Shapes of the first and second filter layers 22a and 22b of the optical filter 20 illustrated in
According to an exemplary embodiment, the first and second filter layers 22a and 22b of the optical filter 20 may include the perovskite material. The perovskite material may be formed in a colloid perovskite solution process. The colloid perovskite material formed in the colloid perovskite solution process may include a core and ligand selectively surrounding the core. Core material, that is, the perovskite material, may be represented as a chemical formula of ABX3, wherein A denotes ammonium salt or Cs, B denotes Sn or Pb, and X denotes a halogen element such as Cl, Br or I. The ligand selectively surrounding the core may include various chemical compounds having a hydrophobic alkyl group. The ligand may be a material such as carboxylic acid, phosphonic acid, and amine. In addition, the first and second filter layers 22a and 22b of the optical filter 20 may be selectively formed of the perovskite material obtained (or manufactured) via a bulk process, not the solution process.
The base substrate 21 of the optical filter 20 may formed of a material having a transparent property and may include glass, sapphire, quartz, transparent polymer, etc. However, the exemplary embodiment is not limited thereto.
According to an exemplary embodiment, the optical filter 20 may be formed independently of the photodetector 30 illustrated in
Referring to
For example, the first solution 41 may include CsPbBr3 and the second solution 42 may include CsPbI3. The third solution 43 may be provided by mixing the first and second solutions 41 and 42 with various composition ratios and may have a chemical formula as CsPbBr3-xIx. In this case, the value of x may have a range of equal to or greater than 0 to equal to or less than 3 (0≤x≤3), and various perovskite materials may be combined by varying the composition ratios. Organic enzymes such as chloroform and toluene may be used as enzymes in the first and second solutions 41 and 42.
When a material corresponding to “X” in the chemical formula ABX3 of the perovskite material includes at least two of Cl, Br, and I, filtering wavelength ranges of optical signals of the incident light may be changed by controlling respective composition ratios of at least two of Cl, Br, and I. For example, the perovskite material may be CsPbBr3-xClx (0≤x≤3) or CsPbBr3-xIx (0≤x≤3). As illustrated in
The solution process may be executed at a room temperature. As a result, the colloid perovskite material having various band-gaps may be formed by mixing the first and second solutions 41 and 42 at the room temperature in various combinations and undergoing an anion exchange.
The optical filter 20 may be formed by doping the third solution 43 formed as illustrated in
The first and second filter layers 22a and 22b may be formed of materials having different band-gaps from each other, and the plurality of filter layers formed on the base substrate 21 may be formed of the perovskite materials having different band-gaps from each other. The plurality of the first and second filter layers 22a and 22b of the optical filter 20 may be formed of the perovskite materials having completely different band-gaps from each other. In this manner, the perovskite materials having various band-gaps may be obtained from a small number of samples and thus, the optical filter 20 and a small optical spectrometer may be easily provided according to an exemplary embodiment.
In
Referring to
Referring to
Referring to
The p-type layer 24 may include the perovskite material and the perovskite material may be represented as a chemical formula of ABX3, wherein A represents the ammonium salt, or Cs, etc., B represents Sn, or Pb, etc., and X represents the halogen material such as Cl, Br, and I.
When the optical filter and the photodetector are integrally formed in this manner, the optical signal L12 incident on the p-type layer 24 may be filtered by the p-type layer 24, and the p-type layer 24 and the n-type layer 26 may be respectively connected to the signal processor 40 in
According to exemplary embodiments, an optical filter including a perovskite material layer and an optical spectrometer including the optical filter are provided. The perovskite material layer used for the optical filter may be formed in a simple method via a combination of several materials. Optical filters having low dependence on an optical incident angle and small-sized optical spectrometers including the optical filters may be provided by the optical filter including the perovskite material layer.
It should be understood that the exemplary embodiments described herein should be considered in a descriptive sense only and not for purposes of limitation. Descriptions of features or aspects within each embodiment should typically be considered as available for other similar features or aspects in other exemplary embodiments.
While one or more exemplary embodiments have been described with reference to the figures, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope as defined by the following claims.
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