This patent document pertains generally to fuel cells, and more particularly, but not by way of limitation, to a portable or micro-fuel cell system and methods therefor.
A fuel cell is an electrochemical energy conversion device that utilizes the reaction of fuel and oxygen to produce electricity. Fuel cells operate continuously as long as fuel is present. When hydrogen is used as the fuel, the only by-product is water vapor. The conversion reaction of the fuel cell occurs electrochemically and the energy is released as a combination of electrical energy and heat. The electrical energy can do useful work directly, while the heat can be dispersed.
Portable electrical devices, such as cellular phones and laptop computers (among others), demand a significant amount of electricity to operate. The primary and optionally secondary batteries that currently provide power to these devices are reaching performance limitations. As such, it is likely that battery sources may not be able to provide the necessary power to future portable devices, which will likely require even greater electrical power needs. Fuel cells are a viable alternative power source to traditional batteries, but are currently limited by their relatively large size, low energy density levels and insufficient power output. These drawbacks of current fuel cells are the result of, among other things, the awkward integration of current fuel cell components and positioning requirements in electrical devices.
It is with this recognition of the foregoing state of the technology that the present subject matter providing a portable fuel cell system that is able to maintain a high energy density and provide sufficient power output within an all-inclusive system has been conceived and is now set forth in the text and drawings associated with this patent document.
Embodiments of the present subject relate to a fuel cell system. In one example, the fuel cell system includes at least one fuel cell or fuel cell layer including an anode, a cathode, and an electrolyte interposed therebetween; a fuel or a fuel storage material; a fuel reservoir including at least one surface positioned adjacent a first portion of the at least one fuel cell or fuel cell layer in which the fuel reservoir is configured to store the fuel or the fuel storage material; a current collecting circuit contacting a second portion of the at least one fuel cell or fuel cell layer in which the current collecting circuit is configured to receive and distribute current generated by the fuel cell or fuel cell layer; and a fuel plenum interposed between the at least one reservoir surface and the first portion of the at least one fuel cell or fuel cell layer.
In another example, the fuel cell system includes a fuel reservoir; a system cover; an enclosed region; and at least one fuel cell. The fuel reservoir is configured to store fuel or a fuel storage material. The system cover is configured to be attachable with the fuel reservoir, thereby forming an enclosed region therein. The at least one fuel cell includes one or more flexible walls comprising an anode or a cathode of the fuel cell. The flexible walls are structurally arranged to form a reactant plenum and are supported, when pressurized, by a portion of one or both of the fuel reservoir or the system cover.
Embodiments of the present subject matter also relate to methods of fabricating a fuel cell system. One method includes forming a fuel cell or a fuel cell layer; coupling a fuel reservoir with a first portion of the fuel cell or fuel cell layer such that a fuel plenum is formed therebetween; disposing a current collecting circuit adjacent to a second portion of the fuel cell or fuel cell layer; disposing a system cover having at least one air access port over one or more of the current collecting circuit, the fuel cell or fuel cell layer, or a portion of the fuel reservoir, including positioning the at least one air access port near the second portion of the fuel cell or the fuel cell layer; and coupling the system cover with the fuel reservoir.
Another method includes forming a fuel reservoir configured to store fuel therein; forming a system cover; coupling the system cover with a portion of the fuel reservoir including forming an enclosed region; and disposing at least one fuel cell in the enclosed region including arranging one or more flexible fuel cell walls to form at least one reactant plenum. In various examples, forming the fuel reservoir and system cover includes forming a support for the one or more flexible fuel cell walls.
These and other aspects, advantages, and features of the present systems and methods will become apparent from a consideration of the following description and associated drawings.
In the drawings, which are not necessarily drawn to scale, like numerals describe similar components throughout the several views. Like numerals having different letter suffixes represent different instances of similar components. The drawings illustrate generally, by way of example, but not by way of limitation, various embodiments discussed in the present patent document.
The following detailed description includes references to the accompanying drawings, which form a part of the detailed description. The drawings show, by way of illustration, specific embodiments in which the present systems and methods may be practiced. These embodiments, which are also referred to herein as “examples,” are described in enough detail to enable those skilled in the art to practice the present systems and methods. The embodiments may be combined, other embodiments may be utilized, or structural and logical changes may be made without departing from the scope of the present systems and methods. The following detailed description is, therefore, not to be taken in a limiting sense, and the scope of the present systems and methods are defined by the appended claims and their equivalents.
In this document, the terms “a” or “an” are used to include one or more than one, and the term “or” is used to refer to a nonexclusive or unless otherwise indicated. In addition, it is to be understood that the phraseology or terminology employed herein, and not otherwise defined, is for the purpose of description only and not of limitation. Furthermore, all publications, patents, and patent documents referred to in this document are incorporated by reference herein in their entirety, as though individually incorporated by reference. In the event of inconsistent usages between this document and those documents so incorporated by reference, the usage in the incorporated reference should be considered supplementary to that of this document; for irreconcilable inconsistencies, the usage in this document controls.
If they are going to be used to power electrical devices, such as cellular phones, satellite phones, laptop computers, computer accessories, displays, personal audio or video players, medical devices, televisions, transmitters, receivers, lighting devices including outdoor lighting or flashlights, electronic toys, power tools or any device conventionally used with batteries, it is desirable and even necessary for fuel cell systems to occupy only a small volume of the overall electrical device volume, maintain high energy density, and provide sufficient power output. However, current fuel cell systems are either too large to be use in the electrical devices or fail to maintain the high energy density and provide the energy required to power the electrical devices for a sufficient period of time. Advantageously, the present subject matter provides a fuel cell system that is able to maintain a high energy density and provide sufficient power output, yet still occupy a relatively small volume of the overall electrical device volume. In addition, the present fuel cell systems may operate passively, requiring no pumps, valves or heaters, and may instantly startup without having to rely on any supplemental battery or other power source.
Referring now to the drawings, particularly to
The fuel reservoir 104 may comprise a cellular fuel tank, such as is discussed in commonly-owned Zimmermann, U.S. patent application Ser. No. ______ (Attorney Docket No. 2269.004US1), entitled “CELLULAR RESERVOIR AND METHODS RELATED THERETO,” filed even date herewith, or as is discussed in commonly-owned Zimmermann, U.S. patent application Ser. No. 11/473,591 (Attorney Docket No. 2269.017US1), entitled “FLUID ENCLOSURE AND METHODS RELATED THERETO,” filed on Jun. 23, 2006, the disclosures of which are incorporated herein by reference in their entirety. The fuel reservoir 104 encloses a fuel, such as hydrogen, or a fuel storage material, such as a hydrogen storage material as is discussed in commonly-owned Zimmermann, U.S. patent application Ser. No. 11/379,970 (Attorney Docket No. 2269.008US1), filed on Apr. 24, 2006, the disclosure of which is incorporated herein by reference in its entirety. In one example, the hydrogen storage material includes a metal hydride. The hydrogen storage material may store hydrogen using one or both of physisorption or chemisorption techniques.
As illustrated in
Power from the fuel cell layer 102 may be gathered by a current collecting circuit 106, which collects the current generated by the fuel cell layer 102 and routes it out of the system 100 via a power output connector 116 or alternatively into the conditioning electronics section 120 (e.g., an electronic conditioning circuit). In the example shown, but as may vary, the power output connector 116 is attached to both the current collector circuit 106 and the optional conditioning electronics section 120. The current collecting circuit 106 may be flexible to conform to a shape or location of the fuel cell layer 102 or other fuel cell system component. In one example, the fuel cell system 100 provides a peak power output of up to about 4 Watts, while in other examples, the fuel cell system 100 may provide a peak power output of about 2-3 Watts. In various examples, the average power output of the fuel cell system is between about 0.2-1.8 Watts, such about 0.5-1.5 Watts, about 0.75-1.25 Watts, or about 1 Watt. In various examples, the fuel cell system 100 provides an energy density of about 200-600 Watt-hr/L or more, such as about 250-350 Watt-hr/L or about 300 Watt-hr/L. In various examples, the fuel cell system 100 includes a size of about 25 cubic centimeters or less. In certain examples, the size of the fuel cell system 100 is about 10 cubic centimeter or less.
In various examples, the fuel reservoir 104 includes a refueling port 112 and a pressure regulator 110. The refueling port 112 may be a pressure activated valve that allows a flow of fluid, for example, fluid fuel, into the fuel reservoir 104. In one example, the refueling port 112 includes the type discussed in Zimmermann, U.S. patent application Ser. No. ______ (Attorney Docket No. 2269.003US1), entitled “REFUELING VALVE FOR A FUEL STORAGE SYSTEM AND METHOD THEREFOR,” filed even date herewith, the disclosure of which is incorporated herein by reference in its entirety. In the example shown, the refueling valve 112 is coupled with a lower wall 114 of the fuel reservoir 104.
The pressure regulator 110 may be designed to reduce a fuel reservoir pressure to a more constant, lower pressure that is acceptable to the fuel cell layer 102. In one example, the pressure regulator 110 is integrated with an upper wall 115 of the fuel reservoir 104 and includes one or more of a regulator body, a resilient member, a diaphragm, a regulator valve, or a seal member. In such an example, the diaphragm and the regulator valve may be movingly responsive to a pressure difference between a first chamber pressure and a second chamber pressure.
In the example shown, a fuel plenum 212 (
Optionally, the fuel cell system 100 may comprise a system cover 124 or a porous protective member 118. The system cover 124 may be utilized to assist the attachment of such things as the fuel cell layer 102 and the fuel reservoir 104. Among other things, the system cover 124 may be constructed of a rigid, but ductile material, such as steel or aluminum. Other examples of suitable materials for the system cover 124 include rigid plastics, such as Ultem® (a registered trademark of General Electric Company) or polyethylene. In various examples, the system cover 124 includes one or more air access ports 206 (
The porous protective member 118 may provide protection to the fuel cell cathode 108 while still allowing air to flow thereto. In one example, the porous protective member 118 protects the cathode 108 from interferents in the ambient air. In certain examples, the porous protective member 118 may be disposed adjacent to the fuel cell layer 102 on the anode side to provide protection to the anode 107 while still allowing fuel to flow therethrough.
In this example, as fuel (e.g., hydrogen) flows 210 from the fuel reservoir 104, through the pressure regulator 110, and into the fuel plenum 212, the fuel pressure 202 exerts a force on the fuel cell layer 102 in a direction toward the current collecting circuit 106, providing a contact therebetween. As shown, the mechanical binding of the system cover 124 to the fuel reservoir 104 exerts a cover pressure 204 on the current collecting circuit 106 toward the fuel cell layer 102 (i.e., in the opposite direction of fuel pressure 202), further providing efficient contact between the components of fuel cell system 100.
There are many options for the fuel cell system 100. For instance, in certain examples, the fuel plenum 212 includes a size less than about 1 mm in width (wherein the width is the distance substantially perpendicular to the fuel reservoir 104 and extending from the fuel reservoir 104 to the fuel cell layer 102), while in other examples, the fuel plenum 212 includes a width greater than 1 mm. In certain examples, the current collecting circuit 106 may be disposed underneath the fuel cell layer 102, integrated with the fuel cell layer 102, or within the fuel plenum 212, rather than contacting a second side 252 of the fuel cell layer 102. In such examples, the connection between the fuel cell layer 102 and the current collecting circuit 106 may not be activated by the outward force 202 created through the fuel pressure, but rather through a more positive means of connection (e.g., a bonding process).
At 406, a current collecting circuit is disposed adjacent to a second portion of the at least one fuel cell. In one example, the current collecting circuit is electrically coupled with a portable electronic device. In another example, the current collecting circuit is electrically coupled with an electronic conditioning circuit.
Further, at 408, a system cover having at least one air access port is disposed over one or more of the current collecting circuit, the at least one fuel cell, or a portion of the fuel reservoir, in which the at least one air access port is positioned near the second portion of the at least one fuel cell. In one example, a protective porous member is disposed between the at least one air access port and the second portion of the at least one fuel cell. At 410, the system cover is coupled with the fuel reservoir. In one example, the system cover is coupled to the fuel reservoir by welding, soldering, brazing, crimping, gluing, thermal adhesive, pressure sensitive adhesive, or one or more mechanical structures (e.g., fasteners or protrusions). The mechanical structure may optionally be releasable.
Referring now to
The system cover 124 is attachable with a portion of fuel reservoir 104 via, among other things, a weld, a solder, a braze, a crimp, the use of an adhesive, or one or more mechanical structures, thereby forming the enclosed region 504, as shown. The one or more fuel cell layers 102 may be disposed in the enclosed region 504 such that their respective flexible walls 502 are structurally arranged to form at least one reactant plenum 506. The one or more flexible walls 502 are supported by a portion of one or both of the fuel reservoir 104 or the system cover 124. In various examples, the cathode 108 may be accessible from an outside of the flexible wall 502 and exposed to ambient air via air access ports in the system cover 124, while the anode 107 may be accessible from an inside of the flexible wall 502 and exposed to a reactant, such as hydrogen fuel, as is discussed in commonly-owned Mclean et al., U.S. patent application Ser. No. 11/327,516, entitled “FLEXIBLE FUEL CELL STRUCTURES HAVING EXTERNAL SUPPORT,” filed on Jan. 9, 2006, and commonly-owned Mclean et al., U.S. patent application Ser. No. 11/185,755, entitled “DEVICES POWERED BY CONFORMABLE FUEL CELLS,” filed on Jul. 21, 2005, the disclosures of which are hereby incorporated by reference in their entirety. The current collecting circuit 106 (integral with the fuel cell layer 102) is configured to receive current generated by the fuel cell layer 102 and distribute such current to, for example, a portable electronic device.
In various examples, a plenum inlet 550 fluidly connects the reactant plenum 506 and the fuel reservoir 104 or ambient air. As reactant enters via the plenum inlet 550, a reactant pressure pressurizes the fuel plenum 506, thus urging the one or more flexible walls 502 of the fuel cell layer 102 toward the supporting portions of one or both of the fuel reservoir 104 or the system cover 124.
At 608, at least one fuel cell including an anode, a cathode, and an electrolyte interposed therebetween is disposed in the enclosed region. In various examples, multiple fuel cells are formed to create a fuel cell layer. In one example, one or more flexible fuel cell walls comprise one or both of the fuel cell anode or the fuel cell cathode. Accordingly, in another example, disposing the at least one fuel cell into the enclosed region includes arranging the one or more flexible fuel cell walls to form at least one reactant plenum. In various examples, forming the fuel reservoir and the system cover includes forming a support for the one or more flexible fuel cell walls such that when a reactant enters a plenum inlet and pressurizes the reactant plenum, the fuel cell walls expand and conform to a shape of the one or more supports.
At 610, a current collecting circuit is integrated with the at least one fuel cell. In various examples, the current collecting circuit is configured to collect current from the at least one fuel cell and distribute such current to one or more electrical devices, such as portable electrical devices.
Fuel cell systems and methods for their manufacture are provided herein. Among other things, the present systems and methods provide for a fuel cell system providing sufficient power output and a high energy density, all within a relatively small amount of space. The fuel cell system can operate as a stand alone power source or be integrated into an electrical device. Further, the fuel cell system need not rely on pumps, valves or heaters for its operation, saving precious energy and electrical device volume.
It is to be understood that the above description is intended to be illustrative, and not restrictive. For example, the above-described embodiments (and/or aspects thereof) may be used in combination with each other. Many other embodiments will be apparent to those of skill in the art upon reviewing the above description. The scope of the invention should, therefore, be determined with reference to the appended claims, along with the full scope of equivalents to which such claims are entitled. In the appended claims, the terms “including” and “in which” are used as the plain-English equivalents of the respective terms “comprising” and “wherein.”Also, in the following claims, the terms “including” and “comprising” are open-ended, that is, a system, device, article, or process that includes elements in addition to those listed after such a term in a claim are still deemed to fall within the scope of that claim. Moreover, in the following claims, the terms “first,” “second,” and “third,” etc. are used merely as labels, and are not intended to impose numerical requirements on their objects.
The Abstract of the Disclosure is provided to comply with 37 C.F.R. §1.72(b), requiring an abstract that will allow the reader to quickly ascertain the nature of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. In addition, in the foregoing Detailed Description, various features may be grouped together to streamline the disclosure. This method of disclosure is not to be interpreted as reflecting an intention that the claimed embodiments require more features than are expressly recited in each claim. Rather, as the following claims reflect, inventive subject matter may lie in less than all features of a single disclosed embodiment. Thus the following claims are hereby incorporated into the Detailed Description, with each claim standing on its own as a separate embodiment.
This non-provisional application claims the benefit of priority under 35 U.S.C. §119(e) to U.S. Provisional Patent Application Ser. No. 60/757,750, filed Jan. 9, 2006, which is herein incorporated by reference in its entirety.
Number | Date | Country | |
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60757750 | Jan 2006 | US |