The present disclosure relates to an electroplating method that leads to more uniform main pole layers in magnetic recording heads by selectively depositing thicker films on regions of a wafer that are susceptible to a higher chemical mechanical polish (CMP) thinning rate during a subsequent process step.
Electroplating methods are commonly used in numerous applications such as depositing metal films including copper interconnects in semiconductor devices and forming magnetic layers in magnetic recording devices. Although magnetic layers in read and write heads may be deposited by a sputtering method, an electroplating process is usually preferred because the sputtering process produces a magnetic layer with large magnetocrystalline anisotropy and higher internal stress. Electroplating is capable of generating a magnetic layer with a smaller crystal grain size and a smoother surface that leads to a high magnetic flux density (BS) value and low coercive force (HC).
In an electroplating process, an electric current is passed through an electroplating cell comprised of a working electrode (cathode), counter electrode (anode), and an aqueous electrolyte solution of positive ions of the metals to be plated on a substrate in physical contact with the cathode. By applying a potential to the electrodes, an electrochemical process is initiated wherein cations migrate to the cathode and anions migrate to the anode. Metallic ions such as Fe+2, Co+2, and Ni+2 deposit on a substrate (cathode) to form an alloy that may be NiFe, CoFe, or CoNiFe, for example. The substrate typically has an uppermost seed layer on which a photoresist layer is patterned to provide openings over the seed layer that define the shape of the metal layer to be plated. Once the metal layer is deposited, the photoresist layer is removed. The magnetic layers which become a bottom pole layer and top pole layer in a write head can be formed in this manner.
During the manufacture of magnetic recording heads, the devices are typically built on an AlTiC wafer with a flat or notch along an edge of the wafer. The flat or notch may be used for orientation identification (in a plane with x-axis and y-axis dimensions) and is sometimes required for equipment such as exposure tools to process wafers. Unfortunately, the presence of a flat or notch can adversely produce poor within-wafer uniformity because of its asymmetric nature.
Referring to
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Another approach to overcome the low K-block thickness issue is to plate a thicker main pole layer in the k-block in order to compensate for a greater thinning rate in that region during the CMP step. However, it is very difficult to produce the desired plating thickness profile by using a conventional thief current adjustment method that involves a thief plate ring (auxiliary cathode) around the wafer during the plating process. Any localized thief current adjustment to the block of interest will also affect plating thickness in the remaining blocks. Thus, there is no available means to selectively plate a higher main pole layer thickness in certain regions of a wafer without affecting thickness in other regions. An improved electroplating method is desired that enables a thicker main pole layer to be formed in selected regions of a wafer while maintaining other magnetic properties in the electroplated layer.
One objective of the present disclosure is to provide an electroplating method that deposits thicker magnetic films in selected regions of a wafer that have a higher thinning rate during a subsequent chemical mechanical polish (CMP) process such that within wafer uniformity is significantly improved after the CMP process.
A further objective of the present disclosure is to provide an electroplating method according to the first objective that provides a consistent main pole layer composition across the wafer, and that maintains within wafer electroplating thickness uniformity in the non-selected regions.
According to one embodiment of the present disclosure, an electroplating apparatus is employed that includes a tank filled with an electroplating solution, a wafer (work piece) attached to a cathode plate and surrounded by a thief plate at the bottom of the tank, an anode that is positioned in an upper portion of the plating solution, and a paddle having a notch formed therein that is attached to guide rails and moves back and forth over the wafer in a direction parallel to the wafer plane and at a fixed distance above the wafer surface. In one design scheme, the paddle has three rectangular surfaces of essentially equal shape that are joined at their lengthwise edges to form a triangular shape from an end view. Thus, the paddle has three rectangular sides in a middle section that connects two ends having a triangular shape. Optionally, the middle section may be round, square, or rectangular. The lengthwise dimension (length) of each of the three sides is along a first axis direction. One of the three sides is a bottom side that is aligned parallel to the wafer surface and faces the bottom of the tank. The bottom side has a width along a second axis direction wherein the second axis is perpendicular to the first axis. The remaining two sides extend from the bottom side and join at a top edge that is a first height distance along a third axis from the bottom side. The third axis is perpendicular to both of the first and second axes. Preferably, the length of each paddle side is greater than the diameter of the wafer and the thief plate.
As the paddle moves across the tank in a direction that is perpendicular to the first axis and parallel to the wafer flat, the bottom side remains a fixed distance from the wafer surface. When a current is applied to the electroplating solution, the paddle is moved to effectively mix the solution so that the electrolytes are kept in a uniform distribution within the tank. Once the paddle moves from a starting position along one side of the tank to an opposite side of the tank, the movement is reversed to return to the starting position and complete one cycle. Multiple cycles of paddle movement may be employed during an electroplating process and the rate of movement may be adjusted to optimize the rate of magnetic layer deposition.
A key feature according to one embodiment of the present disclosure is that a notch is formed in the paddle with an opening in the bottom side that corresponds to the width of K-block such that when the paddle passes over the wafer, one side of the notch is aligned above the side of K-block that is closest to the wafer flat and a second side of the notch is aligned above a K-block side opposite to that of the aforementioned K-block side. Thus, the notch is formed proximate to a first end of the paddle that passes over the wafer flat, and has a lengthwise dimension in a first axis direction and a width equivalent to the width of a paddle end along the second axis direction. In this case, the width of K-block is a dimension along a first axis direction that is perpendicular to the wafer flat and is typically smaller than the length of K-block which is along a second axis direction that is parallel to the wafer flat. From a cross-sectional view along a plane that bisects the paddle in a lengthwise dimension, the notch appears with a rectangular shape such that two sides formed perpendicular to the bottom side are of equal height and are connected by a top section that is parallel to the bottom side. Thus, the length of the top section of the notch is the distance between the two notch sides along the first axis direction and is essentially equal to the width of K-block. Moreover, the notch passes directly over K-block twice during each cycle of paddle movement. As the height of the notch along the third axis direction is increased up to about 50% of the entire height of the paddle, there is an increasingly greater thickness difference between magnetic layers electroplated in K-block compared with those deposited in other regions of the wafer.
According to a second embodiment, the notch formed in the paddle is modified such that the two sides are not of equal height from a cross-sectional view. In particular, the height of a first side of the notch that is nearer the first end of the paddle is greater than the height of the second side of the notch that is closer to a midpoint of the paddle. In one aspect, the second side may have a zero height which means the top section is tapered with respect to the bottom side and connects the first side with the bottom side. In other words, the height of the notch becomes smaller with increasing distance from the first end of the paddle that passes over the wafer flat. The advantage of the tapered notch is that the thickness within K-block may be controlled so that there is a steeper thickness gradient from a K-block side which is closer to the wafer flat to an opposite side adjacent to other blocks compared with the rectangular notch design.
There is a third embodiment wherein the first or second embodiment is modified to include a second notch proximate to the other (second) end of the paddle. The second notch may have two sides of equal height connected by a top section as previously described with respect to the first embodiment, or may have a tapered shape as in the second embodiment wherein a first side near the second end of the paddle is connected by a sloped section to the bottom side of the paddle. Preferably, the second notch passes directly over J-block during an electroplating process and in one aspect has a lengthwise dimension along a top section that is essentially equivalent to the width of J-block. Here width is defined as the distance between two long sides of J-block and is along an axis that is perpendicular to the wafer flat. The height of the second notch is typically less than the height of the first notch that passes over K-block since the CMP thinning rate of the electroplated layer in J-block is generally less than in K-block. As a result, the smaller height of the second notch causes a lesser thickness of magnetic layer to be formed in J-block compared with K-block, but still a greater magnetic layer thickness than in other blocks on the wafer.
According to a fourth embodiment, two paddles may be employed during an electroplating process and are maintained at a constant distance from each other during a paddle movement cycle. Preferably, a first paddle moves from a starting position along one side of the tank to a second position that is about halfway across the tank and stops with its lengthwise direction along an axis that is perpendicular to the wafer flat. Meanwhile, a second paddle has a starting position near the second position of the first paddle and moves to a side of the tank opposite the first side of the tank as the first paddle moves to its second position. The two paddles move back and forth across the bottom of the tank and above the wafer in concert (same direction) with the same rate of cycle movement. Preferably, the two paddles have an equivalent single or double notch design but the present disclosure also anticipates that one paddle may have a different notch design than the other paddle.
Conventional electroplating conditions may be used with the paddle designs of the present disclosure. For example, a substrate (wafer) is provided upon which a seed layer has been formed. Above the seed layer is a patterned photoresist layer with openings that correspond to the shape of the desired magnetic layer to be deposited in a subsequent step. A layer made of CoFe, NiFe, CoFe alloy such as CoFeNi, or a NiFe alloy is then electroplated on the substrate in an electroplating cell comprised of an anode and a cathode (working electrode) which are immersed in an electrolyte solution. A reference electrode with a stable, fixed voltage may be employed. Furthermore, there is a power source (potentiostat) with leads affixed thereto wherein one lead connects to the anode and supplies a positive voltage and a second lead connects to the cathode to provide a negative voltage when the cell is operating. A third lead connects to the reference electrode. Additives such as a stress reducer, surfactant, and leveling agent may be used to modify certain properties in the plated layer.
a and 4b are an oblique view and cross-sectional view, respectively, of a conventional paddle design with three rectangular surfaces joined to form a triangular end shape in
a is a thickness contour plot across a wafer following electroplating with the conventional paddle in
a and 6c are an oblique view and cross-sectional view, respectively, of a notched paddle design according to a first embodiment of the present disclosure.
a is a thickness contour plot across a wafer following electroplating with the paddle design in
a and 9b are an oblique view and cross-sectional view, respectively, of a tapered notch paddle according to a second embodiment of the present disclosure.
The present disclosure is a method of selectively electrodepositing a thicker metal or alloy layer on portions of a wafer that experience a higher thinning rate during a subsequent CMP process. Metal or alloy layer deposition is controlled by one or more notches in a paddle where a notch is positioned to pass directly over a region (block) on a wafer where a higher plating thickness is desired than in other regions of the wafer. The terms electroplating, plating, and electrodeposition may be used interchangeably. Although the exemplary embodiments relate to main pole layer deposition during the fabrication of magnetic recording heads, one skilled in the art will appreciate that the method disclosed herein may also be used to electroplate other materials such as permalloy, copper, gold, and the like in microelectronic devices or other applications.
Referring to
It should be understood that a metal or alloy layer deposited according to the present disclosure is preferably formed on a seed layer (not shown) disposed on wafer 40. The wafer is generally comprised of a substrate that may be a write gap layer in a partially formed write head, for example. Furthermore, the partially completed write head may be formed on a read head structure in a combined read/write head configuration. The seed layer may be deposited by a sputtering process and preferably has the same composition as intended for the subsequently deposited metal or alloy layer. Typically, the fabrication process involves forming an insulation layer on a substrate. A photoresist layer is formed on the insulation layer and is patterned to define openings having the desired shape from a top view of the metal or alloy layer to be deposited in a subsequent step. A thin seed layer is deposited within the openings to promote the deposition of the magnetic layer during the electroplating process. Once the magnetic layer is electroplated to fill the openings, the photoresist layer is removed by a conventional process such as a chemical mechanical polish (CMP) process that also planarizes the metal or alloy layer across the entire wafer.
In one aspect, the electroplated metal or alloy layer is comprised of a soft magnetic material having a certain thickness and is made of CoFe or an alloy thereof such as CoFeNi, or is NiFe or a NiFe alloy. When the soft magnetic layer is a main pole layer in a write head, the deposited thickness is about 2 to 3 microns. However, the thickness of an electroplated magnetic layer according to the present disclosure may be less than 2 microns as appreciated by those skilled in the art.
In the exemplary embodiment, the plating solution 17 is aqueous based and is comprised of Fe+2 and Co+2 salts and optionally contains one or more other metal cations such as Ni+2 that are added as chloride and/or sulfate salts. Boric acid (H3BO3) is preferably added to buffer the plating solution 17 and thereby maintains a pH in the range of 2.0 to 3.0. The plating solution also contains one or more aryl sulfinate salts such as sodium benzenesulfinate to reduce the amount of brighteners and leveling agents necessary for optimum properties in the electroplated magnetic layer and also to improve magnetic softness in the electroplated film. Other additives may be employed to optimize the performance of the plating solution. For example, saccharin may be used as a stress reducing agent and sodium lauryl sulfate may serve as a surfactant. In one embodiment, the plating solution 17 is maintained at a temperature between 10° C. and 25° C. Furthermore, either a direct current (DC) or pulsed DC mode may be used with a duty ratio of about 15% to 40% and a cycle time of about 30 to 1000 ms to supply a peak current density of 30 to 60 mA/cm2 that powers the electroplating process. The duty ratio during each cycle may vary and is based on an “ON” time of 10 to 50 ms and an “OFF” time of 20 to 200 ms. Using these conditions, a magnetic layer comprised of CoFe, CoNiFe, or the like is deposited at the rate of about 500 to 1700 Angstroms per minute. Typically, the electroplating process is terminated after a predetermined length of time that corresponds to a desired thickness.
When a magnetic layer made of CoFe, CoFeNi, or the like is electroplated, the anode 16 is preferably Co (or Ni for a Ni alloy). A positive potential is applied to the anode and a negative potential is applied to the cathode comprised of thief plate 11 and wafer 40 by electrical leads (not shown) from the power source (not shown). As a result, an electroplating potential is established between the anode 16 and cathode such that an electric current flows from the anode to the cathode to drive the electroplating process. The wafer 40 is preferably affixed to a base plate by a clamp or other conventional means.
Referring to
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A key feature of the present disclosure is the paddle design that leads to a higher plating thickness in selected regions of the wafer such as K-block where thinning is greater during a subsequent CMP process. As a result, the higher plating thickness in K-block offsets a higher thinning rate in that region during the CMP step to yield a more uniform main pole thickness across the wafer at the completion of the main pole fabrication sequence. According to one embodiment shown in
According to one embodiment wherein the wafer diameter is 6 inches and the thief plate is a one inch wide ring around the entire edge of the wafer, there is a total distance of 8 inches across the wafer diameter and adjoining sections of thief plate ring on opposite sides thereof. In this example, the paddle length m is preferably about 9 inches such that a half inch section of paddle extends beyond the thief plate ring on opposite sides of the wafer when the paddle is aligned over a center of the wafer. When a larger size wafer with an 8 inch diameter, for example, is employed for the electroplating process, and the thief plate ring has a one inch width, then the paddle length m is increased accordingly to around 11 inches.
Referring to
The width of K-block may vary depending on wafer diameter and layout of the device pattern. In an example where a six inch diameter wafer is used with a ten block design shown in
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In
In an alternative embodiment (not shown), the paddle 21 may have a circular shape, or a non-triangular shape such as a square or rectangle from an end view. An important feature is that a notch is formed in a paddle side that faces a wafer surface during an electroplating process. Preferably, the notch has a dimension along the lengthwise direction of the paddle that is essentially the same magnitude as the width of a region where a greater thickness of the electroplated layer is desired. In this case, the width of the region is between two parallel sides thereof and is measured in a direction that is perpendicular to the wafer flat. Furthermore, one side of the notch that is formed parallel to an end of the paddle is aligned above a first parallel side of the wafer region and an opposite side of the notch is aligned above a second parallel side of the wafer region during a paddle movement cycle. The ends of the paddle extend beyond the edge of the wafer and do not pass over the wafer during a paddle movement cycle.
Referring to
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Although a rectangular shape is depicted for the second notch 25 in the exemplary embodiment, the second notch may have a tapered design as described in the second embodiment when the first notch 20 has a rectangular shape. In yet another embodiment, the first notch may be tapered as in the second embodiment and the second notch may have a rectangular shape as previously described. Moreover, one or both of the first and second notches may have two sides and a tapered top section as described with respect to the third embodiment.
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In
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According to one embodiment of the present disclosure, a magnetic field is applied along the x-axis, for example, during the deposition of the main pole layer on wafer 40. However, a magnetic field may not be applied during the electroplating. Moreover, there may be an anneal process involving the application of a magnetic field parallel to the film plane following the electroplating process that further improves softness in the main pole layer. The annealing process is preferably carried out in an oven after the electroplated substrate is removed from the electroplating bath. Magnetic annealing is one of the most common methods used with magnetic layers in write heads in order to improve writer performance. Generally, only a hard-axis anneal or an easy-axis anneal is employed during writer fabrication. However, the present disclosure also anticipates a two step anneal process wherein the electroplated layer is subjected to a hard axis anneal and then to an easy axis anneal. The anneal steps are preferably performed at a temperature between 180° C. and 250° C. so that a read head adjacent to the write head in a combined read/write head structure is not damaged. In addition, the applied magnetic field during the anneal steps is kept at 300 Oe or less to prevent altering the preferred direction of magnetic moment in the pinned layer within the read head.
Following the anneal step, a conventional CMP process is preferably performed to planarize the electroplated layer. As mentioned previously with respect to the preferred embodiments, a single notch or double notch paddle design is advantageously employed during the electroplating process to selectively deposit a greater main pole thickness in one or more regions of a wafer to offset a higher thinning rate in those same regions during the CMP process. Furthermore, the tapered notch design enables additional flexibility in that the thickness gradient within certain regions such as K-block and J-block may be controlled to form a higher magnetic layer thickness along a side of the block that is closer to the wafer edge and a lower thickness along an opposite side of the block. The height of the notch may be increased to increase the thickness differential between the magnetic layer thickness in K-block, for example, and other blocks on the wafer. It should be understood that the electroplated layer need not be magnetic since a Cu layer or other metal or alloy layers may be electroplated for other applications according to the method described herein and still benefit from improved thickness uniformity across the wafer following a subsequent CMP process. The single or dual notch design having a rectangular or tapered notch may be formed in a non-triangular paddle with a circular, rectangular, or square shape, for example, from an end view.
While this disclosure has been particularly shown and described with reference to, the preferred embodiment thereof, it will be understood by those skilled in the art that various changes in form and details may be made without departing from the spirit and scope of this disclosure.
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