Polishing apparatus and method for forming an integrated circuit

Information

  • Patent Grant
  • 6443809
  • Patent Number
    6,443,809
  • Date Filed
    Tuesday, November 16, 1999
    25 years ago
  • Date Issued
    Tuesday, September 3, 2002
    22 years ago
Abstract
In one embodiment, a semiconductor substrate (38) is uniformly polished using a polishing pad (16) that has a first polishing region (26), a second polishing region (28), and a third polishing region (30). The semiconductor substrate (38) is aligned to the polishing pad (16), such that the center of the semiconductor substrate (38) overlies the second polishing region (28), and the edge of the semiconductor substrate overlies the first polishing region (26) and the third polishing region (30). During polishing, the semiconductor substrate (38) is not radially oscillated over the surface of the polishing pad, and as a result a more uniform polishing rate is achieved across the semiconductor substrate (38). This allows the semiconductor substrate (38) to be uniformly polished from center to edge, and increases die yield because die located on the semiconductor substrate (38) are not over polished.
Description




FIELD OF INVENTION




The present invention relates to integrated circuit fabrication, and more specifically to a polishing apparatus and to a method for polishing a layer of material in an integrated circuit.




BACKGROUND OF THE INVENTION




Polishing processes, and more specifically chemical-mechanical polishing processes, have been used in the semiconductor industry to prepare both single crystal substrates and silicon on insulator substrates. In addition, chemical-mechanical polishing processes have also been used to planarize various conductive and insulating layers subsequently deposited on these substrates, during the integrated circuit fabrication process. For example, chemical-mechanical polishing has been used to planarize interlevel dielectric layers that lie in between two different levels of metal interconnect. Planarizing the interlevel dielectric layer, prior to the formation of the next level of interconnect, is highly desirable because it allows the next level of interconnect to be subsequently patterned and etched without the formation of conductive metal stringers, which can electrically short adjacent metal lines, and without the formation of thinned or notched metal lines, which can adversely effect device reliability. Similarly, chemical-mechanical polishing has been used to planarize conductive materials, such as tungsten, copper, and aluminum, to form planar contact plugs, via plugs, and interconnects. In addition, chemical-mechanical polishing has also been used to form trench isolation. In this process, trenches are formed and then subsequently filled with a deposited dielectric layer, such as silicon dioxide. The dielectric layer is then polished back to form dielectric filled isolation trenches, which are nearly planar with the adjacent active regions. In addition to being planar, the resulting trench isolation is also desirable because it allows the space separating adjacent active regions to be minimized, and thus allows integrated circuits with high device packing densities to be fabricated.




Unfortunately, the conductive and dielectric layers formed on the semiconductor substrate during the integrated circuit fabrication process cannot be uniformly polished with current polishing equipment and polishing processes. One of the main reasons for this is that the polishing rate near the edge of the semiconductor substrate is often much higher than that near the center of the semiconductor substrate. Thus, portions of the conductive and dielectric layers which lie near the edge of the semiconductor substrate are often over-polished, and therefore semiconductor die located near the edge of the semiconductor substrate are lost. These die represent a substantial revenue loss to integrated circuit manufactures.




Accordingly, a need exists for a polishing process and polishing apparatus that can polish semiconductor substrates with improved center to edge uniformity.











BRIEF DESCRIPTION OF THE DRAWINGS




The present invention may be more fully understood by a description of certain preferred embodiments in conjunction with the attached drawings in which:





FIG. 1

illustrates, in cross-section, a polishing apparatus in accordance with one embodiment of the present invention;





FIG. 2

illustrates, in plan view, a portion of the polishing apparatus of

FIG. 1

;





FIGS. 3-6

illustrate, in cross-section, process steps in accordance with one embodiment of the present invention;





FIGS. 7-9

illustrate, in cross-section, process steps in accordance with another embodiment of the present invention; and





FIGS. 10-13

illustrate, in cross-section, process steps in accordance with another embodiment of the present invention.











DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT




The present invention provides a polishing apparatus, and a method for uniformly polishing a layer of material in an integrated circuit therewith. The polishing apparatus comprises a carrier, an alignment detector, and a polishing pad having a first polishing region, a second polishing region, and a third polishing region. The alignment detector accurately aligns the carrier to the second polishing region, and a semiconductor substrates mounted to the carrier is aligned to the polishing pad such that its center overlies the second polishing region, and its edge overlies the first polishing region and the third polishing region by a predetermined amount. During polishing, the semiconductor substrate is not radially oscillated over the surface of the polishing pad, and as a result a more uniform polishing rate is achieved across the semiconductor substrate. This allows the semiconductor substrate to be uniformly polished from center to edge, and increases die yield because die on the semiconductor substrate are not over polished.





FIG. 1

illustrates, in cross section, a polishing apparatus


10


in accordance with one embodiment of the present invention. In this particular embodiment, polishing apparatus


10


comprises a polishing platen


12


, an under pad


14


, a polishing pad


16


, a carrier


18


, a slurry dispenser


20


, and an alignment detector


22


.




In one embodiment, polishing platen


12


comprises an alignment knob


24


, which is used to align polishing pad


16


and under pad


14


to polishing platen


12


, as shown in FIG.


1


. It should be appreciated that alignment knob


24


may be formed having either a tapered sidewall, or a vertical sidewall as shown in FIG.


1


.




In one embodiment, under pad


14


is a felt based under pad comprising polyurethane. For example, under pad


14


may be a SUBA IV under pad which is commercially available from RODEL, Inc.




Polishing pad


16


comprises a first polishing region


26


, a second polishing region


28


, and a third polishing region


30


. In one embodiment, polishing pad


16


is made of a material comprising polyurethane. It should be appreciated that polishing pad


16


and under pad


14


may be formed as separate pads, or as a composite pad.




In one embodiment, first polishing region


26


comprises holes


32


, second polishing region


28


comprises holes


34


, and third polishing region


30


comprises holes


36


, as shown in FIG.


1


. Note as used in this specification, holes are distinguished from pores because holes are formed in the polishing pad after the polishing pad material has been formed. In one embodiment, the holes are used to locally adjust the polishing rate of the semiconductor substrate by supplying differing amounts of slurry to different areas of the semiconductor substrate so that the semiconductor substrate can be more uniformly polished from center to edge.




In one embodiment, a more uniform polishing rate is achieved by providing less slurry to the edge of the semiconductor substrate, than to its center. It should be appreciated that this can be accomplished in a variety of ways. For example, holes


34


may have a greater depth than holes


32


and holes


36


so that more slurry is provided to the center of the semiconductor substrate, as shown in FIG.


1


. Alternatively, holes


34


may have a greater width than holes


32


and holes


36


, or holes


34


may have a greater width and depth than holes


32


and holes


36


so that more slurry is provided to the center of the semiconductor substrate. Alternatively, second polishing region


28


may have a greater hole density than first polishing region


26


and third polishing region


30


, or polishing pad


16


may be formed such that only second polishing region


28


contains holes so that more slurry is provided to the center of the semiconductor substrate.




In an alternative embodiment, a more uniform polishing rate is achieved by providing more slurry to the edge of the semiconductor substrate, than to its center. It should be appreciated that this can also be accomplished in a variety of ways. For example, in this case holes


32


and holes


36


may have a greater depth than holes


34


so that more slurry is provided to the edge of the semiconductor substrate. Alternatively, holes


32


and holes


36


may have a greater width than holes


34


, or holes


32


and holes


36


may have a greater width and depth than holes


34


so that more slurry is provided to the edge of the semiconductor substrate. Alternatively, first polishing region


26


and third polishing region


30


may have a greater hole density than second polishing region


28


, or polishing pad


16


may be formed such that only first polishing region


26


and third polishing region


30


contain holes so that more slurry is provided to the edge of the semiconductor substrate.




In an alternative embodiment, first polishing region


26


comprises a first pore density, second polishing region


28


comprises a second pore density, and third polishing region


30


comprises a third pore density. Note as used in this specification, pores are distinguished from holes because pores are formed in the polishing pad when the polishing pad material is formed. In this embodiment, first polishing region


26


, second polishing region


28


, and third polishing region


30


locally adjust the polishing rate of the semiconductor substrate by supplying differing amounts of slurry to different areas of the semiconductor substrate so that the semiconductor substrate can be more uniformly polished from center to edge.




In one embodiment, a more uniform polishing rate is achieved across the semiconductor substrate by providing less slurry to the edge of the semiconductor substrate, than to its center. In this particular embodiment, second polishing region


28


has a pore density which is greater than the pore density of first polishing region


26


and third polishing region


30


so that more slurry is provided to the center of the semiconductor substrate.




In an alternative embodiment, a more uniform polishing rate is achieved across the semiconductor substrate by providing more slurry to the edge of the semiconductor substrate, than to its center. In this particular embodiment, second polishing region


28


has a pore density which is less than the pore density of first polishing region


26


and third polishing region


30


so that more slurry is provided to the edge of the semiconductor substrate.




Carrier


18


is aligned to second polishing region


28


, in a manner similar to that used to align a photomask to a semiconductor substrate, using alignment detector


22


. More specifically, alignment detector


22


is used to align semiconductor substrate


38


to polishing pad


16


so that semiconductor substrate


38


can be uniformly polished by first polishing region


26


, second polishing region


28


and third polishing region


30


. In one embodiment, alignment detector


22


comprises a video camera which is used to accurately align carrier


18


to second polishing region


28


. In an alternative embodiment, alignment detector


22


comprises a laser which is used to accurately align carrier


18


to second polishing region


28


.




The operation of polishing apparatus


10


will now be briefly discussed. A semiconductor substrate


38


is mounted to carrier


18


of polishing apparatus


10


, as shown in FIG.


1


. Alignment detector


22


then aligns carrier


18


and semiconductor substrate


38


to second polishing region


28


. In one embodiment, alignment detector


22


optically locates the outside perimeter of second polishing region


28


, and then aligns carrier


18


with respect to the outside perimeter of second polishing region


28


. As a result, the center of semiconductor substrate


38


overlies second polishing region


28


, and the perimeter


40


of semiconductor substrate


38


overlies first polishing region


26


and third polishing region


30


by a predetermined amount, as shown in FIG.


1


. Semiconductor substrate


38


is then rotated by carrier


18


, and polishing pad


16


is rotated by polishing platen


12


. In addition, slurry


42


is dispensed onto polishing pad


16


by slurry dispenser


20


during polishing. Note, carrier


18


and polishing platen


12


may be rotated in either the same direction, or in opposite directions. It is important to note, that semiconductor substrate


38


is not radially oscillated over the surface of polishing pad


16


during polishing. Therefore, during polishing the center of semiconductor substrate


38


continually overlies second polishing region


28


, and remains at a fixed distance from the perimeter


44


of polishing pad


16


, while the edge of semiconductor substrate


38


is polished by first polishing region


26


and third polishing region


30


. As a result, a more uniform polishing rate is achieved across semiconductor substrate


38


, and it is polished with improved center to edge uniformity. It should be appreciated that this improved polishing uniformity increases die yield because die on the semiconductor substrate


38


are not over polished.





FIG. 2

illustrates, in plan view, a portion of polishing apparatus


10


of FIG.


1


. Note that, carrier


18


and polishing pad


16


are illustrated as being rotated in opposite directions.




FIG.


3


through

FIG. 6

illustrate, in cross-section, process steps in accordance with one embodiment of the present invention wherein a trench isolation structure is formed in an integrated circuit. Shown in

FIG. 3

, is a portion


46


of an integrated circuit structure comprising a semiconductor substrate


48


, a buffer layer


50


, a polish-stop layer


52


, and a photoresist mask


54


. Semiconductor substrate


48


is preferably a monocrystalline silicon substrate. Alternatively, semiconductor substrate


48


may be a silicon-on-insulator (SOI) substrate, a silicon-on-sapphire (SOS) substrate, a silicon-germanium substrate, or the like. Buffer layer


50


typically has a thickness ranging from 5 to 100 nanometers, and is preferably a thermal oxide layer which is formed by thermally oxidizing a portion of semiconductor substrate


48


. Alternatively, buffer layer


50


may be a chemical vapor deposited silicon oxide layer. Following the formation of buffer layer


50


, polish-stop layer


52


is formed over buffer layer


50


. Polish-stop layer


52


typically has a thickness ranging from 50 to 200 nanometers, and is preferably a silicon nitride layer. Alternatively, polish-stop layer


52


may be a boronitride layer, a silicon oxynitride layer, or the like. Photoresist mask


54


, which overlies a portion of polish-stop layer


52


, is formed using standard photolithographic patterning processes.




In

FIG. 4

, photoresist mask


54


is used to etch polish-stop layer


52


and underlying buffer layer


50


, and form a patterned trench mask


56


that overlies a portion of semiconductor substrate


48


. In addition, semiconductor substrate


48


is etched in regions not covered by patterned trench mask


56


to form trenches


58


in semiconductor substrate


48


. Note, patterned trench mask


56


comprises a remaining portion of polish-stop layer


52


and a remaining portion of buffer layer


50


. Trenches


58


and patterned trench mask


56


are formed using conventional etching techniques. It should be appreciated that photoresist mask


54


may be removed using conventional photoresist stripping techniques, either before or after trenches


58


have been formed.




In

FIG. 5

, a dielectric layer


60


is then formed overlying semiconductor substrate


48


. Dielectric layer


60


overlies pattern trench mask


56


and lies within trenches


58


, such that it substantially fills trenches


58


. In a preferred embodiment, dielectric layer


60


is a layer of plasma oxide, which is formed using a commercially available high density plasma deposition system. In an alternative embodiment, dielectric layer


60


is a layer of chemically vapor deposited oxide, which is deposited using ozone and tetraethylorthosilicate (TEOS) as source gases. It should be appreciated that dielectric layer


60


may also be formed using other dielectric materials, such as germanium oxide, boro-phosphate-silicate-glass (BPSG), phosphate-silicate-glass (PSG), boro-silicate-glass (BSG), spin-on-glass, or the like, and that it may be may be formed using other techniques such, electron cyclotron resonance deposition, spin-on deposition, or the like. In addition, it should also be appreciated that a trench liner (not shown) may also be formed within trenches


58


prior to forming dielectric layer


60


. For example, a portion of semiconductor substrate


48


may be thermally oxidized to form a thermal oxide layer along the sidewall and bottom of trenches


58


prior to depositing dielectric layer


60


. Note, the trench liner will have a thickness which is insufficient to fill trenches


58


.




In

FIG. 6

, dielectric layer


60


is then uniformly polished, as described above in

FIG. 1

, to expose a portion of patterned trench mask


56


, and leave a remaining portion


62


of dielectric layer


60


in trenches


58


. In one embodiment, dielectric layer


60


is a layer of silicon oxide and is polished using a slurry comprising potassium hydroxide, deionized water, and a silica abrasive. Alternatively, dielectric layer


60


may be polished using a slurry comprising potassium hydroxide, deionized water, and an alumina abrasive, or using a slurry comprising ammonium hydroxide, deionized water, and a silica abrasive. After being exposed, patterned trench mask


56


is then subsequently removed to define active regions and trench isolation regions within semiconductor substrate


48


(not shown). Patterned trench mask


56


is removed using a wet or a dry etch process, or a combination thereof.




FIG.


7


through

FIG. 9

illustrate, in cross-section, process steps in accordance with one embodiment of the present invention, wherein a planarized interlevel dielectric layer is formed in an integrated circuit. Shown in

FIG. 7

, is a portion


64


of an integrated circuit structure comprising a semiconductor substrate


66


, a dielectric layer


68


, and patterned conductive members


70


. Semiconductor substrate


66


is similar to semiconductor substrate


48


of FIG.


3


. In one embodiment, dielectric layer


68


is a gate dielectric layer. In an alternative embodiment, dielectric layer


68


is an interlevel dielectric layer. If dielectric layer


68


is a gate dielectric layer, then semiconductor substrate


66


is preferably thermally oxidized to form dielectric layer


68


. It should be appreciated, however, that other dielectric materials, such as silicon oxynitride or chemical vapor deposited silicon dioxide may also be used to form a gate dielectric layer. If dielectric layer


68


is an interlevel dielectric layer then dielectric layer


68


may be a layer of silicon dioxide, a layer of silicon nitride, a layer of boro-phosphate-silicate-glass (BPSG), a layer of phosphate-silicate-glass (PSG), a layer of spin-on-glass (SOG), a silicon oxynitride layer, a polyimide layer, or the like. In addition, a combination of the foregoing dielectric materials may also be used to form dielectric layer


68


. After dielectric layer


68


is formed, a conductive layer of material is formed overlying dielectric layer


68


, and then patterned using conventional lithographic processes to form conductive members


70


. Conductive members


70


may be formed using a doped polysilicon layer, a metal layer, a metal silicide layer, a metal nitride layer, or a combination thereof.




In

FIG. 8

, a dielectric layer


72


is then formed overlying semiconductor substrate


66


. Dielectric layer


72


may be a layer of silicon dioxide, a layer of silicon nitride, a layer of boro-phosphate-silicate-glass (BPSG), a layer of phosphate-silicate-glass (PSG), a layer of spin-on-glass (SOG), a silicon oxynitride layer, a polyimide layer, or the like. In addition, a combination of the foregoing dielectric materials may also be used to form dielectric layer


72


.




In

FIG. 9

, dielectric layer


72


is then uniformly polished, as described above in

FIG. 1

, to form a planarized interlevel dielectric layer


74


. In one embodiment, dielectric layer


72


is a layer of silicon oxide and is polished using a slurry comprising potassium hydroxide, deionized water, and a silica abrasive. Alternatively, dielectric layer


72


may be polished using a slurry comprising potassium hydroxide, deionized water, and an alumina abrasive, or using a slurry comprising ammonium hydroxide, deionized water, and a silica abrasive.




FIG.


10


through

FIG. 13

illustrate, in cross-section, process steps in accordance with one embodiment of the present invention, wherein a conductive member is formed in an integrated circuit. Shown in

FIG. 10

, is a portion


76


of an integrated circuit structure comprising a semiconductor substrate


78


, a conductive region


80


, a dielectric layer


82


, and a photoresist mask


84


. Semiconductor substrate


78


is similar to semiconductor substrate


48


of FIG.


3


. In one embodiment conductive region


80


is a doped region which has been formed within a portion of semiconductor substrate


78


. For example, it may be a doped source region, a doped drain region, a doped well contact, or the like. In an alternative embodiment, conductive region


80


is a patterned conductive member, such as a gate electrode, a contact plug, a via plug, an interconnect, or the like. Note, that if conductive region


80


is a gate electrode, a via plug, or an interconnect, then at least one dielectric layer (not shown) will lie between conductive region


80


and semiconductor substrate


78


. Dielectric layer


82


may be a layer of silicon dioxide, a layer of silicon nitride, a layer of boro-phosphate-silicate-glass (BPSG), a layer of phosphate-silicate-glass (PSG), a layer of spin-on-glass (SOG), a silicon oxynitride layer, a polyimide layer, or the like. In addition, a combination of the foregoing dielectric materials may also be used to form dielectric layer


82


. Photoresist mask


84


, which overlies a portion of dielectric layer


82


, is formed using standard photolithographic patterning processes.




In

FIG. 11

, dielectric layer


82


is etched using photoresist mask


84


to form an opening


86


within dielectric layer


82


. A portion of conductive region


80


is exposed within opening


86


, as shown in FIG.


11


. It should be appreciated that dielectric layer


82


may be etched using a wet or a dry etch process, or a combination thereof.




In

FIG. 12

, a barrier layer


88


is then formed overlying semiconductor substrate


78


. Barrier layer


88


overlies dielectric layer


82


and lies within opening


86


, such that it does not fill opening


86


. A conductive layer


90


is then formed overlying barrier layer


88


, such that opening


86


is substantially filled by conductive layer


90


. Barrier layer


88


may be a metal nitride layer, such as titanium nitride, tantalum nitride, tungsten nitride, tantalum-silicon nitride, or the like, or a metal layer, such a layer of titanium, a layer of tantalum, a layer of tungsten, or the like, or a combination thereof. For example, barrier layer


88


may be a composite layer of titanium and titanium nitride. Conductive layer


90


may be an aluminum layer, an aluminum alloy layer, a copper layer, a tungsten layer, a doped polysilicon layer, or the like.




In

FIG. 13

, conductive layer


90


and barrier layer


88


are then uniformly polished, as described above in

FIG. 1

, to form a conductive member


92


, such as a contact plug, a via plug, or an inlaid interconnect. In one embodiment, wherein conductive layer


90


is a tungsten layer and barrier layer


88


comprises titanium nitride, a slurry comprising ferric nitrate, deionized water, and a silica abrasive is used to form conductive member


92


. Alternatively, tungsten and titanium nitride may also be polished using a slurry comprising hydrogen peroxide, deionized water, and a silica abrasive. In an alternative embodiment, wherein conductive layer


90


is a copper layer and barrier layer


88


comprises tantalum, a slurry comprising hydrogen peroxide, deionized water, and a silica abrasive is used to form conductive member


92


.




Thus it is apparent that there has been provided, in accordance with the present invention, a polishing apparatus and a method for polishing a layer of material in an integrated circuit that fully meets the need and advantages set forth previously. Although the invention has been described and illustrated with reference to specific embodiments thereof, it is not intended that the invention be limited to these illustrative embodiments. Those skilled in the art will recognize that modifications and variations can be made without departing from the spirit of the invention. Therefore, it is intended that this invention encompass all such variations and modifications as fall within the scope of the appended claims.



Claims
  • 1. A method for forming an integrated circuit comprising the steps of:providing a substrate having a center and a perimeter; forming a layer of material overlaying the substrate; providing a polishing pad having a perimeter and a center, the polishing pad comprising a first polishing region, a second polishing region, and a third polishing region, wherein the second polishing region lies between the first polishing region and the third polishing region; aligning the substrate to the polishing pad such that the center of the substrate overlies the second polishing region, a first portion of the perimeter of the substrate overlies the first polishing region, and a second portion of the perimeter of the substrate overlies the third polishing region; and polishing the layer of material overlying the substrate using the polishing pad, wherein the center of the substrate remains at a fixed distance from the perimeter of the polishing pad while the layer of material is polished, wherein the first polishing region comprises a first plurality of holes having a first hole depth and a first hole width, the second polishing region comprises a second plurality of holes having a second hole depth and a second hole width, and the third polishing region comprises a third plurality of holes having a third hole depth and a third hole width, wherein the second hole depth to be greater than the first depth and the third hole depth.
  • 2. The method of claim 1, wherein the first polishing region has a first hole density, the second polishing region has a second hole density, and the third polishing region has a third hole density.
  • 3. The method of claim 2, wherein the second hole density is greater than the first hole density and the third hole density.
  • 4. The method of claim 1, wherein the second hole width to be greater than the first hole width and the third hole width.
  • 5. A method for forming an integrated circuit comprising the steps of:providing a substrate having a center and a perimeter; forming a layer of material overlying the substrate; providing a polishing pad having a perimeter and a center, the polishing pad comprising a first polishing region, a second polishing region, and a third polishing region, wherein the second polishing region lies between the first polishing region and the third polishing region; using an alignment detector to align the substrate to the second polishing region of the polishing pad, such that the center of the substrate overlies the second polishing region, a first portion of the perimeter of the substrate overlies the first polishing region, and a second portion of the perimeter of the substrate overlies the third polishing region; and polishing the layer of material overlying the substrate using the polishing pad, wherein the center of the substrate remains at a fixed distance from the perimeter of the polishing pad while the layer of the material is polished, wherein the first polishing region comprises a first plurality of holes having a first hole depth and a first hole width, the second polishing region comprises a second plurality of holes having a second hole depth and a second hole width, and the third polishing region comprises a third plurality of holes having a third hole depth and a third hole width, wherein the second hole width is different than the first hole width and the third hole width.
  • 6. The method of claim 5, wherein the second hole width is less than the first hole width and the third hole width.
  • 7. The method of claim 5, wherein the second hole width is greater than the first hole width and the third hole width.
  • 8. The method of claim 5, wherein the layer of material comprises a dielectric layer.
  • 9. The method of claim 5, wherein the second hole depth is different than the first hole depth and the third hole depth.
  • 10. The method of claim 9, wherein the second hole depth is greater than the first hole depth and the third hole depth.
  • 11. The method of claim 9, wherein the second hole depth is less than the first hole depth and the third hole depth.
  • 12. The method of claim 5, wherein the layer of material comprises a conductive layer.
  • 13. The method of claim 5, wherein the alignment detector comprises a laser.
  • 14. The method of claim 5, wherein the alignment detector comprises a video camera.
  • 15. The method of claim 5, wherein the layer of material is further characterized as a copper layer.
  • 16. The method of claim 15, further comprising the step of dispensing a slurry comprising hydrogen peroxide on the polishing pad.
  • 17. The method of claim 5, wherein the layer of material is further characterized as a tungsten layer.
  • 18. The method of claim 17, further comprising the step of dispensing a slurry comprising ferric nitrate on the polishing pad.
  • 19. The method of claim 5, wherein the layer of material is further characterized as a silicon oxide layer.
  • 20. The method of claim 19, further comprising the step of dispensing a slurry comprising potassium hydroxide on the polishing pad.
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