Information
-
Patent Grant
-
6443809
-
Patent Number
6,443,809
-
Date Filed
Tuesday, November 16, 199925 years ago
-
Date Issued
Tuesday, September 3, 200222 years ago
-
Inventors
-
Original Assignees
-
Examiners
Agents
- Wagner, Murabito & Hao LLP
-
CPC
-
US Classifications
Field of Search
US
- 451 6
- 451 41
- 451 57
- 451 550
- 451 548
- 451 527
- 451 530
-
International Classifications
-
Abstract
In one embodiment, a semiconductor substrate (38) is uniformly polished using a polishing pad (16) that has a first polishing region (26), a second polishing region (28), and a third polishing region (30). The semiconductor substrate (38) is aligned to the polishing pad (16), such that the center of the semiconductor substrate (38) overlies the second polishing region (28), and the edge of the semiconductor substrate overlies the first polishing region (26) and the third polishing region (30). During polishing, the semiconductor substrate (38) is not radially oscillated over the surface of the polishing pad, and as a result a more uniform polishing rate is achieved across the semiconductor substrate (38). This allows the semiconductor substrate (38) to be uniformly polished from center to edge, and increases die yield because die located on the semiconductor substrate (38) are not over polished.
Description
FIELD OF INVENTION
The present invention relates to integrated circuit fabrication, and more specifically to a polishing apparatus and to a method for polishing a layer of material in an integrated circuit.
BACKGROUND OF THE INVENTION
Polishing processes, and more specifically chemical-mechanical polishing processes, have been used in the semiconductor industry to prepare both single crystal substrates and silicon on insulator substrates. In addition, chemical-mechanical polishing processes have also been used to planarize various conductive and insulating layers subsequently deposited on these substrates, during the integrated circuit fabrication process. For example, chemical-mechanical polishing has been used to planarize interlevel dielectric layers that lie in between two different levels of metal interconnect. Planarizing the interlevel dielectric layer, prior to the formation of the next level of interconnect, is highly desirable because it allows the next level of interconnect to be subsequently patterned and etched without the formation of conductive metal stringers, which can electrically short adjacent metal lines, and without the formation of thinned or notched metal lines, which can adversely effect device reliability. Similarly, chemical-mechanical polishing has been used to planarize conductive materials, such as tungsten, copper, and aluminum, to form planar contact plugs, via plugs, and interconnects. In addition, chemical-mechanical polishing has also been used to form trench isolation. In this process, trenches are formed and then subsequently filled with a deposited dielectric layer, such as silicon dioxide. The dielectric layer is then polished back to form dielectric filled isolation trenches, which are nearly planar with the adjacent active regions. In addition to being planar, the resulting trench isolation is also desirable because it allows the space separating adjacent active regions to be minimized, and thus allows integrated circuits with high device packing densities to be fabricated.
Unfortunately, the conductive and dielectric layers formed on the semiconductor substrate during the integrated circuit fabrication process cannot be uniformly polished with current polishing equipment and polishing processes. One of the main reasons for this is that the polishing rate near the edge of the semiconductor substrate is often much higher than that near the center of the semiconductor substrate. Thus, portions of the conductive and dielectric layers which lie near the edge of the semiconductor substrate are often over-polished, and therefore semiconductor die located near the edge of the semiconductor substrate are lost. These die represent a substantial revenue loss to integrated circuit manufactures.
Accordingly, a need exists for a polishing process and polishing apparatus that can polish semiconductor substrates with improved center to edge uniformity.
BRIEF DESCRIPTION OF THE DRAWINGS
The present invention may be more fully understood by a description of certain preferred embodiments in conjunction with the attached drawings in which:
FIG. 1
illustrates, in cross-section, a polishing apparatus in accordance with one embodiment of the present invention;
FIG. 2
illustrates, in plan view, a portion of the polishing apparatus of
FIG. 1
;
FIGS. 3-6
illustrate, in cross-section, process steps in accordance with one embodiment of the present invention;
FIGS. 7-9
illustrate, in cross-section, process steps in accordance with another embodiment of the present invention; and
FIGS. 10-13
illustrate, in cross-section, process steps in accordance with another embodiment of the present invention.
DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT
The present invention provides a polishing apparatus, and a method for uniformly polishing a layer of material in an integrated circuit therewith. The polishing apparatus comprises a carrier, an alignment detector, and a polishing pad having a first polishing region, a second polishing region, and a third polishing region. The alignment detector accurately aligns the carrier to the second polishing region, and a semiconductor substrates mounted to the carrier is aligned to the polishing pad such that its center overlies the second polishing region, and its edge overlies the first polishing region and the third polishing region by a predetermined amount. During polishing, the semiconductor substrate is not radially oscillated over the surface of the polishing pad, and as a result a more uniform polishing rate is achieved across the semiconductor substrate. This allows the semiconductor substrate to be uniformly polished from center to edge, and increases die yield because die on the semiconductor substrate are not over polished.
FIG. 1
illustrates, in cross section, a polishing apparatus
10
in accordance with one embodiment of the present invention. In this particular embodiment, polishing apparatus
10
comprises a polishing platen
12
, an under pad
14
, a polishing pad
16
, a carrier
18
, a slurry dispenser
20
, and an alignment detector
22
.
In one embodiment, polishing platen
12
comprises an alignment knob
24
, which is used to align polishing pad
16
and under pad
14
to polishing platen
12
, as shown in FIG.
1
. It should be appreciated that alignment knob
24
may be formed having either a tapered sidewall, or a vertical sidewall as shown in FIG.
1
.
In one embodiment, under pad
14
is a felt based under pad comprising polyurethane. For example, under pad
14
may be a SUBA IV under pad which is commercially available from RODEL, Inc.
Polishing pad
16
comprises a first polishing region
26
, a second polishing region
28
, and a third polishing region
30
. In one embodiment, polishing pad
16
is made of a material comprising polyurethane. It should be appreciated that polishing pad
16
and under pad
14
may be formed as separate pads, or as a composite pad.
In one embodiment, first polishing region
26
comprises holes
32
, second polishing region
28
comprises holes
34
, and third polishing region
30
comprises holes
36
, as shown in FIG.
1
. Note as used in this specification, holes are distinguished from pores because holes are formed in the polishing pad after the polishing pad material has been formed. In one embodiment, the holes are used to locally adjust the polishing rate of the semiconductor substrate by supplying differing amounts of slurry to different areas of the semiconductor substrate so that the semiconductor substrate can be more uniformly polished from center to edge.
In one embodiment, a more uniform polishing rate is achieved by providing less slurry to the edge of the semiconductor substrate, than to its center. It should be appreciated that this can be accomplished in a variety of ways. For example, holes
34
may have a greater depth than holes
32
and holes
36
so that more slurry is provided to the center of the semiconductor substrate, as shown in FIG.
1
. Alternatively, holes
34
may have a greater width than holes
32
and holes
36
, or holes
34
may have a greater width and depth than holes
32
and holes
36
so that more slurry is provided to the center of the semiconductor substrate. Alternatively, second polishing region
28
may have a greater hole density than first polishing region
26
and third polishing region
30
, or polishing pad
16
may be formed such that only second polishing region
28
contains holes so that more slurry is provided to the center of the semiconductor substrate.
In an alternative embodiment, a more uniform polishing rate is achieved by providing more slurry to the edge of the semiconductor substrate, than to its center. It should be appreciated that this can also be accomplished in a variety of ways. For example, in this case holes
32
and holes
36
may have a greater depth than holes
34
so that more slurry is provided to the edge of the semiconductor substrate. Alternatively, holes
32
and holes
36
may have a greater width than holes
34
, or holes
32
and holes
36
may have a greater width and depth than holes
34
so that more slurry is provided to the edge of the semiconductor substrate. Alternatively, first polishing region
26
and third polishing region
30
may have a greater hole density than second polishing region
28
, or polishing pad
16
may be formed such that only first polishing region
26
and third polishing region
30
contain holes so that more slurry is provided to the edge of the semiconductor substrate.
In an alternative embodiment, first polishing region
26
comprises a first pore density, second polishing region
28
comprises a second pore density, and third polishing region
30
comprises a third pore density. Note as used in this specification, pores are distinguished from holes because pores are formed in the polishing pad when the polishing pad material is formed. In this embodiment, first polishing region
26
, second polishing region
28
, and third polishing region
30
locally adjust the polishing rate of the semiconductor substrate by supplying differing amounts of slurry to different areas of the semiconductor substrate so that the semiconductor substrate can be more uniformly polished from center to edge.
In one embodiment, a more uniform polishing rate is achieved across the semiconductor substrate by providing less slurry to the edge of the semiconductor substrate, than to its center. In this particular embodiment, second polishing region
28
has a pore density which is greater than the pore density of first polishing region
26
and third polishing region
30
so that more slurry is provided to the center of the semiconductor substrate.
In an alternative embodiment, a more uniform polishing rate is achieved across the semiconductor substrate by providing more slurry to the edge of the semiconductor substrate, than to its center. In this particular embodiment, second polishing region
28
has a pore density which is less than the pore density of first polishing region
26
and third polishing region
30
so that more slurry is provided to the edge of the semiconductor substrate.
Carrier
18
is aligned to second polishing region
28
, in a manner similar to that used to align a photomask to a semiconductor substrate, using alignment detector
22
. More specifically, alignment detector
22
is used to align semiconductor substrate
38
to polishing pad
16
so that semiconductor substrate
38
can be uniformly polished by first polishing region
26
, second polishing region
28
and third polishing region
30
. In one embodiment, alignment detector
22
comprises a video camera which is used to accurately align carrier
18
to second polishing region
28
. In an alternative embodiment, alignment detector
22
comprises a laser which is used to accurately align carrier
18
to second polishing region
28
.
The operation of polishing apparatus
10
will now be briefly discussed. A semiconductor substrate
38
is mounted to carrier
18
of polishing apparatus
10
, as shown in FIG.
1
. Alignment detector
22
then aligns carrier
18
and semiconductor substrate
38
to second polishing region
28
. In one embodiment, alignment detector
22
optically locates the outside perimeter of second polishing region
28
, and then aligns carrier
18
with respect to the outside perimeter of second polishing region
28
. As a result, the center of semiconductor substrate
38
overlies second polishing region
28
, and the perimeter
40
of semiconductor substrate
38
overlies first polishing region
26
and third polishing region
30
by a predetermined amount, as shown in FIG.
1
. Semiconductor substrate
38
is then rotated by carrier
18
, and polishing pad
16
is rotated by polishing platen
12
. In addition, slurry
42
is dispensed onto polishing pad
16
by slurry dispenser
20
during polishing. Note, carrier
18
and polishing platen
12
may be rotated in either the same direction, or in opposite directions. It is important to note, that semiconductor substrate
38
is not radially oscillated over the surface of polishing pad
16
during polishing. Therefore, during polishing the center of semiconductor substrate
38
continually overlies second polishing region
28
, and remains at a fixed distance from the perimeter
44
of polishing pad
16
, while the edge of semiconductor substrate
38
is polished by first polishing region
26
and third polishing region
30
. As a result, a more uniform polishing rate is achieved across semiconductor substrate
38
, and it is polished with improved center to edge uniformity. It should be appreciated that this improved polishing uniformity increases die yield because die on the semiconductor substrate
38
are not over polished.
FIG. 2
illustrates, in plan view, a portion of polishing apparatus
10
of FIG.
1
. Note that, carrier
18
and polishing pad
16
are illustrated as being rotated in opposite directions.
FIG.
3
through
FIG. 6
illustrate, in cross-section, process steps in accordance with one embodiment of the present invention wherein a trench isolation structure is formed in an integrated circuit. Shown in
FIG. 3
, is a portion
46
of an integrated circuit structure comprising a semiconductor substrate
48
, a buffer layer
50
, a polish-stop layer
52
, and a photoresist mask
54
. Semiconductor substrate
48
is preferably a monocrystalline silicon substrate. Alternatively, semiconductor substrate
48
may be a silicon-on-insulator (SOI) substrate, a silicon-on-sapphire (SOS) substrate, a silicon-germanium substrate, or the like. Buffer layer
50
typically has a thickness ranging from 5 to 100 nanometers, and is preferably a thermal oxide layer which is formed by thermally oxidizing a portion of semiconductor substrate
48
. Alternatively, buffer layer
50
may be a chemical vapor deposited silicon oxide layer. Following the formation of buffer layer
50
, polish-stop layer
52
is formed over buffer layer
50
. Polish-stop layer
52
typically has a thickness ranging from 50 to 200 nanometers, and is preferably a silicon nitride layer. Alternatively, polish-stop layer
52
may be a boronitride layer, a silicon oxynitride layer, or the like. Photoresist mask
54
, which overlies a portion of polish-stop layer
52
, is formed using standard photolithographic patterning processes.
In
FIG. 4
, photoresist mask
54
is used to etch polish-stop layer
52
and underlying buffer layer
50
, and form a patterned trench mask
56
that overlies a portion of semiconductor substrate
48
. In addition, semiconductor substrate
48
is etched in regions not covered by patterned trench mask
56
to form trenches
58
in semiconductor substrate
48
. Note, patterned trench mask
56
comprises a remaining portion of polish-stop layer
52
and a remaining portion of buffer layer
50
. Trenches
58
and patterned trench mask
56
are formed using conventional etching techniques. It should be appreciated that photoresist mask
54
may be removed using conventional photoresist stripping techniques, either before or after trenches
58
have been formed.
In
FIG. 5
, a dielectric layer
60
is then formed overlying semiconductor substrate
48
. Dielectric layer
60
overlies pattern trench mask
56
and lies within trenches
58
, such that it substantially fills trenches
58
. In a preferred embodiment, dielectric layer
60
is a layer of plasma oxide, which is formed using a commercially available high density plasma deposition system. In an alternative embodiment, dielectric layer
60
is a layer of chemically vapor deposited oxide, which is deposited using ozone and tetraethylorthosilicate (TEOS) as source gases. It should be appreciated that dielectric layer
60
may also be formed using other dielectric materials, such as germanium oxide, boro-phosphate-silicate-glass (BPSG), phosphate-silicate-glass (PSG), boro-silicate-glass (BSG), spin-on-glass, or the like, and that it may be may be formed using other techniques such, electron cyclotron resonance deposition, spin-on deposition, or the like. In addition, it should also be appreciated that a trench liner (not shown) may also be formed within trenches
58
prior to forming dielectric layer
60
. For example, a portion of semiconductor substrate
48
may be thermally oxidized to form a thermal oxide layer along the sidewall and bottom of trenches
58
prior to depositing dielectric layer
60
. Note, the trench liner will have a thickness which is insufficient to fill trenches
58
.
In
FIG. 6
, dielectric layer
60
is then uniformly polished, as described above in
FIG. 1
, to expose a portion of patterned trench mask
56
, and leave a remaining portion
62
of dielectric layer
60
in trenches
58
. In one embodiment, dielectric layer
60
is a layer of silicon oxide and is polished using a slurry comprising potassium hydroxide, deionized water, and a silica abrasive. Alternatively, dielectric layer
60
may be polished using a slurry comprising potassium hydroxide, deionized water, and an alumina abrasive, or using a slurry comprising ammonium hydroxide, deionized water, and a silica abrasive. After being exposed, patterned trench mask
56
is then subsequently removed to define active regions and trench isolation regions within semiconductor substrate
48
(not shown). Patterned trench mask
56
is removed using a wet or a dry etch process, or a combination thereof.
FIG.
7
through
FIG. 9
illustrate, in cross-section, process steps in accordance with one embodiment of the present invention, wherein a planarized interlevel dielectric layer is formed in an integrated circuit. Shown in
FIG. 7
, is a portion
64
of an integrated circuit structure comprising a semiconductor substrate
66
, a dielectric layer
68
, and patterned conductive members
70
. Semiconductor substrate
66
is similar to semiconductor substrate
48
of FIG.
3
. In one embodiment, dielectric layer
68
is a gate dielectric layer. In an alternative embodiment, dielectric layer
68
is an interlevel dielectric layer. If dielectric layer
68
is a gate dielectric layer, then semiconductor substrate
66
is preferably thermally oxidized to form dielectric layer
68
. It should be appreciated, however, that other dielectric materials, such as silicon oxynitride or chemical vapor deposited silicon dioxide may also be used to form a gate dielectric layer. If dielectric layer
68
is an interlevel dielectric layer then dielectric layer
68
may be a layer of silicon dioxide, a layer of silicon nitride, a layer of boro-phosphate-silicate-glass (BPSG), a layer of phosphate-silicate-glass (PSG), a layer of spin-on-glass (SOG), a silicon oxynitride layer, a polyimide layer, or the like. In addition, a combination of the foregoing dielectric materials may also be used to form dielectric layer
68
. After dielectric layer
68
is formed, a conductive layer of material is formed overlying dielectric layer
68
, and then patterned using conventional lithographic processes to form conductive members
70
. Conductive members
70
may be formed using a doped polysilicon layer, a metal layer, a metal silicide layer, a metal nitride layer, or a combination thereof.
In
FIG. 8
, a dielectric layer
72
is then formed overlying semiconductor substrate
66
. Dielectric layer
72
may be a layer of silicon dioxide, a layer of silicon nitride, a layer of boro-phosphate-silicate-glass (BPSG), a layer of phosphate-silicate-glass (PSG), a layer of spin-on-glass (SOG), a silicon oxynitride layer, a polyimide layer, or the like. In addition, a combination of the foregoing dielectric materials may also be used to form dielectric layer
72
.
In
FIG. 9
, dielectric layer
72
is then uniformly polished, as described above in
FIG. 1
, to form a planarized interlevel dielectric layer
74
. In one embodiment, dielectric layer
72
is a layer of silicon oxide and is polished using a slurry comprising potassium hydroxide, deionized water, and a silica abrasive. Alternatively, dielectric layer
72
may be polished using a slurry comprising potassium hydroxide, deionized water, and an alumina abrasive, or using a slurry comprising ammonium hydroxide, deionized water, and a silica abrasive.
FIG.
10
through
FIG. 13
illustrate, in cross-section, process steps in accordance with one embodiment of the present invention, wherein a conductive member is formed in an integrated circuit. Shown in
FIG. 10
, is a portion
76
of an integrated circuit structure comprising a semiconductor substrate
78
, a conductive region
80
, a dielectric layer
82
, and a photoresist mask
84
. Semiconductor substrate
78
is similar to semiconductor substrate
48
of FIG.
3
. In one embodiment conductive region
80
is a doped region which has been formed within a portion of semiconductor substrate
78
. For example, it may be a doped source region, a doped drain region, a doped well contact, or the like. In an alternative embodiment, conductive region
80
is a patterned conductive member, such as a gate electrode, a contact plug, a via plug, an interconnect, or the like. Note, that if conductive region
80
is a gate electrode, a via plug, or an interconnect, then at least one dielectric layer (not shown) will lie between conductive region
80
and semiconductor substrate
78
. Dielectric layer
82
may be a layer of silicon dioxide, a layer of silicon nitride, a layer of boro-phosphate-silicate-glass (BPSG), a layer of phosphate-silicate-glass (PSG), a layer of spin-on-glass (SOG), a silicon oxynitride layer, a polyimide layer, or the like. In addition, a combination of the foregoing dielectric materials may also be used to form dielectric layer
82
. Photoresist mask
84
, which overlies a portion of dielectric layer
82
, is formed using standard photolithographic patterning processes.
In
FIG. 11
, dielectric layer
82
is etched using photoresist mask
84
to form an opening
86
within dielectric layer
82
. A portion of conductive region
80
is exposed within opening
86
, as shown in FIG.
11
. It should be appreciated that dielectric layer
82
may be etched using a wet or a dry etch process, or a combination thereof.
In
FIG. 12
, a barrier layer
88
is then formed overlying semiconductor substrate
78
. Barrier layer
88
overlies dielectric layer
82
and lies within opening
86
, such that it does not fill opening
86
. A conductive layer
90
is then formed overlying barrier layer
88
, such that opening
86
is substantially filled by conductive layer
90
. Barrier layer
88
may be a metal nitride layer, such as titanium nitride, tantalum nitride, tungsten nitride, tantalum-silicon nitride, or the like, or a metal layer, such a layer of titanium, a layer of tantalum, a layer of tungsten, or the like, or a combination thereof. For example, barrier layer
88
may be a composite layer of titanium and titanium nitride. Conductive layer
90
may be an aluminum layer, an aluminum alloy layer, a copper layer, a tungsten layer, a doped polysilicon layer, or the like.
In
FIG. 13
, conductive layer
90
and barrier layer
88
are then uniformly polished, as described above in
FIG. 1
, to form a conductive member
92
, such as a contact plug, a via plug, or an inlaid interconnect. In one embodiment, wherein conductive layer
90
is a tungsten layer and barrier layer
88
comprises titanium nitride, a slurry comprising ferric nitrate, deionized water, and a silica abrasive is used to form conductive member
92
. Alternatively, tungsten and titanium nitride may also be polished using a slurry comprising hydrogen peroxide, deionized water, and a silica abrasive. In an alternative embodiment, wherein conductive layer
90
is a copper layer and barrier layer
88
comprises tantalum, a slurry comprising hydrogen peroxide, deionized water, and a silica abrasive is used to form conductive member
92
.
Thus it is apparent that there has been provided, in accordance with the present invention, a polishing apparatus and a method for polishing a layer of material in an integrated circuit that fully meets the need and advantages set forth previously. Although the invention has been described and illustrated with reference to specific embodiments thereof, it is not intended that the invention be limited to these illustrative embodiments. Those skilled in the art will recognize that modifications and variations can be made without departing from the spirit of the invention. Therefore, it is intended that this invention encompass all such variations and modifications as fall within the scope of the appended claims.
Claims
- 1. A method for forming an integrated circuit comprising the steps of:providing a substrate having a center and a perimeter; forming a layer of material overlaying the substrate; providing a polishing pad having a perimeter and a center, the polishing pad comprising a first polishing region, a second polishing region, and a third polishing region, wherein the second polishing region lies between the first polishing region and the third polishing region; aligning the substrate to the polishing pad such that the center of the substrate overlies the second polishing region, a first portion of the perimeter of the substrate overlies the first polishing region, and a second portion of the perimeter of the substrate overlies the third polishing region; and polishing the layer of material overlying the substrate using the polishing pad, wherein the center of the substrate remains at a fixed distance from the perimeter of the polishing pad while the layer of material is polished, wherein the first polishing region comprises a first plurality of holes having a first hole depth and a first hole width, the second polishing region comprises a second plurality of holes having a second hole depth and a second hole width, and the third polishing region comprises a third plurality of holes having a third hole depth and a third hole width, wherein the second hole depth to be greater than the first depth and the third hole depth.
- 2. The method of claim 1, wherein the first polishing region has a first hole density, the second polishing region has a second hole density, and the third polishing region has a third hole density.
- 3. The method of claim 2, wherein the second hole density is greater than the first hole density and the third hole density.
- 4. The method of claim 1, wherein the second hole width to be greater than the first hole width and the third hole width.
- 5. A method for forming an integrated circuit comprising the steps of:providing a substrate having a center and a perimeter; forming a layer of material overlying the substrate; providing a polishing pad having a perimeter and a center, the polishing pad comprising a first polishing region, a second polishing region, and a third polishing region, wherein the second polishing region lies between the first polishing region and the third polishing region; using an alignment detector to align the substrate to the second polishing region of the polishing pad, such that the center of the substrate overlies the second polishing region, a first portion of the perimeter of the substrate overlies the first polishing region, and a second portion of the perimeter of the substrate overlies the third polishing region; and polishing the layer of material overlying the substrate using the polishing pad, wherein the center of the substrate remains at a fixed distance from the perimeter of the polishing pad while the layer of the material is polished, wherein the first polishing region comprises a first plurality of holes having a first hole depth and a first hole width, the second polishing region comprises a second plurality of holes having a second hole depth and a second hole width, and the third polishing region comprises a third plurality of holes having a third hole depth and a third hole width, wherein the second hole width is different than the first hole width and the third hole width.
- 6. The method of claim 5, wherein the second hole width is less than the first hole width and the third hole width.
- 7. The method of claim 5, wherein the second hole width is greater than the first hole width and the third hole width.
- 8. The method of claim 5, wherein the layer of material comprises a dielectric layer.
- 9. The method of claim 5, wherein the second hole depth is different than the first hole depth and the third hole depth.
- 10. The method of claim 9, wherein the second hole depth is greater than the first hole depth and the third hole depth.
- 11. The method of claim 9, wherein the second hole depth is less than the first hole depth and the third hole depth.
- 12. The method of claim 5, wherein the layer of material comprises a conductive layer.
- 13. The method of claim 5, wherein the alignment detector comprises a laser.
- 14. The method of claim 5, wherein the alignment detector comprises a video camera.
- 15. The method of claim 5, wherein the layer of material is further characterized as a copper layer.
- 16. The method of claim 15, further comprising the step of dispensing a slurry comprising hydrogen peroxide on the polishing pad.
- 17. The method of claim 5, wherein the layer of material is further characterized as a tungsten layer.
- 18. The method of claim 17, further comprising the step of dispensing a slurry comprising ferric nitrate on the polishing pad.
- 19. The method of claim 5, wherein the layer of material is further characterized as a silicon oxide layer.
- 20. The method of claim 19, further comprising the step of dispensing a slurry comprising potassium hydroxide on the polishing pad.
US Referenced Citations (7)