Platinum-ruthenium containing catalyst formulations for hydrogen generation

BACKGROUND OF THE INVENTION

[0002] 1. Field of the Invention

[0003] This invention relates to methods and catalysts to generate a hydrogen-rich gas from gas mixtures containing carbon monoxide and water, such as water-containing syngas mixtures. More particularly, the invention includes methods using both precious metal- and non-precious metal-containing catalysts. The catalysts may be supported on a variety of catalyst support materials. Catalysts of the invention exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation.

[0004] 2. Discussion of the Related Art

[0005] Numerous chemical and energy-producing processes require a hydrogen-rich composition (e.g. feed stream.) A hydrogen-rich feed stream is typically combined with other reactants to carry out various processes. Nitrogen fixation processes, for example, produce ammonia by reacting feed streams containing hydrogen and nitrogen under high pressures and temperatures in the presence of a catalyst. In other processes, the hydrogen-rich feed stream should not contain components detrimental to the process. Fuel cells such as polymer electrode membrane (PEM) fuel cells, produce energy from a hydrogen-rich feed stream. PEM fuel cells typically operate with a feed stream gas inlet temperature of less than 450° C. Carbon monoxide is excluded from the feed stream to the extent possible to prevent poisoning of the electrode catalyst, which is typically a platinum-containing catalyst. See U.S. Pat. No. 6,299,995.

[0006] One route for producing a hydrogen-rich gas is hydrocarbon steam reforming. In a hydrocarbon steam reforming process steam is reacted with a hydrocarbon fuel, such as methane, iso-octane, toluene, etc., to produce hydrogen gas and carbon dioxide. The reaction, shown below with methane (CH4), is strongly endothermic; it requires a significant amount of heat.

CH4+2H2O→4H2+CO2

[0007] In the petrochemical industry, hydrocarbon steam reforming of natural gas is typically performed at temperatures in excess of 900° C. Even for catalyst assisted hydrocarbon steam reforming the temperature requirement is often still above 700° C. See, for example, U.S. Pat. No. 6,303,098. Steam reforming of hydrocarbons, such as methane, using nickel- and gold-containing catalysts and temperatures greater than 450° C. is described in U.S. Pat. No. 5,997,835. The catalyzed process forms a hydrogen-rich gas, with depressed carbon formation.

[0008] One example of effective hydrocarbon steam reforming catalysts is the Sinfelt compositions which are composed of Pt, a Group 11 metal, and a Group 8-10 metal. Group 11 metals include Cu, Ag and Au while Group 8-10 metals include the other noble metals. These catalyst formulations are well known in the promotion of hydrogenation, hydrogenolysis, hydrocracking, dealkylation of aromatics, and naphtha reforming processes. See, for example, U.S. Pat. Nos. 3,567,625 and 3,953,368. The application of catalysts based on the Sinfelt model to water gas shift (“WGS”) reaction, in particular at conditions suitable for lower temperature WGS applications such as PEM fuel cells, has not been previously reported.

[0009] Purified hydrogen-containing feed streams have also been produced by filtering the gas mixture produced by hydrocarbon steam reformation through hydrogen-permeable and hydrogen-selective membranes. See, for example, U.S. Pat. No. 6,221,117. Such approaches suffer from drawbacks due to the complexity of the system and slow flow rates through the membranes.

[0010] Another method of producing a hydrogen-rich gas such as a feed stream starts with a gas mixture containing hydrogen and carbon monoxide with the absence of any substantial amount of water. For instance, this may be the product of reforming of a hydrocarbon or an alcohol, and selectively removes the carbon monoxide from that gas mixture. The carbon monoxide can be removed by absorption of the carbon monoxide and/or by its oxidation to carbon dioxide. Such a process utilizing a ruthenium based catalyst to remove and oxidize the carbon monoxide is disclosed in U.S. Pat. No. 6,190,430.

[0011] The water gas shift reaction is another mechanism for producing a hydrogen-rich gas but from water (steam) and carbon monoxide. An equilibrium process, the water gas shift reaction, shown below, converts water and carbon monoxide to hydrogen and carbon dioxide, and vice versa.

[0012] Various catalysts have been developed to catalyze the WGS reaction. These catalysts are typically intended for use at temperatures greater than 450° C. and/or pressures above 1 bar. For instance, U.S. Pat. No. 5,030,440 relates to a palladium and platinum-containing catalyst formulation for catalyzing the shift reaction at 550-650° C. See also U.S. Pat. No. 5,830,425 for an iron/copper based catalyst formulation.

[0013] Catalytic conversion of water and carbon monoxide under water gas shift reaction conditions has been used to produce hydrogen-rich and carbon monoxide-poor gas mixtures. Existing WGS catalysts, however, do not exhibit sufficient activity at a given temperature to reach thermodynamic equilibrium concentrations of hydrogen and carbon monoxide such that the product gas may subsequently be used as a hydrogen feed stream. Specifically, existing catalyst formulations are not sufficiently active at low temperatures, that is, below about 450° C. See U.S. Pat. No. 5,030,440.

[0014] Platinum (Pt) is a well-known catalyst for both hydrocarbon steam reforming and water gas shift reactions. Under typical hydrocarbon steam reforming conditions, high temperature (above 850° C.) and high pressure (greater than 10 bar), the WGS reaction may occur post-reforming over the hydrocarbon steam reforming catalyst due to the high temperature and generally unselective catalyst compositions. See, for instance, U.S. Pat. Nos. 6,254,807, 5,368,835, 5,134,109, and 5,030,440 for a variety of catalyst compositions and reaction conditions under which the water gas shift reaction may occur post-reforming.

[0015] Metals such as cobalt (Co), ruthenium (Ru), palladium (Pd), rhodium (Rh) and nickel (Ni) have also been used as WGS catalysts but are normally too active for the selective WGS reaction and cause methanation of CO to CH4 under typical reaction conditions. In other words, the hydrogen produced by the water gas shift reaction is consumed as it reacts with the CO present in the presence of such catalysts to yield methane. This methanation reaction activity has limited the utility of metals such as Co, Ru, Pd, Rh and Ni as water gas shift catalysts.

[0016] A need exists, therefore, for a method to produce a hydrogen-rich gas, such as a hydrogen-rich syngas, and catalysts which are highly active and highly selective for both hydrogen generation and carbon monoxide oxidation at moderate temperatures (e.g. below about 450° C.) to provide a hydrogen-rich syngas from a gas mixture containing hydrogen and carbon monoxide.

SUMMARY OF THE INVENTION

[0017] The invention meets the need for highly active and selective catalysts for the generation of hydrogen and the oxidation of carbon monoxide and to thereby provide a hydrogen-rich gas, such as a hydrogen-rich syngas, from a gas mixture of at least carbon monoxide and water. Accordingly, the invention provides methods and catalysts for producing a hydrogen-rich gas.

[0018] The invention is, in a first general embodiment, a method for producing a hydrogen-rich gas (e.g., syngas) by contacting a CO-containing gas, such as a syngas mixture, with a water gas shift catalyst in the presence of water at a temperature of not more than 450° C. In the first general embodiment, the water gas shift catalyst comprises a) Pt, its oxides or mixtures thereof, b) Ru, its oxides or mixtures thereof, and c) at least one member selected from the group consisting of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof. In another method of the first general embodiment, the water gas shift catalyst comprises Pt, its oxides or mixtures thereof, Ru, its oxides or mixtures thereof, and at least one member selected from the group consisting of Sc, Y, Ti, V, Mo, Fe, Ir, La, and Ce, their oxides and mixtures thereof. The catalyst may be supported on a carrier, for example, at least one member selected from the group consisting of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide and mixtures thereof. The method of the invention may be conducted at a temperature ranging from about 150° C. to about 450° C.

[0019] In a second general embodiment, the invention relates to the water gas shift catalysts themselves—both supported and unsupported catalysts. The inventive water gas shift catalyst comprises, in a first, general embodiment, Pt, its oxides or mixtures thereof, Ru, its oxides or mixtures thereof, and at least one member selected from the group consisting of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof. In another catalyst of the first general embodiment, the water gas shift catalyst comprises Pt, its oxides or mixtures thereof, Ru, its oxides or mixtures thereof, and at least one member selected from the group consisting of Sc, Y, Ti, V, Mo, Fe, Ir, La, and Ce, their oxides and mixtures thereof. The catalyst may be supported on a carrier comprising at least one member selected from the group consisting of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide and mixtures thereof.

[0020] In a third general embodiment, the invention is directed to the aforementioned water gas shift catalysts of the second general embodiment in an apparatus for generating a hydrogen gas containing stream from a hydrocarbon or substituted hydrocarbon feed stream. The apparatus further comprises, in addition to the WGS catalyst, a fuel reformer, a water gas shift reactor, and a temperature controller. Such a specific WGS apparatus may be located within another larger apparatus, either stationary or otherwise, for generating energy, or a desired product or feed stream, either gaseous or liquid.

[0021] The following described preferred embodiments of the WGS catalyst can be used in each one of the first, second, and third general embodiments or in specific, related embodiments (e.g., fuel cell reactors, fuel processors, hydrocarbon steam reformers.)

[0022] In one preferred embodiment the water gas shift catalyst comprises Pt, its oxides or mixtures thereof, Ru, its oxides or mixtures thereof, and at least one member selected from the group consisting of Sc, Y, Ti, V, Mo, Fe, Ir, La, and Ce, their oxides and mixtures thereof.

[0023] In a second preferred embodiment the water gas shift catalyst may be formulated from Pt, its oxides or mixtures thereof, Ru, its oxides or mixtures thereof, Co, its oxides or mixtures thereof and at least one of K, Cs, V, Mo, Mn, Fe, La, and Ce, their oxides and mixtures thereof.

[0024] In third preferred embodiment the water gas shift catalyst comprises Pt, its oxides or mixtures thereof, Ru, its oxides or mixtures thereof, and at least one of Mo, Fe, and Ce, their oxides and mixtures thereof.

[0025] In yet another preferred embodiment the water gas shift catalyst comprises Pt, its oxides or mixtures thereof, Ru, its oxides or mixtures thereof, Fe, its oxides or mixtures thereof, and optionally Ce, its oxides or mixtures thereof

BRIEF DESCRIPTION OF THE DRAWINGS

[0026] The patent or application file contains at least one drawing executed in color. Copies of this patent or patent application publication with color drawing(s) will be provided by the Office upon request and payment of the necessary fee.

[0027] The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate preferred embodiments of the invention and together with the detailed description serve to explain the principles of the invention. In the drawings:

[0028]
FIGS. 1A through 1F illustrate the process of producing the library test wafer. The legend for FIG. 1A also applies to FIGS. 1B through 1F exclusively.

[0029]
FIGS. 2A through 2F illustrate the process of producing the library test wafer. The legend for FIG. 2A also applies to FIGS. 2B through 2F exclusively.

[0030]
FIGS. 3A through 3G illustrate the process of producing the library test wafer. The legend for FIG. 3A also applies to FIGS. 3B through 3G exclusively.

[0031]
FIGS. 4A through 4G illustrate the process of producing the library test wafer. The legend for FIG. 4A also applies to FIGS. 4B through 4G exclusively.

[0032]
FIGS. 5A through 5H illustrate the process of producing the library test wafer. The legend for FIG. 5A also applies to FIGS. 5B through 5H exclusively.

[0033]
FIGS. 6A through 6C illustrate the process of producing the library test wafer, and

[0034]

6
D through 6H illustrate SpotFire plots of the CO conversion versus CO2 production for the wafer under WGS conditions at various temperatures. The legend for FIG. 6A also applies to FIGS. 6B, and 6C exclusively.

[0035]
FIGS. 7A through 7F illustrate the process of producing a library test wafer, and

[0036]

7
G, 7H and 7I, illustrate SpotFire plots of the CO conversion versus CO2 production for the wafer under WGS conditions at various temperatures. The legend for FIG. 7A also applies to FIGS. 7B through 7F exclusively.

[0037]
FIGS. 8A through 8E illustrate the process of producing a library test wafer and 8F, illustrates SpotFire plots of the CO conversion versus CO2 production for the wafer under WGS conditions. The legend for FIG. 8E also applies to FIGS. 8A through 8D exclusively.

[0038]
FIGS. 9A through 9G illustrate the process of producing a library test wafer and

[0039]

9
H, illustrates SpotFire plots of the CO conversion versus CO2 production for the wafer under WGS conditions. The legend for FIG. 9A also applies to FIGS. 9B through 9G exclusively.

[0040]
FIGS. 10A through 101 illustrate the process of producing a library test wafer and

[0041]

10
J, 10K and 10L, illustrate SpotFire plots of the CO conversion versus CO2 production for the wafer under WGS conditions at various temperatures. The legend for FIG. 11A also applies to FIGS. 10B through 10I exclusively.

[0042]
FIGS. 11A through 11I illustrate the process of producing a library test wafer and

[0043]

11
J and 11K illustrate SpotFire plots of the CO conversion versus CO2 production for the wafer under WGS conditions. The legend for FIG. 11A also applies to FIGS. 11B through 11I exclusively.

[0044]
FIGS. 12A through 12C illustrate plots of the CO concentration versus temperature for scaled-up catalyst samples under WGS conditions at various space velocities. The legends for each of FIGS. 12A, 12B, and 12C apply to each figure exclusively.

[0045]
FIG. 13 illustrates plots of CO concentration versus temperature for scaled-up catalyst samples under WGS conditions.

[0046]
FIG. 14 illustrates plots of CO concentration versus temperature for scaled-up catalyst samples under WGS conditions.

[0047]
FIGS. 15A through 15F illustrate the compositional make-up of various exemplary library test wafers.

[0048]
FIG. 16A illustrates a representative plot of CO conversion versus CO2 production for a prototypical library test wafer at various temperature,

[0049]

16
B, illustrates the effect of catalyst selectivity and activity versus the WGS mass balance, and

[0050]

16
C, illustrates the effect of temperature on catalyst performance under WGS conditions.

[0051]
FIG. 17 illustrates plots of CO concentration versus temperature for scaled-up catalyst samples under WGS conditions.

DETAILED DESCRIPTION OF THE INVENTION

[0052] The invention relates to a method for producing a hydrogen-rich gas, such as a hydrogen-rich syngas. According to the method a CO-containing gas such as a syngas contacts a water gas shift catalyst, in the presence of water, preferably a stoichiometric excess of water, preferably at a reaction temperature of less than about 450° C. to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. The reaction pressure is preferably not more than about 10 bar. The invention also relates to a water gas shift catalyst itself and to apparatus such as water gas shift reactors and fuel processing apparatus comprising such WGS catalysts.

[0053] A water gas shift catalyst according to the invention comprises:

[0054] a) Pt, its oxides or mixtures thereof;

[0055] b) Ru, its oxides or mixtures thereof; and

[0056] c) at least one member selected from the group consisting of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide.

[0057] The WGS catalysts of the invention comprise combinations of at least three metals or metalloids, selected from at least three group indicated above, in each and every possible permutation and combination, except as specifically and expressly excluded. Although particular subgroupings of preferred combinations of metals or metalloids are also presented, the present invention is not limited to the particularly recited subgroupings.

[0058] Discussion regarding the particular function of various components of catalysts and catalyst systems is provided herewith solely to explain the advantage of the invention, and is not limiting as to the scope of the invention or the intended use, function, or mechanism of the various components and/or compositions disclosed and claimed. As such, any discussion of component and/or compositional function is made, without being bound by theory and by current understanding, unless and except such requirements are expressly recited in the claims. Generally, for example, and without being bound by theory, the metals, Pt, component a), and Ru, component b), both have activity as WGS catalysts. The metals or metalloids of component c) may themselves have activity as WGS catalysts, such as Co, but function in combination with either or both of Pt and Ru to impart beneficial properties to the catalyst of the invention.

[0059] Catalysts of the invention can catalyze the WGS reaction at varying temperatures, avoid or attenuate unwanted side reactions such as methanation reactions, as well as generate a hydrogen-rich gas, such as a hydrogen-rich syngas. The composition of the WGS catalysts of the invention and their use in WGS reactions are discussed below.

[0060] 1. Definitions

[0061] Water gas shift (“WGS”) reaction: Reaction which produces hydrogen and carbon dioxide from water and carbon monoxide, and vice versa:

[0062] Generally, and unless explicitly stated to the contrary, each of the WGS catalysts of the invention can be advantageously applied both in connection with the forward reaction as shown above (i.e. for the production of H2), or alternatively, in connection with the reverse reaction as shown above (i.e., for the production of CO). As such, the various catalysts disclosed herein can be used to specifically control the ratio of H2 to CO in a gas stream.

[0063] Methanation reaction: Reaction which produces methane and water from a carbon source, such as carbon monoxide or carbon dioxide, and hydrogen:

[0064] “Syngas” (also called synthesis gas): Gaseous mixture comprising hydrogen (H2) and carbon monoxide (CO) which may also contain other gas components such as carbon dioxide (CO2), water (H2O), methane (CH4) and nitrogen (N2).

[0065] LTS: Refers to “low temperature shift” reaction conditions where the reaction temperature is less than about 250° C., preferably ranging from about 150° C. to about 250° C.

[0066] MTS: Refers to “medium temperature shift” reaction conditions where the reaction temperature ranges from about 250° C. to about 350° C.

[0067] HTS: Refers to “high temperature shift” reaction conditions where the reaction temperature is more than about 350° C. and up to about 450° C.

[0068] Hydrocarbon: Compound containing hydrogen, carbon, and, optionally, oxygen.

[0069] The Periodic Table of the Elements is based on the present IUPAC convention, thus, for example, Group 9 comprises Co, Rh, and Ir. (See http://www.iupac.org dated May 30, 2002.)

[0070] As discussed herein, the catalyst composition nomenclature uses a dash (i.e., “-”) to separate catalyst component groups where a catalyst may contain one or more of the catalyst components listed for each component group, brackets (i.e., “{ }”) are used to enclose the members of a catalyst component group, “{two of . . . }” is used if two or more members of a catalyst component group are required to be present in a catalyst composition, “blank” is used within the “{ }” to indicate the possible choice that no additional element is added, and a slash (i.e., “/”) is used to separate supported catalyst components from their support material, if any. Additionally, the elements within a catalyst composition formulation include all possible oxidation states, including oxides, or salts, or mixtures thereof.

[0071] Using this shorthand nomenclature in this specification, for example, “Pt—{Rh, Ni}—{Na, K, Fe, Os}/ZrO2” would represent catalyst compositions containing Pt, one or more of Rh and Ni, and one or more of Na, K, Fe, and Os supported on ZrO2; all of the catalyst elements may be in any possible oxidation state, unless explicitly indicated otherwise. “Pt—Rh—Ni—{two of Na, K, Fe, Os}” would represent a supported or unsupported catalyst composition containing Pt, Rh, and Ni, and two or more of Na, K, Fe, and Os. “Rh—{Cu,Ag,Au}—{Na, K, blank}/TiO2” would represent catalyst compositions containing Rh, one or more of Cu, Ag and Au, and, optionally, and one of Na or K supported on TiO2.

[0072] 2. WGS Catalyst

[0073] A water gas shift catalyst of the invention comprises:

[0074] a) Pt, its oxides or mixtures thereof;

[0075] b) Ru, its oxides or mixtures thereof; and

[0076] c) at least one member selected from the group consisting of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide.

[0077] In one preferred general embodiment, the water gas shift catalyst comprises Pt, its oxides or mixtures thereof, Ru, its oxides or mixtures thereof, and at least one member selected from the group consisting of Sc, Y, Ti, V, Mo, Fe, Ir, La, and Ce, their oxides and mixtures thereof, and in another preferred general embodiment, the water gas shift catalyst comprises Pt, its oxides or mixtures thereof, Ru, its oxides or mixtures thereof, Co, its oxides or mixtures thereof, and at least one of K, Cs, V, Mo, Mn, Fe, La, and Ce, their oxides and mixtures thereof. Suitable carriers for supported catalysts are discussed below.

[0078] The catalyst components are typically present in a mixture of the reduced or oxide forms; typically one of the forms will predominate in the mixture. A WGS catalyst of the invention may be prepared by mixing the metals and/or metalloids in their elemental forms or as oxides or salts to form a catalyst precursor. This catalyst precursor mixture generally undergoes a calcination and/or reductive treatment, which may be in-situ (within the reactor), prior to use as a WGS catalyst. Without being bound by theory, the catalytically active species are generally understood to be species which are in the reduced elemental state or in other possible higher oxidation states. The catalyst precursor species are believed to be substantially completely converted to the catalytically active species by the pre-use treatment. Nonetheless, the catalyst component species present after calcination and/or reduction may be a mixture of catalytically active species such as the reduced metal or other possible higher oxidation states and uncalcined or unreduced species depending on the efficiency of the calcination and/or reduction conditions.

[0079] A. Catalyst Compositions

[0080] As discussed above, one embodiment of the invention is a catalyst for catalyzing the water gas shift reaction (or its reverse reaction). According to the invention, a WGS catalyst may have the following composition:

[0081] a) Pt, its oxides and mixtures thereof;

[0082] b) Ru, its oxides and mixtures thereof; and

[0083] c) at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof.

[0084] The amount of each component present in a given catalyst according to the present invention may vary depending on the reaction conditions under which the catalyst is intended to operate. Generally, a Group 8, 9 or 10 metal component, may be present in an amount ranging from about 0.01 wt. % to about 10 wt. %, preferably about 0.01 wt. % to about 2 wt. %, and more preferably about 0.05 wt. % to about 0.5 wt. %. The lanthanide elements may be present, typically, in amounts ranging from about 0.05 wt. % to about 20 wt. %, preferably about 0.1 wt. % to about 15 wt. %. The main group and metalloid elements may be present in amounts ranging, generally, from about 0.01 wt. % to about 15 wt. %, preferably about 0.02 wt. % to about 10 wt. %.

[0085] The above weight percentages are calculated on the total weight of the catalyst component in its final state in the catalyst composition after the final catalyst preparation step (i.e., the resulting oxidation state or states) with respect to the total weight of all catalyst components plus the support material, if any. The presence of a given catalyst component in the support material and the extent and type of its interaction with other catalyst components may effect the amount of a component needed to achieve the desired performance effect.

[0086] Other WGS catalysts which embody the invention are listed below. Utilizing the shorthand notation discussed above, where each metal may be present in its reduced form or in a higher oxidation state, the following compositions are examples of preferred catalyst compositions:

Pt—Ru—{Ti, Mo, Fe, Ce}.

Pt—Ru—{V, Mo, Ce}.

Pt—Ru—{V, Mo, Fe}.

Pt—Ru—{Fe, Co, Ir}.

Pt—Ru—{Sc, Y, La, Ce}.

Pt—Ru—Fe—Ce.

Pt—Ru—Ti—{Mo, Fe, Ce}.

[0087] One preferred quaternary catalyst is Pt, Ru, Co and one or more of K, Cs, V, Mo, Mn, Fe, La, and Ce. Another preferred ternary catalyst embodiment is Pt, Ru and one or more of Sc, Y, La, Ce.

[0088] The catalysts may be more advantageously applied in specific operating temperature ranges. For instance, Pt, Ru and one or more of La and Ce provides high activity in the LTS temperature range; while Pt, Ru, Fe and Ce, preferably on TiO2, is preferably utilized in the higher HTS temperature range. For the MTS temperature range, Pt, Ru, Ce and Ti on ZrO2 and Pt, Ru, Fe, Ce on ZrO2 are particularly preferred. Pt, Ru, Fe on ZrO2 may be utilized at both MTS and HTS temperature conditions and provides high selectivity. Titania supported formulations may be utilized advantageously at both LTS and MTS include Pt, Ru, and one or more of V, Mo and Ce, and at HTS, Pt, Ru, and one or more of V, Mo and Fe.

[0089] B. Catalyst Component a): Pt

[0090] A first component in a catalyst of the invention is Pt, component a). Pt, like all metal components, may be present in a combination of its reduced forms and its oxides. Catalysts of the invention may contain mixtures of these metal states.

[0091] Pt is recognized as a catalyst for the WGS reaction. Typically Pt alone is too active and unselective towards the formation of hydrogen under typical WGS conditions. However, as demonstrated here, properly modified Pt containing catalyst formulations may provide both increased selectivity to hydrogen generation at high activity levels under WGS reaction conditions.

[0092] C. Catalyst Component b): Ru

[0093] Ruthenium and other metals including, for instance, cobalt, palladium, rhodium, and nickel have been used as WGS catalysts but are normally too active for the selective WGS reaction and cause methanation of CO to CH4 under typical WGS reaction conditions. In other words, the hydrogen produced by the water gas shift reaction is consumed as it reacts with the CO present in the presence of such catalysts to yield methane. This methanation reaction activity has limited the utility of such metals as water gas shift catalysts.

[0094] Unmodified Ru has been shown to catalyze the methanation reaction under WGS conditions. However, according to the present invention, Ru may be converted to a highly active and selective WGS catalyst by adjusting the Ru loading and alloying with other catalyst components which may moderate the activity of Ru for the methanation reaction. In combinations of the invention, Pt was found to efficiently alter the selectivity of unmodified Ru. According to the present invention, various dopants may be added to the Pt and Ru containing catalyst formulations and some preferred catalysts include, for example, Pt—Ru—Co, Pt—Ru—Fe, Pt—Ru—Ti, Pt—Ru—Co—Fe and Pt—Ru—Ti—V. The resulting catalyst compositions are highly active and selective WGS catalysts, and exhibit increased selectivity for the WGS reaction over the competing methanation reaction.

[0095] Pt—Ru compositions can also be gradually moderated, while enhancing WGS selectivity at the expense of activity, by adding additional catalyst components such as, for instance, alkali metals, rare earth metals and lanthanides.

[0096] D. Catalyst Component c): “Functional” Metals or Metalloids

[0097] The WGS catalysts of the invention contain at least three metals or metalloids. In addition to the first two components, discussed above, a WGS catalyst contains metals or metalloids which, when used in combination with Pt and Ru, function to impart beneficial properties to the catalyst of the invention. A catalyst of the invention, then, further comprises at least one member of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof, component c).

[0098] A catalyst of the invention may include Pt and Ru containing catalysts which may further include activity or selectivity enhancing promoters such as Ti, V, Mo, Fe, Co, Ge, Sn, Sb, La, Ce, Pr, Sm or Eu. Preferred carriers include, for instance, zirconia, ceria and titania. Preferred supported catalysts include, for example, Pt—Ru—Co—Fe on ZrO2 or TiO2, Pt—Ru—Co—Na/ZrO2, Pt—Ru—Ti on ZrO2 or CeOx, and Pt—Ru—Ce—Ti on ZrO2.

[0099] Pt—Ru—Co containing catalyst compositions may preferably comprise one or more of K, Cs, V, Mo, Mn, Fe, La and Ce.

[0100] E. Functional Classification of Catalyst Components

[0101] Without limiting the scope of the invention, discussion of the functions of the various catalyst components is offered, along with a template for composing catalyst compositions according to the invention. The following classification of various catalyst components will direct one of skill in the art in the selection of various catalyst components to formulate WGS catalyst compositions according to the present invention and depending on the reaction conditions of interest.

[0102] Furthermore, according to the invention, there are several classes of catalyst components and metals which may be incorporated into a water gas shift catalyst. Hence, the various elements recited as components in any of the described embodiments (e.g., as component (c)), may be included in any various combination and permutation to achieve a catalyst composition that is coarsely or finely tuned for a specific application (e.g. including for a specific set of conditions, such as, temperature, pressure, space velocity, catalyst precursor, catalyst loading, catalyst surface area/presentation, reactant flow rates, reactant ratios, etc.). In some cases, the effect of a given component may vary with the operating temperature for the catalyst. These catalyst components may function as, for instance, activators or moderators depending upon their effect on the performance characteristics of the catalyst. For example, if greater activity is desired, an activator may be incorporated into a catalyst, or a moderator may be replaced by at least one activator or, alternatively, by at least one moderator one step further up the “activity ladder.” An “activity ladder” ranks secondary or added catalyst components, such as activators or moderators, in order of the magnitude of their respective effect on the performance of a principal catalyst constituent. Conversely, if WGS selectivity of a catalyst needs to be increased (e.g., decrease the occurrence of the competing methanation reaction), then either an activator may be removed from the catalyst or, alternatively, the current moderator may be replaced by at least one moderator one step down the “activity ladder.” The function of these catalyst component may be further described as “hard” or “soft” depending on the relative effect obtained by incorporating a given component into a catalyst. The catalyst components may be metals, metalloids, or even non-metals.

[0103] For instance, typically, a WGS catalyst according to the invention suitable for use under LTS conditions employs activators and may only be minimally moderated, if at all, because activation is generally the important parameter to be considered under LTS conditions. Such LTS catalysts also may preferably employ high surface area carriers to enhance catalyst activity. Conversely, WGS catalysts used in HTS conditions may benefit from the catalyst being moderated because selectivity and methanation are parameters to be considered. Such HTS catalysts may use, for example, low surface area carriers. Accordingly, operating temperature may be considered in selecting a WGS catalyst according to the present invention for a particular operating environment.

[0104] Activators according to the present invention may include Ru and Co as active and selective WGS-promoting metals. Ir has also been observed to have a slight moderating or activating function, depending on the presence of other counter metals. Other activators may include, but are not limited to, Ti, Zr, V, Mo, La, Ce, Pr and Eu. Ce may be the most active rare earth metal for activating the WGS reaction. La, Pr, Sm and Eu may also be active, particularly at lower temperatures. For HTS, Pr and Sm are preferred soft moderators enhancing selectivity without sacrificing much activity. For LTS, La and Eu may be useful activators. In general, all lanthanides, other than Ce, show comparable performance and tend to moderate rather than activate noble metal containing catalyst systems. Y is a highly selective moderator for HTS systems whereas La and Eu are active and comparable to Ce for LTS. La is only slightly moderating when doping Ce and may therefore be used to adjust the selectivity of Ce containing catalyst systems.

[0105] Catalyst components that are slightly moderating and highly selective over a broad temperature range (e.g., a temperature range of at least about 50° C., preferably at least about 75° C., and most preferably a temperature range of at least about 100° C.), where such temperature range is included within the overall preferred temperature ranges of up to about 450° C. include Y, Mo, Fe, Pr and Sm; these tend to be selective but not very active at low temperatures, about 250° C. The redox dopants Mo, Fe, Pr and Sm generally lose activity with increasing pre-reduction temperatures while Fe becomes moderately active on its own at high WGS reaction temperatures.

[0106] Moderators may also include Ge, Sn and Sb. Typically, for moderators to exert a moderating function, they should be substantially in the reduced or metallic state. Ge alloyed with Sn is an example of an alloy that was found to be highly active, even for low temperature systems, when in the fully oxidized state that is when treated at a pre-reduction temperature of about 300° C. which reduces the noble metals selectively but does not change the active oxidized state of the redox dopants in a catalyst composition.

[0107] E. Supports

[0108] The support or carrier may be any support or carrier used with the catalyst which allows the water gas shift reaction to proceed. The support or carrier may be a porous, adsorptive, high surface area support with a surface area of about 25 to about 500 m2/g. The porous carrier material may be relatively inert to the conditions utilized in the WGS process, and may include carrier materials that have traditionally be utilized in hydrocarbon stream reforming processes, such as, (1) activated carbon, coke, or charcoal; (2) silica or silica gel, silicon carbide, clays, and silicates including those synthetically prepared and naturally occurring, for example, china clay, diatomaceous earth, fuller's earth, kaolin, etc.; (3) ceramics, porcelain, bauxite; (4) refractory inorganic oxides such as alumina, titanium dioxide, zirconium oxide, magnesia, etc.; (5) crystalline and amorphous aluminosilicates such as naturally occurring or synthetically prepared mordenite and/or faujasite; and, (6) combinations of these groups.

[0109] When a WGS catalyst of the invention is a supported catalyst, the support utilized may contain one or more of the metals (or metalloids) of the catalyst. The support may contain sufficient or excess amounts of the metal for the catalyst such that the catalyst may be formed by combining the other components with the support. Examples of such supports include ceria which can contribute cerium, Ce, (component c)) to a catalyst, or iron oxide which can contribute iron, Fe, (component c)). When such supports are used the amount of the catalyst component in the support typically may be far in excess of the amount of the catalyst component needed for the catalyst. Thus the support may act as both an active catalyst component and a support material for the catalyst. Alternatively, the support may have only minor amounts of a metal making up the WGS catalyst such that the catalyst may be formed by combining all desired components on the support.

[0110] Carrier screening with catalysts containing Pt as the only active noble metal revealed that a water gas shift catalyst may also be supported on a carrier comprising alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, yttria and iron oxide. Perovskite may also be utilized as a support for the inventive catalyst formulations.

[0111] Zirconia, titania and ceria may be supports for the present invention and provide high activity for the WGS reaction. Preferably, zirconia is in the monoclinic phase. Highly pure ceria was found to activate PtRuTi in HTS conditions. Niobia, yttria and iron oxide carriers provide high selectivity but are also less active which is believed to be due to a lack of surface area. Pt on magnesia carriers formulated to have high surface areas (approximately 100 m2/g) exhibit high selectivity but also exhibit activity which decreases rapidly with falling reaction temperature.

[0112] Iron, yttrium, and magnesium oxides may be utilized as primary layers on zirconia carriers to provide both higher surface area and low moderator concentration.

[0113] In general, alumina has been found to be an active but unselective carrier for Pt only containing WGS catalysts. However, the selectivity of gamma alumina may be improved by doping with Y, Zr, Co, or one of the rare earth elements, such as, for example, La and Ce. This doping may be accomplished by addition of the oxides or other salts such as nitrates, in either liquid or solid form, to the alumina. Other possible dopants to increase the selectivity include redox dopants, such as for instance, Re, Mo, Fe and basic dopants. Preferred is an embodiment of gamma alumina combined with yttria or with both Zr and/or Co which exhibit both high activity and selectivity over a broad temperature range.

[0114] High surface area aluminas, such as gamma-, delta-, or theta-alumina are preferred alumina carriers. Other alumina carriers, such as mixed silica alumina, sol-gel alumina, as well as sol-gel or co-precipitated alumina-zirconia carriers may be used. Alumina typically has a higher surface area and a higher pore volume than carriers such as zirconia and offers a price advantage over other more expensive carriers.

[0115] F. Methods of Making a WGS Catalyst

[0116] As set forth above, a WGS catalyst of the invention may be prepared by mixing the metals and/or metalloids in their elemental forms or as oxides or salts to form a catalyst precursor, which generally undergoes a calcination and/or reductive treatment. Without being bound by theory, the catalytically active species are generally understood to be species which are in the reduced elemental state or in other possible higher oxidation states.

[0117] The WGS catalysts of the invention may be prepared by any well known catalyst synthesis processes. See, for example, U.S. Pat. Nos. 6,299,995 and 6,293,979. Spray drying, precipitation, impregnation, incipient wetness, ion exchange, fluid bed coating, physical or chemical vapor deposition are just examples of several methods that may be utilized to make the present WGS catalysts. Preferred approaches, include, for instance, impregnation or incipient wetness. The catalyst may be in any suitable form, such as, pellets, granular, bed, or monolith. See also the co-pending US Patent Application No. ______ filed on the same date as the present application titled “Methods For The Preparation Of Catalysts For Hydrogen Generation” to Hagemayer et al. under Attorney Docket No. 7080-011-01 for further details on methods of catalyst preparation and catalyst precursors. The complete disclosure of the above mentioned application and all other references cited herein are incorporated herein in their entireties for all purposes.

[0118] The WGS catalyst of the invention may be prepared on a solid support or carrier material. Preferably, the support or carrier is, or is coated with, a high surface area material onto which the precursors of the catalyst are added by any of several different possible techniques, as set forth above and as known in the art. The catalyst of the invention may be employed in the form of pellets, or on a support, preferably a monolith, for instance a honeycomb monolith.

[0119] Catalyst precursor solutions are preferably composed of easily decomposable forms of the catalyst component in a sufficiently high enough concentration to permit convenient preparation. Examples of easily decomposable precursor forms include the nitrate, amine, and oxalate salts. Typically chlorine containing precursors are avoided to prevent chlorine poisoning of the catalyst. Solutions can be aqueous or non-aqueous solutions. Exemplary non-aqueous solvents can include polar solvents, aprotic solvents, alcohols, and crown ethers, for example, tetrahydrofuran and ethanol. Concentration of the precursor solutions generally may be up to the solubility limitations of the preparation technique with consideration given to such parameters as, for example, porosity of the support, number of impregnation steps, pH of the precursor solutions, and so forth. The appropriate catalyst component precursor concentration can be readily determined by one of ordinary skill in the art of catalyst preparation.

[0120] Li—The acetate, hydroxide, nitrate and formate salts are both possible catalyst precursors for lithium.

[0121] Na—Sodium acetate, alkoxides including methoxide, propoxide, and ethoxide, bicarbonate, carbonate, citrate, formate, hydroxide, nitrate, nitrite and oxalate may be used to prepare WGS catalysts of the invention.

[0122] Mg—Water soluble magnesium precursors include the nitrate, acetate, lactate and formate salts.

[0123] K—Potassium nitrate, acetate, carbonate, hydroxide and formate are possible potassium catalyst precursors. The KOAc salt is volatile with possible potassium losses when heating up to calcination temperature.

[0124] Ca—The nitrate, acetate and hydroxide salts, preferable salts highly soluble in water, may be used to prepare catalysts of the invention.

[0125] Sc—The nitrate salt, Sc(NO3)3 may be a precursor for scandium.

[0126] Ti—Titanium precursors which may be utilized in the present invention include ammonium titanyl oxalate, (NH4)2TiO(C2O4)2, available from Aldrich, and titanium(IV) bis(ammonium lactato)dihydroxide, 50 wt % solution in water,

[0127] [CH3CH(O—)CO2NH4]2Ti(OH)2, available from Aldrich. Other titanium containing precursors include Ti oxalate prepared by dissolving a Ti(IV) alkoxide, such as Ti(IV) propoxide, Ti(OCH2CH2CH3)4, (Aldrich) in 1M aqueous oxalic acid at 60° C. and stirring for a couple of hours, to produce a 0.72M clear colorless solution; TiO(acac)oxalate prepared by dissolving Ti(IV) oxide acetylacetonate, TiO(acac)2, (Aldrich) in 1.5M aqueous oxalic acid at 60° C. with stirring for a couple of hours, following by cooling to room temperature overnight to produce 1M clear yellow-brown solution; TiO(acac)2, may also be dissolved in dilute acetic acid (50:50 HOAc:H2O) at room temperature to produce a 1M clear yellow solution of TiO acac. Preferably, titanium dioxide in the anatase form is utilized as a catalyst precursor material.

[0128] V—Vanadium (IV) oxalate, a vanadium precursor, may be prepared from V2O5, (Aldrich), which is slurried in 1.5M aqueous oxalic acid on hot plate for 1 hour until it turns dark blue due to V(V) reduction to V(IV) by oxalic acid. Ammonium metavanadate(V), (NH4)VO3, (Cerac, Alfa) may be used as a precursor by dissolving it in water, preferably hot, about 80° C. water. Various polycarboxylic organic acid vanadium precursors can be prepared and used as catalyst precursors, for example, citric, maleic, malonic, and tatartic. Vanadium citrate can be prepared by reacting V2O5 with citric acid, and heating to about 80° C. Ammonium vanadium(V) oxalate may be prepared by reacting (NH4)VO3 and NH4OH in room temperature water, increasing temperature to 90° C., stirring to dissolve all solids, cooling to room temperature and adding oxalic acid; this produces a clear orange solution, which is stable for about 2 days. Ammonium vanadium(V) citrate and ammonium vanadium(V) lactate are both prepared by shaking NH4VO3 in, respectively, aqueous citric acid or aqueous lactic acid, at room temperature. Diammonium vanadium(V) citrate may be prepared by dissolving, for instance, 0.25M NH4VO3 in citric acid diammonium salt (Alfa) at room temperature. An exemplary method of preparing ammonium vanadium(V) formate is to dissolve NH4VO3 (0.25M) in water at 95° C., react with 98% formic acid and NH4OH to produce the desired ammonium vanadium(V) formate; this method may be utilized to prepare vanadium formate solutions of 0.5 M V concentration or higher.

[0129] Cr—Both the nitrate and acetate hydroxides are possible catalyst precursors for chromium.

[0130] Mn—Manganese nitrate, manganese acetate (Aldrich) and manganese formate (Alfa) are all possible catalyst precursors for manganese.

[0131] Fe—Iron (III) nitrate, Fe(NO3)3, iron(III) ammonium oxalate, (NH4)3 Fe(C2O4)3, iron(III) oxalate, Fe2(C2O4)3, and iron(II) acetate, Fe(OAc)2, are all water soluble; although the iron(III)oxalate undergoes thermal decomposition at only 100° C. Potassium iron(III) oxalate, iron(III) formate and iron(III) citrate are additional iron precursors.

[0132] Co—Both cobalt nitrate and acetate are water soluble precursor solutions. The cobalt (II) formate, CO(OOCH)2, has low solubility in cold water of about 5 g/100 ml; while cobalt (II) oxalate is soluble in aqueous NH4OH. Another possible precursor is sodium hexanitrocobaltate(III), Na3Co(NO2)6 which is water soluble, with gradual decomposition of aqueous solutions slowed by addition of small amounts of acetic acid. Hexaammine Co(III) nitrate is also soluble in hot (65° C.) water and NMe4OH. Cobalt citrate, prepared by dissolving Co(OH)2 in aqueous citric acid at 80° C. for 1 to 2 hours, is another suitable cobalt precursor.

[0133] Ni—Nickel nitrate, Ni(NO3)2, and nickel formate are both possible nickel precursors. The nickel formate may be prepared by dissolving Ni(HCO2)2 in water and adding formic acid, or by dissolving in dilute formic acid, to produce clear greenish solutions.

[0134] Cu—Copper precursors include nitrate, Cu(NO3)2, acetate, Cu(OAc)2, and formate, Cu(OOCH)2, which are increasingly less water soluble in the order presented. Ammonium hydroxide is used to solublize oxalate, Cu(C2O4)2, and Cu(NH3)4(OH)2 which is soluble in aqueous 5N NH4OH. Copper citrate and copper amine carbonate may be prepared from Cu(OH)2.

[0135] Zn—Zinc nitrate, acetate and formate are all water soluble and possible catalyst precursors. Ammonium zinc carbonate, (NH4)2Zn(OH)2CO3, prepared by reacting zinc hydroxide and ammonium carbonate for a week at room temperature, is another possible precursor for zinc.

[0136] Ge—Germanium oxalate may be prepared from amorphous Ge(IV) oxide, glycol-soluble GeO2, (Aldrich) by reaction with 1M aqueous oxalic acid at room temperature. H2GeO3 may be prepared by dissolving GeO2 in water at 80° C. and adding 3 drops of NH4OH (25%) to produce a clear, colorless H2GeO3 solution. (NMe4)2GeO3 may be prepared by dissolving 0.25 M GeO2 in 0.1 M NMe4OH. (NH4)2GeO3 may be prepared by dissolving 0.25 M GeO2 in 0.25M NH4OH.

[0137] Rb—The nitrate, acetate, carbonate and hydroxide salts may be used as catalyst precursors to prepare the WGS catalyst of the invention. Preferred are water soluble salts.

[0138] Sr—The acetate is soluble in cold water to produce a clear colorless solution.

[0139] Y—Yttrium nitrate and acetate are both possible catalyst precursors.

[0140] Zr—Zirconyl nitrate and acetate, commercially available from Aldrich, and ammonium Zr carbonate and zirconia, available from MEI, are possible precursors for zirconium in either or both the support or catalyst formulation itself

[0141] Nb—Niobium oxalate prepared by dissolving niobium (V) ethoxide in aqueous oxalic acid at 60° C. for 12 hours is a possible catalyst precursor. Another preparative route to the oxalate is dissolving niobic acid or niobic oxide (Nb2O5) in oxalic acid at 65° C. Ammonium Nb oxalate is also a possible catalyst precursor for niobium. Dissolving niobic oxide (0.10 M Nb) in NMe4OH (0.25 M) and stirring overnight at 65° C. will produce (NMe4)2NbO6.

[0142] Mo—Molybdenum containing precursor solutions may be derived from ammonium molybdate (NH4)2MoO4 (Aldrich) dissolved in room temperature water; Mo oxalate prepared by dissolving MoO3 (Aldrich) in 1. SM aqueous oxalic acid at 60° C. overnight; and ammonium Mo oxalate prepared from (NH4)6Mo7O24.4H2O (Strem) dissolved in 1M aqueous oxalic acid at room temperature. (NH4)6Mo7O24.4H2O (Strem) may also be dissolved in water at room temperature to produce a stable solution of ammonium paramolybdate tetrahydrate. Molybdic acid, H2MoO4, (Alfa Aesar or Aldrich) may each be dissolved in room temperature water to produce 1M Mo containing solutions.

[0143] Ru—Ru nitrosyl nitrate, Ru(NO)(NO3)3 (Aldrich), potassium ruthenium oxide, K2RuO4.H2O, potassium perruthenate, KRuO4, ruthenium nitrosyl acetate, Ru(NO)(OAc)3, and tetrabutylammonium perruthenate, NBu4RuO4, are all possible ruthenium metal catalyst precursors. NMe4Ru(NO)(OH)4 solution can be prepared by dissolving Ru(NO)(OH)3 (0.1 M) (H. C. Starck) in NMe4OH (0.12M) at 80° C. produces a clear dark red-brown 0.1M Ru solution useful as a catalyst precursor solution.

[0144] Rh—A suitable rhodium catalyst precursor is Rh nitrate (Aldrich or Strem).

[0145] Pd—Catalyst compositions containing Pd can be prepared by using precursors like Pd nitrate, typically stabilized by dilute HNO3, and available as a 10 wt. % solution from Aldrich, or Pd(NH3)2(NO2)2 available as a 5 wt. % Pd commercial solution, stabilized by dilute NH4OH. Pd(NH3)4(NO3)2 and Pd(H3)4(OH)2 are also available commercially.

[0146] Ag—Silver nitrate, silver nitrite, silver diammine nitrite, and silveracetate are possible silver catalyst precursors.

[0147] Cd—Cadmium nitrate is water soluble and a suitable catalyst precursor.

[0148] In—Indium formate and indium nitrate are preferred precursors for indium.

[0149] Sn—Tin oxalate produced by reacting the acetate with oxalic acid may be used as a catalyst precursor. Tin tartrate, SnC4H4O6, in NMe4OH at about 0.25 M Sn concentration, and tin acetate, also dissolved in NMe4OH at about 0.25 M Sn concentration, may be used as catalyst precursors.

[0150] Sb—Ammonium antimony oxalate produced by reacting the acetate with oxalic acid and ammonia is a suitable antimony precursor. Antimony oxalate, Sb2(C2O4)3, available from Pfaltz & Bauer, is a water soluble precursor. Potassium antimony oxide, KSbO3, and antimony citrate, prepared by stirring antimony(II) acetate in 1 M citric acid at room temperature, are both possible catalyst precursors.

[0151] Te—Telluric acid, Te(OH)6, may be used as a precursor for tellurium.

[0152] Cs—Cs salts including the nitrate, acetate, carbonate, and hydroxide are soluble in water and possible catalyst precursors.

[0153] Ba—Barium acetate and barium nitrate are both suitable precursors for barium catalyst components.

[0154] La—Lanthanum precursors include nitrate, La(NO3)3, acetate, La(OAc)3, and perchlorate, La(ClO4)3, all of which may be prepared as aqueous solutions.

[0155] Ce—Ce(III) and Ce(IV) solutions may be prepared from Ce(III) nitrate hexahydrate, Ce(NO3)3.6H2O, (Aldrich) and ammonium cerium(IV) nitrate, (NH4)2Ce(NO3)6, (Aldrich), respectively, by dissolution in room temperature water. Nitric acid, 5 vol. %, may be added to the Ce(III) salt to increase solubility and stability. Ce(OAc)3 (Alfa) and Ce(NO3)4 (Alfa) may also be utilized as catalyst precursors.

[0156] Pr, Nd, Sm and Eu—The nitrate, Ln(NO3)3, or acetate, Ln(O2CCH3)3, are possible catalyst precursors for these lanthanides.

[0157] Hf—Hafnoyl chloride and nitrate are both possible precursors. Preparing the hafnoyl nitrate by dissolving Hf(acac)4 in dilute HNO3 at low heat provides a clear stable solution of hafnoyl nitrate.

[0158] Ta—Tantalum oxalate solution, Ta2O(C2O4)4, available from H. C. Starck, or prepared by dissolving Ta(OEt)5 in aqueous oxalic acid at 60° C. for 12 hours, is a possible catalyst precursor.

[0159] W—Ammonium metatungstate hydrate, (NH4)6W12O39, is water soluble and a possible tungsten catalyst precursor. H2WO4 is reacted with NH4OH and NMe4OH, respectively, to prepare (NH4)2WO4 and (NMe4)2WO4 which are both possible precursors.

[0160] Re—Rhenium oxide in H2O2, perrhenic acid, (HReO4), NaReO4 and NH4ReO4 are suitable rhenium precursors.

[0161] Ir—Hexachloroiridate acid, H2IrCl6, potassium hexacyanoiridate and potassium hexanitroiridate are all possible catalyst precursors for iridium.

[0162] Pt—Platinum containing catalyst compositions may be prepared by using any one of a number of precursor solutions, such as, Pt(NH3)4(NO3)2 (Aldrich, Alfa, Heraeus, or Strem), Pt(NH3)2(NO2)2, in nitric acid, Pt(NH3)4(OH)2 (Alfa), K2Pt(NO2)4, Pt(NO3)2, PtCl4 and H2PtCl6 (chloroplatinic acid). Pt(NH3)4(HCO3)2, Pt(NH3)4(HPO4), (NMe4)2Pt(OH)6, H2Pt(OH)6, K2Pt(OH)6, Na2Pt(OH)6 and K2Pt(CN)6 are also possible choices along with Pt oxalate salts, such as K2Pt(C2O4)2. The Pt oxalate salts may be prepared from Pt(NH3)4(OH)2 which is reacted with 1M oxalic acid solution to produce a clear, colorless solution of the desired Pt oxalate salts.

[0163] Au—Auric acid, HAuCl4, in dilute HCl at about 5% Au may be a gold precursor. Gold nitrate in 0.1 M concentration may be prepared by dissolving HAu(NO3)4 (Alfa) in concentrated nitric acid, followed by stirring at room temperature for 1 week in the dark, then diluting 1:1 with water to produce a yellow solution. It should be noted that further dilution may result in Au precipitation. More concentrated, 0.25M, for example, gold nitrate may be prepared by starting with Au(OH)3 (Alfa). NaAu(OH)4, KAu(OH)4, and NMe4Au(OH)4 may each be prepared from Au(OH)3 dissolved in bases NaOH, KOH, or NMe4OH, respectively, in base concentrations ranging from, for instance, 0.25 M or higher.

[0164] 3. Producing a Hydrogen-Rich Gas, Such as, a Hydrogen-Rich Syngas

[0165] The invention also relates to a method for producing a hydrogen-rich gas, such as a hydrogen-rich syngas. An additional embodiment of the invention may be directed to a method of producing a CO depleted gas, such as a CO-depleted syngas.

[0166] A CO-containing gas, such as a syngas contacts with a water gas shift catalyst in the presence of water according to the method of the invention. The reaction preferably may occur at a temperature of less than 450° C. to produce a hydrogen-rich gas such as a hydrogen-rich syngas.

[0167] A method of the invention may be utilized over a broad range of reaction conditions. Preferably, the method is conducted at a pressure of no more than about 75 bar, preferably at a pressure of no more than about 50 bar to produce a hydrogen-rich syngas. Even more preferred is to have the reaction occur at a pressure of no more than about 25 bar, or even no more than about 15 bar, or not more than about 10 bar. Especially preferred is to have the reaction occur at, or about atmospheric pressure. Depending on the formulation of the catalyst according to the present invention, the present method may be conducted at reactant gas temperatures ranging from less than about 150° C. to up to about 450° C. Preferably, the reaction occurs at a temperature selected from one or more temperature subranges of LTS, MTS and/or HTS as described above. Space velocities may range from about 1 hr−1 up to about 1,000,000 hr−1. Feed ratios, temperature, pressure and the desired product ratio are factors that would normally be considered by one of skill in the art to determine a desired optimum space velocity for a particular catalyst formulation.

[0168] 4. Fuel Processor Apparatus

[0169] The invention further relates to a fuel processing system for generation of a hydrogen-rich gas from a hydrocarbon or substituted hydrocarbon fuel. Such a fuel processing system would comprise, for example, a fuel reformer, a water gas shift reactor and a temperature controller.

[0170] The fuel reformer would convert a fuel reactant stream comprising a hydrocarbon or a substituted hydrocarbon fuel to a reformed product stream comprising carbon monoxide and water. The fuel reformer may typically have an inlet for receiving the reactant stream, a reaction chamber for converting the reactant stream to the product stream, and an outlet for discharging the product stream.

[0171] The fuel processor system would also comprise a water gas shift reactor for effecting a water gas shift reaction at a temperature of less than about 450° C. This water gas shift reactor may comprise an inlet for receiving a water gas shift feed stream comprising carbon monoxide and water from the product stream of the fuel reformer, a reaction chamber having a water gas shift catalyst as described herein located therein, and an outlet for discharging the resulting hydrogen-rich gas. The water gas shift catalyst would preferable be effective for generating hydrogen and carbon dioxide from the water gas shift feed stream.

[0172] The temperature controller may be adapted to maintain the temperature of the reaction chamber of the water gas shift reactor at a temperature of less than about 450° C.

5. INDUSTRIAL APPLICATIONS

[0173] Syngas is used as a reactant feed in number of industrial applications, including for example, methanol synthesis, ammonia synthesis, oxoaldehyde synthesis from olefins (typically in combination with a subsequent hydrogenation to form the corresponding oxoalcohol), hydrogenations and carbonylations. Each of these various industrial applications preferably includes a certain ratio of H2 to CO in the syngas reactant stream. For methanol synthesis the ratio of H2:CO is preferably about 2:1. For oxosynthesis of oxoaldehydes from olefins, the ratio of H2:CO is preferably about 1:1. For ammonia synthesis, the ratio of H2 to N2 (e.g., supplied from air) is preferably about 3:1. For hydrogenations, syngas feed streams that have higher ratios of H2:CO are preferred (e.g., feed streams that are H2 enriched, and that are preferably substantially H2 pure feed streams). Carbonylation reactions are preferably effected using feed streams that have lower ratios of H2:CO (e.g., feed streams that are CO enriched, and that are preferably substantially CO pure feed streams).

[0174] The WGS catalysts of the present invention, and the methods disclosed herein that employ such WGS catalysts, can be applied industrially to adjust or control the relative ratio H2:CO in a feed stream for a synthesis reaction, such as methanol synthesis, ammonia synthesis, oxoaldehyde synthesis, hydrogenation reactions and carbonylation reactions. In one embodiment, for example, a syngas product stream comprising CO and H2 can be produced from a hydrocarbon by a reforming reaction in a reformer (e.g., by steam reforming of a hydrocarbon such as methanol or naphtha). The syngas product stream can then be fed (directly or indirectly after further downstream processing) as the feed stream to a WGS reactor, preferably having a temperature controller adapted to maintain the temperature of the WGS reactor at a temperature of about 450° C. or less during the WGS reaction (or at lower temperatures or temperature ranges as described herein in connection with the catalysts of the present invention). The WGS catalyst(s) employed in the WGS reactor are preferably selected from one or more of the catalysts and/or methods of the invention. The feed stream to the WGS reactor is contacted with the WGS catalyst(s) under reaction conditions effective for controlling the ratio of H2:CO in the product stream from the WGS reactor (i.e., the “shifted product stream”) to the desired ratio for the downstream reaction of interest (e.g., methanol synthesis), including to ratios described above in connection with the various reactions of industrial significance. As a non-limiting example, a syngas product stream from a methane steam reformer will typically have a H2:CO ratio of about 6:1. The WGS catalyst(s) of the present invention can be employed in a WGS reaction (in the forward direction as shown above) to further enhance the amount of H2 relative to CO, for example to more than about 10:1, for a downstream hydrogenation reaction. As another example, the ratio of H2:CO in such a syngas product stream can be reduced by using a WGS catalyst(s) of the present invention in a WGS reaction (in the reverse direction as shown above) to achieve or approach the desired 2:1 ratio for methanol synthesis. Other examples will be known to a person of skill in the art in view of the teachings of the present invention.

[0175] A person of skill in the art will understand and appreciate that with respect to each of the preferred catalyst embodiments as described in the preceding paragraphs, the particular components of each embodiment can be present in their elemental state, or in one or more oxide states, or mixtures thereof.

[0176] Although the foregoing description is directed to the preferred embodiments of the invention, it is noted that other variations and modifications will be apparent to those skilled in the art, and which may be made without departing from the spirit or scope of the invention.

EXAMPLES

[0177] General

[0178] Small quantity catalyst composition samples are generally prepared by automated liquid dispensing robots (Cavro Scientific Instruments) on flat quartz test wafers.

[0179] Generally supported catalysts are prepared by providing a catalyst support (e.g. alumina, silica, titania, etc.) to the wafer substrate, typically as a slurry composition using a liquid-handling robot to individual regions or locations on the substrate or by wash-coating a surface of the substrate using techniques known to those of skill in the art, and drying to form dried solid support material on the substrate. Discrete regions of the support-containing substrate are then impregnated with specified compositions intended to operate as catalysts or catalyst precursors, with the compositions comprising metals (e.g. various combinations of transition metal salts). In some circumstances the compositions are delivered to the region as a mixture of different metal-containing components and in some circumstances (additionally or alternatively) repeated or repetitive impregnation steps are performed using different metal-containing precursors. The compositions are dried to form supported catalyst precursors. The supported catalyst precursors are treated by calcining and/or reducing to form active supported catalytic materials at discrete regions on the wafer substrate.

[0180] The catalytic materials (e.g. supported or bulk) on the substrate are tested for activity and selectivity for the WGS reaction using a scanning mass spectrometer (SMS) comprising a scanning/sniffing probe and a mass spectrometer. More details on the scanning mass spectrometer instrument and screening procedure are set forth in U.S. Pat. No. 6,248,540, in European Patent No. EP 1019947 and in European Patent Application No. EP 1186892 and corresponding U.S. application Ser. No. 09/652,489 filed Aug. 31, 2000 by Wang et al., the complete disclosure of each of which is incorporated herein in its entirety. Generally, the reaction conditions (e.g. contact time and/or space velocities, temperature, pressure, etc.) associated with the scanning mass spectrometer catalyst screening reactor are controlled such that partial conversions (i.e., non-equilibrium conversions, e.g., ranging from about 10% to about 40% conversion) are obtained in the scanning mass spectrometer, for discrimination and ranking of catalyst activities for the various catalytic materials being screened. Additionally, the reaction conditions and catalyst loadings are established such that the results scale appropriately with the reaction conditions and catalyst loadings of larger scale laboratory research reactors for WGS reactions. A limited set of tie-point experiments are performed to demonstrate the scalability of results determined using the scanning mass spectrometer to those using larger scale laboratory research reactors for WGS reactions. See, for example, Example 12 below.

[0181] Preparative and Testing Procedures

[0182] The catalysts and compositions of the present invention were identified using high-throughput experimental technology, with the catalysts being prepared and tested in library format, as described generally above, and in more detail below. Specifically, such techniques were used for identifying catalyst compositions that were active and selective as WGS catalysts. As used in these examples, a “catalyst library” refers to an associated collection of candidate WGS catalysts arrayed on a wafer substrate, and having at least two, and typically three or more common metal components (including metals in the fully reduced state, or in a partially or fully oxidized state, such as metal salts), but differing from each other with respect to relative stoichiometry of the common metal components.

[0183] Depending on the library design and the scope of the investigation with respect to a particular library, multiple (i.e., two or more) libraries were typically formed on each wafer substrate. A first group of test wafers each comprised about 100 different catalyst compositions formed on a three-inch wafer substrate, typically with most catalysts being formed using at least three different metals. A second group of test wafers each comprised about 225 different catalyst compositions on a four-inch wafer substrate, again typically with most catalysts being formed using at least three different metals. Each test wafer itself typically comprised multiple libraries. Each library typically comprised binary, ternary or higher-order compositions—that is, for example, as ternary compositions that comprised at least three components (e.g., A, B, C) combined in various relative ratios to form catalytic materials having a molar stoichiometry covering a range of interest (e.g., typically ranging from about 20% to about 80% or more (e.g. to about 100% in some cases) of each component). For supported catalysts, in addition to varying component stoichiometry for the ternary compositions, relative total metal loadings were also investigated.

[0184] Typical libraries formed on the first group of (three-inch) test wafers included, for example, “five-point libraries” (e.g., twenty libraries, each having five different associated catalyst compositions), or “ten-point” libraries (e.g., ten libraries, each having ten different associated catalyst compositions), or “fifteen-point libraries” (e.g., six libraries, each having fifteen different associated catalyst compositions) or “twenty-point libraries” (e.g., five libraries, each having twenty different associated catalyst compositions). Typical libraries formed on the second group of (four-inch) test wafers included, for example, “nine-point libraries” (e.g., twenty-five libraries, each having nine different associated catalyst compositions), or “twenty-five point” libraries (e.g., nine libraries, each having twenty-five different associated catalyst compositions). Larger compositional investigations, including “fifty-point libraries” (e.g., two or more libraries on a test wafer, each having fifty associated catalyst compositions), were also investigated. Typically, the stoichiometric increments of candidate catalyst library members ranged from about 1.5% (e.g. for a “fifty-five point ternary”) to about 15% (e.g., for a “five-point” ternary). See, generally, for example, WO 00/17413 for a more detailed discussion of library design and array organization. FIG. 15A to 15F of the instant application shows library designs for libraries prepared on a common test wafer, as graphically represented using Library Studio® (Symyx Technologies, Inc., Santa Clara, Calif.), where the libraries may vary with respect to both stoichiometry and catalyst loading. Libraries of catalytic materials that vary with respect to relative stoichiometry and/or relative catalyst loading can also be represented in a compositional table, such as is shown in the several examples of this application.

[0185] Referring to FIG. 15A, for example, the test wafer includes nine libraries, where each of the nine libraries comprise nine different ternary compositions of the same three-component system. In the nomenclature of the following examples, such a test wafer is said to include nine, nine-point-ternary (“9PT”) libraries. The library depicted in the upper right hand corner of this test wafer includes catalyst compositions comprising components A, B and X1 in 9 different stoichiometries. As another example, with reference to FIG. 15B, a partial test wafer is depicted that includes a fifteen-point-ternary (“15PT”) library having catalyst compositions of Pt, Pd and Cu in fifteen various stoichiometries. Generally, the composition of each catalyst included within a library is graphically represented by an association between the relative amount (e.g., moles or weight) of individual components of the composition and the relative area shown as corresponding to that component. Hence, referring again to the fifteen different catalyst compositions depicted on the partial test wafer represented in FIG. 155B, it can be seen that each composition includes Pt (red), Pd (green) and Cu (blue), with the relative amount of Pt increasing from column 1 to column 5 (but being the same as compared between rows within a given column), with the relative amount of Pd decreasing from row 1 to row 5 (but being the same as compared between columns within a given row), and with the relative amount of Cu decreasing from a maximum value at row 5, column 1 to a minimum at, for example, row 1, column 1. FIG. 15C shows a test wafer that includes a fifty-point-ternary (“50PT”) library having catalyst compositions of Pt, Pd and Cu in fifty various stoichiometries. This test library could also include another fifty-point ternary library (not shown), for example with three different components of interest.

[0186]
FIGS. 15D through 15F are graphical representations of two fifty-point ternary libraries (“bis 50PT libraries”) at various stages of preparation—including a Pt—Au—Ag/CeO2 library (shown as the upper right ternary library of FIG. 15E) and a Pt—Au—Ce/ZrO2 library (shown as the lower left ternary library of FIG. 15E). Note that the Pt—Au—Ag/CeO2 library also includes binary-impregnated compositions—Pt—Au/CeO2 binary catalysts (row 2) and Pt—Ag/CeO2 (column 10). Likewise, the Pt—Au—Ce/ZrO2 library includes binary-impregnated compositions—Pt—Ce/ZrO2 (row 11) and Au—Ce/ZrO2 (column 1). Briefly, the bis 50PT libraries were prepared by depositing CeO2 and ZrO2 supports onto respective portions of the test wafer as represented graphically in FIG. 15D. The supports were deposited onto the test wafer as a slurry in a liquid media using a liquid handling robot, and the test wafer was subsequently dried to form dried supports. Thereafter, salts of Pt, Au and Ag were impregnated onto the regions of the test wafer containing the CeO2 supports in the various relative stoichiometries as represented in FIG. 15E (upper-right-hand library). Likewise, salts of Pt, Au and Ce were impregnated onto the regions of the test wafer containing the ZrO2 supports in the various relative stoichiometries as represented in FIG. 15E (lower-left-hand library). FIG. 15F is a graphical representation of the composite library design, including the relative amount of catalyst support.

[0187] Specific compositions of tested catalytic materials of the invention are detailed in the following examples for selected libraries.

[0188] Performance benchmarks and reference experiments (e.g., blanks) were also provided on each quartz catalyst test wafer as a basis for comparing the catalyst compositions of the libraries on the test wafer. The benchmark catalytic material formulations included a Pt/zirconia catalyst standard with about 3% Pt catalyst loading (by weight, relative to total weight of catalyst and support). The Pt/zirconia standard was typically synthesized by impregnating 3 μL of, for example, 1.0% or 2.5% by weight, Pt stock solution onto zirconia supports on the wafer prior to calcination and reduction pretreatment.

[0189] Typically wafers were calcined in air at a temperature ranging from 300° C. to 500° C. and/or reduced under a continuous flow of 5% hydrogen at a temperature ranging from about 200° C. to about 500° C. (e.g., 450° C.). Specific treatment protocols are described below with respect to each of the libraries of the examples.

[0190] For testing using the scanning mass spectrometer, the catalyst wafers were mounted on a wafer holder which provided movement in an XY plane. The sniffing/scanning probe of the scanning mass spectrometer moved in the Z direction (a direction normal to the XY plane of movement for the wafer holder), and approached in close proximity to the wafer to surround each independent catalyst element, deliver the feed gas and transmit the product gas stream from the catalyst surface to the quadrupole mass spectrometer. Each element was heated locally from the backside using a CO2 laser, allowing for an accessible temperature range of about 2000 to about 600° C. The mass spectrometer monitored seven masses for hydrogen, methane, water, carbon monoxide, argon, carbon dioxide and krypton: 2, 16, 18, 28, 40, 44 and 84, respectively.

[0191] Catalyst compositions were tested at various reaction temperatures, typically including for example at about 250° C., 300° C., 350° C. and/or 400° C. Particularly for LTS formulations, testing of catalyst activity at reaction temperatures may start as low as 200° C. The feed gas typically consisted of 51.6% H2, 7.4% Kr, 7.4% CO, 7.4% CO2 and 26.2% H2O. The H2, CO, CO2 and Kr internal standard are premixed in a single gas cylinder and then combined with the water feed. Treated water (18.1 mega-ohms-cm at 27.5° C.) produced by a Barnstead Nano Pure Ultra Water system was used, without degassing.

[0192] Data Processing and Analysis

[0193] Data analysis was based on mass balance plots where CO conversion was plotted versus CO2 production. The mass spectrometer signals were uncalibrated for CO and CO2 but were based on Kr-normalized mass spectrometer signals. The software package SpotFire™ (sold by SpotFire, Inc. of Somerville, Mass.) was used for data visualization.

[0194] A representative plot of CO conversion versus CO2 production for a WGS reaction is shown in FIG. 16A involving, for discussion purposes, two ternary catalyst systems—a Pt—Au—Ag/CeO2 catalyst library and a Pt—Au—Ce/ZrO2 catalyst library—as described above in connection with FIGS. 15D through 15F. The catalyst compositions of these libraries were screened at four temperatures: 250° C., 300° C., 350° C. and 400° C. With reference to the schematic diagram shown in FIG. 16B, active and highly selective WGS catalysts (e.g., Line I of FIG. 16B) will approach a line defined by the mass balance for the water-gas-shift reaction (the “WGS diagonal”) with minimal deviation, even at relatively high conversions (i.e., at CO conversions approaching the thermodynamic equilibrium conversion (point “TE” on FIG. 16B)). Highly active catalysts may begin to deviate from the WGS diagonal due to cross-over to the competing methanation reaction (point “M” on FIG. 16C). Catalyst compositions that exhibit such deviation may still, however, be useful WGS catalysts depending on the conversion level at which such deviation occurs. For example, catalysts that first deviate from the WGS diagonal at higher conversion levels (e.g., Line II of FIG. 16B) can be employed as effective WGS catalysts by reducing the overall conversion (e.g., by lowering catalyst loading or by increasing space velocity) to the operational point near the WGS diagonal. In contrast, catalysts that deviate from the WGS diagonal at low conversion levels (e.g., Line III of FIG. 16B) will be relatively less effective as WGS catalysts, since they are unselective for the WGS reaction even at low conversions. Temperature affects the thermodynamic maximum CO conversion, and can affect the point of deviation from the mass-balance WGS diagonal as well as the overall shape of the deviating trajectory, since lower temperatures will generally reduce catalytic activity. For some compositions, lower temperatures will result in a more selective catalyst, demonstrated by a WGS trajectory that more closely approximates the WGS mass-balance diagonal. (See FIG. 16C). Referring again to FIG. 16A, it can be seen that the Pt—Au—Ag/CeO2 and the Pt—Au—Ce/ZrO2 catalyst compositions are active and selective WGS catalysts at each of the screened temperatures, and particularly at lower temperatures.

[0195] Generally, the compositions on a given wafer substrate were tested together in a common experimental run using the scanning mass spectrometer and the results were considered together. In this application, candidate catalyst compositions of a particular library on the substrate (e.g., ternary or higher-order catalysts comprising three or more metal components) were considered as promising candidates for an active and selective commercial catalyst for the WGS reaction based on a comparison to the Pt/ZrO2 standard composition included on that wafer. Specifically, libraries of catalytic materials were deemed to be particularly preferred WGS catalysts if the results demonstrated that a meaningful number of catalyst compositions in that library compared favorably to the Pt/ZrO2 standard composition included on the wafer substrate with respect to catalytic performance. In this context, a meaningful number of compositions was generally considered to be at least three of the tested compositions of a given library. Also in this context, favorable comparison means that the compositions had catalytic performance that was as good as or better than the standard on that wafer, considering factors such as conversion, selectivity and catalyst loading. All catalyst compositions of a given library were in many cases positively identified as active and selective WGS catalysts even in situations where only some of the library members compared favorably to the Pt/ZrO2 standard, and other compositions within that library compared less than favorably to the Pt/ZrO2 standard. In such situations, the basis for also including members of the library that compared somewhat less favorably to the standard is that these members in fact positively catalyzed the WGS reaction (i.e., were effective as catalysts for this reaction). Additionally, it is noted that such compositions may be synthesized and/or tested under more optimally tuned conditions (e.g., synthesis conditions, treatment conditions and/or testing conditions (e.g., temperature)) than occurred during actual testing in the library format, and significantly, that the optimal conditions for the particular catalytic materials being tested may differ from the optimal conditions for the Pt/ZrO2 standard—such that the actual test conditions may have been closer to the optimal conditions for the standard than for some of the particular members. Therefore, it was specifically contemplated that optimization of synthesis, treatment and/or screening conditions, within the generally defined ranges of the invention as set forth herein, would result in even more active and selective WGS catalysts than what was demonstrated in the experiments supporting this invention. Hence, in view of the foregoing discussion, the entire range of compositions defined by each of the claimed compositions (e.g., each three-component catalytic material, or each four-component catalytic material) was demonstrated as being effective for catalyzing the WGS reaction. Further optimization is considered, with various specific advantages associated with various specific catalyst compositions, depending on the desired or required commercial application of interest. Such optimization can be achieved, for example, using techniques and instruments such as those described in U.S. Pat. No. 6,149,882, or those described in WO 01/66245 and its corresponding U.S. applications, U.S. Ser. No. 09/801,390, entitled “Parallel Flow Process Optimization Reactor” filed Mar. 7, 2001 by Bergh et al., and U.S. Ser. No. 09/801,389, entitled “Parallel Flow Reactor Having Variable Feed Composition” filed Mar. 7, 2001 by Bergh et al., each of which are incorporated herein by reference for all purposes.

[0196] Additionally, based on the results of screening of initial libraries, selective additional “focus” libraries were selectively prepared and tested to confirm the results of the initial library screening, and to further identify better performing compositions, in some cases under the same and/or different conditions. The test wafers for the focus libraries typically comprised about 225 different candidate catalyst compositions formed on a four-inch wafer substrate, with one or more libraries (e.g. associated ternary compositions A, B, C) formed on each test wafer. Again, the metal-containing components of a given library were typically combined in various relative ratios to form catalysts having stoichiometry ranging from about 0% to about 100% of each component, and for example, having stoichiometric increments of about 10% or less, typically about 2% or less (e.g., for a “fifty-six point ternary”). Focus libraries are more generally discussed, for example, in WO 00/17413. Such focus libraries were evaluated according to the protocols described above for the initial libraries.

[0197] The raw residual gas analyzer (“rga”) signal values generated by the mass spectrometer for the individual gases are uncalibrated and therefore different gases may not be directly compared. Methane data (mass 16) was also collected as a control. The signals are typically standardized by using the raw rga signal for krypton (mass 84) to remove the effect of gas flow rate variations. Thus, for each library element, the standardized signal is determined as, for example, sH2O=raw H2O/raw Kr; sCO=raw CO/raw Kr; sCO2=raw CO2/raw Kr and so forth.

[0198] Blank or inlet concentrations are determined from the average of the standardized signals for all blank library elements, i.e. library elements for which the composition contains at most only support. For example, bavg H2O=average sH2O for all blank elements in the library; bavg CO=average sCO for all blank elements in the library; and so forth.

[0199] Conversion percentages are calculated using the blank averages to estimate the input level (e.g., bavg CO) and the standardized signal (e.g., sCO) as the output for each library element of interest. Thus, for each library element, COconversion=100×(bavg CO−sCO)/bavg CO and H2COconversion=100×(bavg H2O−sH2O)/bavg H2O.

[0200] The carbon monoxide (CO) to carbon dioxide (CO2) selectivity is estimated by dividing the amount of CO2 produced (sCO2−bavg CO2) by the amount of CO consumed (bavg CO−sCO). The CO2 and CO signals are not directly comparable because the rga signals are uncalibrated. However, an empirical conversion constant (0.6 CO2 units=1 CO unit) has been derived, based on the behavior of highly selective standard catalyst compositions. The selectivity of the highly selective standard catalyst compositions approach 100% selectivity at low conversion rates. Therefore, for each library element, estimated CO to CO2 selectivity=100×0.6×(sCO2−bavg CO2)/(bavg CO−sCO). Low CO consumption rates can produce highly variable results, and thus the reproducibility of CO2 selectivity values is maintained by artificially limiting the CO2 selectivity to a range of 0 to 140%.

[0201] The complete disclosure of all references cited herein are incorporated herein in their entireties for all purposes.

[0202] The following examples are representative of the screening of libraries that lead to identification of the particularly claimed inventions herein.

Example 1

[0203] A 6.8% Pt/titania masterbatch was prepared by incipient wetness impregnation of 1000 mg titania powder (Degussa Aerolyst 7708, less than 100 mesh sieve fraction) with 1,300 μl of Pt(NH3)2(NO2)2 stock solution (5% Pt, STREM) and dried overnight at ambient, then at 80° C., then at 110° C.

[0204] 500 mg of the 6.8% Pt/TiO2 masterbatch was slurried into 4 ml of EG/H2O/MEO 40/30/30 mixture and then slurry-dispensed onto a 3″ quartz wafer in two layers of 3 μl slurry each for a total dispense volume of 6 μl.

[0205] The Pt/TiO2 precoated wafer was then impregnated with 25 different metal solutions in squares of 2 by 2 wells by direct dispensing from metal stock solution vials onto the wafer at 2 μl dispense volume/well. The wafer was dried, calcined in air at 450° C. for 2 hours and then reduced in 5% H2/Ar at 450° C. for 2 hours. See FIGS. 1A-1F.

[0206] The reduced library was then screened in scanning mass spectrometer (“SMS”) for WGS activity with a H2/CO/CO2/H2O mixed feed at 250° C., 300° C., 350° C., and 400° C. This set of experiments demonstrated active and selective WGS catalyst formulations of Pt with various metals on TiO2 support.

Example 2

[0207] A 3″ quartz wafer was precoated with TiO2, CeO2 and ZrO2 carriers by slurry dispensing (Degussa Aerolyst 7711/Degussa P25 70:30 titania mix), (Aldrich ceria 21,157-5) and (Norton XZ16052/MEI FZO923 70:30 zirconia mix) onto the wafer.

[0208] The carrier-precoated wafer was dried and then impregnated with Ru, Ce, Fe gradients. The Ru, Ce, Fe gradients were premixed in a microtiter plate by dilution of Ru nitrosyl nitrate stock solution (1.5% Ru), Ce nitrate stock solution (1M Ce) and Fe nitrate stock solution (1M Fe) with water and transferred from the microtiter plate to the wafer by Cavro dispensing (3 μl dispense volume per well). The wafer was dried and then impregnated with Ti gradients. The Ti gradients were premixed in a microtiter plate by dilution of ammonium titanyl oxalate stock solution (1M Ti) with water and then transferred from the microtiter plate to the wafer by Cavro dispensing (3 μl dispense volume per well). The wafer was dried and then impregnated with Pt gradients. The Pt gradients were premixed in a microtiter plate by dilution of Pt(NH3)2(NO2)2 stock solution (5% Pt) with water and then transferred from the microtiter plate to the wafer by Cavro dispensing (3 μl dispense volume per well). The wafer was dried, calcined in air at 500° C. for 1 hour and then reduced in 5% H2/Ar at 300° C. for 4 hours. See FIGS. 2A-2E.

[0209] The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H2O mixed feed at 250° C., 300° C., 350° C., and 400° C. This set of experiments demonstrated active and selective WGS catalyst formulations of Pt—Ce—Fe containing formulations on ZrO2 and TiO2 supports.

Example 3

[0210] A 4″ quartz wafer was precoated with zirconia carrier by repeated slurry dispensing zirconia (ZrO2 Norton XZ16052/MEI FZO923 70:30 mixture, 2×4 μl for a total of 8 μl zirconia slurry, 1 g ZrO2 mix slurried in 4 ml EG/H2O 1:1) onto the wafer.

[0211] The zirconia carrier-precoated wafer was dried and then impregnated with Pt by Cavro dispensing from a Pt(NH3)2(NO2)2 stock solution vial (2.5% Pt) directly onto the wafer by 3 μl dispense volume/well. Six internal standards were spotted into 6 first row/last column wells (4 μl zirconia slurry+3 μl 2.5% Pt solution). The wafer was dried for 10 minutes at 70

[0212] The wafer was then impregnated with Co—Ru and Ru—Pt gradients by Cavro dispensing from Co nitrate (0.5M Co), Ru nitrosyl nitrate (1% Ru) and Pt(NH3)2(NO2)2 (5% Pt) stock solution vials to a microtiter plate followed by transferring replicas of the 8-point and 7-point gradients onto the wafer at 3 μl dispense volume/well. The wafer was dried and then impregnated with FeCo by Cavro dispensing from Fe nitrate (1M Fe) and Co nitrate (0.5M Co) stock solution vials to a microtiter plate (8-point and 7-point gradients) followed by transferring replicas of the Fe—H2O and Fe—Co gradients onto the wafer, 3 μl dispense volume per well. The wafer was dried and then impregnated with Pt by Cavro dispensing from a Pt(NH3)2(NO2)2 stock solution vial (2.5% Pt) directly onto the wafer by 3 μl dispense volume/well.

[0213] Thus four sub-libraries: 8×8 quaternary PtRuCoFe (Pt first) and 8×7 quaternary PtRuCoFe (Pt last, to check the effect of order of Pt addition) and 7×8 ternary RuCoFe and 7×7 quaternary PtRuCoFe are mapped out as rectangles/squares with orthogonal gradients. The wafer was dried, calcined in air at 500° C. for 1 hour and then reduced in 5% H2/Ar at 400° C. for 3 hours. A commercial catalyst was slurried into 5 positions of the first row and last column as external standards (3 μl catalyst slurry). See FIGS. 3A-3G.

[0214] The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H2O mixed feed at 250° C., 300° C., 350° C., and 400° C. This set of experiments demonstrated active and selective WGS catalyst formulations of Pt—Ru—Co—Fe and Pt-free Ru—Co—Fe compositions.

Example 4

[0215] A 4″ quartz wafer was precoated with ZrO2 carrier by slurry dispensing 3 μl of mixed zirconia powder slurry (Norton ZrO2 XZ16052/MEI ZrO2 FZO923 70:30, 1.5 g ZrO2/4 ml MEO/EG/H2O 50:25:25).

[0216] The zirconia carrier precoated wafer was impregnated with {Sc, Y, La, Ce} gradients by Cavro dispensing from Sc, Y, La, Ce nitrate stock solution vials to a microtiter plate (single column 7-point and 8-point gradients) followed by transferring replicas of the four 7P and 8P columns onto the wafer (2.5 μl dispense volume per well, 8 replicas of the 7PCs and 7 replicas of the 8PCs). Six internal standards were also synthesized by spotting 3 μl of a Pt(NH3)2(NO2)2 stock solution (2.5% Pt) into the corresponding first row/last column positions. The wafer was slowly dried at room temperature and then impregnated with Ru gradient by Cavro dispensing from Ru nitrosyl nitrate stock solution vial to microtiter plate (single row 8-point and 7-point gradients; water vial in Pt position) followed by transferring replicas of the 7P and 8P row onto the wafer (2.5 μl dispense volume per well, 16 replicas of the 7PR gradient and 14 replicas of the 8PR gradient, 7×8=56 point ternaries, four 56PT on the wafer). The wafer was slowly dried at room temperature and then impregnated with Pt gradient by Cavro dispensing from Pt(NH3)2(NO2)2 stock solution vial to microtiter plate (single row 8-point and 7-point gradients; water vial in Ru position) followed by transferring replicas of the 7P and 8P row onto the wafer (2.5 μl dispense volume per well, 16 replicas of the 7PR gradient and 14 replicas of the 8PR gradient, 7×8=56 point ternaries, four 56PT on the wafer). The wafer was dried and then calcined in air at 500° C. for 1 hour followed by reduction with 5% H2/N2 at 400° C. for 2 hours. Commercial catalyst was slurried into 5 positions of the first row and last column as external standards (3 μl catalyst slurry/well). See FIGS. 4A-4G.

[0217] The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H2O mixed feed at 250° C., 300° C. and 350° C. This set of experiments demonstrated active and selective WGS catalyst formulations of Pt—Ru—{La, Ce} at MTS and HTS reaction conditions.

Example 5

[0218] A 4″ quartz wafer was precoated with ZrO2 carrier by slurry dispensing 3 μl of mixed zirconia powder slurry (Norton ZrO2 XZ16052/MEI ZrO2 FZO923 70:30, 1.5 g ZrO2/4 ml MEO/EG/H2O 50:25:25).

[0219] The zirconia carrier precoated wafer was impregnated with Co gradients by Cavro dispensing from Co nitrate stock solution vial to microtiter plate (single column 7-point and 8-point Co gradients) followed by transferring replicas of the 7P and 8P column onto the wafer (2.5 μl dispense volume per well, 16 replicas of the 7PC and 14 replicas of the 8PC). The wafer was slowly dried at room temperature and then impregnated with Ru gradients by Cavro dispensing from Ru nitrosyl nitrate stock solution vial to microtiter plate (single row 8-point and 7-point Ru gradients) followed by transferring replicas of the 7P and 8P row onto the wafer (2.5 μl dispense volume per well, 16 replicas of the 7PR gradient and 14 replicas of the 8PR gradient, 7×8=56 point ternaries, four 56PT on the wafer). Six internal standards were also synthesized by spotting 3 μl of Pt(NH3)2(NO2)2 stock solution (2.5% Pt) into the corresponding first row/last column positions. The wafer was slowly dried at room temperature and then impregnated with K by Cavro dispensing 2.5 μl/well from 0.2M KNO3 tock solution vial directly onto the lower half of the wafer. The wafer was dried and then impregnated with Pt by Cavro dispensing 2.5 μl/well from Pt(NH3)2(NO2)2 stock solution vials directly onto the wafer (left hand side of wafer uniformly impregnated with 1% Pt solution and right hand side uniformly impregnated with 2% Pt solution). The wafer was slowly dried at room temperature, calcined in air at 450° C. for 2 hours and then reduced in a flow of 5% H2/N2 at 400° C. for 2 hours. Commercial catalyst was slurried into 5 positions of the first row and last column as external standards (3 μl catalyst slurry/well). See FIGS. 5A-5H.

[0220] The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H2O mixed feed at 250° C., 300° C. and 350° C. This set of experiments demonstrated active and selective WGS catalyst formulations of Pt—Ru—Co compositions.

Example 6

[0221] A 3″ quartz wafer was coated with niobia, ceria and magnesia carriers by slurry-dispensing aqueous carrier slurries onto the wafer (4 μl slurry/well, 1 g of carrier powder slurried in 2 ml H2O for niobia and ceria; 500 mg of carrier powder slurried in 2 ml H2O for magnesia). Niobia carriers were produced by Norton, product numbers 2001250214, 2000250356, 2000250355, 2000250354 and 2000250351. Cerias came from Norton (product numbers 2001080053, 2001080052 and 2001080051) and Aldrich (product number 21,157-50. Magnesia was obtained from Aldrich (product number 24,338-8).

[0222] The carrier precoated wafer was then loaded with the same Pt gradient for each carrier in a single impregnation step by liquid dispensing 3 μl Pt(NH3)2(NO2)2 solution (5% Pt) from microtiter plate to wafer. The wafer was dried and then reduced in 5% H2/Ar at 450° C. for 2 hours. See FIGS. 6A through 6C.

[0223] The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H2O mixed feed at 250° C., 300° C., 350° C., and 400° C. Results at 250° C., 300° C., 350° C., and 400° C. are presented in FIGS. 6D through 6H.

[0224] This set of experiments demonstrated active and selective WGS catalyst formulations of various Pt on one of Nb oxide, Ce oxide or Mg oxide formulations on the wafer. Various Norton niobia carriers were found to be very active and selective over a broad temperature range. Norton ceria 2001080051 was found to be very selective at higher temperatures. Magnesia was less active than either of niobia or ceria but did exhibit highly selective WGS performance.

Example 7

[0225] A 4″ quartz wafer was coated with fourteen different catalyst carriers by slurry-dispensing the carrier slurries onto the wafer. Each wafer column was coated with a different carrier, except for columns 14 and 15 which were both coated with gamma-alumina, described below:

[0226] Ceria, 99.5% purity; 9 to 15 nm particle size; BET (m2/g): 55-95; Alfa 43136; dispensed onto the wafer from a slurry of 0.75 g powder slurried in 4 mL ethylene glycol (“EG”)/H2O/MEO 40:30:30 mixture.

[0227] Ceria, produced by the low temperature calcination of precipitated Ce hydroxide; dispensed onto the wafer from a slurry of 1.5 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0228] Zirconia; 99.8% purity; BET (m2/g): greater than 90; Norton XZ16052; dispensed onto the wafer from a slurry of 1.5 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0229] Zirconia; 99.8% purity; BET (m2/g): 269; Norton XZ16154; dispensed onto the wafer from a slurry of 1.5 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0230] Titania; BET (m2/g): 45; Degussa Aerolyst 7708; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0231] Titania; 99% purity; BET (m2/g): 37; Norton XT25384; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0232] Niobia; 97% purity; BET (m2/g): 27; Norton 355; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0233] Lanthania; 99.999% purity; Gemre-5N from Gemch Co., Ltd. (Shanghai, China); dispensed onto the wafer from a slurry of 1.5 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0234] Mixed Fe—Ce—O; coprecipitated Fe and Ce oxalate; calcined at 360° C.; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0235] Mixed La—Ce—O; coprecipitated La and Ce oxalate; calcined at 760° C.; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0236] Mixed Sb3O4—SnO2 carrier from Alfa; 99.5% purity; BET (m2/g): 30-80; Sb3O4:SnO2 ratio is 10:90 by weight; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0237] Mixed Fe—Cr—Al—O; commercially available high temperature water gas shift catalyst; dispensed onto the wafer from a slurry of 1.0 powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0238] Fe2O3/FeOOH; BET (m2/g): 14; 50:50 physical mixture of commercial powders (Bayferrox 720N: Bayoxide E3920 from Bayer); dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0239] 14 and 15) Gamma-Al2O3; BET (m2/g): 150; Condea Catalox Sba150; dispensed onto the wafer from a slurry of 1.0 g powder slurried in 4 mL EG/H2O/MEO 40:30:30 mixture.

[0240] In all cases, except for carrier 1, the slurries were applied in 3 μL per well; carrier 1 was deposited as two aliquots of 3 μl/well. The wafer was then dried at 70° C. for 10 minutes.

[0241] Columns 14 and 15 were coated with 2.5 L per well of zirconyl nitrate (0.25M) and lanthanum nitrate (0.25M), respectively, then dried for 10 minutes at 70° C. The first 13 columns of the carrier coated wafer were then loaded with a 15 point Pt gradient by liquid dispensing of 3 μL Pt(NH3)2(NO2)2 solution (1% Pt) from microtiter plate to wafer. The wafer was dried at 70° C. for 10 minutes. Columns 14 and 15 were then loaded with a 15 point Pt gradient by liquid dispensing of 3 μL Pt(NH3)2(NO2)2 solution (1% Pt) from microtiter plate to wafer. The wafer was dried at 70° C. for 10 minutes, calcined in air at 350° C. for 2 hours, then reduced in 5% H2/Ar at 450° C. for 2 hours. Six internal standards were synthesized by spotting 3 μL Pt(NH3)2(NO2)2 solution (1.0% Pt) into the corresponding first row/last column positions. See FIGS. 7A through 7F.

[0242] The reduced library was then screened in SMS for WGS activity with a H21CO/CO2/H2O mixed feed at 250° C. and 300° C. The CO conversion versus CO2 production results at 250° C. and 300° C. are presented in FIGS. 7G, 7H and 71. More detailed test results, such as, CO conversion, CO2 production and CH4 production at 250° C. and 300° C. for each of the 225 individual catalyst wells on the test wafer are presented in Table 1.

[0243] This set of experiments demonstrated active and selective WGS catalyst formulations of various Pt on various of the oxide carrier formulations on the wafer.

Example 8

[0244] A 4″ quartz wafer was precoated with zirconia carrier by repeated slurry dispensing zirconia powder (Norton XZ16052) onto the wafer. The slurry was composed of 1.5 g zirconia powder in 4 mL of a MEO/EG/H2O 40:30:30 mixture. A total of 3 μL of slurry was deposited on each spot.

[0245] The zirconia carrier precoated wafer was impregnated with concentration gradients of Ru—Co, Ru—Ce, Ru—La and Ru—La solution by Cavro dispensing from metal stock solutions vials to a microtiter plate followed by transferring replicas of the 8 col.×7P, 7 col.×8P, 8 col.×7P, and 7 col.×8P gradients, respectively, onto the wafer (2.5 μl dispense volume per well). Co, Ce and La were provided as their nitrates, Zr as the zirconyl nitrate and Ru as the nitrosyl nitrate. The wafer was dried at 70° C. for 10 minutes and then was uniformly coated with 2.5 μl/well of a Pt(NH3)2(NO2)2 stock solution (1% Pt).

[0246] The wafer was dried at 70° C. for 10 minutes, calcined in air at 350° C. for 2 hours, then reduced in 5% H2/Ar at 300° C. for 2 hours. Seven internal standards were synthesized by spotting 2.5 μl Pt(NH3)2(NO2)2 solution (1.0% Pt) into the corresponding first row/last column and center positions. See FIGS. 8A through 8E.

[0247] The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H2O mixed feed at 300° C. The CO conversion versus CO2 production results at 300° C. are presented in FIG. 8F. More detailed test results, such as, CO conversion, CO2 production and CH4 production at 300° C. for each of the 225 individual catalyst wells on the test wafer are presented in Table 2.

[0248] This set of experiments demonstrated active and selective WGS catalyst formulations of Pt—Ru—{Co, Ce, La, Zr} compositions on the wafer.

Example 9

[0249] A 4″ quartz wafer was precoated with zirconia carrier by repeated slurry dispensing zirconia powder (Norton XZ16052) onto the wafer. The slurry was composed of 1.5 g zirconia powder in 4 mL of a MEO/EG/H2O 40:30:30 mixture. A total of 3 μL of slurry was deposited on each spot.

[0250] The zirconia carrier precoated wafer was impregnated with concentration gradients of Ti, Zr, Fe and La solution by Cavro dispensing from metal stock solutions vials to a microtiter plate followed by transferring replicas of the 8P Ti, 7P Zr, 8P Fe and 7P La gradients, respectively, onto the wafer (2.5 μl dispense volume per well). Fe and La were provided as their nitrates, Zr as the zirconyl nitrate and Ti as the ammonium titanyl oxalate. The wafer was dried at 70° C. for 10 minutes and then a 7P and 8P×2 gradient of Ru, as the nitrosyl nitrate was transferred from a microtiter plate to the wafer (2.5 μl dispense volume/well.) The wafer was dried at 70° C. for 10 minutes and then was uniformly coated with 2.5 μl/well of a Pt(NH3)2(NO2)2 stock solution (1% Pt).

[0251] The wafer was dried at 70° C. for 10 minutes, calcined in air at 450° C. for 2 hours, then reduced in 5% H2/Ar at 450° C. for 2 hours. Seven internal standards were synthesized by spotting 2.5 μl Pt(NH3)2(NO2)2 solution (1.0% Pt) into the corresponding first row/last column and center positions. See FIGS. 9A through 9G.

[0252] The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H2O mixed feed at 250° C. and 300° C. The CO conversion versus CO2 production results at 350° C. are presented in FIG. 9H. More detailed test results, such as, CO conversion, CO2 production and CH4 production at 350° C. for each of the 225 individual catalyst wells on the test wafer are presented in Table 3.

[0253] This set of experiments demonstrated active and selective WGS catalyst formulations of Pt—Ru—{Ti, Zr, Ti, Fe} compositions on the wafer.

Example 10

[0254] A 4″ quartz wafer was precoated with zirconia carrier by repeated slurry dispensing zirconia powder (Norton XZ16052) onto the wafer. The slurry was composed of 1.5 g zirconia powder in 4 mL of a MEO/EG/H2O 40:30:30 mixture. A total of 3 μL of slurry was deposited on each spot.

[0255] The zirconia carrier precoated wafer was impregnated with 7P concentration gradients of Ti, Zr, V, Mo and Co and 8P concentration gradients of Ge, Sn, Sb, La and Ce by Cavro dispensing from metal stock solutions vials to a microtiter plate followed by transferring replicas of the gradients onto the wafer (2.5 μl dispense volume per well). Co, La and Ce were provided as their nitrates, Zr as the zirconyl nitrate, Ti as the ammonium titanyl oxalate, Sb as ammonium antimony oxalate, V, Ge and Sn as their oxalates and Mo as molybdic acid. The wafer was dried at 70° C. for 10 minutes and then a 7 and 8 point gradients of Fe, Ru and Rh were transferred from a microtiter plate to the wafer (2.5 μl dispense volume/well.) Fe and Rh were provided as their nitrates, Ru as the nitrosyl nitrate. The wafer was dried at 70° C. for 10 minutes and then was uniformly coated with 2.5 μl/well of a Pt(NH3)2(NO2)2 stock solution (1% Pt).

[0256] The wafer was dried at 70° C. for 10 minutes, calcined in air at 450° C. for 2 hours, then reduced in 5% H2/Ar at 450° C. for 2 hours. Nine internal standards were synthesized by spotting 2.5 μl Pt(NH3)2(NO2)2 solution (1.0% Pt) into the corresponding first row/last column positions. See FIGS. 10A through 10F.

[0257] The reduced library was then screened in SMS for WGS activity with a H2/CO/CO2/H2O mixed feed at 300° C. and 350° C. The CO conversion versus CO2 production results at 300° C. and 350° C. are presented in FIGS. 10G, 10H and 101. More detailed test results, such as, CO conversion, CO2 production and CH4 production at 250° C. and 300° C. for each of the 225 individual catalyst wells on the test wafer are presented in Table 4.

[0258] This set of experiments demonstrated active and selective WGS catalyst formulations of Pt—Ru—{Ti, Zr, V, Mo, Co, Ge, Sn, Sb, La, Ce} compositions on the wafer.

Example 11

[0259] A 4″ quartz wafer was precoated with zirconia carrier by repeated slurry dispensing zirconia powder (Norton XZ16052) onto the wafer. The slurry was composed of 1.5 g zirconia powder in 4 mL of a MEO/EG/H2O 40:30:30 mixture. A total of 3 μL of slurry was deposited on each spot.

[0260] The zirconia carrier precoated wafer was impregnated with 5P concentration gradients of Co, Ru and Mo by Cavro dispensing from metal stock solutions vials to a microtiter plate followed by transferring replicas of the gradients onto the wafer (2.5 μl dispense volume per well). Co was provided as its nitrate, Mo as molybdic acid and Ru as the nitrosyl nitrate. The wafer was dried at 70° C. for 10 minutes.

[0261] The wafer was then impregnated with 5P concentration gradients of Ce, Co, Ru, La, Zr, Cu, Re and Ge. Ce was provided as its nitrate and as ammonium cerium(IV) nitrate; Co as its acetate and as sodium hexanitrocobaltate(III); Ru as potassium perruthenate, KRuO4, ruthenium nitrosyl acetate, Ru(NO)(OAc)3; La and Cu as their nitrates; Zr as zirconyl nitrate and zirconyl acetate; Re as NH4ReO4; and Ge as the oxalate.

[0262] The wafer was dried at 70° C. for 10 minutes and then was uniformly coated with 2.5 μl/well of a Pt(NH3)2(NO2)2 stock solution (1% Pt).

[0263] The wafer was dried at 70° C. for 10 minutes, calcined in air at 350° C. for 2 hours, then reduced in 5% H2/Ar at 300° C. for 2 hours. Nine internal standards were synthesized by spotting 2.5 μl Pt(NH3)2(NO2)2 solution (1.0% Pt) into the corresponding first row/last column positions. See FIGS. 11A through 11F.

[0264] The reduced library was then screened in SMS for WGS activity with a H21CO/CO2/H2O mixed feed at 250° C. The CO conversion versus CO2 production results at 250° C. are presented in FIG. 11G. More detailed test results, such as, CO conversion, CO2 production and CH4 production at 250° C. for each of the 225 individual catalyst wells on the test wafer are presented in Table 5.

[0265] This set of experiments demonstrated active and selective WGS catalyst formulations of Pt—Ru—{Co, Ce, Mo, Na, K, La, Zr, Re, Cu, Ge} compositions on the wafer.

Example 12

[0266] Scale-up catalyst samples were prepared by using incipient wetness impregnation of 2.5 grams of ZrO2 support (Norton, 80-120 mesh) which had been weighed into a 10-dram vial. Aqueous metal precursor salt solutions were then added in the order Ru, Co, Pt and Na. The precursor salt solutions are set forth in Table 7. Following each metal addition, the catalysts were dried at 80° C. overnight and then calcined in air as follows:

[0267] After Ru or Co addition—450° C. for 3 hours

[0268] After Pt addition—300° C. for 3 hours.

[0269] Following Na addition, the catalysts were calcined at 300° C. for 3 hours, and then the catalysts were reduced in-situ at 300° C. for 3 hours in a 10% H2/N2 feed.

1TABLE 6Catalyst compositionsCatalyst ID% Ru% Co% Pt% Na1001-010.50.5651001-020.51651001-030.51.5651001-0410.5651001-0511651001-0611.5651001-071.50.5651001-081.51651001-091.51.5651001-1011601001-1111351001-121167.51001-1301601001-140165

[0270]

2

TABLE 7

Metal precursors

Precursor
Concentration

Ru(NO)(NO3)3
1.5%
Ru w/w

Co(NO3)2
1
Molar

Pt(NH3)4(OH)2
9.06%
Pt w/w

NaOH
3
Molar

[0271] Catalyst Testing Conditions

[0272] Catalysts were tested in a fixed bed reactor. Approximately 0.15 g of catalyst was weighed and mixed with an equivalent mass of SiC. The mixture was loaded into a reactor and heated to reaction temperature. Reaction gases were delivered via mass flow controllers (Brooks) with water introduced with a metering pump (Quizix). The composition of the reaction mixture was as follows: H2 50%, CO 10%, CO2 10%, and H2O 30%. The reactant mixture was passed through a pre-heater before contacting the catalyst bed. Following reaction, the product gases were analyzed using a micro gas chromatograph (Varian). Compositional data on the space velocity diagrams are on a dry basis with water removed.

[0273] Testing Results

[0274]
FIGS. 12A through 12C show the CO composition in the product stream following the scale-up testing at gas hour space velocities of 50,000, 100,000 and 150,000 h−1. All materials showed WGS activity at the tested temperatures and space velocities as shown. Selectivies were all greater than 99% to CO2 with the exception of catalyst sample 1001-8 (selectivity of 98.5% to CO2 at GHSV=50,000 at 325° C.).

Example 13

[0275] Scale-up catalyst samples were prepared by using incipient wetness impregnation of 0.75 grams of ZrO2 support (Norton, 80-120 mesh) which had been weighed into a 10-dram vial. Aqueous metal precursor salt solutions were then added in the order Ru, Pt and one of Na, K, or Li. The precursor salt solutions were tetraammineplatinum (II) hydroxide (9.09% Pt (w/w)), ruthenium (III) nitrosylnitrate (1.5% Ru (w/v)), sodium hydroxide (3.0N), lithium hydroxide monohydrate (2.5M), and potassium hydroxide (13.92% K). All reagents were nominally research grade from Aldrich, Strem, or Alfa. Following each metal addition, the catalysts were dried at 80° C. overnight and then calcined in air as follows:

[0276] After Ru addition—450° C. for 3 hours

[0277] After Pt addition—300° C. for 3 hours

[0278] Following Na, K, or Li addition, the catalysts were calcined at 300° C. for 3 hours, and then the catalysts were reduced in-situ at 300° C. for 3 hours in a 10% H2/N2 feed.

[0279] Catalyst Testing Conditions

[0280] Catalysts were tested in a fixed bed reactor. Approximately 0.15 g of catalyst was weighed and mixed with an equivalent mass of SiC. The mixture was loaded into a reactor and heated to reaction temperature. Reaction gases were delivered via mass flow controllers (Brooks) with water introduced with a metering pump (Quizix). The composition of the reaction mixture was as follows: H2 50%, CO 10%, CO2 10%, and H2O 30%. The reactant mixture was passed through a pre-heater before contacting the catalyst bed. Following reaction, the product gases were analyzed using a micro gas chromatograph (Varian Instruments, or Shimadzu). Compositional data on the performance diagram (FIG. 13) is on a dry basis with water removed.

[0281] Testing Results

[0282]
FIG. 13 shows the CO composition in the product stream following the scale-up testing at gas hour space velocities of 50,000 h−1.

3TABLE 8Catalyst Composition (mass ratio)RowColSupportRuPtNaKLiA10.9050.010.060.02500A20.880.010.060.0500A30.9050.010.0600.0250A40.880.010.0600.050A50.9050.010.06000.025A60.880.010.06000.05B10.9050.010.060.02500B20.880.010.060.0500B30.9050.010.0600.0250B40.880.010.0600.050B50.9050.010.06000.025B60.880.010.06000.05C10.8950.020.060.02500C20.870.020.060.0500C30.8950.020.0600.0250C40.870.020.0600.050C50.8950.020.06000.025C60.870.020.06000.05D10.8950.020.060.02500D20.870.020.060.0500D30.8950.020.0600.0250D40.870.020.0600.050D50.8950.020.06000.025D60.870.020.06000.05

Example 14

[0283] Scale-up catalyst samples were prepared by using incipient wetness impregnation of 0.75 grams of ZrO2 support (Norton, 80-120 mesh) which had been weighed into a 10-dram vial. Aqueous metal precursor salt solutions were then added in the order: Ru, one of Y, Sc, or La, and Pt. The precursor salt solutions were tetraammineplatimum (II) hydroxide (9.09% Pt (w/w)), ruthenium (III) nitrosylnitrate (1.5% Ru), yttrium (III) nitrate (1.0M), scandium (III) nitrate (4.2% Sc), lanthanum (III) nitrate (1.0M), and potassium hydroxide (13.92% K). All reagents were nominally research grade from Aldrich, Strem, or Alfa. Following each metal addition, the catalysts were dried at 80° C. overnight and then calcined in air-as follows:

4After Ru addition450° C. for 3 hoursAfter Pt addition300° C. for 3 hoursAfter Y, Sc, or La addition450° C. for 3 hours.

[0284] Following the final addition, the catalysts were reduced in-situ at 300° C. for 3 hours in a 10% H2/N2 feed.

[0285] Catalyst Testing Conditions

[0286] Catalysts were tested in a fixed bed reactor. Approximately 0.15 g of catalyst was weighed and mixed with an equivalent mass of SiC. The mixture was loaded into a reactor and heated to reaction temperature. Reaction gases were delivered via mass flow controllers (Brooks) with water introduced with a metering pump (Quizix). The composition of the reaction mixture was as follows: H2 50%, CO 10%, CO2 10%, and H2O 30%. The reactant mixture was passed through a pre-heater before contacting the catalyst bed. Following reaction, the product gases were analyzed using a micro gas chromatograph (Varian Instruments, or Shimadzu). Compositional data on the performance diagram (FIG. 14) is on a dry basis with water removed.

[0287] Testing Results

[0288]
FIG. 14 shows the CO composition in the product stream following the scale-up testing at gas hour space velocities of 50,000 h−1.

5TABLE 9Catalyst Composition (mass ratio)RowColSupportRuPtYScLaA10.9050.010.060.02500A20.880.010.060.0500A30.9050.010.0600.0250A40.880.010.0600.050A50.9050.010.06000.025A60.880.010.06000.05B10.9050.010.060.02500B20.880.010.060.0500B30.9050.010.0600.0250B40.880.010.0600.050B50.9050.010.06000.025B60.880.010.06000.05C10.8950.020.060.02500C20.870.020.060.0500C30.8950.020.0600.0250C40.870.020.0600.050C50.8950.020.06000.025C60.870.020.06000.05D10.8950.020.060.02500D20.870.020.060.0500D30.8950.020.0600.0250D40.870.020.0600.050D50.8950.020.06000.025D60.870.020.06000.05

Example 15

[0289] Scale-up catalyst samples were prepared by using incipient wetness impregnation of 0.75 grams of ZrO2 support (Norton, 80-120 mesh) which had been weighed into a 10-dram vial. Aqueous metal precursor salt solutions were then added in the order: Ru, V, Pt, and finally Na. The precursor salt solutions were tetraammineplatinum (II) hydroxide solution (9.09% Pt (w/w)), ruthenium (III) nitrosylnitrate (1.5% Ru (w/v), vanadium citrate (1.0M), and sodium hydroxide (3.0 N). All starting reagents were nominally research grade from Aldrich, Strem, or Alfa. Following each metal addition, the catalysts were dried at 80° C. overnight and then calcined in air as follows:

6After Pt addition300° C. for 3 hoursAfter Ru addition450° C. for 3 hoursAfter V addition350° C. for 3 hours.

[0290] Following Na addition, the catalysts were calcined at 300° C. for 3 hours, and then the catalysts were reduced in-situ at 300° C. for 3 hours in a 10% H2/N2 feed.

[0291] Catalyst Testing Conditions

[0292] Catalysts were tested in a fixed bed reactor. Approximately 0.15 g of catalyst was weighed and mixed with an equivalent mass of SiC. The mixture was loaded into a reactor and heated to reaction temperature. Reaction gases were delivered via mass flow controllers (Brooks) with water introduced with a metering pump (Quizix). The composition of the reaction mixture was as follows: H2 50%, CO 10%, CO2 10%, and H2O 30%. The reactant mixture was passed through a pre-heater before contacting the catalyst bed. Following reaction, the product gases were analyzed using a micro gas chromatograph (Varian Instruments, or Shimadzu). Compositional data on the performance diagram (FIG. 17) is on a dry basis with water removed.

[0293] Testing Results

[0294]
FIG. 17 shows the CO composition in the product stream following the scale-up testing at a gas hour space velocity of 50,000 h−1.

7TABLE 10Catalyst Compositions (mass ratio)Cat IDSupportPtRuVNa1006−0191.036.000.250.222.501006−0290.816.000.250.432.501006−0390.376.010.250.872.501006−0488.536.000.250.225.001006−0588.316.000.250.435.001006−0687.876.010.250.875.011006−0786.036.000.250.227.501006−0885.816.000.250.437.511006−0985.376.010.250.877.511006−1090.786.000.500.222.501006−1188.286.000.500.225.001006−1285.786.000.500.227.50

[0295]

8

TABLE I

Tem-

pera-

ture:

250 C.

Pt1.0%/

R
C
COCONV
H2OCONV
CO2PROD
CO2PERPROD
CH4PROD
Zr 02_std
LaNO33

real
real
real
real
real
real
real
real
real

1
1
24.0554
20.3567
1.0059
36.8713
0.1785
0.1275
0

1
2
−1.7201
3.3539
0.049
1.7972
0.0067
0
0

1
3
−1.3278
2.2499
0.0009
0.0315
−0.0026
0
0

1
4
−1.208
2.4958
0.005
0.1823
−0.0038
0
0

1
5
−1.3966
−0.6647
0.0138
0.5067
−0.0024
0
0

1
6
−0.857
−0.806
0.0089
0.3249
−0.0058
0
0

1
7
26.8747
16.7142
0.9416
34.513
0.151
0.1275
0

1
8
−0.1762
0.0001
0.0106
0.3868
−0.0076
0
0

1
9
−0.605
−1.4054
0.0016
0.0598
−0.0081
0
0

1
10
−0.1705
5.1803
−0.0005
−0.0171
−0.0108
0
0

1
11
0.0287
−2.3403
−0.0261
−0.9568
−0.0134
0
0

1
12
−0.3619
−2.3753
−0.0191
−0.6997
−0.0107
0
0

1
13
26.9134
15.6985
0.9206
33.7449
0.1456
0.1275
0

1
14
0.2866
−1.4436
0.0104
0.3794
−0.0009
0
0

1
15
−0.2691
−2.5021
−0.0098
−0.3592
−0.0125
0
0

1
16
26.3015
15.0776
0.9071
33.2485
0.1422
0.1275
0

2
1
10.3797
7.5635
0.2714
9.9469
0.0465
0
0

2
2
22.2742
13.6256
0.7038
25.7961
0.1014
0
0

2
3
20.1518
11.8043
0.6181
22.6557
0.0925
0
0

2
4
14.7068
7.5278
0.4396
16.1127
0.074
0
0

2
5
12.5748
6.9812
0.3538
12.9691
0.0619
0
0

2
6
12.5733
7.5902
0.3721
13.6375
0.065
0
0

2
7
3.9682
1.1157
0.1053
3.861
0.0291
0
0

2
8
4.2902
1.5276
0.1017
3.728
0.0316
0
0

2
9
17.5859
9.8527
0.5611
20.5685
0.0868
0
0

2
10
4.0056
0.7967
0.1073
3.9343
0.0337
0
0

2
11
0.4511
−1.4852
−0.0262
−0.9611
0.0142
0
0

2
12
8.7515
3.1358
0.2704
9.9096
0.0534
0
0

2
13
1.1667
−0.4291
0.0028
0.1022
0.0172
0
0

2
14
5.3788
3.039
0.1661
6.0891
0.0402
0
0

2
15
13.8175
7.9862
0.4538
16.6329
0.0753
0
0.625

2
16
0.5892
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3
1
23.0341
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0

3
2
24.8268
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0

3
3
21.0312
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24.2545
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0
0

3
4
15.3062
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0

3
5
13.1818
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0

3
6
14.4778
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0

3
7
5.5717
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0

3
8
6.8228
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0

3
9
18.2423
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3
10
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0

3
11
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3
12
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3
13
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3
14
6.7207
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3
15
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3
16
1.6968
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0
0

4
1
25.6701
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0

4
2
23.653
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0

4
3
22.8118
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4
4
16.4182
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0

4
5
14.5564
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0

4
5
15.7933
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0

4
7
6.1716
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0

4
8
7.1386
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0
0

4
9
20.7303
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0

4
10
8.9131
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4
11
1.6189
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4
12
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4
13
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4
14
6.4031
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0

4
15
15.6125
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0.625

4
16
27.9195
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0

5
1
23.5648
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0

5
2
24.3053
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0
0

5
3
22.341
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0

5
4
17.6158
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0

5
5
14.2387
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0
0

5
6
15.1152
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0

5
7
6.2094
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0

5
8
7.6993
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0

5
9
20.3032
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0

5
10
10.467
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0

5
11
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0

5
12
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0

5
13
2.4786
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0

5
14
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0

5
15
11.8585
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0
0.625

5
16
0.172
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0
0

6
1
22.8548
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0
0

6
2
25.4205
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0
0

6
3
25.0359
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0
0

6
4
19.8242
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0
0

6
5
15.5667
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0
0

6
6
14.9248
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0
0

6
7
6.2748
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0
0

6
8
8.4858
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0
0

6
9
21.0027
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0

6
10
4.1864
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0
0

6
11
−1.2373
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5
12
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0

6
13
1.0716
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0

6
14
6.6959
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0

6
15
14.9263
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0.625

6
16
0.9734
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0
0

7
1
22.5418
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0
0

7
2
25.3352
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0
0

7
3
25.4575
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0
0

7
4
20.6572
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0
0

7
5
15.932
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0
0

7
6
15.7862
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0
0

7
7
6.5518
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0
0

7
8
8.798
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0
0

7
9
23.0075
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0
0

7
10
9.2334
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0

7
11
0.7033
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0
0

7
12
9.8812
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0
0

7
13
1.8315
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0
0

7
14
5.9233
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0
0

7
15
11.3981
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0
0.625

7
16
26.5669
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0.1275
0

8
1
22.7201
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25.4388
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0
0

8
2
25.5968
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0
0

8
3
26.9015
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0
0

8
4
22.6912
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0
0

8
5
16.1513
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0
0

8
6
14.9604
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0
0

8
7
9.1106
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0
0

8
8
11.6445
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0
0

8
9
22.1496
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0
0

8
10
10.7574
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0
0

8
11
3.6004
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0
0

8
12
11.534
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0
0

8
13
1.3464
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0
0

8
14
6.4094
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0
0

8
15
12.8137
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0
0.625

8
16
0.6005
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0
0

9
1
22.4957
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0
0

9
2
25.986
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0
0

9
3
26.7278
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0
0

9
4
21.7825
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0
0

9
5
17.2508
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0
0

9
6
16.9581
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0
0

9
7
6.3335
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0
0

9
8
11.9448
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0
0

9
9
22.3682
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0

9
10
10.6395
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0

9
11
0.7463
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0

9
12
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0

9
13
2.2734
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0

9
14
5.2473
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0

9
15
14.1744
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0
0.625

9
16
1.1167
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0
0

10
1
21.0706
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0
0

10
2
26.8869
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0

10
3
26.6813
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0
0

10
4
22.8526
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0
0

10
5
16.4643
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0
0

10
6
16.974
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0
0

10
7
7.0764
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0
0

10
8
10.3301
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0
0

10
9
22.9265
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0

10
10
12.4677
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0
0

10
11
0.5969
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0

10
12
13.3324
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0
0

10
13
1.9031
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0

10
14
6.4847
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0
0

10
15
13.3979
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0
0.625

10
16
25.4495
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0

11
1
20.1375
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0
0

11
2
27.139
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0

11
3
26.9388
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0

11
4
24.5762
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0
0

11
5
15.1923
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0
0

11
6
15.7362
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0

11
7
6.9524
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0

11
8
10.7228
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0

11
9
21.6871
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0

11
10
10.2552
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0

11
11
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11
12
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0

11
13
2.1161
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0

11
14
5.318
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0

11
15
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0.625

11
16
0.8455
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0

12
1
15.9884
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0

12
2
27.3984
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0

12
3
28.1625
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0

12
4
24.8213
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0

12
5
16.5105
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0

12
6
16.2367
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0
0

12
7
7.0822
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0

12
8
11.1025
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0

12
9
23.5429
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12
10
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12
11
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12
12
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12
13
1.2187
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0

12
14
5.5276
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0

12
15
13.3469
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0
0.625

12
16
1.0083
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0

13
1
18.6644
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0
0

13
2
27.845
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0

13
3
27.3697
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0
0

13
4
25.678
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0

13
5
15.7945
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0
0

13
6
15.3463
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0

13
7
6.7754
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0
0

13
8
11.692
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0

13
9
23.2809
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0
0

13
10
13.5562
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0

13
11
1.1357
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0

13
12
14.0892
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0

13
13
1.2307
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0

13
14
5.0473
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0
0

13
15
12.8894
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0
0.625

13
16
27.0196
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0

14
1
21.6824
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0
0

14
2
27.9534
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0

14
3
28.3871
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0

14
4
26.5322
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0

14
5
17.27
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0
0

14
6
16.6826
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0

14
7
7.7667
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0

14
8
13.2575
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0

14
9
24.5972
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0
0

14
10
14.1237
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0

14
11
−0.172
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14
12
15.8277
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0

14
13
1.0637
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0
0

14
14
4.6635
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0
0

14
15
12.9488
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0.625

14
16
0.3061
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0

15
1
17.1998
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0
0

15
2
27.4482
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0.933
34.1967
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0
0

15
3
28.1178
18.8556
0.9242
33.8763
0.1324
0
0

15
4
26.8701
17.1463
0.856
31.3778
0.1258
0
0

15
5
17.6631
10.9667
0.5845
21.4248
0.0858
0
0

15
6
17.1402
10.8854
0.5425
19.8853
0.0798
0
0

15
7
8.2663
5.3027
0.2441
8.9487
0.0387
0
0

15
8
11.9892
6.7241
0.3904
14.3081
0.0566
0
0

15
9
24.1606
15.639
0.8291
30.3902
0.1118
0
0

15
10
15.0377
10.3936
0.4614
16.9136
0.0638
0
0

15
11
0.2191
−0.9933
−0.0152
−0.558
0.0074
0
0

15
12
16.1138
9.1228
0.5094
18.6707
0.0732
0
0

15
13
2.4821
0.3422
0.0309
1.1317
0.0144
0
0

15
14
5.4454
0.6463
0.189
6.9276
0.035
0
0

15
15
14.0229
7.8558
0.4492
16.4654
0.0681
0
0.625

15
16
0.4686
−0.7131
0.0197
0.7216
0.01
0
0

16
1
7.4861
4.4402
0.2493
9.1386
0.0401
0
0

16
2
29.0506
17.8613
0.9483
34.7579
0.1412
0
0

16
3
29.4694
17.4993
0.9236
33.8554
0.1479
0
0

16
4
28.4749
16.4322
0.9104
33.3693
0.1531
0
0

16
5
22.0326
12.6858
0.7055
25.8606
0.1115
0
0

16
6
20.0805
12.1402
0.6291
23.0594
0.0943
0
0

16
7
9.0587
5.2161
0.2666
9.7703
0.0461
0
0

16
8
13.983
9.3075
0.4391
16.0948
0.0636
0
0

16
9
26.9905
17.0719
0.877
32.1456
0.1198
0
0

16
10
14.704
8.6762
0.4886
17.9102
0.073
0
0

16
11
0.7191
−1.4742
−0.0041
−0.1519
0.0077
0
0

16
12
19.314
11.1355
0.6495
23.808
0.0899
0
0

16
13
2.4636
0.033
0.0679
2.4886
0.0206
0
0

16
14
11.4461
6.8975
0.3856
14.134
0.0639
0
0

16
15
20.8264
13.1623
0.7
25.6595
0.0961
0
0.625

16
16
26.7851
15.9945
0.9048
33.1661
0.1319
0.1275
0

Tem-

pera-

ture:

250 C.

SUM—
mol %
mol %
mol %

R
C
PtNH32NO22
ZrONO32
micromols
La
Pt
Zr

real
real
real
real

1
1
0
0
0.1275
0
100
0

1
2
0
0
0
0
0
0

1
3
0
0
0
0
0
0

1
4
0
0
0
0
0
0

1
5
0
0
0
0
0
0

1
6
0
0
0
0
0
0

1
7
0
0
0.1275
0
100
0

1
8
0
0
0
0
0
0

1
9
0
0
0
0
0
0

1
10
0
0
0
0
0
0

1
11
0
0
0
0
0
0

1
12
0
0
0
0
0
0

1
13
0
0
0.1275
0
100
0

1
14
0
0
0
0
0
0

1
15
0
0
0
0
0
0

1
16
0
0
0.1275
0
100
0

2
1
0.0319
0
0.0319
0
100
0

2
2
0.0319
0
0.0319
0
100
0

2
3
0.0319
0
0.0319
0
100
0

2
4
0.0319
0
0.0319
0
100
0

2
5
0.0319
0
0.0319
0
100
0

2
6
0.0319
0
0.0319
0
100
0

2
7
0.0319
0
0.0319
0
100
0

2
8
0.0319
0
0.0319
0
100
0

2
9
0.0319
0
0.0319
0
100
0

2
10
0.0319
0
0.0319
0
100
0

2
11
0.0319
0
0.0319
0
100
0

2
12
0.0319
0
0.0319
0
100
0

2
13
0.0319
0
0.0319
0
100
0

2
14
0.0319
0.625
0.6569
0
4.85
95.15

2
15
0.0319
0
0.6569
95.15
4.85
0

2
16
0
0
0
0
0
0

3
1
0.0387
0
0.0387
0
100
0

3
2
0.0387
0
0.0387
0
100
0

3
3
0.0387
0
0.0387
0
100
0

3
4
0.0387
0
0.0387
0
100
0

3
5
0.0387
0
0.0387
0
100
0

3
6
0.0387
0
0.0387
0
100
0

3
7
0.0387
0
0.0387
0
100
0

3
8
0.0387
0
0.0387
0
100
0

3
9
0.0387
0
0.0387
0
100
0

3
10
0.0387
0
0.0387
0
100
0

3
11
0.0387
0
0.0387
0
100
0

3
12
0.0387
0
0.0387
0
100
0

3
13
0.0387
0
0.0387
0
100
0

3
14
0.0387
0.625
0.6637
0
5.83
94.17

3
15
0.0387
0
0.6637
94.17
5.83
0

3
16
0
0
0
0
0
0

4
1
0.0455
0
0.0455
0
100
0

4
2
0.0455
0
0.0455
0
100
0

4
3
0.0455
0
0.0455
0
100
0

4
4
0.0455
0
0.0455
0
100
0

4
5
0.0455
0
0.0455
0
100
0

4
5
0.0455
0
0.0455
0
100
0

4
7
0.0455
0
0.0455
0
100
0

4
8
0.0455
0
0.0455
0
100
0

4
9
0.0455
0
0.0455
0
100
0

4
10
0.0455
0
0.0455
0
100
0

4
11
0.0455
0
0.0455
0
100
0

4
12
0.0455
0
0.0455
0
100
0

4
13
0.0455
0
0.0455
0
100
0

4
14
0.0455
0.625
0.6705
0
6.79
93.21

4
15
0.0455
0
0.6705
93.21
6.79
0

4
16
0
0
0.1275
0
100
0

5
1
0.0524
0
0.0524
0
100
0

5
2
0.0524
0
0.0524
0
100
0

5
3
0.0524
0
0.0524
0
100
0

5
4
0.0524
0
0.0524
0
100
0

5
5
0.0524
0
0.0524
0
100
0

5
6
0.0524
0
0.0524
0
100
0

5
7
0.0524
0
0.0524
0
100
0

5
8
0.0524
0
0.0524
0
100
0

5
9
0.0524
0
0.0524
0
100
0

5
10
0.0524
0
0.0524
0
100
0

5
11
0.0524
0
0.0524
0
100
0

5
12
0.0524
0
0.0524
0
100
0

5
13
0.0524
0
0.0524
0
100
0

5
14
0.0524
0.625
0.6774
0
7.73
92.27

5
15
0.0524
0
0.6774
92.27
7.73
0

5
16
0
0
0
0
0
0

6
1
0.0592
0
0.0592
0
100
0

6
2
0.0592
0
0.0592
0
100
0

6
3
0.0592
0
0.0592
0
100
0

6
4
0.0592
0
0.0592
0
100
0

6
5
0.0592
0
0.0592
0
100
0

6
6
0.0592
0
0.0592
0
100
0

6
7
0.0592
0
0.0592
0
100
0

6
8
0.0592
0
0.0592
0
100
0

6
9
0.0592
0
0.0592
0
100
0

6
10
0.0592
0
0.0592
0
100
0

6
11
0.0592
0
0.0592
0
100
0

5
12
0.0592
0
0.0592
0
100
0

6
13
0.0592
0
0.0592
0
100
0

6
14
0.0592
0.625
0.6842
0
8.65
91.35

6
15
0.0592
0
0.6842
91.35
8.65
0

6
16
0
0
0
0
0
0

7
1
0.066
0
0.066
0
100
0

7
2
0.066
0
0.066
0
100
0

7
3
0.066
0
0.066
0
100
0

7
4
0.066
0
0.066
0
100
0

7
5
0.066
0
0.066
0
100
0

7
6
0.066
0
0.066
0
100
0

7
7
0.066
0
0.066
0
100
0

7
8
0.066
0
0.066
0
100
0

7
9
0.066
0
0.066
0
100
0

7
10
0.066
0
0.066
0
100
0

7
11
0.066
0
0.066
0
100
0

7
12
0.066
0
0.066
0
100
0

7
13
0.066
0
0.066
0
100
0

7
14
0.066
0.625
0.691
0
9.55
90.45

7
15
0.066
0
0.691
90.45
9.55
0

7
16
0
0
0.1275
0
100
0

8
1
0.0729
0
0.0729
0
100
0

8
2
0.0729
0
0.0729
0
100
0

8
3
0.0729
0
0.0729
0
100
0

8
4
0.0729
0
0.0729
0
100
0

8
5
0.0729
0
0.0729
0
100
0

8
6
0.0729
0
0.0729
0
100
0

8
7
0.0729
0
0.0729
0
100
0

8
8
0.0729
0
0.0729
0
100
0

8
9
0.0729
0
0.0729
0
100
0

8
10
0.0729
0
0.0729
0
100
0

8
11
0.0729
0
0.0729
0
100
0

8
12
0.0729
0
0.0729
0
100
0

8
13
0.0729
0
0.0729
0
100
0

8
14
0.0729
0.625
0.6979
0
10.44
89.56

8
15
0.0729
0
0.6979
89.56
10.44
0

8
16
0
0
0
0
0
0

9
1
0.0797
0
0.0797
0
100
0

9
2
0.0797
0
0.0797
0
100
0

9
3
0.0797
0
0.0797
0
100
0

9
4
0.0797
0
0.0797
0
100
0

9
5
0.0797
0
0.0797
0
100
0

9
6
0.0797
0
0.0797
0
100
0

9
7
0.0797
0
0.0797
0
100
0

9
8
0.0797
0
0.0797
0
100
0

9
9
0.0797
0
0.0797
0
100
0

9
10
0.0797
0
0.0797
0
100
0

9
11
0.0797
0
0.0797
0
100
0

9
12
0.0797
0
0.0797
0
100
0

9
13
0.0797
0
0.0797
0
100
0

9
14
0.0797
0.625
0.7047
0
11.31
88.69

9
15
0.0797
0
0.7047
88.69
11.31
0

9
16
0
0
0
0
0
0

10
1
0.0865
0
0.0865
0
100
0

10
2
0.0865
0
0.0865
0
100
0

10
3
0.0865
0
0.0865
0
100
0

10
4
0.0865
0
0.0865
0
100
0

10
5
0.0865
0
0.0865
0
100
0

10
6
0.0865
0
0.0865
0
100
0

10
7
0.0865
0
0.0865
0
100
0

10
8
0.0865
0
0.0865
0
100
0

10
9
0.0865
0
0.0865
0
100
0

10
10
0.0865
0
0.0865
0
100
0

10
11
0.0865
0
0.0865
0
100
0

10
12
0.0865
0
0.0865
0
100
0

10
13
0.0865
0
0.0865
0
100
0

10
14
0.0865
0.625
0.7115
0
12.16
87.84

10
15
0.0865
0
0.7115
87.84
12.16
0

10
16
0
0
0.1275
0
100
0

11
1
0.0933
0
0.0933
0
100
0

11
2
0.0933
0
0.0933
0
100
0

11
3
0.0933
0
0.0933
0
100
0

11
4
0.0933
0
0.0933
0
100
0

11
5
0.0933
0
0.0933
0
100
0

11
6
0.0933
0
0.0933
0
100
0

11
7
0.0933
0
0.0933
0
100
0

11
8
0.0933
0
0.0933
0
100
0

11
9
0.0933
0
0.0933
0
100
0

11
10
0.0933
0
0.0933
0
100
0

11
11
0.0933
0
0.0933
0
100
0

11
12
0.0933
0
0.0933
0
100
0

11
13
0.0933
0
0.0933
0
100
0

11
14
0.0933
0.625
0.7183
0
12.99
87.01

11
15
0.0933
0
0.7183
87.01
12.99
0

11
16
0
0
0
0
0
0

12
1
0.1002
0
0.1002
0
100
0

12
2
0.1002
0
0.1002
0
100
0

12
3
0.1002
0
0.1002
0
100
0

12
4
0.1002
0
0.1002
0
100
0

12
5
0.1002
0
0.1002
0
100
0

12
6
0.1002
0
0.1002
0
100
0

12
7
0.1002
0
0.1002
0
100
0

12
8
0.1002
0
0.1002
0
100
0

12
9
0.1002
0
0.1002
0
100
0

12
10
0.1002
0
0.1002
0
100
0

12
11
0.1002
0
0.1002
0
100
0

12
12
0.1002
0
0.1002
0
100
0

12
13
0.1002
0
0.1002
0
100
0

12
14
0.1002
0.625
0.7252
0
13.81
86.19

12
15
0.1002
0
0.7252
86.19
13.81
0

12
16
0
0
0
0
0
0

13
1
0.107
0
0.107
0
100
0

13
2
0.107
0
0.107
0
100
0

13
3
0.107
0
0.107
0
100
0

13
4
0.107
0
0.107
0
100
0

13
5
0.107
0
0.107
0
100
0

13
6
0.107
0
0.107
0
100
0

13
7
0.107
0
0.107
0
100
0

13
8
0.107
0
0.107
0
100
0

13
9
0.107
0
0.107
0
100
0

13
10
0.107
0
0.107
0
100
0

13
11
0.107
0
0.107
0
100
0

13
12
0.107
0
0.107
0
100
0

13
13
0.107
0
0.107
0
100
0

13
14
0.107
0.625
0.732
0
14.62
85.38

13
15
0.107
0
0.732
85.38
14.62
0

13
16
0
0
0.1275
0
100
0

14
1
0.1138
0
0.1138
0
100
0

14
2
0.1138
0
0.1138
0
100
0

14
3
0.1138
0
0.1138
0
100
0

14
4
0.1138
0
0.1138
0
100
0

14
5
0.1138
0
0.1138
0
100
0

14
6
0.1138
0
0.1138
0
100
0

14
7
0.1138
0
0.1138
0
100
0

14
8
0.1138
0
0.1138
0
100
0

14
9
0.1138
0
0.1138
0
100
0

14
10
0.1138
0
0.1138
0
100
0

14
11
0.1138
0
0.1138
0
100
0

14
12
0.1138
0
0.1138
0
100
0

14
13
0.1138
0
0.1138
0
100
0

14
14
0.1138
0.625
0.7388
0
15.41
84.59

14
15
0.1138
0
0.7388
84.59
15.41
0

14
16
0
0
0
0
0
0

15
1
0.1207
0
0.1207
0
100
0

15
2
0.1207
0
0.1207
0
100
0

15
3
0.1207
0
0.1207
0
100
0

15
4
0.1207
0
0.1207
0
100
0

15
5
0.1207
0
0.1207
0
100
0

15
6
0.1207
0
0.1207
0
100
0

15
7
0.1207
0
0.1207
0
100
0

15
8
0.1207
0
0.1207
0
100
0

15
9
0.1207
0
0.1207
0
100
0

15
10
0.1207
0
0.1207
0
100
0

15
11
0.1207
0
0.1207
0
100
0

15
12
0.1207
0
0.1207
0
100
0

15
13
0.1207
0
0.1207
0
100
0

15
14
0.1207
0.625
0.7457
0
16.18
83.82

15
15
0.1207
0
0.7457
83.82
16.18
0

15
16
0
0
0
0
0
0

16
1
0.1275
0
0.1275
0
100
0

16
2
0.1275
0
0.1275
0
100
0

16
3
0.1275
0
0.1275
0
100
0

16
4
0.1275
0
0.1275
0
100
0

16
5
0.1275
0
0.1275
0
100
0

16
6
0.1275
0
0.1275
0
100
0

16
7
0.1275
0
0.1275
0
100
0

16
8
0.1275
0
0.1275
0
100
0

16
9
0.1275
0
0.1275
0
100
0

16
10
0.1275
0
0.1275
0
100
0

16
11
0.1275
0
0.1275
0
100
0

16
12
0.1275
0
0.1275
0
100
0

16
13
0.1275
0
0.1275
0
100
0

16
14
0.1275
0.625
0.7525
0
16.94
83.06

16
15
0.1275
0
0.7525
83.06
16.94
0

16
16
0
0
0.1275
0
100
0

Tem-

pera-

ture:

300 C.

Pt1.0%/

R
C
COCONV
H2OCONV
CO2PROD
CO2PERPROD
CH4PROD
Zr02_std
LaNO33

1
1
26.0412
13.6761
0.7608
27.4327
0.1592
0.1275
0

1
2
1.9716
2.4686
0.0066
0.2386
0.0092
0
0

1
3
0.3229
0.3952
−0.0391
−1.4081
0.0062
0
0

1
4
0.6417
0.8578
−0.0504
−1.8187
−0.0005
0
0

1
5
0.173
0.5233
−0.0449
−1.6183
0.0024
0
0

1
6
0.3624
0.0747
−0.0376
−1.3546
−0.0039
0
0

1
7
26.157
12.3934
0.797
28.7383
0.1699
0.1275
0

1
8
3.5333
0.2801
−0.0585
−2.108
−0.0107
0
0

1
9
−1.8657
−3.8002
−0.0104
−0.375
0.0197
0
0

1
10
2.592
0.129
−0.014
−0.5051
−0.0253
0
0

1
11
−3.1613
−1.397
−0.0273
−0.9858
0.0043
0
0

1
12
−0.5382
−0.741
−0.0195
−0.7042
−0.0352
0
0

1
13
25.293
12.9331
0.8097
29.194
0.1597
0.1275
0

1
14
0.8774
0.3654
−0.018
−0.648
0.0052
0
0

1
15
−1.2793
0.1383
−0.0181
−0.6543
0.0027
0
0

1
16
25.6735
12.143
0.7277
26.2368
0.1566
0.1275
0

2
1
14.8766
10.2106
0.3917
14.1217
0.0524
0
0

2
2
20.4545
14.6181
0.746
26.8969
0.1088
0
0

2
3
19.9352
12.3858
0.6977
25.1579
0.1196
0
0

2
4
16.0396
10.1097
0.6511
23.4768
0.109
0
0

2
5
15.904
10.2101
0.4597
16.5765
0.0626
0
0

2
6
14.9915
9.8692
0.3995
14.4034
0.0662
0
0

2
7
6.2101
5.2473
0.1852
6.6763
0.0252
0
0

2
8
9.4972
5.8339
0.283
10.205
0.0496
0
0

2
9
21.1669
13.9111
0.6435
23.2016
0.0932
0
0

2
10
8.0932
5.8934
0.2958
10.6661
0.0493
0
0

2
11
0.4906
0.3109
−0.0754
−2.7173
0.0004
0
0

2
12
12.7979
8.96
0.445
16.0439
0.0703
0
0

2
13
1.7683
2.1621
0.0286
1.0326
0.0176
0
0

2
14
11.5049
8.9483
0.3603
12.9899
0.0656
0
0

2
15
19.2509
11.5249
0.6541
23.5849
0.0881
0
0.625

2
16
−2.2275
0.1022
0.0038
0.136
0.001
0
0

3
1
19.5625
13.7405
0.7553
27.2322
0.1169
0
0

3
2
23.3448
16.4986
0.7782
28.0599
0.1055
0
0

3
3
20.2746
14.4888
0.7447
26.8513
0.1236
0
0

3
4
21.042
14.6567
0.5975
21.5435
0.0868
0
0

3
5
15.227
11.3009
0.5184
18.6931
0.0896
0
0

3
6
16.2981
13.1574
0.4916
17.7266
0.0804
0
0

3
7
7.5318
7.7146
0.2177
7.8495
0.0364
0
0

3
8
14.1025
10.9954
0.419
15.1061
0.0628
0
0

3
9
20.9253
15.3432
0.7024
25.3266
0.1019
0
0

3
10
13.728
11.1605
0.4466
16.1033
0.0679
0
0

3
11
−1.0656
0.7638
−0.03
−1.0824
−0.001
0
0

3
12
12.0316
9.0087
0.4143
14.9372
0.064
0
0

3
13
2.3735
2.427
0.0472
1.7003
0.0158
0
0

3
14
10.011
6.6184
0.4321
15.5784
0.078
0
0

3
15
17.1288
11.9418
0.6936
25.0081
0.1016
0
0.625

3
16
−0.0207
−0.0056
0.0564
2.0341
−0.003
0
0

4
1
23.9972
15.9845
0.7717
27.8233
0.119
0
0

4
2
24.3635
16.2531
0.7072
25.5007
0.1199
0
0

4
3
21.4425
14.1432
0.7498
27.0362
0.1265
0
0

4
4
19.4479
12.996
0.6822
24.5996
0.107
0
0

4
5
16.0527
11.3163
0.5819
20.98
0.0935
0
0

4
6
17.5309
11.186
0.5671
20.447
0.0842
0
0

4
7
8.0993
5.7381
0.3374
12.166
0.0503
0
0

4
8
14.119
9.8107
0.5489
19.7929
0.0801
0
0

4
9
23.2762
14.9011
0.7786
28.0723
0.1033
0
0

4
10
14.7194
10.4363
0.5718
20.6185
0.08
0
0

4
11
1.1453
0.3882
−0.067
−2.4162
−0.0168
0
0

4
12
12.7656
8.8311
0.4759
17.1582
0.0689
0
0

4
13
4.4502
1.323
0.0072
0.2593
0.0135
0
0

4
14
13.3844
9.4729
0.4141
14.9311
0.0687
0
0

4
15
20.7018
14.4153
0.6795
24.5002
0.0932
0
0.625

4
16
26.3093
12.5646
0.7405
26.6988
0.1561
0.1275
0

5
1
21.4105
14.4067
0.7125
25.6898
0.11
0
0

5
2
22.1022
14.8036
0.819
29.5304
0.1282
0
0

5
3
22.5933
14.8442
0.7244
26.1201
0.1233
0
0

5
4
21.0057
13.8057
0.6911
24.9201
0.1153
0
0

5
5
17.672
12.2393
0.5728
20.6522
0.0902
0
0

5
6
16.0245
11.7967
0.5902
21.2789
0.0941
0
0

5
7
8.682
6.8022
0.35
12.6185
0.0569
0
0

5
8
16.2047
10.7313
0.5656
20.3921
0.0857
0
0

5
9
21.0729
14.0649
0.7974
28.7515
0.124
0
0

5
10
18.1655
12.1093
0.6249
22.5323
0.094
0
0

5
11
−3.2789
−1.8833
0.0173
0.625
−0.017
0
0

5
12
12.1376
7.6528
0.5085
18.3339
0.0689
0
0

5
13
2.8719
1.6064
0.0398
1.4347
0.0232
0
0

5
14
11.6313
7.1984
0.3756
13.5442
0.064
0
0

5
15
18.7077
12.3422
0.6784
24.4596
0.1017
0
0.625

5
16
−0.923
0.6423
0.0024
0.0871
−0.0005
0
0

6
1
22.0063
14.1082
0.7772
28.0216
0.121
0
0

6
2
23.7522
14.4251
0.8181
29.4983
0.1363
0
0

6
3
23.7349
12.7968
0.778
28.0518
0.1487
0
0

6
4
21.7688
12.1769
0.7488
27.0006
0.1335
0
0

6
5
18.6185
12.368
0.6292
22.6862
0.1057
0
0

6
6
17.435
11.7025
0.6457
23.2833
0.0997
0
0

6
7
9.5496
7.4033
0.4005
14.4418
0.0656
0
0

6
8
18.8345
12.608
0.602
21.7077
0.0895
0
0

6
9
22.7783
14.5707
0.7858
28.3319
0.1268
0
0

6
10
14.2889
9.3319
0.4808
17.3344
0.0626
0
0

6
11
−1.4423
−3.1898
0.0072
0.2597
−0.0242
0
0

6
12
14.6391
9.1343
0.5169
18.6393
0.0784
0
0

6
13
1.3924
0.1849
0.1067
3.8458
0.0254
0
0

6
14
12.4467
7.9011
0.47
16.947
0.0796
0
0

6
15
20.5551
12.4877
0.7241
26.1085
0.1086
0
0.625

6
16
1.8224
1.9194
0.0293
1.0577
−0.001
0
0

7
1
20.1793
13.5157
0.7141
25.7483
0.1062
0
0

7
2
23.9199
15.0715
0.7923
28.5691
0.1334
0
0

7
3
24.0921
13.8724
0.7704
27.7794
0.1489
0
0

7
4
22.4883
13.3333
0.7472
26.9401
0.1331
0
0

7
5
18.3753
10.967
0.6933
24.9964
0.1147
0
0

7
6
19.1636
11.8882
0.594
21.4179
0.0973
0
0

7
7
11.6242
8.7829
0.358
12.9075
0.0589
0
0

7
8
18.9461
11.9304
0.6075
21.9057
0.0865
0
0

7
9
20.8727
13.268
0.8581
30.9391
0.1366
0
0

7
10
19.7469
12.533
0.627
22.6084
0.0889
0
0

7
11
0.2661
−1.0746
−0.0206
−0.7417
−0.0241
0
0

7
12
14.9635
8.7674
0.5117
18.4485
0.0776
0
0

7
13
2.473
1.1259
0.0915
3.3004
0.0134
0
0

7
14
10.4908
6.4436
0.4097
14.774
0.0771
0
0

7
15
17.9387
11.3159
0.7335
26.449
0.109
0
0.625

7
16
24.6649
12.1883
0.7892
28.4564
0.1735
0.1275
0

8
1
20.4072
13.9072
0.7031
25.3521
0.1107
0
0

8
2
23.2299
15.5533
0.8078
29.1272
0.1368
0
0

8
3
24.3029
13.9797
0.7799
28.1203
0.1564
0
0

8
4
22.2113
14.5975
0.7495
27.0256
0.1425
0
0

8
5
18.1577
13.0692
0.6943
25.034
0.1167
0
0

8
6
16.4584
11.241
0.6799
24.5135
0.1128
0
0

8
7
11.3178
9.6452
0.4321
15.5795
0.0596
0
0

8
8
20.8336
14.4605
0.6457
23.2815
0.0922
0
0

8
9
23.346
15.3942
0.8346
30.0941
0.1169
0
0

8
10
20.3283
13.3467
0.6964
25.1102
0.1063
0
0

8
11
6.0017
3.7447
0.2344
8.4523
0.0402
0
0

8
12
14.0669
9.2173
0.572
20.6246
0.0862
0
0

8
13
0.4343
−0.3379
0.1029
3.7103
0.0224
0
0

8
14
12.9196
8.2041
0.4689
16.9054
0.0749
0
0

8
15
20.3025
12.6472
0.6618
23.8639
0.1
0
0.625

8
16
0.7273
0.7062
−0.0175
−0.63
−0.0087
0
0

9
1
19.0866
13.801
0.6956
25.0805
0.1067
0
0

9
2
23.4011
15.4022
0.8062
29.0677
0.1362
0
0

9
3
24.2636
14.0356
0.8069
29.094
0.1585
0
0

9
4
23.0618
13.7204
0.7603
27.4122
0.137
0
0

9
5
19.2953
12.3324
0.6838
24.6546
0.1191
0
0

9
6
16.4524
11.6941
0.5833
21.033
0.0966
0
0

9
7
8.8155
6.193
0.4081
14.7154
0.0678
0
0

9
8
18.3421
12.4823
0.6492
23.4094
0.095
0
0

9
9
22.5571
15.4221
0.8241
29.7153
0.1201
0
0

9
10
18.2863
13.1397
0.6724
24.2444
0.0988
0
0

9
11
−1.5339
−0.5868
−0.0006
−0.0218
−0.0198
0
0

9
12
13.9602
9.1693
0.5547
20.0022
0.0819
0
0

9
13
1.1827
1.2849
0.1107
3.9916
0.0024
0
0

9
14
10.2757
6.1288
0.3969
14.3106
0.0711
0
0

9
15
19.4095
11.4849
0.732
26.3918
0.1116
0
0.625

9
16
−0.4746
0.3
0.0649
2.3389
0.0106
0
0

10
1
19.6155
13.2592
0.7151
25.784
0.1137
0
0

10
2
24.4255
14.2114
0.8452
30.474
0.1541
0
0

10
3
25.1167
12.0723
0.8229
29.6706
0.1783
0
0

10
4
23.9367
12.0867
0.8302
29.934
0.1595
0
0

10
5
20.499
11.2772
0.6949
25.0561
0.1257
0
0

10
6
18.4277
10.342
0.652
23.5077
0.1136
0
0

10
7
10.6829
8.2331
0.4943
17.8212
0.0797
0
0

10
8
21.0351
13.5697
0.6934
25.0025
0.1016
0
0

10
9
23.3546
15.5724
0.8319
29.9961
0.1265
0
0

10
10
20.2733
13.206
0.7226
26.0547
0.1094
0
0

10
11
−2.2709
−1.6818
−0.003
−0.1081
−0.0191
0
0

10
12
15.5394
9.154
0.5767
20.7948
0.0875
0
0

10
13
2.338
0.6958
0.1166
4.204
0.0286
0
0

10
14
11.8371
7.0502
0.4485
16.1702
0.0781
0
0

10
15
18.9643
11.9052
0.7159
25.8125
0.1082
0
0.625

10
16
23.3683
12.0328
0.7792
28.0962
0.1577
0.1275
0

11
1
18.6802
11.5742
0.6796
24.5045
0.1057
0
0

11
2
25.0222
13.9863
0.8039
28.9852
0.1512
0
0

11
3
25.6394
13.1215
0.8122
29.2838
0.1687
0
0

11
4
24.6744
14.5183
0.7802
28.132
0.1536
0
0

11
5
19.3295
12.6135
0.685
24.6995
0.1225
0
0

11
6
18.7665
11.7823
0.6491
23.4044
0.1112
0
0

11
7
12.0459
8.262
0.4669
16.8355
0.0746
0
0

11
8
19.7356
12.2924
0.7225
26.0526
0.1072
0
0

11
9
23.3494
14.4131
0.8518
30.7139
0.1298
0
0

11
10
19.1323
12.6849
0.7094
25.5779
0.105
0
0

11
11
−0.9895
−0.2695
−0.004
−0.1435
−0.0127
0
0

11
12
14.8304
10.1963
0.582
20.9867
0.0899
0
0

11
13
2.208
2.5587
0.1029
3.7107
0.0204
0
0

11
14
10.9763
6.4266
0.3918
14.1258
0.0707
0
0

11
15
18.1906
10.6621
0.698
25.1685
0.106
0
0.625

11
16
−0.9643
−0.7161
0.0392
1.4143
−0.0048
0
0

12
1
15.4588
10.1833
0.5953
21.4632
0.1001
0
0

12
2
24.7319
13.6012
0.8478
30.5688
0.161
0
0

12
3
26.8912
12.8758
0.8008
28.8754
0.1851
0
0

12
4
24.6558
12.9216
0.8196
29.5504
0.1758
0
0

12
5
20.5267
12.1018
0.7215
26.0139
0.1329
0
0

12
6
18.4287
11.4481
0.6811
24.5589
0.1172
0
0

12
7
13.4393
9.372
0.4909
17.6995
0.0793
0
0

12
8
21.0809
13.9911
0.7512
27.0875
0.111
0
0

12
9
23.772
15.0448
0.8517
30.7084
0.1339
0
0

12
10
19.8095
12.8912
0.7381
26.6137
0.1093
0
0

12
11
−1.4941
−1.399
−0.0134
−0.4846
−0.018
0
0

12
12
16.0743
10.6539
0.5977
21.5507
0.092
0
0

12
13
2.0581
1.6359
0.1105
3.986
0.0298
0
0

12
14
10.744
6.4761
0.4184
15.0852
0.076
0
0

12
15
18.2843
10.3265
0.6975
25.1492
0.112
0
0.625

12
16
−0.4083
−1.1083
0.0632
2.2805
0.02
0
0

13
1
17.3784
11.3659
0.6531
23.5471
0.1026
0
0

13
2
24.8735
13.9698
0.8645
31.1714
0.1634
0
0

13
3
26.731
13.2379
0.8304
29.9397
0.1799
0
0

13
4
25.0125
13.3208
0.8199
29.5626
0.1706
0
0

13
5
20.9959
12.5637
0.7
25.2389
0.1263
0
0

13
6
19.7859
13.0643
0.6384
23.0182
0.1112
0
0

13
7
12.7701
8.6484
0.4737
17.0786
0.0821
0
0

13
8
19.9798
12.3643
0.7421
26.7561
0.1113
0
0

13
9
23.9004
15.4262
0.8368
30.1725
0.1326
0
0

13
10
20.1688
14.395
0.7685
27.7093
0.1134
0
0

13
11
−1.5531
−0.2131
0.0003
0.0093
−0.0139
0
0

13
12
16.261
10.9519
0.6007
21.66
0.0928
0
0

13
13
2.1579
1.7026
0.1307
4.7131
0.0287
0
0

13
14
10.3449
7.0881
0.4013
14.4697
0.0725
0
0

13
15
17.9906
12.3676
0.6892
24.8485
0.1057
0
0.625

13
16
24.9296
12.3107
0.7853
28.3135
0.1895
0.1275
0

14
1
19.7006
13.895
0.7196
25.9447
0.1225
0
0

14
2
24.628
13.7864
0.8645
31.1715
0.1715
0
0

14
3
27.0603
12.7211
0.8226
29.6605
0.2007
0
0

14
4
24.9719
12.0514
0.83
29.9259
0.1896
0
0

14
5
20.0669
11.3486
0.7334
26.4431
0.1416
0
0

14
6
19.3148
11.3116
0.7073
25.5033
0.128
0
0

14
7
13.0698
9.2496
0.5178
18.6703
0.0862
0
0

14
8
21.4825
14.0766
0.7634
27.5263
0.1153
0
0

14
9
23.8379
15.3459
0.8607
31.0347
0.1367
0
0

14
10
21.5278
13.8928
0.7851
28.3081
0.1137
0
0

14
11
−2.1621
−1.2165
−0.0091
−0.3271
−0.0078
0
0

14
12
17.3041
11.5725
0.646
23.2923
0.0958
0
0

14
13
1.949
2.0565
0.0896
3.2302
0.028
0
0

14
14
9.3689
6.5087
0.3449
12.4353
0.0636
0
0

14
15
18.4324
12.0276
0.6914
24.9297
0.1067
0
0.625

14
16
−0.7558
−0.6898
0.0165
0.5934
0.0011
0
0

15
1
18.1472
11.9418
0.6987
25.1939
0.1082
0
0

15
2
24.7631
13.6604
0.8641
31.1563
0.1697
0
0

15
3
26.1211
11.8227
0.834
30.0705
0.2037
0
0

15
4
24.5677
11.9552
0.7923
28.5692
0.1875
0
0

15
5
20.0898
11.474
0.7193
25.9371
0.144
0
0

15
6
19.3675
11.6613
0.6822
24.5972
0.1254
0
0

15
7
12.9911
8.3415
0.5124
18.477
0.0905
0
0

15
8
19.4851
12.9013
0.711
25.6353
0.1146
0
0

15
9
23.6077
14.5462
0.8618
31.074
0.1436
0
0

15
10
21.2589
13.7735
0.7922
28.5624
0.1207
0
0

15
11
−1.3789
−1.3203
0.0019
0.0686
−0.0106
0
0

15
12
16.8366
10.3498
0.6489
23.3953
0.1014
0
0

15
13
2.5374
0.8067
0.138
4.9742
0.0357
0
0

15
14
11.1396
7.0915
0.4088
14.741
0.0773
0
0

15
15
17.5426
10.4944
0.7045
25.4019
0.1136
0
0.625

15
16
−0.4051
−0.4444
0.0729
2.6294
0.0112
0
0

16
1
15.0725
8.0994
0.5869
21.1613
0.0985
0
0

16
2
24.67
8.6858
0.7009
25.2716
0.2051
0
0

16
3
27.4278
6.3099
0.707
25.4923
0.2645
0
0

16
4
24.8032
6.1186
0.6967
25.1217
0.2372
0
0

16
5
20.9479
7.854
0.6707
24.1843
0.1784
0
0

16
6
19.4346
9.972
0.6893
24.8548
0.1408
0
0

16
7
14.3144
8.9315
0.5183
18.6864
0.0889
0
0

16
8
20.6449
13.6205
0.7023
25.3217
0.1142
0
0

16
9
24.2561
14.785
0.854
30.7919
0.1506
0
0

16
10
21.0486
14.0733
0.6995
25.2209
0.1084
0
0

16
11
−2.2759
−0.0846
0.0413
1.4879
0.024
0
0

16
12
17.1423
10.7518
0.5869
21.1613
0.0898
0
0

16
13
3.0092
2.0883
0.2069
7.4586
0.0432
0
0

16
14
12.8714
7.6083
0.5142
18.5415
0.1069
0
0

16
15
17.5841
9.9481
0.6294
22.6946
0.129
0
0.625

16
16
25.0686
11.1805
0.8288
29.884
0.1822
0.1275
0

Tem-

pera-

ture:

300 C.

Sum—
mol %
mol %
mol %

R
C
PtNH32NO22
ZrONO32
micromols
La
Pt
Zr

1
1
0
0
0.1275
0
100
0

1
2
0
0
0
0
0
0

1
3
0
0
0
0
0
0

1
4
0
0
0
0
0
0

1
5
0
0
0
0
0
0

1
6
0
0
0
0
0
0

1
7
0
0
0.1275
0
100
0

1
8
0
0
0
0
0
0

1
9
0
0
0
0
0
0

1
10
0
0
0
0
0
0

1
11
0
0
0
0
0
0

1
12
0
0
0
0
0
0

1
13
0
0
0.1275
0
100
0

1
14
0
0
0
0
0
0

1
15
0
0
0
0
0
0

1
16
0
0
0.1275
0
100
0

2
1
0.0319
0
0.0319
0
100
0

2
2
0.0319
0
0.0319
0
100
0

2
3
0.0319
0
0.0319
0
100
0

2
4
0.0319
0
0.0319
0
100
0

2
5
0.0319
0
0.0319
0
100
0

2
6
0.0319
0
0.0319
0
100
0

2
7
0.0319
0
0.0319
0
100
0

2
8
0.0319
0
0.0319
0
100
0

2
9
0.0319
0
0.0319
0
100
0

2
10
0.0319
0
0.0319
0
100
0

2
11
0.0319
0
0.0319
0
100
0

2
12
0.0319
0
0.0319
0
100
0

2
13
0.0319
0
0.0319
0
100
0

2
14
0.0319
0.625
0.6569
0
4.85
95.15

2
15
0.0319
0
0.6569
95.15
4.85
0

2
16
0
0
0
0
0
0

3
1
0.0387
0
0.0387
0
100
0

3
2
0.0387
0
0.0387
0
100
0

3
3
0.0387
0
0.0387
0
100
0

3
4
0.0387
0
0.0387
0
100
0

3
5
0.0387
0
0.0387
0
100
0

3
6
0.0387
0
0.0387
0
100
0

3
7
0.0387
0
0.0387
0
100
0

3
8
0.0387
0
0.0387
0
100
0

3
9
0.0387
0
0.0387
0
100
0

3
10
0.0387
0
0.0387
0
100
0

3
11
0.0387
0
0.0387
0
100
0

3
12
0.0387
0
0.0387
0
100
0

3
13
0.0387
0
0.0387
0
100
0

3
14
0.0387
0.625
0.6637
0
5.83
94.17

3
15
0.0387
0
0.6637
94.17
5.83
0

3
16
0
0
0
0
0
0

4
1
0.0455
0
0.0455
0
100
0

4
2
0.0455
0
0.0455
0
100
0

4
3
0.0455
0
0.0455
0
100
0

4
4
0.0455
0
0.0455
0
100
0

4
5
0.0455
0
0.0455
0
100
0

4
6
0.0455
0
0.0455
0
100
0

4
7
0.0455
0
0.0455
0
100
0

4
8
0.0455
0
0.0455
0
100
0

4
9
0.0455
0
0.0455
0
100
0

4
10
0.0455
0
0.0455
0
100
0

4
11
0.0455
0
0.0455
0
100
0

4
12
0.0455
0
0.0455
0
100
0

4
13
0.0455
0
0.0455
0
100
0

4
14
0.0455
0.625
0.6705
0
6.79
93.21

4
15
0.0455
0
0.6705
93.21
6.79
0

4
16
0
0
0.1275
0
100
0

5
1
0.0524
0
0.0524
0
100
0

5
2
0.0524
0
0.0524
0
100
0

5
3
0.0524
0
0.0524
0
100
0

5
4
0.0524
0
0.0524
0
100
0

5
5
0.0524
0
0.0524
0
100
0

5
6
0.0524
0
0.0524
0
100
0

5
7
0.0524
0
0.0524
0
100
0

5
8
0.0524
0
0.0524
0
100
0

5
9
0.0524
0
0.0524
0
100
0

5
10
0.0524
0
0.0524
0
100
0

5
11
0.0524
0
0.0524
0
100
0

5
12
0.0524
0
0.0524
0
100
0

5
13
0.0524
0
0.0524
0
100
0

5
14
0.0524
0.625
0.6774
0
7.73
92.27

5
15
0.0524
0
0.6774
92.27
7.73
0

5
16
0
0
0
0
0
0

6
1
0.0592
0
0.0592
0
100
0

6
2
0.0592
0
0.0592
0
100
0

6
3
0.0592
0
0.0592
0
100
0

6
4
0.0592
0
0.0592
0
100
0

6
5
0.0592
0
0.0592
0
100
0

6
6
0.0592
0
0.0592
0
100
0

6
7
0.0592
0
0.0592
0
100
0

6
8
0.0592
0
0.0592
0
100
0

6
9
0.0592
0
0.0592
0
100
0

6
10
0.0592
0
0.0592
0
100
0

6
11
0.0592
0
0.0592
0
100
0

6
12
0.0592
0
0.0592
0
100
0

6
13
0.0592
0
0.0592
0
100
0

6
14
0.0592
0.625
0.6842
0
8.65
91.35

6
15
0.0592
0
0.6842
91.35
8.65
0

6
16
0
0
0
0
0
0

7
1
0.066
0
0.066
0
100
0

7
2
0.066
0
0.066
0
100
0

7
3
0.066
0
0.066
0
100
0

7
4
0.066
0
0.066
0
100
0

7
5
0.066
0
0.066
0
100
0

7
6
0.066
0
0.066
0
100
0

7
7
0.066
0
0.066
0
100
0

7
8
0.066
0
0.066
0
100
0

7
9
0.066
0
0.066
0
100
0

7
10
0.066
0
0.066
0
100
0

7
11
0.066
0
0.066
0
100
0

7
12
0.066
0
0.066
0
100
0

7
13
0.066
0
0.066
0
100
0

7
14
0.066
0.625
0.691
0
9.55
90.45

7
15
0.066
0
0.691
90.45
9.55
0

7
16
0
0
0.1275
0
100
0

8
1
0.0729
0
0.0729
0
100
0

8
2
0.0729
0
0.0729
0
100
0

8
3
0.0729
0
0.0729
0
100
0

8
4
0.0729
0
0.0729
0
100
0

8
5
0.0729
0
0.0729
0
100
0

8
6
0.0729
0
0.0729
0
100
0

8
7
0.0729
0
0.0729
0
100
0

8
8
0.0729
0
0.0729
0
100
0

8
9
0.0729
0
0.0729
0
100
0

8
10
0.0729
0
0.0729
0
100
0

8
11
0.0729
0
0.0729
0
100
0

8
12
0.0729
0
0.0729
0
100
0

8
13
0.0729
0
0.0729
0
100
0

8
14
0.0729
0.625
0.6979
0
10.44
89.56

8
15
0.0729
0
0.6979
89.56
10.44
0

8
16
0
0
0
0
0
0

9
1
0.0797
0
0.0797
0
100
0

9
2
0.0797
0
0.0797
0
100
0

9
3
0.0797
0
0.0797
0
100
0

9
4
0.0797
0
0.0797
0
100
0

9
5
0.0797
0
0.0797
0
100
0

9
6
0.0797
0
0.0797
0
100
0

9
7
0.0797
0
0.0797
0
100
0

9
8
0.0797
0
0.0797
0
100
0

9
9
0.0797
0
0.0797
0
100
0

9
10
0.0797
0
0.0797
0
100
0

9
11
0.0797
0
0.0797
0
100
0

9
12
0.0797
0
0.0797
0
100
0

9
13
0.0797
0
0.0797
0
100
0

9
14
0.0797
0.625
0.7047
0
11.31
88.69

9
15
0.0797
0
0.7047
88.69
11.31
0

9
16
0
0
0
0
0
0

10
1
0.0865
0
0.0865
0
100
0

10
2
0.0865
0
0.0865
0
100
0

10
3
0.0865
0
0.0865
0
100
0

10
4
0.0865
0
0.0865
0
100
0

10
5
0.0865
0
0.0865
0
100
0

10
6
0.0865
0
0.0865
0
100
0

10
7
0.0865
0
0.0865
0
100
0

10
8
0.0865
0
0.0865
0
100
0

10
9
0.0865
0
0.0865
0
100
0

10
10
0.0865
0
0.0865
0
100
0

10
11
0.0865
0
0.0865
0
100
0

10
12
0.0865
0
0.0865
0
100
0

10
13
0.0865
0
0.0865
0
100
0

10
14
0.0865
0.625
0.7115
0
12.16
87.84

10
15
0.0865
0
0.7115
87.84
12.16
0

10
16
0
0
0.1275
0
100
0

11
1
0.0933
0
0.0933
0
100
0

11
2
0.0933
0
0.0933
0
100
0

11
3
0.0933
0
0.0933
0
100
0

11
4
0.0933
0
0.0933
0
100
0

11
5
0.0933
0
0.0933
0
100
0

11
6
0.0933
0
0.0933
0
100
0

11
7
0.0933
0
0.0933
0
100
0

11
8
0.0933
0
0.0933
0
100
0

11
9
0.0933
0
0.0933
0
100
0

11
10
0.0933
0
0.0933
0
100
0

11
11
0.0933
0
0.0933
0
100
0

11
12
0.0933
0
0.0933
0
100
0

11
13
0.0933
0
0.0933
0
100
0

11
14
0.0933
0.625
0.7183
0
12.99
87.01

11
15
0.0933
0
0.7183
87.01
12.99
0

11
16
0
0
0
0
0
0

12
1
0.1002
0
0.1002
0
100
0

12
2
0.1002
0
0.1002
0
100
0

12
3
0.1002
0
0.1002
0
100
0

12
4
0.1002
0
0.1002
0
100
0

12
5
0.1002
0
0.1002
0
100
0

12
6
0.1002
0
0.1002
0
100
0

12
7
0.1002
0
0.1002
0
100
0

12
8
0.1002
0
0.1002
0
100
0

12
9
0.1002
0
0.1002
0
100
0

12
10
0.1002
0
0.1002
0
100
0

12
11
0.1002
0
0.1002
0
100
0

12
12
0.1002
0
0.1002
0
100
0

12
13
0.1002
0
0.1002
0
100
0

12
14
0.1002
0.625
0.7252
0
13.81
86.19

12
15
0.1002
0
0.7252
86.19
13.81
0

12
16
0
0
0
0
0
0

13
1
0.107
0
0.107
0
100
0

13
2
0.107
0
0.107
0
100
0

13
3
0.107
0
0.107
0
100
0

13
4
0.107
0
0.107
0
100
0

13
5
0.107
0
0.107
0
100
0

13
6
0.107
0
0.107
0
100
0

13
7
0.107
0
0.107
0
100
0

13
8
0.107
0
0.107
0
100
0

13
9
0.107
0
0.107
0
100
0

13
10
0.107
0
0.107
0
100
0

13
11
0.107
0
0.107
0
100
0

13
12
0.107
0
0.107
0
100
0

13
13
0.107
0
0.107
0
100
0

13
14
0.107
0.625
0.732
0
14.62
85.38

13
15
0.107
0
0.732
85.38
14.62
0

13
16
0
0
0.1275
0
100
0

14
1
0.1138
0
0.1138
0
100
0

14
2
0.1138
0
0.1138
0
100
0

14
3
0.1138
0
0.1138
0
100
0

14
4
0.1138
0
0.1138
0
100
0

14
5
0.1138
0
0.1138
0
100
0

14
6
0.1138
0
0.1138
0
100
0

14
7
0.1138
0
0.1138
0
100
0

14
8
0.1138
0
0.1138
0
100
0

14
9
0.1138
0
0.1138
0
100
0

14
10
0.1138
0
0.1138
0
100
0

14
11
0.1138
0
0.1138
0
100
0

14
12
0.1138
0
0.1138
0
100
0

14
13
0.1138
0
0.1138
0
100
0

14
14
0.1138
0.625
0.7388
0
15.41
84.59

14
15
0.1138
0
0.7388
84.59
15.41
0

14
16
0
0
0
0
0
0

15
1
0.1207
0
0.1207
0
100
0

15
2
0.1207
0
0.1207
0
100
0

15
3
0.1207
0
0.1207
0
100
0

15
4
0.1207
0
0.1207
0
100
0

15
5
0.1207
0
0.1207
0
100
0

15
6
0.1207
0
0.1207
0
100
0

15
7
0.1207
0
0.1207
0
100
0

15
8
0.1207
0
0.1207
0
100
0

15
9
0.1207
0
0.1207
0
100
0

15
10
0.1207
0
0.1207
0
100
0

15
11
0.1207
0
0.1207
0
100
0

15
12
0.1207
0
0.1207
0
100
0

15
13
0.1207
0
0.1207
0
100
0

15
14
0.1207
0.625
0.7457
0
16.18
83.82

15
15
0.1207
0
0.7457
83.82
16.18
0

15
16
0
0
0
0
0
0

16
1
0.1275
0
0.1275
0
100
0

16
2
0.1275
0
0.1275
0
100
0

16
3
0.1275
0
0.1275
0
100
0

16
4
0.1275
0
0.1275
0
100
0

16
5
0.1275
0
0.1275
0
100
0

16
6
0.1275
0
0.1275
0
100
0

16
7
0.1275
0
0.1275
0
100
0

16
8
0.1275
0
0.1275
0
100
0

16
9
0.1275
0
0.1275
0
100
0

16
10
0.1275
0
0.1275
0
100
0

16
11
0.1275
0
0.1275
0
100
0

16
12
0.1275
0
0.1275
0
100
0

16
13
0.1275
0
0.1275
0
100
0

16
14
0.1275
0.625
0.7525
0
16.94
83.06

16
15
0.1275
0
0.7525
83.06
16.94
0

16
16
0
0
0.1275
0
100
0

[0296]

9

TABLE II

Tem-

pera-

ture:

300 C.

Pt1.O%/

R
C
COCONV
H2OCONV
CO2PROD
CO2PERPROD
CH4PROD
ZrO2_std
CeNO33
CoNO32
LaNO33

real
real
real
real
real
real
real
real
real
real
real

1
1
15.7986
12.2353
0.7443
26.6989
0.2025
0.1275
0
0
0

1
2
−1.6605
−0.4015
0.1746
6.262
0.0427
0
0
0
0

1
3
−3.3432
−2.8739
0.0909
3.2591
0.0249
0
0
0
0

1
4
−1.5889
−0.7581
0.0327
1.1725
0.0101
0
0
0
0

1
5
−2.0416
−3.6101
−0.0004
−0.0146
0.0061
0
0
0
0

1
6
−1.3072
−0.2928
0.0061
0.2203
0.0037
0
0
0
0

1
7
24.1641
14.6796
0.7194
25.8057
0.2092
0.1275
0
0
0

1
8
1.2706
5.1132
0.0383
1.3744
0.0043
0
0
0
0

1
9
−1.1139
0.6947
−0.0229
0.8203
−0.0034
0
0
0
0

1
10
−0.9348
−1.4821
−0.0293
−1.0513
−0.0048
0
0
0
0

1
11
−1.0936
−1.3466
−0.0321
1.1501
−0.0057
0
0
0
0

1
12
−0.8945
−2.7312
−0.0352
−1.2629
−0.0051
0
0
0
0

1
13
25.7122
17.2709
0.741
26.5814
0.1961
0.1275
0
0
0

1
14
1.3216
0.8855
0.0278
0.9969
0.0005
0
0
0
0

1
15
−0.3328
1.9579
−0.047
1.6868
−0.0116
0
0
0
0

1
16
−0.6388
3.8351
−0.0427
−1.5333
−0.0128
0
0
0
0

2
1
32.8134
−1.3954
0.4991
17.9018
0.4047
0
0
0.125
0

2
2
33.7634
−0.7213
0.5627
20.1852
0.398
0
0
0.1964
0

2
3
35.6619
−2.2873
0.5592
20.0582
0.4282
0
0
0.2679
0

2
4
37.1438
1.718
0.5576
20.0006
0.441
0
0
0.3393
0

2
5
33.8684
3.0561
0.6422
23.0365
0.3684
0
0
0.4107
0

2
6
38.7621
−0.7205
0.5983
21.4623
0.4682
0
0
0.4821
0

2
7
40.2724
−3.055
0.626
22.4563
0.4782
0
0
0.5536
0

2
8
39.7217
0.3938
0.6248
22.4111
0.4722
0
0
0.625
0

2
9
42.5893
−5.4627
0.5821
20.8809
0.5336
0
0.125
0
0

2
10
42.9319
−4.3894
0.5503
19.7403
0.5457
0
0.2083
0
0

2
11
44.9469
2.5644
0.4728
16.9586
0.5904
0
0.2917
0
0

2
12
43.7075
3.1894
0.5096
18.2796
0.5759
0
0.375
0
0

2
13
43.5857
5.9922
0.5426
19.4617
0.5695
0
0.4583
0
0

2
14
40.9417
1.3479
0.6538
23.4524
0.4792
0
0.5417
0
0

2
15
40.1679
2.0486
0.5739
20.5869
0.5011
0
0.625
0
0

2
16
1.1432
1.1008
0.0195
0.7001
0.0042
0
0
0
0

3
1
30.033
1.4197
0.5289
18.9724
0.3491
0
0
0.125
0

3
2
30.5845
7.6416
0.5106
18.3171
0.3379
0
0
0.1964
0

3
3
31.5558
6.8985
0.5846
20.9711
0.3398
0
0
0.2679
0

3
4
34.6039
−1.0478
0.6413
23.0055
0.3861
0
0
0.3393
0

3
5
34.405
1.0827
0.6592
23.6444
0.3741
0
0
0.4107
0

3
6
35.4145
8.0388
0.6032
21.6388
0.3881
0
0
0.4821
0

3
7
37.4154
2.8929
0.6467
23.1968
0.419
0
0
0.5536
0

3
8
39.1571
3.1565
0.6197
22.2277
0.4582
0
0
0.625
0

3
9
39.1656
−1.0481
0.6204
22.2537
0.4536
0
0.125
0
0

3
10
40.5621
−2.6868
0.6187
22.1937
0.4797
0
0.2083
0
0

3
11
39.3799
2.8396
0.6225
22.3281
0.4421
0
0.2917
0
0

3
12
38.9106
0.6095
0.6545
23.4766
0.4343
0
0.375
0
0

3
13
38.3087
1.387
0.6603
23.6849
0.4235
0
0.4583
0
0

3
14
35.4529
7.7118
0.7044
25.2688
0.3434
0
0.5417
0
0

3
15
35.3735
4.4028
0.7249
26.002
0.3536
0
0.625
0
0

3
16
2.2186
2.1022
0.0059
0.2132
−0.0054
0
0
0
0

4
1
27.7939
2.0527
0.618
22.1679
0.2794
0
0
0.125
0

4
2
28.7345
6.1964
0.591
21.2004
0.2887
0
0
0.1964
0

4
3
30.3974
4.4338
0.6781
24.3227
0.2923
0
0
0.2679
0

4
4
30.8476
10.9069
0.6382
22.8913
0.2878
0
0
0.3393
0

4
5
30.6757
6.3734
0.7218
25.8911
0.2804
0
0
0.4107
0

4
6
32.9835
8.0351
0.7198
25.8179
0.3086
0
0
0.4821
0

4
7
35.2867
7.3641
0.6966
24.9863
0.3575
0
0
0.5536
0

4
8
37.1287
3.7413
0.7004
25.1237
0.3921
0
0
0.625
0

4
9
36.5671
2.466
0.7133
25.5863
0.3845
0
0.125
0
0

4
10
35.6761
6.0619
0.6991
25.0759
0.3652
0
0.2083
0
0

4
11
34.9428
6.2846
0.7942
28.4874
0.3268
0
0.2917
0
0

4
12
37.1032
1.9047
0.7067
25.3505
0.3882
0
0.375
0
0

4
13
34.4347
8.2312
0.7447
26.7117
0.324
0
0.4583
0
0

4
14
34.207
9.192
0.7779
27.9022
0.3061
0
0.5417
0
0

4
15
33.6393
6.2152
0.733
26.2937
0.3276
0
0.625
0
0

4
16
29.037
2.5062
0.7589
27.2208
0.2249
0.1275
0
0
0

5
1
24.6087
9.2263
0.6037
21.6552
0.2131
0
0
0.125
0

5
2
24.4075
6.9158
0.6723
24.1157
0.2
0
0
0.1964
0

5
3
24.7587
11.5748
0.6582
23.6105
0.192
0
0
0.2679
0

5
4
26.0583
10.8227
0.7272
26.0839
0.2021
0
0
0.3393
0

5
5
26.7883
11.4538
0.7439
26.684
0.2078
0
0
0.4107
0

5
6
29.7276
12.1832
0.6912
24.7934
0.2622
0
0
0.4821
0

5
7
32.3989
8.3866
0.736
26.4015
0.299
0
0
0.5536
0

5
8
35.6774
6.061
0.7044
25.2678
0.3669
0
0
0.625
0

5
9
32.3798
8.4298
0.7432
26.6599
0.2933
0
0.125
0
0

5
10
31.9094
−3.0193
0.8329
29.8765
0.2864
0
0.2083
0
0

5
11
30.4447
11.1084
0.7665
27.4944
0.2561
0
0.2917
0
0

5
12
31.9944
9.2381
0.7809
28.012
0.2744
0
0.375
0
0

5
13
30.7158
12.7032
0.7995
28.6788
0.2396
0
0.4583
0
0

5
14
31.2335
10.2373
0.7458
26.7508
0.2628
0
0.5417
0
0

5
15
29.6651
11.0649
0.8412
30.176
0.2256
0
0.625
0
0

5
16
2.021
2.859
0.0241
0.8632
0.0025
0
0
0
0

6
1
21.9959
11.5419
0.6402
22.9643
0.1567
0
0
0.125
0

6
2
23.2401
11.6565
0.6519
23.3824
0.1671
0
0
0.1964
0

6
3
23.4456
10.5787
0.6472
23.2142
0.1684
0
0
0.2679
0

6
4
24.307
12.7023
0.699
25.0731
0.1689
0
0
0.3393
0

6
5
25.1127
14.8654
0.7048
25.2801
0.1705
0
0
0.4107
0

6
6
27.3528
15.4064
0.695
24.9286
0.2121
0
0
0.4821
0

6
7
27.7231
13.6272
0.7298
26.1773
0.2096
0
0
0.5536
0

6
8
30.9183
12.3963
0.7109
25.5005
0.2709
0
0
0.625
0

6
9
31.5914
9.2633
0.8099
29.0513
0.2665
0
0.125
0
0

6
10
28.5927
14.8272
0.7457
26.7502
0.218
0
0.2083
0
0

6
11
29.3514
14.8513
0.757
27.1537
0.2308
0
0.2917
0
0

6
12
28.9816
17.4189
0.7629
27.3641
0.2128
0
0.375
0
0

6
13
28.941
15.9195
0.838
30.0593
0.1974
0
0.4583
0
0

6
14
27.4163
18.9987
0.7599
27.2585
0.203
0
0.5417
0
0

6
15
28.7449
11.147
0.819
29.378
0.2121
0
0.625
0
0

6
16
0.9839
1.6606
−0.0142
−0.5093
−0.004
0
0
0
0

7
1
18.9135
12.9412
0.6042
21.6717
0.1144
0
0
0.125
0

7
2
20.7984
12.6454
0.6392
22.9269
0.1259
0
0
0.1964
0

7
3
21.3309
14.0442
0.6719
24.1021
0.1203
0
0
0.2679
0

7
4
23.3179
12.6244
0.7101
25.4707
0.1495
0
0
0.3393
0

7
5
22.311
15.9169
0.6986
25.0598
0.1228
0
0
0.4107
0

7
6
24.9395
15.9225
0.717
25.7205
0.1568
0
0
0.4821
0

7
7
27.218
13.6346
0.757
27.1547
0.194
0
0
0.5536
0

7
8
29.1374
13.3752
0.7671
27.5172
0.223
0
0
0.625
0

7
9
27.2823
14.9173
0.7823
28.0598
0.18
0
0.125
0
0

7
10
26.7129
17.0388
0.7718
27.6846
0.1641
0
0.2083
0
0

7
11
27.8928
14.018
0.8136
29.1832
0.1802
0
0.2917
0
0

7
12
27.6216
14.289
0.8323
29.8536
0.171
0
0.375
0
0

7
13
27.1789
15.5566
0.8155
29.2535
0.1736
0
0.4583
0
0

7
14
26.9576
15.5396
0.8192
29.3865
0.1669
0
0.5417
0
0

7
15
26.8378
18.0959
0.8043
28.8522
0.1535
0
0.625
0
0

7
16
0.8467
−0.7636
−0.0188
−0.6755
0.0049
0
0
0
0

8
1
19.7963
10.1989
0.6673
23.9369
0.121
0
0
0.125
0

8
2
21.0441
12.1292
0.6771
24.2868
0.1148
0
0
0.1964
0

8
3
21.5826
10.3589
0.7165
25.7009
0.1225
0
0
0.2679
0

8
4
22.5419
11.3314
0.748
26.8328
0.1302
0
0
0.3393
0

8
5
21.6915
15.8069
0.7002
25.1158
0.1194
0
0
0.4107
0

8
6
23.1549
15.2824
0.7452
26.7299
0.134
0
0
0.4821
0

8
7
25.5149
14.244
0.7133
25.5881
0.1741
0
0
0.5536
0

8
8
30.5353
11.7823
0.7776
27.8942
0.2489
0
0
0.625
0

8
9
27.3885
11.511
0.828
29.7013
0.1795
0
0.125
0
0

8
10
25.7173
17.922
0.7754
27.8131
0.1478
0
0.2083
0
0

8
11
26.4144
13.4264
0.8202
29.4217
0.1633
0
0.2917
0
0

8
12
27.705
13.0097
0.8866
31.8026
0.1641
0
0.375
0
0

8
13
25.995
17.4887
0.7963
28.5649
0.1547
0
0.4583
0
0

8
14
26.4681
16.9554
0.79
28.3384
0.1536
0
0.5417
0
0

8
15
26.4678
13.3955
0.8162
29.2769
0.159
0
0.625
0
0

8
16
0.9966
1.4271
−0.0301
1.0794
0.001
0
0
0
0

9
1
31.9347
0.0878
0.5856
21.005
0.3559
0
0
0
0.125

9
2
31.1011
4.4646
0.6363
22.8244
0.313
0
0
0
0.2083

9
3
30.3085
5.038
0.6449
23.1338
0.292
0
0
0
0.2917

9
4
34.5542
−0.385
0.6428
23.0592
0.3696
0
0
0
0.375

9
5
32.8174
2.5843
0.688
24.6778
0.3271
0
0
0
0.4583

9
6
33.2672
3.4632
0.7089
25.4293
0.3193
0
0
0
0.5417

9
7
33.3406
6.7818
0.7546
27.0667
0.3065
0
0
0
0.625

9
8
30.1425
10.1464
0.8068
28.94
0.2311
0.1275
0
0
0

9
9
26.7465
13.6126
0.797
28.5881
0.1718
0
0.125
0
0

9
10
25.7719
14.0036
0.7994
28.6761
0.1518
0
0.2083
0
0

9
11
26.5309
12.4669
0.8451
30.3128
0.1559
0
0.2917
0
0

9
12
25.9916
18.1407
0.7856
28.1815
0.1412
0
0.375
0
0

9
13
27.5347
12.2179
0.8823
31.65
0.1621
0
0.4583
0
0

9
14
27.449
13.4272
0.8785
31.514
0.1596
0
0.5417
0
0

9
15
27.2031
12.7934
0.8659
31.0587
0.16
0
0.625
0
0

9
16
1.4263
0.8064
−0.0206
−0.738
−0.008
0
0
0
0

10
1
32.3674
−1.4914
0.5724
20.534
0.364
0
0
0
0.125

10
2
29.9213
4.6079
0.6504
23.3302
0.2906
0
0
0
0.2083

10
3
31.2861
3.8032
0.6813
24.4397
0.2991
0
0
0
0.2917

10
4
30.3873
6.0311
0.7192
25.7991
0.267
0
0
0
0.375

10
5
28.9002
6.7708
0.7204
25.841
0.2411
0
0
0
0.4583

10
6
32.0239
4.8199
0.6949
24.9252
0.3029
0
0
0
0.5417

10
7
30.5572
5.6388
0.7245
25.9878
0.2706
0
0
0
0.625

10
8
40.4396
−5.5116
0.616
22.0945
0.4779
0
0
0
0

10
9
36.6242
−0.3514
0.6861
24.6123
0.3891
0
0
0
0

10
10
36.4527
2.4838
0.6743
24.1867
0.3709
0
0
0
0

10
11
41.5385
−5.8909
0.5621
20.1619
0.4989
0
0
0
0

10
12
40.6949
−2.4705
0.5969
21.4112
0.4762
0
0
0
0

10
13
42.2576
−5.7126
0.5576
20.0014
0.5199
0
0
0
0

10
14
41.6714
−3.6275
0.5605
20.1036
0.5139
0
0
0
0

10
15
42.1852
−8.2409
0.5642
20.2385
0.5399
0
0
0
0

10
16
29.0608
11.8827
0.7591
27.2282
0.2128
0.1275
0
0
0

11
1
28.5929
−0.5506
0.6211
22.279
0.2956
0
0
0
0.125

11
2
29.7686
2.427
0.6583
23.6124
0.3009
0
0
0
0.2083

11
3
27.9031
6.2226
0.7105
25.4845
0.2357
0
0
0
0.2917

11
4
27.7859
5.6743
0.7722
27.6991
0.2233
0
0
0
0.375

11
5
28.1184
7.2772
0.7741
27.7691
0.2183
0
0
0
0.4583

11
6
29.7411
6.3505
0.739
26.5098
0.2566
0
0
0
0.5417

11
7
28.9209
10.6911
0.7589
27.2215
0.2176
0
0
0
0.625

11
8
38.2687
−0.4875
0.6363
22.8233
0.4263
0
0
0
0

11
9
36.0972
1.1534
0.6782
24.3267
0.3858
0
0
0
0

11
10
37.1677
0.2763
0.6847
24.5606
0.3885
0
0
0
0

11
11
36.4236
−0.1779
0.7178
25.7481
0.3764
0
0
0
0

11
12
36.1786
1.7764
0.7141
25.6149
0.3717
0
0
0
0

11
13
36.8922
0.6262
0.7317
26.2452
0.3798
0
0
0
0

11
14
37.7602
−1.1368
0.6728
24.133
0.4075
0
0
0
0

11
15
37.5647
0.0323
0.6314
22.6471
0.4137
0
0
0
0

11
16
2.1619
−0.4379
0.0003
0.0124
0.0018
0
0
0
0

12
1
26.4704
3.8573
0.6373
22.8618
0.244
0
0
0
0.125

12
2
25.123
8.1044
0.6894
24.7289
0.1974
0
0
0
0.2083

12
3
25.0006
11.6691
0.6754
24.2266
0.1793
0
0
0
0.2917

12
4
25.7496
9.018
0.7275
26.094
0.1858
0
0
0
0.375

12
5
26.83
9.6173
0.7402
26.5507
0.1975
0
0
0
0.4583

12
6
27.8818
9.0527
0.7288
26.1427
0.2213
0
0
0
0.5417

12
7
27.1932
8.8863
0.7352
26.3714
0.2004
0
0
0
0.625

12
8
33.3109
4.6111
0.6956
24.952
0.3233
0
0
0
0

12
9
34.2433
1.3375
0.6874
24.657
0.3411
0
0
0
0

12
10
33.5455
4.5252
0.6868
24.6346
0.3233
0
0
0
0

12
11
33.7382
2.6662
0.6856
24.5945
0.3378
0
0
0
0

12
12
32.2421
4.4152
0.7066
25.3444
0.3056
0
0
0
0

12
13
32.1276
4.4582
0.7235
25.9518
0.2931
0
0
0
0

12
14
33.6765
4.2381
0.6886
24.6996
0.3353
0
0
0
0

12
15
32.8047
1.0222
0.6672
23.9322
0.335
0
0
0
0

12
16
0.201
−6.0934
−0.0375
−1.3439
−0.0082
0
0
0
0

13
1
23.6285
7.246
0.6392
22.9288
0.1884
0
0
0
0.125

13
2
24.886
9.7562
0.7072
25.3683
0.1859
0
0
0
0.2083

13
3
24.8624
12.4265
0.6961
24.9691
0.1723
0
0
0
0.2917

13
4
24.9826
10.6722
0.7365
26.4171
0.1754
0
0
0
0.375

13
5
25.7305
12.1843
0.7732
27.7354
0.1708
0
0
0
0.4583

13
6
25.6747
13.2113
0.7366
26.4231
0.1687
0
0
0
0.5417

13
7
26.0976
11.7018
0.7694
27.5973
0.172
0
0
0
0.625

13
8
30.4445
8.5999
0.7335
26.3099
0.2569
0
0
0
0

13
9
30.2838
9.6966
0.7263
26.0542
0.2549
0
0
0
0

13
10
30.4598
8.76
0.7709
27.6538
0.2542
0
0
0
0

13
11
30.3413
9.6956
0.7293
26.1594
0.2487
0
0
0
0

13
12
30.4805
9.6042
0.7384
26.487
0.2567
0
0
0
0

13
13
30.7866
8.4894
0.7264
26.0577
0.2594
0
0
0
0

13
14
30.0474
8.3188
0.7452
26.7323
0.2523
0
0
0
0

13
15
29.1492
8.7192
0.722
25.9001
0.2422
0
0
0
0

13
16
0.1828
−0.1024
−0.0281
−1.0092
−0.0071
0
0
0
0

14
1
22.2722
8.7244
0.645
23.1379
0.1695
0
0
0
0.125

14
2
22.5234
10.8931
0.7013
25.1544
0.1529
0
0
0
0.2083

14
3
23.2966
10.4674
0.73
26.1842
0.1515
0
0
0
0.2917

14
4
23.0657
11.1311
0.7205
25.8432
0.1445
0
0
0
0.375

14
5
23.5149
10.9662
0.7361
26.4053
0.1454
0
0
0
0.4583

14
6
24.2862
10.9726
0.7503
26.9142
0.1569
0
0
0
0.5417

14
7
24.5053
10.8821
0.7621
27.3379
0.1507
0
0
0
0.625

14
8
27.3028
9.2784
0.6918
24.8137
0.2118
0
0
0
0

14
9
27.5076
9.6923
0.7089
25.4269
0.2149
0
0
0
0

14
10
28.334
9.5711
0.7353
26.3752
0.2233
0
0
0
0

14
11
27.0996
10.2648
0.7052
25.2943
0.205
0
0
0
0

14
12
27.44
10.2454
0.7478
26.8252
0.2075
0
0
0
0

14
13
27.1174
10.8853
0.7218
25.8925
0.1998
0
0
0
0

14
14
27.7049
8.9747
0.7326
26.2773
0.2161
0
0
0
0

14
15
26.6173
9.1156
0.7031
25.2221
0.2044
0
0
0
0

14
16
0.0041
−1.9313
0.0371
1.3316
0.0149
0
0
0
0

15
1
21.3327
7.9702
0.6812
24.4361
0.1457
0
0
0
0.125

15
2
22.5406
10.7433
0.6941
24.897
0.164
0
0
0
0.2083

15
3
23.3395
12.6857
0.7286
26.1338
0.1508
0
0
0
0.2917

15
4
22.5094
11.0489
0.6988
25.0645
0.1555
0
0
0
0.375

15
5
24.0319
11.5771
0.7533
27.0223
0.1559
0
0
0
0.4583

15
6
23.7127
13.4441
0.7425
26.6323
0.1473
0
0
0
0.5417

15
7
23.9044
13.6139
0.74
26.5431
0.1463
0
0
0
0.625

15
8
27.3093
8.6187
0.6879
24.6757
0.2267
0
0
0
0

15
9
25.8606
9.1289
0.6874
24.6566
0.2042
0
0
0
0

15
10
27.5146
9.542
0.7239
25.968
0.2143
0
0
0
0

15
11
26.8709
11.7285
0.7185
25.7726
0.1928
0
0
0
0

15
12
27.18
9.7353
0.7526
26.9952
0.2076
0
0
0
0

15
13
26.1355
11.7091
0.7385
26.4915
0.193
0
0
0
0

15
14
26.448
10.1089
0.7389
26.504
0.1951
0
0
0
0

15
15
25.0723
11.1257
0.717
25.7198
0.1817
0
0
0
0

15
16
0.1716
0.3824
−0.0242
−0.8681
−0.0157
0
0
0
0

16
1
18.4383
9.1302
0.5999
21.5188
0.1141
0
0
0
0.125

16
2
19.8583
4.0253
0.4578
16.4203
0.1998
0
0
0
0.2083

16
3
19.5944
4.9317
0.4823
17.2995
0.1854
0
0
0
0.2917

16
4
20.6005
6.4056
0.535
19.1892
0.1902
0
0
0
0.375

16
5
20.7488
9.2272
0.6225
22.3294
0.16
0
0
0
0.4583

16
6
22.0224
9.9861
0.696
24.9647
0.1575
0
0
0
0.5417

16
7
22.6337
10.2429
0.6902
24.7569
0.1565
0
0
0
0.625

16
8
25.0532
7.0189
0.6701
24.0379
0.2148
0
0
0
0

16
9
24.7299
6.5606
0.6124
21.9688
0.2183
0
0
0
0

16
10
24.7277
6.8082
0.5753
20.6349
0.2229
0
0
0
0

16
11
24.3287
6.2367
0.5779
20.7309
0.22
0
0
0
0

16
12
23.4654
5.4951
0.5533
19.8459
0.2196
0
0
0
0

16
13
24.6899
6.4164
0.6203
22.2522
0.2161
0
0
0
0

16
14
23.6155
3.836
0.5379
19.2945
0.2324
0
0
0
0

16
15
22.1905
5.0337
0.5364
19.2395
0.212
0
0
0
0

16
16
27.2507
9.604
0.8059
28.9067
0.2014
0.1275
0
0
0

Tem-

pera-

ture:

PtNH32NO22

300 C.

(unsta-

SUM—
mol %
mol %
mol %
mol %
mol %
mol %

R
C
bilized)
RuNONO33
ZrONO32
micromols
C
Co
La
Pt
Ru
Zr

real
real
real
real
real

1
1
0
0
0
0.1275
0
0
0
100
0
0

1
2
0
0
0
0
0
0
0
0
0
0

1
3
0
0
0
0
0
0
0
0
0
0

1
4
0
0
0
0
0
0
0
0
0
0

1
5
0
0
0
0
0
0
0
0
0
0

1
6
0
0
0
0
0
0
0
0
0
0

1
7
0
0
0
0.1275
0
0
0
100
0
0

1
8
0
0
0
0
0
0
0
0
0
0

1
9
0
0
0
0
0
0
0
0
0
0

1
10
0
0
0
0
0
0
0
0
0
0

1
11
0
0
0
0
0
0
0
0
0
0

1
12
0
0
0
0
0
0
0
0
0
0

1
13
0
0
0
0.1275
0
0
0
100
0
0

1
14
0
0
0
0
0
0
0
0
0
0

1
15
0
0
0
0
0
0
0
0
0
0

1
16
0
0
0
0
0
0
0
0
0
0

2
1
0.1275
0.0618
0
0.3143
0
39.77
0
40.56
19.67
0

2
2
0.1275
0.0618
0
0.3857
0
50.92
0
33.05
16.02
0

2
3
0.1275
0.0618
0
0.4572
0
58.59
0
27.89
13.52
0

2
4
0.1275
0.0618
0
0.5286
0
64.19
0
24.12
11.69
0

2
5
0.1275
0.0618
0
0.6
0
68.45
0
21.25
10.3
0

2
6
0.1275
0.0618
0
0.6715
0
71.81
0
18.99
9.21
0

2
7
0.1275
0.0618
0
0.7429
0
74.52
0
17.16
8.32
0

2
8
0.1275
0.0618
0
0.8143
0
76.75
0
15.66
7.59
0

2
9
0.1275
0.0618
0
0.3143
39.77
0
0
40.56
19.67
0

2
10
0.1275
0.0618
0
0.3976
52.39
0
0
32.06
15.54
0

2
11
0.1275
0.0618
0
0.481
60.64
0
0
26.51
12.85
0

2
12
0.1275
0.0618
0
0.5643
66.45
0
0
22.59
10.95
0

2
13
0.1275
0.0618
0
0.6476
70.77
0
0
19.69
9.54
0

2
14
0.1275
0.0618
0
0.731
74.1
0
0
17.44
8.46
0

2
15
0.1275
0.0618
0
0.8143
76.75
0
0
15.66
7.59
0

2
16
0
0
0
0
0
0
0
0
0
0

3
1
0.1275
0.0536
0
0.3061
0
40.84
0
41.66
17.5
0

3
2
0.1275
0.0536
0
0.3775
0
52.03
0
33.77
14.19
0

3
3
0.1275
0.0536
0
0.4489
0
59.67
0
28.4
11.93
0

3
4
0.1275
0.0536
0
0.5204
0
65.2
0
24.5
10.3
0

3
5
0.1275
0.0536
0
0.5918
0
69.4
0
21.54
9.05
0

3
6
0.1275
0.0536
0
0.6632
0
72.7
0
19.22
8.08
0

3
7
0.1275
0.0536
0
0.7346
0
75.35
0
17.36
7.29
0

3
8
0.1275
0.0536
0
0.8061
0
77.54
0
15.82
6.65
0

3
9
0.1275
0.0547
0
0.3072
40.68
0
0
41.5
17.82
0

3
10
0.1275
0.0547
0
0.3906
53.34
0
0
32.64
14.02
0

3
11
0.1275
0.0547
0
0.4739
61.54
0
0
26.9
11.55
0

3
12
0.1275
0.0547
0
0.5572
67.29
0
0
22.88
9.82
0

3
13
0.1275
0.0547
0
0.6406
71.55
0
0
19.9
8.55
0

3
14
0.1275
0.0547
0
0.7239
74.82
0
0
17.61
7.56
0

3
15
0.1275
0.0547
0
0.8072
77.42
0
0
15.79
6.78
0

3
16
0
0
0
0
0
0
0
0
0
0

4
1
0.1275
0.0453
0
0.2978
0
41.97
0
42.81
15.22
0

4
2
0.1275
0.0453
0
0.3693
0
53.2
0
34.53
12.28
0

4
3
0.1275
0.0453
0
0.4407
0
60.78
0
28.93
10.29
0

4
4
0.1275
0.0453
0
0.5121
0
66.25
0
24.9
8.85
0

4
5
0.1275
0.0453
0
0.5835
0
70.38
0
21.85
7.77
0

4
6
0.1275
0.0453
0
0.655
0
73.61
0
19.47
6.92
0

4
7
0.1275
0.0453
0
0.7264
0
76.21
0
17.55
6.24
0

4
8
0.1275
0.0453
0
0.7978
0
78.34
0
15.98
5.68
0

4
9
0.1275
0.0477
0
0.3002
41.64
0
0
42.47
15.88
0

4
10
0.1275
0.0477
0
0.3835
54.32
0
0
33.24
12.43
0

4
11
0.1275
0.0477
0
0.4669
62.48
0
0
27.31
10.21
0

4
12
0.1275
0.0477
0
0.5502
68.16
0
0
23.17
8.67
0

4
13
0.1275
0.0477
0
0.6335
72.35
0
0
20.13
7.53
0

4
14
0.1275
0.0477
0
0.7169
75.56
0
0
17.79
6.65
0

4
15
0.1275
0.0477
0
0.8002
78.11
0
0
15.93
5.96
0

4
16
0
0
0
0.1275
0
0
0
100
0
0

5
1
0.1275
0.0371
0
0.2896
0
43.16
0
44.03
12.81
0

5
2
0.1275
0.0371
0
0.361
0
54.41
0
35.32
10.27
0

5
3
0.1275
0.0371
0
0.4324
0
61.94
0
29.48
8.58
0

5
4
0.1275
0.0371
0
0.5039
0
67.34
0
25.3
7.36
0

5
5
0.1275
0.0371
0
0.5753
0
71.39
0
22.16
6.45
0

5
6
0.1275
0.0371
0
0.6467
0
74.55
0
19.71
5.73
0

5
7
0.1275
0.0371
0
0.7182
0
77.08
0
17.75
5.16
0

5
8
0.1275
0.0371
0
0.7896
0
79.16
0
16.15
4.7
0

5
9
0.1275
0.0406
0
0.2931
42.64
0
0
43.5
13.86
0

5
10
0.1275
0.0406
0
0.3765
55.34
0
0
33.87
10.79
0

5
11
0.1275
0.0406
0
0.4598
63.44
0
0
27.73
8.83
0

5
12
0.1275
0.0406
0
0.5431
69.05
0
0
23.48
7.48
0

5
13
0.1275
0.0406
0
0.6265
73.16
0
0
20.35
6.48
0

5
14
0.1275
0.0406
0
0.7098
76.31
0
0
17.96
5.72
0

5
15
0.1275
0.0406
0
0.7931
78.8
0
0
16.08
5.12
0

5
16
0
0
0
0
0
0
0
0
0
0

6
1
0.1275
0.0288
0
0.2813
0
44.43
0
45.32
10.25
0

6
2
0.1275
0.0288
0
0.3528
0
55.68
0
36.14
8.18
0

6
3
0.1275
0.0288
0
0.4242
0
63.14
0
30.06
6.8
0

6
4
0.1275
0.0288
0
0.4956
0
68.46
0
25.72
5.82
0

6
5
0.1275
0.0288
0
0.5671
0
72.43
0
22.48
5.09
0

6
6
0.1275
0.0288
0
0.6385
0
75.51
0
19.97
4.52
0

6
7
0.1275
0.0288
0
0.7099
0
77.98
0
17.96
4.06
0

6
8
0.1275
0.0288
0
0.7813
0
79.99
0
16.32
3.69
0

6
9
0.1275
0.0336
0
0.2861
43.7
0
0
44.57
11.73
0

6
10
0.1275
0.0336
0
0.3694
56.4
0
0
34.52
9.08
0

6
11
0.1275
0.0336
0
0.4527
64.43
0
0
28.16
7.41
0

6
12
0.1275
0.0336
0
0.5361
69.96
0
0
23.78
6.26
0

6
13
0.1275
0.0336
0
0.6194
74
0
0
20.58
5.42
0

6
14
0.1275
0.0336
0
0.7027
77.08
0
0
18.14
4.78
0

6
15
0.1275
0.0336
0
0.7861
79.51
0
0
16.22
4.27
0

6
16
0
0
0
0
0
0
0
0
0
0

7
1
0.1275
0.0206
0
0.2731
0
45.77
0
46.69
7.54
0

7
2
0.1275
0.0206
0
0.3445
0
57.01
0
37.01
5.98
0

7
3
0.1275
0.0206
0
0.416
0
64.39
0
30.65
4.95
0

7
4
0.1275
0.0206
0
0.4874
0
69.61
0
26.16
4.23
0

7
5
0.1275
0.0206
0
0.5588
0
73.5
0
22.82
3.69
0

7
6
0.1275
0.0206
0
0.6302
0
76.5
0
20.23
3.27
0

7
7
0.1275
0.0206
0
0.7017
0
78.89
0
18.17
2.94
0

7
8
0.1275
0.0206
0
0.7731
0
80.84
0
16.49
2.67
0

7
9
0.1275
0.0265
0
0.279
44.8
0
0
45.7
9.5
0

7
10
0.1275
0.0265
0
0.3623
57.5
0
0
35.19
7.31
0

7
11
0.1275
0.0265
0
0.4457
65.45
0
0
28.61
5.94
0

7
12
0.1275
0.0265
0
0.529
70.89
0
0
24.1
5.01
0

7
13
0.1275
0.0265
0
0.6123
74.85
0
0
20.82
4.33
0

7
14
0.1275
0.0265
0
0.6957
77.86
0
0
18.33
3.81
0

7
15
0.1275
0.0265
0
0.779
80.23
0
0
16.37
3.4
0

7
16
0
0
0
0
0
0
0
0
0
0

8
1
0.1275
0.0124
0
0.2649
0
47.19
0
48.14
4.67
0

8
2
0.1275
0.0124
0
0.3363
0
58.41
0
37.91
3.68
0

8
3
0.1275
0.0124
0
0.4077
0
65.7
0
31.27
3.03
0

8
4
0.1275
0.0124
0
0.4791
0
70.81
0
26.61
2.58
0

8
5
0.1275
0.0124
0
0.5506
0
74.6
0
23.16
2.25
0

8
6
0.1275
0.0124
0
0.622
0
77.51
0
20.5
1.99
0

8
7
0.1275
0.0124
0
0.6934
0
79.83
0
18.39
1.78
0

8
8
0.1275
0.0124
0
0.7649
0
81.71
0
16.67
1.62
0

8
9
0.1275
0.0194
0
0.2719
45.97
0
0
46.89
7.14
0

8
10
0.1275
0.0194
0
0.3553
58.64
0
0
35.89
5.47
0

8
11
0.1275
0.0194
0
0.4386
66.5
0
0
29.07
4.43
0

8
12
0.1275
0.0194
0
0.5219
71.85
0
0
24.43
3.72
0

8
13
0.1275
0.0194
0
0.6053
75.73
0
0
21.07
3.21
0

8
14
0.1275
0.0194
0
0.6886
78.66
0
0
18.52
2.82
0

8
15
0.1275
0.0194
0
0.7719
80.97
0
0
16.52
2.52
0

8
16
0
0
0
0
0
0
0
0
0
0

9
1
0.1275
0.0618
0
0.3143
0
0
39.77
40.56
19.67
0

9
2
0.1275
0.0618
0
0.3976
0
0
52.39
32.06
15.54
0

9
3
0.1275
0.0618
0
0.481
0
0
60.64
26.51
12.85
0

9
4
0.1275
0.0618
0
0.5643
0
0
66.45
22.59
10.95
0

9
5
0.1275
0.0618
0
0.6476
0
0
70.77
19.69
9.54
0

9
6
0.1275
0.0618
0
0.731
0
0
74.1
17.44
8.46
0

9
7
0.1275
0.0618
0
0.8143
0
0
76.75
15.66
7.59
0

9
8
0
0
0
0.1275
0
0
0
100
0
0

9
9
0.1275
0.0124
0
0.2649
47.19
0
0
48.14
4.67
0

9
10
0.1275
0.0124
0
0.3482
59.83
0
0
36.62
3.55
0

9
11
0.1275
0.0124
0
0.4315
67.59
0
0
29.55
2.86
0

9
12
0.1275
0.0124
0
0.5149
72.83
0
0
24.76
2.4
0

9
13
0.1275
0.0124
0
0.5982
76.62
0
0
21.31
2.07
0

9
14
0.1275
0.0124
0
0.6815
79.48
0
0
18.71
1.81
0

9
15
0.1275
0.0124
0
0.7649
81.71
0
0
16.67
1.62
0

9
16
0
0
0
0
0
0
0
0
0
0

10
1
0.1275
0.0547
0
0.3072
0
0
40.68
41.5
17.82
0

10
2
0.1275
0.0547
0
0.3906
0
0
53.34
32.64
14.02
0

10
3
0.1275
0.0547
0
0.4739
0
0
61.54
26.9
11.55
0

10
4
0.1275
0.0547
0
0.5572
0
0
67.29
22.88
9.82
0

10
5
0.1275
0.0547
0
0.6406
0
0
71.55
19.9
8.55
0

10
6
0.1275
0.0547
0
0.7239
0
0
74.82
17.61
7.56
0

10
7
0.1275
0.0547
0
0.8072
0
0
77.42
15.79
6.78
0

10
8
0.1275
0.0618
0.125
0.3143
0
0
0
40.56
19.67
39.77

10
9
0.1275
0.0618
0.1964
0.3857
0
0
0
33.05
16.02
50.92

10
10
0.1275
0.0618
0.2679
0.4572
0
0
0
27.89
13.52
58.59

10
11
0.1275
0.0618
0.3393
0.5286
0
0
0
24.12
11.69
64.19

10
12
0.1275
0.0618
0.4107
0.6
0
0
0
21.25
10.3
68.45

10
13
0.1275
0.0618
0.4821
0.6715
0
0
0
18.99
9.21
71.81

10
14
0.1275
0.0618
0.5536
0.7429
0
0
0
17.16
8.32
74.52

10
15
0.1275
0.0618
0.625
0.8143
0
0
0
15.66
7.59
76.75

10
16
0
0
0
0.1275
0
0
0
100
0
0

11
1
0.1275
0.0477
0
0.3002
0
0
41.64
42.47
15.88
0

11
2
0.1275
0.0477
0
0.3835
0
0
54.32
33.24
12.43
0

11
3
0.1275
0.0477
0
0.4669
0
0
62.48
27.31
10.21
0

11
4
0.1275
0.0477
0
0.5502
0
0
68.16
23.17
8.67
0

11
5
0.1275
0.0477
0
0.6335
0
0
72.35
20.13
7.53
0

11
6
0.1275
0.0477
0
0.7169
0
0
75.56
17.79
6.65
0

11
7
0.1275
0.0477
0
0.8002
0
0
78.11
15.93
5.96
0

11
8
0.1275
0.0536
0.125
0.3061
0
0
0
41.66
17.5
40.84

11
9
0.1275
0.0536
0.1964
0.3775
0
0
0
33.77
14.19
52.03

11
10
0.1275
0.0536
0.2679
0.4489
0
0
0
28.4
11.93
59.67

11
11
0.1275
0.0536
0.3393
0.5204
0
0
0
24.5
10.3
65.2

11
12
0.1275
0.0536
0.4107
0.5918
0
0
0
21.54
9.05
69.4

11
13
0.1275
0.0536
0.4821
0.6632
0
0
0
19.22
8.08
72.7

11
14
0.1275
0.0536
0.5536
0.7346
0
0
0
17.36
7.29
75.35

11
15
0.1275
0.0536
0.625
0.8061
0
0
0
15.82
6.65
77.54

11
16
0
0
0
0
0
0
0
0
0
0

12
1
0.1275
0.0406
0
0.2931
0
0
42.64
43.5
13.86
0

12
2
0.1275
0.0406
0
0.3765
0
0
55.34
33.87
10.79
0

12
3
0.1275
0.0406
0
0.4598
0
0
63.44
27.73
8.83
0

12
4
0.1275
0.0406
0
0.5431
0
0
69.05
23.48
7.48
0

12
5
0.1275
0.0406
0
0.6265
0
0
73.16
20.35
6.48
0

12
6
0.1275
0.0406
0
0.7098
0
0
76.31
17.96
5.72
0

12
7
0.1275
0.0406
0
0.7931
0
0
78.8
16.08
5.12
0

12
8
0.1275
0.0453
0.125
0.2978
0
0
0
42.81
15.22
41.97

12
9
0.1275
0.0453
0.1964
0.3693
0
0
0
34.53
12.28
53.2

12
10
0.1275
0.0453
0.2679
0.4407
0
0
0
28.93
10.29
60.78

12
11
0.1275
0.0453
0.3393
0.5121
0
0
0
24.9
8.85
66.25

12
12
0.1275
0.0453
0.4107
0.5835
0
0
0
21.85
7.77
70.38

12
13
0.1275
0.0453
0.4821
0.655
0
0
0
19.47
6.92
73.61

12
14
0.1275
0.0453
0.5536
0.7264
0
0
0
17.55
6.24
76.21

12
15
0.1275
0.0453
0.625
0.7978
0
0
0
15.98
5.68
78.34

12
16
0
0
0
0
0
0
0
0
0
0

13
1
0.1275
0.0336
0
0.2861
0
0
43.7
44.57
11.73
0

13
2
0.1275
0.0336
0
0.3694
0
0
56.4
34.52
9.08
0

13
3
0.1275
0.0336
0
0.4527
0
0
64.43
28.16
7.41
0

13
4
0.1275
0.0336
0
0.5361
0
0
69.96
23.78
6.26
0

13
5
0.1275
0.0336
0
0.6194
0
0
74
20.58
5.42
0

13
6
0.1275
0.0336
0
0.7027
0
0
77.08
18.14
4.78
0

13
7
0.1275
0.0336
0
0.7861
0
0
79.510939 28
16.22
4.27
0

13
8
0.1275
0.0371
0.125
0.2896
0
0
0
44.03
12.81
43.16

13
9
0.1275
0.0371
0.1964
0.361
0
0
0
35.32
10.27
54.41

13
10
0.1275
0.0371
0.2679
0.4324
0
0
0
29.48
8.58
61.94

13
11
0.1275
0.0371
0.3393
0.5039
0
0
0
25.3
7.36
67.34

13
12
0.1275
0.0371
0.4107
0.5753
0
0
0
22.16
6.45
71.39

13
13
0.1275
0.0371
0.4821
0.6467
0
0
0
19.71
5.73
74.55

13
14
0.1275
0.0371
0.5536
0.7182
0
0
0
17.75
5.16
77.08

13
15
0.1275
0.0371
0.625
0.7896
0
0
0
16.15
4.7
79.16

13
16
0
0
0
0
0
0
0
0
0
0

14
1
0.1275
0.0265
0
0.279
0
0
44.8
45.7
9.5
0

14
2
0.1275
0.0265
0
0.3623
0
0
57.5
35.19
7.31
0

14
3
0.1275
0.0265
0
0.4457
0
0
65.45
28.61
5.94
0

14
4
0.1275
0.0265
0
0.529
0
0
70.89
24.1
5.01
0

14
5
0.1275
0.0265
0
0.6123
0
0
74.85
20.82
4.33
0

14
6
0.1275
0.0265
0
0.6957
0
0
77.86
18.33
3.81
0

14
7
0.1275
0.0265
0
0.779
0
0
80.23
16.37
3.4
0

14
8
0.1275
0.0288
0.125
0.2813
0
0
0
45.32
10.25
44.43

14
9
0.1275
0.0288
0.1964
0.3528
0
0
0
36.14
8.18
55.68

14
10
0.1275
0.0288
0.2679
0.4242
0
0
0
30.06
6.8
63.14

14
11
0.1275
0.0288
0.3393
0.4956
0
0
0
25.72
5.82
68.46

14
12
0.1275
0.0288
0.4107
0.5671
0
0
0
22.48
5.09
72.43

14
13
0.1275
0.0288
0.4821
0.6385
0
0
0
19.97
4.52
75.51

14
14
0.1275
0.0288
0.5536
0.7099
0
0
0
17.96
4.06
77.98

14
15
0.1275
0.0288
0.625
0.7813
0
0
0
16.32
3.69
79.99

14
16
0
0
0
0
0
0
0
0
0
0

15
1
0.1275
0.0194
0
0.2719
0
0
45.97
46.89
7.14
0

15
2
0.1275
0.0194
0
0.3553
0
0
58.64
35.89
5.47
0

15
3
0.1275
0.0194
0
0.4386
0
0
66.5
29.07
4.43
0

15
4
0.1275
0.0194
0
0.5219
0
0
71.85
24.43
3.72
0

15
5
0.1275
0.0194
0
0.6053
0
0
75.73
21.07
3.21
0

15
6
0.1275
0.0194
0
0.6886
0
0
78.66
18.52
2.82
0

15
7
0.1275
0.0194
0
0.7719
0
0
80.97
16.52
2.52
0

15
8
0.1275
0.0206
0.125
0.2731
0
0
0
46.69
7.54
45.77

15
9
0.1275
0.0206
0.1964
0.3445
0
0
0
37.01
5.98
57.01

15
10
0.1275
0.0206
0.2679
0.416
0
0
0
30.65
4.95
64.39

15
11
0.1275
0.0206
0.3393
0.4874
0
0
0
26.16
4.23
69.61

15
12
0.1275
0.0206
0.4107
0.5588
0
0
0
22.82
3.69
73.5

15
13
0.1275
0.0206
0.4821
0.6302
0
0
0
20.23
3.27
76.5

15
14
0.1275
0.0206
0.5536
0.7017
0
0
0
18.17
2.94
78.89

15
15
0.1275
0.0206
0.625
0.7731
0
0
0
16.49
2.67
80.84

15
16
0
0
0
0
0
0
0
0
0
0

16
1
0.1275
0.0124
0
0.2649
0
0
47.19
48.14
4.67
0

16
2
0.1275
0.0124
0
0.3482
0
0
59.83
36.62
3.55
0

16
3
0.1275
0.0124
0
0.4315
0
0
67.59
29.55
2.86
0

16
4
0.1275
0.0124
0
0.5149
0
0
72.83
24.76
2.4
0

16
5
0.1275
0.0124
0
0.5982
0
0
76.62
21.31
2.07
0

16
6
0.1275
0.0124
0
0.6815
0
0
79.48
18.71
1.81
0

16
7
0.1275
0.0124
0
0.7649
0
0
81.71
16.67
1.62
0

16
8
0.1275
0.0124
0.125
0.2649
0
0
0
48.14
4.67
47.19

16
9
0.1275
0.0124
0.1964
0.3363
0
0
0
37.91
3.68
58.41

16
10
0.1275
0.0124
0.2679
0.4077
0
0
0
31.27
3.03
65.7

16
11
0.1275
0.0124
0.3393
0.4791
0
0
0
26.61
2.58
70.81

16
12
0.1275
0.0124
0.4107
0.5506
0
0
0
23.16
2.25
74.6

16
13
0.1275
0.0124
0.4821
0.622
0
0
0
20.5
1.99
77.51

16
14
0.1275
0.0124
0.5536
0.6934
0
0
0
18.39
1.78
79.83

16
15
0.1275
0.0124
0.625
0.7649
0
0
0
16.67
1.62
81.71

16
16
0
0
0
0.1275
0
0
0
100
0
0

[0297]

10

TABLE III

Tem-

pera-

ture:

350 C.

Pt1.O%/

R
C
COCONV
H2OCONV
C02PROD
C02PERPROD
CH4PROD
ZrO2_std
FeNO33
LaNO33
NH42TiOOX2
PtNH32NO22

real
real
real
real
real
real
real
real
real
real
real
real

1
1
20.7413
4.5453
0.4037
14.2873
0.2832
0.1275
0
0
0
0

1
2
1.0598
3.2201
0.0461
1.6326
0.0082
0
0
0
0
0

1
3
0.3696
3.2009
0.0209
0.7387
−0.0014
0
0
0
0
0

1
4
−1.0203
−0.9111
0.0365
1.2925
0.0097
0
0
0
0
0

1
5
−2.8069
−1.4712
−0.0045
−0.1594
0.0035
0
0
0
0
0

1
6
1.2699
0.7698
0.0267
0.9456
−0.0025
0
0
0
0
0

1
7
22.8232
0.1219
0.3846
13.6114
0.2965
0.1275
0
0
0
0

1
8
0.4252
0.1401
0.0533
1.8856
0.0072
0
0
0
0
0

1
9
1.4669
−0.5073
−0.0007
−0.0261
0.0032
0
0
0
0
0

1
10
2.0773
−1.1689
−0.0485
−1.718
0.0095
0
0
0
0
0

1
11
−0.8957
−0.9498
−0.0091
−0.323
0.0031
0
0
0
0
0

1
12
−0.3021
−1.806
0.0083
0.2942
0.0111
0
0
0
0
0

1
13
25.9974
0.7334
0.3505
12.4037
0.2894
0.1275
0
0
0
0

1
14
1.2968
0.9153
−0.0072
−0.2552
−0.0033
0
0
0
0
0

1
15
0.893
−1.0793
−0.0514
−1.8181
−0.0164
0
0
0
0
0

1
16
−3.6064
−2.6611
−0.0589
−2.0841
−0.0103
0
0
0
0
0

2
1
36.4164
−9.1836
0.224
7.9287
0.4854
0
0
0
0.25
0.1275

2
2
32.2119
−6.3228
0.3721
13.1684
0.4486
0
0
0
0.3571
0.1275

2
3
29.8229
−1.9943
0.4247
15.0311
0.3876
0
0
0
0.4643
0.1275

2
4
27.3051
1.7265
0.4455
15.7652
0.3255
0
0
0
0.5714
0.1275

2
5
22.2937
4.0704
0.4641
16.4261
0.2389
0
0
0
0.6786
0.1275

2
6
29.9281
2.3445
0.375
13.2711
0.3194
0
0
0
0.7857
0.1275

2
7
24.6797
1.8511
0.4513
15.9733
0.28
0
0
0
0.8929
0.1275

2
8
28.5064
−0.3051
0.3989
14.1171
0.2946
0
0
0
1
0.1275

2
9
38.4488
−15.6748
0.167
5.9104
0.5834
0
0
0
0
0.1275

2
10
40.0503
−15.804
0.1247
4.4135
0.5902
0
0
0
0
0.1275

2
11
33.9267
−10.9429
0.2674
9.463
0.5144
0
0
0
0
0.1275

2
12
38.1132
−13.3928
0.2259
7.9943
0.5492
0
0
0
0
0.1275

2
13
34.3869
−10.4026
0.257
9.0953
0.4914
0
0
0
0
0.1275

2
14
31.4203
−8.6136
0.2798
9.9036
0.4646
0
0
0
0
0.1275

2
15
29.7046
−7.6415
0.3448
12.2034
0.4301
0
0
0
0
0.1275

2
16
−1.8459
−1.4873
−0.0338
−1.1967
−0.0128
0
0
0
0
0

3
1
31.7288
−7.8872
0.2471
8.7457
0.4413
0
0
0
0.25
0.1275

3
2
34.0629
−5.6821
0.256
9.0589
0.4354
0
0
0
0.3571
0.1275

3
3
29.4633
−2.7934
0.4371
15.4689
0.3748
0
0
0
0.4643
0.1275

3
4
30.2582
−0.7269
0.38
13.4485
0.3535
0
0
0
0.5714
0.1275

3
5
29.4253
1.5896
0.3706
13.1141
0.3126
0
0
0
0.6786
0.1275

3
6
26.3528
1.2142
0.4479
15.8514
0.3145
0
0
0
0.7857
0.1275

3
7
25.601
3.7998
0.4435
15.696
0.2671
0
0
0
0.8929
0.1275

3
8
28.0192
0.1689
0.3905
13.8196
0.3192
0
0
0
1
0.1275

3
9
36.7685
−14.6028
0.1933
6.8418
0.585
0
0
0
0
0.1275

3
10
38.5741
−13.8552
0.1662
5.8823
0.5767
0
0
0
0
0.1275

3
11
34.4052
−10.9205
0.2356
8.3394
0.5019
0
0
0
0
0.1275

3
12
35.2739
−11.206
0.2317
8.1987
0.5274
0
0
0
0
0.1275

3
13
33.0412
−8.7461
0.2758
9.7594
0.4592
0
0
0
0
0.1275

3
14
31.7936
−7.5655
0.2977
10.5345
0.423
0
0
0
0
0.1275

3
15
29.6191
−5.2198
0.3214
11.374
0.3907
0
0
0
0
0.1275

3
16
3.3918
1.8726
0.022
0.777
−0.0062
0
0
0
0
0

4
1
30.7111
−6.7516
0.2778
9.8331
0.4345
0
0
0
0.25
0.1275

4
2
34.112
−8.2462
0.3332
11.7925
0.4978
0
0
0
0.3571
0.1275

4
3
33.5412
−4.8305
0.3278
11.5992
0.443
0
0
0
0.4643
0.1275

4
4
31.9087
−3.1967
0.3645
12.8999
0.3859
0
0
0
0.5714
0.1275

4
5
29.1731
−1.3136
0.3976
14.0705
0.3672
0
0
0
0.6786
0.1275

4
6
28.959
1.8937
0.4366
15.4518
0.3113
0
0
0
0.7857
0.1275

4
7
26.9015
0.3211
0.3995
14.1375
0.3117
0
0
0
0.8929
0.1275

4
8
26.7599
−1.572
0.439
15.5364
0.3368
0
0
0
1
0.1275

4
9
36.6065
−14.1833
0.204
7.2199
0.5364
0
0
0
0
0.1275

4
10
37.5816
−14.2423
0.229
8.1061
0.5755
0
0
0
0
0.1275

4
11
35.0624
−10.1028
0.2407
8.5191
0.5053
0
0
0
0
0.1275

4
12
33.2279
−9.7613
0.2899
10.2593
0.4724
0
0
0
0
0.1275

4
13
34.1838
−7.8874
0.2324
8.2249
0.4515
0
0
0
0
0.1275

4
14
29.5376
−2.5807
0.2827
10.0032
0.3721
0
0
0
0
0.1275

4
15
30.3227
−4.5925
0.2567
9.083
0.4123
0
0
0
0
0.1275

4
16
22.7864
−1.4265
0.358
12.6711
0.3074
0.1275
0
0
0
0

5
1
30.9515
−6.8352
0.2834
10.0285
0.4339
0
0
0
0.25
0.1275

5
2
33.089
−7.242
0.3069
10.8609
0.4608
0
0
0
0.3571
0.1275

5
3
30.0762
−2.4391
0.3773
13.3544
0.3784
0
0
0
0.4643
0.1275

5
4
29.2359
−1.2812
0.3524
12.4716
0.3598
0
0
0
0.5714
0.1275

5
5
27.9512
−0.1446
0.4363
15.4392
0.3348
0
0
0
0.6786
0.1275

5
6
27.6019
0.704
0.4437
15.7037
0.322
0
0
0
0.7857
0.1275

5
7
24.3249
2.9181
0.4752
16.8168
0.2789
0
0
0
0.8929
0.1275

5
8
26.7686
2.751
0.4201
14.8681
0.3014
0
0
0
1
0.1275

5
9
35.0835
−10.3253
0.223
7.8906
0.5058
0
0
0
0
0.1275

5
10
34.9171
−11.3667
0.2561
9.0638
0.5114
0
0
0
0
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31.6349
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27.1453
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26.8358
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32.6313
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6
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27.041
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7
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7
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29.9105
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7
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8
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25.981
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8
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8
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23.6274
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8
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8
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8
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8
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8
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0.5678
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9
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9
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9
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9
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9
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9
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9
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9
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9
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9
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9
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9
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9
16
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10
1
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10
2
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10
3
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10
4
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10
5
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10
6
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10
7
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10
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10
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10
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10
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10
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10
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10
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10
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11
7
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11
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9
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7
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8
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9
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12
11
29.2723
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12
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1
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13
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13
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13
4
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5
24.2518
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13
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13
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8
30.5494
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13
9
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26.763
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13
11
23.8381
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13
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24.4559
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13
13
22.6291
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13
14
22.058
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13
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13
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14
1
23.1422
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14
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23.5238
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14
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5
19.1287
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14
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14
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14
8
26.1629
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14
9
27.6928
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14
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23.6323
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14
11
22.9238
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14
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20.0974
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14
13
20.8567
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14
14
20.5092
3.8209
0.4542
16.0726
0.246
0
0
0.8929
0
0.1275

14
15
19.5783
3.9669
0.4226
14.9574
0.2347
0
0
1
0
0.1275

14
16
−1.2663
0.2287
0.0049
0.1744
0.0028
0
0
0
0
0

15
1
19.7175
1.5028
0.4362
15.4385
0.251
0
0.25
0
0
0.1275

15
2
18.0113
3.3898
0.3705
13.1108
0.2201
0
0.375
0
0
0.1275

15
3
15.9884
3.6197
0.375
13.2711
0.2024
0
0.5
0
0
0.1275

15
4
14.8384
6.1755
0.3784
13.3915
0.1718
0
0.625
0
0
0.1275

15
5
17.968
4.6171
0.3723
13.1769
0.2031
0
0.75
0
0
0.1275

15
6
12.6392
8.1823
0.4391
15.54
0.1278
0
0.875
0
0
0.1275

15
7
12.908
10.31
0.421
14.899
0.1178
0
1
0
0
0.1275

15
8
22.4908
3.7563
0.4451
15.7514
0.2796
0
0
0.25
0
0.1275

15
9
20.5065
4.7112
0.4265
15.0938
0.2479
0
0
0.3571
0
0.1275

15
10
20.472
5.2749
0.4461
15.7859
0.2487
0
0
0.4643
0
0.1275

15
11
19.2131
5.2423
0.4553
16.1141
0.2276
0
0
0.5714
0
0.1275

15
12
19.315
5.6034
0.4378
15.4948
0.222
0
0
0.6786
0
0.1275

15
13
19.2915
5.4631
0.4068
14.3951
0.2215
0
0
0.7857
0
0.1275

15
14
19.5125
4.9808
0.4193
14.8397
0.2264
0
0
0.8929
0
0.1275

15
15
19.5687
5.6104
0.4234
14.9856
0.2286
0
0
1
0
0.1275

15
16
1.5744
2.0866
0.0612
2.1664
0.0059
0
0
0
0
0

16
1
15.3115
8.3071
0.4772
16.8896
0.1389
0
0.25
0
0
0.1275

16
2
5.2619
4.7062
0.2088
7.3912
0.0611
0
0.375
0
0
0.1275

16
3
4.8009
4.1018
0.1945
6.8835
0.0422
0
0.5
0
0
0.1275

16
4
3.6868
3.1471
0.1868
6.6103
0.0426
0
0.625
0
0
0.1275

16
5
6.4671
6.2139
0.2776
9.8227
0.0482
0
0.75
0
0
0.1275

16
6
10.0153
8.3873
0.3889
13.7622
0.0946
0
0.875
0
0
0.1275

16
7
9.1584
7.6145
0.405
14.3326
0.0867
0
1
0
0
0.1275

16
8
20.3819
3.6436
0.397
14.051
0.2505
0
0
0.25
0
0.1275

16
9
20.4977
2.9382
0.3951
13.9812
0.2412
0
0
0.3571
0
0.1275

16
10
17.6443
2.4709
0.3937
13.9331
0.2379
0
0
0.4643
0
0.1275

16
11
17.6931
2.9484
0.3976
14.0709
0.2315
0
0
0.5714
0
0.1275

16
12
14.4659
1.353
0.3206
11.3452
0.2104
0
0
0.6786
0
0.1275

16
13
14.2303
1.2746
0.2638
9.3376
0.1943
0
0
0.7857
0
0.1275

16
14
14.9027
1.4698
0.3273
11.5832
0.2194
0
0
0.8929
0
0.1275

16
15
12.5533
1.487
0.2375
8.406
0.1927
0
0
1
0
0.1275

16
16
20.3125
2.973
0.4288
15.1746
0.2463
0.1275
0
0
0
0

Tem-

pera-

ture:

350 C.

SUM—
mol %
mol %
mol %
mol %
mol %
mol %

R
C
RuNONO33
ZrONO32
micromols
Fe
La
Ti
Pt
Ru
Zr

real
real
real
real

1
1
0
0
0.1275
0
0
0
100
0
0

1
2
0
0
0
0
0
0
0
0
0

1
3
0
0
0
0
0
0
0
0
0

1
4
0
0
0
0
0
0
0
0
0

1
5
0
0
0
0
0
0
0
0
0

1
6
0
0
0
0
0
0
0
0
0

1
7
0
0
0.1275
0
0
0
100
0
0

1
8
0
0
0
0
0
0
0
0
0

1
9
0
0
0
0
0
0
0
0
0

1
10
0
0
0
0
0
0
0
0
0

1
11
0
0
0
0
0
0
0
0
0

1
12
0
0
0
0
0
0
0
0
0

1
13
0
0
0.1275
0
0
0
100
0
0

1
14
0
0
0
0
0
0
0
0
0

1
15
0
0
0
0
0
0
0
0
0

1
16
0
0
0
0
0
0
0
0
0

2
1
0.0989
0
0.4764
0
0
52.48
26.76
20.76
0

2
2
0.0989
0
0.5835
0
0
61.2
21.85
16.95
0

2
3
0.0989
0
0.6907
0
0
67.22
18.46
14.32
0

2
4
0.0989
0
0.7978
0
0
71.62
15.98
12.4
0

2
5
0.0989
0
0.905
0
0
74.98
14.09
10.93
0

2
6
0.0989
0
1.0121
0
0
77.63
12.6
9.77
0

2
7
0.0989
0
1.1193
0
0
79.77
11.39
8.84
0

2
8
0.0989
0
1.2264
0
0
81.54
10.4
8.06
0

2
9
0.0989
0.25
0.4764
0
0
0
26.76
20.76
52.48

2
10
0.0989
0.375
0.6014
0
0
0
21.2
16.44
62.35

2
11
0.0989
0.5
0.7264
0
0
0
17.55
13.62
68.83

2
12
0.0989
0.625
0.8514
0
0
0
14.98
11.62
73.41

2
13
0.0989
0.75
0.9764
0
0
0
13.06
10.13
76.81

2
14
0.0989
0.875
1.1014
0
0
0
11.58
8.98
79.44

2
15
0.0989
1
1.2264
0
0
0
10.4
8.06
81.54

2
16
0
0
0
0
0
0
0
0
0

3
1
0.0865
0
0.464
0
0
53.87
27.48
18.65
0

3
2
0.0865
0
0.5712
0
0
62.53
22.32
15.15
0

3
3
0.0865
0
0.6783
0
0
68.45
18.8
12.76
0

3
4
0.0865
0
0.7855
0
0
72.75
16.23
11.02
0

3
5
0.0865
0
0.8926
0
0
76.02
14.28
9.69
0

3
6
0.0865
0
0.9998
0
0
78.59
12.75
8.66
0

3
7
0.0865
0
1.1069
0
0
80.66
11.52
7.82
0

3
8
0.0865
0
1.214
0
0
82.37
10.5
7.13
0

3
9
0.0883
0.25
0.4658
0
0
0
27.37
18.96
53.67

3
10
0.0883
0.375
0.5908
0
0
0
21.58
14.95
63.47

3
11
0.0883
0.5
0.7158
0
0
0
17.81
12.34
69.85

3
12
0.0883
0.625
0.8408
0
0
0
15.16
10.5
74.33

3
13
0.0883
0.75
0.9658
0
0
0
13.2
9.14
77.66

3
14
0.0883
0.875
1.0908
0
0
0
11.69
8.1
80.22

3
15
0.0883
1
1.2158
0
0
0
10.49
7.26
82.25

3
16
0
0
0
0
0
0
0
0
0

4
1
0.0742
0
0.4517
0
0
55.35
28.23
16.42
0

4
2
0.0742
0
0.5588
0
0
63.91
22.82
13.27
0

4
3
0.0742
0
0.666
0
0
69.72
19.15
11.14
0

4
4
0.0742
0
0.7731
0
0
73.91
16.49
9.59
0

4
5
0.0742
0
0.8802
0
0
77.09
14.48
8.43
0

4
6
0.0742
0
0.9874
0
0
79.57
12.91
7.51
0

4
7
0.0742
0
1.0945
0
0
81.57
11.65
6.78
0

4
8
0.0742
0
1.2017
0
0
83.22
10.61
6.17
0

4
9
0.0777
0.25
0.4552
0
0
0
28.01
17.07
54.92

4
10
0.0777
0.375
0.5802
0
0
0
21.97
13.39
64.63

4
11
0.0777
0.5
0.7052
0
0
0
18.08
11.02
70.9

4
12
0.0777
0.625
0.8302
0
0
0
15.36
9.36
75.28

4
13
0.0777
0.75
0.9552
0
0
0
13.35
8.14
78.52

4
14
0.0777
0.875
1.0802
0
0
0
11.8
7.19
81

4
15
0.0777
1
1.2052
0
0
0
10.58
6.45
82.97

4
16
0
0
0.1275
0
0
0
100
0
0

5
1
0.0618
0
0.4393
0
0
56.91
29.02
14.07
0

5
2
0.0618
0
0.5465
0
0
65.36
23.33
11.31
0

5
3
0.0618
0
0.6536
0
0
71.04
19.51
9.46
0

5
4
0.0618
0
0.7607
0
0
75.11
16.76
8.13
0

5
5
0.0618
0
0.8679
0
0
78.19
14.69
7.12
0

5
6
0.0618
0
0.975
0
0
80.58
13.08
6.34
0

5
7
0.0618
0
1.0822
0
0
82.51
11.78
5.71
0

5
8
0.0618
0
1.1893
0
0
84.08
10.72
5.2
0

5
9
0.0671
0.25
0.4446
0
0
0
28.68
15.09
56.23

5
10
0.0671
0.375
0.5696
0
0
0
22.38
11.78
65.83

5
11
0.0671
0.5
0.6946
0
0
0
18.36
9.66
71.98

5
12
0.0671
0.625
0.8196
0
0
0
15.56
8.19
76.26

5
13
0.0671
0.75
0.9446
0
0
0
13.5
7.1
79.4

5
14
0.0671
0.875
1.0696
0
0
0
11.92
6.27
81.81

5
15
0.0671
1
1.1946
0
0
0
10.67
5.62
83.71

5
16
0
0
0
0
0
0
0
0
0

6
1
0.0495
0
0.427
0
0
58.55
29.86298161
11.58215248
0

6
2
0.0495
0
0.5341
0
0
66.87
23.87
9.26
0

6
3
0.0495
0
0.6412
0
0
72.4
19.88
7.71
0

6
4
0.0495
0
0.7484
0
0
76.36
17.04
6.61
0

6
5
0.0495
0
0.8555
0
0
79.32
14.9
5.78
0

6
5
0.0495
0
0.9627
0
0
81.62
13.24
5.14
0

6
7
0.0495
0
1.0698
0
0
83.46
11.92
4.62
0

6
8
0.0495
0
1.177
0
0
84.97
10.83
4.2
0

6
9
0.0565
0.25
0.434
0
0
0
29.38
13.02
57.6

6
10
0.0565
0.375
0.559
0
0
0
22.81
10.11
67.08

6
11
0.0565
0.5
0.684
0
0
0
18.64
8.26
73.1

6
12
0.0565
0.625
0.809
0
0
0
15.76
6.99
77.25

6
13
0.0565
0.75
0.934
0
0
0
13.65
6.05
80.3

6
14
0.0565
0.875
1.059
0
0
0
12.04
5.34
82.62

6
15
0.0565
1
1.184
0
0
0
10.77
4.77
84.46

6
16
0
0
0
0
0
0
0
0
0

7
1
0.0371
0
0.4146
0
0
60.3
30.75
8.95
0

7
2
0.0371
0
0.5217
0
0
68.45
24.44
7.11
0

7
3
0.0371
0
0.6289
0
0
73.83
20.27
5.9
0

7
4
0.0371
0
0.736
0
0
77.64
17.32
5.04
0

7
5
0.0371
0
0.8432
0
0
80.48
15.12
4.4
0

7
6
0.0371
0
0.9503
0
0
82.68
13.42
3.9
0

7
7
0.0371
0
1.0574
0
0
84.44
12.06
3.51
0

7
8
0.0371
0
1.1646
0
0
85.87
10.95
3.18
0

7
9
0.0459
0.25
0.4234
0
0
0
30.11
10.84
59.04

7
10
0.0459
0.375
0.5484
0
0
0
23.25
8.37
68.38

7
11
0.0459
0.5
0.6734
0
0
0
18.93
6.82
74.25

7
12
0.0459
0.625
0.7984
0
0
0
15.97
5.75
78.28

7
13
0.0459
0.75
0.9234
0
0
0
13.81
4.97
81.22

7
14
0.0459
0.875
1.0484
0
0
0
12.16
4.38
83.46

7
15
0.0459
1
1.1734
0
0
0
10.87
3.91
85.22

7
16
0
0
0
0
0
0
0
0
0

8
1
0.0247
0
0.4022
0
0
62.15
31.7
6.15
0

8
2
0.0247
0
0.5094
0
0
70.11
25.03
4.85
0

8
3
0.0247
0
0.6165
0
0
75.31
20.68
4.01
0

8
4
0.0247
0
0.7237
0
0
78.96
17.62
3.42
0

8
5
0.0247
0
0.8308
0
0
81.68
15.35
2.98
0

8
6
0.0247
0
0.9379
0
0
83.77
13.59
2.64
0

8
7
0.0247
0
1.0451
0
0
85.43
12.2
2.37
0

8
8
0.0247
0
1.1522
0
0
86.79
11.07
2.15
0

8
9
0.0353
0.25
0.4128
0
0
0
30.89
8.56
60.56

8
10
0.0353
0.375
0.5378
0
0
0
23.71
6.57
69.73

8
11
0.0353
0.5
0.6628
0
0
0
19.24
5.33
75.44

8
12
0.0353
0.625
0.7878
0
0
0
16.18
4.48
79.33

8
13
0.0353
0.75
0.9128
0
0
0
13.97
3.87
82.16

8
14
0.0353
0.875
1.0378
0
0
0
12.29
3.4
84.31

8
15
0.0353
1
1.1628
0
0
0
10.96
3.04
86

8
16
0
0
0
0
0
0
0
0
0

9
1
0.0989
0
0.4764
52.48
0
0
26.76
20.76
0

9
2
0.0989
0
0.6014
62.35
0
0
21.2
16.44
0

9
3
0.0989
0
0.7264
68.83
0
0
17.55
13.62
0

9
4
0.0989
0
0.8514
73.41
0
0
14.98
11.62
0

9
5
0.0989
0
0.9764
76.81
0
0
13.06
10.13
0

9
6
0.0989
0
1.1014
79.44
0
0
11.58
8.98
0

9
7
0.0989
0
1.2264
81.54
0
0
10.4
8.06
0

9
8
0
0
0.1275
0
0
0
100
0
0

9
9
0.0247
0.25
0.4022
0
0
0
31.7
6.15
62.15

9
10
0.0247
0.375
0.5272
0
0
0
24.18
4.69
71.13

9
11
0.0247
0.5
0.6522
0
0
0
19.55
3.79
76.66

9
12
0.0247
0.625
0.7772
0
0
0
16.4
3.18
80.41

9
13
0.0247
0.75
0.9022
0
0
0
14.13
2.74
83.13

9
14
0.0247
0.875
1.0272
0
0
0
12.41
2.41
85.18

9
15
0.0247
1
1.1522
0
0
0
11.07
2.15
86.79

9
16
0
0
0
0
0
0
0
0
0

10
1
0.0883
0
0.4658
53.67
0
0
27.37
18.96
0

10
2
0.0883
0
0.5908
63.47
0
0
21.58
14.95
0

10
3
0.0883
0
0.7158
69.85
0
0
17.81
12.34
0

10
4
0.0883
0
0.8408
74.33
0
0
15.16
10.5
0

10
5
0.0883
0
0.9658
77.66
0
0
13.2
9.14
0

10
6
0.0883
0
1.0908
80.22
0
0
11.69
8.1
0

10
7
0.0883
0
1.2158
82.25
0
0
10.49
7.26
0

10
8
0.0989
0
0.4764
0
52.48
0
26.76
20.76
0

10
9
0.0989
0
0.5835
0
61.2
0
21.85
16.95
0

10
10
0.0989
0
0.6907
0
67.22
0
18.46
14.32
0

10
11
0.0989
0
0.7978
0
71.62
0
15.98
12.4
0

10
12
0.0989
0
0.905
0
74.98
0
14.09
10.93
0

10
13
0.0989
0
1.0121
0
77.63
0
12.6
9.77
0

10
14
0.0989
0
1.1193
0
79.77
0
11.39
8.84
0

10
15
0.0989
0
1.2264
0
81.54
0
10.4
8.06
0

10
16
0
0
0.1275
0
0
0
100
0
0

11
1
0.0777
0
0.4552
54.92
0
0
28.01
17.07
0

11
2
0.0777
0
0.5802
64.63
0
0
21.97
13.39
0

11
3
0.0777
0
0.7052
70.9
0
0
18.08
11.02
0

11
4
0.0777
0
0.8302
75.28
0
0
15.36
9.36
0

11
5
0.0777
0
0.9552
78.52
0
0
13.35
8.14
0

11
5
0.0777
0
1.0802
81
0
0
11.8
7.19
0

11
7
0.0777
0
1.2052
82.97
0
0
10.58
6.45
0

11
8
0.0865
0
0.464
0
53.87
0
27.48
18.65
0

11
9
0.0865
0
0.5712
0
62.53
0
22.32
15.15
0

11
10
0.0865
0
0.6783
0
68.45
0
18.8
12.76
0

11
11
0.0865
0
0.7855
0
72.75
0
16.23
11.02
0

11
12
0.0865
0
0.8926
0
76.02
0
14.28
9.69
0

11
13
0.0865
0
0.9998
0
78.59
0
12.75
8.66
0

11
14
0.0865
0
1.1069
0
80.66
0
11.52
7.82
0

11
15
0.0865
0
1.214
0
82.37
0
10.5
7.13
0

11
16
0
0
0
0
0
0
0
0
0

12
1
0.0671
0
0.4446
56.23
0
0
28.68
15.09
0

12
2
0.0671
0
0.5696
65.83
0
0
22.38
11.78
0

12
3
0.0671
0
0.6946
71.98
0
0
18.36
9.66
0

12
4
0.0671
0
0.8196
76.26
0
0
15.56
8.19
0

12
5
0.0671
0
0.9446
79.4
0
0
13.5
7.1
0

12
6
0.0671
0
1.0696
81.81
0
0
11.92
6.27
0

12
7
0.0671
0
1.1946
83.71
0
0
10.67
5.62
0

12
8
0.0742
0
0.4517
0
55.35
0
28.23
16.42
0

12
9
0.0742
0
0.5588
0
63.91
0
22.82
13.27
0

12
10
0.0742
0
0.666
0
69.72
0
19.15
11.14
0

12
11
0.0742
0
0.7731
0
73.91
0
16.49
9.59
0

12
12
0.0742
0
0.8802
0
77.09
0
14.48
8.43
0

12
13
0.0742
0
0.9874
0
79.57
0
12.91
7.51
0

12
14
0.0742
0
1.0945
0
81.57
0
11.65
6.78
0

12
15
0.0742
0
1.2017
0
83.22
0
10.61
6.17
0

12
16
0
0
0
0
0
0
0
0
0

13
1
0.0565
0
0.434
57.6
0
0
29.37691318
13.02129626
0

13
2
0.0565
0
0.559
67.08
0
0
22.80800387
10.1096318
0

13
3
0.0565
0
0.684
73.1
0
0
18.63996156
8.262149952
0

13
4
0.0565
0
0.809
77.25
0
0
15.75991947
6.985573305
0

13
5
0.0565
0
0.934
80.3
0
0
13.6507548
6.050687537
0

13
6
0.0565
0
1.059
82.62
0
0
12.03949764
5.336498926
0

13
7
0.0565
0
1.184
84.46
0
0
10.76845115
4.773108456
0

13
8
0.0618
0
0.4393
0
56.91
0
29.02262057
14.07028027
0

13
9
0.0618
0
0.5465
0
65.36
0
23.33218905
11.31153675
0

13
10
0.0618
0
0.6536
0
71.04
0
19.50739766
9.457262887
0

13
11
0.0618
0
0.7607
0
75.11
0
16.75997261
8.125300447
0

13
12
0.0618
0
0.8679
0
78.19
0
14.69090509
7.122208397
0

13
13
0.0618
0
0.975
0
80.58
0
13.07656404
6.339569528
0

13
14
0.0618
0
1.0822
0
82.51
0
11.78188673
5.711904889
0

13
15
0.0618
0
1.1893
0
84.08
0
10.72047927
5.19733039
0

13
16
0
0
0
0
0
0
0
0
0

14
1
0.0459
0
0.4234
59.04
0
0
30.11
10.84
0

14
2
0.0459
0
0.5484
68.38
0
0
23.25
8.37
0

14
3
0.0459
0
0.6734
74.25
0
0
18.93
6.82
0

14
4
0.0459
0
0.7984
78.28
0
0
15.97
5.75
0

14
5
0.0459
0
0.9234
81.22
0
0
13.81
4.97
0

14
6
0.0459
0
1.0484
83.46
0
0
12.16
4.38
0

14
7
0.0459
0
1.1734
85.22
0
0
10.87
3.91
0

14
8
0.0495
0
0.427
0
58.55
0
29.86
11.58
0

14
9
0.0495
0
0.5341
0
66.87
0
23.87
9.26
0

14
10
0.0495
0
0.6412
0
72.4
0
19.88
7.71
0

14
11
0.0495
0
0.7484
0
76.36
0
17.04
6.61
0

14
12
0.0495
0
0.8555
0
79.32
0
14.9
5.78
0

14
13
0.0495
0
0.9627
0
81.62
0
13.24
5.14
0

14
14
0.0495
0
1.0698
0
83.46
0
11.92
4.62
0

14
15
0.0495
0
1.177
0
84.97
0
10.83
4.2
0

14
16
0
0
0
0
0
0
0
0
0

15
1
0.0353
0
0.4128
60.56
0
0
30.89
8.56
0

15
2
0.0353
0
0.5378
69.73
0
0
23.71
6.57
0

15
3
0.0353
0
0.6628
75.44
0
0
19.24
5.33
0

15
4
0.0353
0
0.7878
79.33
0
0
16.18
4.48
0

15
5
0.0353
0
0.9128
82.16
0
0
13.97
3.87
0

15
6
0.0353
0
1.0378
84.31
0
0
12.29
3.4
0

15
7
0.0353
0
1.1628
86
0
0
10.96
3.04
0

15
8
0.0371
0
0.4146
0
60.3
0
30.75
8.95
0

15
9
0.0371
0
0.5217
0
68.45
0
24.44
7.11
0

15
10
0.0371
0
0.6289
0
73.83
0
20.27
5.9
0

15
11
0.0371
0
0.736
0
77.64
0
17.32
5.04
0

15
12
0.0371
0
0.8432
0
80.48
0
15.12
4.4
0

15
13
0.0371
0
0.9503
0
82.68
0
13.42
3.9
0

15
14
0.0371
0
1.0574
0
84.44
0
12.06
3.51
0

15
15
0.0371
0
1.1646
0
85.87
0
10.95
3.18
0

15
16
0
0
0
0
0
0
0
0
0

16
1
0.0247
0
0.4022
62.15
0
0
31.7
6.15
0

16
2
0.0247
0
0.5272
71.13
0
0
24.18
4.69
0

16
3
0.0247
0
0.6522
76.66
0
0
19.55
3.79
0

16
4
0.0247
0
0.7772
80.41
0
0
16.4
3.18
0

16
5
0.0247
0
0.9022
83.13
0
0
14.13
2.74
0

16
6
0.0247
0
1.0272
85.18
0
0
12.41
2.41
0

16
7
0.0247
0
1.1522
86.79
0
0
11.07
2.15
0

16
8
0.0247
0
0.4022
0
62.15
0
31.7
6.15
0

16
9
0.0247
0
0.5094
0
70.11
0
25.03
4.85
0

16
10
0.0247
0
0.6165
0
75.31
0
20.68
4.01
0

16
11
0.0247
0
0.7237
0
78.96
0
17.62
3.42
0

16
12
0.0247
0
0.8308
0
81.68
0
15.35
2.98
0

16
13
0.0247
0
0.9379
0
83.77
0
13.59
2.64
0

16
14
0.0247
0
1.0451
0
85.43
0
12.2
2.37
0

16
15
0.0247
0
1.1522
0
86.79
0
11.07
2.15
0

16
16
0
0
0.1275
0
0
0
100
0
0

[0298]

11

Table IV

Tem-

pera-

ture:

300 C.

Pt1.0%/

R
C
COCONV
H2OCONV
CO2PROD
CO2PERPROD
CH4PROD
ZrO2std
CoNO32
FeNO33
GeOX2
H2MoO4
LaNO33

real
real
real
real
real
real
real
real
real
real
real
real
real

1
1
25.8564
17.3624
0.9641
34.8524
0.1872
0.1275
0
0
0
0
0

1
2
−3.5288
−1.0034
0.0465
1.6792
0.0188
0
0
0
0
0
0

1
3
−3.2594
−1.1661
0.0166
0.5998
0.0121
0
0
0
0
0
0

1
4
−2.9732
−3.7232
0.008
0.2881
0.0087
0
0
0
0
0
0

1
5
−2.8279
−4.1686
−0.0176
−0.636
0.0037
0
0
0
0
0
0

1
6
−0.8995
−1.8273
0.0207
0.7469
0.007
0
0
0
0
0
0

1
7
29.8929
15.3753
0.9475
34.2529
0.1713
0.1275
0
0
0
0
0

1
8
0.2455
−0.7786
0.0364
1.317
0.0059
0
0
0
0
0
0

1
9
1.8628
1.8933
0.0797
2.8821
0.0104
0
0
0
0
0
0

1
10
−1.0457
−1.7441
−0.0214
−0.7745
0.0034
0
0
0
0
0
0

1
11
−0.9415
−1.632
−0.0272
−0.9819
−0.0032
0
0
0
0
0
0

1
12
−1.4473
−2.099
−0.0436
−1.5778
−0.0067
0
0
0
0
0
0

1
13
29.7322
15.3824
0.922
33.3294
0.1512
0.1275
0
0
0
0
0

1
14
−0.4246
−0.0063
−0.0224
−0.8114
−0.005
0
0
0
0
0
0

1
15
−0.9697
−0.7029
−0.0374
−1.3523
−0.0056
0
0
0
0
0
0

1
16
32.2511
15.0975
0.9551
34.5247
0.1837
0.1275
0
0
0
0
0

2
1
25.7402
15.132
0.821
29.6779
0.1024
0
0
1
0
0
0

2
2
23.6205
13.0894
0.7368
26.6334
0.0932
0
0
1
0
0
0

2
3
22.2339
13.8399
0.7116
25.7223
0.0904
0
0
1
0
0
0

2
4
10.2788
6.0504
0.3053
11.0365
0.0334
0
0
1
0
1
0

2
5
24.8097
18.3968
0.7586
27.4246
0.0984
0
1
1
0
0
0

2
6
30.7805
17.4659
0.9424
34.0689
0.1445
0
0
0
0
0
0

2
7
24.5818
17.5787
0.7641
27.6231
0.1029
0
0
0
0
0
0

2
8
30.0483
18.2382
1.0024
36.2373
0.1267
0
0
0
0
0
0

2
9
8.9325
5.5702
0.275
9.9397
0.0302
0
0
0
0
1
0

2
10
48.0297
−3.6479
0.6535
23.6248
0.5638
0
1
0
0
0
0

2
11
33.7357
12.0981
0.8374
30.2711
0.2395
0
0
0
0
0
0

2
12
25.0185
12.5103
0.7266
26.268
0.133
0
0
0
0
0
0

2
13
32.2828
17.7494
1.0157
36.7159
0.148
0
0
0
0
0
0

2
14
14.7003
10.1762
0.4613
16.6741
0.0611
0
0
0
0
1
0

2
15
40.8678
6.002
0.8233
29.7614
0.3924
0
1
0
0
0
0

2
16
−0.6906
−1.1865
−0.0214
−0.7728
−0.0011
0
0
0
0
0
0

3
1
25.0677
15.2287
0.7962
28.781
0.0976
0
0
0.875
0
0
0

3
2
21.7886
14.5137
0.6935
25.0715
0.0867
0
0
0.875
0
0
0

3
3
23.5288
15.7457
0.7124
25.7537
0.0872
0
0
0.875
0
0
0

3
4
10.7835
7.3033
0.3034
10.9679
0.0327
0
0
0.875
0
0.875
0

3
5
35.9677
7.7821
0.8095
29.2621
0.2747
0
0.875
0.875
0
0
0

3
6
29.594
18.255
0.8479
30.6516
0.1306
0
0
0
0
0
0

3
7
27.2904
16.7775
0.7916
28.6165
0.117
0
0
0
0
0
0

3
8
32.0759
21.3168
1.0149
36.687
0.1287
0
0
0
0
0
0

3
9
11.3167
8.9989
0.3238
11.7044
0.0337
0
0
0
0
0.875
0

3
10
47.8794
1.867
0.6668
24.1028
0.5212
0
0.875
0
0
0
0

3
11
38.1087
10.0964
0.8129
29.3858
0.2958
0
0
0
0
0
0

3
12
29.1087
12.0353
0.731
26.4253
0.167
0
0
0
0
0
0

3
13
32.9772
21.6736
1.001
36.1859
0.1453
0
0
0
0
0
0

3
14
26.1774
17.2847
0.7394
26.7277
0.0884
0
0
0
0
0.875
0

3
15
44.0139
7.4653
0.7942
28.7088
0.4053
0
0.875
0
0
0
0

3
16
3.3654
3.7276
0.0426
1.5406
−0.0027
0
0
0
0
0
0

4
1
25.492
16.5937
0.7634
27.5979
0.0911
0
0
0.75
0
0
0

4
2
25.0526
16.4405
0.7271
26.2844
0.0861
0
0
0.75
0
0
0

4
3
26.6439
16.1513
0.7463
26.977
0.0889
0
0
0.75
0
0
0

4
4
8.939
4.4471
0.1855
6.7042
0.0195
0
0
0.75
0
0.75
0

4
5
31.3599
14.4563
0.7785
28.1423
0.1927
0
0.75
0.75
0
0
0

4
6
32.6696
17.1698
0.8987
32.4874
0.1475
0
0
0
0
0
0

4
7
31.6017
13.1545
0.7725
27.9246
0.1942
0
0
0
0
0
0

4
8
33.4823
19.718
1.0123
36.5929
0.1326
0
0
0
0
0
0

4
9
12.4995
6.3069
0.375
13.5551
0.046
0
0
0
0
0.75
0

4
10
48.6152
−4.3375
0.6394
23.115
0.5697
0
0.75
0
0
0
0

4
11
42.989
5.7041
0.7377
26.6675
0.3792
0
0
0
0
0
0

4
12
32.6771
8.7176
0.7127
25.7625
0.245
0
0
0
0
0
0

4
13
35.464
14.8498
0.9578
34.6247
0.2053
0
0
0
0
0
0

4
14
24.0107
14.9324
0.72
26.0278
0.0894
0
0
0
0
0.75
0

4
15
39.2751
8.6633
0.8092
29.2522
0.319
0
0.75
0
0
0
0

4
16
31.806
15.0401
0.8979
32.4605
0.1745
0.1275
0
0
0
0
0

5
1
26.262
16.477
0.7293
26.3635
0.088
0
0
0.625
0
0
0

5
2
23.9323
15.5571
0.7185
25.9736
0.0827
0
0
0.625
0
0
0

5
3
25.3808
16.1474
0.7857
28.403
0.0965
0
0
0.625
0
0
0

5
4
9.1171
4.2487
0.2386
8.6247
0.0208
0
0
0.625
0
0.625
0

5
5
26.6273
17.4591
0.8121
29.3586
0.1114
0
0.625
0.625
0
0
0

5
6
32.4494
18.2364
0.8924
32.2599
0.1711
0
0
0
0
0
0

5
7
40.5821
7.1924
0.6488
23.4554
0.3589
0
0
0
0
0
0

5
8
32.5308
20.5892
0.9922
35.8668
0.1299
0
0
0
0
0
0

5
9
18.0317
15.0408
0.5278
19.0801
0.0576
0
0
0
0
0.625
0

5
10
46.3191
0.5778
0.6724
24.3059
0.5198
0
0.625
0
0
0
0

5
11
44.6369
1.626
0.6829
24.6876
0.4534
0
0
0
0
0
0

5
12
35.4393
5.7506
0.6467
23.3795
0.3016
0
0
0
0
0
0

5
13
35.4493
21.0168
0.9146
33.0625
0.189
0
0
0
0
0
0

5
14
27.0781
19.2557
0.7971
28.8141
0.1019
0
0
0
0
0.625
0

5
15
37.2533
13.087
0.8139
29.4226
0.2787
0
0.625
0
0
0
0

5
16
3.6561
3.1878
0.0318
1.148
−0.0025
0
0
0
0
0
0

6
1
24.6778
22.0399
0.7405
26.7684
0.0826
0
0
0.5
0
0
0

6
2
25.2229
17.6846
0.7461
26.9722
0.0905
0
0
0.5
0
0
0

6
3
25.0098
18.2845
0.7368
26.6363
0.0886
0
0
0.5
0
0
0

6
4
15.0796
11.334
0.4265
15.4161
0.0468
0
0
0.5
0
0.5
0

6
5
26.4442
21.9848
0.7821
28.2731
0.0996
0
0.5
0.5
0
0
0

6
6
33.7204
18.2395
0.854
30.8704
0.2042
0
0
0
0
0
0

6
7
48.6329
0.1423
0.5077
8.353
0.5727
0
0
0
0
0
0

6
8
32.9598
20.2321
0.977
35.3184
0.1325
0
0
0
0
0
0

6
9
27.4847
16.0934
0.809
29.2465
0.1045
0
0
0
0
0.5
0

6
10
47.3126
1.909
0.6511
23.536
0.5108
0
0.5
0
0
0
0

6
11
44.8464
3.0427
0.6707
24.2472
0.4515
0
0
0
0
0
0

6
12
38.7726
6.4545
0.5984
21.6335
0.3634
0
0
0
0
0
0

6
13
38.5156
3.2083
0.8575
30.9968
0.2641
0
0
0
0
0
0

6
14
28.7859
18.1087
0.8805
31.8313
0.1271
0
0
0
0
0.5
0

6
15
35.4929
17.1934
0.7562
27.3345
0.2432
0
0.5
0
0
0
0

6
16
2.5988
1.2055
−0.0164
−0.5943
−0.0095
0
0
0
0
0
0

7
1
23.6924
16.7271
0.7004
25.3191
0.0826
0
0
0.375
0
0
0

7
2
25.1267
21.1141
0.7418
26.8149
0.0847
0
0
0.375
0
0
0

7
3
25.8959
18.4176
0.7671
27.7314
0.0901
0
0
0.375
0
0
0

7
4
18.8393
12.6193
0.5341
19.3068
0.0639
0
0
0.375
0
0.375
0

7
5
28.357
18.3763
0.8591
31.0555
0.1054
0
0.375
0.375
0
0
0

7
6
37.6451
12.7384
0.8363
30.2303
0.2795
0
0
0
0
0
0

7
7
50.5621
−8.9297
0.4671
16.885
0.6403
0
0
0
0
0
0

7
8
32.2364
19.6481
0.956
34.5605
0.1362
0
0
0
0
0
0

7
9
28.8909
18.0531
0.8701
31.4548
0.1113
0
0
0
0
0.375
0

7
10
47.559
2.1238
0.5786
20.9158
0.5312
0
0.375
0
0
0
0

7
11
46.2019
1.1774
0.6161
22.2705
0.4965
0
0
0
0
0
0

7
12
41.8835
−0.2463
0.5734
20.7288
0.4401
0
0
0
0
0
0

7
13
38.9385
11.7442
0.8471
30.6208
0.2895
0
0
0
0
0
0

7
14
32.6869
21.8404
0.9441
34.1293
0.1518
0
0
0
0
0.375
0

7
15
33.6641
15.6957
0.7471
27.007
0.2395
0
0.375
0
0
0
0

7
16
34.1815
15.6762
0.9132
33.013
0.1882
0.1275
0
0
0
0
0

8
1
24.3356
15.0031
0.7199
26.0256
0.0889
0
0
0.25
0
0
0

8
2
24.501
16.4553
0.7674
27.7415
0.097
0
0
0.25
0
0
0

8
3
26.1797
15.4862
0.7758
28.0436
0.0977
0
0
0.25
0
0
0

8
4
23.9023
13.5114
0.6887
24.8975
0.0864
0
0
0.25
0
0.25
0

8
5
27.2773
16.1215
0.8158
29.4917
0.1019
0
0.25
0.25
0
0
0

8
6
43.6154
1.6883
0.7068
25.5505
0.4304
0
0
0
0
0
0

8
7
54.0389
−18.2872
0.2857
10.327
0.768
0
0
0
0
0
0

8
8
32.2327
19.5627
0.9111
32.9365
0.1482
0
0
0
0
0
0

8
9
29.5791
16.0012
0.8473
30.6296
0.1394
0
0
0
0
0.25
0

8
10
49.7662
−9.2035
0.5443
19.6769
0.6038
0
0.25
0
0
0
0

8
11
48.2982
−7.9653
0.5573
20.1458
0.566
0
0
0
0
0
0

8
12
43.5519
−1.5649
0.5715
20.6589
0.4762
0
0
0
0
0
0

8
13
42.773
7.9963
0.7849
28.3752
0.3819
0
0
0
0
0
0

8
14
31.8568
17.6636
0.8855
32.0102
0.1807
0
0
0
0
0.25
0

8
15
35.8667
9.7526
0.7675
27.7441
0.275
0
0.25
0
0
0
0

8
16
1.3994
3.1514
−0.006
−0.2176
−0.0045
0
0
0
0
0
0

9
1
18.3331
11.0666
0.5484
19.8255
0.0638
0
0
0.25
0.2
0
0

9
2
22.798
15.9195
0.6977
25.2221
0.0827
0
0
0.4375
0
0
0

9
3
13.6014
15.3552
0.3517
12.7144
0.0312
0
0
0.625
0
0
0

9
4
28.351
21.8465
0.8623
31.1733
0.1033
0
0
0.8125
0
0
1

9
5
29.4335
21.2793
0.9293
33.5925
0.1106
0
1
0
0
0
0

9
6
21.2667
16.5714
0.5955
21.5278
0.0682
0
0
0
0.2
0
0

9
7
25.3599
18.0756
0.7027
25.402
0.0854
0
0
0
0
0
0

9
8
21.966
14.7363
0.6219
22.481
0.0736
0
0
0
0
0
0

9
9
31.1704
19.4661
0.8974
32.4422
0.1305
0
0
0
0
0
1

9
10
31.8494
19.2923
0.9109
32.9279
0.1397
0
1
0
0
0
0

9
11
17.0166
13.0969
0.4865
17.5882
0.051
0
0
0
0.2
0
0

9
12
25.0631
16.8801
0.7186
25.9785
0.0869
0
0
0
0
0
0

9
13
19.9114
13.2859
0.5459
19.7345
0.0645
0
0
0
0
0
0

9
14
31.5204
18.4006
0.8541
30.874
0.1476
0
0
0
0
0
1

9
15
34.16
17.1821
0.8661
31.3099
0.1905
0
0
0
0
0
0

9
16
2.7882
4.2082
0.0005
0.0192
0.0095
0
0
0
0
0
0

10
1
20.1799
15.6023
0.5626
20.3382
0.0639
0
0
0.25
0.1786
0
0

10
2
23.8584
16.4225
0.6988
25.2598
0.0823
0
0
0.4375
0
0
0

10
3
15.4388
11.8361
0.4277
15.4606
0.0438
0
0
0.625
0
0
0

10
4
29.1664
21.6823
0.8605
31.1062
0.0999
0
0
0.8125
0
0
0.8929

10
3
29.7657
20.4923
0.893
32.2799
0.1072
0
0.8929
0
0
0
0

10
6
22.18
16.7809
0.6181
22.3455
0.0709
0
0
0
0.1786
0
0

10
7
26.8964
18.4335
0.7687
27.7879
0.0978
0
0
0
0
0
0

10
8
22.7626
17.3084
0.6298
22.7655
0.0704
0
0
0
0
0
0

10
9
31.0541
20.3764
0.8791
31.7796
0.1285
0
0
0
0
0
0.8929

10
10
31.5314
20.1611
0.8887
32.1276
0.1379
0
0.8929
0
0
0
0

10
11
18.497
14.278
0.5299
9.1546
0.054
0
0
0
0.1786
0
0

10
12
27.0928
17.5518
0.777
28.0886
0.1001
0
0
0
0
0
0

10
13
23.9418
16.8238
0.6968
25.1885
0.0802
0
0
0
0
0
0

10
14
32.8367
16.8366
0.8584
31.0301
0.1726
0
0
0
0
0
0.8929

10
15
35.3845
16.154
0.8552
30.9151
0.2129
0
0.8929
0
0
0
0

10
16
32.4924
16.3973
0.857
30.9802
0.1675
0.1275
0
0
0
0
0

11
1
17.8706
12.5355
0.539
19.4849
0.0583
0
0
0.25
0.1571
0
0

11
2
22.1385
14.6388
0.6381
23.0678
0.0756
0
0
0.4375
0
0
0

11
3
16.2493
9.7877
0.4863
17.5787
0.0511
0
0
0.625
0
0
0

11
4
28.4408
19.613
0.8619
31.1555
0.1022
0
0
0.8125
0
0
0.7857

11
5
28.7788
20.3358
0.8639
31.2296
0.1008
0
0.7857
1
0
5
0

11
6
21.3341
15.2564
0.5892
21.2992
0.0673
0
0
0
0.1571
0
0

11
7
27.2565
17.5295
0.7991
28.886
0.1046
0
0
0
0
0
0

11
8
22.8741
15.5232
0.6559
23.7095
0.0754
0
0
0
0
0
0

11
9
31.075
18.1195
0.917
33.1497
0.1331
0
0
0
0
0
0.7857

11
10
31.3771
18.8457
0.8762
31.6749
0.1522
0
0.7857
0
0
0
0

11
11
21.3374
14.1823
0.6491
23.4647
0.0785
0
0
0
0.1571
0
0

11
12
25.5254
16.7175
0.76
27.4744
0.1037
0
0
0
0
0
0

11
13
20.9039
14.4462
0.64
23.1367
0.0754
0
0
0
0
0
0

11
14
33.7178
14.9458
0.8333
30.1232
0.2011
0
0
0
0
0
0.7857

11
15
34.0506
15.3472
0.8472
30.6271
0.2145
0
0.7857
0
0
0
0

11
16
0.2666
0.8625
−0.0072
−0.2617
−0.0041
0
0
0
0
0
0

12
1
18.4252
12.5906
0.6282
22.7083
0.0734
0
0
0.25
0.1357
0
0

12
2
21.4727
15.7898
0.6968
25.1879
0.0852
0
0
0.4375
0
0
0

12
3
14.1262
12.3376
0.4687
16.9417
0.0497
0
0
0.625
0
0
0

12
4
26.6361
19.8449
0.8375
30.2751
0.0896
0
0
0.8125
0
0
0.6786

12
5
26.1247
23.2018
0.7532
27.2264
0.0813
0
0.6786
1
0
0
0

12
6
25.9088
17.9446
0.7612
27.5175
0.0905
0
0
0
0.1357
0
0

12
7
25.573
24.4683
0.7131
25.7792
0.0985
0
0
0
0
0
0

12
8
24.262
17.1356
0.7712
27.8785
0.0918
0
0
0
0
0
0

12
9
29.8063
15.9041
0.8712
31.4939
0.1526
0
0
0
0
0
0.6786

12
10
34.0875
13.806
0.859
31.0513
0.2288
0
0.6786
0
0
0
0

12
11
23.2764
16.0656
0.7007
25.3292
0.0852
0
0
0
0.1357
0
0

12
12
26.9347
14.5078
0.7474
27.0175
0.115
0
0
0
0
0
0

12
13
25.0739
14.2758
0.813
29.3912
0.1076
0
0
0
0
0
0

12
14
34.2818
9.7762
0.8339
30.1465
0.2607
0
0
0
0
0
0.6786

12
15
35.628
9.6941
0.8181
29.5727
0.2742
0
0.6786
0
0
0
0

12
16
0.8243
0.262
0.0134
0.4858
0.0025
0
0
0
0
0
0

13
1
18.3427
17.1145
0.5463
19.7493
0.0541
0
0
0.25
0.1143
0
0

13
2
21.3958
19.2387
0.599
21.6519
0.063
0
0
0.4375
0
0
0

13
3
15.8656
13.3135
0.449
16.2312
0.0452
0
0
0.625
0
0
0

13
4
27.8323
18.0095
0.8182
29.5764
0.0982
0
0
0.8125
0
0
0.5714

13
5
27.6816
18.912
0.8077
29.1984
0.0936
0
0.5714
1
0
0
0

13
6
26.0154
20.0225
0.8041
29.0693
0.0909
0
0
0
0.1143
0
0

13
7
27.321
17.8397
0.8275
29.9151
0.1259
0
0
0
0
0
0

13
8
25.8111
17.8768
0.7658
27.6837
0.0907
0
0
0
0
0
0

13
9
32.5862
15.9816
0.7969
28.8078
0.1975
0
0
0
0
0
0.5714

13
10
41.3818
4.9336
0.7015
25.3603
0.3954
0
0.5714
0
0
0
0

13
11
24.8301
17.6776
0.6894
24.9214
0.0831
0
0
0
0.1143
0
0

13
12
26.8437
15.7759
0.7715
27.8911
0.1353
0
0
0
0
0
0

13
13
24.7873
17.0919
0.751
27.1481
0.0946
0
0
0
0
0
0

13
14
34.4795
12.7622
0.74
26.7515
0.2396
0
0
0
0
0
0.5714

13
15
36.4404
11.2958
0.7768
28.0793
0.2677
0
0.5714
0
0
0
0

13
16
32.5622
16.8288
0.7849
28.3746
0.1755
0.1275
0
0
0
0
0

14
1
20.2567
12.3853
0.6712
24.2633
0.0852
0
0
0.25
0.0929
0
0

14
2
22.68
15.5979
0.7275
26.2996
0.0862
0
0
0.4375
0
0
0

14
3
7.0763
12.9293
0.5885
21.273
0.0675
0
0
0.625
0
0
0

14
4
26.0405
18.4515
0.8042
29.07
0.1036
0
0
0.8125
0
0
0.4643

14
5
26.0927
19.3723
0.7707
27.8589
0.0941
0
0.4643
1
0
0
0

14
6
24.2827
16.6636
0.7693
27.8114
0.0989
0
0
0
0.0929
0
0

14
7
27.8195
15.8631
0.8198
29.6364
0.1473
0
0
0
0
0
0

14
8
26.9972
16.5785
0.8076
29.1956
0.11
0
0
0
0
0
0

14
9
38.8468
6.9959
0.7191
25.9951
0.3418
0
0
0
0
0
0.4643

14
10
48.9533
4.4406
0.5294
9.1373
0.5957
0
0.4643
0
0
0
0

14
11
24.6424
16.8798
0.7738
27.9708
0.1041
0
0
0
0.0929
0
0

14
12
28.1407
13.399
0.7724
27.9235
0.1621
0
0
0
0
0
0

14
13
27.1547
16.2099
0.7593
27.4492
0.1341
0
0
0
0
0
0

14
14
36.8809
8.2728
0.6993
25.2804
0.3112
0
0
0
0
0
0.4643

14
15
36.4174
8.3339
0.7383
26.6874
0.3082
0
0.4643
0
0
0
0

14
16
1.1257
0.8364
−0.0533
−1.9279
−0.0116
0
0
0
0
0
0

15
1
19.9305
15.9556
0.6162
22.277
0.071
0
0
0.25
0.0714
0
0

15
2
22.3009
14.3322
0.743
26.8605
0.0864
0
0
0.4375
0
0
0

15
3
18.8732
13.6249
0.6143
22.2054
0.0672
0
0
0.625
0
0
0

15
4
24.0558
15.8686
0.7818
28.2606
0.103
0
0
0.8125
0
0
3.3571

15
5
25.927
17.3231
0.7769
28.0848
0.0937
0
0.3571
1
0
0
0

15
6
26.5932
17.8376
0.8142
29.4341
0.1077
0
0
0
0.0714
0
0

15
7
29.5785
15.1647
0.8206
29.6653
0.2062
0
0
0
0
0
0

15
8
27.0224
17.6058
0.8195
29.6227
0.1215
0
0
0
0
0
0

15
9
45.5964
−1.427
0.6094
22.031
0.5239
0
0
0
0
0
0.3571

15
10
47.7892
−4.8284
0.5902
21.3358
0.5789
0
3.3571
0
0
0
0

15
11
27.2611
16.2992
0.784
28.3422
0.1126
0
0
0
0.0714
0
0

15
12
30.9992
12.5497
0.7158
25.8775
0.2007
0
0
0
0
0
0

15
13
31.8053
9.9612
0.7893
28.5319
0.2159
0
0
0
0
0
0

15
14
37.3824
5.9023
0.7393
26.7266
0.3762
0
0
0
0
0
0.3571

15
15
38.1161
5.5222
0.698
25.2309
0.3851
0
0.3571
0
0
0
0

15
16
0.8754
0.7034
−0.0221
−0.7984
−0.0015
0
0
0
0
0
0

16
1
5.642
6.3495
0.1244
4.4983
0.0117
0
0
0.25
0.05
0
0

16
2
20.1376
15.5842
0.6325
22.8636
0.0761
0
0
0.4375
0
0
0

16
3
17.72
15.0247
0.5638
20.3814
0.0668
0
0
0.625
0
0
0

16
4
20.745
16.5113
0.6768
24.4663
0.0809
0
0
0.8125
0
0
0.25

16
5
23.4069
16.7755
0.7548
27.2856
0.0951
0
0.25
1
0
0
0

16
6
28.4013
17.264
0.8013
28.9677
0.1431
0
0
0
0.05
0
0

16
7
34.7081
11.4293
0.7565
27.3464
0.2707
0
0
0
0
0
0

16
8
31.5206
15.0594
0.7868
28.4425
0.1976
0
0
0
0
0
0

16
9
50.5474
−10.4983
0.4745
17.1519
0.6572
0
0
0
0
0
0.25

16
10
53.9071
−15.5894
0.3503
12.6648
0.7563
0
0.25
0
0
0
0

16
11
28.0202
14.2589
0.7625
27.5636
0.156
0
0
0
0.05
0
0

16
12
37.4585
−1.0934
0.6168
22.2983
0.4116
0
0
0
0
0
0

16
13
38.0537
−0.1529
0.5897
21.3174
0.4244
0
0
0
0
0
0

16
14
43.3047
−5.8456
0.4632
16.7442
0.5402
0
0
0
0
0
0.25

16
15
43.8393
−6.2457
0.4623
16.7117
0.5811
0
0.25
0
0
0
0

16
16
31.5947
17.1493
0.9526
34.4377
0.162
0.1275
0
0
0
0
0

Tem-

pera-

ture:

SUM—

300 C.

micro-
mol %
mol %

R
C
NH42nOOX2
NH43SbOX3
PtNH32NO22
RhNO33
RuNONO33
SnOX2
VOX2
ZrONO32
mols
CO
Fe

real
real
real
real
real
real
real
real
real
real

1
1
0
0
0
0
0
0
0
0
0.1275
0
0

1
2
0
0
0
0
0
0
0
0
0
0
0

1
3
0
0
0
0
0
0
0
0
0
0
0

1
4
0
0
0
0
0
0
0
0
0
0
0

1
5
0
0
0
0
0
0
0
0
0
0
0

1
6
0
0
0
0
0
0
0
0
0
0
0

1
7
0
0
0
0
0
0
0
0
0.1275
0
0

1
8
0
0
0
0
0
0
0
0
0
0
0

1
9
0
0
0
0
0
0
0
0
0
0
0

1
10
0
0
0
0
0
0
0
0
0
0
0

1
11
0
0
0
0
0
0
0
0
0
0
0

1
12
0
0
0
0
0
0
0
0
0
0
0

1
13
0
0
0
0
0
0
0
0
0.1275
0
0

1
14
0
0
0
0
0
0
0
0
0
0
0

1
15
0
0
0
0
0
0
0
0
0
0
0

1
16
0
0
0
0
0
0
0
0
0.1275
0
0

2
1
1
0
0.1275
0
0
0
0
0
2.1275
0
47

2
2
0
0
0.1275
0
0
0
0
1
2.1275
0
47

2
3
0
0
0.1275
0
0
0
1
0
2.1275
0
47

2
4
0
0
0.1275
0
0
0
0
0
2.1275
0
47

2
5
0
0
0.1275
0
0
0
0
0
2.1275
47
47

2
6
1
0
0.1275
0
0.0245
0
0
0
1.152
0
0

2
7
0
0
0.1275
0
0.0245
0
0
1
1.152
0
0

2
8
0
0
0.1275
0
0.0245
0
1
0
1.152
0
0

2
9
0
0
0.1275
0
0.0245
0
0
0
1.152
0
0

2
10
0
0
0.1275
0
0.0245
0
0
0
1.152
86.81
0

2
11
1
0
0.1275
0.0243
0
0
0
0
1.1518
0
0

2
12
0
0
0.1275
0.0243
0
0
0
1
1.1518
0
0

2
13
0
0
0.1275
0.0243
0
0
1
0
1.1518
0
0

2
14
0
0
0.1275
0.0243
0
0
0
0
1.1518
0
0

2
15
0
0
0.1275
0.0243
0
0
0
0
1.1518
86.82
0

2
16
0
0
0
0
0
0
0
0
0
0
0

3
1
0.875
0
0.1275
0
0
0
0
0
1.8775
0
46.6

3
2
0
0
0.1275
0
0
0
0
0.875
1.8775
0
46.6

3
3
0
0
0.1275
0
0
0
0.875
0
1.8775
0
46.6

3
4
0
0
0.1275
0
0
0
0
0
1.8775
0
46.6

3
5
0
0
0.1275
0
0
0
0
0
1.8775
46.6
46.6

3
6
0.875
0
0.1275
0
0.0368
0
0
0
1.0393
0
0

3
7
0
0
0.1275
0
0.0368
0
0
0.875
1.0393
0
0

3
8
0
0
0.1275
0
0.0368
0
0.875
0
1.0393
0
0

3
9
0
0
0.1275
0
0.0368
0
0
0
1.0393
0
0

3
10
0
0
0.1275
0
0.0368
0
0
0
1.0393
84.2
0

3
11
0.875
0
0.1275
0.0365
0
0
0
0
1.039
0
0

3
12
0
0
0.1275
0.0365
0
0
0
0.875
1.039
0
0

3
13
0
0
0.1275
0.0365
0
0
0.875
0
1.039
0
0

3
14
0
0
0.1275
0.0365
0
0
0
0
1.039
0
0

3
15
0
0
0.1275
0.0365
0
0
0
0
1.039
84.22
0

3
16
0
0
0
0
0
0
0
0
0
0
0

4
1
0.75
0
0.1275
0
0
0
0
0
1.6275
0
46.08

4
2
0
0
0.1275
0
0
0
0
0.75
1.6275
0
46.08

4
3
0
0
3.1275
0
0
0
0.75
0
1.6275
0
46.08

4
4
0
0
0.1275
0
0
0
0
0
1.6275
0
46.08

4
5
0
0
0.1275
0
0
0
0
0
1.6275
46.08
46.08

4
6
0.75
0
0.1275
0
0.049
0
0
0
0.9265
0
0

4
7
0
0
0.1275
0
0.049
0
0
0.75
0.9265
0
0

4
8
0
0
0.1275
0
0.049
0
0.75
0
0.9265
0
0

4
9
0
0
0.1275
0
0.049
0
0
0
0.9265
0
0

4
10
0
0
0.1275
0
0.049
0
0
0
0.9265
80.95
0

4
11
0.75
0
0.1275
0.0486
0
0
0
0
0.9261
0
0

4
12
0
0
0.1275
0.0486
0
0
0
0.75
0.9261
0
0

4
13
0
0
0.1275
0.0486
0
0
0.75
0
0.9261
0
0

4
14
0
0
0.1275
0.0486
0
0
0
0
0.9261
0
0

4
15
0
0
0.1275
0.0486
0
0
0
0
0.9261
80.98
0

4
16
0
0
0
0
0
0
0
0
0.1275
0
0

5
1
0.625
0
0.1275
0
0
0
0
0
1.3775
0
45.37

5
2
0
0
0.1275
0
0
0
0
0.625
1.3775
0
45.37

5
3
0
0
0.1275
0
0
0
0.625
0
1.3775
0
45.37

5
4
0
0
0.1275
0
0
0
0
0
1.3775
0
45.37

5
5
0
0
0.1275
0
0
0
0
0
1.3775
45.37
45.37

5
6
0.625
0
0.1275
0
0.0613
0
0
0
0.8138
0
0

5
7
0
0
0.1275
0
0.0613
0
0
0.625
0.8138
0
0

5
8
0
0
0.1275
0
0.0613
0
0.625
0
0.8138
0
0

5
9
0
0
0.1275
0
0.0613
0
0
0
0.8138
0
0

5
10
0
0
0.1275
0
0.0613
0
0
0
0.8138
76.8
0

5
11
0.625
0
0.1275
0.0608
0
0
0
0
0.8133
0
0

5
12
0
0
0.1275
0.0608
0
0
0
0.625
0.8133
0
0

5
13
0
0
0.1275
0.0608
0
0
0.625
0
0.8133
0
0

5
14
0
0
0.1275
0.0608
0
0
0
0
0.8133
0
0

5
15
0
0
0.1275
0.0608
0
0
0
0
0.8133
76.85
0

5
16
0
0
0
0
0
0
0
0
0
0
0

6
1
0.5
0
0.1275
0
0
0
0
0
1.1275
0
44.35

6
2
0
0
0.1275
0
0
0
0
0.5
1.1275
0
44.35

6
3
0
0
0.1275
0
0
0
0.5
0
1.1275
0
44.35

6
4
0
0
0.1275
0
0
0
0
0
1.1275
0
44.35

6
5
0
0
0.1275
0
0
0
0
0
1.1275
44.35
44.35

6
6
0.5
0
0.1275
0
0.0735
0
0
0
0.701
0
0

6
7
0
0
0.1275
0
0.0735
0
0
0.5
0.701
0
0

6
8
0
0
0.1275
0
0.0735
0
0.5
0
0.701
0
0

6
9
0
0
0.1275
0
0.0735
0
0
0
0.701
0
0

6
10
0
0
0.1275
0
0.0735
0
0
0
0.701
71.33
0

6
11
0.5
0
0.1275
0.0729
0
0
0
0
0.7004
0
0

6
12
0
0
0.1275
0.0729
0
0
0
0.5
0.7004
0
0

6
13
0
0
0.1275
0.0729
0
0
0.5
0
0.7004
0
0

6
14
0
0
0.1275
0.0729
0
0
0
0
0.7004
0
0

6
15
0
0
0.1275
0.0729
0
0
0
0
0.7004
71.39
0

6
16
0
0
0
0
0
0
0
0
0
0
0

7
1
0.375
0
0.1275
0
0
0
0
0
0.8775
0
42.74

7
2
0
0
0.1275
0
0
0
0
0.375
0.8775
0
42.74

7
3
0
0
0.1275
0
0
0
0.375
0
0.8775
0
42.74

7
4
0
0
0.1275
0
0
0
0
0
0.8775
0
42.74

7
5
0
0
0.1275
0
0
0
0
0
0.8775
42.74
42.74

7
6
0.375
0
0.1275
0
0.0858
0
0
0
0.5883
0
0

7
7
0
0
0.1275
0
0.0858
0
0
0.375
0.5883
0
0

7
8
0
0
0.1275
0
0.0858
0
0.375
0
0.5883
0
0

7
9
0
0
0.1275
0
0.0858
0
0
0
0.5883
0
0

7
10
0
0
0.1275
0
0.0858
0
0
0
0.5883
63.75
0

7
11
0.375
0
0.1275
0.0851
0
0
0
0
0.5876
0
0

7
12
0
0
0.1275
0.0851
0
0
0
0.375
0.5876
0
0

7
13
0
0
0.1275
0.0851
0
0
0.375
0
0.5876
0
0

7
14
0
0
0.1275
0.0851
0
0
0
0
0.5876
0
0

7
15
0
0
0.1275
0.0851
0
0
0
0
0.5876
63.82
0

7
16
0
0
0
0
0
0
0
0
0.1275
0
0

8
1
0.25
0
0.1275
0
0
0
0
0
0.6275
0
39.84

8
2
0
0
0.1275
0
0
0
0
0.25
0.6275
0
39.84

8
3
0
0
0.1275
0
0
0
0.25
0
0.6275
0
39.84

8
4
0
0
0.1275
0
0
0
0
0
0.6275
0
39.84

8
5
0
0
0.1275
0
0
0
0
0
0.6275
39.84
39.84

8
6
0.25
0
0.1275
0
0.098
0
0
0
0.4755
0
0

8
7
0
0
0.1275
0
0.098
0
0
0.25
0.4755
0
0

8
8
0
0
3.1275
0
0.098
0
0.25
0
0.4755
0
0

8
9
0
0
0.1275
0
0.098
0
0
0
0.4755
0
0

8
10
0
0
0.1275
0
0.098
0
0
0
0.4755
52.58
0

8
11
0.25
0
0.1275
0.0972
0
0
0
0
0.4747
0
0

8
12
0
0
0.1275
0.0972
0
0
0
0.25
0.4747
0
0

8
13
0
0
0.1275
0.0972
0
0
0.25
0
0.4747
0
0

8
14
0
0
0.1275
0.0972
0
0
0
0
0.4747
0
0

8
15
0
0
0.1275
0.0972
0
0
0
0
0.4747
52.66
0

8
16
0
0
0
0
0
0
0
0
0
0
0

9
1
0
0
0.1275
0
0
0
0
0
0.5775
0
43.29

9
2
0
0
0.1275
0
0
0.2
0
0
0.765
0
57.19

9
3
0
0.2
0.1275
0
0
0
0
0
0.9525
0
65.62

9
4
0
0
0.1275
0
0
0
0
0
1.94
0
41.88

9
5
0
0
0.1275
0
0
0
0
0
2.1275
47
47

9
6
0
0
0.1275
0
0.0245
0
0
0
0.352
0
0

9
7
0
0
0.1275
0
0.0245
0.2
0
0
0.352
0
0

9
8
0
0.2
0.1275
0
0.0245
0
0
0
0.352
0
0

9
9
0
0
0.1275
0
0.0245
0
0
0
1.152
0
0

9
10
0
0
0.1275
0
0.0245
0
0
0
1.152
86.81
0

9
11
0
0
0.1275
0.0243
0
0
0
0
0.3518
0
0

9
12
0
0
0.1275
0.0243
0
0.2
0
0
0.3518
0
0

9
13
0
0.2
0.1275
0.0243
0
0
0
0
0.3518
0
0

9
14
0
0
0.1275
0.0243
0
0
0
0
0.3518
0
0

9
15
0
0
0.1275
0.0243
0
0
0
0
1.1518
86.82
0

9
16
0
0
0
0
0
0
0
0
0
0
0

10
1
0
0
0.1275
0
0
0
0
0
0.5561
0
44.96

10
2
0
0
0.1275
0
0
0.1786
0
0
0.7436
0
58.84

10
3
0
0.1786
0.1275
0
0
0
0
0
0.9311
0
67.13

10
4
0
0
0.1275
0
0
0
0
0
1.8329
0
44.33

10
5
0
0
0.1275
0
0
0
0
0
2.0204
44.19
49.5

10
6
0
0
0.1275
0
0.035
0
0
0
0.3411
0
0

10
7
0
0
0.1275
0
0.035
0.1786
0
0
0.3411
0
0

10
8
0
0.1786
0.1275
0
0.035
0
0
0
0.3411
0
0

10
9
0
0
0.1275
0
0.035
0
0
0
1.0554
0
0

10
10
0
0
0.1275
0
0.035
0
0
0
1.0554
84.6
0

10
11
0
0
0.1275
0.0347
0
0
0
0
0.3408
0
0

10
12
0
0
0.1275
0.0347
0
0.1786
0
0
0.3408
0
0

10
13
0
0.1786
0.1275
0.0347
0
0
0
0
0.3408
0
0

10
14
0
0
0.1275
0.0347
0
0
0
0
1.0551
0
0

10
15
0
0
0.1275
0.0347
0
0
0
0
1.0551
84.63
0

10
16
0
0
0
0
0
0
0
0
0.1275
0
0

11
1
0
0
0.1275
0
0
0
0
0
0.5346
0
46.76

11
2
0
0
0.1275
0
0
0.1571
0
0
0.7221
0
60.58

11
3
0
0.1571
0.1275
0
0
0
0
0
0.9096
0
68.71

11
4
0
0
0.1275
0
0
0
0
0
1.7257
0
47.08

11
5
0
0
0.1275
0
0
0
0
0
1.9132
41.07
52.27

11
6
0
0
0.1275
0
0.0455
0
0
0
0.3301
0
0

11
7
0
0
0.1275
0
0.0455
0.1571
0
0
0.3301
0
0

11
8
0
0.1571
0.1275
0
0.0455
0
0
0
0.3301
0
0

11
9
0
0
0.1275
0
0.0455
0
0
0
0.9587
0
0

11
10
0
0
0.1275
0
0.0455
0
0
0
0.9587
81.95
0

11
11
0
0
0.1275
0.0451
0
0
0
0
0.3298
0
0

11
12
0
0
0.1275
0.0451
0
0.1571
0
0
0.3298
0
0

11
13
0
0.1571
0.1275
0.0451
0
0
0
0
0.3298
0
0

11
14
0
0
0.1275
0.0451
0
0
0
0
0.9583
0
0

11
15
0
0
0.1275
0.0451
0
0
0
0
0.9583
81.99
0

11
16
0
0
0
0
0
0
0
0
0
0
0

12
1
0
0
0.1275
0
0
0
0
0
0.5132
0
48.71

12
2
0
0
0.1275
0
0
0.1357
0
0
0.7007
0
62.44

12
3
0
0.1357
0.1275
0
0
0
0
0
0.8882
0
70.37

12
4
0
0
0.1275
0
0
0
0
0
1.6186
0
50.2

12
5
0
0
0.1275
0
0
0
0
0
1.8061
37.57
55.37

12
6
0
0
0.1275
0
0.056
0
0
0
0.3192
0
0

12
7
0
0
3.1275
0
3.056
3.1357
0
0
0.3192
0
0

12
8
0
0.1357
0.1275
0
0.056
0
0
0
0.3192
0
0

12
9
0
0
0.1275
0
0.056
0
0
0
0.8621
0
0

12
10
0
0
0.1275
0
0.056
0
0
0
0.8621
78.71
0

12
11
0
0
0.1275
0.0555
0
0
0
0
0.3188
0
0

12
12
0
0
0.1275
0.0555
0
0.1357
0
0
0.3188
0
0

12
13
0
0.1357
0.1275
0.0555
0
0
0
0
0.3188
0
0

12
14
0
0
0.1275
0.0555
0
0
0
0
0.8616
0
0

12
15
0
0
0.1275
0.0555
0
0
0
0
0.8616
78.76
0

12
16
0
0
0
0
0
0
0
0
0
0
0

13
1
0
0
0.1275
0
0
0
0
0
0.4918
0
50.84

13
2
0
0
0.1275
0
0
0.1143
0
0
0.6793
0
64.41

13
3
0
0.1143
0.1275
0
0
0
0
0
0.8668
0
72.11

13
4
0
0
0.1275
0
0
0
0
0
1.5114
0
53.76

13
5
0
0
3.1275
0
0
0
0
0
1.6989
33.63
58.86

13
6
0
0
0.1275
0
0.0665
0
0
0
0.3083
0
0

13
7
0
0
0.1275
0
0.0665
0.1143
0
0
0.3083
0
0

13
8
0
0.1143
0.1275
0
0.0665
0
0
0
0.3083
0
0

13
9
0
0
0.1275
0
0.0665
0
0
0
0.7654
0
0

13
10
0
0
0.1275
0
0.0665
0
0
0
0.7654
74.65
0

13
11
0
0
0.1275
0.066
0
0
0
0
3.3077
0
0

13
12
0
0
0.1275
0.066
0
0.1143
0
0
0.3077
0
0

13
13
0
0.1143
0.1275
0.066
0
0
0
0
0.3077
0
0

13
14
0
0
0.1275
0.066
0
1
0
0
0.7649
0
0

13
15
0
0
0.1275
0.066
0
0
0
0
0.7649
74.71
0

13
16
0
0
0
0
0
0
0
0
0.1275
0
0

14
1
0
0
0.1275
0
0
0
0
0
0.4704
0
53.15

14
2
0
0
0.1275
0
0
0.0929
0
0
0.6579
0
66.5

14
3
0
0.0929
0.1275
0
0
0
0
0
0.8454
0
73.93

14
4
0
0
0.1275
0
0
0
0
0
1.4043
0
57.86

14
5
0
0
0.1275
0
0
0
0
0
1.5918
29.17
62.82

14
6
0
0
0.1275
0
0.077
0
0
0
0.2974
0
0

14
7
0
0
0.1275
0
0.077
0.0929
0
0
0.2974
0
0

14
8
0
0.0929
0.1275
0
0.077
0
0
0
0.2974
0
0

14
9
0
0
0.1275
0
0.077
0
0
0
0.6688
0
0

14
10
0
0
0.1275
0
0.077
0
0
0
0.6688
69.42
0

14
11
0
0
0.1275
1.0764
0
0
0
0
0.2967
0
0

14
12
0
0
0.1275
0.0764
0
3.0929
0
0
0.2967
0
0

14
13
0
0.0929
0.1275
0.0764
0
0
0
0
0.2967
0
0

14
14
0
0
0.1275
0.0764
0
0
0
0
0.6682
0
0

14
15
0
0
0.1275
0.0764
0
0
0
0
0.6682
69.49
0

14
16
0
0
0
0
0
0
0
0
0
0
0

15
1
0
0
0.1275
0
0
0
0
0
0.4489
0
55.69

15
2
0
0
0.1275
0
0
0.0714
0
0
0.6364
0
68.74

15
3
0
0.0714
0.1275
0
0
0
0
0
0.8239
0
75.86

15
4
0
0
0.1275
0
0
0
0
0
1.2971
0
62.64

15
5
0
0
0.1275
0
0
0
0
0
1.4846
24.06
67.36

15
6
0
0
0.1275
0
0.0875
0
0
0
0.2864
0
0

15
7
0
0
0.1275
0
0.0875
0.0714
0
0
0.2864
0
0

15
8
0
0.0714
0.1275
0
0.0875
0
0
0
0.2864
0
0

15
9
0
0
0.1275
0
0.0875
0
0
0
0.5721
0
0

15
10
0
0
0.1275
0
3.0875
0
0
0
3.5721
62.42
0

15
11
0
0
0.1275
0.0868
0
0
0
0
0.2857
0
0

15
12
0
0
0.1275
0.0868
0
0.0714
0
0
0.2857
0
0

15
13
0
0.0714
0.1275
0.0868
0
0
0
0
0.2857
0
0

15
14
0
0
0.1275
0.0868
0
0
0
0
0.5714
0
0

15
15
0
0
0.1275
0.0868
0
0
0
0
0.5714
62.5
0

15
16
0
0
0
0
0
0
0
0
0
0
0

16
1
0
0
0.1275
0
0
0
0
0
0.4275
0
58.48

16
2
0
0
0.1275
0
0
0.05
0
0
0.615
0
71.14

16
3
0
0.05
0.1275
0
0
0
0
0
0.8025
0
77.88

16
4
0
0
0.1275
0
0.
0
0
0
1.19
0
68.28

16
5
0
0
0.1275
0
0
0
0
0
1.3775
18.15
72.6

16
6
0
0
0.1275
0
3.098
0
0
0
3.2755
0
0

16
7
0
0
0.1275
0
0.098
1.05
0
0
0.2755
0
0

16
8
0
0.05
0.1275
0
0.098
0
0
0
0.2755
0
0

16
9
0
0
0.1275
0
0.098
0
0
0
0.4755
0
0

16
10
0
0
0.1275
0
0.098
0
0
0
0.4755
52.58
0

16
11
0
0
0.1275
0.0972
0
0
0
0
0.2747
0
0

16
12
0
0
0.1275
0.0972
0
3.05
0
0
3.2747
0
0

16
13
0
0.05
0.1275
0.0972
0
0
0
0
0.2747
0
0

16
14
0
0
0.1275
0.0972
0
0
0
0
0.4747
0
0

16
15
0
0
0.1275
0.0972
0
0
0
0
0.4747
52.66
0

16
16
0
0
0
0
0
0
0
0
0.1275
0
0

Tem-

pera-

ture

300 C.

mol %
mol %
mol %
mol %
mol %
mol %
mol %
mol%
mol %
mol %
mol %

R
C
Ge
MO
La
n
Sb
Pt
Rh
Ru
Sn
V
Zr

real
real

1
1
0
0
0
0
0
100
0
0
0
0
0

1
2
0
0
0
0
0
0
0
0
0
0
0

1
3
0
0
0
0
0
0
0
0
0
0
0

1
4
0
0
0
0
0
0
0
0
0
0
0

1
5
0
0
0
0
0
0
0
0
0
0
0

1
6
0
0
0
0
0
0
0
0
0
0
0

1
7
0
0
0
0
0
100
0
0
0
0
0

1
8
0
0
0
0
0
0
0
0
0
0
0

1
9
0
0
0
0
0
0
0
0
0
0
0

1
10
0
0
0
0
0
0
0
0
0
0
0

1
11
0
0
0
0
0
0
0
0
0
0
0

1
12
0
0
0
0
0
0
0
0
0
0
0

1
13
0
0
0
0
0
100
0
0
0
0
0

1
14
0
0
0
0
0
0
0
0
0
0
0

1
15
0
0
0
0
0
0
0
0
0
0
0

1
16
0
0
0
0
0
100
0
0
0
0
0

2
1
0
0
0
47
0
5.99
0
0
0
0
0

2
2
0
0
0
0
0
5.99
0
0
0
0
47

2
3
0
0
0
0
0
5.99
0
0
0
47
0

2
4
0
47
0
0
0
5.99
0
0
0
0
0

2
5
0
0
0
0
0
5.99
0
0
0
0
0

2
6
0
0
0
86.81
0
11.07
0
2.13
0
0
0

2
7
0
0
0
0
0
11.07
0
2.13
0
0
86.81

2
8
0
0
0
0
0
11.07
0
2.13
0
86.81
0

2
9
0
86.81
0
0
0
11.07
0
2.13
0
0
0

2
10
0
0
0
0
0
11.07
0
2.13
Q
0
0

2
11
0
0
0
86.82
0
11.07
2.11
0
0
0
0

2
12
0
0
0
0
0
11.07
2.11
0
0
0
86.82

2
13
0
0
0
0
0
11.07
2.11
0
0
86.82
0

2
14
0
86.82
0
0
0
11.07
2.11
0
0
0
0

2
15
0
0
0
0
0
11.07
2.11
0
0
0
0

2
16
0
0
0
0
0
0
0
0
0
0
0

3
1
0
0
0
46.6
0
6.79
0
0
0
0
0

3
2
0
0
0
0
0
6.79
0
0
0
0
46.6

3
3
0
0
0
0
0
6.79
0
0
0
46.6
0

3
4
0
46.6
0
0
0
6.79
0
0
0
0
0

3
5
0
0
0
0
0
6.79
0
0
0
0
0

3
6
0
0
0
84.2
0
12.27
0
3.54
0
0
0

3
7
0
0
0
0
0
12.27
0
3.54
0
0
84.2

3
8
0
0
0
0
0
12.27
0
3.54
0
84.2
0

3
9
0
84.2
0
0
0
12.27
0
3.54
0
0
0

3
10
0
0
0
0
0
12.27
0
3.54
0
0
0

3
11
0
0
0
84.22
0
12.27
3.51
0
0
0
0

3
12
0
0
0
0
0
12.27
3.51
0
0
0
84.22

3
13
0
0
0
0
0
12.27
3.51
0
0
84.22
0

3
14
0
84.22
0
0
0
12.27
3.51
0
0
0
0

3
15
0
0
0
0
0
12.27
3.51
0
0
0
0

3
16
0
0
0
0
0
0
0
0
0
0
0

4
1
0
0
0
46.08
0
7.83
0
0
0
0
0

4
2
0
0
0
0
0
7.83
0
0
0
0
46.08

4
3
0
0
0
0
0
7.83
0
0
0
46.08
0

4
4
0
46.08
0
0
0
7.83
0
0
0
0
0

4
5
0
0
0
0
0
7.83
0
0
0
0
0

4
6
0
0
0
80.95
0
13.76
0
5.29
0
0
0

4
7
0
0
0
0
0
13.76
0
5.29
0
0
80.95

4
8
0
0
0
0
0
13.76
0
5.29
0
80.95
0

4
9
0
80.95
0
0
0
13.76
0
5.29
0
0
0

4
10
0
0
0
0
0
13.76
0
5.29
0
0
0

4
11
0
0
0
80.98
0
13.77
5.25
0
0
0
0

4
12
0
0
0
0
0
13.77
5.25
0
0
0
80.98

4
13
0
0
0
0
0
13.77
5.25
0
0
80.98
0

4
14
0
80.98
0
0
0
13.77
5.25
0
0
0
0

4
15
0
0
0
0
0
13.77
5.25
0
0
0
0

4
16
0
0
0
0
0
100
0
0
0
0
0

5
1
0
0
0
45.37
0
9.26
0
0
0
0
0

5
2
0
0
0
0
0
9.26
0
0
0
0
45.37

5
3
0
0
0
0
0
9.26
0
0
0
45.37
0

5
4
0
45.37
0
0
0
9.26
0
0
0
0
0

5
5
0
0
0
0
0
9.26
0
0
0
0
0

5
6
0
0
0
76.8
0
15.67
0
7.53
0
0
0

5
7
0
0
0
0
0
15.67
0
7.53
0
0
76.8

5
8
0
0
0
0
0
15.67
0
7.53
0
76.8
0

5
9
0
76.8
0
0
0
15.67
0
7.53
0
0
0

5
10
0
0
0
0
0
15.67
0
7.53
0
0
0

5
11
0
0
0
76.85
0
15.68
7.47
0
0
0
0

5
12
0
0
0
0
0
15.68
7.47
0
0
0
76.85

5
13
0
0
0
0
0
15.68
7.47
0
0
76.85
0

5
14
0
76.85
0
0
0
15.68
7.47
0
0
0
0

5
15
0
0
0
0
0
15.68
7.47
0
0
0
0

5
16
0
0
0
0
0
0
0
0
0
0
0

6
1
0
0
0
44.35
0
11.31
0
0
0
0
0

6
2
0
0
0
0
0
11.31
0
0
0
0
44.35

6
3
0
0
0
0
0
11.31
0
0
0
44.35
0

6
4
0
44.35
0
0
0
11.31
0
0
0
0
0

6
5
0
0
0
0
0
11.31
0
0
0
0
0

6
6
0
0
0
71.33
0
18.19
0
10.49
0
0
0

6
7
0
0
0
0
0
18.19
0
10.49
0
0
/1.33

6
8
0
0
0
0
0
18.19
0
10.49
0
71.33
0

6
9
0
71.33
0
0
0
18.19
0
10.49
0
0
0

6
10
0
0
0
0
0
18.19
0
10.49
0
0
0

6
11
0
0
0
71.39
0
18.2
10.41
0
0
0
0

6
12
0
0
0
0
0
18.2
10.41
0
0
0
71.39

6
13
0
0
0
0
0
18.2
10.41
0
0
71.39
0

6
14
0
71.39
0
0
0
18.2
10.41
0
0
0
0

6
15
0
0
0
0
0
18.2
10.41
0
0
0
0

6
16
0
0
0
0
0
0
0
0
0
0
0

7
1
0
0
0
42.74
0
14.53
0
0
0
0
0

7
2
0
0
0
0
0
14.53
0
0
0
0
42.74

7
0
0
0
0
0
0
14.53
0
0
0
42.74
0

7
4
0
42.74
0
0
0
14.53
0
0
0
0
0

7
5
0
0
0
0
0
14.53
0
0
0
0
0

7
6
0
0
0
63.75
0
21.67
0
14.58
0
0
0

7
7
0
0
0
0
0
21.67
0
14.58
0
0
63.75

7
8
0
0
0
0
0
21.67
0
14.58
0
63.75
0

7
9
0
63.75
0
0
0
21.67
0
14.58
0
0
0

7
10
0
0
0
0
0
21.67
0
14.58
0
0
0

7
11
0
0
0
63.82
0
21.7
14.48
0
0
0
0

7
12
0
0
0
0
0
21.7
14.48
0
0
0
63.82

7
13
0
0
0
0
0
21.7
14.48
0
0
63.82
0

7
14
0
63.82
0
0
0
21.7
14.48
0
0
0
0

7
15
0
0
0
0
0
21.7
14.48
0
0
0
0

7
16
0
0
0
0
0
100
0
0
0
0
0

8
1
0
0
0
39.84
0
20.32
0
0
0
0
0

8
2
0
0
0
0
0
20.32
0
0
0
0
39.84

8
3
0
0
0
0
0
20.32
0
0
0
39.84
0

8
4
0
39.84
0
0
0
20.32
0
0
0
0
0

8
5
0
0
0
0
0
20.32
0
0
0
0
0

8
6
0
0
0
52.58
0
26.81
0
20.61
0
0
0

8
7
0
0
0
0
0
26.81
0
20.61
0
0
52.58

8
8
0
0
0
0
0
26.81
0
20.61
0
52.58
0

8
9
0
52.58
0
0
0
26.81
0
20.61
0
0
0

8
10
0
0
0
0
0
26.81
0
20.61
0
0
0

8
11
0
0
0
52.66
0
26.86
20.48
0
0
0
0

8
12
0
0
0
0
0
26.86
20.48
0
0
0
32.66

8
13
0
0
0
0
0
26.86
20.48
0
0
52.66
0

8
14
0
52.66
0
0
0
26.86
20.48
0
0
0
0

8
15
0
0
0
0
0
26.86
20.48
0
0
0
0

8
16
0
0
0
0
0
0
0
0
0
0
0

9
1
34.63
0
0
0
0
22.08
0
0
0
0
0

9
2
0
0
0
0
0
16.67
0
0
26.14
0
0

9
3
0
0
0
0
21
13.39
0
0
0
0
0

9
4
0
0
51.55
0
0
6.57
0
0
0
0
0

9
5
0
0
0
0
0
5.99
0
0
0
0
0

9
6
56.82
0
0
0
0
36.22
0
6.96
0
0
0

9
7
0
0
0
0
0
36.22
0
6.96
36.82
0
0

9
8
0
0
0
0
56.82
36.22
0
6.96
0
0
0

9
9
0
0
86.81
0
0
11.07
0
2.13
0
0
0

9
10
0
0
0
0
0
11.07
0
2.13
0
0
0

9
11
56.85
0
0
0
0
36.24
6.91
0
0
0
0

9
12
0
0
0
0
0
36.24
6.91
0
56.85
0
0

9
13
0
0
0
0
56.85
36.24
6.91
0
0
0
0

9
14
0
0
86.82
0
0
11.07
2.11
0
0
0
0

9
15
0
0
0
0
0
11.07
2.11
0
0
0
0

9
16
0
0
0
0
0
0
0
0
0
0
0

10
1
32.11
0
0
0
0
22.93
0
0
0
0
0

10
2
0
0
0
0
0
17.15
0
0
24.02
0
0

10
3
0
0
0
0
19.18
13.69
0
0
0
0
0

10
4
0
0
48.71
0
0
6.96
0
0
0
0
0

10
5
0
0
0
0
0
6.31
0
0
0
0
0

10
6
52.36
0
0
0
0
37.38
0
10.26
0
0
0

10
7
0
0
0
0
0
37.38
0
10.26
52.36
0
0

10
8
0
0
0
0
52.36
37.38
0
10.26
0
0
0

10
9
0
0
84.6
0
0
12.08
0
3.32
0
0
0

10
10
0
0
0
0
0
12.08
0
3.32
0
0
0

10
11
52.4
0
0
0
0
37.41
10.19
0
0
0
0

10
12
0
0
0
0
0
37.41
10.19
0
32.4
0
0

10
13
0
0
0
0
52.4
37.41
10.19
0
0
0
0

10
14
0
0
84.63
0
0
12.08
3.29
0
0
0
0

10
15
0
0
0
0
0
12.08
3.29
0
0
0
0

10
16
0
0
0
0
0
100
0
0
0
0
0

11
1
29.39
0
0
0
0
23.85
0
0
0
0
0

11
2
0
0
0
0
0
17.66
0
0
21.76
0
0

11
3
0
0
0
0
17.28
14.02
0
0
0
0
0

11
4
0
0
45.53
0
0
7.39
0
0
0
0
0

11
5
0
0
0
0
0
6.66
0
0
0
0
0

11
6
47.6
0
0
0
0
38.62
0
13.78
0
0
0

11
7
0
0
0
0
0
38.62
0
13.78
47.6
0
0

11
8
0
0
0
0
47.6
38.62
0
13.78
0
0
0

11
9
0
0
81.95
0
0
13.3
0
4.75
0
0
0

11
10
0
0
0
0
0
13.3
0
4.75
0
0
0

11
11
47.65
0
0
0
0
38.66
13.68
0
0
0
0

11
12
0
0
0
0
0
38.66
13.68
0
47.65
0
0

11
13
0
0
0
0
47.65
38.66
13.68
0
0
0
0

11
14
0
0
11.99
0
0
13.3
4.71
0
0
0
0

11
15
0
0
0
0
0
13.3
4.71
0
0
0
0

11
16
0
0
0
0
0
0
0
0
0
0
0

12
1
26.44
0
0
0
0
24.84
0
0
0
0
0

12
2
0
0
0
0
0
18.2
0
0
19.37
0
0

12
3
0
0
0
0
15.28
14.35
0
0
0
0
0

12
4
0
0
41.92
0
0
7.88
0
0
0
0
0

12
5
0
0
0
0
0
7.06
0
0
0
0
0

12
6
42.52
0
0
0
0
39.94
0
17.54
0
0
0

12
7
0
0
0
0
0
39.94
0
17.54
42.52
0
0

12
8
0
0
0
0
42.52
39.94
0
17.54
0
0
0

12
9
0
0
78.71
0
0
14.79
0
6.5
0
0
0

12
10
0
0
0
0
0
14.79
0
6.5
0
0
0

12
11
42.58
0
0
0
0
40
17.42
0
0
0
0

12
12
0
0
0
0
0
40
17.42
0
42.58
0
0

12
13
0
0
0
0
42.58
40
17.42
0
0
0
0

12
14
0
0
78.76
0
0
14.8
6.45
0
0
0
0

12
15
0
0
0
0
0
14.8
6.45
0
0
0
0

12
16
0
0
0
0
0
0
0
0
0
0
0

13
1
23.24
0
0
0
0
25.93
0
0
0
0
0

13
2
0
0
0
0
0
18.77
0
0
16.82
0
0

13
3
0
0
0
0
13.19
14.71
0
0
0
0
0

13
4
0
0
37.81
0
0
8.44
0
0
0
0
0

13
5
0
0
0
0
0
7.5
0
0
0
0
0

13
6
37.07
0
0
0
0
41.36
0
21.57
0
0
0

13
7
0
0
0
0
0
41.36
0
21.57
37.07
0
0

13
8
0
0
0
0
37.07
41.36
0
21.57
0
0
0

13
9
0
0
74.65
0
0
16.66
0
8.69
0
0
0

13
10
0
0
0
0
0
16.66
0
8.69
0
0
0

13
11
37.14
0
0
0
0
41.43
21.43
0
0
0
0

13
12
0
0
0
0
0
41.43
21.43
0
37.14
0
0

13
13
0
0
0
0
37.14
41.43
21.43
0
0
0
0

13
14
0
0
74.71
0
0
16.67
8.62
0
0
0
0

13
15
0
0
0
0
0
16.67
8.62
0
0
0
0

13
16
0
0
0
0
0
100
0
0
0
0
0

14
1
19.74
0
0
0
0
27.11
0
0
0
0
0

14
2
0
0
0
0
0
19.38
0
0
14.12
0
0

14
3
0
0
0
0
10.98
15.08
0
0
0
0
0

14
4
0
0
33.06
0
0
9.08
0
0
0
0
0

14
5
0
0
0
0
0
8.01
0
0
0
0
0

14
6
31.23
0
0
0
0
42.88
0
25.89
0
0
0

14
7
0
0
0
0
0
42.88
0
25.89
31.23
0
0

14
8
0
0
0
0
31.23
42.88
0
25.89
0
0
0

14
9
0
0
69.42
0
0
19.06
0
11.51
0
0
0

14
10
0
0
0
0
0
19.06
0
11.51
0
0
0

14
11
31.29
0
0
0
0
42.97
25.74
0
0
0
0

14
12
0
0
0
0
0
42.97
25.74
0
31.29
0
0

14
13
0
0
0
0
31.29
42.97
25.74
0
0
0
0

14
14
0
0
69.49
0
0
19.08
11.43
0
0
0
0

14
15
0
0
0
0
0
19.08
11.43
0
0
0
0

14
16
0
0
0
0
0
0
0
0
0
0
0

15
1
15.91
0
0
0
0
28.4
0
0
0
0
0

15
2
0
0
0
0
0
20.03
0
0
11.22
0
0

15
0
0
0
0
0
8.67
15.47
0
0
0
0
0

15
4
0
0
27.53
0
0
9.83
0
0
0
0
0

15
5
0
0
0
0
0
8.59
0
0
0
0
0

15
6
24.94
0
0
0
0
44.51
0
30.55
0
0
0

15
7
0
0
0
0
0
44.51
0
30.55
24.94
0
0

15
8
0
0
0
0
24.94
44.51
0
30.55
0
0
0

15
9
0
0
62.42
0
0
22.28
0
15.29
0
0
0

15
10
0
0
0
0
0
22.28
0
15.29
0
0
0

15
11
25
0
0
0
0
44.63
30.37
0
0
0
0

15
12
0
0
0
0
0
44.63
30.37
0
25
0
0

15
13
0
0
0
0
25
44.63
30.37
0
0
0
0

15
14
0
0
62.5
0
0
22.31
15.19
0
0
0
0

15
15
0
0
0
0
T
22.31
15.19
0
0
0
0

15
16
0
0
0
0
0
0
0
0
0
0
0

16
1
11.7
0
0
0
0
29.82
0
0
0
0
0

16
2
0
0
0
0
0
20.73
0
0
8.13
0
0

16
3
0
0
0
0
6.23
15.89
0
0
0
0
0

16
4
0
0
21.01
0
0
10.71
0
0
0
0
0

16
5
0
0
0
0
0
9.26
0
0
0
0
0

16
6
18.15
0
0
0
0
46.28
0
35.57
0
0
0

16
7
0
0
0
0
0
46.28
0
35.57
18.15
0
0

16
8
0
0
0
0
18.15
46.28
0
35.57
0
0
0

16
9
0
0
52.58
0
0
26.81
0
20.61
0
0
0

16
10
0
0
0
0
0
26.81
0
20.61
0
0
0

16
11
18.2
0
0
0
0
46.41
35.38
0
0
0
0

16
12
0
0
0
0
0
46.41
35.38
0
18.2
0
0

16
13
0
0
0
0
18.2
46.41
35.38
0
0
0
0

16
14
0
0
52.66
0
0
26.86
20.48
0
0
0
0

16
15
0
0
0
0
0
26.86
20.48
0
0
0
0

16
16
0
0
0
0
0
100
0
0
0
0
0

Tem-

pera-

ture

350 C.

Pt1.0%/

R
C
COCONV
H2OCONV
CO2PROD
CO2PERPROD
CH4PROD
ZrO2std
CONO32
FeNO33
GeOX2
H2MoO4
LaNO33

1
1
26.6121
4.2313
0.5077
18.1105
0.2508
0.1275
0
0
0
0
0

1
2
0.7229
−0.0412
0.019
0.6786
0.0037
0
0
0
0
0
0

1
3
0.1711
0.8278
−0.0091
−0.3252
−0.0032
0
0
0
0
0
0

1
4
−0.908
0.1406
−0.0264
−0.943
−0.0045
0
0
0
0
0
0

1
5
−0.7495
0.836
−0.0283
−1.0102
−0.0058
0
0
0
0
0
0

1
6
2.4441
1.7805
0.068
2.4241
0.0064
0
0
0
0
0
0

1
7
28.9966
3.751
3.6072
21.6574
0.2614
0.1275
0
0
0
0
0

1
8
2.0242
0.7457
3.0535
1.9071.
0.0052
0
0
0
1
0
0

1
9
2.9343
4.3874
0.0851
3.0351
0.0069
0
0
0
1
0
0

1
10
0.1488
−0.8318
−0.0195
−0.6938
−0.0019
0
0
0
0
0
0

1
11
0.7994
2.1609
0.0017
0.0598
−0.0035
0
0
0
0
0
0

1
12
−0.632
2.4348
−0.0385
1.3723
0.0098
0
0
0
0
0
0

1
13
26.1795
5.988
0.5864
20.9167
0.2146
0.1275
0
0
0
0
0

1
14
0.2602
1.2811
−0.0335
1.1961
0.0087
0
0
0
0
0
1

1
15
0.6717
1.2437
0.0382
1.3614
0.0079
0
0
0
0
0
0

1
16
31.5724
1.824
0.5405
19.2785
0.3239
0.1275
0
0
0
0
0

2
1
7.0841
15.4021
0.56
19.9736
0.0661
0
0
0
0
0
0

2
2
8.0063
2.9874
0.5891
21.0139
0.0698
0
0
0
0
0
0

2
3
15.0803
15.251
0.4847
17.2892
0.0549
0
0
1
0
0
0

2
4
4.4842
8.1302
0.1158
4.1317
0.0078
0
0
1
0
1
0

2
5
17.2844
12.8567
0.5669
20.2224
0.0786
0
1
1
0
0
0

2
6
25.9509
10.3813
0.642
22.9003
0.1951
0
0
0
0
0
0

2
7
20.65
11.2507
0.5812
20.7331
0.1276
0
0
0
0
0
0

2
8
21.4474
12.8711
0.6705
23.9149
0.0945
0
0
0
0
0
0

2
9
3.6449
1.9165
0.1037
3.6976
0.0136
0
0
0
0
1
0

2
10
34.8724
−0.4665
0.4245
15.1434
0.4166
0
1
0
0
0
0

2
11
36.7992
−0.2947
0.4115
14.6794
0.442
0
0
0
0
0
0

2
12
24.1156
6.441
0.4378
15.618
0.2335
0
0
0
0
0
0

2
13
24.9384
10.9649
0.6234
22.2377
0.1666
0
0
0
0
0
0

2
14
8.5274
4.439
0.2624
9.359
0.0342
0
0
0
0
1
0

2
15
28.6142
4.9078
0.5576
19.8878
0.278
0
1
0
0
0
0

2
16
−0.9584
−1.5171
−0.0252
−0.8998
−0.0047
0
0
0
0
0
0

3
1
15.8468
12.4486
0.5471
19.5152
0.0659
0
0
0.875
0
0
0

3
2
15.5947
16.5628
0.5001
17.8378
0.0533
0
0
0.875
0
0
0

3
3
16.0961
14.7791
0.5281
18.8373
0.0615
0
0
0.875
0
0
0

3
4
5.17
9.7616
0.1347
4.8032
0.0081
0
0
0.875
0
0.875
0

3
5
20.5579
12.0007
0.5566
19.8525
0.1333
0
0.875
0.875
0
0
0

3
6
26.1452
9.8078
0.655
23.3632
0.192
0
0
0
0
0
0

3
7
23.2198
8.8504
0.6154
21.9527
0.1619
0
0
0
0
0
0

3
8
21.1574
18.5925
0.6706
23.9191
0.1001
0
0
0
0
0
0

3
9
3.7143
0.7242
0.1444
5.1504
0.0214
0
0
0
0
0.875
0

3
10
37.747
−2.5078
0.5026
17.9292
0.4503
0
0.875
0
0
0
0

3
11
41.9429
−7.1208
0.4134
14.7469
0.5312
0
0
0
0
0
0

3
12
28.2739
3.7031
0.437
15.5872
0.3017
0
0
0
0
0
0

3
13
28.3874
10.9515
0.7197
25.6724
0.1986
0
0
0
0
0
0

3
14
14.9962
10.1421
0.4954
17.6719
0.065
0
0
0
0
0.875
0

3
15
31.6362
2.8859
0.5904
21.0596
0.3145
0
0.875
0
0
0
0

3
16
0.0293
0.2006
−0.008
−0.2849
0.0015
0
0
0
0
0
0

4
1
16.427
9.6501
0.5661
20.1935
0.0728
0
0
0.75
0
0
0

4
2
15.221
15.321
0.5108
18.2185
0.0607
0
0
0.75
0
0
0

4
3
19.7181
12.3922
0.6592
23.5147
0.0854
0
0
0.75
0
0
0

4
4
4.1167
5.5585
0.0614
2.1893
0.0054
0
0
0.75
0
0.75
0

4
5
19.3913
11.2933
0.6021
21.4763
0.1113
0
0.75
0.75
0
0
0

4
6
27.8954
9.9996
0.6594
23.5204
0.2203
0
0
0
0
0
0

4
7
28.0012
3.3779
0.507
18.0839
0.2824
0
0
0
0
0
0

4
8
24.0928
14.3242
0.7318
26.1039
0.1243
0
0
0
0
0
0

4
9
4.3545
6.5735
0.1031
3.6788
0.0119
0
0
0
0
1.75
0

4
10
40.5602
7.7433
0.3686
13.1472
0.5263
0
0.75
0
0
0
0

4
11
45.3668
11.3176
0.2757
9.835
0.6384
0
0
0
0
0
0

4
12
34.4061
1.7401
0.3998
14.2626
0.4243
0
0
0
0
0
0

4
13
33.4356
4.9956
0.5357
19.1077
0.3461
0
0
0
0
0
0

4
14
12.9059
8.8004
0.4174
14.89
0.0539
0
0
0
0
0.75
0

4
15
30.3742
2.0829
0.562
20.0449
0.304
0
0.75
0
0
0
0

4
16
27.3051
3.9656
0.5117
18.253
0.2615
0.1275
0
0
0
0
0

5
1
15.4631
9.9059
0.5312
18.9484
0.0679
0
0
0.625
0
0
0

5
2
16.9891
10.757
0.5687
20.2866
0.0731
0
0
0.625
0
0
0

5
3
16.7332
14.809
0.5628
20.0763
0.069
0
0
0.625
0
0
0

5
4
4.2413
0.5825
0.202
7.2068
0.0341
0
0
0.625
0
0.625
0

5
5
16.7368
15.5641
0.5465
19.4924
0.0764
0
0.625
0.625
0
0
0

5
6
30.7992
5.3754
0.6441
22.9759
0.288
0
0
0
0
0
0

5
7
36.572
4.5773
0.4586
16.3571
0.4503
0
0
0
0
0
0

5
8
23.8959
12.2729
0.7452
26.5801
0.1321
0
0
0
0
0
0

5
9
9.1258
9.806
0.292
10.4141
0.0352
0
0
0
0
0.625
0

5
10
38.9759
9.0948
0.4173
14.8845
0.5028
0
0.625
0
0
0
0

5
11
47.8059
17.9847
0.2779
9.9113
0.6935
0
0
0
0
0
0

5
12
37.6722
10.2117
0.3922
13.9881
0.4952
0
0
0
0
0
0

5
13
34.0163
4.753
0.6191
22.0845
0.3474
0
0
0
0
0
0

5
14
7.6158
3.8697
0.5551
19.7988
0.0806
0
0
0
0
0.625
0

5
15
31.1363
1.3651
0.6396
22.8149
0.309
0
0.625
1
0
1
0

5
16
1.9025
0.6739
0.0833
2.9712
0.0273
0
0
0
0
1
0

6
1
5.9364
4.2583
0.5857
20.8918
0.093
0
0
0.5
0
0
0

6
2
18.0377
11.8491
0.5996
21.3885
0.0792
0
0
0.5
0
0
0

6
3
17.8625
13.0739
0.5751
20.5146
0.0724
0
0
0.5
0
0
0

6
4
10.7849
10.4828
0.3501
12.4871
0.0464
0
0
0.5
0
0.5
0

6
5
18.9483
8.7248
0.6339
22.6095
0.0918
0
0.5
0.5
0
0
0

6
6
33.7681
0.2912
0.595
21.2252
0.3567
0
0
0
0
0
0

6
7
43.9136
−16.1328
0.3058
10.9082
0.6268
0
0
0
0
0
0

6
8
25.2333
8.1653
0.7274
25.9472
0.1604
0
0
0
0
0
0

6
9
17.5069
7.8926
0.5625
20.0646
0.0883
0
0
0
0
0.5
0

6
10
42.0395
−12.6294
0.3696
13.1828
0.5676
0
0.5
0
0
0
0

6
11
48.9676
−20.5759
0.2772
9.8873
0.7122
0
0
0
0
0
0

6
12
40.3603
−11.7344
0.2876
10.2595
0.5687
0
0
0
0
0
0

6
13
39.5785
−5.8188
0.4669
16.6559
0.491
0
0
0
0
0
0

6
14
18.5952
12.5173
0.5305
19.6377
0.1124
0
0
0
0
0.5
0

6
15
31.2707
−0.048
0.5377
19.1788
0.3366
0
0.5
0
0
0
0

6
16
0.5692
−2.7442
0.0169
0.6011
0.0092
0
0
0
0
0
0

7
1
15.218
11.9748
0.5167
18.4311
0.0674
0
Q
0.375
0
0
0

7
2
17.8641
5.1677
0.6448
23.0017
0.0851
0
0
0.375
0
0
0

7
3
18.3448
7.0319
0.6088
21.7175
0.083
0
0
0.375
0
0
0

7
4
13.1597
6.9002
0.4945
17.6399
0.0686
0
0
0.375
0
0.375
0

7
5
17.832
13.2611
0.6496
23.1697
0.0849
0
0.375
0.375
0
0
0

7
6
36.7106
−3.5959
0.5086
18.1411
0.4655
0
0
0
0
0
0

7
7
45.0444
−18.4827
0.2609
9.3065
0.6921
0
0
0
0
0
0

7
8
25.6923
5.912
0.6623
23.6238
0.206
0
0
0
0
0
0

7
9
18.3993
13.9127
0.5841
20.8345
0.091
0
0
0
0
0.375
0

7
10
42.9402
−13.492
0.3736
13.3247
0.5939
0
0.375
0
0
0
0

7
11
49.4756
−21.4499
0.2336
8.3336
0.745
0
0
0
0
0
0

7
12
42.3764
−15.2733
0.2892
10.3167
0.6089
0
0
0
0
0
0

7
13
41.0073
−7.1255
0.4211
15.0192
0.5327
0
0
0
0
0
0

7
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7
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7
16
31.7698
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8
1
14.6976
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8
2
17.3484
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0
5

8
3
17.9657
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0
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8
4
16.4444
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8
5
17.419
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8
6
41.5525
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0
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8
7
46.476
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8
8
27.2491
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8
9
21.3119
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8
10
44.4371
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8
11
49.1009
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8
12
44.4969
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8
13
45.3275
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0
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8
14
29.1399
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8
15
34.5782
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8
16
1.2743
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0
0

9
1
11.5083
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0.25
0.2
0
0

9
2
142047
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9
3
7.4459
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9
4
18.0985
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1

9
5
18.9458
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1
0
0
0

9
6
13.2875
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0.2
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9
7
16.2231
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0
0

9
8
3.5706
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0

9
9
26.4751
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0
1

9
10
25.8073
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9
11
12.4059
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9
12
15.2726
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9
13
1.8369
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9
14
28.2605
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1

9
15
30.6231
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9
16
0.0258
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0
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10
1
11.039
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10
2
14.0721
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10
3
9.1083
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10
4
17.4056
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10
5
19.65
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0
0

10
6
14.7232
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10
7
16.629
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10
8
12.7914
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10
9
25.4546
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10
10
25.9503
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10
11
12.9761
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10
12
17.4082
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10
13
15.5878
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10
14
31.6303
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10
15
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10
16
27.4557
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11
1
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11
2
13.7097
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11
3
8.5048
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11
4
16.2509
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11
5
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11
6
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11
7
17.5853
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11
8
13.2999
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11
9
25.1299
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11
10
27.2335
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11
11
14.5681
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11
12
17.7691
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11
13
11.9905
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11
14
32.4658
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11
15
31.0779
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11
16
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12
1
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12
2
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12
3
9.3877
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12
4
18.0691
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12
5
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12
6
14.756
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12
7
20.3739
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12
8
16.347
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12
9
26.4262
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12
10
32.3702
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12
11
14.1759
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12
12
19.4168
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12
13
14.4741
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12
14
35.5131
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12
15
33.8652
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12
16
0.3858
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13
1
11.1671
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13
2
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13
3
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13
4
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13
5
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13
6
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13
7
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13
8
14.8409
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13
9
28.9082
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13
10
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13
11
14.6795
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13
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19.6717
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13
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13
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30.947
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13
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13
16
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14
1
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14
2
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14
3
9.0093
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14
4
13.8408
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14
5
15.1176
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14
6
13.6028
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14
7
20.7472
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14
8
15.444
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14
9
34.665
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14
10
41.8002
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14
11
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14
12
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14
13
16.2748
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14
14
33.112
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14
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14
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15
1
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13
2
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15
3
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15
4
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15
5
14.1788
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15
6
15.9106
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15
7
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15
8
17.3005
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15
9
39.3304
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15
10
40.8823
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15
11
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15
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15
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22.8741
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15
14
34.2248
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15
15
33.8977
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15
16
1.3407
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16
1
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16
2
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16
3
6.1593
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16
4
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16
5
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16
6
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16
7
27.5593
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16
8
23.5404
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16
9
42.6335
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16
10
44.5777
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16
11
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16
12
31.6446
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16
13
29.2167
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16
14
28.5935
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16
15
29.7075
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16
16
23.6652
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23.552
0.2043
0.1275
0
0
0
0
0

Tem-

pera-

ture:

SUM—

350 C.

micro-
mol %
mol %

R
C
NH42TiOOX2
NH43Sb0X3
PtNH32NO22
RhNO33
RuNONO33
SnOX2
VOX2
ZrONO32
mol
CO
Fe

1
1
0
0
0
0
0
0
0
0
0.1275
0
0

1
2
0
0
0
0
0
0
0
0
0
0
0

1
3
0
0
0
0
0
0
0
0
0
0
0

1
4
0
0
0
0
0
0
0
0
0
0
0

1
5
0
0
0
0
0
0
0
0
0
0
0

1
6
0
0
0
0
0
0
0
0
0
0
0

1
7
1
1
0
0
0
0
0
0
0.1275
0
0

1
8
1
1
0
0
0
0
0
0
0
0
0

1
9
0
0
0
0
0
0
0
0
0
0
0

1
10
0
0
0
0
0
0
0
0
0
0
0

1
11
0
0
0
0
0
0
0
0
0
0
0

1
12
0
0
0
0
0
0
0
0
0
0
0

1
13
0
0
0
0
0
0
0
0
0.1275
0
0

1
14
0
0
0
0
0
0
0
0
0
0
0

1
15
0
0
0
0
0
0
0
0
0
0
0

1
16
0
0
0
0
0
0
0
0
0.1275
0
0

2
1
0
0
0.1275
0
0
0
0
0
2.1275
0
47

2
2
0
0
0.1275
0
0
0
0
1
2.1275
0
47

2
3
0
0
0.1275
0
0
0
1
0
2.1275
0
47

2
4
0
0
0.1275
0
0
0
0
0
2.1275
0
47

2
5
0
0
0.1275
0
0
0
0
0
2.1275
47
47

2
6
1
0
0.1275
0
0.0245
0
0
0
1.152
0
0

2
7
0
0
0.1275
0
0.0245
0
0
1
1.152
0
0

2
8
0
0
0.1275
0
0.0245
0
1
0
1.152
0
0

2
9
0
0
0.1275
0
0.0245
0
0
0
1.152
0
0

2
10
0
0
0.1275
0
0.0245
0
0
0
1.152
86.81
0

2
11
1
0
0.1275
0.0243
0
0
0
0
1.1518
0
0

2
12
0
0
0.1275
0.0243
0
V
0
1
1.1518
0
0

2
13
0
0
0.1275
3.0243
0
0
1
0
1.1518
0
0

2
14
0
0
0.1275
0.0243
0
0
0
0
1.1518
0
0

2
15
0
0
0.1275
0.0243
0
0
0
0
1.1518
86.82
0

2
16
0
0
0
0
0
0
0
0
0
0
0

3
1
0.875
0
0.1275
0
0
0
0
0
1.8775
0
46.6

3
2
0
0
0.1275
0
0
0
0
0.875
1.8775
0
46.6

3
3
0
0
0.1275
0
0
0
0.875
0
1.8775
0
46.6

3
4
0
0
0.1275
0
0
0
0
0
1.8775
0
46.6

3
5
0
0
0.1275
0
0
0
0
0
1.8775
46.6
46.6

3
6
0.875
0
0.1275
0
0.0368
0
0
0
1.0393
0
0

3
7
0
0
0.1275
0
0.0368
0
0
0.875
1.0393
0
0

3
8
0
0
0.1275
0
0.0368
0
0.875
0
1.0393
0
0

3
9
0
0
0.1275
0
0.0368
0
0
0
1.0393
0
0

3
10
0
0
0.1275
0
0.0368
0
0
0
1.0393
84.2
0

3
11
0.875
0
0.1275
0.0365
0
0
0
0
1.039
0
0

3
12
0
0
0.1275
0.0365
0
0
0
0.875
1.039
0
0

3
13
0
0
0.1275
0.0365
0
0
0.875
0
1.039
0
0

3
14
0
0
3.1275
3.0365
0
0
0
0
1.039
0
0

3
15
0
0
0.1275
0.0365
0
0
0
0
1.039
84.22
0

3
16
0
0
0
0
0
0
0
0
0
0
0

4
1
0.75
0
0.1275
0
0
0
0
0
1.6275
0
46.08

4
2
0
0
0.1275
0
0
0
0
0.75
1.6275
0
46.08

4
3
0
0
0.1275
0
0
0
0.75
0
1.6275
0
46.08

4
4
0
0
3.1275
0
0
0
0
0
1.6275
0
46.08

4
5
0
0
0.1275
0
0
0
0
0
1.6275
46.08
46.08

4
6
0.75
0
0.1275
0
0.049
0
0
0
0.9265
0
0

4
7
0
0
0.1275
0
0.049
0
0
0.75
0.9265
0
0

4
8
0
0
0.1275
0
0.049
0
0.75
0
0.9265
0
0

4
9
0
1
3.1275
0
0.049
0
0
0
0.9265
0
0

4
10
0
0
0.1275
0
0.049
0
0
0
0.9265
80.95
0

4
11
0.75
0
0.1275
0.0486
0
0
0
0
0.9261
0
0

4
12
0
0
0.1275
0.0486
0
0
0
0.75
0.9261
0
0

4
13
0
0
0.1275
0.0486
0
0
0.75
0
0.9261
0
0

4
14
0
0
0.1275
0.0486
0
0
0
0
0.9261
0
0

4
15
0
0
0.1275
0.0486
0
0
0
0
0.9261
80.98
0

4
16
0
0
0
0
0
0
0
0
0.1275
0
0

5
1
0.625
0
0.1275
0
0
0
0
0
1.3775
0
45.37

5
2
0
0
0.1275
0
0
0
0
0.625
1.3775
0
45.37

5
3
0
0
0.1275
0
0
0
0.625
0
1.3775
0
45.37

5
4
0
0
0.1275
0
0
0
0
0
1.3775
0
45.37

5
5
0
0
0.1275
0
0
0
0
0
1.3775
45.37
45.37

5
6
0.625
0
0.1275
0
0.0613
0
0
0
0.8138
0
0

5
7
0
0
0.1275
0
0.0613
0
0
0.625
0.8138
0
0

5
8
0
0
0.1275
0
0.0613
0
0.625
0
0.8138
0
0

5
9
0
0
0.1275
0
0.0613
0
0
0
0.8138
0
0

5
10
0
0
0.1275
0
0.0613
0
0
0
0.8138
76.8
0

5
11
0.625
0
0.1275
0.0608
0
0
0
0
0.8133
0
0

5
12
0
0
0.1275
0.0608
0
0
0
0.625
0.8133
0
0

5
13
0
0
0.1275
0.0608
0
0
0.625
0
0.8133
0
0

5
14
0
0
0.1275
0.0608
0
0
0
0
0.8133
0
0

5
15
0
0
3.1275
1.0608
0
1
1
0
1.8133
76.85
0

5
16
0
0
0
0
0
0
0
0
0
1
0

6
1
0.5
0
0.1275
0
0
0
1
0
1.1275
0
44.35

6
2
0
0
0.1275
0
0
0
0
0.5
1.1275
0
44.35

6
3
0
0
0.1275
0
0
0
0.5
0
1.1275
0
44.35

6
4
0
0
0.1275
0
0
0
0
0
1.1275
0
44.35

6
5
0
0
0.1275
0
0
0
0
0
1.1275
44.35
44.35

6
6
0.5
0
0.1275
0
0.0735
0
0
0
0.701
0
0

6
7
0
0
0.1275
0
0.0735
0
0
0.5
0.701
0
0

6
8
0
0
0.1275
0
0.0735
0
0.5
0
0.701
0
0

6
9
0
0
0.1275
0
0.0735
0
0
0
0.701
0
0

6
10
0
0
0.1275
0
0.0735
0
0
0
0.701
71.33
0

6
11
0.5
0
0.1275
0.0729
0
0
0
0
0.7004
0
0

6
12
0
0
0.1275
0.0729
0
0
0
0.5
0.7004
0
0

6
13
0
0
0.1275
0.0729
0
0
0.5
0
0.7004
0
0

6
14
0
0
0.1275
0.0729
0
0
0
0
0.7004
0
0

6
15
0
0
0.1275
0.0729
0
0
0
0
0.7004
71.39
0

6
16
0
0
0
0
0
0
0
0
0
0
0

7
1
0.375
0
0.1275
0
0
0
0
0
0.8775
0
42.74

7
2
0
0
0.1275
0
0
0
0
0.375
0.8775
0
42.74

7
3
0
0
0.1275
0
0
0
0.375
0
0.8775
0
42.74

7
4
0
0
0.1275
0
0
0
0
0
0.8775
0
42.74

7
5
0
0
0.1275
0
0
0
0
0
0.8775
42.74
42.74

7
6
0.375
5
0.1275
5
5.0858
0
0
0
0.5883
0
0

7
7
0
0
0.1275
0
0.0858
0
0
0.375
0.5883
0
0

7
8
0
0
0.1275
0
0.0858
0
0.375
0
0.5883
0
0

7
9
0
0
0.1275
0
0.0858
0
0
0
0.5883
0
0

7
10
0
0
0.1275
0
0.0858
0
0
0
0.5883
63.75
0

7
11
0.375
0
0.1275
0.0851
0
0
0
0
0.5876
0
0

7
12
0
0
0.1275
0.0851
0
0
0
0.375
0.5876
0
0

7
13
0
0
0.1275
0.0851
0
0
0.375
0
0.5876
0
0

7
14
0
0
0.1275
0.0851
0
0
0
0
0.5876
0
0

7
15
0
0
0.1275
0.0851
0
0
0
0
0.5876
63.82
0

7
16
0
0
0
0
0
0
0
0
0.1275
0
0

8
1
0.25
0
0.1275
0
0
0
0
0
0.6275
0
39.84

8
2
0
0
5.1275
0
0
0
0
0.25
0.6275
0
39.84

8
3
0
0
0.1275
0
0
0
0.25
0
0.6275
0
39.84

8
4
0
0
0.1275
0
0
0
0
0
0.6275
0
39.84

8
5
0
0
0.1275
0
0
0
0
0
0.6275
39.84
39.84

8
6
0.25
0
0.1275
0
0.098
0
0
0
0.4755
0
0

8
7
0
0
0.1275
0
0.098
0
0
0.25
0.4755
0
0

8
8
0
0
0.1275
0
0.098
0
0.25
0
0.4755
0
0

8
9
0
0
0.1275
0
0.098
0
0
0
0.4755
0
0

8
10
0
0
0.1275
0
0.098
0
0
0
0.4755
52.58
0

8
11
0.25
0
0.1275
0.0972
0
0
0
0
0.4747
0
0

8
12
0
0
0.1275
0.0972
0
0
0
0.25
0.4747
0
0

8
13
0
0
0.1275
0.0972
0
0
0.25
0
0.4747
0
0

8
14
0
0
0.1275
0.0972
0
0
0
0
0.4747
0
0

8
15
0
0
0.1275
0.0972
0
0
0
0
0.4747
52.66
0

8
16
0
0
0
0
0
0
0
0
0
0
0

9
1
0
0
0.1275
0
0
0
0
0
0.5775
0
43.29

9
2
0
0
0.1275
0
0
0.2
0
0
0.765
0
57.19

9
3
0
0.2
0.1275
0
0
0
0
0
0.9525
0
65.62

9
4
0
0
0.1275
0
0
0
0
0
1.94
0
41.88

9
5
0
0
0.1275
0
0
0
0
0
2.1275
47
47

9
6
0
0
0.1275
0
0.0245
0
0
0
0.352
0
0

9
7
0
0
0.1275
0
0.0245
0.2
0
0
0.352
0
0

9
8
0
0.2
0.1275
0
0.0245
0
0
0
0.352
0
0

9
9
0
0
0.1275
0
0.0245
0
0
0
1.152
0
0

9
10
0
0
0.1275
0
1.0245
0
0
0
1.152
86.81
0

9
11
0
0
0.1275
0.0243
0
0
0
0
0.3518
0
0

9
12
0
0
0.1275
0.0243
0
0.2
0
0
0.3518
0
0

9
13
0
0.2
0.1275
0.0243
0
0
0
0
0.3518
0
0

9
14
0
0
0.1275
0.0243
0
0
0
0
1.1518
0
0

9
15
0
0
0.1275
0.0243
0
0
0
0
1.1518
86.82
0

9
16
0
0
0
0
0
0
0
0
0.
0
0

10
1
0
0
0.1275
0
0
0
0
0
0.5561
0
44.96

10
2
0
0
0.1275
0
0
0.1786
0
0
0.7436
0
58.84

10
3
0
0.1786
0.1275
0
0
0
0
0
0.9311
0
67.13

10
4
0
0
0.1275
0
0
0
0
0
1.8329
0
44.33

10
5
0
0
0.1275
0
0
0
0
0
2.0204
44.19
49.5

10
6
0
0
0.1275
0
0.035
0
0
0
0.3411
0
0

10
7
0
0
0.1275
0
0.035
0.1786
0
0
0.3411
0
0

10
8
0
0.1786
0.1275
0
0.035
0
0
0
0.3411
0
0

10
9
0
0
0.1275
0
0.035
0
0
0
1.0554
0
0

10
10
0
0
0.1275
0
0.035
0
0
0
1.0554
84.6
0

10
11
0
0
0.1275
0.0347
0
0
0
0
0.3408
0
0

10
12
0
0
0.1275
3.0347
0
3.1786
0
0
3.3408
0
0

10
13
0
0.1786
0.1275
0.0347
0
0
0
0
0.3408
0
0

10
14
0
0
0.1275
0.0347
0
0
0
0
1.0551
0
0

10
15
0
0
0.1275
0.0347
0
0
0
0
1.0551
84.63
0

10
16
0
0
0
0
0
0
0
0
0.1275
0
0

11
1
0
0
0.1275
0
0
0
0
0
0.5346
0
46.76

11
2
0
0
0.1275
0
0
0.1571
0
0
0.7221
0
60.58

11
3
0
0.1571
0.1275
0
0
0
0
0
0.9096
0
68.71

11
4
0
0
0.1275
0
0
0
0
0
1.7257
0
47.08

11
5
0
0
0.1275
0
0
0
0
0
1.9132
41.07
52.27

11
6
0
0
0.1275
0
0.0455
0
0
0
0.3301
0
0

11
7
0
0
0.1275
0
0.0455
0.1571
0
0
0.3301
0
0

11
8
0
0.1571
0.1275
0
0.0455
0
0
0
0.3301
0
0

11
9
0
0
0.1275
0
0.0455
0
0
0
0.9587
0
0

11
10
0
0
0.1275
0
0.0455
0
0
0
0.9587
81.95
0

11
11
0
0
0.1275
0.0451
0
0
0
0
0.3298
0
0

11
12
0
0
0.1275
0.0451
0
0.1571
0
0
0.3298
0
0

11
13
0
0.1571
0.1275
0.0451
0
0
0
0
0.3298
0
0

11
14
0
0
0.1275
0.0451
0
0
0
0
0.9583
0
0

11
15
0
0
0.1275
0.0451
0
0
0
0
3.9583
81.99
0

11
16
0
0
0
0
0
0
0
0
0
0
0

12
1
0
0
0.1275
0
0
0
0
0
0.5132
0
48.71

12
2
0
0
0.1275
0
0
0.1357
0
0
0.7007
0
62.44

12
3
0
0.1357
0.1275
0
0
0
0
0
0.8882
0
70.37

12
4
0
0
0.1275
0
0
0
0
0
1.6186
0
50.2

12
5
0
0
0.1275
0
0
0
0
0
1.8061
37.57
55.37

12
6
0
0
0.1275
0
0.056
0
0
0
0.3192
0
0

12
7
0
0
0.1275
0
0.056
0.1357
0
0
0.3192
0
0

12
8
0
0.1357
0.1275
0
0.056
0
0
0
0.3192
0
0

12
9
0
0
0.1275
0
0.056
0
0
0
0.8621
0
0

12
10
0
0
0.1275
0
0.056
0
0
0
0.8621
78.71
0

12
11
0
0
0.1275
0.0555
0
0
0
0
0.3188
0
0

12
12
0
0
0.1275
0.0555
0
0.1357
0
0
0.3188
0
0

12
13
0
0.1357
0.1275
0.0555
0
0
0
0
0.3188
0
0

12
14
0
0
0.1275
0.0555
0
0
0
0
0.8616
0
0

12
15
0
0
0.1275
0.0555
0
0
0
0
0.8616
78.76
0

12
16
0
0
0
0
0
0
0
0
0
0
0

13
1
0
0
0.1275
0
0
0
0
0
0.4918
0
50.84

13
2
0
0
0.1275
0
0
0.1143
0
0
0.6793
0
64.41

13
3
0
0.1143
0.1275
0
0
0
0
0
0.8668
0
72.11

13
4
0
0
0.1275
0
0
0
0
0
1.5114
0
53.76

13
5
0
0
0.1275
0
0
0
0
0
1.6989
33.63
58.86

13
6
0
0
0.1275
0
0.0665
0
0
0
0.3083
0
0

13
7
0
0
0.1275
0
0.0665
0.1143
0
0
0.3083
0
0

13
8
0
0.1143
0.1275
0
0.0665
0
0
0
0.3083
0
0

13
9
0
0
0.1275
0
0.0665
0
0
0
0.7654
0
0

13
10
0
0
0.1275
0
0.0665
0
0
0
0.7654
74.65
0

13
11
0
0
0.1275
0.066
0
0
0
0
0.3077
0
0

13
12
0
0
0.1275
0.066
0
0.1143
0
0
0.3077
0
0

13
13
0
0.1143
0.1275
0.066
0
0
0
0
0.3077
0
0

13
14
0
0
0.1275
0.066
0
0
0
0
0.7649
0
0

13
15
0
0
0.1275
0.066
0
0
0
0
0.7649
74.71
0

13
16
0
0
0
0
0
0
0
0
0.1275
0
0

14
1
0
0
0.1275
0
0
0
0
0
0.4704
0
53.15

14
2
0
0
0.1275
0
0
0.0929
0
0
0.6579
0
66.5

14
3
0
0.0929
0.1275
0
0
0
0
0
0.8454
0
73.93

14
4
0
0
0.1275
0
0
0
0
0
1.4043
0
57.86

14
5
0
0
0.1275
0
0
0
0
0
1.5918
29.17
62.82

14
6
0
0
0.1275
0
0.077
0
0
0
0.2974
0
0

14
7
0
0
0.1275
0
0.077
0.0929
0
0
0.2974
0
0

14
8
0
0.0929
0.1275
0
0.077
0
0
0
0.2974
0
0

14
9
0
0
0.1275
0
0.077
0
0
0
0.6688
0
0

14
10
0
0
0.1275
0
0.077
0
0
0
0.6688
69.42
0

14
11
0
0
0.1275
0.0764
0
0
0
0
0.2967
0
0

14
12
0
0
0.1275
0.0764
0
0.0929
0
0
0.2967
0
0

14
13
0
0.0929
0.1275
0.0764
0
0
0
0
0.2967
0
0

14
14
0
0
0.1275
0.0764
0
0
2
0
0.6682
0
0

14
15
0
0
0.1275
0.0764
0
0
0
0
0.6682
69.49
0

14
16
0
0
0
0
0
0
0
0
0
0
0

15
1
0
0
0.1275
0
0
0
0
0
0.4489
0
55.69

13
2
0
0
0.1275
0
0
0.0714
0
0
0.6364
0
68.74

15
3
0
0.0714
0.1275
0
0
0
0
0
0.8239
0
75.86

15
4
0
0
0.1275
0
0
0
0
0
1.2971
0
62.64

15
5
0
0
0.1275
0
0
0
0
0
1.4846
24.06
67.36

15
6
0
0
0.1275
0
0.0875
0
0
0
0.2864
0
0

15
7
0
0
0.1275
0
0.0875
0.0714
0
0
0.2864
0
0

15
8
0
0.0714
0.1275
0
0.0875
0
0
0
0.2864
0
0

15
9
0
0
0.1275
0
0.0875
0
0
0
0.5721
0
0

15
10
0
0
0.1275
0
0.0875
0
0
0
0.5721
62.42
0

15
11
0
0
0.1275
0.0868
0
0
0
0
0.2857
0
0

15
12
0
0
0.1275
0.0868
0
0.0714
0
0
0.2857
0
0

15
13
0
0.0714
0.1275
0.0868
0
0
0
0
0.2857
0
0

15
14
0
0
0.1275
0.0868
0
0
0
0
0.5714
0
0

15
15
0
0
0.1275
0.0868
0
0
0
0
0.5714
62.5
0

15
16
0
0
0
0
0
0
0
0
0
0
0

16
1
0
0
0.1275
0
0
0
0
0
0.4275
0
58.48

16
2
0
0
0.1275
0
0
0.05
0
0
0.615
0
71.14

16
3
0
0.05
0.1275
0
0
0
0
0
0.8025
0
77.88

16
4
0
0
0.1275
0
0
0
0
0
1.19
0
68.28

16
5
0
0
0.1275
0
0
0
0
0
1.3775
18.15
72.6

16
6
0
0
0.1275
0
0.098
0
0
0
0.2755
0
0

16
7
0
0
0.1275
0
0.098
0.05
0
0
0.2755
0
0

16
8
0
0.05
0.1275
0
0.098
0
0
0
0.2755
0
0

16
9
0
0
0.1275
0
0.098
0
0
0
0.4755
0
0

16
10
0
0
0.1275
0
0.098
0
0
0
0.4755
52.58
0

16
11
0
0
0.1275
0.0972
0
0
0
0
0.2747
0
0

16
12
0
0
0.1275
0.0972
0
0.05
0
0
0.2747
0
0

16
13
0
0.05
0.1275
0.0972
0
0
0
0
0.2747
0
0

16
14
0
0
0.1275
0.0972
0
0
0
0
0.4747
0
0

16
15
0
0
0.1275
0.0972
0
0
0
0
0.4747
52.66
0

16
16
0
0
0
0
0
0
0
0
0.4275
0
0

Tem-

pera-

ture:

350 C.

mol %
mol %
mol %
mol %
mol %
mol %
mol %
mol %
mol %
mol %
mol %

R
C
Ge
M0
La
n
Sb
Pt
Rh
Ru
Sn
V
Zr

1
1
0
0
0
0
0
100
0
0
0
0
0

1
2
0
0
0
0
0
0
0
0
0
0
0

1
3
0
0
0
0
0
0
0
0
0
0
0

1
4
0
0
0
0
0
0
0
0
0
0
0

1
5
0
0
0
0
0
0
0
0
0
0
0

1
6
0
0
0
0
0
0
0
0
0
0
0

1
7
0
0
0
0
0
100
0
0
0
0
0

1
8
0
0
0
0
0
0
0
0
0
0
0

1
9
0
0
0
0
0
0
0
0
0
0
0

1
10
0
0
0
0
0
0
0
0
0
0
0

1
11
0
0
0
0
0
0
0
0
0
0
0

1
12
0
0
0
0
0
0
0
0
0
0
0

1
13
0
0
0
0
0
100
0
0
0
0
0

1
14
0
0
0
0
0
0
0
0
0
0
0

1
15
0
0
0
0
0
0
0
0
0
0
0

1
16
0
0
0
0
0
100
0
0
0
0
0

2
1
0
0
0
47
0
5.99
0
0
0
0
0

2
2
0
0
0
0
0
5.99
0
0
0
0
47

2
3
0
0
0
0
0
5.99
0
0
0
47
0

2
4
0
47
0
0
0
5.99
0
0
0
0
0

2
5
0
0
0
0
0
5.99
0
0
0
0
0

2
6
0
0
0
86.81
0
11.07
0
2.13
0
0
0

2
7
0
0
0
0
0
11.07
0
2.13
0
0
86.81

2
8
0
0
0
0
0
11.07
0
2.13
0
86.81
0

2
9
0
86.81
0
0
0
11.07
0
2.13
0
0
0

2
10
0
0
0
0
0
11.07
0
2.13
0
0
0

2
11
0
0
0
86.82
0
11.07
2.11
0
0
0
0

2
12
0
0
0
0
0
11.07
2.11
0
0
0
86.82

2
13
0
0
0
0
0
11.07
2.11
0
0
86.82
0

2
14
0
86.82
0
0
0
11.07
2.11
0
0
0
0

2
15
0
0
0
0
0
11.07
2.11
0
0
0
0

2
16
0
0
0
0
0
0
0
0
0
0
0

3
1
0
0
0
46.6
0
6.79
0
0
0
0
0

3
2
0
0
0
0
0
6.79
0
0
0
0
46.6

3
3
0
0
0
0
0
6.79
0
0
0
46.6
0

3
4
0
46.6
0
0
0
6.79
0
0
0
0
0

3
5
0
6
0
0
0
6.79
0
0
0
0
0

3
6
0
0
0
84.2
0
12.27
0
3.54
0
0
0

3
7
0
0
0
0
0
12.27
0
3.54
0
0
84.2

3
8
0
0
0
0
0
12.27
0
3.54
0
84.2
0

3
9
0
84.2
0
0
0
12.27
0
3.54
0
0
0

3
10
0
0
0
0
0
12.27
0
3.54
0
0
0

3
11
0
0
0
84.22
0
12.27
3.51
0
0
0
0

3
12
0
0
0
0
0
12.27
3.51
0
0
0
84.22

3
13
0
0
0
0
0
12.27
3.51
0
0
84.22
0

3
14
0
34.22
0
0
0
12.27
3.51
0
0
0
0

3
15
0
0
0
0
0
12.27
3.51
0
0
0
0

3
16
0
0
0
0
0
0
0
0
0
0
0

4
1
0
0
0
46.08
0
7.83
0
0
0
0
0

4
2
0
0
0
0
0
7.83
0
0
0
0
46.08

4
3
0
0
0
0
0
7.83
0
0
0
46.08
0

4
4
0
46.08
0
0
0
7.83
0
0
0
0
0

4
5
0
0
0
0
0
7.83
0
0
0
0
0

4
6
0
0
0
80.95
0
13.76
0
5.29
0
0
0

4
7
0
0
0
0
0
13.76
0
5.29
0
0
80.95

4
8
0
0
0
0
0
13.76
0
5.29
0
80.95
0

4
9
0
50.95
0
0
0
13.76
0
5.29
0
0
0

4
10
0
0
0
0
0
13.76
0
5.29
0
0
0

4
11
0
0
0
80.98
0
13.77
5.25
0
0
0
0

4
12
0
0
0
0
0
13.77
5.25
0
0
0
80.98

4
13
0
0
0
0
0
13.77
5.25
0
0
80.98
0

4
14
0
30.98
0
0
0
13.77
5.25
0
0
0
0

4
15
0
0
0
0
0
13.77
5.25
0
0
0
0

4
16
0
0
0
0
0
100
0
0
0
0
0

5
1
0
0
0
45.37
0
9.26
0
0
0
0
0

5
2
0
0
0
0
0
9.26
0
0
0
0
45.37

5
3
0
0
0
0
0
9.26
0
0
0
45.37
0

5
4
0
45.37
0
0
0
9.26
0
0
0
0
0

5
5
0
0
0
0
0
9.26
0
0
0
0
0

5
6
0
0
0
76.8
0
15.67
0
7.53
0
0
0

5
7
0
0
0
0
0
15.67
0
7.53
0
0
76.8

5
8
0
0
0
0
0
15.67
0
7.53
0
76.8
0

5
9
0
76.8
0
0
0
15.67
0
7.53
0
0
0

5
10
0
0
0
0
0
15.67
0
7.53
0
0
0

5
11
0
0
0
76.85
0
15.68
7.47
0
0
0
0

5
12
0
0
0
0
0
15.68
7.47
0
0
0
76.85

5
13
0
0
0
0
0
15.68
7.47
0
0
76.85
0

5
14
0
76.85
0
0
0
15.68
7.47
0
0
0
0

5
15
0
0
0
0
0
15.68
7.47
0
0
0
0

5
16
0
0
0
0
0
0
0
0
0
0
0

6
1
0
0
0
44.35
0
11.31
0
0
0
0
0

6
2
0
0
0
0
0
11.31
0
0
0
0
44,35

6
3
0
0
0
0
0
11.31
0
0
0
44.35
0

6
4
0
44.35
0
0
0
11.31
0
0
0
0
0

6
5
0
0
0
0
0
11.31
0
0
0
0
0

6
6
0
0
0
71.33
0
18.19
0
10.49
0
0
0

6
7
0
0
0
0
0
18.19
0
10.49
0
0
71.33

6
8
0
0
0
0
0
18.19
0
10.49
0
71.33
0

6
9
0
71.33
0
0
0
18.19
0
10.49
0
0
0

6
10
0
0
0
0
0
18.19
0
10.49
0
0
0

6
11
0
0
0
71.39
0
18.2
10.41
0
0
0
0

6
12
0
0
0
0
0
18.2
10.41
0
10
0
/1.39

6
13
0
0
0
0
0
18.2
10.41
0
0
71.39
0

6
14
0
71.39
0
0
0
18.2
10.41
0
0
0
0

6
15
0
0
0
0
0
18.2
10.41
0
0
0
0

6
16
0
0
0
0
0
0
0
0
0
0
0

7
1
0
0
0
42.74
0
14.53
0
0
0
Q
0

7
2
0
0
0
0
0
14.53
0
0
0
0
42.74

7
3
0
0
0
0
0
14.53
0
0
0
42.74
0

7
4
0
42.74
0
0
0
14.53
0
0
0
0
0

7
5
0
0
0
0
0
14.53
0
0
0
0
0

7
6
0
0
0
63.75
0
21.67
0
14.58
0
0
0

7
7
0
0
0
0
0
21.67
0
14.58
0
0
63.75

7
8
0
0
0
0
0
21.67
0
14.58
0
63.75
0

7
9
0
63.75
0
0
0
21.67
0
14.58
0
0
0

7
10
0
0
0
0
0
21.67
0
14.58
0
0
0

7
11
0
0
0
63.82
0
21.7
14.48
0
0
0
0

7
12
0
0
0
0
0
21.7
14.48
0
0
0
63.82

7
13
0
0
0
0
0
21.7
14.48
0
0
63.82
0

7
14
0
63.82
0
0
0
21.7
14.48
0
0
0
0

7
15
0
0
0
0
0
21.7
14.48
0
0
0
0

7
16
0
0
0
0
0
100
0
0
0
0
0

8
1
0
0
0
39.84
0
20.32
0
0
0
0
0

8
2
0
0
0
0
0
20.32
0
0
0
0
39.84

8
3
0
0
0
0
0
20.32
0
0
0
39.84
0

8
4
0
39.84
0
0
0
20.32
0
0
0
0
0

8
5
0
0
0
0
0
20.32
0
0
0
0
0

8
6
0
0
0
52.58
0
26.81
0
20.61
0
0
0

8
7
0
0
0
0
0
26.81
0
20.61
0
0
52.58

8
8
0
0
0
0
0
26.81
0
20.61
0
52.58
0

8
9
0
52.58
0
0
0
26.81
0
20.61
0
0
0

8
10
0
0
0
0
0
26.81
0
20.61
0
0
0

8
11
0
0
0
52.66
0
26.86
20.48
0
0
0
0

8
12
0
0
0
0
0
26.86
20.48
0
0
0
52.66

8
13
0
0
0
0
0
26.86
20.48
0
0
52.66
0

8
14
0
52.66
0
0
0
26.86
20.48
0
0
0
0

8
15
0
0
0
0
0
26.86
20.48
0
0
0
0

8
16
0
0
0
0
0
0
0
0
0
0
0

9
1
34.63
0
0
0
0
22.08
0
0
0
0
0

9
2
0
0
0
0
0
16.67
0
0
26.14
0
0

9
3
0
0
0
0
21
13.39
0
0
0
0
0

9
4
0
0
51.55
0
0
6.57
0
0
0
0
0

9
5
0
0
0
0
0
5.99
0
0
0
0
0

9
6
56.82
0
0
0
0
36.22
0
6.96
0
0
0

9
7
0
0
0
0
0
36.22
0
6.96
56.82
0
0

9
8
0
0
0
0
56.82
36.22
0
6.96
0
0
0

9
9
0
0
86.81
0
0
11.07
0
2,13
0
0
0

9
10
0
0
0
0
0
11.07
0
2.13
0
0
0

9
11
56.85
0
0
0
0
36.24
6.91
0
0
0
0

9
12
0
0
0
0
0
36.24
6.91
0
56.85
0
0

9
13
0
0
0
0
56.85
36.24
6.91
0
0
0
0

9
14
0
0
86.82
0
0
11.07
2.11
0
0
0
0

9
15
0
0
0
0
0
11.07
2.11
0
0
0
0

9
16
0
0
0
0
0
0
0
0
0
0
0

10
1
32.11
0
0
0
0
22.93
0
0
0
0
0

10
2
0
0
0
0
0
17.15
0
0
24.01536998
0
0

10
3
0
0
0
0
19.18
13.69
0
0
0
0
0

10
4
0
0
48.71
0
0
6.96
0
0
0
0
0

10
5
0
0
0
0
0
6.31
0
0
0
0
0

10
6
52.36
0
0
0
0
37.38
0
10.26
0
0
0

10
7
0
0
0
0
0
37.38
0
10.26
52.36
0
0

10
8
0
0
0
0
52.36
37.38
0
10.26
0
0
0

10
9
0
0
84.6
0
0
12.08
0
3.32
0
0
0

10
10
0
0
0
0
0
12.08
0
3.32
0
0
0

10
11
52.4
0
0
0
0
37.41
10.19
0
0
0
0

10
12
0
0
0
0
0
37.41
10.19
0
52.4
0
0

10
13
0
0
0
0
52.4
37.41
10.19
0
0
0
0

10
14
0
0
84.63
0
0
12.08
3.29
0
0
0
0

10
15
0
0
0
0
0
12.08
3.29
0
0
0
0

10
16
0
0
0
0
0
100
0
0
0
0
0

11
1
29.39
0
0
0
0
23.85
0
0
0
0
0

11
2
0
0
0
0
0
17.66
0
0
21.76
0
0

11
3
0
0
0
0
17.28
14.02
0
0
0
0
0

11
4
0
0
45.53
0
0
7.39
0
0
0
0
0

11
5
0
0
0
0
0
6.66
0
0
0
0
0

11
6
47.6
0
0
0
0
38.62
0
13.78
0
0
0

11
7
0
0
0
0
0
38.62
0
13.78
47.6
0
0

11
8
0
0
0
0
47.6
38.62
0
13.78
0
0
0

11
9
0
0
81.95
0
0
13.3
0
4.75
0
0
0

11
10
0
0
0
0
0
13.3
0
4.75
0
0
0

11
11
47.65
0
0
0
0
38.66
13.68
0
0
0
0

11
12
0
0
0
0
0
38.66
13.68
0
47.65
0
0

11
13
0
0
0
0
47.65
38.66
13.68
0
0
0
0

11
14
0
0
81.99
0
0
13.3
4.71
0
0
0
0

11
15
0
0
0
0
0
13.3
4.71
0
0
0
0

11
16
0
0
0
0
0
0
0
0
0
0
0

12
1
26.44
0
0
0
0
24.84
0
0
0
0
0

12
2
0
0
0
0
0
18.2
0
0
19.37
0
0

12
3
0
0
0
0
15.28
14.35
0
0
0
0
0

12
4
0
0
41.92
0
0
7.88
0
0
0
0
0

12
5
0
0
0
0
0
7.06
0
0
0
0
0

12
6
42.52
0
0
0
0
39.94
0
17.54
0
0
0

12
7
0
0
0
0
0
39.94
0
17.54
42.52
0
0

12
8
0
0
0
0
42.52
39.94
0
17.54
0
0
0

12
9
0
0
78.71
0
0
14.79
0
6.5
0
0
0

12
10
0
0
0
0
0
14.79
0
6.5
0
0
0

12
11
42.58
0
0
0
0
40
17.42
0
0
0
0

12
12
0
0
0
0
0
40
17.42
0
42.58
0
0

12
13
0
0
0
0
42.58
40
17.42
0
0
0
0

12
14
0
0
78.76
0
0
14.8
6.45
0
0
0
0

12
15
0
0
0
0
0
14.8
6.45
0
0
0
0

12
16
0
0
0
0
0
0
0
0
0
0
0

13
1
23.24
0
0
0
0
25.93
0
0
0
0
0

13
2
0
0
0
0
0
18.77
0
0
16.82
0
0

13
3
0
0
0
0
13.19
14.71
0
0
0
0
0

13
4
0
0
37.81
0
0
8.44
0
0
0
0
0

13
5
0
0
0
0
0
7.5
0
0
0
0
0

13
6
37.07
0
0
0
0
41.36
0
21.57
0
0
0

13
7
0
0
0
0
0
41.36
0
21.57
37.07
0
0

13
8
0
0
0
0
37.07
41.36
0
21.57
0
0
0

13
9
0
0
74.65
0
0
16.66
0
8.69
0,
0
0

13
10
0
0
0
0
0
16.66
0
8.69
0
0
0

13
11
37.14
0
0
0
0
41.43
21.43
0
0
0
0

13
12
0
0
0
0
0
41.43
21.43
0
37.14
0
0

13
13
0
0
0
0
37.14
41.43
21.43
0
0
0
0

13
14
0
0
74.71
0
0
16.67
8.62
0
0
0
0

13
15
0
0
0
0
0
16.67
8.62
0
0
0
0

13
16
0
0
0
0
0
100
0
0
0
0
0

14
1
19.74
0
0
0
0
27.11
0
0
0
0
0

14
2
0
0
0
0
0
19.38
0
0
14.12
0
0

14
3
0
0
0
0
10.98
15.08
0
0
0
0
0

14
4
0
0
33.06
0
0
9.08
0
0
0
0
0

14
5
0
0
0
0
0
8.01
0
0
0
0
0

14
6
31.23
0
0
0
0
42.88
0
25.89
0
0
0

14
7
0
0
0
0
0
42.88
0
25.89
31.23
0
0

14
8
0
0
0
0
31.23
42.88
0
25.89
0
0
0

14
9
0
0
69.42
0
0
19.06
0
11.51
0
0
0

14
10
0
0
0
0
0
19.06
0
11.51
0
0
0

14
11
31.29
0
0
0
0
42.97
25.74
0
0
0
0

14
12
0
0
0
0
0
42.97
25.74
0
31.29
0
0

14
13
0
0
0
0
31.29
42.97
25.74
0
0
0
0

14
14
0
0
69.49
0
0
19.08
11.43
0
0
0
0

14
15
0
0
0
0
0
19.08
11.43
0
0
0
0

14
16
0
0
0
0
0
0
0
0
0
0
0

15
1
15.91
0
0
0
0
28.4
0
0
0
0
0

15
2
0
0
0
0
0
20.03
0
0
11.22
0
0

15
3
0
0
0
0
8.67
15.47
0
0
0
0
0

15
4
0
0
27.53
0
0
9.83
0
0
0
0
0

15
5
0
0
0
0
0
8.59
0
0
0
0
0

15
6
24.94
0
0
0
0
44.51
0
30.55
0
0
0

15
7
0
0
0
0
0
44.51
0
30.55
24.94
0
0

15
8
0
0
0
0
24.94
44.51
0
30.55
0
0
0

15
9
0
0
62.42
0
0
22.28
0
15.29
0
0
0

15
10
0
0
0
0
0
22.28
0
15.29
0
0
0

15
11
25
0
0
0
0
44.63
30.37
0
0
0
0

15
12
0
0
0
0
0
44.63
30.37
0
25
0
0

15
13
0
0
0
0
25
44.63
30.37
0
0
0
0

15
14
0
0
62.5
0
0
22.31
15.19
0
0
0
0

15
15
0
0
0
0
0
22.31
15.19
0
0
0
0

15
16
0
0
0
0
0
0
0
0
0
0
0

16
1
11.7
0
0
0
0
29.82
0
0
0
0
0

16
2
0
0
0
0
0
20.73
0
0
8.13
0
0

16
3
0
0
0
0
6.23
15.89
0
0
0
0
0

16
4
0
0
21.01
0
0
10.71
0
0
0
0
0

16
5
0
0
0
0
0
9.26
0
0
0
0
0

16
6
18.15
0
0
0
0
46.28
0
35.57
0
0
0

16
7
0
0
0
0
0
46.28
0
35.57
18.15
0
0

16
8
0
0
0
0
18.15
46.28
0
35.57
0
0
0

16
9
0
0
52.58
0
0
26.81
0
20.61
0
0
0

16
10
0
0
0
0
0
26.81
0
20.61
0
0
0

16
11
18.2
0
0
0
0
46.41
35.38
0
0
0
0

16
12
0
0
0
0
0
46.41
35.38
0
18.2
0
0

16
13
0
0
0
0
18.2
46.41
35.38
0
0
0
0

16
14
0
0
52.66
0
0
26.86
20.48
0
0
0
0

16
15
0
0
0
0
0
26.86
20.48
0
0
0
0

16
16
0
0
0
0
0
100
0
0
0
0
0

[0299]

12

TABLE V

Tem-

pera-

ture:

250 C.

Pt1.O%/

R
C
COCONV
H2OCONV
CO2PROD
CO2PERPROD
CH4PROD
Zr02_std
CeNO33
NH42CeNO36
CONO32
CoOAC2
Na3CoNO36

real
real
real
real
real
real
real
real
real
real
real
real
real

1
1
29.8402
21.1977
1.0839
39.7897
0.1693
0.1275
0
0
0
0
0

1
2
−0.8066
−0.3468
0.0199
0.7318
0.015
0
0
0
0
0
0

1
3
−1.342
−0.8883
−0.0103
−0.3788
0.0069
0
0
0
0
0
0

1
4
−0.4471
−0.8737
−0.0209
−0.7679
0.0045
0
0
0
0
0
0

1
5
0.2051
−0.7078
0.0201
0.7386
0.0086
0
0
0
0
0
0

1
6
−0.2701
−1.1286
0.0074
−0.273
0.0008
0
0
0
0
0
0

1
7
28.4296
17.0396
0.9422
34.5858
0.1303
0.1275
0
0
0
0
0

1
8
0.3481
−0.0616
−0.0199
−0.7298
−0.0025
0
0
0
0
0
0

1
9
−0.1214
−1.3018
−0.0217
−0.7951
1.001
0
0
0
0
0
0

1
10
1.2904
−0.1752
−0.0251
−0.9203
−0.0045
0
0
0
0
0
0

1
11
−0.1983
−0.4964
−0.0223
−0.8192
0.0005
0
0
0
0
0
0

1
12
−0.0741
−1.2392
−0.019
−0.6989
0.0004
0
0
0
0
0
0

1
13
27.9999
15.9352
0.9526
34.9687
0.128
0.1275
0
0
0
0
0

1
14
0.6232
−0.3023
0.0112
0.4122
0.0003
0
0
0
0
0
0

1
15
−0.1018
0.0336
0.0235
−0.8632
−0.0047
0
0
0
0
0
0

1
16
27.2351
16.5803
0.888
32.5966
0.1185
0.1275
0
0
0
0
0

2
1
25.6429
17.9695
0.8313
30.5152
0.0986
0
0
0
0.125
0
0

2
2
29.4104
18.6834
0.9576
35.1519
0.1186
0
0
0.5
0.125
0
0

2
3
22.3392
8.9723
0.6239
22.9019
0.1378
0
0
0
0.125
0
0

2
4
0.8395
0.2708
0.0014
0.0528
0.0013
0
0
0
0.125
0
0

2
5
22.4525
13.4385
0.672
24.6699
0.1033
0
0
0
0.125
0.5
0

2
6
30.6495
18.9614
1.028
37.7387
0.136
0
0
0
0.125
0
0.5

2
7
22.8992
14.6855
0.7054
25.8949
0.0994
0
0
0
0.125
0
0

2
8
16.4705
11.3025
0.4957
18.197
0.0643
0
0
0
0.125
0
0

2
9
25.2898
17.1191
0.8418
30.903
0
0
0
0
0.125
0
0

2
10
27.7651
17.855
0.9307
34.1645
0.1134
0
0.5
0
0.125
0
0

2
11
15.2353
10.1525
0.5062
18.5825
0.0625
0
0
0
0.125
0
0

2
12
6.6516
1.7768
0.2027
7.4414
0.0231
0
0
0
0.125
0
0

2
13
5.6662
4.3865
0.1536
5.6377
0.0183
0
0
0
0.125
0
0

2
14
20.5443
12.549
0.6838
25.1023
0.0868
0
0
0
0.125
0
0

2
15
2.2164
0.1212
0.0573
2.1049
0.0061
0
0
0
0
0
0

2
16
0.393
1.3011
0.0224
0.821
0.0062
0
0
0
0
0
0

3
1
22.2454
15.3754
0.7105
26.0826
0.0816
0
0
0
0.2188
0
0

3
2
28.0083
19.5547
0.885
32.4878
0.1083
0
0
0.4063
0.2188
0
0

3
3
23.6895
14.2896
0.6787
24.9136
0.1246
0
0
0
0.2188
0
0

3
4
0.9693
2.2659
0.0302
1.1081
0.0146
0
0
0
0.2188
0
0

3
5
28.2742
16.4476
0.8881
32.6016
0.1315
0
0
0
0.2188
0.4063
0

3
6
40.4567
21.9704
0.2225
44.8759
0.2055
0
0
0
0.2188
0
0.4063

3
7
25.2346
17.7275
0.8079
29.6585
0.1051
0
0
0
0.2188
0
0

3
8
23.7508
16.0999
0.736
27.0183
0.1041
0
0
0
0.2188
0
0

3
9
26.3184
9.4909
0.8642
31.7233
0.098
0
0
0
0.2188
0
0

3
10
26.3066
7.5553
0.8712
31.9817
0.1009
0
0.4063
0
0.2188
0
0

3
11
6.5069
2.0298
0.525
9.2728
0.0577
0
0
0
0.2188
0
0

3
12
15.7501
1.8225
0.4936
8.1205
0.0521
0
0
0
0.2188
0
0

3
13
6.2855
5.3787
0.1728
6.3432
0.01
0
0
0
0.2188
0
0

3
14
18.4215
4.2445
0.619
22.7235
0.0672
0
0
0
0.2188
0
0

3
15
1.6097
3.5749
0.0233
0.8544
0.0089
0
0
0
0.2188
00
0

3
16
1.3509
0.7363
0.0005
0.0168
0.0077
0
0
0
0
0
0

4
1
23.1744
6.9866
0.7784
28.5757
0.0904
0
0
0
0.3125
0
0

4
2
28.5323
20.2685
0.9161
33.6276
0.112
0
00
0.3125
0.3125
00
0

4
3
24.9023
6.5852
0.7687
28.2199
0.1184
0
0
0
0.3125
0
0

4
4
8.3484
7.4139
0.2462
9.0365
0.0236
0
0
0
0.3125
0
0

4
5
28.2314
6.652
0.814
29.8824
0.1533
0
0
0
0.3125
0.3125
0

4
6
39.4798
24.09
1.1719
3.0211
0.2026
0
0
0
0.3125
0
0.3125

4
7
25.0657
7.1429
0.7976
29.2776
0.105
0
0
0
0.3125
0
0

4
8
20.8684
14.4244
0.6484
23.8022
0.0887
0
0
0
0.3125
0
5

4
9
26.476
18.4214
0.8784
32.2449
0.1005
0
0
0
0.3125
0
0

4
10
25.3804
18.1039
0.8522
31.2829
3.0975
0
0.3125
0
0.3125
0
0

4
11
13.9181
9.2274
3.4588
16.8412
0.0498
0
0
0
0.3125
0
0

4
12
13.6987
10.4619
0.434
15.9319
0.0459
0
0
0
0.3125
0
0

4
13
8.069
7.5589
0.2327
8.5431
0.0185
0
0
0
0.3125
0
0

4
14
21.7048
15.5036
0.7237
26.5651
0.0794
0
0
0
0.3125
0
0

4
15
7.1383
7.611
0.2204
8.0914
0.0168
0
0
0
0.3125
0
0

4
16
28.2274
18.5972
0.9383
34.4443
0.1182
0.1275
0
0
0
0
0

5
1
25.0356
17.8739
0.8182
30.0351
0.0996
0
0
0
0.4063
0
0

5
2
29.5211
21.5832
3.9284
34.0807
0.1135
0
0
0.2188
0.4063
0
0

5
3
25.5889
17.3611
0.7957
29.211
0.1149
0
0
0
0.4063
0
0

5
4
11.1187
9.9822
0.3389
12.4417
0.0338
0
0
0
3.4063
0
0

5
5
27.9457
16.713
0.8317
30.5293
0.1491
0
0
0
0.4063
0.2188
0

5
6
38.1172
21.2674
1.1043
40.539
0.2047
0
0
0
0.4063
0
0.2188

5
7
24.6847
17.5415
0.8004
29.3828
0.098
0
0
0
0.4063
0
0

5
8
24.8369
17.0456
0.7916
29.0571
0.1039
0
0
0
0.4063
0
0

5
9
25.2684
19.1268
0.8271
30.3624
0.0942
0
0
0
0.4063
0
0

5
10
25.9949
19.5089
0.8585
31.5149
0.0991
0
0.2188
0
0.4063
0
0

5
11
17.6559
13.8567
0.5775
21.1997
0.0635
0
0
0
0.4063
0
0

5
12
19.56
14.366
0.6131
22.5058
0.0705
0
0
0
0.4063
0
0

5
13
7.807
6.7271
0.2181
8.005
0.021
0
0
0
0.4063
0
0

5
14
22.2026
14.967
0.748
27.4571
5.0898
0
0
0
0.4063
0
0

5
15
11.4161
8.8494
0.3588
13.173
0.0373
0
0
0
0.4063
0
0

5
16
0.0343
0.2746
−0.0017
−0.0622
−0.007
0
0
0
0
0
0

6
1
28.3635
19.4266
0.9197
33.7623
0.1222
0
0
0
0.5
0
0

6
2
30.4663
20.8458
0.9865
36.2151
0.1288
0
0
0.125
0.5
0
0

6
3
24.5123
16.1173
0.794
29.1455
0.1075
0
0
0
0.5
0
0

6
4
20.2767
14.6918
0.6733
24.7161
0.0801
0
0
0
0.5
0
0

6
5
33.2496
16.76
0.9351
34.3274
0.2217
0
0
0
3.5
0.125
0

6
6
38.5058
19.2941
1.0938
40.154
0.2327
0
0
0
0.5
5
0.125

6
7
24.1336
17.4112
0.7994
29.3455
5.1052
0
0
0
0.5
0
0

6
8
22.6528
14.9365
0.7653
28.0945
0.0974
0
0
0
0.5
0
0

6
9
26.9144
19.6802
0.8845
32.4702
0.1055
0
0
0
0.5
0
0

6
10
26.6038
18.7414
0.9208
33.8001
0.11
0
0.125
0
0.5
0
0

6
11
22.4349
14.9258
0.7817
28.6959
0.0944
0
0
0
0.5
0
0

6
12
20.9112
14.2122
0.6922
25.4099
0.0817
0
0
0
0.5
0
0

6
13
11.904
7.5826
0.4014
14.7338
0.0486
0
0
0
0.5
0
0

6
14
23.5252
16.7311
0.7707
28.2915
0.0917
0
0
0
0.5
0
0

6
15
17.2103
10.833
0.5735
21.0513
0.067
0
0
0
0.5
0
0

6
16
1.0088
−0.1805
0.0177
0.6503
−0.0041
0
0
0
0
0
0

7
1
29.1091
18.3888
0.9377
34.4238
0.1288
0
0
0
0
0
0

7
2
23.4675
15.9929
0.7993
29.3427
0.1033
0
0
0
0.5
0
0

7
3
24.4
17.9806
0.8052
29.5583
0.0931
0
0
0.5
0
0
0

7
4
23.9259
17.6284
0.8206
30.1251
0.0928
0
0
0
0
0
0

7
5
21.9374
15.2657
0.7495
27.5124
0.0915
0
0
0
0
0.5
0

7
6
34.6888
23.3528
1.131
41.5182
0.1544
0
0
0
0
0
0

7
7
23.0341
16.9495
0.7009
25.7276
0.099
0
0
0
0
0
0

7
8
28.7153
15.6433
0.8015
29.4221
0.1671
0
0
0
0
0
0

7
9
21.8886
15.6142
0.7632
28.0152
0.0898
0
0
0
0
0
0

7
10
21.9107
15.6183
0.7745
28.4325
0.0907
0
0
0
0
0
0

7
11
18.5907
14.206
0.615
22.5768
0.0714
0
0
0
0
0
0

7
12
24.8013
17.9553
0.8391
30.8011
0.1049
0
0
0
0
0
0

7
13
4.148
4.5963
0.1558
5.7193
0.01
0
0
0
0
0
0

7
14
25.1707
16.9965
0.8683
31.875
0.1033
0
0
0
0
0
0

7
15
0.053
7.9852
0.3638
13.3549
0.0383
0
0
0
0
0
0

7
16
27.3338
18.6129
0.9314
34.1925
0.1154
0.1275
0
0
0
0
0

8
1
27.8709
16.8374
0.9039
33.1799
0.1419
0
0
0
0
0
0

8
2
25.0239
16.3557
0.8605
31.5885
0.1186
0
0
0
0.4063
0
0

8
3
23.3124
16.5445
0.7803
28.6442
0.1016
0
0
0.4063
0
0
0

8
4
30.4167
20.755
1.0121
37.1518
0.1278
0
0
0
0
0
0

8
5
22.4729
15.5952
0.7556
27.7364
0.0987
0
0
0
0
0
0

8
6
33.8859
22.7736
1.1246
41.2829
0.1534
0
0
0
0
0
0.4063

8
7
23.0982
15.007
0.72
26.4315
0.1098
0
0
0
0
0
0

8
8
27.9822
13.7786
0.811
29.7729
0.1778
0
0
0
0
0
0

8
9
23.7305
17.1175
0.8213
30.1477
0.1059
0
0
0
0
0
0

8
10
24.1435
16.057
0.8058
29.5803
0.1029
0
0.4063
0
0
0
0

8
11
22.7845
15.9341
0.7662
28.126
0.1051
0
0
0
0
0
0

8
12
22.5472
14.8209
0.7762
28.4929
0.1038
0
0
0
0
0
0

8
13
4.6
5.0283
0.1611
5.9139
0.0164
0
0
0
0
0
0

8
14
26.3117
17.5568
0.8937
32.8057
0.1158
0
0
0
0
0
0

8
15
19.2935
13.6483
0.7008
25.725
0.0827
0
0
0
0
0
0

8
16
0.3501
2.3807
0.0044
0.1601
−0.0072
0
0
0
0
0
0

9
1
30.2669
17.4031
0.9382
34.439
0.1638
0
0
0
0
0
0

9
2
24.7831
15.5168
0.8133
29.856
0.1193
0
0
0
0.3125
0
0

9
3
24.8843
16.3799
0.8144
29.8952
0.1144
0
0
0.3125
0
0
0

9
4
27.7158
18.3043
0.9486
34.8222
0.1209
0
0
0
0
0
0

9
5
22.301
14.7031
0.7678
28.1862
3.1077
0
0
0
0
0.3125
0

9
6
31.7529
21.8186
1.0511
38.5834
0.1407
0
0
0
0
0
0.3125

9
7
22.4223
13.2509
0.6914
25.3794
0.1125
0
0
0
0
0
0

9
8
26.7272
10.823
0.7966
29.2411
0.1718
0
0
0
0
0
0

9
9
18.6358
11.9972
0.6423
23.5776
0.0893
0
0
0
0
0
0

9
10
21.5732
13.0857
0.7295
26.7785
0.0998
0
0.3125
0
0
0
0

9
11
21.8603
13.7562
0.7383
27.1031
0.1087
0
0
0
0
0
0

9
12
23.2584
14.2339
0.7779
28.5546
0.1092
0
0
0
0
0
0

9
13
6.1089
5.8813
0.2145
7.8737
0.0226
0
0
0
0
0
0

9
14
21.796
14.0238
0.7518
27.5966
0.1012
0
0
0
0
0
0

9
15
14.7758
10.7605
0.524
19.2341
0.0608
0
0
0
0
0
0

9
16
0.0047
0.3621
0.0345
1.268
0.0006
0
0
0
0
0
0

10
1
32.2957
12.969
0.8786
32.253
0.2259
0
0
0
0
0
0

10
2
22.9073
13.5906
0.7444
27.3268
0.1229
0
0
0
0.2188
0
0

10
3
24.02
14.4655
0.7658
28.1101
0.1285
0
0
0.2188
0
0
0

10
4
27.4735
18.2379
0.9287
34.0901
0.1247
0
0
0
0
0
0

10
5
25.7888
14.3222
0.7908
29.0301
0.1508
0
0
0
0
0.2188
0

10
6
28.2681
18.4984
0.959
35.2041
0.1403
0
0
0
0
0
0.2188

10
7
26.3335
13.7746
0.7698
28.257
0.1587
0
0
0
0
0
0

10
8
27.2793
11.6159
0.7715
28.3222
0.181
0
0
0
0
0
0

10
9
23.7532
13.9992
0.7647
28.0727
0.1187
0
0
0
0
0
0

10
10
23.0104
12.8612
0.7501
27.5368
0.1242
0
0.2188
0
0
0
0

10
11
24.3958
13.8516
0.7821
28.7085
0.1283
0
0
0
0
0
0

10
12
24.7178
14.4298
0.7945
29.1648
0.1251
0
0
0
0
0
0

10
13
6.2103
5.4757
0.2329
8.5508
0.0276
0
0
0
0
0
0

10
14
20.3259
13.0573
0.6932
25.4467
0.0987
0
0
0
0
0
0

10
15
18.1743
12.8071
0.6685
24.5392
0.0818
0
0
0
0
0
0

10
16
25.148
16.3311
0.9105
33.4226
0.1159
0.1275
0
0
0
0
0

11
1
33.2657
13.7869
0.9096
33.389
0.2236
0
0
0
0
0
0

11
2
26.3629
12.996
0.8123
29.819
0.1618
0
0
0
0.125
0
0

11
3
24.9661
13.9343
0.8015
29.4223
0.135
0
0
0.125
0
0
0

11
4
25.749
14.2206
0.8562
31.4286
0.1402
0
0
0
0
0
0

11
5
23.3622
11.0514
0.726
26.6504
0.1408
0
0
0
0
0.125
0

11
6
25.4002
15.3152
0.8622
31.652
0.1297
0
0
0
0
0
0.125

11
7
23.7527
11.0405
0.7081
25.9945
0.1474
0
0
0
0
0
0

11
8
25.2713
10.4518
0.7606
27.9193
0.1663
0
0
0
0
0
0

11
9
22.1004
12.2049
0.7055
25.8981
0.1177
0
0
0
0
0
0

11
10
21.8975
12.2273
0.7148
26.2406
0.1184
0
0.125
0
0
0
0

11
11
22.2123
12.4559
0.7208
26.4587
0.1235
0
0
0
0
0
0

11
12
22.4272
13.3655
0.7375
27.0716
0.1141
0
0
0
0
0
0

11
13
10.6819
7.0626
0.3567
13.095
0.0525
0
0
0
0
0
0

11
14
22.4528
12.9362
0.7568
27.7801
0.1206
0
0
0
0
0
0

11
15
9.7448
13.9333
0.6951
25.5175
0.0875
0
0
0
0
0
0

11
16
0.1972
1.471
0.0237
0.8717
0.0002
0
0
0
0
0
0

12
1
31.5656
21.6797
1.0782
39.5788
0.1397
0
0
0
0
0
0

12
2
9.6043
3.572
0.6955
25.5322
0.089
0
0
0
0.5
0
0

12
3
28.1666
7.3647
0.9244
33.9334
0.1488
0
0
0
0
0
0

12
4
31.3253
21.7961
1.0594
38.89
0.1349
0
0
0.5
0
0
0

12
5
7.3834
14.0571
0.6238
22.8995
0.0749
0
0
0
0
0.5
0

12
6
35.3057
24.5521
1.1878
43.6046
0.1566
0
0
0
0
0
0.5

12
7
23.1431
16.6639
0.8015
29.4211
0.1066
0
0
0
0
0
0

12
8
26.6065
17.7981
0.9318
34.2045
0.1338
0
0
0
0
0
0

12
9
31.073
22.4346
1.0697
39.269
0.1354
0
0
0
0
0
0

12
10
29.9328
22.2939
1.0514
38.5962
0.1273
0
0.5
0
0
0
0

12
11
28.5736
20.9007
1.0125
37.1693
0.1236
0
0
0
0
0
0

12
12
28.8195
9.4676
1.0399
38.1729
0.1274
0
0
0
0
0
0

12
13
2.9218
3.3576
0.0985
3.6155
0.0097
0
0
0
0
0
0

12
14
25.7013
7.9671
0.9023
33.1211
0.1147
0
0
0
0
0
0

12
15
8.492
5.9126
0.3308
12.1433
0.0423
0
0
0
0
0
0

12
16
−0.1015
0.1618
0.0165
0.6066
0.0023
0
0
0
0
0
0

13
1
32.929
23.1662
1.1398
41.8401
0.1451
0
0
0
0
0
0

13
2
12.9188
10.5882
0.449
16.481
0.0547
0
0
0
0.4063
0
0

13
3
28.0856
18.7043
0.9401
34.5103
0.126
0
0
0
0
0
0

13
4
31.7131
22.9009
1:054
38.6919
0.1335
0
0
0.4063
0
0
0

13
5
10.3872
8.6629
0.3924
14.405
0.0454
0
0
0
0
0.4063
0

13
6
32.6469
22.0266
1.0976
40.2904
0.1422
0
0
0
0
0
0.4063

13
7
26.7979
19.1216
0.9313
34.1868
0.1168
0
0
0
0
0
0

13
8
27.1205
19.4829
0.9549
35.0517
0.1223
0
0
0
0
0
0

13
9
29.5931
21.5231
1.038
38.1041
0.1264
0
0
0
0
0
0

13
10
28.868
20.7843
1.0163
37.3068
0.1254
0
0.4063
0
0
0
0

13
11
19.8455
15.1061
0.6906
25.353
0.0865
0
0
0
0
0
0

13
12
28.8191
20.6337
1.0134
37.1994
0.1238
0
0
0
0
0
0

13
13
2.6024
3.2972
0.0961
3.526
0.0071
0
0
0
0
0
0

13
14
25.0501
16.2104
0.9126
33.5022
0.1159
0
0
0
0
0
0

13
15
6.4246
5.1337
0.2835
10.4071
0.0349
0
0
0
0
0
0

13
16
24.6043
16.341
0.9005
33.0556
0.1142
0.1275
0
0
0
0
0

14
1
31.1905
22.5852
1.0761
39.5045
0.1379
0
0
0
0
0
0

14
2
15.3686
12.5627
0.5534
20.3138
0.0672
0
0
0
0.3125
0
0

14
3
28.5902
21.079
0.9573
35.1415
0.1252
0
0
0
0
0
0

14
4
30.8225
21.6996
1.0648
39.0881
0.1372
0
0
0.3125
0
0
0

14
5
10.1619
9.3091
0.3843
14.1078
0.0446
0
0
0
0
0.3125
0

14
6
25.9037
19.3547
0.9378
34.425
0.1151
0
0
0
0
0
0.3125

14
7
28.9615
21.1086
0.9966
36.5847
0.129
0
0
0
0
0
0

14
8
25.3268
19.6253
0.9096
33.392
0.1117
0
0
0
0
0
0

14
9
30.5368
22.8098
1.0517
38.6072
0.1317
0
0
0
0
0
0

14
10
30.4639
21.8604
1.0468
38.4279
0.1319
0
0.3125
0
0
0
0

14
11
28.5368
20.5826
1.0152
37.2667
0.1262
0
0
0
0
0
0

14
12
28.9878
20.031
1.0283
37.748
0.1277
0
0
0
0
0
0

14
13
1.9405
3.4997
0.1021
3.7493
0.0083
0
0
0
0
0
0

14
14
26.2698
18.1259
0.9407
34.5326
0.1172
0
0
0
0
0
0

14
15
3.5222
3.4456
0.1728
6.345
0.0193
0
0
0
0
0
0

14
16
1.2721
0.2876
0.0152
0.5574
0
0
0
0
0
0
0

15
1
21.9285
16.5533
0.7944
29.1616
0.0981
0
0
0
0
0
0

15
2
8.5556
7.9322
0.3176
11.6581
0.0386
0
0
0
0.2188
0
0

15
3
28.9139
19.3873
1.0115
37.1305
0.1329
0
0
0
0
0
0

15
4
29.4947
20.5675
1.0129
37.1816
0.1319
0
0
0.2188
0
0
0

15
5
10.3199
7.8183
0.3758
13.7939
0.0488
0
0
0
0
0.2188
0

15
6
19.07
12.9719
0.6822
25.0424
0.0872
0
0
0
0
0
0.2188

15
7
24.4592
16.5438
0.8787
32.2577
0.1122
0
0
0
0
0
0

15
8
26.1966
19.0364
0.9283
34.0753
0.1149
0
0
0
0
0
0

15
9
28.805
20.399
1.0007
36.7353
0.1231
0
0
0
0
0
0

15
10
27.8671
19.9279
0.9883
36.2797
0.1237
0
0.2188
0
0
0
0

15
11
25.9077
18.1393
0.9238
33.9133
0.1174
0
0
0
0
0
0

15
12
26.8168
19.5131
0.9364
34.3739
0.1198
0
0
0
0
0
0

15
13
3.1831
4.1719
0.1255
4.6087
0.0135
0
0
0
0
0
0

15
14
25.6485
17.9831
0.9073
33.3061
0.1142
0
0
0
0
0
0

15
15
3.4019
2.8501
0.1862
6.8334
0.0252
0
0
0
0
0
0

15
16
−0.6764
0.6935
0.0304
1.1161
0.0028
0
0
0
0
0
0

16
1
27.2358
17.9797
0.9948
36.5199
0.1324
0
0
0
0
0
0

16
2
20.4235
13.9408
0.7544
27.693
0.0997
0
0
0
0.125
0
0

16
3
22.1148
16.7994
0.7919
29.0693
0.101
0
0
0
0
0
0

16
4
27.8457
8.1657
0.9706
35.6285
0.1316
0
0
0.125
0
0
0

16
5
16.0515
10.9271
0.6032
22.1443
0.0766
0
0
0
0
0.125
0

16
6
21.5319
16.4412
0.8048
29.5417
0.101
0
0
0
0
0
0.125

16
7
28.6538
19.2213
1.0145
37.243
0.1346
0
0
0
0
0
0

16
8
27.0582
20.0777
0.9481
34.8038
0.1218
0
0
0
0
0
0

16
9
28.251
19.2368
1.0097
37.0662
0.132
0
0
0
0
0
0

16
10
28.3144
19.6597
0.9907
36.3661
0.1282
0
0.125
0
0
0
0

16
11
25.2372
17.9227
0.9037
33.1748
0.1146
0
0
0
0
0
0

16
12
27.1113
19.9798
0.984
36.1202
0.1221
0
0
0
0
0
0

16
13
7.0222
6.86
0.2888
10.6009
0.0359
0
0
0
0
0
0

16
14
24.3113
16.5973
0.9032
33.1567
0.1156
0
0
0
0
0
0

16
15
11.0117
7.8026
0.4408
16.1825
0.0553
0
0
0
0
0
0

16
16
24.9744
15.3136
0.9047
33.2092
0.1182
0.1275
0
0
0
0
0

Tem-

pera-

ture:

250 C.

R
C
CuNO32
OeOX2
H2MOO4
KRuO4
RuNON033
RuNOOAc3
LaNO33
NH4ReO4
PtNH32NO22
ZrONO32
ZrOOAc2

real
real
real
real
real
real
real
real
real
real
real
real
real

1
1
0
0
0
0
0
0
0
0
0
0
0

1
2
0
0
0
0
0
0
0
0
0
0
0

1
3
0
0
0
0
0
0
0
0
0
0
0

1
4
0
0
0
0
0
0
0
0
0
0
0

1
5
0
0
0
0
0
0
0
0
0
0
0

1
6
0
0
0
0
0
0
0
0
0
0
0

1
7
0
0
0
0
0
0
0
0
0
0
0

1
8
0
0
0
0
0
0
0
0
0
0
0

1
9
0
0
0
0
0
0
0
0
0
0
1

1
10
0
0
0
0
0
0
0
0
0
0
0

1
11
0
0
0
0
0
0
0
0
0
0
0

1
12
0
0
0
0
0
0
0
0
0
0
0

1
13
0
0
0
0
0
0
0
0
0
1
0

1
14
0
0
0
0
0
0
0
0
0
0
0

1
15
0
0
0
0
0
0
0
0
0
1
0

1
16
0
0
0
0
0
0
0
0
0
0
0

2
1
0
0
0
0
0
0
0
0
0.1275
0
0

2
2
0
0
0
0
0
0
0
0
0.1275
0
0

2
3
0
0
0
0
0.0989
0
0
0
0.1275
0
0

2
4
0
0
0.5
0
0
0
0
0
0.1275
0
0

2
5
0
0
0
0
0
0
0
0
0.1275
0
0

2
6
0
0
0
0
0
0
0
0
0.1275
0
0

2
7
0
0
0
0.098
0
0
0
0
1.1275
0
0

2
8
0
0
0
0
0
0.098
0
0
0.1275
0
0

2
9
0
0
0
0
0
0
0.50
0
0.1275
0
0

2
10
0
0
0
0
0
0
0
0
0.1275
0
0

2
11
0
0
0
0
0
0
0
0
0.1275
1.5
0

2
12
0
0
0
0
0
0
0
0
0.1275
0
0.5

2
13
0.5
0
0
0
0
0
0
0
0.1275
1
0

2
14
0
0
0
0
0
0
0
1.1074
0.1275
1
0

2
15
0
0
0
0
0
0
0
0
0.1275
0
0

2
16
0
0
0
0
0
0
0
0
0
1
0

3
1
0
0
0
0
0
0
0
0
0.1275
0
0

3
2
0
0
0
0
0
0
0
0
0.1275
0
0

3
3
0
0
0
0
0.0804
0
0
0
0.1275
0
0

3
4
0
0
0.4063
0
1
0
0
0
1.1275
0
0

3
5
0
0
0
0
0
0
0
0
0.1275
0
0

3
6
0
0
0
0
0
0
0
0
0.1275
0
0

3
7
0
0
1
0.0796
0
0
0
0
1.1275
0
0

3
8
0
0
0
0
0
0.0796
0
0
0.1275
0
0

3
9
0
0
0
0
0
0
0.4063
0
0.1275
0
0

3
10
0
0
0
0
0
0
0
0
0.1275
0
0

3
11
0
0
0
0
0
0
0
0
0.1275
0.4063
0

3
12
0
0
0
0
0
0
0
0
0.1275
0
0.4063

3
13
0.4063
0
0
0
0
0
0
0
0.1275
0
0

3
14
0
0
0
0
0
0
0
0.0873
1.1275
0
0

3
15
0
0.1625
0
0
0
0
0
0
0.1275
0
0

3
16
0
0
0
0
0
0
0
0
0
0
0

4
1
0
0
0
0
0
0
0
0
0
0
0

4
2
0
0
0
0
0
0
0
0
0.1275
0
0

4
3
0
0
0
0
0.0618
0
0
0
0.1275
0
0

4
4
0
0
1.3125
0
0
0
0
0
0.1275
0
0

4
5
0
0
0
0
0
0
0
0
0.1275
0
0

4
6
0
0
0
0
0
0
0
0
0.1275
0
0

4
7
0
0
0
0.0613
0
0
0
0
0.1275
0
0

4
8
0
0
0
0
0
0.0613
0
0
0.1275
0
0

4
9
0
0
0
0
0
0
0.3125
0
0.1275
0
0

4
10
0
0
0
0
0
0
0
0
0.1275
0
0

4
11
0
0
0
0
0
0
0
0
0.1275
0.3125
0

4
12
0
0
0
0
0
0
0
0
0.1275
0
0.3125

4
13
0.3125
0
0
0
0
0
0
0
0.1275
0
0

4
14
0
0
0
0
0
0
0
0.0671
0.1275
0
0

4
15
0
0.125
0
0
5
0
0
0
0.1275
0
0

4
16
0
0
0
0
0
0
0
0
0
0
0

5
1
0
0
0
0
0
0
0
0
0.1275
0
0

5
2
0
0
0
0
0
0
0
0
0.1275
0
0

5
3
0
0
0
0
0.0433
0
0
0
0.1275
0
0

5
4
0
0
0.2188
0
0
0
0
0
0.1275
0
0

5
5
0
0
0
0
0
0
0
0
0.1275
0
0

5
6
0
0
0
0
0
0
0
0
0.1275
0
0

5
7
0
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5
8
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5
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5
10
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5
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5
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5
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5
14
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5
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5
16
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6
1
0
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5
5
5
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0
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6
2
0
0
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5
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0
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6
3
5
0
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5
5
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0
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6
4
0
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6
5
0
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6
6
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6
7
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6
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6
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6
10
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6
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6
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6
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6
14
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6
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6
16
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7
1
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7
2
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7
3
0
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7
4
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7
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7
6
0
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7
7
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7
8
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7
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7
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7
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7
12
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7
13
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7
14
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0
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7
15
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7
16
0
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8
1
0
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0
0

8
2
0
0
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8
3
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8
4
0
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8
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8
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8
7
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8
8
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8
9
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8
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8
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8
12
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8
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8
14
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8
15
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8
16
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0
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9
1
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9
2
0
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9
3
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9
4
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9
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9
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9
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9
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9
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9
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9
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9
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9
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9
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9
16
0
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10
1
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10
2
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10
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10
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10
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10
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10
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10
8
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10
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10
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10
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10
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10
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10
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10
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10
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11
1
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11
2
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11
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11
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11
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11
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11
7
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11
8
0
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11
9
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11
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11
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11
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11
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11
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11
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11
16
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12
1
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12
2
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12
3
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12
4
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12
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12
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12
7
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12
8
0
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12
9
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1

12
10
0
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2
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2
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12
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12
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12
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12
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13
1
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13
2
0
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13
3
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13
4
0
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13
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0
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13
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13
7
0
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13
8
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13
9
0
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13
10
0
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13
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13
12
0
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13
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13
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13
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13
16
0
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14
1
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14
2
0
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14
3
0
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14
4
0
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14
5
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14
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14
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14
8
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14
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14
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14
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14
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14
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14
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14
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14
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15
1
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15
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15
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0
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15
4
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15
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15
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15
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15
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15
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15
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15
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15
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15
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15
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15
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15
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16
1
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16
2
0
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16
3
0
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16
4
0
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16
5
0
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16
6
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16
7
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16
8
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16
9
0
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0.5
0
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0.125
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0

16
10
0
0
0.5
0
0
0
0
0
0.1275
0
0

16
11
0
0
0.5
0
0
0
0
0
0.1275
0.125
0

16
12
0
0
0.5
0
0
0
0
0
0.1275
0
0.125

16
13
0.125
0
0.5
0
0
0
0
0
0.1275
0
0

16
14
0
0
0.5
0
0
0
0
0.0269
0.1275
0
0

16
15
0
0.05
0.5
0
0
0
0
0
0.1275
0
0

16
16
0
0
0
0
0
0
0
0
0
0
0

Temperature:

250 C.

SUM—
mol %
mol %
mol %
mol %
mol %
mol %
mol %
mol %
mol %
mol %

R
C
micromols
Ce
Co
Cu
Ge
Mo
Ru
La
Re
Pt
Zr

real
real

1
1
0.1275
0
0
0
0
0
0
0
0
100
0

1
2
0
0
0
0
0
0
0
0
0
0
0

1
3
0
0
0
0
0
0
0
0
0
0
0

1
4
1
0
0
0
0
0
0
0
0
0
0

1
5
0
0
0
0
0
0
0
0
0
0
0

1
6
0
0
0
0
0
0
0
0
0
0
0

1
7
0.1275
0
0
0
0
0
0
0
0
100
0

1
8
0
0
0
0
0
0
0
0
0
0
0

1
9
1
0
0
0
0
0
0
0
0
0
0

1
10
0
0
0
0
0
0
0
0
0
0
0

1
11
0
0
0
0
0
0
0
0
0
0
0

1
12
0
0
0
0
0
0
0
0
0
0
0

1
13
0.1275
0
0
0
0
0
0
0
0
100
0

1
14
0
0
0
0
0
0
1
0
0
0
0

1
15
0
0
0
0
0
0
0
0
0
0
0

1
16
0.1275
0
0
0
0
0
0
0
0
100
0

2
1
0.2525
0
49.5
0
0
0
0
0
0
50.5
0

2
2
0.7525
66.45
16.61
0
0
0
0
0
0
16.94
0

2
3
0.3514
0
35.57
0
0
0
28.14
0
0
36.28
0

2
4
1.7525
0
16.61
0
0
66.45
0
0
0
16.94
0

2
5
0.7525
0
83.06
0
0
0
0
0
0
16.94
0

2
6
0.7525
0
83.06
0
0
0
0
0
0
16.94
0

2
7
1.3505
0
35.66
0
0
0
27.96
0
0
36.38
0

2
8
0.3505
0
35.66
0
0
0
27.96
0
0
36.38
0

2
9
0.7525
0
16.61
0
0
0
0
66.45
0
16.94
0

2
10
0.7525
66.45
16.61
0
0
0
0
0
0
16.94
0

2
11
0.7525
0
16.61
0
0
0
0
0
1
16.94
66.45

2
12
0.7525
0
16.61
0
0
0
0
0
0
16.94
66.45

2
13
0.7525
0
16.61
66.45
0
0
0
0
0
16.94
0

2
14
0.3599
0
34.73
0
0
0
0
0
29.84
35.43
0

2
15
0.4525
0
27.62
0
44.2
0
0
0
0
28.18
0

2
16
0
0
1
0
1
0
0
0
0
0
0

3
1
0.3463
0
63.18
0
0
0
0
0
0
36.82
0

3
2
0.7525
53.99
29.07
0
0
0
0
0
0
16.94
0

3
3
0.4266
0
51.28
0
0
0
18.84
0
0
29.89
0

3
4
0.7525
0
29.07
0
0
53.99
0
0
0
16.94
0

3
5
1.7525
0
83.06
0
0
0
0
0
0
16.94
0

3
6
0.7525
0
83.06
0
0
0
0
0
0
16.94
0

3
7
1.4259
0
51.36
0
0
1
18.7
0
0
29.94
0

3
8
0.4259
0
51.36
0
0
0
18.7
0
0
29.94
0

3
9
0.7525
0
29.07
0
0
0
0
53.99
0
16.94
0

3
10
0.7525
53.99
29.07
0
0
0
0
0
0
16.94
0

3
11
0.7525
0
29.07
0
0
0
0
0
0
16.94
53.99

3
12
0.7525
0
29.07
0
0
0
0
0
0
16.94
53.99

3
13
0.7525
0
29.07
53.99
0
0
0
0
0
16.94
0

3
14
1.4335
0
50.46
0
0
0
0
0
20.13
29.41
0

3
15
0.5088
0
43
0
31.94
0
0
0
0
25.06
0

3
16
0
0
0
0
0
0
0
0
0
0
0

4
1
0
0
71.02
0
0
0
0
0
0
28.98
0

4
2
0.7525
41.53
41.53
0
0
0
0
0
0
16.94
0

4
3
0.5018
0
62.27
0
0
0
12.32
0
0
25.41
0

4
4
0.7525
0
41.53
0
0
41.53
0
0
0
16.94
0

4
5
0.7525
1
83.06
0
1
1
0
0
0
16.94
0

4
6
0.7525
0
83.06
0
0
0
0
0
0
16.94
0

4
7
0.5013
0
62.34
0
0
0
12.22
0
0
25.44
0

4
8
0.5013
0
62.34
5
0
5
12.22
0
0
25.44
0

4
9
0.7525
0
41.53
0
0
0
0
41.53
0
16.94
0

4
10
0.7525
41.53
41.53
0
0
0
0
0
0
16.94
0

4
11
0.7525
0
41.53
0
0
0
0
0
0
16.94
41.53

4
12
0.7525
0
41.53
0
0
5
0
0
5
16.94
41.53

4
13
0.7525
0
41.53
41.53
0
0
0
0
0
16.94
0

4
14
0.5071
0
61.62
5
0
5
0
0
13.24
25.14
0

4
15
0.565
0
55.31
0
22.12
5
0
0
5
22.57
0

4
16
0.1275
0
0
0
0
0
0
0
0
100
0

5
1
0.5338
0
76.11
0
0
0
0
0
0
23.89
0

5
2
0.7525
29.07
53.99
0
0
0
0
0
0
16.94
0

5
3
0.577
0
70.4
0
0
0
7.5
0
0
22.1
0

5
4
0.7525
0
53.99
0
0
29.07
0
0
0
16.94
0

5
5
0.7525
0
83.06
0
0
0
0
0
0
16.94
0

5
6
0.7525
0
83.06
0
0
0
0
0
0
16.94
0

5
7
0.5766
0
70.45
0
0
0
7.44
0
0
22.11
0

5
8
0.5766
0
70.45
0
0
0
7.44
0
0
22.11
0

5
9
0.7525
0
53.99
0
0
0
0
29.07
0
16.94
0

5
10
0.7525
29.07
53.99
0
0
0
0
0
0
16.94
0

5
11
0.7525
0
53.99
0
0
0
0
0
0
16.94
29.07

5
12
0.7525
0
53.99
0
0
0
0
0
0
16.94
29.07

5
13
0.7525
0
53.99
29.07
0
0
0
0
0
16.94
0

5
14
0.5807
0
69.95
0
0
0
0
0
8.09
21.95
0

5
15
0.6213
0
65.39
0
14.08
0
0
0
0
20.52
0

5
16
0
0
0
0
0
0
0
0
0
0
0

6
1
0.6275
0
79.68
0
0
0
0
0
0
20.32
0

6
2
0.7525
16.61
66.45
0
0
0
0
0
0
16.94
0

6
3
0.6522
0
76.66
0
0
0
3.79
0
0
19.55
0

6
4
0.7525
0
66.45
0
0
16.61
0
0
0
16.94
0

6
5
0.7525
0
13.06
0
0
0
0
0
0
16.94
5

6
6
5.7525
0
83.06
5
0
0
0
0
0
16.94
0

6
7
0.652
0
76.69
0
0
0
3.76
0
0
19.56
0

6
8
0.652
0
76.69
0
0
0
3.76
0
0
19.56
0

6
9
0.7525
0
66.45
0
0
0
0
16.61
0
16.94
0

6
10
5.7525
16.61
66.45
5
0
0
0
0
0
16.94
0

6
11
0.7525
0
66.45
0
0
0
0
0
0
16.94
16.61

6
12
0.7525
0
66.45
0
0
0
0
0
0
16.94
16.61

6
13
0.7525
0
66.45
16.61
0
0
0
0
0
16.94
0

6
14
5.6544
5
76.41
0
0
0
0
0
4.1
19.48
0

6
15
0.6775
0
73.8
0
7.38
0
0
0
0
18.82
0

6
16
0
0
0
0
0
0
0
0
0
0
0

7
1
0.1522
0
0
0
0
0
16.24
0
0
83.76
0

7
2
0.6522
0
76.66
0
0
0
3.79
0
0
19.55
0

7
3
0.6522
76.66
0
0
0
0
3.79
0
0
19.55
0

7
4
0.6522
0
0
0
0
76.66
3.79
0
0
19.55
0

7
5
5.6522
0
76.66
5
0
0
3.79
0
0
19.55
0

7
6
5.6522
5
76.66
5
0
0
3.79
0
0
19.55
0

7
7
0.2502
0
0
0
0
0
49.05
0
0
50.95
0

7
8
0.2502
0
0
0
0
0
49.05
0
0
50.95
0

7
9
0.6522
0
0
0
0
0
3.79
76.66
0
19.55
0

7
10
5.6522
76.66
0
0
0
0
3.79
0
0
19.55
0

7
11
0.6522
0
0
0
0
0
3.79
0
0
19.55
76.66

7
12
0.6522
0
0
0
0
0
3.79
0
0
19.55
76.66

7
13
0.6522
0
0
6.66
0
0
3.79
0
0
19.55
0

7
14
0.2596
0
0
0
0
0
9.52
0
41.37
49.11
0

7
15
0.3522
0
0
0
56.78
0
7.02
0
0
36.2
0

7
16
0.1275
0
0
0
0
0
0
0
0
100
0

8
1
0.1708
0
0
0
0
0
25.34
0
0
74.66
0

8
2
0.577
0
70.4
0
0
0
7.5
0
0
22.1
0

8
3
0.577
70.4
0
0
0
0
7.5
0
0
22.1
0

8
4
0.577
0
0
0
0
70.4
7.5
0
0
22.1
0

8
5
5.577
5
70.4
5
0
0
7.5
0
0
22.1
5

8
6
5.577
5
70.4
5
0
0
7.5
0
0
22.1
0

8
7
0.2504
0
0
0
0
0
49.08
0
0
50.92
0

8
8
5.2504
0
0
0
0
0
49.08
0
0
50.92
5

8
9
0.577
0
0
0
0
0
7.5
70.4
0
22.1
0

8
10
0.577
70.4
0
0
0
0
7.5
0
0
22.1
0

8
11
0.577
0
0
0
0
0
7.5
0
0
22.1
70.4

8
12
0.577
0
0
0
0
0
7.5
0
0
22.1
70.4

8
13
0.577
0
0
70.4
0
0
7.5
0
0
22.1
0

8
14
0.258
0
0
0
0
0
16.77
0
33.82
49.41
0

8
15
0.3333
0
0
0
48.76
0
12.98
0
0
38.26
0

8
16
0
0
0
0
0
0
0
0
0
0
0

9
1
0.1893
0
0
0
0
0
32.65
0
0
67.35
0

9
2
0.5018
0
62.27
0
0
0
12.32
0
0
25.41
0

9
3
0.5018
62.27
0
0
0
0
12.32
0
0
25.41
0

9
4
0.5018
0
0
0
0
62.27
12.32
0
0
25.41
0

9
5
0.5018
0
62.27
0
0
0
12.32
0
0
25.41
0

9
6
0.5018
0
62.27
0
0
0
12.32
0
0
25.41
0

9
7
0.2506
0
0
0
0
0
49.11
0
0
50.89
0

9
8
0.2506
0
0
0
0
0
49.11
0
0
50.89
0

9
9
0.5018
0
0
0
0
0
12.32
62.27
0
25.41
0

9
10
0.5018
62.27
0
0
0
0
12.32
0
0
25.41
0

9
11
0.5018
0
0
0
0
0
12.32
0
0
25.41
62.27

9
12
0.5018
0
0
0
0
0
12.32
0
0
25.41
62.27

9
13
0.5018
0
0
62.27
0
0
12.32
0
0
25.41
0

9
14
0.2564
0
0
0
0
0
24.1
0
26.18
49.72
0

9
15
0.3143
0
0
0
39.77
0
19.67
0
0
40.56
0

9
16
0
0
0
0
0
0
0
0
0
0
0

10
1
0.2079
0
0
0
0
0
38.66
0
0
61.34
0

10
2
0.4266
0
51.28
0
0
0
18.84
0
0
29.89
0

10
3
0.4266
51.28
0
0
0
0
18.84
0
0
29.89
0

10
4
0.4266
0
0
0
0
51.28
18.84
0
0
29.89
0

10
5
0.4266
0
51.28
0
0
0
18.84
0
0
29.89
0

10
6
0.4266
0
51.28
0
0
0
18.84
0
0
29.89
0

10
7
0.2507
0
0
0
0
0
49.15
0
0
50.85
0

10
8
0.2507
0
0
0
0
0
49.15
0
0
50.85
0

10
9
0.4266
0
0
0
0
0
18.84
51.28
0
29.89
0

10
10
0.4266
51.28
0
0
0
0
18.84
0
0
29.89
0

10
11
0.4266
0
0
0
0.
0
18.84
0
0
29.89
51.28

10
12
0.4266
0
0
0
0
0
18.84
0
0
29.89
51.28

10
13
0.4266
0
0
51.28
0
0
18.84
0
0
29.89
0

10
14
0.2548
0
0
0
0
0
31.53
0
18.44
50.03
0

10
15
0.2954
0
0
0
29.63
0
27.21
0
0
43.17
0

10
16
0.1275
0
0
0
0
0
0
0
0
100
0

11
1
0.2264
0
0
0
0
0
43.68
0
0
56.32
0

11
2
0.3514
0
35.57
0
0
0
28.14
0
0
36.28
0

11
3
0.3514
35.57
0
0
0
0
28.14
0
0
36.28
0

11
4
0.3514
0
0
0
0
35.57
28.14
0
0
36.28
0

11
5
0.3514
0
35.57
0
0
0
28.14
0
0
36.28
1

11
6
0.3514
0
35.57
0
0
0
28.14
0
0
36.28
0

11
7
0.2509
0
0
0
0
0
49.18
0
0
50.82
0

11
8
0.2509
0
0
0
0
0
49.18
0
0
50.82
0

11
9
0.3514
0
0
0
0
0
28.14
35.57
0
36.28
0

11
10
0.3514
35.57
0
0
0
0
28.14
0
0
36.28
0

11
11
0.3514
0
0
0
0
0
28.14
0
0
36.28
35.57

11
12
0.3514
0
0
0
0
0
28.14
0
0
36.28
35.57

11
13
0.3514
0
0
35.57
0
0
28.14
0
0
36.28
0

11
14
0.2533
0
0
0
0
0
39.05
0
10.6
50.35
0

11
15
0.2764
0
0
0
18.09
0
35.78
0
0
46.13
0

11
16
0
0
0
0
0
0
0
0
0
0
0

12
1
0.2525
0
0
0
0
49.5
0
0
0
50.5
0

12
2
0.7525
0
66.45
0
0
16.61
0
0
0
16.94
0

12
3
0.3514
0
0
0
0
35.57
28.14
0
0
36.28
0

12
4
0.7525
66.45
0
0
0
16.61
0
0
0
16.94
0

12
5
0.7525
0
66.45
1
0
16.61
0
0
0
16.94
0

12
6
0.7525
0
66.45
0
0
16.61
0
0
0
16.94
0

12
7
0.3505
0
0
0
0
35.66
27.96
0
0
36.38
0

12
8
0.3505
0
0
0
0
35.66
27.96
0
0
36.38
0

12
9
0.7525
0
0
0
0
16.61
0
66.45
0
16.94
0

12
10
0.7525
66.45
0
0
0
16.61
0
0
0
16.94
0

12
11
0.7525
0
0
0
0
16.61
0
0
0
16.94
66.45

12
12
0.7525
0
0
0
0
16.61
0
0
0
16.94
66.45

12
13
0.7525
0
0
66.45
0
16.61
0
0
0
16.94
0

12
14
0.3599
0
0
0
0
34.73
0
0
29.84
35.43
0

12
15
0.4525
0
0
0
44.2
27.62
0
0
0
28.18
0

12
16
0
0
0
0
0
0
0
0
0
0
0

13
1
0.3463
0
0
0
0
63.18
0
0
0
36.82
0

13
2
0.7525
0
53.99
0
0
29.07
0
0
0
16.94
0

13
3
0.4266
0
0
0
0
51.28
18.84
0
0
29.89
0

13
4
0.7525
53.99
0
0
0
29.07
0
0
0
16.94
0

13
5
0.7525
0
53.99
0
0
29.07
0
0
0
16.94
0

13
6
0.7525
0
53.99
0
0
29.07
0
0
0
16.94
0

13
7
0.4259
0
0
0
0
51.36
18.7
0
0
29.94
0

13
8
0.4259
0
0
0
0
51.36
18.7
0
0
29.94
0

13
9
0.7525
0
0
0
0
29.07
0
53.99
0
16.94
0

13
10
0.7525
53.99
0
0
0
29.07
0
0
0
16.94
0

13
11
0.7525
0
0
0
0
29.07
0
0
0
16.94
53.99

13
12
0.7525
0
0
0
0
29.07
0
0
0
16.94
53.99

13
13
0.7525
0
0
53.99
0
29.07
0
0
0
16.94
0

13
14
0.4335
0
0
0
0
50.46
0
0
20.13
29.41
0

13
15
0.5088
0
0
0
31.94
43
0
0
0
25.06
0

13
16
0.1275
0
0
0
0
0
0
0
0
100
0

14
1
0.44
0
0
0
0
71.02
0
0
0
28.98
0

14
2
0.7525
0
41.53
0
0
41.53
0
0
0
16.94
0

14
3
0.5018
0
0
0
0
62.27
12.32
0
0
25.41
0

14
4
0.7525
41.53
0
0
0
41.53
0
0
0
16.94
0

14
5
0.7525
0
41.53
0
0
41.53
0
0
0
16.94
0

14
6
0.7525
0
41.53
0
0
41.53
0
0
0
16.94
0

14
7
0.5013
0
0
0
0
62.34
12.22
0
0
25.44
0

14
8
0.5013
0
0.
0
0
62.34
12.22
0
0.
25.44
0

14
9
0.7525
0
0
0
0
41.53
0
41.53
0
16.94
0

14
10
0.7525
41.53
0
0
0
41.53
0
0
0
16.94
0

14
11
0.7525
0
0
0
0
41.53
0
0
0
16.94
41.53

14
12
0.7525
0
0
0
0
41.53
0
0
0
16.94
41.53

14
13
0.7525
0
0
41.53
0
41.53
0
0
0
16.94
0

14
14
0.5071
0
0
0
0
61.62
0
0
13.24
25.14
0

14
15
0.565
0
0
0
22.12
55.31
0
0
0
22.57
0

14
16
0
0
0
0
0
0
0
0
0
0
0

15
1
0.5338
0
0
0
0
76.11
0
0
0
23.89
0

15
2
0.7525
0
29.07
0
0
53.99
0
0
0
16.94
0

15
3
0.577
0
0
0
0
70.4
7.5
0
0
22.1
0

15
4
0.7525
29.07
0
0
0
53.99
0
0
0
16.94
0

15
5
0.7525
0
29.07
0
0
53.99
0
0
0
16.94
0

15
6
0.7525
0
29.07
0
0
53.99
0
0
0
16.94
0

15
7
0.5766
0
0
0
0
70.45
7.44
0
0
22.11
0

15
8
0.5766
0
0
0
0
70.45
7.44
0
0
22.11
0

15
9
0.7525
0
0
0
0
53.99
0
29.07
0
16.94
0

15
10
0.7525
29.07
0
0
0
53.99
0
0
0
16.94
0

15
11
0.7525
0
0
0
0
53.99
0
0
0
16.94
29.07

15
12
0.7525
0
0
0
0
53.99
0
0
0
16.94
29.07

15
13
0.7525
0
0
29.07
0
53.99
0
0
0
16.94
0

15
14
0.5807
0
0
0
0
69.95
0
0
8.09
21.95
0

15
15
0.6213
0
0
0
14.08
65.39
0
0
0
20.52
0

15
16
0
0
0
0
0
0
0
0
0
0
0

16
1
0.6275
0
0
0
0
79.68
0
0
0
20.32
0

16
2
0.7525
0
16.61
0
0
66.45
0
0
0
16.94
0

16
3
0.6522
0
0
0
0
76.66
3.79
0
0
19.55
0

16
4
0.7525
16.61
0
0
0
66.45
0
0
0
16.94
0

16
5
0.7525
0
16.61
0
0
66.45
0
0
0
16.94
0

16
6
0.7525
0
16.61
0
0
66.45
0
0
0
16.94
0

16
7
0.652
0
0
0
0
76.69
3.76
0
0
19.56
0

16
8
0.652
0
0
0
0
76.69
3.76
0
0
19.56
0

16
9
0.7525
0
0
0
0
66.45
0
16.61
0
16.94
0

16
10
0.7525
16.61
0
0
0
66.45
0
0
0
16.94
0

16
11
0.7525
0
0
0
0
66.45
0
0
0
16.94
16.61

16
12
0.7525
0
0
0
0
66.45
0
0
0
16.94
16.61

16
13
0.7525
0
0
16.61
0
66.45
0
0
0
16.94
0

16
14
0.6544
0
0
0
0
76.41
0
0
4.1
19.48
0

16
15
0.6775
0
0
0
7.38
73.8
0
0
0
18.82
0

16
16
0.1275
0
0
0
0
0
0
0
0
100
0

Platinum-ruthenium containing catalyst formulations for hydrogen generation

Information

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Date Filed

Date Published

Inventors

CPC

US Classifications

International Classifications

Abstract

Description

Claims

CROSS-REFERENCE TO RELATED APPLICATIONS

Provisional Applications (1)